Distributions of hydrothermal activity along the Mid-Atlantic Ridge: interplay of magmatic and tectonic controls

Hydrothermal activity has been investigated along three different sections of the slow-spreading Mid-Atlantic Ridge (MAR): 11°20′–30°N, 36–38°N and the Reykjanes Ridge, 57°45′–63°06′N. When considered in total, the incidence of venting along these three sections of the MAR compares well with the predictions of a model in which frequency of venting is linearly related to ridge-crest spreading-rate. At the scale of individual study areas, however, departure from the model is observed by up to an order of magnitude. Venting is anomalously rare along the Reykjanes Ridge but anomalously abundant along the MAR 36–38°N. Whilst such variability may be within the error of the linear spreading-rate model, we note that the interplay between magmatic and tectonic processes also differs between the three study areas. In the case of the Reykjanes Ridge we propose that the low incidence of venting reported may reflect a limitation of the sampling/investigative strategy because the style of venting which predominates may not give rise to conventional black-smoker hydrothermal plumes. Along the oblique and broadly segmented MAR 36–38°N, we propose that vigorous hydrothermal venting in broad segment-end non-transform discontinuities may be focussed along deeply penetrating active faults with the requisite heat supply being supported through some combination of along-axis magmatic intrusions and thermal release associated with the serpentinisation of crustal peridotites.     

Helium-3 and manganese at the 21°N East Pacific Rise hydrothermal site

Water samples collected at the 21°N hydrothermal site on the East Pacific Rise crest, including Deep-Tow and hydrocast samples collected in 1977 and three hot vent water samples collected recently with the submersible “Alvin”, contain significant additions of³He,⁴He, and Mn. Although the vent water collections were at least 50-fold diluted with ambient seawater, they are up to 53 times enriched in³He and 7.4 times enriched in⁴He relative to saturated seawater, with concentrations of total dissolvable manganese (TDM) up to 310 μg/kg.³He and⁴He covary in the vent samples, with³He/⁴He about 8 times the atmospheric ratio, reflecting a mantle helium source. In contrast to the helium isotopes the Mn/³He ratio in the vent samples is variable, ranging from 4.3 × 10⁴ up to 1.0 × 10⁵ g/cm³. Profiles of³He/⁴He and TDM in the water column at 21°N show a sharp maximum ofδ(³He) = 47%and TDM= 0.69 μg/kg, much higher than the average values of 34% and 0.2 μg/kg for the deep water in this region. This spike in³He and Mn occurs at 2400 m depth, 200 m above the level of the 21°N vents, and 100 m higher than any local bathymetry, evidence for upward transport of the hydrothermal discharge via rising plumes of hot vent water. Two of the 21°N Deep-Tow samples associated with small (?0.010°C) temperature anomalies hadδ(³He) = 38%and TDM= 0.28 and 0.58 μg/kg, also slightly elevated relative to background. The Deep-Tow and hydrocast samples have lower Mn/³He ratios than average vent samples due to Mn removal by scavenging. Comparison of vent samples and water column measurements at 21°N indicate that the pure vent water could be detected using³He and Mn even when diluted ～10⁵ times with seawater, confirming that these two tracers are extremely sensitive indicators of submarine hydrothermal activity.     

A high-temperature hydrothermal deposit on the East Pacific Rise near 7°N

A SEABEAM survey of the East Pacific Rise (EPR) led to the selection of several sites having structural characteristics favorable for hydrothermal activity. Dredging of such an area located at 7°N on the EPR resulted in the recovery of sulfides, oxides and fresh basalt. Chemical analyses and isotopic compositions showed that the recovered pyrites were probably precipitated directly from hot vent hydrothermal waters. Chemical analyses and isotopic composition of manganese-iron oxides indicated that they too were of hydrothermal origin. ²¹⁰Pb/Pb measurements yielded ages of 90 ± 10years for the deposits. This site may still be undergoing hydrothermal activity.     

Zinc stable isotopes in seafloor hydrothermal vent fluids and chimneys

Many of the heaviest and lightest natural zinc (Zn) isotope ratios have been discovered in hydrothermal ore deposits. However, the processes responsible for fractionating Zn isotopes in hydrothermal systems are poorly understood. In order to better assess the total range of Zn isotopes in hydrothermal systems and to understand the factors which are responsible for this isotopic fractionation, we have measured Zn isotopes in seafloor hydrothermal fluids from numerous vents at 9–10°N and 21°N on the East Pacific Rise (EPR), the TAG hydrothermal field on the Mid-Atlantic Ridge, and in the Guaymas Basin. Fluid δ⁶⁶Zn values measured at these sites range from + 0.00‰ to + 1.04‰. Of the many physical and chemical parameters examined, only temperature was found to correlate with fluid δ⁶⁶Zn values. Lower temperature fluids (< 250 °C) had both heavier and more variable δ⁶⁶Zn values compared to higher temperature fluids from the same hydrothermal fields. We suggest that subsurface cooling of hydrothermal fluids leads to precipitation of isotopically light sphalerite (Zn sulfide), and that this process is a primary cause of Zn isotope variation in hydrothermal fluids. Thermodynamic calculations carried out to determine saturation state of sphalerite in the vent fluids support this hypothesis with isotopically heaviest Zn found in fluids that were calculated to be saturated with respect to sphalerite. We have also measured Zn isotopes in chimney sulfides recovered from a high-temperature (383 °C) and a low-temperature (203 °C) vent at 9–10°N on the EPR and, in both cases, found that the δ⁶⁶Zn of chimney minerals was lighter or similar to the fluid δ⁶⁶Zn. The first measurements of Zn isotopes in hydrothermal fluids have revealed large variations in hydrothermal fluid δ⁶⁶Zn, and suggest that subsurface Zn sulfide precipitation is a primary factor in causing variations in fluid δ⁶⁶Zn. By understanding how chemical processes that occur beneath the seafloor affect hydrothermal fluid δ⁶⁶Zn, Zn isotopes may be used as a tracer for studying hydrothermal processes.     

Water column anomalies associated with hydrothermal activity in the Guaymas Basin,Gulf of California

Sea floor hydrothermal activity in the Guaymas Basin, Gulf of California, is quite different from that associated with ridge crest spreading centers. Injection of hydrothermal fluids occurs in the bottom of a semi-enclosed basin and water column anomalies produced by this activity increase to much higher values than in the open ocean. In the Guaymas Basin the hydrothermal venting generates large clouds of fine suspended particulate matter (SPM) 100–300 m above active mounds and chimneys. These hydrothermal clouds have potential temperature anomalies of about 0.010–0.020°C, are enriched in dissolved silica, particulate manganese, and depleted in dissolved oxygen relative to areas away from the vents. The particulate manganese values increase from about 3 nmol/kg at ～ 1000 m, well above the enclosing topography of the subsill basin, to 100–150 nmol/kg in the clouds of SPM and in the bottom nepheloid layer. The particulate Mn in the hydrothermal clouds appears to originate from both direct precipitation of dissolved Mn²⁺ injected by the vents and entrainment of Mn-rich SPM in the rising hydrothermal plumes. Injection of silica-rich vent fluids into the basin bottom waters produces a silica anomaly of 10–15 μmol relative to the other deep basins of the Gulf of California. Spillover of Guaymas Basin deep water produces a silica plume just above the basin sill depth which is detectable to the mouth of the Gulf. A simple two-endmember mixing model indicates that the deep waters of the Guaymas Basin contain approximately 0.1% hydrothermal fluid. Oxygen anomalies associated with the hydrothermal clouds are on the order of 5 μmol relative to regions away from active vents. The basin as a whole shows a depletion in oxygen of about 13 μmol relative to the other deep basins of the Gulf. The mixing model shows that this oxygen consumption can be explained by the oxidation of dissolved sulfide and methane injected by the hydrothermal vents. Box models of the deep basins of the southern Gulf of California indicate that the Guaymas Basin has a significantly higher source term for dissolved silica and sink term for dissolved oxygen than the other basins. The calculated flux of hydrothermal fluids into the Guaymas Basin is 10–12 m³/s.     

Time-series temperature measurements at high-temperature hydrothermal vents, East Pacific Rise 9°49′–51′N: evidence for monitoring a crustal cracking event

Temperature measurements of hydrothermal vent fluids provide an important indicator of the physical and chemical state of mid-ocean ridge crest hydrothermal and magmatic systems. Changes in vent fluid temperature and chemistry can have dramatic effects on biological communities that inhabit these unique ecosystems. In an attempt to understand temporal variability of ridge crest hydrothermal activity as it relates to geological processes at the ridge axis, six high-temperature hydrothermal vents on the East Pacific Rise crest between 9°49′N and 9°51′N were instrumented and sampled repeatedly during five years following a submarine volcanic eruption in 1991. Bio9 vent, located on the floor of the axial trough near 9°50.2′N, has the most complete record of fluid temperatures from 1991 to 1997, including a continuous temperature record of nearly three years (1994–1997). Bio9 vent fluids were 368°C in 1991, increased to an estimated temperature ≥388°C after a second volcanic event in 1992, and thereafter declined over the next 2 years reaching a temperature of 365°C in December 1993. Continuous temperature records and point measurements made by Alvin's thermocouple probe show Bio9 vent fluids were stable for 15 months at 365±1°C, until March 26, 1995. On March 26, an abrupt 7°C increase occurred over a period of eight days at this vent, and a maximum temperature of 372±1°C persisted for 14 days. The vent fluid cooled gradually over 3.5 months to 366±1°C, and for several months at the end of the recording period the temperature increased a few degrees. A continuous record of fluid temperature at this vent between November 1995 and November 1997 shows a 5±1°C increase for the two-year period. The abrupt temperature increase at Bio9 vent, and coincident changes in faunal community structure, and geochemistry of vent fluids from this area suggest that a crustal event occurred, either in the form of a cracking front in the crust or intrusion of a small dike. Based on the results of a microseismicity experiment conducted around the Bio9 vent in 1995 [Sohn et al., Trans. Am. Geophys. Union 78 (1997) F647; Sohn et al., Nature (in press)], and the identification of a small earthquake swarm which occurred on March 22, 1995 we conclude that the temperature anomaly measured at Bio9 four days following the swarm was caused by a cracking front penetrating into hot crustal rocks beneath the vent.     

Characteristics of hydrothermal plumes from two vent fields on the Juan de Fuca Ridge, northeast Pacific Ocean

Deep CTD/transmissometer tows and water bottle sampling were used during 1985 to map the regional distribution of the neutrally-buoyant plumes emanating from each of two major vent fields on the Southern Symmetrical Segment (SSS) and Endeavour Segment (ES) of the Juan de Fuca Ridge. At both vent fields, emissions from point and diffuse hydrothermal sources coalesced into a single 200-m-thick plume elongated in the direction of current flow and with characteristic temperature anomalies of 0.02–0.05°C and light-attenuation anomalies of 0.01–0.08 m⁻¹ (10–80 μg/l above background). Temperature anomalies in the core of each plume were uniform as far downcurrent as the plumes were mapped (10–15 km). Downcurrent light-attenuation trends were non-uniform and differed between plumes, apparently because different vent fluid chemistries at each field cause significant differences in the settling characteristics of the hydrothermal precipitates. Vent fluids from the SSS are metal-dominated and mostly precipitate very fine-grained hydrous Fe-oxides that remain suspended in the plume. Vent fluids from the ES are sulfur-dominated and precipitate a high proportion of coarser-grained Fe-sulfides that rapidly settle from the plume. The integrated flux of each vent field was estimated from measurements of the advective transport of each plume. Heat flux was 1700 ± 1100 MW from the ES and 580 ± 351 MW from the SSS. Particle flux varied from 546 ± 312 g/s to 204 ± 116 g/s at the ES depending on distance from the vent field, and was 92 ± 48 g/s from the SSS.     

Flow rates in the axial hot springs of the East Pacific Rise (21°N): Implications for the heat budget and the formation of massive sulfide deposits

The first in-situ measurements of flow rates in submarine hot springs (temperatures between 275° and 350°C) were made in the hot springs of the East Pacific Rise at 21°N during November, 1981. The flow rates ranged between 0.7 and 2.4 m/s. We estimate that the total rates at which heat and mass are transported from the three hot spring areas—OBS, National Geographic, and Southwest Vents—are ca. 2.2×10⁸ W and 150 kg of fluid/s respectively. The very high rate of heat loss precludes the existence of hot springs as steady state features of the East Pacific Rise at 21°N. We estimate that hot springs are active for a maximum of ca. 40,000 years. Chemical and/or mechanical clogging of the vents can drastically reduce the lifetime of the hot springs.Using a simple model of plume development [1], we calculated that less than 3% of the sulfide particles that are entrained in the hydrothermal plumes at 21°N settle from the plumes before dispersal by a lateral submarine current at a height of ca. 250 m above the seafloor [2]. The time that is required to form the sulfide mounds that surround the hot springs by the accumulation of sulfide particles that settle from the plumes is ca. 70–85 years. The current rate at which sulfide particles settle from the hydrothermal plumes and accumulate near the hot springs appears to be too small to lead to the formation of large massive sulfide deposits such as the Mavrouni deposit on Cyprus [3], within the time limits that are suggested by our thermal energy balance calculations.     

Heat loss from the earth: A constraint on Archaean tectonics from the relation between geothermal gradients and the rate of plate production

The models suggested for the oceanic lithosphere which best predict oceanic heat flow and depth profiles are the constant thickness model and a model in which the lithosphere thickens away from the ridge with a heat source at its base. The latter is considered to be more physically realistic. Such a model, constrained by the observed oceanic heat flow and depth profiles and a temperature at the ridge crest of between 1100°C and 1300°C, requires a heat source at the base of the lithosphere of between 0.5 and 0.9 h.f.u., thermal conductivities for the mantle between 0.005 and 0.0095 cal cm⁻¹ °C⁻¹ s⁻¹ and a coefficient of thermal expansion at 840°C between 4.1 × 10⁻⁵ and 5.1 × 10⁻⁵ °C⁻¹. Plate creation and subduction are calculated to dissipate about 45% of the total earth heat loss for this model. The efficiency of this mechanism of heat loss is shown to be strongly dependent on the magnitude of the basal heat source. A relation is derived for total earth heat loss as a function of the rate of plate creation and the amount of heat transported to the base of plates. The estimated heat transport to the base of the oceanic lithosphere is similar to estimates of mantle heat flow into the base of the continental lithosphere. If this relation existed in the past and if metamorphic conditions in late Archaean high-grade terrains can be used to provide a maximum constraint on equilibrium Archaean continental thermal gradients, heat flow into the base of the lithosphere in the late Archaean must have been less than about 1.2–1.5 h.f.u. The relation between earth heat loss, the rate of plate creation and the rate of heat transport to the base of the lithosphere suggests that a significant proportion of the heat loss in the Archaean must have taken place by the processes of plate creation and subduction. The Archaean plate processes may have involved much more rapid production of plates only slightly thinner than at present.     

Geochemical anomalies of hydrothermal plume at EPR 13°N

During the DY105-12, 14cruise (R/V DAYANG YIHAO, November 2003) on East Pacific Rise (EPR) 12- 13°N, the submarine hydrothermal activity was investigated and the CTD hydrocast was carried out at EPR12°39′N-12°54′N. From the temperature anomalies and the concentrations of magnesium, chlorine, bromine in seawater samples, we discover that magnesium depletes 9.3%-22.4%, chlorine and bro- mine enrich 10.3%-28.7% and 10.7%-29.0% respectively relative to normal seawater at the stations which have chemistry anomalies, moreover temperature and chemistry anomalies are at the same layer. The depletion of magnesium in the plume may be caused by a fluid lacking of magnesium which rises after the hydrothermal fluid reaches the equilibrium with ambient seawater, the enrichment of chlorine and bromine might be the result of inputting later brine which is generated by phase separation due to hydrothermal activity. In addition, the Br/Cl ratio in the abnormal layers at the survey area is identical to that in seawater, which implies that halite dissolution (or precipitation) occurs neither when the fluid is vented nor when hydrothermal fluid entraining ambient seawater rises to form plume. From the ab- normal instance at E55 station, it is very possible that there might exist a new hydrothermal vent site.     

U,U andTh in seawater

We have developed techniques to determine²³⁸U,²³⁴U and²³²Th concentrations in seawater by isotope dilution mass spectrometry. U measurements are made using a²³³U²³⁶U double spike to correct for instrumental fractionation. Measurements on uranium standards demonstrate that²³⁴U/²³⁸U ratios can be measured accurately and reproducibly.²³⁴U/²³⁸U can be measured routinely to ± 5‰ (2σ) for a sample of 5 × 10⁹ atoms of²³⁴U (3 × 10⁻⁸ g of total U, 10 ml of seawater). Data acquisition time is 1 hour. The small sample size, high precision and short data acquisition time are superior to-counting techniques.²³⁸U is measured to ± 2‰ (2σ) for a sample of 8 × 10¹² atoms of²³⁸U ( 3 × 10⁻⁹ g of U, 1 ml of seawater).²³²Th is measured to ± 20‰ with 3 × 10¹¹²³²Th atoms (10⁻¹⁰ g²³²Th, 1 1 of seawater). This small sample size will greatly facilitate investigation of the²³²Th concentration in the oceans. Using these techniques, we have measured²³⁸U,²³⁴U and²³²Th in vertical profiles of unfiltered, acidified seawater from the Atlantic and²³⁸U and²³⁴U in vertical profiles from the Pacific. Determinations of²³⁴U/²³⁸U at depths ranging from 0 to 4900 m in the Atlantic (7°44′N, 40°43′W) and the Pacific (14°41′N, 160°01′W) Oceans are the same within experimental error (± 5‰,2σ). The average of these²³⁴U/²³⁸U measurements is 144 ± 2‰ (2σ) higher than the equilibrium ratio of 5.472 × 10⁻⁵. U concentrations, normalized to 35‰ salinity, range from 3.162 to 3.281 ng/g, a range of 3.8%. The average concentration of the Pacific samples (31°4′N, 159°1′W) is 1% higher than that of the Atlantic (7°44′N, 40°43′W and 31°49′N, 64°6′W).²³²Th concentrations from an Atlantic profile range from 0.092 to 0.145 pg/g. The observed constancy of the²³⁴U/²³⁸U ratio is consistent with the predicted range of²³⁴U/²³⁸U using a simple two-☐ model and the residence time of deep water in the ocean determined from¹⁴C. The variation in salinity-normalized U concentrations suggests that U may be much more reactive in the marine environment than previously thought.     

The roles of surface heat flux and ocean heat transport convergence in determining Atlantic Ocean temperature variability

The temperature variability of the Atlantic Ocean is investigated using an eddy-permitting (1/4°) global ocean model (ORCA-025) forced with historical surface meteorological fields from 1958 to 2001. The simulation of volume-averaged temperature and the vertical structure of the zonally averaged temperature trends are compared with those from observations. In regions with a high number of observations, in particular above a depth of 500 m and between 22° N and 65° N, the model simulation and the dataset are in good agreement. The relative contribution of variability in ocean heat transport (OHT) convergence and net surface heat flux to changes in ocean heat content is investigated with a focus on three regions: the subpolar and subtropical gyres and the tropics. The surface heat flux plays a relatively minor role in year-to-year changes in the subpolar and subtropical regions, but in the tropical North Atlantic, its role is of similar significance to the ocean heat transport convergence. The strongest signal during the study period is a cooling of the subpolar gyre between 1970 and 1990, which subsequently reversed as the mid-latitude OHT convergence transitioned from an anomalously weak to an anomalously strong state. We also explore whether model OHT anomalies can be linked to surface flux anomalies through a Hovmöller analysis of the Atlantic sector. At low latitudes, increased ocean heat gain coincides with anomalously strong northward transport, whereas at mid-high latitudes, reduced ocean heat loss is associated with anomalously weak heat transport.     

Structure of hydrothermal plumes at the Logatchev vent field, 14°45′N, Mid-Atlantic Ridge: evidence from geochemical and geophysical data

In the Seventh cruise of R/V “Professor Logatchev” anomalies of natural electric field (EF), Eh and pS were discovered using a towed instrument package (RIFT) at 14°45′N on the MAR (Logatchev hydrothermal field). The anomalous zone (AZ) is situated close (10–35 m) to two low-temperature venting areas of degrading sulphides and a black smoker (Irina-Microsmoke) forming a distinct buoyant plume. Over or close to the main area of high-temperature venting situated to the south-east from the AZ, no EF or Eh anomalies were observed. According to the results of Mir dives the highly mineralised solutions from smoking craters at the main mound mostly form non-buoyant plumes (reverse-plumes). The buoyant plume structure shows the differentiation of the electrical and Eh fields within the plume. Maxima of the EF, Eh and E_H2S anomalies were revealed in the lower part (15 m) of the plume. The negative redox potential plume coupled with a sulphide anomaly is more localized in comparison with the EF. This observation indicates a distinct change in the composition of buoyant plume water, which may be due to the formation and fallout of early formed Fe sulphide particles soon after venting.     

An assessment of the effect of chemical scavenging within submarine hydrothermal plumes upon ocean geochemistry

Profiles of ²¹⁰Pb over the Endeavour and North Cleft Segments of the Juan de Fuca Ridge are used to model a time scale for the scavenging, by hydrothermal plumes, of reactive elements in seawater. The hydrothermal plumes above these ridge segments are sites of intense scavenging removal of ²¹⁰Pb. At Endeavour, the total ²¹⁰Pb activities within the plume are as low as 8 dpm/100 l and dissolved activities are as low as 3 dpm/100 l. At the North Cleft, which is characterized by higher particulate Fe concentrations, the total ²¹⁰Pb activities are 4.5 dpm/100 l, the dissolved activities are 1–2 dpm/100 l and the ²¹⁰Pb activities are deficient with respect to the activity of the ²¹⁰Po daughter. These are perhaps the lowest ²¹⁰Pb activities ever measured in the deep sea. The large gradient of ²¹⁰Pb between the plume and surrounding deep water suggests that scavenging is focused into the plumes through horizontal transport. The implication, therefore, is that this process might impact the ocean on a scale larger than that local to the ridge crest. By coupling published measurements of particle flux from Endeavour with ²¹⁰Pb activities on particles trapped at that site, the total volume of seawater stripped of ²¹⁰Pb per year for that site was calculated to be 7.4 × 10¹² l/y. Globally, the extrapolated volume flux of seawater stripped of reactive constituents is 5.7 × 10¹⁵ l/y, such that the entire ocean is processed in this manner in 2.4×10⁵ y. The geochemical cycle of elements with ocean residence times much shorter than this (e.g., Pb and Th) will not be greatly affected by hydrothermal scavenging. On the other hand, this process holds significance for the geochemistry of other elements scavenged by hydrothermal plumes, such as P and V, whose ocean residence times are > 10⁴ y.     

Growth of large sulfide structures on the endeavour segment of the Juan de Fuca ridge

Mapping and sampling with DSRV “Alvin” has established that sulfide blocks 0.5 m across, dredged from the axial valley of the Endeavour Segment at 47°57′N, are samples of unusually large sulfide structures. The steep-sided structures, up to 30 m in length, 20 m in height, and 10–15 m across, are localized by venting along normal faults at the base of the western axial valley wall, and are distributed for about 200 m along strike paralleling the 020 trend of the ridge crest. High-temperature fluids (350 to more than 400°C) pass through the massive sulfide structures and enter seawater through small, concentric “nozzle-like” features projecting from the top or the sides of the larger vent structures. Diffuse, low-temperature flow is pervasive in the vicinity of the active sulfide structures, exiting from basalt and sulfide surfaces alike. Evidence of recent volcanic activity is sparse.The two largest samples taken with the dredge would not have been recoverable using the submersible. These samples represent massive, complex portions of the sulfide structures which were not closely associated with rapid high-temperature fluid flow at the time of sampling; they contain textural evidence of sealed hydrothermal fluid exit channels. Mineralogy is dominated by Fe sulfides nnd amorphous silica. Pyrite, marcasite, wurtzite, chalcopyrite, and iss are the most common sulfide phases. Pyrrhotite, galena, and sphalerite are present in trace amounts. Barite, amorphous silica, and chalcedony are the only non-sulfide phases; anhydrite is not observed in any of the dredge samples, although it is common in the chimney-like samples recovered by “Alvin”.Specific mineralogical-textural zones within the dredge samples are anaoogous to individual layers in East Pacific Rise at 21°N and southern Juan de Fuca Ridge samples, with two exceptions: a coarse-grained, highly porous Fe sulfide-rich interior containing sulfidized tubeworm casts, and a 2–5 cm thick zone near the outer margin of the samples dominated by late stage amorphous silica. The porous interior may have formed by dendritic crystal growth from a slowly circulating fluid within a large enclosed chamber. The amorphous silica deposited from a seawater/hydrothermal fluid mixture percolating slowly through the walls of the enclosed chamber; conductive cooling of the fluid as it traversed the walls allowed amorphous silica to precipitate. These silica-rich zones are the densest, most durable portions of the structures and may be responsible for the lasting stability of the large sulfide features.Observations in these samples are consistent with two distinct phases of development. Phase 1 is analogous to chimney growth and construction at 21°N and ends when flow channels become sealed to rapid flow of through-going fluid. The flow is evidently redirected within the structure. Phase 2 includes dissolution of anhydrite and precipitation of amorphous silica during conductive cooling of sluggishly circulating hydrothermal fluid or seawater/hydrothermal fluid mixtures. Evolution of vent structures through phase 2 allows lateral and vertical growth of unusually large structures.     

REE diffusion in calcite

Chemical diffusion of four rare-earth elements (La, Nd, Dy and Yb) has been measured in natural calcite under anhydrous conditions, using rare-earth carbonate powders as the source of diffusants. Experiments were run in sealed silica capsules along with finely ground calcite to ensure stability of the single-crystal samples during diffusion anneals. Rutherford backscattering spectroscopy (RBS) was used to measure diffusion profiles. The following Arrhenius relations were obtained over the temperature range 600–850°C: D_La =2.6×10⁻¹⁴ exp(−147±14 kJ mol⁻¹/RT) m² s⁻¹, D_Nd =2.4×10⁻¹⁴ exp(−150±13 kJ mol⁻¹/RT) m² s⁻¹, D_Dy =2.9×10⁻¹⁴ exp(−145±25 kJ mol⁻¹/RT) m² s⁻¹, D_Yb =3.9×10⁻¹² exp(−186±23 kJ mol⁻¹/RT) m² s⁻¹. In contrast to previous findings for refractory silicates (e.g. zircon), differences in transport rates among the REE are not pronounced over the range of temperature conditions investigated in this study. Diffusion of the REE is significantly slower than diffusion of the divalent cations Sr and Pb and slower than transport of Ca and C at temperatures above 650°C. Fine-scale zoning and isotopic and REE chemical signatures may be retained in calcites under many conditions if diffusion is the dominant process affecting alteration.     

洋壳渗透率结构对其内部热液对流的影响研究——基于热力学数值模拟

洋底特殊环境的限制使数值模拟成为研究海底热液对流与成矿机制的有效方法.本文通过数值模拟的方法,研究洋壳渗透率单因素变化对热液对流系统的形态和输出参数（热液喷发温度和热流值）进行研究.模拟结果表明,洋壳平均渗透率分别与热液喷发温度和热量输出呈反相关和正相关关系,符合达西流体热对流的基本解析规律.另外,洋壳渗透率的垂向变化不会使洋壳内部的对流系统产生明显的横向偏移,只使热液羽规模在垂向上产生规律性变化,且渗透率越大,热液羽规模越小.渗透率在水平方向的变化则是引发热液羽和热液喷发位置横向偏移的主要因素,且只有在特定的渗透率水平变化率范围内,上涌热液羽才会发生向高渗区的明显偏移,这也从一定程度上解释了现今拆离断层相关的热液系统均未发育于断层终止线上的事实.以大西洋Trans-Atlantic Geotraverse（TAG）热液区为例,断裂带高渗区必然影响相邻洋壳内部热液的上涌路径,但受区内拆离断裂带周缘的渗透率水平变化规律的影响,上涌热液羽不至于完全偏移至断裂带,从而产生拆离断层上盘的热液活动.

     

Magmatism and tectonic processes in Area A hydrothermal vent on the Southwest Indian Ridge

The hydrothermal vent in Area A(37.78°S,49.65°E)is the first active hydrothermal vent discovered on the Southwest Indian Ridge(SWIR).Heat source and adequate bulk permeability are two necessary factors for the formation of a hydrothermal vent.Along the SWIR 49.3°E to 51.2°E,the gravity-derived crustal thickness is up to 9.0 km,much thicker than the average thickness of the global oceanic crust.This characteristic indicates that the magma supply in this area is robust,which is possibly affected by a hotspot.The large-scale residual mantle Bouguer anomalies(RMBA)reveal prominent negative-gravity anomalies between the first-order ridge segment(from Indomed to Gallieni,46.0°E to 52.0°E)and the Marion-Del Cano-Crozet region.These anomalies indicate the channel of the hotspot-ridge interaction.The tomography data corrected with theoretical thermal model indicate that the low-velocity anomalies corresponding to this channel can reach the base of the lithosphere.Near the hydrothermal vent area,the topography and crustal thickness at the off-axis area are extremely asymmetrical.South of the SWIR,the high topography corresponds to the thinning crustal thickness.The residual isostatic topography anomalies indicate that Area A is a deviation from the local isostatic equilibrium,similar to the characteristics of the transform fault inside corner.The forward profiles of the magnetic data indicate that the thinning magnetic layer at the south side of Area A corresponds to the shallow,high-velocity area revealed by the OBS,which is the result of tectonic extension of a detachment fault.The active tectonic processes in Area A can provide sufficient crustal permeability to the hydrothermal circulation and may form massive sulfide deposits.     

The Mid-Atlantic Ridge between 29°N and 31°30′N in the last 10 Ma

The segmentation of the Mid-Atlantic Ridge between 29°N and 31°30′ N during the last 10 Ma was studied. Within our survey area the spreading center is segmented at a scale of 25–100 km by non-transform discontinuities and by the 70 km offset Atlantis Transform. The morphology of the spreading center differs north and south of the Atlantis Transform. The spreading axis between 30°30′N and 31°30′N consists of enéchelon volcanic ridges, located within a rift valley with a regional trend of 040°. South of the transform, the spreading center is associated with a well-defined rift valley trending 015°. Magnetic anomalies and the bathymetric traces left by non-transform discontinuities on the flanks of the Mid-Atlantic Ridge provide a record of the evolution of this slow-spreading center over the last 10 Ma. Migration of non-transform offsets was predominantly to the south, except perhaps in the last 2 Ma. The discontinuity traces and the pattern of crustal thickness variations calculated from gravity data suggest that focused mantle upwelling has been maintained for at least 10 Ma south of 30°30′ N. In contrast, north of 30°30′N, the present segmentation configuration and the mantle upwelling centers inferred from gravity data appear to have been established more recently. The orientation of the bathymetric traces suggests that the migration of non-transform offsets is not controlled by the motion of the ridge axis with respect to the mantle. The evolution of the spreading center and the pattern of segmentation is influenced by relative plate motion changes, and by local processes, perhaps related to the amount of melt delivered to spreading segments. Relative plate motion changes over the last 10 Ma in our survey area have included a decrease in spreading rate from 32 mm a⁻¹ to 24 mm a⁻¹, as well as a clockwise change in spreading direction of 13° between anomalies 5 and 4, followed by a counterclockwise change of 4° between anomaly 4 and the present. Interpretation of magnetic anomalies indicates that there are significant variations in spreading asymmetry and rate within and between segments for a given anomaly time. These differences, as well as variations in crustal thickness inferred from gravity data on the flanks of spreading segments, indicate that magmatic and tectonic activity are, in general, not coordinated between adjacent spreading segments.     

Environmental impact in sandy beaches of copper mine tailings at Chañaral, Chile

Since 1938, untreated copper mine tailings of Potrerillos and El Salvador have been disposed into the sea at Chañaral, Chile (26° 21′ Lat. S., 70° 42′ Long. W.). Over 220×10⁶ t of sediments have been dumped. This pollution has caused drastic geomorphological changes in the c. 16 km contaminated area. The occurrence of new artificial beaches and modification of coastal contours are reported. Sandy beach macrofauna monitoring (1975–1982) demonstrated a progressive lowering of density and biomass in those communities affected by copper mine tailings.