Search for methane and upper limits to ethane and SO2 on Mars

The IRTF/CSHELL observations in February 2006 at L_S = 10° and 63–93°W show ～10 ppb of methane at 45°S to 7°N and ～3 ppb outside this region that covers the deepest canyon Valles Marineris. Observations in December 2009 at L_S = 20° and 0–30°W included spectra of the Moon at a similar airmass as a telluric calibrator. A technique for extraction of the martian methane line from a combination of the Mars and Moon spectra has been developed. The observations reveal no methane with an upper limit of 8 ppb. The results of both sessions agree with the observations by Mumma et al. (Mumma, M.J. et al. [2009]. Science 323, 1041–1045) at the same season in February 2006 and are smaller than those in the PFS and TES maps. Production and removal of the biological methane on Mars do not significantly change the redox state of the atmosphere and the balance of hydrogen. A search for ethane at 2977 cm^?1 results in an upper limit of 0.2 ppb. However, this limit does not help to establish the origin of methane on Mars. Reanalysis of our search for SO₂ using TEXES confirms the recently established upper limit of 0.3 ppb. Along with the lack of hot spots and gas vents with endogenic heat sources in the THEMIS observations, the very low upper limit to SO₂ on Mars does not favor geological methane that is less abundant than SO₂ in the outgassing from the terrestrial planets.     

The O2 nightglow in the martian atmosphere by SPICAM onboard of Mars-Express

We present observations of the O₂(a¹Δ_g) nightglow at 1.27 μm on Mars using the SPICAM IR spectrometer onboard of the Mars Express orbiter. In contrast to the O₂(a¹Δ_g) dayglow that results from the ozone photodissociation, the O₂(a¹Δ_g) nightglow is a product of the recombination of O atoms formed by CO₂ photolysis on the dayside at altitudes higher than 80 km and transported downward above the winter pole by the Hadley circulation. The first detections of the O₂(a¹Δ_g) nightglow in 2010 indicate that it is about two order of magnitude less intense than the dayglow (Bertaux, J.-L., Gondet, B., Bibring, J.-P., Montmessin, F., Lefèvre, F. [2010]. Bull. Am. Astron. Soc. 42, 1040; Clancy et al. [2010]. Bull. Am. Astron. Soc. 42, 1041). SPICAM IR sounds the martian atmosphere in the near-IR range (1–1.7 μm) with the spectral resolution of 3.5 cm^?1 in nadir, limb and solar occultation modes. In 2010 the vertical profiles of the O₂(a¹Δ_g) nightside emission have been obtained near the South Pole at latitudes of 82–83°S for two sequences of observations: L_s = 111–120° and L_s = 152–165°. The altitude of the emission maximum varied from 45 km on L_s = 111–120° to 38–49 km on L_s = 152–165°. Averaged vertically integrated intensity of the emission at these latitudes has shown an increase from 0.22 to 0.35 MR. Those values of total vertical emission rate are consistent with the OMEGA observations on Mars-Express in 2010. The estimated density of oxygen atoms at altitudes from 50 to 65 km varies from 1.5 × 10¹¹ to 2.5 × 10¹¹ cm^?3. Comparison with the LMD general circulation model with photochemistry (Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F. [2004]. J. Geophys. Res. 109, E07004; Lefèvre et al. [2008]. Nature 454, 971–975) shows that the model reproduces fairly well the O₂(a¹Δ_g) emission layer observed by SPICAM when the large field of view (>20 km on the limb) of the instrument is taken into account.     

Direct wind measurements from November 2007 in Venus’ upper atmosphere using ground-based heterodyne spectroscopy of CO2 at 10 μm wavelength

Between November 23 and 28, 2007, the Cologne Tuneable Heterodyne Infrared Spectrometer THIS was installed at the McMath-Pierce Solar Telescope (Kitt Peak, Arizona, USA) to determine zonal wind velocities and to estimate the subsolar-to-antisolar flow. We investigate dynamics in the upper atmosphere of Venus by measuring the Doppler shift of fully-resolved non-LTE CO₂ emission lines at 959.3917 cm^?1 (10.423 μm), which probe a narrow altitude region in Venus’ atmosphere around 110 ± 10 km (～1 μbar). The results show no significant zonal wind velocity at the equator. An increase with latitude up to 43 ± 13 m/s at a latitude of 33°N was observed. This confirms the deduction of a minor influence of Venus superrotation at an altitude of 110 km from previous measurements in May 2007 (Sornig et al., 2008). The specific observing geometry enables estimating the maximum cross terminator velocity of the subsolar-to-antisolar flow at 72 ± 47 m/s.     

Titan’s aerosol and stratospheric ice opacities between 18 and 500 μm: Vertical and spectral characteristics from Cassini CIRS

Vertical distributions and spectral characteristics of Titan’s photochemical aerosol and stratospheric ices are determined between 20 and 560 cm^?1 (500–18 μm) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15°N, 15°S, and 58°S, where accurate temperature profiles can be independently determined.In addition, estimates of aerosol and ice abundances at 62°N relative to those at 15°S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are ～3 times more abundant at 62°N than at 15°S. Generally, nitrile ice clouds (probably HCN and HC₃N), as inferred from a composite emission feature at ～160 cm^?1, appear to be located over a narrow altitude range in the stratosphere centered at ～90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58°S.There is some evidence of a second ice cloud layer at ～60 km altitude at 58°S associated with an emission feature at ～80 cm^?1. We speculate that the identify of this cloud may be due to C₂H₆ ice, which in the vapor phase is the most abundant hydrocarbon (next to CH₄) in the stratosphere of Titan.Unlike the highly restricted range of altitudes (50–100 km) associated with organic condensate clouds, Titan’s photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15°N and 58°S latitude. The ratio of aerosol-to-gas scale heights range from 1.3–2.4 at about 160 km to 1.1–1.4 at 300 km, although there is considerable variability with latitude. The aerosol exhibits a very broad emission feature peaking at ～140 cm^?1. Due to its extreme breadth and low wavenumber, we speculate that this feature may be caused by low-energy vibrations of two-dimensional lattice structures of large molecules. Examples of such molecules include polycyclic aromatic hydrocarbons (PAHs) and nitrogenated aromatics.Finally, volume extinction coefficients Nχ_E derived from 15°S CIRS data at a wavelength of λ = 62.5 μm are compared with those derived from the 10°S Huygens Descent Imager/Spectral Radiometer (DISR) data at 1.583 μm. This comparison yields volume extinction coefficient ratios Nχ_E(1.583 μm)/Nχ_E(62.5 μm) of roughly 70 and 20, respectively, for Titan’s aerosol and stratospheric ices. The inferred particle cross-section ratios χ_E(1.583 μm)/χ_E(62.5 μm) appear to be consistent with sub-micron size aerosol particles, and effective radii of only a few microns for stratospheric ice cloud particles.     

Observations of water vapour and carbon monoxide in the Martian atmosphere with the SWC of PFS/MEX

In the history of Mars exploration its atmosphere and planetary climatology aroused particular interest. In the study of the minor gases abundance in the Martian atmosphere, water vapour became especially important, both because it is the most variable trace gas, and because it is involved in several processes characterizing the planetary atmosphere. The water vapour photolysis regulates the Martian atmosphere photochemistry, and so it is strictly related to carbon monoxide. The CO study is very important for the so-called “atmosphere stability problem”, solved by the theoretical modelling involving photochemical reactions in which the H₂O and the CO gases are main characters.The Planetary Fourier Spectrometer (PFS) on board the ESA Mars Express (MEX) mission can probe the Mars atmosphere in the infrared spectral range between 200 and 2000 cm^?1 (5–50 μm) with the Long Wavelength Channel (LWC) and between 1700 and 8000 cm^?1 (1.2–5.8 μm) with the Short Wavelength Channel (SWC). Although there are several H₂O and CO absorption bands in the spectral range covered by PFS, we used the 3845 cm^?1 (2.6 μm) and the 4235 cm^?1 (2.36 μm) bands for the analysis of water vapour and carbon monoxide, respectively, because these ranges are less affected by instrumental problems than the other ones. The gaseous concentrations are retrieved by using an algorithm developed for this purpose.The PFS/SW dataset used in this work covers more than two and a half Martian years from Ls=62° of MY 27 (orbit 634) to Ls=203° of MY 29 (orbit 6537). We measured a mean column density of water vapour of about 9.6 pr. μm and a mean mixing ratio of carbon monoxide of about 990 ppm, but with strong seasonal variations at high latitudes. The seasonal water vapour map reproduces very well the known seasonal water cycle. In the northern summer, water vapour and CO show a good anticorrelation most of the time. This behaviour is due to the carbon dioxide and water sublimation from the north polar ice cap, which dilutes non-condensable species including carbon monoxide. An analogous process takes place during the winter polar cap, but in this case the condensation of carbon dioxide and water vapour causes an increase of the concentration of non-condensable species. Finally, the results show the seasonal variation of the carbon monoxide mixing ratio with the surface pressure.     

Characterizing Io’s Pele,Tvashtar and Pillan plumes: Lessons learned from Hubble

Hubble Space Telescope/Wide Field and Planetary Camera 2 (HST/WFPC2) images of Io obtained between 1995 and 2007 between 0.24 and 0.42 μm led to the detection of the Pele plume in reflected sunlight in 1995 and 1999; imaging of the Pele plume via absorption of jovian light in 1996 and 1999; detection of the Prometheus-type Pillan plume in reflected sunlight in 1997; and detection of the 2007 Pele-type Tvashtar plume eruption in reflected sunlight and via absorption of jovian light. Based on a detailed analysis of these observations we characterize and compare the gas and dust properties of each of the detected plumes. In each case, the brightness of the plumes in reflected sunlight is less at 0.26 μm than at 0.33 μm. Mie scattering analysis of the wavelength dependence of each plume’s reflectance signature suggests that range of particle sizes within the plumes is quite narrow. Assuming a normal distribution of particle sizes, the range of mean particle sizes is ～0.035–0.12 μm for the 1997 Pillan eruption, ～0.05–0.08 μm for the 1999 Pele and 2007 Tvasthar plumes, and ～0.05–0.11 μm for the 1995 Pele plume, and in each case the standard deviation in the particle size distribution is <15%. The Mie analysis also suggests that the 2007 Tvashtar eruption released ～10⁹ g of sulfur dust, the 1999 Pele eruption released ～10⁹ g of SO₂ dust, the 1997 Pillan eruption released ～10¹⁰ g of SO₂ dust, and the 1995 Pele plume may have released ～10¹⁰ g of SO₂ dust. Analysis of the plume absorption signatures recorded in the F255W filter bandpass (0.24–0.28 μm) indicates that the opacity of the 2007 Tvashtar plume was 2× that of the 1996 and 1999 Pele plume eruptions. While the sulfur dust density estimated for the Tvashtar from the reflected sunlight data could have produced 61% of the observed plume opacity, <10% of the 1999 Pele F255W plume opacity could have resulted from the SO₂ dust detected in the eruption. Accounting for the remaining F255W opacity level of the Pele and Tvasthar plumes based on SO₂ and S₂ gas absorption, the SO₂ and S₂ gas density inferred for each plume is almost equivalent corresponding to ～2–6 × 10¹⁶ cm^?2 and 3–5 × 10¹⁵ cm^?2, respectively, producing SO₂ and S₂ gas resurfacing rates ～0.04–0.2 cm yr^?1 and 0.007–0.01 cm yr^?1; and SO₂ and S₂ gas masses ～1–4 × 10¹⁰ g and ～2–3 × 10⁹ g; for a total dust to gas ratio in the plumes ～10^?1–10^?2. The 2007 Tvashtar plume was detected by HST at ～380 ± 40 km in both reflected sunlight and absorbed jovian light; in 1999, the detected Pele plume altitude was 500 km in absorbed jovian light, but in reflected sunlight the detected height was ～2× lower. Thus, for the 1999 Pele plume, similar to the 1979 Voyager Pele plume observations, the most efficient dust reflections occurred in the region closest to the plume vent. The 0.33–0.42 μm brightness of the 1997 Pillan plume was 10–20× greater than the Pele or Tvashtar plumes, exceeding by a factor of 3 the average brightness levels observed within 200 km of 1979 Loki eruption vent. But, the 0.26 μm brightness of the 1997 Pillan plume in reflected sunlight was significantly lower than would be predicted by the dust scattering model. Presuming that the 0.26 μm brightness of the 1997 Pillan plume was attenuated by the eruption plume’s gas component, then an SO₂ gas density ～3–6 × 10¹⁸ cm^?2 is inferred from the data (for S₂/SO₂ ratios ?4%), comparable to the 0.3–2 × 10¹⁸ cm^?2 SO₂ density detected at Loki in 1979 (Pearl, J.C. et al. [1979]. Nature 280, 755; Lellouch et al., 1992), and producing an SO₂ gas mass ～3–8 × 10¹¹ g and an SO₂ resurfacing rate ～8–23 cm yr^?1. These results confirm the connection between high (?10¹⁷ cm^?2) SO₂ gas content and plumes that scatter strongly at nearly blue wavelengths, and it validates the occurrence of high density SO₂ gas eruptions on Io. Noting that the SO₂ gas content inferred from a spectrum of the 2003 Pillan plume was significantly lower ～2 × 10¹⁶ cm^?2 (Jessup, K.L., Spencer, J., Yelle, R. [2007]. Icarus 192, 24–40); and that the Pillan caldera was flooded with fresh SO₂ frost/slush just prior to the 1997 Pillan plume eruption (Geissler, P., McEwen, A., Phillips, C., Keszthelyi, L., Spencer, J. [2004a]. Icarus 169, 29–64; Phillips, C.B. [2000]. Voyager and Galileo SSI Views of Volcanic Resurfacing on Io and the Search for Geologic Activity at Europa. Ph.D. Thesis, Univ. of Ariz., Tucson); we propose that the density of SO₂ gas released by this volcano is directly linked to the local SO₂ frost abundance at the time of eruption.     

Local inversion of magnetic anomalies: Implication for Mars’ crustal evolution

Martian magnetic anomalies have been revealed by the Mars Global Surveyor (MGS) mission in the south hemisphere of Mars. The present study models anomalies located in the ancient Terra Sirenum area between latitudes 26°S and 40°S and longitudes 185°E and 210°E using forward and inverse approaches. While the high-altitude measurements reveal the presence of two main magnetic anomalies, three are detected by low-altitude data. They are modeled as uncorrelated dipolar sources. Forward models predict large magnetizations between 30 and 60 A/m. A generalized non-linear inversion is used to determine the characteristics of the dipoles, based on different subsets of data. Low-altitude measurements inversion leads to more reliable results than those obtained by the inversion of high-altitude measurements only. Inversion of both low- and high-altitude data together provides with three dipoles that explain more than 57% of the signal, within this 10⁶ km² area. All dipoles have large magnetizations. Serpentinization of the early martian crust can explain such remanent magnetizations. Two resulting dipoles are 56 km deep, which suggests a locally thick martian crust. The last one is shallower (31 km). This indicates different origins and/or magnetization processes. Paleomagnetic poles are calculated and located around the Tharsis bulge. It suggests that Tharsis formed at high latitudes and moved toward its present location by polar reorientation.     

Spatial variability,composition and thickness of the seasonal north polar cap of Mars in mid-spring

The planetary fourier spectrometer (PFS) for the Mars express mission (MEX) is an infrared spectrometer operating in the wavelength range from 1.2 to 45 μm by means of two spectral channels, called SWC (short wavelength channel) and LWC (long wavelength channel), covering, respectively, 1.2–5.5 and 5.5–45 μm.The middle-spring Martian north polar cap (Ls∼40°) has been observed by PFS/MEX in illuminated conditions during orbit 452. The SWC spectra are here used to study the cap composition in terms of CO₂ ice, H₂O ice and dust content. Significant spectral variation is noted in the cap interior, and regions of varying CO₂ ice grain sizes, water frost abundance, CO₂ ice cover and dust contamination can be distinguished. In addition, we correlate the infrared spectra with an image acquired during the same orbit by the OMEGA imaging spectrometer and with the altimetry from MOLA data. Many of the spectra variations correlate with heterogeneities noted in the image, although significant spectral variations are not discernible in the visible. The data have been divided into five regions with different latitude ranges and strong similarities in the spectra, and then averaged. Bi-directional reflectance models have been run with the appropriate lighting geometry and used to fit the observed data, allowing for CO₂ ice and H₂O ice grain sizes, dust and H₂O ice contaminations in the form of intimate granular mixtures and spatial mixtures.A wide annulus of dusty water ice surrounds the recessing CO₂ seasonal cap. The inner cap exhibits a layered structure with a thin CO₂ layer with varying concentrations of dark dust, on top of an H₂O ice underneath ground. In the best-fits, the ices beneath the top layer have been considered as spatial mixtures. The results are still very good everywhere in the spectral range, except where the CO₂ ice absorption coefficients are such that even a thin layer is enough to totally absorb the incoming radiation (i.e. the band is saturated). This only happens around 3800 cm⁻¹, inside the strong 2.7-μm CO₂ ice absorption band. The effect of finite snow depth has been investigated through a layered albedo model. The thickness of the CO₂ ice deposits increases with latitude, ranging from 0.5–1 g cm⁻² within region II to 60–80 g cm⁻² within the highest-latitude (up to 84°N) region V.Region I is at the cap edge and extends from 65°N to 72°N latitude. No CO₂ ice is present in this region, which consists of relatively large grains of water ice (20 μm), highly contaminated by dust (0.15 wt%). The adjacent region II is a narrow region [76–79°N] right at the edge of the north residual polar cap. This region is very distinct in the OMEGA image, where it appears to surround the whole residual cap. The CO₂ ice features are barely visible in these spectra, except for the strong saturated 2.7 μm band. It basically consists of a thin layer of 5-mm CO₂ ice on top of an H₂O ice layer with the same composition as region I. A third interesting region III is found all along the shoulder of the residual cap [79–81°N]. It extends over 1.5 km in altitude and over only 2° of latitude and consists of CO₂ ice with a large dust content. It is an admixture of CO₂ ice (3–4 mm), with several tens of ppm by mass of water ice and more than 2 ppt by mass of dust. The surface temperatures have been retrieved from the LWC spectra for each observation. We found an increase in the surface temperature in this region, indicating a spatial mixture of cold CO₂ ice and warmer dust/H₂O ice. Region IV is close to the top of the residual cap [81–84°N]; it is much brighter than region III, with a dust content 10 times lower than the latter. The CO₂ grain size is 3 mm and strong CO₂ ice features are present in the data, indicating a thicker CO₂ ice layer than in region II (1–2 g cm⁻²). The final region V is right at the top of the residual cap (⩾84°N). It is “pure” CO₂ ice (no dust) of 5 mm grain sizes, with 30 ppm by weight of water ice. The CO₂ ice features are very pronounced and the 2.7 μm band is saturated. The optical thickness is close to the semi-infinite limit (30–40 g cm⁻²). Assuming a snowpack density of 0.5 g cm⁻³, we get a minimum thickness of 1–2 cm for the top-layer of regions II and III, 4–10 cm for region IV, and ⩾60–80 cm thickness for region V. These values are in close agreement with several recent results for the south seasonal polar cap.These results should provide new, useful constraints in models of the Martian climate system and volatile cycles.     

The effect of high temperatures on the mid-to-far-infrared emission and near-infrared reflectance spectra of phyllosilicates and natural zeolites: Implications for martian exploration

Most phyllosilicates on Mars appear to be associated with ancient terrains. As such, they may have experienced shock heating produced by impacts and could have been significantly altered or melted. We characterized the effects of high temperatures on the mid-to-far-infrared (mid-to-far-IR) emission (100–1400 cm^?1; 7.1–100 μm) and near-infrared (NIR) reflectance (1.2–2.5 μm) spectra of phyllosilicates by measuring experimentally calcined (100–900 °C) phyllosilicates and also two zeolites. Correlated differential scanning calorimetry (DSC) measurements were also performed on each sample to provide insight into the thermal activities of the phyllosilicates and natural zeolites. Our results indicate that all phyllosilicates exhibit characteristic degradations in both NIR and mid-to-far-IR spectral properties between 400 and 800 °C, mainly attributable to the dehydroxylation and recrystallization processes as temperature increases. Spectral features of natural zeolites persist to higher temperatures compared to features of phyllosilicates during heating treatments. The thermal behaviors of phyllosilicate infrared (IR) properties are greatly influenced by the compositions of the octahedral cations: (1) changes in both the NIR and mid-to-far-IR spectra of phyllosilicates tend to occur at lower temperatures (300–400 °C) in the Fe³⁺-rich samples as compared to the Al³⁺-rich types (400–600 °C); (2) Mg²⁺-trioctahedral phyllosilicates hectorite, saponite, and sepiolite all display major mid-to-far-IR spectral changes at 700 °C, corresponding to the formation of enstatite; (3) phyllosilicates that have minor replacement of Mg²⁺ for Al³⁺ in octahedral positions (e.g. cheto-type montmorillonite and palygorskite) show an absorption band at ～920 cm^?1 that becomes strong at 900 °C. Inconsistency between spectral behaviors in the mid-to-far-IR and NIR regions is also discussed for phyllosilicates. Results from this study have provided suggestive evidence for the scenario that some phyllosilicates could lose all original spectral features in mid-to-far-IR region while maintaining their characteristic hydration bands in NIR region in the same temperature range.     

Trapped Ar isotopes in meteorite ALH 84001 indicate Mars did not have a thick ancient atmosphere

Water is not currently stable in liquid form on the martian surface due to the present mean atmospheric pressure of ～7 mbar and mean global temperature of ～220 K. However, geomorphic features and hydrated mineral assemblages suggest that Mars’ climate was once warmer and liquid water flowed on the surface. These observations may indicate a substantially more massive atmosphere in the past, but there have been few observational constraints on paleoatmospheric pressures. Here we show how the ⁴⁰Ar/³⁶Ar ratios of trapped gases within martian meteorite ALH 84001 constrain paleoatmospheric pressure on Mars during the Noachian era [～4.56–3.8 billion years (Ga)]. Our model indicates that atmospheric pressures did not exceed ～1.5 bar during the first 400 million years (Ma) of the Noachian era, and were <400 mbar by 4.16 Ga. Such pressures of CO₂ are only sufficient to stabilize liquid water on Mars’ surface at low latitudes during seasonally warm periods. Other greenhouse gases like SO₂ and water vapor may have played an important role in intermittently stabilizing liquid water at higher latitudes following major volcanic eruptions or impact events.     

Assessing the long-term variability of Venus winds at cloud level from VIRTIS–Venus Express

The Venus Express (VEX) mission has been in orbit to Venus for more than 4 years now. The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) instrument onboard VEX observes Venus in two channels (visible and infrared) obtaining spectra and multi-wavelength images of the planet that can be used to sample the atmosphere at different altitudes. Day-side images in the ultraviolet range (380 nm) are used to study the dynamics of the upper cloud at 66–72 km while night-side images in the near infrared (1.74 μm) map the opacity of the lower cloud deck at 44–48 km. Here we present a long-term analysis of the global atmospheric dynamics at these levels using a large selection of orbits from the VIRTIS-M dataset covering 860 Earth days that extends our previous work (Sánchez-Lavega, A. et al. [2008]. Geophys. Res. Lett. 35, L13204) and allows studying the variability of the global circulation at the two altitude levels. The atmospheric superrotation is evident with equatorial to mid-latitudes westward velocities of 100 and 60 m s^?1 in the upper and lower cloud layers. These zonal velocities are almost constant in latitude from the equator to 50°S. From 50°S to 90°S the zonal winds at both cloud layers decrease steadily to zero at the pole. Individual cloud tracked winds have errors of 3–10 m s^?1 with a mean of 5 m s^?1 and the standard deviations for a given latitude of our zonal and meridional winds are 9 m s^?1. The zonal winds in the upper cloud change with the local time in a way that can be interpreted in terms of a solar tide. The zonal winds in the lower cloud are stable at mid-latitudes to the tropics and present variability at subpolar latitudes apparently linked to the activity of the South polar vortex. While the upper cloud presents a net meridional motion consistent with the upper branch of a Hadley cell with peak velocity v = 10 m s^?1 at 50°S, the lower cloud meridional motions are less organized with some cloud features moving with intense northwards and southwards motions up to v = ±15 m s^?1 but, on average, with almost null global meridional motions at all latitudes. We also examine the long-term behavior of the winds at these two vertical layers by comparing our extended wind tracked data with results from previous missions.     

Methane emissions from Earth’s degassing: Implications for Mars

The presence of methane on Mars is of great interest, since one possibility for its origin is that it derives from living microbes. However, CH₄ in the martian atmosphere also could be attributable to geologic emissions released through pathways similar to those occurring on Earth. Using recent data on methane degassing of the Earth, we have estimated the relative terrestrial contributions of fossil geologic methane vs. modern methane from living methanogens, and have examined the significance that various geologic sources might have for Mars.Geologic degassing includes microbial methane (produced by ancient methanogens), thermogenic methane (from maturation of sedimentary organic matter), and subordinately geothermal and volcanic methane (mainly produced abiogenically). Our analysis suggests that ～80% of the “natural” emission to the terrestrial atmosphere originates from modern microbial activity and ～20% originates from geologic degassing, for a total CH₄ emission of ～28.0×10⁷ tonnes year^?1.Estimates of methane emission on Mars range from 12.6×10¹ to 57.0×10⁴ tonnes year^?1 and are 3–6 orders of magnitude lower than that estimated for Earth. Nevertheless, the recently detected martian, Northern-Summer-2003 CH₄ plume could be compared with methane expulsion from large mud volcanoes or from the integrated emission of a few hundred gas seeps, such as many of those located in Europe, USA, Mid-East or Asia. Methane could also be released by diffuse microseepage from martian soil, even if macro-seeps or mud volcanoes were lacking or inactive. We calculated that a weak microseepage spread over a few tens of km², as frequently occurs on Earth, may be sufficient to generate the lower estimate of methane emission in the martian atmosphere.At least 65% of Earth’s degassing is provided by kerogen thermogenesis. A similar process may exist on Mars, where kerogen might include abiogenic organics (delivered by meteorites and comets) and remnants of possible, past martian life. The remainder of terrestrial degassed methane is attributed to fossil microbial gas (～25%) and geothermal-volcanic emissions (～10%). Global abiogenic emissions from serpentinization are negligible on Earth, but, on Mars, individual seeps from serpentinization could be significant. Gas discharge from clathrate-permafrost destabilization should also be considered.Finally, we have shown examples of potential degassing pathways on Mars, including mud volcano-like structures, fault and fracture systems, and major volcanic edifices. All these types of structures could provide avenues for extensive gas expulsion, as on Earth. Future investigations of martian methane should be focused on such potential pathways.     

Longitudinal variation and waves in Jupiter’s south equatorial wind jet

A detailed study of the chevron-shaped dark spots on the strong southern equatorial wind jet near 7.5°S planetographic latitude shows variations in velocity with longitude and time. The presence of the large anticyclonic South Equatorial Disturbance (SED) has a profound effect on the chevron velocity, causing slower velocities to its east and increasing with distance from the disturbance. The chevrons move with velocities near the maximum wind jet velocity of ～140 m/s, as deduced by the history of velocities at this latitude and the magnitude of the symmetric wind jet near 7°N latitude. Their repetitive nature is consistent with a gravity-inertia wave (n = 75–100) with phase speed up to 25 m/s, relative to the local flow, but the identity of this wave mode is not well constrained. However, for the first time, high spatial resolution movies from Cassini images show that the chevrons oscillate in latitude with a 6.7 ± 0.7-day period. This oscillating motion has a wavelength of ～20° and a speed of 101 ± 3 m/s, following a pattern similar to that seen in the Rossby wave plumes of the North Equatorial Zone, and possibly reinforced by it. All dates show chevron latitude variability, but it is unclear if this larger wave is present during other epochs, as there are no other suitable time series movies that fully delineate it. In the presence of multiple wave modes, the difference in dominant cloud appearance between 7°N and 7.5°S is likely due to the presence of the Great Red Spot, either through changes in stratification and stability or by acting as a wave boundary.     

Periglacial mass-wasting landforms on Mars suggestive of transient liquid water in the recent past: Insights from solifluction lobes on Svalbard

On Earth, periglacial solifluction is a slow mass-wasting process related to freeze–thaw activity. We compare the morphology of small-scale lobate features on Mars to solifluction lobes in Svalbard to constrain their processes of formation. The analysis is based on high-resolution satellite imagery of Mars (HiRISE, ～25 cm/pxl), aerial images of Svalbard with a similar spatial resolution (HRSC–AX, ～20 cm/pxl) acquired through an air campaign in summer 2008, and ground truth obtained during two summer expeditions in 2009 and 2011 on Svalbard. We present a detailed study of two crater environments on Mars displaying two types of lobate forms, characterized as sorted (clast-banked) and non-sorted lobes. On both Svalbard and Mars such lobes typically occur as clusters of overlapping risers (lobe fronts), pointing to differential velocities in the soil. The martian small-scale lobes have well-defined arcuate risers and lobe treads (surface). Lobe widths range between 14 and 127 m and tread lengths between 13 and 105 m. Riser height is estimated to be approximately 1–5 m. The lobes on Mars share the plan view morphology of solifluction lobes on Svalbard and their morphometry is within the range of values of terrestrial solifluction lobes. The lobes are distinct from permafrost-creep landforms such as rock glaciers. We show the results of a survey of 53 HiRISE images covering latitudes between 59°N and 81°N. Similar to Svalbard, the studied lobate features on Mars occur in close spatial proximity to gullies and thermal contraction polygons. The widespread distribution of the lobate forms in the northern hemisphere and their close association to ground-ice and gullies are best explained by mass-wasting processes related to frost creep, gelifluction and/or plug-like flow. This suggests a protracted process (thousand to several thousands of years) of freeze–thaw activity at the northern high latitudes on Mars. Age constraints on lobe deposits and superposition relationships with gullies and polygons imply a process involving liquid water within the last few million years.     

Water vapor near the cloud tops of Venus from Venus Express/VIRTIS dayside data

Observations of the dayside of Venus performed by the high spectral resolution channel (–H) of the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA Venus Express mission have been used to measure the altitude of the cloud tops and the water vapor abundance around this level with a spatial resolution ranging from 100 to 10 km. CO₂ and H₂O bands between 2.48 and 2.60 μm are analyzed to determine the cloud top altitude and water vapor abundance near this level. At low latitudes (±40°) mean water vapor abundance is equal to 3 ± 1 ppm and the corresponding cloud top altitude at 2.5 μm is equal to 69.5 ± 2 km. Poleward from middle latitudes the cloud top altitude gradually decreases down to 64 km, while the average H₂O abundance reaches its maximum of 5 ppm at 80° of latitude with a large scatter from 1 to 15 ppm. The calculated mass percentage of the sulfuric acid solution in cloud droplets of mode 2 (～1 μm) particles is in the range 75–83%, being in even more narrow interval of 80–83% in low latitudes. No systematic correlation of the dark UV markings with the cloud top altitude or water vapor has been observed.     

Spatial and temporal variations in Titan's surface temperatures from Cassini CIRS observations

We report a wide-ranging study of Titan's surface temperatures by analysis of the Moon's outgoing radiance through a spectral window in the thermal infrared at 19 μm (530 cm^?1) characterized by lower atmospheric opacity. We begin by modeling Cassini Composite Infrared Spectrometer (CIRS) far infrared spectra collected in the period 2004–2010, using a radiative transfer forward model combined with a non-linear optimal estimation inversion method. At low-latitudes, we agree with the HASI near-surface temperature of about 94 K at 10°S (Fulchignoni et al., 2005). We find a systematic decrease from the equator toward the poles, hemispherically asymmetric, of ～1 K at 60° south and ～3 K at 60° north, in general agreement with a previous analysis of CIRS data (Jennings et al., 2009), and with Voyager results from the previous northern winter. Subdividing the available database, corresponding to about one Titan season, into 3 consecutive periods, small seasonal changes of up to 2 K at 60°N became noticeable in the results. In addition, clear evidence of diurnal variations of the surface temperatures near the equator are observed for the first time: we find a trend of slowly increasing temperature from the morning to the early afternoon and a faster decrease during the night. The diurnal change is ～1.5 K, in agreement with model predictions for a surface with a thermal inertia between 300 and 600 J m^?2 s^?1/2 K^?1. These results provide important constraints on coupled surface–atmosphere models of Titan's meteorology and atmospheric dynamic.     

Atomic oxygen on the Venus nightside: Global distribution deduced from airglow mapping

The Visible and Infra-Red Thermal Imaging Spectrometer (VIRTIS) instrument on board the Venus Express spacecraft has measured the O₂(a¹Δ) nightglow distribution at 1.27 μm in the Venus mesosphere for more than two years. Nadir observations have been used to create a statistical map of the emission on Venus nightside. It appears that the statistical 1.6 MR maximum of the emission is located around the antisolar point. Limb observations provide information on the altitude and on the shape of the emission layer. We combine nadir observations essentially covering the southern hemisphere, corrected for the thermal emission of the lower atmosphere, with limb profiles of the northern hemisphere to generate a global map of the Venus nightside emission at 1.27 μm. Given all the O₂(a¹Δ) intensity profiles, O₂(a¹Δ) and O density profiles have been calculated and three-dimensional maps of metastable molecular and atomic oxygen densities have been generated. This global O density nightside distribution improves that available from the VTS3 model, which was based on measurements made above 145 km. The O₂(a¹Δ) hemispheric average density is 2.1 × 10⁹ cm^?3, with a maximum value of 6.5 × 10⁹ cm^?3 at 99.2 km. The O density profiles have been derived from the nightglow data using CO₂ profiles from the empirical VTS3 model or from SPICAV stellar occultations. The O hemispheric average density is 1.9 × 10¹¹ cm^?3 in both cases, with a mean altitude of the peak located at 106.1 km and 103.4 km, respectively. These results tend to confirm the modeled values of 2.8 × 10¹¹ cm^?3 at 104 km and 2.0 × 10¹¹ cm^?3 at 110 km obtained by Brecht et al. [Brecht, A., Bougher, S.W., Gérard, J.-C., Parkinson, C.D., Rafkin, S., Foster, B., 2011a. J. Geophys. Res., in press] and Krasnopolsky [Krasnopolsky, V.A., 2010. Icarus 207, 17–27], respectively. Comparing the oxygen density map derived from the O₂(a¹Δ) nightglow observations, it appears that the morphology is very different and that the densities obtained in this study are about three times higher than those predicted by the VTS3 model.     

Dynamical evolution of the Hungaria asteroids

The Hungarias are a stable asteroid group orbiting between Mars and the main asteroid belt, with high inclinations (16–30°), low eccentricities (e < 0.18), and a narrow range of semi-major axes (1.78–2.06 AU). In order to explore the significance of thermally-induced Yarkovsky drift on the population, we conducted three orbital simulations of a 1000-particle grid in Hungaria a–e–i space. The three simulations included asteroid radii of 0.2, 1.0, and 5.0 km, respectively, with run times of 200 Myr. The results show that mean motion resonances—martian ones in particular—play a significant role in the destabilization of asteroids in the region. We conclude that either the initial Hungaria population was enormous, or, more likely, Hungarias must be replenished through collisional or dynamical means. To test the latter possibility, we conducted three more simulations of the same radii, this time in nearby Mars-crossing space. We find that certain Mars crossers can be trapped in martian resonances, and by a combination of chaotic diffusion and the Yarkovsky effect, can be stabilized by them. Therefore, some Hungarias (around 5% of non-family members with absolute magnitudes H < 15.5 and 10% for H < 17) may represent previously transient Mars crossers that have been adopted in this manner.