Cosmic ray ionization of lower Venus atmosphere

Cosmic ray particles passing through dense lower atmosphere of Venus decay giving rise to various charged and neutral particles. The flux and degradation of dominant cascade particles namely neutrinos and pions are computed and ionization contributions at lower altitudes are estimated. Using the height profile of pion flux, the muon flux is computed and used to estimate ionization at lower altitudes. It is shown that cosmic ray produced ionization descends to much lower altitudes intercepting the thickness of Venus cloud deck. The dynamical features of Venus cloud deck are used to allow the likely charging and charge separation processes resulting into cloud-to-cloud lightning discharges.     

Chemical kinetic model for the lower atmosphere of Venus

A self-consistent chemical kinetic model of the Venus atmosphere at 0-47 km has been calculated for the first time. The model involves 82 reactions of 26 species. Chemical processes in the atmosphere below the clouds are initiated by photochemical products from the middle atmosphere (H₂SO₄, CO, S_x), thermochemistry in the lowest 10 km, and photolysis of S₃. The sulfur bonds in OCS and S_x are weaker than the bonds of other elements in the basic atmospheric species on Venus; therefore the chemistry is mostly sulfur-driven. Sulfur chemistry activates some H and Cl atoms and radicals, though their effect on the chemical composition is weak. The lack of kinetic data for many reactions presents a problem that has been solved using some similar reactions and thermodynamic calculations of inverse processes. Column rates of some reactions in the lower atmosphere exceed the highest rates in the middle atmosphere by two orders of magnitude. However, many reactions are balanced by the inverse processes, and their net rates are comparable to those in the middle atmosphere. The calculated profile of CO is in excellent agreement with the Pioneer Venus and Venera 12 gas chromatographic measurements and slightly above the values from the nightside spectroscopy at 2.3 μm. The OCS profile also agrees with the nightside spectroscopy which is the only source of data for this species. The abundance and vertical profile of gaseous H₂SO₄ are similar to those observed by the Mariner 10 and Magellan radio occultations and ground-based microwave telescopes. While the calculated mean S₃ abundance agrees with the Venera 11-14 observations, a steep decrease in S₃ from the surface to 20 km is not expected from the observations. The ClSO₂ and SO₂Cl₂ mixing ratios are ∼10⁻¹¹ in the lowest scale height. The existing concept of the atmospheric sulfur cycles is incompatible with the observations of the OCS profile. A scheme suggested in the current work involves the basic photochemical cycle, that transforms CO₂ and SO₂ into SO₃, CO, and S_x, and a minor photochemical cycle which forms CO and S_x from OCS. The net effect of thermochemistry in the lowest 10 km is formation of OCS from CO and S_x. Chemistry at 30-40 km removes the downward flux of SO₃ and the upward flux of OCS and increases the downward fluxes of CO and S_x. The geological cycle of sulfur remains unchanged.     

The global distribution of water vapor in the middle atmosphere of Venus

The mean, solar-fixed horizontal and vertical distribution of water vapor in and above the Venusian cloud layer is presented. This is derived from far-infrared measurements made by the Orbiter Infrared Radiometer (OIR) instrument of the Pioneer Venus mission in the rotation band of water vapor at 45 μm, and from the mean solar-fixed temperature field and cloud structure retrieved from temperature soundings by the same instrument in five spectral channels. The water vapor retrieval scheme is discussed together with the calculation of water vapor transmission functions and their experimental verification. The sensitivity of the results to measurement errors and cloud microphysical properties is also considered. Mean water vapor column abundances above cloud unit optical depth at 11.5 μm are found to be greatest at equatorial latitudes in the early afternoon, reaching 50 ± 20 precipitable microns (100 ppm), and fall to less than 3 ± 2 precipitable microns (6 ppm) on the nightside of the planet. On the nightside mixing ratios fall monotonically with altitude, whereas dayside mixing ratios frequently increase with altitude near cloud unit optical depth. These results are broadly consistent with those of earlier Earth-based measurements.     

Variability of carbon monoxide in the mars atmosphere

In January of 1982 we measured a microwave spectrum of CO in the Martian atmosphere utilizing the rotational J = 1 → 2 transition of CO. We have analyzed data and reanalyzed the microwave spectra of R. K. Kakar, J. W. Waters, and W. J. Wilson, (Science196, 1090–1091, 1977, measured in 1975) and J. C. Good and F. P. Schloerb, (Icarus47, 166–172, 1981 measured in 1980) in order to constrain estimates of the temporal variability of CO abundance in the Martian atmosphere. Our values of CO column density from the data of Karar et al., Good and Schloerb, and our own are 1.7 ± 0.9 × 10²⁰, 3.0 ± 1.0 × 10²⁰, and 4.6 ± 2.0 × 10²⁰cm^?2, respectively. The most recent estimate of CO column density from the 1967 infrared spectra of J. Connes, P. Connes, and J.P. Maillard, (Atlas de Spectres Infarouges de Venus, Mars, Jupiter, et Saturne, Editions due Centre National de la Recherche Scientifique, Paris, 1969), is 2.0 ± 0.8 × 10²⁰ cm^?2 (L.D.G. Young and A.T. Young, Icarus30, 75–79, 1977). The large uncertainties given for the microwave measurements are due primarily to uncertainty in the difference between the continuum brightness temperature and atmospheric temperatures of Mars. We have accurately calculated the variation among the observations of the continuum (surface) brightness temperature of Mars, which is primaroly a function of the observed aspect of Mars. A more difficult problem to consider is variability of global atmospheric temperatures among the observations, particularly the effects of global dust storms and the ellipticity of the orbit of Mars. The large bars accompanying our estimates of CO column density from the three sets of microwave measurements are primarily caused by an assumed uncertainty of ±10°K in our atmospheric temperature model due to possible dust in the atmosphere. A qualitative consideration of seasonal variability of global atmospheric temperatures among the measurements suggests that there is not strong evidence for variability of the column abundance of CO on Mars, although variability of 0–100% over a time scale of several years is allowed by the data set. The implication for the variability of Mars O₂ is, crudely, a factor of two less. We found that the altitude distribution of CO in the atmosphere of Mars was not well constrained by any of the spectra, although our spectrum was marginally better fitted by an altitude increasing profile of CO mixing ratios.     

The lower atmosphere of Venus after Vega 1 and 2 missions

We have computed the physical parameters for the Venus atmosphere between 0–64 km altitude by using Vega measurements. The proposed model can be used in order to study the structure of Venus atmosphere and its chemical comoposition between 60–64 km, where an inversion in temperature profiles has been measured by Vega.     

Venus I. Carbon monoxide distribution and molecular-line searches

An observational program to study variations of the vertical distribution of CO in the Venus atmosphere is presented. Measurements of the J = 0 → 1 absorption line at 2.6 mm wavelength are reported for two phase angles in 1977, one near eastern elongation (Feb.) and the other near inferior conjunction (Apr.). The two spectra are significantly different, with the April absorption line being narrower and deeper. The results of numerical inversion calculations show that the CO mixing ratio increases a factor of ～ 100 between 78 and 100 km and that the CO abundance above ～ 100 km is greatest on the night-side hemisphere. These conclusions are in qualitative agreement with theoretical models. In addition to the CO observations, a search for other molecules was made to provide further information on the composition of the Venus middle atmosphere. The J = 0 → 1 transition of ¹³CO was detected and upper limits were derived for nine other molecules.     

Interference of spectral lines in thermal radiation from the lower atmosphere of Venus

The absorption spectrum and thermal radiation fluxes in the lower atmosphere of Venus are calculated using the theory of molecular state interference in the strong collision approximation. Comparison is made with the absorption and radiative transfer calculations in terms of the statistical theory of collisional line broadening and based on an empirical form factor. The calculations show that the line broadening mechanism does not affect the thermal regime of the atmosphere at heights above 60 km, but affects significantly the behavior of the greenhouse effect below the cloud layer.     

Temperature structure in the lower atmosphere of Venus: New results derived from pioneer Venus entry probe measurements

The interpretation of unexpected characteristics of Pioneer Venus temperature measurements, and of the large difference between these and the Venera results, is aided by new Venus temperature profiles derived from engineering measurements of the Pioneer Venus Small-Probe Net Flux Radiometer (SNFR) instruments. To facilitate correction of a temperature-dependent radiometric response, these instruments monitored the temperatures of their deployed radiation detectors. The accurate calibration of the temperature sensors, and their strong thermal coupling to the atmosphere, make it possible to deduce atmospheric temperatures within 2°K (at most altitudes) using a simple two-component thermal model to account for lag effects. These independent temperature profiles generally confirm to high accuracy, the small-probe results of A. Seiff, D. B. Kirk, R. E. Young, R. C. Blanchard, J. T. Findlay, G. M. Kelly, and S. C. Sommer (1980a, J. Geophys. Res.85, pp. 7903–7933) concerning vertical structure and horizontal contrast in the lower atmosphere, although the stable layer below 25 km is found to be slightly more stable (by about 0.4°K/km) and absolute temperatures are an average of 2°K higher. The measured Day-Night thermal contrast is compatible with predicted responses to the diurnal variation in solar heating, except near the cloud base, where 3–5°K differences may be due to thermal radiative heating differences associated with different cloud opacities. Temperature contrasts between latitudes 30 and 60° are roughly consistent with cyclostrophic balance. But pressure and temperature measurements by the Pioneer Venus Sounder probe at 4° latitude, when compared to Small-probe results, imply unreasonably large equatorward accelerations of 100 (m/sec)/day. Poleward accelerations compatible with cyclostrophic balance can be obtained if Sounder-probe temperatures are increased by a scale-factor correction reaching 6–7°K at 13 km.     

Structure of the Venus atmosphere

The structure of the Venus atmosphere is discussed. The data obtained in the 1980s by the last Soviet missions to Venus: orbiters Venera 15, 16 and the entry probes and balloons of Vega 1 and 2 are compared with the Venus International Reference Atmosphere (VIRA) model. VIRA is based on the data of the extensive space investigations of Venus in the 1960s and 1970s. The results of the IR Fourier Spectrometry experiment on Venera 15 are reviewed in detail. This instrument is considered as a precursor of the long wavelength channel of the Planetary Fourier Spectrometer on Venus Express.     

The aeronomy of the upper atmosphere of Venus

Density profiles for CO, O, and O₂ in the Cytherean atmosphere above 90 km are plotted with eddy diffusion coefficient (K) as a parameter, subject to the constraint that the mixing ratios of CO and O₂ approach their observed value or values under the observed upper limit at the lower boundary. It is then shown that the value of K puts upper limits on the amount of hydrogen (in the form of H₂O, HCl, and H₂) the atmosphere near 90km can contain. This value is a function of the density and temperature of hydrogen at the critical level and the magnitude of the total escape flux, where unspecified flux mechanisms other than thermal are postulated ad hoc. In general these constraints call for large values of K to accomodate the atomic hydrogen produced by measured mixing ratios of HCl and H₂O. Hence they constrain thee amount of O in the upper atmosphere to values well under 1% at 130 km unless there are very large hydrogen escape fluxes, 10⁷ cm^?2sec^?1 or larger. The freedom to assume arbitrary amounts of H₂ in the atmosphere is also restricted. We suggest either very effective escape mechanisms—despite low exospheric hydrogen densities—or novel excitation mechanisms for O(3³S) and O(3⁵S) in the upper atmosphere.     

Thermal periodicities in the Venus atmosphere

A search was made for periodic fluctuations in the thermal brightness temperatures recorded by the Pioneer Venus orbiter's infrared radiometer. Data were averaged in 10 × 10° latitude-longitude bins for each of the 72 days the instrument was in operation. This time series of thermal brightness temperatures was then analyzed to determine the amplitude of fluctuations at periods from 2 to 64 days at four levels in the atmosphere (at the cloud tops and at approximately 70, 80, and 90 km). The amplitude of such fluctuations is small at equatorial latitudes and increases to a maximum at 60–70° latitude at most altitudes. The period of the highest amplitude fluctuation is 5.3±0.4 days (at all altitudes) except at 70–80°, where a 2.9-day period which appears to correspond to the polar dipole dominates the cloud-top channel. The amplitude of the periodic fluctuations is a maximum at the cloud tops, decreasing to a minimum at the 80-km channel, and increasing again at the 90-km channel.     

The lower ionosphere of Venus

Galactic cosmic ray bombardment provides a permanent background ionosphere in planetary atmospheres. A transport technique is used to compute the cosmic ray ionization rate profile in a model of the Venusian atmosphere at altitudes between 55 and 100 km. These ionization rates are then applied to a model of ion chemistry to predict equilibrium electron and ion density profiles. Ionization rates for typical solar flare proton events are available from earlier calculations and have been included.     

Small-scale turbulence in the atmosphere of Venus

Previous studies based on radio scintillation measurements of the atmosphere of Venus have identified two regions of small-scale temperature fluctuations located in the vicinity of 45 and 60 km. A global study of the fluctuations near 60 km, which are consistent with wind-shear-generated turbulence, was conducted using the Pioneer Venus measurements. The structure constants of refractive index fluctuations c_n² and temperature fluctuations c_T² increase poleward, peak near 70° latitude, and decrease over the pole; c_n² varies from 2 × 10^?15 to 1.5 × 10^?14m^{$\text{2}\text{3}$} and c_T² from 4 × 10^?3 to 7 × 10^?2°K²m^{$\text{?2}\text{3}$}. These results indicate greater turbulent activity at the higher latitudes. In the region near 45 km the refractive index fluctuations and the corresponding temperature fluctuations are substantially lower. Based on the analysis of one representative occultation measurement, $\text{c}{}_{\mathrm{<mtext>n</mtext>}}{}^2\text{= 2 × 10}{}^{\mathrm{?16}}\text{m}{}^{\mathrm{<mtext>?2</mtext><mtext>3</mtext>}}\text{and}\text{c}{}_{\mathrm{<mtext>T</mtext>}}{}^2\text{= 7.3 × 10}{}^{\mathrm{?4}}\text{°}\text{K}{}^2\text{m}{}^{\mathrm{<mtext>?2</mtext><mtext>3</mtext>}}$ in the 45-km region. The fluctuations in this region also appear to be consistent with wind-shear-generated turbulence. The turbulence level is considerably weaker than that at 60 km; the energy dissipation rate ε is 4.9 × 10^?5m²sec^?3 and the small-scale eddy diffusion coefficient K is 2 × 10³ cm² sec^?1.     

4-Day waves in the Venus atmosphere

Ultraviolet albedo contrasts in the Venus atmosphere are probably large-scale atmospheric waves propagating slowly with respect to the rapid cloud-top zonal winds. Using a simple theoretical model and profiles of mean wind and thermal structure based on Pioneer Venus data, we find planetary-scale gravity waves with phase velocities matching the speeds of the uv markings. We propose an upward-propagating wave and waves trapped at cloud levels as candidates to explain the observed uv features.     

Latitudinal variations of CO and OCS in the lower atmosphere of Venus from near-infrared nightside spectro-imaging

Spectro-imaging of Venus' nightside in the 2.3-μm window provides a powerful means of probing the lower atmosphere in the 25-40 km altitude range. We present observations recorded at the NASA/IRTF in February 2003 and August 2004, using the SpeX spectro-imager in the 2.1-2.5-μm region. Abundances of CO and OCS have been derived as a function of latitude for different longitudes. The CO abundance increases by about 15% between the equatorial region and higher latitudes (±40°). No longitudinal or temporal variations are observed. The OCS abundance shows the opposite variation in observational sets with sufficient S/N. These variations and anticorrelation are consistent with upwelling motions in the equatorial region and downwelling at higher latitudes.     

Net thermal radiation in the atmosphere of Venus

The four entry probes of the Pioneer Venus mission measured the radiative net flux in the atmosphere of Venus at latitudes of 60°N, 31°S, 27°S, and 4°N. The three higher latitude probes carried instruments (small probe net flux radiometers; SNFR) with external sensors. The measured SNFR net fluxes are too large below the clouds, but an error source and correction scheme have been found (H. E. Revercomb, L. A. Sromovsky, and V. E. Suomi, 1982, Icarus52, 279–300). The near-equatorial probe carried an infrared radiometer (LIR) which viewed the atmosphere through a window in the probe. The LIR measurements are reasonable in the clouds, but increase to physically unreasonable levels shortly below the clouds. The probable error source and a correction procedure are identified. Three main conclusions can be drawn from comparisons of the four corrected flux profiles with radiative transfer calculations: (1) thermal net fluxes for the sounder probe do not require a reduction in the Mode 3 number density as has been suggested by O. B. Toon, B. Ragent, D. Colburn, J. Blamont, and C. Cot (1984, Icarus57, 143–160), but the probe measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and water vapor mixing ratios of about 2–5 × 10^?5 near 60°, 2–5 × 10^?4 near 30°, and 5 × 10^?4 near the equator. The suggested latitudinal variation of IR cooling is consistent with descending motions at high latitudes, and it is speculated that it could provide an important additional drive for the general circulation.     

Sulfur chemistry in the middle atmosphere of Venus

Venus Express measurements of the vertical profiles of SO and SO₂ in the middle atmosphere of Venus provide an opportunity to revisit the sulfur chemistry above the middle cloud tops (～58 km). A one dimensional photochemistry-diffusion model is used to simulate the behavior of the whole chemical system including oxygen-, hydrogen-, chlorine-, sulfur-, and nitrogen-bearing species. A sulfur source is required to explain the SO₂ inversion layer above 80 km. The evaporation of the aerosols composed of sulfuric acid (model A) or polysulfur (model B) above 90 km could provide the sulfur source. Measurements of SO₃ and SO (a¹Δ → X³Σ^-) emission at 1.7 μm may be the key to distinguish between the two models.     

Physical parameters of the atmosphere of Venus

The following parameters have been computed for the Cytherean atmosphere: pressure, density, speed of sound, collisional frequency, column mass, density scale, mean-free-path, viscosity, pressure scale, mean particle velocity, number density at an altitude from 0 to 170 km.The chemical composition, the temperature distribution function of the altitude, the surface pressure and the surface temperature measured by Pioneer Venus have been used as input data for these computations.     

Infrared limb darkening of the Venus atmosphere

An analysis of the limb darkening component obtained by Ingersoll and Orton [Icarus21 (1974), 121–128] from the thermal infrared maps of Venus published by Murray, Wildey, and Westphal [J. Geophys. Res.68 (1963), 4813–4818] and Westphal, Wildey, and Murray [Astrophys. J.142 (1965), 799–802] shows that the Cytherean cloud tops were close to radiative equilibrium in 1962. A method for obtaining the optical depth, the extinction coefficient, and the extinction scale height from such data is derived and values are extracted from Marov's [Icarus16 (1972), 415–461] standard model of the Venus atmosphere.