Equilibration of saltation

A two‐dimensional numerical model of the saltation process was developed on a parallel computer in order to investigate the temporal behaviour of transport rate as well as its downwind distribution. Results show that the effects of unsteady flow on the transportation of particulates (sediment) have to be considered in two spatial dimensions (x, y). Transport rate Q(x, t) appears in the transport equation for mass M(x, t): where A = ΔxW denotes unit area composed of unit streamwise length Δx and width W. S(x, t) (units kg m⁻² s⁻¹) stands for the balance over the splash process. A transport equation for transport rate itself is suggested with U _c (x, t) a mean particle velocity at location x as the characteristic velocity of the grain cloud. For a steadily blowing wind over a 50 m long sediment bed it was found that downwind changes in Q cease after roughly 10–40 m, depending on the strength of the wind. The onset of stationarity (∂/∂t=0) was found to be a function of the friction velocity and location. The local equilibrium between transport rate and wind was obtained at different times for different downstream locations. Two time scales were found. One fast response (in the order of 1) to incipient wind and a longer time for equilibrium to be reached throughout the simulation length. Transport rate also has different equilibrium values at different locations. A series of numerical experiments was conducted to determine a propagation speed of the grain cloud. It was found that this velocity relates linearly to friction velocity. Copyright © 2000 John Wiley & Sons, Ltd.     

A coupled model for simulating surface water and groundwater interactions in coastal wetlands

Coastal wetlands are characterized by strong, dynamic interactions between surface water and groundwater. This paper presents a coupled model that simulates interacting surface water and groundwater flow and solute transport processes in these wetlands. The coupled model is based on two existing (sub) models for surface water and groundwater, respectively: ELCIRC (a three‐dimensional (3‐D) finite‐volume/finite‐difference model for simulating shallow water flow and solute transport in rivers, estuaries and coastal seas) and SUTRA (a 3‐D finite‐element/finite‐difference model for simulating variably saturated, variable‐density fluid flow and solute transport in porous media). Both submodels, using compatible unstructured meshes, are coupled spatially at the common interface between the surface water and groundwater bodies. The surface water level and solute concentrations computed by the ELCIRC model are used to determine the boundary conditions of the SUTRA‐based groundwater model at the interface. In turn, the groundwater model provides water and solute fluxes as inputs for the continuity equations of surface water flow and solute transport to account for the mass exchange across the interface. Additionally, flux from the seepage face was routed instantaneously to the nearest surface water cell according to the local sediment surface slope. With an external coupling approach, these two submodels run in parallel using time steps of different sizes. The time step (Δt_g) for the groundwater model is set to be larger than that (Δt_s) used by the surface water model for computational efficiency: Δt_g = M × Δt_s where M is an integer greater than 1. Data exchange takes place between the two submodels through a common database at synchronized times (e.g. end of each Δt_g). The coupled model was validated against two previously reported experiments on surface water and groundwater interactions in coastal lagoons. The results suggest that the model represents well the interacting surface water and groundwater flow and solute transport processes in the lagoons. Copyright © 2011 John Wiley & Sons, Ltd.     

Evaluating overland flow sediment transport capacity

An equation for evaluating the sediment transport capacity of overland flow is a necessary part of a physically based soil erosion model describing sediment detachment and transport as distributed processes. At first, for the hydraulic conditions of small-scale and large-scale roughness, the sediment transport capacity relationship used in the WEPP model is calibrated by Yalin and Govers' equation. The analysis shows that the transport coefficient K_t depends on the Shields parameter, Y, according to a semi-logarithmic (Yalin) or a linear (Govers) equation. The reliability of the semi-logarithmic equation is verified by Smart's, and Aziz and Scott's experimental data. Then the Low's formula, whose applicability is also proved by Smart's, and Aziz and Scott's data, is transformed as a stream power equation in which a stream power coefficient, K_SP, depending on Shields parameter, slope, sediment and water-specific weight, appears. A relationship between transport capacity and effective stream power is also proposed. Finally, the influence of rainfall on sediment transport capacity and the prediction of critical shear stress corresponding to overland flow are examined. © 1998 John Wiley & Sons, Ltd.     

A bed‐load transport model for rough turbulent open‐channel flows on plane beds

Data from flume studies are used to develop a model for predicting bed‐load transport rates in rough turbulent two‐dimensional open‐channel flows moving well sorted non‐cohesive sediments over plane mobile beds. The object is not to predict transport rates in natural channel flows but rather to provide a standard against which measured bed‐load transport rates influenced by factors such as bed forms, bed armouring, or limited sediment availability may be compared in order to assess the impact of these factors on bed‐load transport rates. The model is based on a revised version of Bagnold's basic energy equation i_bs_b = e_bω, where i_b is the immersed bed‐load transport rate, ω is flow power per unit area, e_b is the efficiency coefficient, and s_b is the stress coefficient defined as the ratio of the tangential bed shear stress caused by grain collisions and fluid drag to the immersed weight of the bed load. Expressions are developed for s_b and e_b in terms of G, a normalized measure of sediment transport stage, and these expressions are substituted into the revised energy equation to obtain the bed‐load transport equation i_b = ω G ^3·4. This equation applies regardless of the mode of bed‐load transport (i.e. saltation or sheet flow) and reduces to i_b = ω where G approaches 1 in the sheet‐flow regime. That i_b = ω does not mean that all the available power is dissipated in transporting the bed load. Rather, it reflects the fact that i_b is a transport rate that must be multiplied by s_b to become a work rate before it can be compared with ω. It follows that the proportion of ω that is dissipated in the transport of bed load is i_bs_b/ω, which is approximately 0·6 when i_b = ω. It is suggested that this remarkably high transport efficiency is achieved in sheet flow (1) because the ratio of grain‐to‐grain to grain‐to‐bed collisions increases with bed shear stress, and (2) because on average much more momentum is lost in a grain‐to‐bed collision than in a grain‐to‐grain one. Copyright © 2006 John Wiley & Sons, Ltd.     

A wind tunnel investigation of the influences of fetch length on the flux profile of a sand cloud blowing over a gravel surface

Wind tunnel tests were conducted to examine the fetch effect of a gravel surface on the ?ux pro?le of the sand cloud blowing over it using typical dune sand. The results suggest that the ?ux pro?le of blown sand over a gravel surface differs from that over a sandy surface and is characterized by a peak ?ux at a height above the surface while that over a sandy surface decreases exponentially with height. The ?ux pro?le of a sand cloud over a gravel surface can be expressed by a Gaussian peak function: q = a + b exp (?0·5((h ? c)/d)²), where q is the sand transport rate at height h, and a, b, c and d are regression coef?cients. The signi?cance of the coef?cients in the function could be de?ned in accordance with the fetch length of the gravel surface and wind velocity. Coef?cient c represents the peak ?ux height and increases with both wind velocity and fetch length, implying that the peak ?ux height is related to the bounce height of the particles in the blowing sand cloud. Coef?cient d shows a tendency to increase with both wind velocity and fetch length. The sum of a and b, representing the peak ?ux, increases with wind velocity but decreases with fetch length. The average saltation height derived from the cumulative percentage curve shows a tendency to increase with both the fetch length and wind velocity. For any fetch length of a gravel surface the sand transport equation is expressed as Q = C(1 ? U_t/U)(ρ/g)U³, where Q is the sand transport rate, U is the wind velocity, U_t is the threshold velocity measured at the same height as U, g is the gravitational acceleration, ρ is the air density, C is a proportionality coef?cient that decreases with the fetch length of the gravel surface. At a given wind velocity, the sand transport rate over a gravel surface is only 52–68 per cent of that over a sandy surface. The ?ux rate in true creep over a gravel surface increases with wind velocity but decreases with the fetch length, whereas the creep proportion (the ratio of creep ?ux to the sand transport rate) decreases with both the wind velocity and fetch length. Two‐variable (including fetch length and wind velocity) equations were developed to predict the peak ?ux height, average saltation height and transport rate. Copyright © 2004 John Wiley & Sons, Ltd.     

A mathematical model for steady‐state regolith production at constant erosion rate

It has been hypothesized that many soil profiles reach a steady‐state thickness. In this work, such profiles were simulated using a one‐dimensional model of reaction with advective and diffusive solute transport. A model ‘rock’ is considered, consisting of albite that weathers to kaolinite in the presence of chemically inert quartz. The model yields three different steady‐state regimes of weathering. At the lowest erosion rates, a local‐equilibrium regime is established where albite is completely depleted in the weathering zone. This regime is equivalent to the transport‐limited regime described in the literature. With an increase in erosion rate, transition and kinetic regimes are established. In the transition regime, both albite and kaolinite are present in the weathering zone, but albite does not persist to the soil–air interface. In the weathering‐limited regime, here called the kinetic regime, albite persists to the soil–air interface. The steady‐state thickness of regolith decreases with increasing erosion rate in the local equilibrium and transition regimes, but in the kinetic regime, this thickness is independent of erosion rate. Analytical expressions derived from the model are used to show that regolith production rates decrease exponentially with regolith thickness. The steady‐state regolith thickness increases with the Darcy velocity of the pore fluid, and in the local equilibrium regime may vary markedly with small variations in this velocity and erosion rate. In the weathering‐limited regime, the temperature dependences for chemical weathering rates are related to the activation energy for the rate constant for mineral reaction and to the ΔH of dissolution, while for local equilibrium regimes they are related to the ΔH only. The model illustrates how geochemical and geomorphological observations are related for a simple compositional system. The insights provided will be useful in interpreting natural regolith profiles. Copyright © 2010 John Wiley & Sons, Ltd.     

Remote sensing of volumetric storage changes in lakes

Three‐dimensional remote sensing promises a giant leap forward for surface‐water hydrology in much the same way that radar altimetry transformed physical oceanography. However, the complex geometries of small terrestrial water bodies introduce difficulties, particularly with respect to trade‐offs between changing water depth and inundation area. We use in situ measurements of water‐surface stage (ΔH/dt) and remotely‐sensed area (A) to compute time varying storage changes (ΔS) in nine lakes of the Peace‐Athabasca Delta, Canada. Despite their identical geomorphic setting, regression slopes between ΔH and A vary significantly between lakes, primarily from a predictable ‘area‐effect’ but also small bathymetric variations between basins. On average, lateral contraction/expansion (versus stage adjustment) contributes as little as 7% (versus 93%) to as much as 76% (versus 24%) of overall storage change ΔS. We conclude that both surface‐area and ΔH/dt, rather than just either alone, must be measured to confidently estimate ΔS from space. Copyright © 2009 John Wiley & Sons, Ltd.     

Hysteresis‐based analysis of overland metal transport

Introducing a concept of equivalent mass depth of flow, this study describes the phenomenon of non‐point source pollutant (metal) transport for pavement (or overland) flow in analogy with wave propagation in wide open channels. Hysteretic and normal mass rating curves are developed for runoff rate and mass of 12 dissolved and particulate‐bound metal elements (pollutants) using the rainfall‐runoff and water quality data of the 15 × 20 m² instrumented pavement in Cincinnati, USA. Normal mass rating curves developed for easy computation of pollutant load are found to be of a form similar to Manning's, which is valid for open channel flows. Based on the hysteresis analysis, wave types for dissolution and mixing of particulate‐bound metals are identified. The analysis finds that the second‐order partial‐differential equation normally used for metal transport does not have the efficacy to describe fully the strong non‐linear phenomena such as is described for various metal elements by dynamic waves. In addition, the proportionality concept of the popular SCS‐CN concept is extended for determining the potential maximum metal mass M_p of all the 12 elements transported by a rain storm and related to the antecedent dry period (ADP). For the primary metal zinc element, M_p is found to increase with the ADP and vice versa. Copyright © 2003 John Wiley & Sons, Ltd.     

The causes of bedload pulses in a gravel channel: the implications of bedload grain‐size distributions

Unsteady bedload transport was measured in two c. 5 m wide anabranches of a gravel‐bed braided stream draining the Haut Glacier d'Arolla, Switzerland, during the 1998 and 1999 melt seasons. Bedload was directly sampled using 152 mm square Helley–Smith type samplers deployed from a portable measuring bridge, and independent transport rate estimates for the coarser size fractions were obtained from the dispersion of magnetically tagged tracer pebbles. Bedload transport time series show pulsing behaviour under both marginal (1998) and partial (1999) transport regimes. There are generally weak correlations between transport rates and shear stresses determined from velocity data recorded at the measuring bridge. Characteristic parameters of the bedload grain‐size distributions (D₅₀, D₈₄) are weakly correlated with transport rates. Analysis of full bedload grain‐size distributions reveals greater structure, with a tendency for transport to become less size selective at higher transport rates. The bedload time series show autoregressive behaviour but are dif?cult to distinguish by this method. State–space plots, and associated measures of time‐series separation, reveal the structure of the time series more clearly. The measured pulses have distinctly different time‐series characteristics from those modelled using a one‐dimensional sediment routing model in which bed shear stress and grain size are varied randomly. These results suggest a mechanism of pulse generation based on irregular low‐amplitude bedforms, that may be generated in‐channel or may represent the advection of material supplied by bank erosion events. Copyright © 2003 John Wiley & Sons, Ltd.     

A simple model accounting for the uptake,transport, and deposition of wind‐eroded mineral particles in the hyperarid coastal Atacama Desert of northern Chile

As previously observed in marine sediments collected downwind of African or South American continental sources, recent studies of sediment cores collected at the bottom of Mejillones Bay in north Chile (23°S) show a laminated structure in which the amount of particles of aeolian origin and their size create significant differences between the layers. This suggests inter‐annual to inter‐decadal variations in the strength of the local southerly winds responsible for (1) the erosion of the adjacent hyperarid surface of the Mejillones Pampa, and (2) the subsequent transport of the eroded particles towards the bay. A simple model accounting for the vertical uptake, transport, and deposition of the particles initially set into motion by wind at the surface of the pampa is proposed. This model, which could be adapted to other locations, assumes that the initial rate of (vertical) uptake is proportional to the (horizontal) saltation flux quantified by means of White's equation, that particles are lifted to a height (H), increasing with the magnitude of turbulence, and that sedimentation progressively removes the coarsest particles from the air column as it moves towards the bay. In this model, the proportionality constant (A) linking the vertical flux of particles with the horizontal flux, and the injection height (H) control the magnitude and size distribution of the deposition flux in the bay. Their values are determined using the wind speed measured over the pampa and the size distribution of particles collected in sediment traps deployed in the bay as constraints. After calibration, the model is used to assess the sensitivity of the deposition flux to the wind intensity variations. The possibility of performing such quantitative studies is necessary for interpreting precisely the variability of the aeolian material in the sediment cores collected at the bottom of Mejillones Bay. Copyright © 2010 John Wiley & Sons, Ltd.     

Field experiments constraining the probability distribution of particle travel distances during natural rainstorms on different slope gradients

Rain splash erosion is an important soil transport mechanism on steep hillslopes. The rain splash process is highly stochastic; here we seek to constrain the probability distribution of splash transport distances on natural hillslopes as a function of hillslope gradient and total precipitation depth. Field experiments were conducted under natural precipitation events to observe splash travel on varying slope gradients. The downslope fraction of splash transport on 15°, 25° and 33° gradients were 85%, 96% and 96%, respectively. Maximum splash transport (L_max) was related to the rain splash detachment of soil particles and slope gradient. An empirical relationship of L_max to the precipitation depth and gradient was obtained; it is linearly proportional to hillslope gradient and logarithmically related to precipitation depth. Measured splash distances were calibrated to the fully two‐dimensional (2D) model of splash transport of Furbish et al. (Journal of Geophysical Research 112 : F01001, 2007) that is based on the assumption that radial splash distances are exponentially distributed; calibrated values of mean splash transport distances are an order of magnitude greater than those previously determined in a controlled laboratory setting. We also compared measured data with several one‐dimensional (1D) probability distributions to asses if splash transport distances could be better explained by a heavy‐tailed probability distribution rather than an exponential probability distribution. We find that for hillslopes of 15° and 25°, although a log‐normal probability distribution best describes the data, we find its likelihood is nearly indistinguishable from an exponential distribution based on computing maximum likelihood estimators for all 1D distributions (exponential, log‐normal and Weibull). At 33°, however, we find stronger evidence that measured travel distances are heavy‐tailed. Copyright © 2011 John Wiley & Sons, Ltd.     

Entrainment,displacement and transport of tracer gravels

The mass and size distribution of grain entrainment per unit bed area may be measured by replacing a volume of the bed with tracer gravels and observing the mass difference before and after a transport event. This measure of spatial entrainment is relevant to any process involving size-selective exchange of sediment between transport and bed and may be directly used in calculations of sediment transport rate using an elementary relation for fractional transport components presented here. This relation provides a basis for evaluating tracer data collected by different methods and may be used to provide physical insight regarding the expected behaviour of tracer grains. The variation with grain size of total displacement length L_ti depends on the degree of mobilization of the individual fractions on the bed surface: L_ti is independent of D_i for smaller, fully mobile sizes and decreases rapidly with D_i for larger fractions in a state of partial transport (in which a portion of the surface grains remain immobile through the flow event). The boundary between fully and partially mobile grain sizes increases with flow strength. These inferences are supported by values of L_ti calculated from flume experiments and provide a physical explanation for a summary relation between L_ti and D_i based on field data. © 1997 John Wiley & Sons, Ltd.     

Wind direction and complex sediment transport response across a beach–dune system

Evidence from a field study on wind flow and sediment transport across a beach–dune system under onshore and offshore conditions (including oblique approach angles) indicates that sediment transport response on the back‐beach and stoss slope of the foredune can be exceedingly complex. The upper‐air flow – measured by a sonic anemometer at the top of a 3·5 m tower located on the dune crest – is similar to regional wind records obtained from a nearby meteorological station, but quite different from the near‐surface flow field measured locally across the beach–dune profile by sonic anemometers positioned 20 cm above the sand surface. Flow–form interaction at macro and micro scales leads to strong modulation of the near‐surface wind vectors, including wind speed reductions (due to surface roughness drag and adverse pressure effects induced by the dune) and wind speed increases (due to flow compression toward the top of the dune) as well as pronounced topographic steering during oblique wind approach angles. A conceptual model is proposed, building on the ideas of Sweet and Kocurek (Sedimentology 37 : 1023–1038, 1990), Walker and Nickling (Earth Surface Processes and Landforms 28 : 111–1124, 2002), and Lynch et al. (Earth Surface Processes and Landforms 33 : 991–1005, 2008, Geomorphology 105 : 139–146, 2010), which shows how near‐surface wind vectors are altered for four regional wind conditions: (a) onshore, detached; (b) onshore‐oblique, attached and deflected; (c) offshore, detached; and (d) offshore‐oblique, attached and deflected. High‐frequency measurements of sediment transport intensity during these different events demonstrate that predictions of sediment flux using standard equations driven by regional wind statistics would by unreliable and misleading. It is recommended that field studies routinely implement experimental designs that treat the near‐surface wind field as comprising true vector quantities (with speed and direction) in order that a more robust linkage between the regional (upper air) wind field and the sediment transport response across the beach–dune profile be established. Copyright © 2012 John Wiley & Sons, Ltd.     

Wind effects on sediment transport by raindrop‐impacted shallow flow: a wind‐tunnel study

In wind‐driven rains, wind velocity and direction are expected to affect not only energy input of rains but also shallow ?ow hydraulics by changing roughness induced by raindrop impacts with an angle on ?ow and the unidirectional splashes in the wind direction. A wind‐tunnel study under wind‐driven rains was conducted to determine the effects of horizontal wind velocity and direction on sediment transport by the raindrop‐impacted shallow ?ow. Windless rains and the rains driven by horizontal wind velocities of 6 m s^?1, 10 m s^?1, and 14 m s^?1 were applied to three agricultural soils packed into a 20 by 55 cm soil pan placed on both windward and leeward slopes of 7 per cent, 15 per cent, and 20 per cent. During each rainfall application, sediment and runoff samples were collected at 5‐min intervals at the bottom edge of the soil pan with wide‐mouth bottles and were determined gravimetrically. Based on the interrill erosion mechanics, kinetic energy ?ux (E_rn) as a rainfall parameter and product of unit discharge and slope in the form of q^bS^c_o as a ?ow parameter were used to explain the interactions between impact and ?ow parameters and sediment transport (q_s). The differential sediment transport rates occurred depending on the variation in raindrop trajectory and rain intensity with the wind velocity and direction. Flux of rain energy computed by combining the effects of wind on the velocity, frequency, and angle of raindrop impact reasonably explained the characteristics of wind‐driven rains and acceptably accounted for the differences in sediment delivery rates to the shallow ?ow transport (R₂ ≥ 0·78). Further analysis of the Pearson correlation coef?cients between E_rn and qS_o and q_s also showed that wind velocity and direction signi?cantly affected the hydraulics of the shallow ?ow. E_rn had a smaller correlation coef?cient with the q_s in windward slopes where not only reverse splashes but also reverse lateral raindrop stress with respect to the shallow ?ow direction occurred. However, E_rn was as much effective as qS_o in the sediment transport in the leeward slopes where advance splashes and advance lateral raindrop stress on the ?ow occurred. Copyright © 2004 John Wiley & Sons, Ltd.     

Shoreline development,longshore transport and surface wave dynamics,Pleistocene Lake Bonneville,Utah

Point of the Mountain spit and Fingerpoint spit are two of the largest geomorphic features of Pleistocene Lake Bonneville of the western Great Basin, USA. The spits and their associated shorelines show distinctly different geomorphic expression and genesis; this is a function of their positions within the lake and the dynamics of the waves and storms that formed them. Mapping of geomorphic features, geometry of erosional features, and detailed lithologic analysis of shoreline deposits are used to determine dominant modes of sediment erosion and deposition. The Point of the Mountain spit, located in the eastern portion of the basin, was formed as a result of highly fractured bedrock in a salient of the Wasatch Front being exposed to wave trains that approached from the north‐northwest causing north‐to‐south longshore sediment transport. Shoreline development and sediment transport on the southern portion of the spit were minimal. The Fingerpoint spit, located on an island in the northwest portion of the basin, was formed by bidirectional longshore sediment transport as the result of waves that approached from both the north‐northeast and the south‐southwest. Spit development is a function of surface wave energy and direction which in turn is the integrated result of wind direction, wind intensity, and fetch. Wave transport direction determined from ?eld measurements at Point of the Mountain spit corresponds very well to the direction of maximum fetch (c. 200 km). For the Fingerpoint spit, the hypothesized wave transport direction from the south corresponds with the direction of maximum fetch (c. 350 km). However, wave energy transport from the north had limited fetch (c. 100 km), implying that wind intensity from the north was relatively large. The geometry of the two large Bonneville spits suggests the predominant wind direction from storms during the Pleistocene was from the north and points the way for future studies that can aid in further understanding the nature of Pleistocene wind ?elds in the Great Basin. Copyright © 2004 John Wiley & Sons, Ltd.     

Measuring the flow resistance of submerged grass

Through laboratory experiments conducted in a grass‐lined flume, the hydraulic resistance of grass is measured and quantified. For the grass examined, it is found that Manning's n value is greater than those recommended in well‐established texts such as Chow (1959. Open Channel Flow. McGraw‐Hill: Singapore), relatively lower than those predicted by n‐UR methods, but corresponds well with the value found from calibration studies of two‐ and three‐dimensional numerical models. The assumption of a uniform Manning's n value with flow depth, which is often made in numerical modelling, may be invalid depending on the relative submergence of the vegetation. Drag coefficients are evaluated for a method applicable to three‐dimensional numerical models. Further detailed experimental investigation and application of these approaches within a numerical modelling framework is now recommended. Copyright © 2002 John Wiley & Sons, Ltd.     

Adsorption of Zinc using Tea Factory Waste: Kinetics,Equilibrium and Thermodynamics

In India, the annual production of tea is ca. 857,000 tonnes, which is 27.4% of the total world production. The amount of tea factory waste (TFW) produced per annum after processing is ca. 190,400 tonnes. TFW can be used as a low cost adsorbent for the removal of toxic metals from the aqueous phase. An investigation was carried out to study the feasibility of the use of TFW as an adsorbent for the removal of the heavy metal, zinc. Equilibrium, kinetic and thermodynamic studies were reported. The straight line plot of log (q_e–q) versus time t for the adsorption of zinc shows the validity of the Lagergren equation. The various steps involved in adsorbate transport from the solution to the surface of the adsorbent particles were dealt with by using a Weber‐Morris plot, q_e versus t^0.5 for the TFW. The rate controlling parameters, k_id,1 and k_id,2, were determined and it was found that the macro‐pore diffusion rate was much larger than micro‐pore diffusion rate. A batch sorption model, which assumes the pseudo‐second‐order mechanism, was used to predict the rate constant of sorption, the equilibrium sorption capacity and the initial sorption rate with the effect of initial zinc (II) ion concentration. Equilibrium data obtained from the experiments were analyzed with various isotherms, i. e., Freundlich, Langmuir, Redlich‐Peterson and Tempkin. The adsorption equilibrium was reached in 30 min and the adsorption data fitted well to all models. The maximum adsorption capacity of TFW for zinc (II) ions was determined to be 14.2 mg/g. The capacity of adsorption on Zn(II) increased with increasing temperatures and pH. The maximum uptake level of zinc was observed at pH of 4.2. The various thermodynamic parameters, i. e., ΔG°, ΔH° and ΔS°, were estimated. The thermodynamics of the zinc ion/TFW system indicated a spontaneous, endothermic and random nature of the process. The results showed that the TFW, which has low economical value, is a suitable adsorbent for the removal of zinc (II) ions from aqueous solutions.     

Aeolian sand transport at the Lanphere Dunes,Northern California

Aeolian sand transport was studied at the Lanphere Dunes, a coastal dune complex in northern California, by comparing slipface advance rates with transport predicted based on local wind data. The slipfaces of a 2·5 m high transverse ridge and 10 m high parabolic dune were monitored over a period of three months to estimate sand discharge. The study was performed during the dry season, which has the maximum sand‐driving potential. Over the three month study period, average sand discharge was 12·5 m³ per m width per year at the transverse ridge and 8·8 m³ per m width per year at the parabolic dune. A method was developed for modelling slipfaces that are sinuous and where sediment transport rates are not constant across the width of the slipface. Field measurements were used to generate three‐dimensional representations of dune slipfaces. Periodic measurements over the course of three months were used to compute the volume of displaced sediment. Theoretical sand transport was computed from local wind data using the Bagnold model and compared with the observed transport rates. Predicted rates were substantially lower than observed rates. Wind velocities rarely exceeded the threshold velocity. Discrepancies between the observed and predicted values appear to be caused by a combination of wind data recording procedures and differences between wind velocities at the anemometer location and the site where sand transport was measured. Wind data collected by weather bureaux have been utilized in numerous studies for modelling sediment transport. Such data typically have sample intervals of one hour or greater and are often averaged prior to reporting. The effect of averaging was investigated by comparing sand transport estimates based on daily average wind velocities with those based on the original hourly observations. The daily average data were depleted of high velocity winds and sand transport estimates were accordingly much lower than those based on the hourly data. Copyright © 2000 John Wiley & Sons, Ltd.     

Field studies of sediment transport by overland flow

Field studies on sandy soils of the Cottenham Series in mid-Bedfordshire show that the mean annual rate of sediment transport by overland flow on an 11° mid-slope is 98 g cm¹. The feasibility of using sediment transport equations to predict erosion by overland flow on a storm basis is examined by comparing the observed values of sediment yield with values predicted by four sediment transport equations and a regression equation which relates soil loss to runoff energy and rainfall energy. An expression combining Engelund's sediment transport capacity equation and the Manning equation for flow velocity, as modified by Savat for disturbed flow, best reflects field conditions. Although there is a significant correlation (r = 0.69; n 30) between the observed and predicted values using this expression, the coefficient of determination is too low for predictive purposes. Reasons for this are presented.