Meteorite infall as a function of mass: Implications for the accumulation of meteorites on Antarctic ice

Abstract— Antarctic meteorites are considerably smaller, on average, than those recovered elsewhere in the world, and seem to represent a different portion of the mass distribution of infalling meteorites. When an infall rate appropriate to the size of Antarctic meteorites is used (1000 meteorites 10 grams or larger/km²/10⁶ years), it is found that direct infall can produce the meteorite accumulations found on eight ice fields in the Allan Hills region in times ranging from a few thousand to nearly 200 000 years, with all but the Allan Hills Main and Near Western ice fields requiring less than 30 000 years. Meteorites incorporated into the ice over time are concentrated on the surface when the ice flows into a local area of rapid ablation. The calculated accumulation times, which can be considered the average age of the exposed ice, agree well with terrestrial ages for the meteorites and measured ages of exposed ice. Since vertical concentration of meteorites through removal of ice by ablation is sufficient to explain the observed meteorite accumulations, there is no need to invoke mechanisms to bring meteorites from large areas to the relatively small blue-ice patches where they are found. Once a meteorite is on a bare ice surface, freeze-thaw cycling and wind break down the meteorite and remove it from the ice. The weathering lifetime of a 100-gram meteorite on Antarctic ice is on the order of 10 000 ± 5000 years.     

Thermoluminescence survey of 12 meteorites collected by the European 1988 Antarctic meteorite expedition to Allan Hills and the importance of acid washing for thermoluminescence sensitivity measurements

Abstract— Natural and induced thermoluminescence (TL) data are reported for 12 meteorites recovered from the Allan Hills region of Antarctica by the European field party during the 1988/89 field season. The samples include one with extremely high natural TL, ALH88035, suggestive of exposure to unusually high radiation doses (i.e., low degrees of shielding), and one, ALH88034, whose low natural TL suggests reheating within the last 10⁵ years. The remainder have natural TL values suggestive of terrestrial ages similar to those of other meteorites from Allan Hills. ALH88015 (L6) has induced TL data suggestive of intense shock. TL sensitivities of these meteorites are generally lower than observed falls of their petrologic types, as is also observed for Antarctic meteorites in general. Acid-washing experiments indicate that this is solely the result of terrestrial weathering rather than a nonterrestrial Antarctic—non-Antarctic difference. However, other TL parameters, such as natural TL and induced peak temperature-width, are unchanged by acid washing and are sensitive indicators of a meteorite's metamorphic and recent radiation history.     

The meteorite collection sites of Antarctica

Abstract— Antarctic meteorites have been and are being well studied but the potential for glaciological and climatological information in the sites where they are found is only beginning to be realized. To date, meteorite stranding surfaces have been identified only in East Antarctica: (1) The MacKay Glacier/David Glacier region contains the Allan Hills and the Reckling Moraine/Elephant Moraine stranding surfaces. Because the Allan Hills Main Icefield has a large proportion of meteorites with long terrestrial ages, these concentrations of meteorites must have had catchment areas extending well inland, in contrast to the present. Where known, bedrock topography is mesa-like in form and influences ice flow directions. Ice levels at the Allan Hills may have been higher by 50–100 m in the past. Reckling Moraine and Elephant Moraine are located on a long patch of ice running westward from Reckling Peak; the ice appears to be pouring over a bedrock escarpment. (2) In North Victoria Land, ice diverges around Frontier Mountain and flows into a site behind the barrier where ablation occurs extensively. It is proposed that meteorites and rocks were dumped by ice flow at the mouth of a valley in the lee of the mountain at the site where a meltwater pond existed, in a depression produced by ablation. Later, the pond migrated headward along the valley to a point where it is today, leaving a morainal deposit with the meteorites at a higher level. (3) Between the Beardmore and Law Glaciers, ice flows sluggishly into the southwestern margin of the Walcott Névé. Northeastern sections of the Walcott are virtually barren of meteorites. The entering Plateau ice is diverted northward to flow along the base of Lewis Cliff. This flow apparently terminates in an ice tongue protruding into a vast moraine, where a very large concentration of meteorites was found on the ice. This final segment of flowing ice is called the Lewis Cliff Ice Tongue. Meteorite Moraine, a subsidiary occurrence 2 km to the northeast, is also found against morainal deposits. The origin of the moraines and the history of meteorite concentration at this site is the subject of some debate. (4) The Transantarctic Mountains are submerged along one segment many hundreds of km in length by ice flowing off the Polar Plateau. The Thiel Mountains, Pecora Escarpment and Patuxent Range are the only surface indications of the underlying mountains along this interval, and meteorite stranding surfaces are found at each of these sites. Little is yet known about ice dynamics at these sites. (5) The immense Yamato Mountains meteorite stranding surface covers an area of about 4000 km². So far, most meteorites have been recovered in the upper reaches of this blue ice field, where ice flow is slowed by outlying subice barriers of the Yamato Mountains. Individual massifs in this range extend northward over 50 km, and the Yamato Meteorite Icefield loses 1100 m in elevation over this distance. (6) The Sør Rondane Mountains form a barrier to ice flow off the Polar Plateau. The major meteorite stranding surface associated with this barrier is the Nansenisen Icefield, a large ablation area about 50 km upstream of the mountains. The existence of a meteorite stranding surface at this site has not been explained so far. Most meteorite stranding surfaces have been functioning for a long time. They are sites where net ablation of the surface is occurring; the ice at these sites is stagnant or flowing only slowly, and the numbers of meteorites with great terrestrial ages decrease exponentially. Concentration mechanisms operating at these sites involve ablation, direct infall, time, low temperatures, moderate weathering and wind ablation. Detrimental to concentration are ice flow out of the area and extreme weathering. In spite of the fact that the Antarctic Ice Sheet is thought to be over 10 Ma old, we do not find stranding surfaces with meteorites having greater terrestrial ages than 1 Ma. This suggests that stranding surfaces are transient features, affected on a continental scale by possible extreme warming during late Pliocene and on a smaller scale by regional changes that produce differential effects between icefields. The latter effect is suggested by differences in the average terrestrial age of meteorites at different stranding surfaces. In either case, these sites seem to appear as a result of thinning near the edges of the ice sheet, and stratigraphic sequences may be exposed in the ice at stranding surfaces. We review five models for the production of meteorite stranding surfaces: (1) simple deflation of the ice sheet, in which ablation removes great thicknesses of overlying ice, exposing the contained meteorites while allowing direct falls to accumulate, (2) simple accumulation of direct falls on a bare ice surface that is not deflating, (3) ablation of ice trapped against a barrier, in which meteorites accumulate by direct infall while inflowing ice contributes meteorites by ablation discovery, (4) deceleration of ice by a subice barrier, which allows ablation discovery of meteorites in incoming ice and accumulation of other meteorites on the surface by direct infall and (5) stagnation of ice by encounter with an ice mass able to produce an opposing flow vector, in which ablation discovery and direct infall accumulation processes operate to build the meteorite concentration.     

Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

Amino acids in Antarctic CM1 meteorites and their relationship to other carbonaceous chondrites

Abstract— CM2 carbonaceous chondrites are the most primitive material present in the solar system, and some of their subtypes, the CM and CI chondrites, contain up to 2 wt% of organic carbon. The CM2 carbonaceous chondrites contain a wide variety of complex amino acids, while the CI1 meteorites Orgueil and Ivuna display a much simpler composition, with only glycine and β‐alanine present in significant abundances. CM1 carbonaceous chondrites show a higher degree of aqueous alteration than CM2 types and therefore provide an important link between the CM2 and CI1 carbonaceous chondrites. Relative amino acid concentrations have been shown to be indicative for parent body processes with respect to the formation of this class of compounds. In order to understand the relationship of the amino acid composition between these three types of meteorites, we have analyzed for the first time three Antarctic CM1 chondrites, Meteorite Hills (MET) 01070, Allan Hills (ALH) 88045, and LaPaz Icefield (LAP) 02277, using gas chromatography‐mass spectrometry (GC‐MS) and high performance liquid chromatography‐fluorescence detection (HPLC‐FD). The concentrations of the eight most abundant amino acids in these meteorites were compared to those of the CM2s Murchison, Murray, Mighei, Lewis Cliff (LEW) 90500, ALH 83100, as well as the CI1s Orgueil and Ivuna. The total amino acid concentration in CM1 carbonaceous chondrites was found to be much lower than the average of the CM2s. Relative amino acid abundances were compared in order to identify synthetic relationships between the amino acid compositions in these meteorite classes. Our data support the hypothesis that amino acids in CM‐ and CI‐type meteorites were synthesized under different physical and chemical conditions and may best be explained with differences in the abundances of precursor compounds in the source regions of their parent bodies in combination with the decomposition of amino acids during extended aqueous alteration.     

Fluid mobilization of rare earth elements,Th, and U during the terrestrial alteration of H chondrites

The chemical effects of terrestrial alteration, with a particular focus on lithophile trace elements, were studied for a set of H chondrites displaying various degrees of weathering from fresh falls to altered finds collected from hot deserts. According to their trace element distributions, a considerable fraction of rare earth elements (REEs), Th, and U resides within cracks observed in weathered meteorite specimens. These cracks appear to accumulate unbound REEs locally accompanied by Th and U relative to the major element abundances, especially P and Si. The deposition of Ce is observed in cracks in the case of most of the weathered samples. Trace element maps visually confirm the accumulation of these elements in such cracks, as previously inferred based on chemical leaching experiments. Because the positive Ce anomalies and unbound REE depositions in cracks occur in all weathered samples studied here while none of such features are observed in less altered samples including falls (except for altered fall sample Nuevo Mercurio), these features are interpreted to have been caused by terrestrial weathering following chemical leaching. However, the overall effects on the bulk chemical composition remain limited as the data for all Antarctic meteorites studied in this work (except for heavily weathered sample A 09516, H6) are in good agreement with published data for unaltered meteorites.     

Mass distribution of Antarctic ordinary chondrites and the estimation of the fall-to-specimen ratios

Abstract— The cumulative mass distributions (mass range > 100 g) of each type of Japanese and U.S. Antarctic ordinary chondrites are compared with those of non-Antarctic falls and those obtained from the present-day flux of meteorites. The steeper slope of the mass distribution of Antarctic chondrites is indicative of the presence of several chondrite showers. The fall-to-specimen ratio of Antarctic ordinary chondrites larger than 100 g is about 1:2, indicating that half of them are shower components. The fall-to-specimen ratios of each group range from 1:1 to 1:6; those of the Japanese and U.S. Antarctic meteorite collections are 1:1 to 1:2 and 1:4 for H chondrites, 1:1 to 1:2 and 1:2 for L chondrites, and 1:2 and 1:6 for LL chondrites, indicating that the Japanese collection includes less abundant shower components than the U.S. collection. The fall-to-specimen ratios of each H4-6 and L4-6 type range from 1:1 to 1:4, and U.S. H6 and Japanese H4 have the low ratios of 1:4.     

A preliminary investigation into the nature of carbonaceous material in ordinary chondrites

Abstract— The nature and isotopic composition of carbonaceous components in a variety of ordinary chondrites have been studied using stepped combustion. The samples were chosen to include falls, finds and Antarctic meteorites; specimens from all three chemical groups (H, L and LL) have been analysed. Effort was concentrated mostly on the low petrologic type meteorites (i.e., type 3); however, types 4–6 were also included in the study. Apart from terrestrial contaminants and weathering products, some of the unequilibrated ordinary chondrites appear to contain an indigenous organic component. In addition, most of the samples studied show evidence for an amorphous/graphitic component. This exists as C-rich aggregates or as carbon associated with “Huss” matrix. There does not appear to be any difference in δ¹³C for this carbon between Antarctic and non-Antarctic meteorites. In contrast, low temperature carbon in Antarctic samples is characterized by a ¹³C-enrichment. This is thought to be due to the influence of terrestrial weathering products introduced in the Antarctic. Curiously, the low temperature carbon in non-Antarctic finds appears to be intermediate in δ¹³C between Antarctic finds and non-Antarctic falls. This suggests that the weathering processes which are so obviously apparent from Antarctic samples may also extend, albeit in a more limited way, to non-Antarctic meteorites.     

The flux of meteorites on the Earth's surface

Abstract— We derive values for the number and size distributions of meteorites landing on Earth from a study of photographic observations of bright fireballs with the Canadian camera network. The observations cover 11 years from 1974 to 1985. This analysis is an extension of a previous study and represents a 30% increase in the data base. The cumulative plot of numbers vs estimated mass of the largest fragment for each event shows a change in slope near 0.6 kg due to a deficiency of small meteorites surviving from the group of slow fireballs. The change can be explained by a mass dependence of the fraction of the incoming object that survives as the largest fragment. For larger falls, the main mass appears to represent a decreasing fraction of the total mass of the surviving meteorites and estimates of these effects are used to derive the final distribution of both main masses and total masses of meteoritic events. For total masses greater than 1 kg the population index is 1.82, close to previous estimates. About 9 events per year drop at least 1 kg of meteorites in an area of a million square km and the same area receives an annual influx of 54 kg from meteorite events with total masses between 0.01 and 100 kg. There is sufficient confidence in these results that they may be used for comparison of the present flux of meteorites with values inferred for other times, in particular the long accumulation times of the Antarctic meteorite collections.     

Cosmogenic radionuclides and noble gases in Antarctic H chondrites with high and normal natural thermoluminescence levels

Abstract— We report noble gas data for 37 H chondrites collected from the Allan Hills by EUROMET in the 1988–1989 field season. Among these are 16 specimens with high levels (>100 krad) of natural thermoluminescence (NTL), originally interpreted as signaling their derivation from a single meteoroid with an orbit that became Earth‐crossin‐100 ka ago. One of these 16 is an H3 chondrite with a cosmic‐ray exposure age of ～33 Ma and clearly represents a separate fall. The other 15 H4–6 chondrites derive from three separate meteoroids, each of which is represented by a five or six member group. These groups have mean exposure ages of 3.7, 4.1, and 6.6 Ma: the middle‐group members all contain solar Ne. The two younger groups also seem to each include a few H chondrites with normal NTL levels. Measurements of cosmogenic ¹⁰Be (1.5 Ma), ²⁶AI (710 ka), and ³⁶CI (301 ka) in 14 of the high‐NTL chondrites indicate that all reflect a simple irradiation history. In contrast, many of a different (38 member) randomly selected suite of Antarctic H chondrites seem to have different cosmic‐ray irradiation histories. The 3.7 and 6.6 Ma groups from the 37 member Allan Hills suite come from about 5–30 and about 5–10 cm depths in 80–125 and 60–125 cm radius meteoroids, respectively.     

YAMATO METEORITES COLLECTED IN ANTARCTICA IN 1969

The meteoritic community has been tantalized by reports of extensive meteorite finds in Antarctica by members of the Japanese Antarctic Research Expedition. The National Institute of Polar Research has published this introduction and review of the Yamato meteorites collected in Antarctica in 1969. This welcome review reveals that nine meteorite fragments of meteoritic material were found in the region of the Yamato Mountains. Four pieces greater than 60 g in weight have been identified as an enstatite chondrite, a hypersthene achondrite, a type III carbonaceous chondrite and a bronzite chondrite. In 1973 eleven additional suspected meteorites were recovered. Preliminary results show that three bronzite chondrites and one achondrite are among the new finds. In 1974 over 600 pieces of meteorite-like rock have been collected. The volume contains five articles on the original 1969 material. These include a general discussion on their discovery including photographs of the individuals, and notes on the chemical, mineralogical and petrological characteristics of the four large samples. Two articles deal with detailed mineralogic and magnetic properties of these specimens. Information on these interesting finds is welcome. Information on the 1969 and 1974 material is anxiously awaited.     

Carbonates in CM chondrites: Complex formational histories and comparison to carbonates in CI chondrites

Abstract– CM chondrites are primitive solar‐system materials that have undergone high degrees of aqueous alteration, resulting in the formation of secondary minerals including carbonates. Two different carbonate minerals (calcite/aragonite and dolomite) together constitute 1.4–2.8 vol% of CM chondrites. In contrast, CI chondrites contain four different carbonate minerals: calcite/aragonite, dolomite, breunnerite, and siderite. CI chondrites have abundant dolomite, a mineral that seems to be absent in the most aqueously altered CM chondrites. In this study, carbonates in seven CM chondrites (Y‐791198, LaPaz Icefield 04796, Cold Bokkeveld, Nogoya, Queen Alexandra Range 93005, Allan Hills 83100, and Meteorite Hills 01070) were studied petrographically and by electron microprobe. The results indicate that carbonate formation in CM chondrites differs from that in CI chondrites and is more complex than previously recognized. Our studies of CM chondrites indicate that (1) carbonates formed on the parent asteroid in an aqueous environment that gradually changed in composition, (2) at some stage, Ca and Mg activities in the environment were high enough to form metastable dolomite, and (3) dolomites disappeared in the most aqueously altered CM chondrites.     

Terrestrial microfossils in Antarctic ordinary chondrites

Abstract— Microfossils have been separated and identified in four high metamorphic grade chondrites from Allan Hills and Queen Alexandra Range, Antarctica. Diatoms and opal phytoliths representing both marine and terrestrial flora were recognized among the dust removed from cracks in all meteorites studied. It is likely that contamination of Antarctic meteorites with such biogenic material is ubiquitous. Standard clean room procedures to avoid laboratory introduction of microfossils into the meteorites were followed, and the genera and species identified so far are characteristic of marine, freshwater, and continental environments. The most probable mechanism for introduction of the microfossils into the meteorites is eolian transport to and on the polar ice cap. It is likely that wind-driven systems may sample atmospherically transported material from large portions of the southern hemisphere. Entrainment of terrestrial microfossils is probably a typical interaction of meteorites with the Antarctic environment and must be recognized and accounted for in any attempt to use Antarctic meteorites as sources of extraterrestrial life forms. Organic molecules derived from microfossils are likely to be pervasive throughout any crack network present in a meteorite at all scales from millimeter to submicron. Cracks are a ubiquitous consequence of weathering in and on the Antarctic ice and the probability that crack surfaces contain terrestrial organic materials is high.     

Chemical analyses of meteorites: A compilation of stony and iron meteorite analyses

Abstract— A compilation of the chemical analyses of 241 stony and 36 iron meteorites is presented; 196 analyses were published previously, 81 are new. This compilation includes analyses of new falls, new finds, previously analyzed meteorites, previously analyzed meteorites with suspect values, analyses of separates and inclusions, and analyses of 53 stony and 29 iron meteorites from Antarctica, including one of the “lunar” type. Mean compositions of chondrite falls, finds, and Antarctic chondrites are compared. References are listed for earlier published analyses and an appendix provides an outline of the sampling procedures, sample preparation, and the analytical methods.     

Investigations into an unknown organism on the martian meteorite Allan Hills 84001

Abstract— Examination of fracture surfaces near the fusion crust of the martian meteorite Allan Hills (ALH) 84001 have been conducted using scanning electron microscopy (SEM) and atomic force microscopy (AFM) and has revealed structures strongly resembling mycelium. These structures were compared with similar structures found in Antarctic cryptoendolithic communities. On morphology alone, we conclude that these features are not only terrestrial in origin but probably belong to a member of the Actinomycetales, which we consider was introduced during the Antarctic residency of this meteorite. If true, this is the first documented account of terrestrial microbial activity within a meteorite from the Antarctic blue ice fields. These structures, however, do not bear any resemblance to those postulated to be martian biota, although they are a probable source of the organic contaminants previously reported in this meteorite.     

Allan Hills 88019: An Antarctic H-chondrite with a very long terrestrial age

Abstract— We have measured the concentrations of the cosmogenic radionuclides ¹⁰Be, ²⁶Al and ³⁶Cl (half-lives 1.51 Ma, 716 ka, and 300 ka, respectively) in two different laboratories by accelerator mass spectrometry (AMS) techniques, as well as concentrations and isotopic compositions of stable He, Ne and Ar in the Antarctic H-chondrite Allan Hills (ALH) 88019. In addition, nuclear track densities were measured. From these results, it is concluded that the meteoroid ALH 88019 had a preatmospheric radius of (20 ± 5) cm and a shielding depth for the analyzed samples of between 4 and 8 cm. Using calculated and experimentally determined production rates of cosmogenic nuclides, an exposure age of ～40 Ma is obtained from cosmogenic ²¹Ne and ³⁸Ar. The extremely low concentrations of radionuclides are explained by a very long terrestrial age for this meteorite of 2 ± 0.4 Ma. A similarly long terrestrial age was found so far only for the Antarctic L-chondrite Lewis Cliff (LEW) 86360. Such long ages establish one boundary condition for the history of meteorites in Antarctica.     

Assessment of petrologic subtypes,subgroups, and pairing within CV chondrites in the US Antarctic meteorite collection

Carbonaceous chondrites of the Vigarano group (CV) are primitive (nearly un-metamorphosed) meteorites that provide a wealth of information about the early solar system, including constraints on chondrule formation, origin of calcium-aluminum inclusions, stability of organic compounds, and redox conditions. The US Antarctic meteorite collection contains 119 CV samples from 15 dense collection areas (DCAs) from the TransAntarctic Mountains; these samples have been assigned a preliminary classification as CVs, but not to the subgroups oxidized A, oxidized B, and reduced. Furthermore, variation in petrologic grade can be determined non-destructively using Raman spectroscopy. To update the classification of both subgroups and petrologic types in the collection, we have acquired magnetic susceptibility, metal and sulfide compositions, and Raman spectra. Overall, there are 55 oxidized A samples, 18 oxidized B samples, and 46 reduced samples. Several of the CVs are quite primitive (Lewis Cliffs Ice Tongue and MacAlpine Hills) but are also very small. Multiple pairing groups have been identified in the Miller Range (MIL), Queen Alexandra Range, and Larkman Nunatak DCAs, including all of the subgroups. In MIL 090981, there is evidence for multiple lithologies. We make suggested updates for all the samples, knowing that this information will help to better guide researchers interested in studying the CV chondrites in the US Antarctic meteorite collection.     

An impact-melt origin for lithology A of martian meteorite Elephant Moraine A79001

Abstract— Mixing models using major and trace elements show that the bulk composition of lithology A (xenocryst-bearing magnesian basalt) of Elephant Moraine A79001 (EETA79001) can be reasonably approximated as a simple mixture of ～44% EETA79001 lithology B (ferroan basalt) and ～56% of Allan Hills A77005 (ALHA7705) light lithology (incompatible element-poor lherzolite). Micro-instrumental neutron activation analysis (INAA) data on xenocryst-free groundmass samples of lithology A show that about 20–25% of the melt phase could be dissolved lherzolite. The bulk and groundmass samples of lithology A have excesses in Au, which indicates either meteoritic contamination or addition by some unknown martian geochemical process. Previous workers have suggested that lithology A was formed by either assimilation of cumulates (like ALHA77005), by a basalt (like lithology B), or by mixing of basaltic and lherzolitic magmas. The former scenario is energetically improbable and unlikely to explain the normal Fe/Mg zonation in lithology A groundmass pyroxenes, whereas the latter scenario is unlikely to satisfy the constraints of the mixing model indicating the ultramafic component is poor in incompatible elements. We suggest rather that EETA79001 lithology A is an impact melt composed dominantly of basalt like lithology B and lherzolitic cumulates like the trace-element-poor fraction of ALHA77005 or Y-793605. This model can satisfy the energetic, petrologic, and geochemical constraints imposed by the samples. If EETA79001 lithology A is an impact melt, this would have considerable consequences for current models of martian petrologic evolution. It would call into question the generally accepted age of magmatism of martian basalts and preclude the use of lithology A groundmass as a primary martian basalt composition in experimental studies. Regardless, the latter is required because lithology A groundmass is a hybrid composition.     

Thermally metamorphosed carbonaceous chondrites from data for thermally mobile trace elements

Abstract— We report radiochemical neutron activation analysis (RNAA) data for U, Co, Au, Sb, Ga, Rb, Cs, Se, Ag, Te, Zn, In, Bi, Tl, and Cd (ordered by increasing ease of vaporization and loss from the Murchison CM2 chondrite during open-system heating) in nine Antarctic C2 and C3 chondrites. These meteorites exhibit properties (obtained by reflectance spectroscopy, O isotopic mass spectrometry and/or mineralogy-petrology) suggesting thermal metamorphism in their parent bodies. Five of these meteorites (Asuka (A) 881655, Yamato (Y) 793495, Y-790992, Pecora Escarpment (PCA) 91008, and Y-86789—paired with Y-86720) exhibit significant depletion of the most thermally mobile 1–5 trace elements, which is consistent with open-system loss during extended parent-body heating (under conditions duplicated by week-long heating of the Murchison C2 chondrite, heated at 500–700 °C in a low-pressure (initially 10^?5atm) H₂ atmosphere). From earlier data, three other C3 chondrites—Allan Hills (ALH) 81003, ALH 85003, and Lewis Cliffs (LEW) 85332—show significant Cd depletion. Nine additional C2 and C3 chondrites show no evidence of mobile trace element depletion—including Y-793321, which by all other criteria was mildly metamorphosed thermally. Either metamorphism of these nine meteorites occurred under closed conditions and/or alteration took place under such mild conditions that even Cd could not be lost. The RNAA data suggest that 10 of the 46 Antarctic carbonaceous chondrites (including 4 of 37 from Victoria Land and 6 of 9 from Queen Maud Land) exhibit open-system loss of at least some thermally mobile trace elements by heating in their parent bodies, whereas none of the 25 non-Antarctic falls experienced this. These results are consistent with the idea that the Antarctic sampling of near-Earth material differs from that being sampled today.