Atomic oxygen on the Venus nightside: Global distribution deduced from airglow mapping

The Visible and Infra-Red Thermal Imaging Spectrometer (VIRTIS) instrument on board the Venus Express spacecraft has measured the O₂(a¹Δ) nightglow distribution at 1.27 μm in the Venus mesosphere for more than two years. Nadir observations have been used to create a statistical map of the emission on Venus nightside. It appears that the statistical 1.6 MR maximum of the emission is located around the antisolar point. Limb observations provide information on the altitude and on the shape of the emission layer. We combine nadir observations essentially covering the southern hemisphere, corrected for the thermal emission of the lower atmosphere, with limb profiles of the northern hemisphere to generate a global map of the Venus nightside emission at 1.27 μm. Given all the O₂(a¹Δ) intensity profiles, O₂(a¹Δ) and O density profiles have been calculated and three-dimensional maps of metastable molecular and atomic oxygen densities have been generated. This global O density nightside distribution improves that available from the VTS3 model, which was based on measurements made above 145 km. The O₂(a¹Δ) hemispheric average density is 2.1 × 10⁹ cm^?3, with a maximum value of 6.5 × 10⁹ cm^?3 at 99.2 km. The O density profiles have been derived from the nightglow data using CO₂ profiles from the empirical VTS3 model or from SPICAV stellar occultations. The O hemispheric average density is 1.9 × 10¹¹ cm^?3 in both cases, with a mean altitude of the peak located at 106.1 km and 103.4 km, respectively. These results tend to confirm the modeled values of 2.8 × 10¹¹ cm^?3 at 104 km and 2.0 × 10¹¹ cm^?3 at 110 km obtained by Brecht et al. [Brecht, A., Bougher, S.W., Gérard, J.-C., Parkinson, C.D., Rafkin, S., Foster, B., 2011a. J. Geophys. Res., in press] and Krasnopolsky [Krasnopolsky, V.A., 2010. Icarus 207, 17–27], respectively. Comparing the oxygen density map derived from the O₂(a¹Δ) nightglow observations, it appears that the morphology is very different and that the densities obtained in this study are about three times higher than those predicted by the VTS3 model.     

The role of sputtering and radiolysis in the generation of Europa exosphere

The exosphere of an atmosphereless icy moon is the result of different surface release processes and subsequent modification of the released particles. At Europa icy moon, water molecules are directly released, but photolysis and radiolysis due to solar UV and Jupiter’s magnetospheric plasma, respectively, can result in OH, H, O and (possibly) H₂ production. These molecules can recombine to reform water and/or new chemical species. As a consequence, Europa’s neutral environment becomes a mixture of different molecules, among which, H₂O dominates in the highest altitudes and O₂, formed mainly by radiolysis of ice and subsequent release of the produced molecules, prevails at lower altitudes. In this work, starting from a previously developed Monte Carlo model for the generation of Europa’s exosphere, where the only considered species was water, we make a first attempt to simulate also the H₂ and O₂ components of the neutral environment around Europa, already observed by the Hubble Space Telescope and the Ultraviolet Imaging Spectrograph on board Cassini, during its flyby of Jupiter. Considering a specific configuration where the leading hemisphere coincides with the sunlit hemisphere, we estimate along the Europa–Sun line an O₂ column density of about 1.5 × 10¹⁹ m^?2 at the dayside and 3 × 10¹⁸ m^?2 at the nightside. In this work we also improve our previous estimation of the sputtered H₂O exosphere of this moon, taking into consideration the trailing–leading asymmetry in the magnetospheric ion bombardment and the energy and temperature dependences of the process yields. We find that a density of 1.5 × 10¹² H₂O/m³ is expected at altitudes ～0.1R_E above the surface of the trailing hemisphere. Additionally, we calculate the escape of H₂O, O₂ and H₂. The total number of neutral atoms in Europa’s neutral torus, is estimated to be in the range 7.8 × 10³²–3.3 × 10³³.     

The formation heritage of Jupiter Family Comet 10P/Tempel 2 as revealed by infrared spectroscopy

We present spectral and spatial information for major volatile species in Comet 10P/Tempel 2, based on high-dispersion infrared spectra acquired on UT 2010 July 26 (heliocentric distance R_h = 1.44 AU) and September 18 (R_h = 1.62 AU), following the comet’s perihelion passage on UT 2010 July 04. The total production rate for water on July 26 was (1.90 ± 0.12) × 10²⁸ molecules s^?1, and abundances of six trace gases (relative to water) were: CH₃OH (1.58% ± 0.23%), C₂H₆ (0.39% ± 0.04%), NH₃ (0.83% ± 0.20%), and HCN (0.13% ± 0.02%). A detailed analysis of intensities for water emission lines provided a rotational temperature of 35 ± 3 K. The mean OPR is consistent with nuclear spin populations in statistical equilibrium (OPR = 3.01 ± 0.18), and the (1σ) lower bound corresponds to a spin temperature >38 K. Our measurements were contemporaneous with a jet-like feature observed at optical wavelengths. The spatial profiles of four primary volatiles display strong enhancements in the jet direction, which favors release from a localized vent on the nucleus. The measured IR continuum is much more sharply peaked and is consistent with a dominant contribution from the nucleus itself. The peak intensities for H₂O, CH₃OH, and C₂H₆ are offset by ～200 km in the jet direction, suggesting the possible existence of a distributed source, such as the release of icy grains that subsequently sublimed in the coma. On UT September 18, no obvious emission lines were present in our spectra, nevertheless we obtained a 3σ upper limit Q(H₂O) < 2.86 × 10²⁷ molecules s^?1.     

The O2 nightglow in the martian atmosphere by SPICAM onboard of Mars-Express

We present observations of the O₂(a¹Δ_g) nightglow at 1.27 μm on Mars using the SPICAM IR spectrometer onboard of the Mars Express orbiter. In contrast to the O₂(a¹Δ_g) dayglow that results from the ozone photodissociation, the O₂(a¹Δ_g) nightglow is a product of the recombination of O atoms formed by CO₂ photolysis on the dayside at altitudes higher than 80 km and transported downward above the winter pole by the Hadley circulation. The first detections of the O₂(a¹Δ_g) nightglow in 2010 indicate that it is about two order of magnitude less intense than the dayglow (Bertaux, J.-L., Gondet, B., Bibring, J.-P., Montmessin, F., Lefèvre, F. [2010]. Bull. Am. Astron. Soc. 42, 1040; Clancy et al. [2010]. Bull. Am. Astron. Soc. 42, 1041). SPICAM IR sounds the martian atmosphere in the near-IR range (1–1.7 μm) with the spectral resolution of 3.5 cm^?1 in nadir, limb and solar occultation modes. In 2010 the vertical profiles of the O₂(a¹Δ_g) nightside emission have been obtained near the South Pole at latitudes of 82–83°S for two sequences of observations: L_s = 111–120° and L_s = 152–165°. The altitude of the emission maximum varied from 45 km on L_s = 111–120° to 38–49 km on L_s = 152–165°. Averaged vertically integrated intensity of the emission at these latitudes has shown an increase from 0.22 to 0.35 MR. Those values of total vertical emission rate are consistent with the OMEGA observations on Mars-Express in 2010. The estimated density of oxygen atoms at altitudes from 50 to 65 km varies from 1.5 × 10¹¹ to 2.5 × 10¹¹ cm^?3. Comparison with the LMD general circulation model with photochemistry (Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F. [2004]. J. Geophys. Res. 109, E07004; Lefèvre et al. [2008]. Nature 454, 971–975) shows that the model reproduces fairly well the O₂(a¹Δ_g) emission layer observed by SPICAM when the large field of view (>20 km on the limb) of the instrument is taken into account.     

High resolution investigation of the 7 μm region of the ethane spectrum

Building upon previous studies, we re-investigated the ethane spectrum between 1330 and 1610 cm^?1 by combining unapodized spectra obtained at room temperature with a Bruker Fourier transform spectrometer (FTS) in Brussels and at 131 K with a Bruker FTS in Pasadena. The maximum optical path differences (MOPD) of the two datasets were 450 and 323.7 cm, corresponding to spectral resolutions of 0.0020 and 0.0028 cm^?1, respectively. Of the 15,000 lines observed, over 4592 transitions were assigned to the ν₆ (at 1379 cm^?1), ν₈ (at 1472 cm^?1), ν₄+ν₁₂ (at 1481 cm^?1) and 2ν₄+ν₉ (at 1388 cm^?1) bands, and another 1044 transitions were located for the ν₄+ν₈?ν₄ hot band (at 1472 cm^?1). Our new analysis included an improved implementation of the Hamiltonian calculation needed to interpret the complex spectral structures caused by numerous interactions affecting these four modes of vibration. From these results, we created the first line-by-line database containing the molecular parameters for over 20,000 ¹²C₂H₆ transitions at 7 μm.     

Absorption features in the quasar HS 1603 + 3820 II. Distance to the absorber obtained from photoionisation modelling

We present the photoionisation modelling of the intrinsic absorber in the bright quasar HS 1603 + 3820. We constructed the broad-band spectral energy distribution using the optical/UV/X-ray observations from different instruments as inputs for the photoionisation calculations. The spectra from the Keck telescope show extremely high Civ to Hi ratios, for the first absorber in system A, named A1. This value, together with high column density of Civ ion, place strong constraints on the photoionisation model. We used two photoionisation codes to derive the hydrogen number density at the cloud illuminated surface. By estimating bolometric luminosity of HS 1603 + 3820 using the typical formula for quasars, we calculated the distance to A1. We could find one photoionization solution, by assuming either a constant density cloud (which was modelled using cloudy), or a stratified cloud (which was modelled using titan), as well as the solar abundances. This model explained both the ionic column density of Civ and the high Civ to Hi ratio. The location of A1 is 0.1 pc, and it is situated even closer to the nucleus than the possible location of the Broad Line Region in this object. The upper limit of the distance is sensitive to the adopted covering factor and the carbon abundance. Photoionisation modelling always prefers dense clouds with the number density n₀ = 10¹⁰ − 10¹² cm⁻³, which explains intrinsic absorption in HS 1603 + 3820. This number density is of the same order as that in the disk atmosphere at the implied distance of A1. Therefore, our results show that the disk wind that escapes from the outermost accretion disk atmosphere can build up dense absorber in quasars.     

Mineral reaction buffering of Venus’ atmosphere: A thermochemical constraint and implications for Venus-like planets

The equilibrium suggested as a buffer for CO₂ in the Venus atmosphere, CaCO₃ + SiO₂ = CaSiO₃ + CO₂, cannot act as a buffer at the Venus surface/troposphere – the pressure–temperature slope of the equilibrium and that of the atmosphere (dry adiabat with significant greenhouse heating) do not provide buffering capacity (if indeed CaCO₃ were present). Instead, perturbations to T or P(CO₂) can produce catastrophic expansion or collapse of the atmosphere. This instability can be generalized to all devolatilization reactions that produce a radiatively active gas in a planetary atmosphere dominated by such gases, and gives a simple thermochemical criterion for whether a reaction could buffer such an atmosphere. Simple decarbonation reactions fail this criterion, suggesting that the abundance of CO₂ in a CO₂-dominated atmosphere cannot be buffered by chemical reactions with the surface; a similar conclusion holds for the abundance of H₂O in an H₂O-dominated (steam) atmosphere. Buffering of minor gases is more likely; a mineral buffer equilibrium for SO₂ proposed for Venus, FeS₂ + CO₂ = Fe₃O₄ + SO₂ + CO, passes the thermochemical criterion, as does a reaction involving Ca sulfate. These inferences can be generalized to atmospheres in ‘moist’ adiabatic equilibria, and to extrasolar Venus-like planets, and will help in interpreting the compositions of their atmospheres.     

Identification of C4H5, C4H4, C3H3 and CH3 radicals produced from the reaction of atomic carbon with propene: Implications for the atmospheres of Titan and giant planets and for the interstellar medium

We observed the products C₄H₅, C₄H₄, C₃H₃ and CH₃ of the C(³P) + C₃H₆ reaction using product time-of-flight spectroscopy and selective photoionization. The identified species arise from the product channels C₄H₅ + H, C₄H₄ + 2H and C₃H₃ + CH₃. Product isomers were identified via measurements of photoionization spectra and calculations of adiabatic ionization energy. Product C₄H₅ probably involves three isomers HCCCHCH₃, H₂CCCCH₃ and H₂CCCHCH₂. In contrast, products C₄H₄ and C₃H₃ involve exclusively HCCCHCH₂ and H₂CCCH, respectively. Reaction mechanisms are unraveled with crossed-beam experiments and quantum-chemical calculations. The ³P carbon atom attacks the π orbital of propene (C₃H₆) to form a cyclic complex c-H₂C(C)CHCH₃ that rapidly opens the ring to form H₂CCCHCH₃ followed by decomposition to HCCCHCH₃/H₂CCCCH₃/H₂CCCHCH₂ + H and H₂CCCH + CH₃; the corresponding branching ratios are 7:5:10:78 predicted with RRKM calculations at collision energy 4 kcal mol^?1. Nascent C₄H₅ with enough internal energy further decomposes to HCCCHCH₂ + H. Ratios of products C₄H₅, C₄H₄ and C₃H₃ are experimentally evaluated to be 17:8:75. This work provides a comprehensive look at product channels of the title reaction and gives implications for the formation of hydrocarbons in extra-terrestrial environments such as Titan and carbon-rich interstellar media. We suggest that the title reaction, hitherto excluded in any chemical networks, needs to be taken into account at least in the atmosphere of Titan and carbon-rich molecular clouds where rapid neutral–neutral reactions are dominant and carbon atoms and propene are abundant.     

A photochemical model for the Venus atmosphere at 47–112 km

The model is intended to respond to the recent findings in the Venus atmosphere from the Venus Express and ground-based submillimeter and infrared observations. It extends down to 47 km for comparison with the kinetic model for the lower atmosphere (Krasnopolsky, V.A. [2007]. Icarus 191, 25–37) and to use its results as the boundary conditions. The model numerical accuracy is significantly improved by reduction of the altitude step from 2 km in the previous models to 0.5 km. Effects of the NUV absorber are approximated using the detailed photometric observations at 365 nm from Venera 14. The H₂O profile is not fixed but calculated in the model. The model involves odd nitrogen and OCS chemistries based on the detected NO and OCS abundances. The number of the reactions is significantly reduced by removing of unimportant processes. Column rates for all reactions are given, and balances of production and loss may be analyzed in detail for each species.The calculated vertical profiles of CO, H₂O, HCl, SO₂, SO, OCS and of the O₂ dayglow at 1.27 μm generally agree with the existing observational data; some differences are briefly discussed. The OH dayglow is ～30 kR, brighter than the OH nightglow by a factor of 4. The H + O₃ process dominates in the nightglow excitation and O + HO₂ in the dayglow, because of the reduction of ozone by photolysis. A key feature of Venus’ photochemistry is the formation of sulfuric acid in a narrow layer near the cloud tops that greatly reduces abundances of SO₂ and H₂O above the clouds. Delivery of SO₂ and H₂O through this bottleneck determines the chemistry and its variations above the clouds. Small variations of eddy diffusion near 60 km result in variations of SO₂, SO, and OCS at and above 70 km within a factor of ～30. Variations of the SO₂/H₂O ratio at the lower boundary have similar but weaker effect: the variations within a factor of ～4 are induced by changes of SO₂/H₂O by ±5%. Therefore the observed variations of the mesospheric composition originate from minor variations of the atmospheric dynamics near the cloud layer and do not require volcanism. NO cycles are responsible for production of a quarter of O₂, SO₂, and Cl₂ in the atmosphere. A net effect of photochemistry in the middle atmosphere is the consumption of CO₂, SO₂, and HCl from and return of CO, H₂SO₄, and SO₂Cl₂ to the lower atmosphere. These processes may be balanced by thermochemistry in the lower atmosphere even without outgassing from the interior, though the latter is not ruled out by our models. Some differences between the model and observations and the previous models are briefly discussed.     

A photometric study of the detached binary WY Hydrae with twin components

We present a multicolor photometry for the eclipsing binary WY Hydrae, observed on four nights of 2008 December. From our new observations and Carr’s data, the photometric solutions were deduced by using the updated W–D program. The results show that WY Hya is a detached binary with a mass ratio of q = 0.970(±0.005).By analyzing the O–C curve, it is found that there exists either a continuous period increase or a cyclic variation. From Eq. (2), the orbital period of WY Hya secularly increases at a rate of dP/dt = +3.56(±0.37) × 10^?7 days/yr, which may be interpreted by some mass transfer for the near-contact configuration or tidal dissipation. From Eq. (3), the period and semi-amplitude of the periodic oscillation are P₃ = 95.4(±4.2) yr and A = 0^d.0087(±0^d.0003), respectively. This may be likely attributed by light-time effect via the presence of the assumed third body. Assumed in the coplanar orbit with the binary, the mass of the third body should be M₃ = 0.18 M_⊙. If the unseen additional companion exists, it will extract angular momentum from the binary system. Finally, WY Hya with high fill-out factors (i.e., f_1,2 > 80%), may evolve into a semi-detached configuration.     

Non-thermal water loss of the early Mars: 3D multi-ion hybrid simulations

In this study we analyze the non-thermal loss rates of O⁺, O₂⁺ and CO₂⁺ ions over the last 4.5 billion years (Gyr) in the Martian history by using a 3D hybrid model. For this reason we derived the past solar wind conditions in detail. We take into account the intensified particle flux of the early Sun as well as an Martian atmosphere, which was exposed to a sun's extreme ultraviolet (EUV) radiation flux 4.5 Gyr ago that was 100 times stronger than today. Furthermore, we model the evolution of the interplanetary magnetic field by a Weber & Davis solar wind model. The ‘external’ influences of the Sun's radiation flux and solar wind flux lead to the formation of an ionospheric obstacle by photoionization, charge exchange and electron impact. For the early Martian conditions we could show that charge exchange was the dominant ionization mechanism. Several hybrid simulations for different stages in the evolution of the Martian atmosphere, at 1, 2, 5, 10, 30 and 100 EUV, were performed to analyze the non-thermal escape processes by ion pick-up, momentum transfer from the solar wind to the ionosphere and detached ionospheric plasma clouds. Our results show a non-linear evolution of the loss rates. Using mean solar wind parameters the simulations result in an oxygen loss equivalent to the depth of a global Martian ocean of about 2.6 m over the last 4.5 Gyr. The induced magnetic field strength could be increased up to about 2000 nT. A simulation run with high solar wind density results in an oxygen loss of a Martian ocean up to 205 m depth during 150 million years after the sun reached the zero age mean sequence (ZAMS).     

New wind measurements in Venus’ lower mesosphere from visible spectroscopy

The dynamics of Venus’ mesosphere (70–110 km) is characterized by the superposition of two different wind regimes: (1) Venus’ retrograde superrotation; (2) a sub-solar to anti-solar (SS–AS) flow pattern, driven by solar EUV heating on the sunlit hemisphere. Here, we report on new ground-based velocity measurements in the lower part of the mesosphere. We took advantage of two essentially symmetric Venus elongations in 2001 and 2002 to perform high-resolution Doppler spectroscopy (R=120,000) in ¹²C¹⁶O₂ visible lines of the 5ν₃ band and in a few solar Fraunhofer lines near 8700 Å. These measurements, mapped over several points on Venus’ illuminated hemisphere, probe the region of cloud tops. More precisely, the solar Fraunhofer lines sample levels a few kilometers below the UV features (i.e. near ∼67 km), while the CO₂ lines probe an altitude higher by about 7 km. The wind field over Venus’ disk is retrieved with an rms uncertainty of 15–25 m s⁻¹ on individual measurements. Kinematical fit to a one- or two-component circulation model indicates the dominance of the zonal retrograde flow with a mean equatorial velocity of ∼75 m s⁻¹, exhibiting very strong day-to-day variations (±65 m s⁻¹). Results are very consistent for the two kinds of lines, suggesting a negligible vertical wind shear over 67–74 km. The SS–AS flow is not detected in single-day observations, but combining the results from all data suggests that this component may invade the lower mesosphere with a ∼40 m s⁻¹ velocity.     

Identification of Zirconium Oxide molecular lines in the sunspot umbral spectra

The ZrO molecule has been detected in sunspot umbrae through the identification of following laboratory molecular transitions: ¹Σ⁺ ? X¹Σ⁺ (0, 0), A³Φ₂ ? X²Δ₁ (0, 0), A³Φ₃ ? X²Δ₂ (0, 0), A³Φ₄ ? X²Δ₃ (0, 0), B³Π₂ ? X³Δ₃ (0, 0), B³Π₁ ? X³Δ₂ (0, 0) and B³Π₀ ? X³Δ₁ (0, 0) in red – infrared region using high resolution, visible range Fourier Transform Spectrum of sunspot umbra observed at the National Solar Observatory in Kitt Peak (NSO/KP). Much new identification has been made in the searched spectral wavenumber region from 16650 cm^?1 to 18007 cm^?1 of sunspot spectrum. Equivalent widths of well resolved lines, versus rotational quantum number J have been used to determine the effective rotational temperature for seven bands of the ZrO molecule. This result agrees well with the temperatures derived for other molecules’ presence in sunspot umbrae. It is evident that ZrO molecular lines are formed in higher layers of the atmosphere of relatively “cold” sunspots.     

Chandra X-ray observations of two unusual BAL quasars

We report sensitive Chandra X-ray non-detections of two unusual, luminous Iron Low-Ionization Broad Absorption Line Quasars (FeLoBALs). The observations do detect a non-BAL, wide-binary companion quasar to one of the FeLoBAL quasars. We combine X-ray-derived column density lower limits (assuming solar metallicity) with column densities measured from ultraviolet spectra and CLOUDY photoionization simulations to explore whether constant-density slabs at broad-line region densities can match the physical parameters of these two BAL outflows, and find that they cannot. In the “overlapping-trough” object SDSS J0300+0048, we measure the column density of the X-ray absorbing gas to be N_H ? 1.8 × 10²⁴ cm^?2. From the presence of Fe ii UV78 absorption but lack of Fe ii UV195/UV196 absorption, we infer the density in that part of the absorbing region to be n_e ? 10⁶ cm^?3. We do find that a slab of gas at that density might be able to explain this object’s absorption. In the Fe iii-dominant object SDSS J2215–0045, the X-ray absorbing column density of N_H ? 3.4 × 10²⁴ cm^?2 is consistent with the Fe iii-derived N_H ? 2 × 10²² cm^?2 provided the ionization parameter is log U > 1.0 for both the n_e = 10¹¹ cm^?3 and n_e = 10¹² cm^?3 scenarios considered (such densities are required to produce Fe iii absorption without Fe iiabsorption). However, the velocity width of the absorption rules out its being concentrated in a single slab at these densities. Instead, this object’s spectrum can be explained by a low density, high ionization and high temperature disk wind that encounters and ablates higher density, lower ionization Fe iii-emitting clumps.     

Mars mesospheric zonal wind around northern spring equinox from infrared heterodyne observations of CO2

We present direct observations of Mars zonal wind velocities around northern spring equinox (L_S = 336°, L_S = 355°, L_S = 42°) during martian year 27 and 29. Data was acquired by means of infrared heterodyne spectroscopy of CO₂ features at 959.3917 cm^?1 (10.4232 μm) and 957.8005 cm^?1 (10.4405 μm) using the Cologne Tuneable Heterodyne Infrared Spectrometer (THIS) at the McMath–Pierce telescope of the National Solar Observatory on Kitt Peak in Arizona and the NASA Infrared Telescope Facility on Mauna Kea, Hawaii between 2005 and 2008. Winds were measured on the dayside of Mars with an unprecedented spatial resolution allowing sampling of up to nine independent latitudes over the martian disk. Retrieved wind velocities depend strongly on latitude and season with values ranging from 180 m/s prograde to ?94 m/s retrograde. A comparison of the observational results to predicted values from the Mars Climate Database yield a reasonable agreement between modeling and observation.     

Remote sensing of a comet at millimeter and submillimeter wavelengths from an orbiting spacecraft

The ESA Rosetta Spacecraft, launched on March 2, 2004 with the ultimate destination being Comet 67P/Churyumov–Gerasimenko, carries a relatively small and lightweight millimeter–submillimeter spectrometer instrument, the first of its kind launched into deep space. The instrument, named Microwave Instrument for the Rosetta Orbiter (MIRO), consists of a 30-cm diameter, offset parabolic reflector telescope, which couples energy in the millimeter and submillimeter bands to two heterodyne receivers. Center-band operating frequencies are near 190 GHz (1.6 mm) and 562 GHz (0.5 mm). Broadband, total power continuum measurements can be made in both bands. A 4096-channel spectrometer with 44 kHz resolution is connected to the submillimeter receiver. The spectral resolution is sufficient to observe individual, thermally broadened spectral lines (T⩾10 K). The submillimeter radiometer/spectrometer is fixed tuned to measure four volatile species—CO, CH₃OH, NH₃ and three isotopes of water, H₂¹⁶O, H₂¹⁷O and H₂¹⁸O. The MIRO experiment will use these species as probes of the physical conditions within the nucleus and coma. The basic quantities measured by MIRO are surface temperature, gas production rates and relative abundances, and velocity and excitation temperature of each species, along with their spatial and temporal variability. This information will be used to infer coma structure and outgassing processes, including the nature of the nucleus/coma interface.     

Orbital period investigations of two short-period early-type overcontact binaries BH Cen and V701 Sco in two extremely young galactic clusters IC 2944 and NGC 6383

Both V701 Sco and BH Cen are two early-type short-period overcontact systems (P = 0.^d762 and P = 0.^d792, respectively). V701 Sco is a member of the young galactic cluster NGC 6383, while BH Cen is a component of a younger galactic cluster IC 2944 where star formation is in process. They provide good opportunity to understand the formation and evolution of binary stars. In the present paper, orbital period changes of the two binaries are investigated. It is discovered that the orbital period of BH Cen shows a long-term increase with a rate of dP/dt = +1.70(±0.39) × 10⁻⁷ days/year while it undergoes a cyclic oscillation with a period of 44.6 years and an amplitude of A₃ = 0.^d0216. For V701 Sco, its O-C curve reveals a periodic change with a period of 41.2 years and amplitude of A₃ = 0.^d0158. The mass ratio of BH Cen is 0.84, but V701 Sco contains twin B1-1.5V type stars with a mass ratio of unit. The continuous period increase of BH Cen is caused by the mass transfer from the less massive component to the more massive one at a rate of dM₂/dt = 3.5 × 10⁻⁶ days/year.The cyclic period changes of both systems can be plausibly explained as the results of light-travel time effects suggesting that they are triple systems. The astrophysical parameters of the unseen tertiary components in the two systems have been determined. We think that the invisible tertiary components in both binaries played an important role in the formations and evolutions of the overcontact configurations by bringing angular momentum out from the central systems. For BH Cen, this process created the initial short period and will support its evolution into an overcontact configuration via a Case A mass transfer within the life time of the extremely young cluster IC 2944. For V701 Sco, two identical zero-age main-sequence components in an overcontact configuration suggest that it may have been formed by fission, possibly by the fission of the third body. The fact that no long-term continuous period variations were found for V701 Sco may suggest that an overcontact binary with the mass ratio of unity can be in an equilibrium revealing that the original configuration of the binary was overcontact as is its present state. It has been reported that faint stars in the two extremely young clusters are relatively scare. From the present study, it is shown that faint stars in young clusters are usually formed as companions of OB stars (including binaries). It is very difficult to detect them because of their low luminosity when compared with the more luminous OB stars.     

Observation of DCl and upper limit to NH3 on Venus

To search for DCl in the Venus atmosphere, a spectrum near the D³⁵Cl (1–0) R4 line at 2141.54 cm^?1 was observed using the CSHELL spectrograph at NASA IRTF. Least square fitting to the spectrum by a synthetic spectrum results in a DCl mixing ratio of 17.8 ± 6.8 ppb. Comparing to the HCl abundance of 400 ± 30 ppb (Krasnopolsky [2010a] Icarus, 208, 314–322), the DCl/HCl ratio is equal to 280 ± 110 times the terrestrial D/H = 1.56 × 10^?4. This ratio is similar to that of HDO/H₂O = 240 ± 25 times the terrestrial HDO/H₂O from the VEX/SOIR occultations at 70–110 km. Photochemistry in the Venus mesosphere converts H from HCl to that in H₂O with a rate of 1.9 × 10⁹ cm^?2 s^?1 (Krasnopolsky [2012] Icarus, 218, 230–246). The conversion involves photolysis of HCl; therefore, the photochemistry tends to enrich D/H in HCl and deplete in H₂O. Formation of the sulfuric acid clouds may affect HDO/H₂O as well. The enriched HCl moves down by mixing to the lower atmosphere where thermodynamic equilibriums for H₂ and HCl near the surface correspond to D/H = 0.71 and 0.74 times that in H₂O, respectively. Time to establish these equilibriums is estimated at ～3 years and comparable to the mixing time in the lower atmosphere. Therefore, the enriched HCl from the mesosphere gives D back to H₂O near the surface. Comparison of chemical and mixing times favors a constant HDO/H₂O up to ～100 km and DCl/HCl equal to D/H in H₂O times 0.74.Ammonia is an abundant form of nitrogen in the reducing environments. Thermodynamic equilibriums with N₂ and NO near the surface of Venus give its mixing ratio of 10^?14 and 6 × 10^?7, respectively. A spectrum of Venus near the NH₃ line at 4481.11 cm^?1 was observed at NASA IRTF and resulted in a two-sigma upper limit of 6 ppb for NH₃ above the Venus clouds. This is an improvement of the previous upper limit by a factor of 5. If ammonia exists at the ppb level or less in the lower atmosphere, it quickly dissociates in the mesosphere and weakly affects its photochemistry.     

The XMM-Newton view of the yellow hypergiant IRC + 10420 and its surroundings

Among evolved massive stars likely in transition to the Wolf–Rayet phase, IRC + 10420 is probably one of the most enigmatic. It belongs to the category of yellow hypergiants and it is characterized by quite high mass loss episodes. Even though IRC + 10420 benefited of many observations in several wavelength domains, it has never been a target for an X-ray observatory. We report here on the very first dedicated observation of IRC + 10420 in X-rays, using the XMM-Newton satellite. Even though the target is not detected, we derive X-ray flux upper limits of the order of 1–3 × 10⁻¹⁴ erg cm⁻² s⁻¹ (between 0.3 and 10.0 keV), and we discuss the case of IRC + 10420 in the framework of emission models likely to be adequate for such an object. Using the Optical/UV Monitor on board XMM-Newton, we present the very first upper limits of the flux density of IRC + 10420 in the UV domain (between 1800 and 2250 Å and between 2050 and 2450 Å). Finally, we also report on the detection in this field of 10 X-ray and 7 UV point sources, and we briefly discuss their properties and potential counterparts at longer wavelengths.     

The planetary fourier spectrometer (PFS) onboard the European Venus Express mission

The planetary fourier spectrometer (PFS) for the Venus Express mission is an infrared spectrometer optimized for atmospheric studies. This instrument has a short wavelength (SW) channel that covers the spectral range from 1700 to 11400 cm⁻¹ (0.9–5.5 μm) and a long wavelength (LW) channel that covers 250–1700 cm⁻¹ (5.5–45 μm). Both channels have a uniform spectral resolution of 1.3 cm⁻¹. The instrument field of view FOV is about 1.6 ° (FWHM) for the short wavelength channel and 2.8 ° for the LW channel which corresponds to a spatial resolution of 7 and 12 km when Venus is observed from an altitude of 250 km. PFS can provide unique data necessary to improve our knowledge not only of the atmospheric properties but also surface properties (temperature) and the surface-atmosphere interaction (volcanic activity).PFS works primarily around the pericentre of the orbit, only occasionally observing Venus from larger distances. Each measurements takes 4.5 s, with a repetition time of 11.5 s. By working roughly 1.5 h around pericentre, a total of 460 measurements per orbit will be acquired plus 60 for calibrations. PFS is able to take measurements at all local times, enabling the retrieval of atmospheric vertical temperature profiles on both the day and the night side.The PFS measures a host of atmospheric and surface phenomena on Venus. These include the:(1) thermal surface flux at several wavelengths near 1 μm, with concurrent constraints on surface temperature and emissivity (indicative of composition); (2) the abundances of several highly-diagnostic trace molecular species; (3) atmospheric temperatures from 55 to 100 km altitude; (4) cloud opacities and cloud-tracked winds in the lower-level cloud layers near 50-km altitudes; (5) cloud top pressures of the uppermost haze/cloud region near 70–80 km altitude; and (6) oxygen airglow near the 100 km level. All of these will be observed repeatedly during the 500-day nominal mission of Venus Express to yield an increased understanding of meteorological, dynamical, photochemical, and thermo-chemical processes in the Venus atmosphere. Additionally, PFS will search for and characterize current volcanic activity through spatial and temporal anomalies in both the surface thermal flux and the abundances of volcanic trace species in the lower atmosphere.Measurement of the 15 μm CO₂ band is very important. Its profile gives, by means of a complex temperature profile retrieval technique, the vertical pressure-temperature relation, basis of the global atmospheric study.PFS is made of four modules called O, E, P and S being, respectively, the interferometer and proximity electronics, the digital control unit, the power supply and the pointing device.