Bioaccumulation of heavy metals and radionuclides from seawater by encased embryos of the spotted dogfish Scyliorhinus canicula

Encased embryos of spotted dogfish Scyliorhinus canicula absorbed six radio-isotopes (241Am, 109Cd, 57Co, 134Cs, 54Mn and 65Zn) directly from seawater during short-term experimental exposure, demonstrating the permeability of the egg-case to these contaminants. Embryo to water concentration factors (CFs) ranged from 0.14 for 134Cs to 7.4 for 65Zn. The 65Zn and 57Co CFs increased exponentially with embryo length, whereas the CF for 109Cd declined with length. Among different components of the encased embryo the egg case was the major repository (69-99%) of all six radio-isotopes that were distributed throughout its wall. Egg-case CFs were as high as 10(3) for 57Co and 65Zn, making it the major source of gamma radiation exposure to the embryo and potentially of radio-isotopes for continued absorption by the embryo, following the uptake phase of the experiment. The patterns of uptake by the egg-case approximated linearity for most isotopes and loss rates were isotope-specific; egg-case biokinetics were not greatly affected by the viability of the contained embryo. Within the embryo initial data on radio isotopic distribution show that the skin is their major site of uptake, as previously demonstrated for juveniles.     

Production of selected cosmogenic radionuclides by muons 1. Fast muons

To investigate muon-induced nuclear reactions leading to the production of radionuclides, targets made of C₉H₁₂, SiO₂, Al₂O₃, Al, S, CaCO₃, Fe, Ni, Cu, Gd, Yb and Tl were irradiated with 100 and 190 GeV muons in the NA54 experimental setup at CERN. The radionuclide concentrations were measured with accelerator mass spectrometry and γ-spectroscopy. Results are presented for the corresponding partial formation cross-sections. Several of the long-lived and short-lived radionuclides studied are also produced by fast cosmic ray muons in the atmosphere and at depths underground. Because of their importance to earth sciences investigations, calculations of the depth dependence of production rates by fast cosmic ray muons have been made.     

Production of selected cosmogenic radionuclides by muons: 2. Capture of negative muons

We have determined the production yields for radionuclides in Al₂O₃, SiO₂, S, Ar, K₂SO₄, CaCO₃, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides ¹⁰Be, ¹⁴C and ²⁶Al produced in quartz targets, ²⁶Al in Al₂O₃ and S targets, ³⁶Cl in K₂SO₄ and CaCO₃ targets, and ⁵³Mn in Fe₂O₃ targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ⁻ capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ⁻ capture, by fast muons and by neutron capture.     

Assessment of health safety from ingestion of natural radionuclides in seafoods from a tropical coast, India

The activities of ²¹⁰Po and ²¹⁰Pb were determined in commonly consumed seafoods to evaluate the internal exposure and risk to humans residing Kudankulam coast where a mega nuclear power plant is under construction. The concentration of ²¹⁰Po in seafoods ranged from 1.2 ± 0.7 to 248 ± 8.1 Bq kg⁻¹. Meanwhile, ²¹⁰Pb ranged between 1.1 ± 0.05 and 14.8 ± 1.6 Bq kg⁻¹. The committed effective dose (CED) due to ²¹⁰Po and ²¹⁰Pb varied from 11.04 to 515.6 and 3.93 to 23.5 μSv yr⁻¹, respectively. The lifetime cancer risk for the public due to ²¹⁰Po was in the range of 3.47 × 10⁻⁵-1.62 × 10⁻³ and it was 4.03 × 10⁻⁵-1.96 × 10⁻⁴ due to ²¹⁰Pb. The activity intake, effective dose and cancer risk was found lesser than international guidelines and the seafood intake was considered to be safe for human consumption.     

Seismotectonics and earthquake activity of Kuwait

On March 1997, earthquake monitoring was started inKuwait through the operation of the Kuwait NationalSeismograph Network (KNSN). On Sept. 18, 1997, anearthquake of magnitude 3.9 occurred in the Minagisharea (southwest of Kuwait); it was felt in Kuwait City50 km away from the epicenter which was accuratelylocated using the data of KNSN. Also, some eventswere located in Minagish area and along the westernborders of the State of Kuwait. The same area ofMinagish was shocked on June 2, 1993 with a 4.7magnitude earthquake; it was also felt in Kuwait City. The spatial distribution of the Minagish areaearthquake may show a trend of NE-SW direction. Theisoseismals of the Sept. 18, 1997 earthquake aregenerally elliptical in shape with the major axisoriented NE-SW. The geologic sections and tectonichistory of Kuwait show seismotectonic deformationsince late Eocene time. This activity is related tothe interaction of the Arabian platform and the Zagrosfolded belt. A major break in the sedimentarysuccession which occurred in Kuwait during Eocene andOligocene times indicates that nascent folding anduplift have persisted since that time. The formationof the major topographical feature in Kuwait(Jal-Az-Zor escarpment, Wadi Al-Batin and AhmadiRidge) can be attributed to tectonic activity since Eocene time.The spatial distribution of the recent earthquakeactivity in Kuwait is associated with the surface andsubsurface tectonic structures. The moderate sizeearthquake activity of the State of Kuwait can beconsidered as evidence of recent rejuvenation of thetectonic structures which have been active since Eocene time.     

Glyphosate persistence in seawater

Glyphosate is one of the most widely applied herbicides globally but its persistence in seawater has not been reported. Here we quantify the biodegradation of glyphosate using standard “simulation” flask tests with native bacterial populations and coastal seawater from the Great Barrier Reef. The half-life for glyphosate at 25 °C in low-light was 47 days, extending to 267 days in the dark at 25 °C and 315 days in the dark at 31 °C, which is the longest persistence reported for this herbicide. AMPA, the microbial transformation product of glyphosate, was detected under all conditions, confirming that degradation was mediated by the native microbial community. This study demonstrates glyphosate is moderately persistent in the marine water under low light conditions and is highly persistent in the dark. Little degradation would be expected during flood plumes in the tropics, which could potentially deliver dissolved and sediment-bound glyphosate far from shore.     

Ground Water Contamination in Kuwait Resulting from the 1991 Gulf War: A Preliminary Assessment

A large number of oil wells in Kuwait were damaged and ignited by the retreating Iraqi troops during the 1991 Gulf War. The resulting spillage of huge volumes of crude oil on the surface gave rise to oil lakes and crude oil–impregnated soil. Moreover, products of crude oil combustion had spread over a large tract of the ground surface, causing widespread contamination of soil. Hydrocarbon contamination of ground water by the infiltrating runoff water carrying the contaminants from the surface soil to the water table and/or through direct contact with the crude oil leaking through the damaged casing in the subsurface was feared. This preliminary study was carried out to investigate the extent and nature of this possible contamination of ground water. The results indicate that the shallow fresh water lenses present under the Umm Al-Aish water field and in the southeastern parts of the Raudhatain water field in North Kuwait were affected by hydrocarbon pollution. Standard methods like the determination of the contents of the total petroleum hydrocarbon by the Fourier transform infrared method and 16 polyaromatic hydrocarbons using the gas chromatography-mass spectrometry method did not work well, possibly due to the environmental degradation of the crude oil over time. The fluorescence methods and the total organic carbon and total organic matter gave better indications of the intensity and the extent of ground water pollution. The brackish water fields of South and Central Kuwait were, however, free of any indications of hydrocarbon contamination.     

Natural radionuclides in the water of Narragansett Bay

The concentrations of radionuclides of the U-Th series (²³⁸U,²³⁴Th,²³⁴U,²³⁰Th,²²⁶Ra,²¹⁰Pb,²¹⁰Po, and²³²Th,²²⁸Ra,²²⁸Th) in the water of Narragansett Bay are reported. Analysis of the total, particulate, dissolved and colloidal forms of Th isotopes reveal a consistent removal behavior which is controlled mainly by the particulate matter concentration and the sediment resuspension rate. Half-removal times of Th from solution onto particles range from 1.5 to 15 days, and settling velocities of Th containing particles range generally between 1 and 11 m/day.²¹⁰Pb and²¹⁰Po concentrations are seasonally dependent, with higher concentrations and slower removal during the early summer (half-removal times from solution onto particles of 1–5 days in winter and up to 2 months in early summer).     

The distribution of halomethanes in the coastal waters of Kuwait

Chlorination of sea water used as cooling and feed water in the combined desalination-power plants of Kuwait leads to the formation of appreciable quantities of halomethanes. Significant concentrations of these compounds (up to 90 μg l⁻¹ as total haloforms) are present in the sea in the immediate vicinity of the out-falls from these plants. Beyond the point of discharge, the distributions of these compounds are consistent with the hydrography of the area, concentrations falling to below the detection limit (0.1 μg l⁻¹) within a few kilometres as a result of mixing and evaporation. Bromoform generally accounts for 95% of the total halomethanes, almost all of the remainder being dibromochloromethane.     

Water availability for the greening of Kuwait

Water resources for agricultural development and landscape enhancement in Kuwait are very scarce; the quality is saline (brackish), and the soil texture is sandy, incapable of holding nutrients and moisture. Most of the rainfall in Kuwait either evaporates due to the high temperatures or percolates through the soil. The rainfall is not sufficient to recharge the underground water supply. A variety of alternative water sources have been studied, including seawater desalination and wastewater treatment. Wastewater treatment proved to be convenient due to the relatively low salinity detected in the treated water. Furthermore, the amount of wastewater is expected to increase as more residential areas are connected to the sewage system as the population increases.

The development of a greenery plan for Kuwait requires intensive water management. This goal can be achieved through manpower training in landscape development, selection of plants tolerant to arid environments, usage of appropriate irrigation and drainage systems, promotion of greenery programs within public and the governmental agencies for their direct participation in urban area beautification, and extension of wastewater treatment techniques.     

Caffeine in Boston Harbor seawater

Caffeine has been detected in Boston Harbor seawater with concentrations ranging from 140 to 1600 ng l(-1), and in Massachusetts Bay seawater at concentrations from 5.2 to 71 ng l(-1). Sources of caffeine appear to be anthropogenic with higher concentrations in the seawater of Boston's inner harbor and in freshwater sources to the harbor. Charles River water and Deer Island sewage treatment plant effluent, the two major sources of freshwater to the harbor, contained 370 and 6700 ng l(-1) of caffeine, respectively, in 1998. Sewage influent and effluent concentrations appear to be consistent with consumption estimates of caffeinated beverages for the Boston area and total organic carbon removal targets for treated sewage. Caffeine was inversely correlated to salinity in a transect from the mouth of Boston Harbor to Stellwagen Basin, indicating it may be a useful chemical tracer of anthropogenic inputs to marine systems.     

Neodymium isotopic variations in seawater

New data for the direct measurement of the isotopic composition of neodymium in Atlantic Ocean seawater are compared with previous measurements of Pacific Ocean seawater and ferromanganese sediments from major ocean basins. Data for Atlantic seawater are in excellent agreement with Nd isotopic measurements made on Atlantic ferromanganese sediments and are distinctly different from the observed compositions of Pacific samples. These results clearly demonstrate the existence of distinctive differences in the isotopic composition of Nd in the waters of the major ocean basins and are characteristic of the ocean basin sampled. The average ε_Nd(0) values for the major oceans as determined by data from seawater and ferromanganese sediments are as follows: Atlantic Ocean,ε_Nd(0) ? ?12 ± 2; Indian Ocean,ε_Nd(0) ? ?8 ± 2; Pacific Ocean,ε_Nd(0) ? ?3 ± 2. These values are considerably less than ε_Nd(0) value sources with oceanic mantle affinities indicating that the REE in the oceans are dominated by continental sources. The difference in the absolute abundance of¹⁴³Nd between the Pacific and Atlantic Oceans corresponds to ～10⁶ atoms¹⁴³Nd per gram of seawater. The correspondence between the¹⁴³Nd/¹⁴⁴Nd in seawater and in the associated sediments suggests the possible application of this approach to paleo-oceanography.Distinctive differences in ε_Nd(0) values are observed in the Atlantic Ocean between deep-ocean water associated with North Atlantic Deep Water and near-surface water. This suggests that North Atlantic Deep Water may be relatively well mixed with respect to Nd isotopic composition whereas near-surface water may be quite heterogeneous, reflecting different sources for surface waters relative to deep water. This suggests that it may be possible to distinguish the sources of water masses within an ocean basin on the basis of Nd isotopic composition.The Nd isotopic variations in seawater are used to relate the residence time of Nd and mixing rates between the oceans.     

Spatial and temporal characterizations of water quality in Kuwait Bay

The spatial and temporal patterns of water quality in Kuwait Bay have been investigated using data from six stations between 2009 and 2011. The results showed that most of water quality parameters such as phosphorus (PO₄), nitrate (NO₃), dissolved oxygen (DO), and Total Suspended Solids (TSS) fluctuated over time and space. Based on Water Quality Index (WQI) data, six stations were significantly clustered into two main classes using cluster analysis, one group located in western side of the Bay, and other in eastern side. Three principal components are responsible for water quality variations in the Bay. The first component included DO and pH. The second included PO₄, TSS and NO₃, and the last component contained seawater temperature and turbidity. The spatial and temporal patterns of water quality in Kuwait Bay are mainly controlled by seasonal variations and discharges from point sources of pollution along Kuwait Bay’s coast as well as from Shatt Al-Arab River.