Combined U-Pb SHRIMP and Hf isotope Complex, Rio Negro Province, Argentina： of the Patagonia composite terrane study of the Late Paleozoic Yaminué Implications for the origin and evolution

We have carried out zircon U-Pb SHRIMP dating and Hf isotope determinations on a biotite paraschist and on a tonalitic orthogneiss of the Yaminue Complex,and re-evaluate this complex in the broader context of the tectonic evolution of the Patagonia composite terrane.In the metasedimentary unit （msuYC）,the youngest detrital zircon dated at 318±5 Ma（Mississippian/Pennsylvanian boundary） indicates a Pennsylvanian（or younger） depositional age.The three main age populations peak at 474,454 and 374 Ma.Preliminary Hf isotope data for two detrital zircons（447 and 655 Ma） yieldedε（Hf） values of -0.32 and 0.48,indicating that their primary sources contained small amounts of recycled crustal components(of Calymmian age;T_DM 1.56 Ga).Zircons from the orthogneiss（miuYC;intrusive into msuYC） show a crystallization age of 261.3±2.7 Ma（Capitanian;late middle Permian） which is broadly coeval with deformation,and Neoarchean-Paleoproterozoic inheritance.Meaningful core-rim relationship between Neoarchean zircon cores and late Permian rims is well defined,indicating the occurrence of Archean crust in this sector of Patagonia.Hf T_DM of Permian zircons is mainly Meso-Paleoarchean（2.97-3.35 Ga）,with highly negativeε（Hf） values（ca.-33）.Hf T_DM of inherited Neoarchean zircon cores is also Meso-Paleoarchean（3.14-3.45 Ga） but more juvenile（ε（Hf） = -0.3）.Hf isotopes reinforce the presence of unexposed ancient crust in this area. Combining geological and isotope data,as well as geophysical models,we identify the Yaminue Complex within the La Esperanza-Yaminue crustal block flanked by two other,distinct crustal blocks:the Eastern block which forms part of the Patagonia terrane sensu stricto,located in the eastern Patagonian region,and the Western block forming part of the Southern Patagonia terrane.Their origins and timing of amalgamation to form the Patagonia composite terrane are also discussed.     

Genesis and tectonic setting of Late Jurassic-Early Cretaceous granites in Nachatang area,Central Lhasa Terrane: Constraints from geochemistry,chronology and Hf isotopesSCIEI北大核心CSCD

西藏中拉萨地块东段大规模侏罗纪-白垩纪花岗岩类的成因类型及构造背景尚未得到有效约束,该时期岩浆作用的时空分布、岩石成因以及深部动力学机制等问题亟需新的深入研究。本文对中拉萨地块东段南缘那茶淌地区的花岗岩类进行了系统的岩相学、元素地球化学、年代学和锆石Hf同位素研究。LA-MC-ICPMS锆石U-Pb定年结果显示,那茶淌地区黑云母二长花岗岩成岩年龄为147±1.4Ma,花岗闪长岩年龄为140.6±1.3Ma,系晚侏罗世-早白垩世中酸性岩浆活动的产物。在元素地球化学组成上,黑云母二长花岗岩和花岗闪长岩的主量元素组成具有富SiO₂(分别为71.02%～71.81%和65.17%～66.73%)、Al₂O₃(分别为13.45%～13.57%和14.43%～15.20%)、碱金属(Na₂O+K₂O)(分别为6.79%～7.48%和6.55%～7.37%),贫TiO₂(分别为0.15%～0.21%和0.10%～0.13%)等特征,显示I型准铝-弱过铝质(A/CNK=0...     

Metallogeny of the Huaaobaote Ag-polymetallic deposit in Inner Mongolia: Constraints from zircon and cassiterite U-Pb datingSCIEI北大核心CSCD

花敖包特超大型银多金属矿床位于大兴安岭南段,矿体主要呈脉状赋存于二叠系寿山沟组的断裂中,部分矿体呈囊状产于寿山沟组与华力西期蛇绿岩的接触带中。矿体主要包括银铅锌锑矿体、锡铜矿体、铜铅锌矿体、锡矿体和银矿体。花敖包特矿床可划分为4个成矿阶段,分别为石英-锡石-毒砂-黄铁矿阶段(Ⅰ阶段)、石英-绢云母-锡石-黄铜矿-毒砂-磁黄铁矿-闪锌矿-黝铜矿阶段(Ⅱ阶段)、石英-绢云母-萤石-方解石-闪锌矿-方铅矿-黄铁矿-辉锑矿-含银硫盐矿物阶段(Ⅲ阶段)和石英-方解石-黄铁矿-辉银矿-深红银矿阶段(Ⅳ阶段)。对花敖包特矿区2件次流纹岩样品开展了LA-ICP-MS锆石U-Pb定年,分别获得135.4±0.8Ma和134.8±0.8Ma的年龄。对成矿Ⅰ阶段锡矿石和Ⅱ阶段锡铜矿石进行了LA-ICP-MS锡石U-Pb定年,分别获得136.3±2.0Ma和134.3±1.7Ma的加权平均年龄。定年结果表明,花敖包特矿床次流纹岩、锡矿体和锡铜矿体均形成于早白垩世。尽管二者形成时间相近,但脉体穿切关系及矿化分带特征均表明次流纹岩并非成矿物质和成矿流体的主要来源。本文认为,花敖包特矿床真正的成矿地质体为隐伏于矿区深部的次火山岩钟,其矿床成因类型为与次火山岩相关的热液矿床。     

Sedimentary features of the Miocene strata of the Jinding Zn-Pb ore concentration area,the SE Tibetan Plateau: Fillings of a peripheral foreland basin in the oblique collision beltSCIEI北大核心CSCD

兰坪中-新生代盆地位于青藏高原东南缘的三江造山带中段,受印度-欧亚大陆斜向碰撞相关构造的强烈影响,导致地层序列及时代归属难辨,区域地质与成矿作用认识存在诸多分歧。先期完成的区域地质调查发现,在金顶铅锌矿集区内常见的含石膏岩地层并非前人认为的古新统云龙组的一部分,而是角度不整合于前古新统之上的一套新地层,暂定名为中新统金顶砂泥岩。系统的剖面测量和详细的沉积学研究表明,金顶砂泥岩从下到上由洪积相砾岩、辫状河三角洲相粉-细砂岩夹泥岩和砾岩以及湖泊相粉砂岩夹泥岩组成,石膏层位于砾岩之上。辫状河三角洲相中频繁出现灰绿色、灰黑色粉砂质泥岩及黄铁矿结核层,可能是频繁的区域性挤压作用造成的逆冲-走滑断层使上三叠统基底岩系中古油气藏破裂、泄露所致;该套地层内广泛发育的同沉积逆断层(视正断层)、滑脱褶皱和液化砂脉等软沉积物变形构造,指示沉积盆地发育期间地壳发生了NEE-SWW向缩短。金顶砂泥岩是印度-欧亚大陆碰撞背景下近东西向挤压构造诱发并控制的周缘前陆盆地沉积,时代为中新世。这一认识为深入理解大陆斜向碰撞带构造演化及大规模金属成矿作用提供了新的资料。     

Cassiterite U-Pb age,fluid inclusion and H-O-S-Pb isotope geochemistry of the Xiaogushan Sn-Zn deposit in the southern Great Xing'an Range,NE ChinaSCIEI北大核心CSCD

毛登-小孤山地区是大兴安岭南段锡多金属成矿带代表性矿区,由小孤山锡锌矿床和毛登锡钼铋多金属矿床组成。小孤山矿床锡石U-Pb Tera-Wasserburg谐和年龄为134.8±1.9Ma,表明其形成于早白垩世。该矿床成矿过程可划分为4个阶段:锡石-黄铁矿-石英-电气石阶段(Ⅰ阶段)、锡石-黄铜矿-闪锌矿-石英-萤石阶段(Ⅱ阶段)、闪锌矿-方铅矿-石英-萤石阶段(Ⅲ阶段)、黄铁矿-石英-方解石阶段(Ⅳ阶段)。小孤山矿床主要发育富液两相包裹体(WL型)、富气两相包裹体(WG型)及含子矿物包裹体(S型)。Ⅰ、Ⅱ和Ⅲ阶段均发育WL、WG和S型包裹体,Ⅳ阶段仅出现WL型包裹体。从Ⅰ至Ⅳ阶段流体包裹体均一温度/盐度分别为420-443℃/8.3%-52.0%NaCleqv、286-379℃/4.0%-40.2%NaCleqv、214-299℃/3.8%-36.1%NaCleqv、178-195℃/2.1%-3.3%NaCleqv,表明从早阶段到晚阶段成矿流体由高温高盐度向低温低盐度转化,且前三个阶段流体盐度波动大,暗示成矿流体发生了多次沸腾。矿床的δ18O水介于-2.6‰-11.0‰,δD介于-107‰--91‰,Ⅰ和Ⅱ阶段的成矿流体以岩浆水为主,Ⅲ阶段开始有大气降水的加入。硫化物的δ34SCDT值介于-3.3‰--0.6‰,206Pb/204Pb介于17.772-18.427,207Pb/204Pb介于15.482-15.679,208Pb/204Pb介于37.668-38.622,表明成矿物质来源于早白垩世花岗质岩浆。流体沸腾和降温是矿质沉淀的两种主要机制。     

U-Pb ages and Hf isotope compositions of detrital zircons from the sandstone in the early cretaceous Wawukuang formation in the Jiaolai Basin,Shandong Province and its tectonic implicationsEI北大核心CSCD

LA-ICP-MS U-Pb dating and in situ Hf isotope analysis were carried out for the detrital zircons to constrain the depositional age and provenance of the Wawukuang Formation, which is believed as the earliest unit of the Laiyang Group in the Jiaolai Basin, and its implications. Most of these detrital zircons from the feldspar quartz sandstone in the Wawukuang Formation are magmatic in origin, which are euhedral-subhedral and display oscillatory zoning in CL images; whereas few Late Triassic detrital zircons are metamorphic in origin and structureless in CL images. U-Pb isotopic dating of 82 zircon grains yields age populations at ca. 129 Ma, 158 Ma, 224 Ma, 253 Ma, 461 Ma, 724 Ma, 1851 Ma and 2456 Ma. U-Pb dating and Hf isotopic results indicate that: 1) the Wawukuang Formation deposited during the Early Cretaceous (129-106 Ma); 2) the detrital zircons with the ages of 1851 Ma and 2456 Ma mainly sourced from the Precambrian basement rocks of the North China Craton; the Neoproterozoic (729-721 Ma) magmatic zircons and the Late Triassic (226-216 Ma) metamorphic zircons sourced from the Su-Lu terrane; The Late Paleozoic detrital zircons could source from the Late Paleozoic igneous rocks in the northern margin of the North China Craton; the Late Triassic (231-223 Ma) magmatic zircons and the 158-129 Ma zircons sourced from the coeval igneous rocks in the Jiaobei and Jiaodong; 3) the deposition age and provenance of the Jiaolai Basin are different from those of the Hefei Basin; 4) the recognition of clastic sediments from the Su-Lu terrane in the Wawukuang Formation suggests that the Su-Lu terrane was under denudation in the Early Cretaceous. ©, 2015, Science Press. All right reserved.     

Metallogenic age and fluid evolution of the Kangshan Au-polymetallic deposit in the southern margin of the North China Craton: Constraints from monazite U-Pb age,and in-situ trace elements and S isotopes of pyriteSCIEI北大核心CSCD

小秦岭-熊耳山金矿集区位于华北克拉通南缘,发育众多伴生铅锌银等金属的金矿,成为揭示克拉通破坏型金矿成因的天然实验室。产于小秦岭-熊耳山金矿集区内的康山金多金属矿床受控于北东向的中生代脆性断裂,赋存于新太古代变质岩和中元古代火山岩中。成矿过程可分为4个热液阶段:石英±黄铁矿阶段、石英-黄铁矿-黄铜矿-自然金阶段、多金属硫化物-自然金-石英-铁白云石阶段、石英-方解石±萤石阶段。本文获得康山金多金属矿床金成矿阶段热液独居石LA-ICP-MS U-Pb年龄为131.7±4.6Ma,与晚中生代华北克拉通破坏有关的岩浆热液成矿作用时代一致。本次研究开展的各阶段黄铁矿原位微量元素单点和扫面分析,发现第2阶段Au与Co、Ni、As呈正相关关系,且有明显的振荡环带,Cu、Ag、Sb、Pb、Bi这几种元素从黄铁矿颗粒的核部向边缘含量逐渐降低,且黄铁矿颗粒中出现富含这些元素的矿物包裹体,说明该阶段发生流体沸腾作用;而第3阶段黄铁矿中各微量元素含量为所有阶段中最低,黄铁矿无振荡环带且裂隙中有富含各微量元素的硫化物充填,说明各种元素在该阶段均得到充分卸载,且成矿流体的化学性质较稳定。结合前人关于该矿床各阶段流体包裹体分析结果,表明流体沸腾是Au的主要沉淀机制,而流体混合是Pb、Zn、Ag的主要沉淀机制。黄铁矿中微量元素含量指示,从第1阶段到第3阶段流体温度依次降低;第2和第3阶段流体fO2比第1阶段高且后两者相差不大。根据黄铁矿Co、Ni含量及比值的计算,认为第1和第2阶段黄铁矿为岩浆热液成因,第3阶段黄铁矿受围岩物质影响。黄铁矿原位S同位素分析得到第1至第3阶段黄铁矿δ34S分别为+6.6‰-+8.9‰、+5.0‰-+7.2‰和+6.0‰-+8.7‰,均与区域花岗岩类的S同位素值类似。综上所述,本文得出康山金多金属矿床形成于早白垩世与华北克拉通破坏有关的岩浆热液成矿作用。