Investigation of submarine groundwater discharge to tidal rivers: Evidence for regional and local scale seepage

Fluxes of submarine groundwater discharge (SGD) were investigated into two tidal rivers on the north and south shore of Long Island, NY, during July 2015. Ground‐based handheld thermal infrared (TIR) imagery, combined with direct push‐point piezometer sampling, documented spatially heterogeneous small‐scale intertidal seepage zones. Pore waters were relatively fresh and enriched in nitrogen (N) within these small‐scale seeps. Pore waters sampled just 20 cm away, outside the boundary of the ground‐based TIR‐located seepage zone, were more saline and lower in N. These ground‐based TIR‐identified seeps geochemically represented the terrestrial fresh groundwater endmember, whereas N in pore waters sampled outside of the TIR‐identified seeps was derived from the remineralization of organic matter introduced into the sediment by tidal seawater infiltration. A ²²²Rn (radon‐222) time‐series was used to quantify fresh SGD‐associated N fluxes using the N endmembers sampled from the ground‐based TIR pore water profiles. N fluxes were up‐scaled to groundwater seepage zones identified from high‐resolution airborne TIR imagery using the two‐dimensional size of the airborne TIR surface water anomalies, relative to the N flux from the time‐series sampling location. Results suggest that the N load from the north‐shore tidal river to Long Island Sound is underrepresented by at least 1.6–3.6%, whereas the N load from SGD to a south‐shore tidal river may be up to 9% higher than previous estimates. These results demonstrate the importance of SGD in supplying nutrients to the lower reaches of tidal rivers and suggest that N loads in other tidal river environments may be underestimated if SGD is not accounted for.     

Nutrient budget of a montane evergreen broad‐leaved forest at Ailao Mountain National Nature Reserve,Yunnan, southwest China

Hydrological fluxes and associated nutrient budget were studied during a 2 year period (1998–99) in a montane moist evergreen broad‐leaved forest at Ailao Mountain, Yunnan. Water samples of rainfall, throughfall, and stemflow, and of surface runoff, soil water, and stream flow were collected bimonthly to determine the concentration and fluxes of nutrients. Soil budgets were determined from the difference between precipitation input (including nutrient leaching from canopy) and output via runoff and drainage. The forest was characterized by low canopy interception and surface runoff, and high percolation and stream flow. Concentrations of nutrients were increased in throughfall and stemflow compared with precipitation. Surface runoff and drainage water had higher nutrient concentrations than precipitation and stream water. Total nitrogen and NH₄⁺‐N concentrations were higher in soil water than stream water, whereas K⁺, Ca²⁺, and Mg²⁺ concentrations were lower in the former than the latter. Annual nutrient fluxes decreased with soil depth following the pattern of water flux. Annual losses of most nutrient elements via stream flow were less than the corresponding inputs via throughfall and stemflow, except for calcium, for which solute loss was greater than the inputs via precipitation. Leaching losses of that element may be compensated by weathering. Losses of nitrogen, phosphorus, potassium, magnesium, sodium, and sulphur could be replaced through atmospheric inputs. Copyright © 2002 John Wiley & Sons, Ltd.     

‘Thermohaline front’ off the east coast of India and its generating mechanism

Physical oceanography measurements reveal a strong salinity (0.18 psu km^?1) and temperature (0.07 °C km^?1) front off the east coast of India in December 1997. T–S diagrams suggest lateral mixing between the fresh water at the coast and the ambient warmer, saltier water. This front seems to be the result of southward advection of fresh and cool water, formed in the northern Bay of Bengal during the monsoon, by the East Indian Coastal Current, as suggested by the large-scale salinity structure in the SODA re-analysis and the anti-cyclonic gyre in the northwestern Bay of Bengal during winter. The data further reveals an offshore front in January, which appears to be the result of a meso-scale re-circulation around an eddy, bringing cold and freshwater from the northern Bay of Bengal further away from the shore. Our cruise data hence illustrates that very strong salinity fronts can appear in the Bay of Bengal after the monsoon, as a result of intense coastal circulation and stirring by eddies.     

Intertidal spring dynamics and coastal nutrient loading revealed through geophysics,drone surveys,and in-situ monitoring

Coastal eutrophication poses an increasing risk to ecosystem health due to enhanced nutrient loading to the global coastline. Submarine groundwater discharge (SGD) represents a significant pathway for nitrate-nitrogen (NO₃-N) transport to the coast, but diffusive SGD transport is difficult to monitor directly, given the low flux rates and expansive discharge areas. In contrast, focused SGD from intertidal springs can potentially be sampled and directly gauged, providing unique insight into SGD and associated contaminant transport. Basin Head is a coastal lagoon in Prince Edward Island, Canada that is a federally protected ecosystem. Nitrate-nitrogen is conveyed from agricultural fields in the contributing watershed to the eutrophic lagoon via intertidal groundwater springs and groundwater-dominated tributaries. We used several field methods to characterize groundwater discharge, nutrient loading, and in-channel mixing associated with intertidal springs. The tributaries and intertidal springs were gauged and sampled to estimate a representative summer nitrate load to the lagoon. Our analysis revealed that NO₃-N export to the lagoon through tributaries and springs throughout summer 2023 was on average 401 kg N/month, with the combined spring loading comparable in magnitude to the combined tributary loading. We collected thermal infrared and visual imagery using drone surveys and found spatial overlap between cold-water plumes from the spring discharge and macroalgae blooms, indicating the local thermal and ecosystem impacts of the focused SGD. We also mapped the electrical resistivity (salinity) distribution in the water column around one large spring with electromagnetic geophysics at different tidal stages to reveal the three-dimensional spring plume dynamics. Results showed that the fresher spring water floated above the saline lagoon water with the brackish plume oriented in the direction of the tidal current. Collectively, our multi-pronged field investigations help elucidate the hydrologic, thermal, and nutrient dynamics of intertidal springs and the cascading ecosystem impacts.     

Response of deep groundwater to land use change in desert basins of the Trans‐Pecos region,Texas, USA: Effects on infiltration,recharge, and nitrogen fluxes

Quantifying the effects of anthropogenic processes on groundwater in arid regions can be complicated by thick unsaturated zones with long transit times. Human activities can alter water and nutrient fluxes, but their impact on groundwater is not always clear. This study of basins in the Trans‐Pecos region of Texas links anthropogenic land use and vegetation change with alterations to unsaturated zone fluxes and regional increases in basin groundwater NO₃^? concentrations. Median increases in groundwater NO₃^? (by 0.7–0.9 mg‐N/l over periods ranging from 10 to 50+ years) occurred despite low precipitation (220–360 mm/year), high potential evapotranspiration (~1570 mm/year), and thick unsaturated zones (10–150+ m). Recent model simulations indicate net infiltration and groundwater recharge can occur beneath Trans‐Pecos basin floors, and may have increased due to irrigation and vegetation change. These processes were investigated further with chemical and isotopic data from groundwater and unsaturated zone cores. Some unsaturated zone solute profiles indicate flushing of natural salt accumulations has occurred. Results are consistent with human‐influenced flushing of naturally accumulated unsaturated zone nitrogen as an important source of NO₃^? to the groundwater. Regional mass balance calculations indicate the mass of natural unsaturated zone NO₃^? (122–910 kg‐N/ha) was sufficient to cause the observed groundwater NO₃^? increases, especially if augmented locally with the addition of fertilizer N. Groundwater NO₃^? trends can be explained by small volumes of high NO₃^? modern recharge mixed with larger volumes of older groundwater in wells. This study illustrates the importance of combining long‐term monitoring and targeted process studies to improve understanding of human impacts on recharge and nutrient cycling in arid regions, which are vulnerable to the effects of climate change and increasing human reliance on dryland ecosystems.     

Terrestrial‐originated submarine groundwater discharge through deep multilayered aquifer systems beneath the seafloor

A large quantity of submarine groundwater discharge (SGD) of about 1000 m³ day^?1 m^?1 of the 600‐km‐long shoreline of South Atlantic Bight has been estimated by Moore (Global Biogeochemical Cycles, 2010b, 24, GB4005, doi: 10.1029/2009GB003747 ). However, there is great uncertainty in estimating the percentage of net, land‐originated groundwater recharge of SGD. Moreover, most previous studies considered the homogeneous case for the coastal superficial aquifers. Here, we investigated the terrestrial‐originated SGD through a multilayered submarine aquifer system, which comprises two confined aquifers and two semi‐permeable layers. The inland recharge includes a constant part representing the annual average and a periodical part representing its seasonal variation. An analytical solution was derived and used to analyse the distributions of the terrestrial‐originated SGD from the multilayered aquifers along the Winyah Bay transect, South Atlantic Bight. It is found that the width of the zone of SGD from the upper aquifer ranges from ~0.8 to ~8.0 km depending on the leakance of the seabed semi‐permeable layer. A head of the upper aquifer at a coastline 1.0 m higher than the mean sea level will cause a SGD of 1.82– 18.3 m³ day^?1 m^?1 from that aquifer as the seabed semi‐permeable layer's leakance varies from 0.001 to 0.1 day^?1, providing considerable possibility for considerable land‐originated SGD. Seasonal terrestrial‐originated SGD variations predicted by the analytical model provide consistent explanation of the seasonal variation of ²²⁶Ra observed by Moore (Journal of Geophysics, 2007, 112, C10013, doi: 10.1029/2007JC004199 ). The contribution of the lower aquifer to SGD is only 1.2–12% of that of the upper aquifer. Copyright © 2014 John Wiley & Sons, Ltd.     

Surface water–groundwater exchange dynamics in a tidal freshwater zone

In coastal rivers, tides can propagate for tens to hundreds of kilometres inland beyond the saltwater line. Yet the influence of tides on river–aquifer connectivity and solute transport in tidal freshwater zones (TFZs) is largely unknown. We estimate that along the TFZ of White Clay Creek (Delaware, USA), 11% of river water exchanges through tidal bank storage zones. Additional hyporheic processes such as flow through bedforms likely contribute even more exchange. The turnover length associated with tidal bank storage is 150 km, on the order of turnover lengths for all hyporheic exchange processes in non‐tidal rivers of similar size. Based on measurements at a transect of piezometers located 17 km from the coast, tides exchange 0.36 m³ of water across the banks and 0.86 m³ across the bed per unit river length. Exchange fluxes range from ?1.66 to 2.26 m day^?1 across the bank and ?0.84 to 1.88 m day^?1 across the bed. During rising tide, river water infiltrates into the riparian aquifer, and the downstream transport rate in the channel is low. During falling tide, stored groundwater is released to the river, and the downstream transport rate in the channel increases. Tidal bank storage zones may remove nutrients or other contaminants from river water and attenuate nutrient loads to coasts. Alternating expansion and contraction of aerobic zones in the riparian aquifer likely influence contaminant removal along flow paths. A clear need exists to understand contaminant removal and other ecosystem services in TFZs and adopt best management practices to promote these ecosystem services. Copyright © 2015 John Wiley & Sons, Ltd.     

Nutrient fluxes induced by disturbance in Meiliang Bay of Lake Taihu

A wave flume experiment was conducted to study nutrient fluxes at water-sediment interface of Meiliang Bay under different hydrodynamic conditions. The results reveal that hydrodynamics has remarkable effects on nutrient fluxes in this area. With a bottom wave stress of 0.019 N m^?2 (equivalent to disturbance caused by wind SE 5–7 m s^?1 at the sediment sample site of Meiliang Bay), the fluxes of TN, TDN and NH₄ ⁺-N were separately 1.92 × 10^?3, ?1.81 × 10^?4 and 5.28 × 10^?4 mg m^?2 s^?1 (positive for upward and negative for downward), but for TP, TDP and SRP, the fluxes were 5.69 × 10^?4, 1.68 × 10^?4 and ?1.29 × 10^?4 mg m^?2 s^?1. In order to calculate the released amount of nutrients based on these results, statistic analysis on the long-term meteorological data was conducted. The result shows that the maximum lasting time for wind SE 5–7 m s^?1 in this area is about 15 h in summer. Further calculation shows that 111 t TN, 32 t NH₄ ⁺-N, 34 t TP and 10 t TDP can be released into water (the sediment area was 47.45% of the whole surface area), resulting in concentration increase of 0.025, 0.007, 0.007 and 0.002 mg L^?1 separately. With stronger disturbance (bottom wave stress is 0.217 N m^?2 which is equivalent to disturbance caused by wind SE 10–11 m s^?1 at the same site), there has been significant increase of nutrient fluxes (1.16 × 10^?2, 6.76 × 10^?3, 1.14 × 10^?2 and 2.14 × 10^?3 mg m^?2 s^?1 for TN, DTN and NH₄ ⁺-N and TP). The exceptions were TDP with flux having a decrease (measured to be 9.54 × 10^?5 mg m^?2 s^?1) and SRP with flux having a small increase (measured to be 5.42 × 10^?5 mg m^?2 s^?1). The same statistic analysis on meteorological data reveal that the maximum lasting time for wind SE 10–11 m s^?1 is no more than 5 h. Based on the nutrient fluxes and the wind lasting-time, similar calculations were also made suggesting that 232 t TN, 134.9 t TDN, 228 t NH₄ ⁺-N, 42.7 t TP, 2.0 t TDP and 1.1 t SRP will be released from sediment at this hydrodynamic condition resulting in the concentration increases of 0.050, 0.029, 0.049, 0.009, 0.0004 and 0.0002 mg L^?1. Therefore in shallow lakes, surface disturbance can lead to significant increase of nutrient concentrations although some components in water column had negative flux with weak disturbance (e.g. TDN and SRP in this experiment). In this case, sediment looks to be a source of nutrients. These nutrients deposited in sediment can be carried or released into water with sediment resuspension or changes of environmental conditions at water-sediment interface, which can have great effects on aquatic ecosystem and is also the characteristics of shallow lakes.     

Long‐term assessment of nutrient flow pathway dynamics and in‐stream fate in a temperate karst agroecosystem watershed

Nutrient dynamics in karst agroecosystems remain poorly understood, in part due to limited long‐term nested datasets that can discriminate upland and in‐stream processes. We present a 10‐year dataset from a karst watershed in the Inner‐Bluegrass Region of central Kentucky, consisting of nitrate (nitrate‐N [NO₃^?]), dissolved reactive phosphorus (DRP), total organic carbon (TOC), and total ammoniacal‐N (TAN) measurements at nested spring and stream sites as well as flowrate at the watershed outlet. Hydrograph separation techniques were coupled with multiple linear regression and Empirical Mode Decomposition time‐series analysis to determine significance of seasonal processes and to generate continuous estimates of nutrient pathway loadings. Further, we used model results of benthic algae growth and decomposition dynamics from a nearby watershed to assess if transient storage in algal biomass could explain differences in spring and downstream watershed nutrient loading. Results highlight statistically significant seasonality for all nutrients at stream sites, but only for NO₃^? at springs with longitudinal variability showing significant decreases occurring from spring to stream sites for NO₃^? and DRP, and significant increases for TOC and TAN. Pathway loading analysis highlighted the importance of slow flow pathways to source approximately 70% of DRP and 80% of NO₃^?. Results for in‐stream dynamics suggest that benthic autotroph dynamics can explain summer deviations for TOC, TAN, and DRP but not NO₃^?. Regarding upland dynamics, our findings agree well with existing perceptions in karst for N pathways and upland source seasonality but deviate from perceptions that karst conduits are retentive of P, reflecting the limited buffering capacity of the soil profile and conduit sediments in the Inner‐Bluegrass. Regarding in‐stream fate, our findings highlighted the significance of seasonally driven nutrient processing in the bedrock‐controlled streambed to influence nutrient fluxes at the watershed outlet. Contrary to existing perceptions, we found high N attenuation and an unexplained NO₃^? sink in the bedrock stream, leading us to postulate that floating macrophytes facilitate high rates of denitrification.     

Present state of oil pollution in the northern Indian Ocean

A consolidated picture of oil pollution for the northern Indian Ocean is presented. Oil slicks were sighted on 5582 observations, about 83.5% of the total observations of 6689. The range of concentrations, of the floating tar balls, is 0–6.0 mg/m² in the Arabian Sea. Similarly, the oil tanker route in the Bay of Bengal has the range of 0–69.75 mg/m². North of this route, the Bay of Bengal is comparatively free from this floating tar. Mean concentrations of dissolved and dispersed hydrocarbons for 0–20 m are 32.5 and 24.1 μg kg^?1, respectively, in the Arabian Sea and the Bay of Bengal.     

‘Thermohaline front’ off the east coast of India and its generating mechanism

Physical oceanography measurements reveal a strong salinity (0.18 psu km⁻¹) and temperature (0.07 °C km⁻¹) front off the east coast of India in December 1997. T–S diagrams suggest lateral mixing between the fresh water at the coast and the ambient warmer, saltier water. This front seems to be the result of southward advection of fresh and cool water, formed in the northern Bay of Bengal during the monsoon, by the East Indian Coastal Current, as suggested by the large-scale salinity structure in the SODA re-analysis and the anti-cyclonic gyre in the northwestern Bay of Bengal during winter. The data further reveals an offshore front in January, which appears to be the result of a meso-scale re-circulation around an eddy, bringing cold and freshwater from the northern Bay of Bengal further away from the shore. Our cruise data hence illustrates that very strong salinity fronts can appear in the Bay of Bengal after the monsoon, as a result of intense coastal circulation and stirring by eddies.

     

Effect of variable‐density groundwater flow on nitrate flux to coastal waters

A two‐dimensional variable‐density groundwater flow and transport model was developed to provide a conceptual understanding of past and future conditions of nitrate (NO₃) transport and estimate groundwater nitrate flux to the Gulf of Mexico. Simulation results show that contaminant discharge to the coast decreases as the extent of saltwater intrusion increases. Other natural and/or artificial surface waters such as navigation channels may serve as major sinks for contaminant loading and act to alter expected transport pathways discharging contaminants to other areas. Concentrations of NO₃ in the saturated zone were estimated to range between 30 and 160 mg?L^?1 as NO₃. Relatively high hydraulic vertical gradients and mixing likely play a significant role in the transport processes, enhancing dilution and contaminant migration to depth. Residence times of NO₃ in the deeper aquifers vary from 100 (locally) to about 300 years through the investigated aquifer system. NO₃ mass fluxes from the shallow aquifers (0 to 5.7 × 10⁴ mg?m^?2?day^?1) were primarily directed towards the navigation channel, which intersects and captures a portion of the shallow groundwater flow/discharge. Direct NO₃ discharge to the sea (i.e. Gulf of Mexico) from the shallow aquifer was very low (0 to 9.0 × 10¹ mg · m^?2?day^?1) compared with discharge from the deeper aquifer system (0 to 8.2 × 10³ mg?m^?2?day^?1). Both model‐calibrated and radiocarbon tracer‐determined contaminant flux estimates reveal similar discharge trends, validating the use of the model for density‐dependent flow conditions. The modelling approach shows promise to evaluate contaminant and nutrient loading for similar coastal regions worldwide. Copyright © 2015 John Wiley & Sons, Ltd.     

Influence of macroinvertebrates on physico‐chemical and microbial processes in hyporheic sediments

The objective of this study was to measure the effects of invertebrates on the physical characteristics and microbial processes in hyporheic sediments. We investigated the impacts of an assemblage of three taxa (asellids, chironomid larvae, and tubificid worms) on sediment distribution, water fluxes, sediment organic carbon, biofilm (attached bacteria) characteristics, and O₂, dissolved organic carbon NO₃^?, NO₂^?, and NH₄⁺ concentrations in slow filtration sand–gravel columns. The results showed that invertebrates clearly modified the distribution of particles in the sediment column, probably because of the structures (tubes, macropores, and faecal pellets) produced by the three taxa in the sediment. Our assessment of water fluxes indicated that invertebrate activities led to an increase in the porosity of the sediment columns. In addition, aerobic (O₂ consumption) and anaerobic (denitrification and fermentative decomposition of organic matter) microbial processes occurring in the sediment were stimulated in the presence of invertebrates. Finally, the present study demonstrates that invertebrates can act as ecosystem engineers in heterogeneous sediments that are under the influence of an advective flux of water. The solute residence time increased in columns containing the faunal assemblage. Micro‐organisms used more dissolved organic matter and nutrients in the presence of invertebrates because invertebrate activities increased the contact between the biofilm and water. We conclude that engineering by invertebrates in natural conditions modifies characteristics of the hyporheic zone and thereby enhances both the porosity of the sediment and the solute transport across the benthic interface. Copyright © 2002 John Wiley & Sons, Ltd.     

Effect of basin physical characteristics on solute fluxes in nine alpine/subalpine basins,Colorado, USA

Alpine/subalpine basins may exhibit substantial variability in solute fluxes despite many apparent similarities in basin characteristics. An evaluation of controls on spatial patterns in solute fluxes may allow development of predictive tools for assessing basin sensitivity to outside perturbations such as climate change or deposition of atmospheric pollutants. Relationships between basin physical characteristics, determined from geographical information system (GIS) tools, and solute fluxes and mineral weathering rates were explored for nine alpine/subalpine basins in Rocky Mountain National Park, Colorado, using correlation analyses for 1993 and 1994 data. Stream‐water nitrate fluxes were correlated positively with basin characteristics associated with the talus environment; i.e., the fractional amounts of steep slopes (≥ 30°), unvegetated terrain and young debris (primarily Holocene till) in the basins, and were correlated negatively with fractional amounts of subalpine meadow terrain. Correlations with nitrate indicate the importance of the talus environment in promoting nitrate flux and the mitigating effect of areas with established vegetation, such as subalpine meadows. Total mineral weathering rates for the basins ranged from about 300 to 600 mol ha^?1 year^?1. Oligoclase weathering accounted for 30 to 73% of the total mineral weathering flux, and was positively correlated with the amount of old debris (primarily Pleistocene glacial till) in the basins. Although calcite is found in trace amounts in bedrock, calcite weathering accounted for up to 44% of the total mineral weathering flux. Calcite was strongly correlated with steep slope, unvegetated terrain, and young debris—probably because physical weathering in steep‐gradient areas exposes fresh mineral surfaces that contain calcite for chemical weathering. Oligoclase and calcite weathering are the dominant sources of alkalinity in the basins. However, atmospherically deposited acids consume much of the alkalinity generated by weathering of calcite and other minerals in the talus environment. Published in 2001 by John Wiley & Sons, Ltd.     

Using Rn to estimate submarine groundwater discharge (SGD) and the associated nutrient fluxes into Xiangshan Bay,East China Sea

Continuous radon (²²²Rn) monitoring was conducted at two stations (site A and site B) with different perpendicular distance from the shoreline in Xiangshan Bay, East China Sea. Based on a ²²²Rn balance model (various sources and sinks of ²²²Rn in coastal water), the average rate of SGD was estimated to be 0.69 cm/day and 0.23 cm/day for site A and site B, respectively. The results from a nutrient analysis of the groundwater indicate that the associated nutrients fluxes loading through the SGD pathway were 4.27 × 10⁶ mol/day for DIN, 2.24 × 10⁴ mol/day for DIP and 1.82 × 10⁶ mol/day for DSi, respectively, which were comparable to or even higher than the levels observed in the local streams. Therefore, adequate attention should be paid to the importance of SGD as one source of nutrients during the eutrophication control process in this area.     

Nested‐Scale Nutrient Flux in a Mixed‐Land‐Use Urbanizing Watershed

To improve quantitative understanding of mixed‐land‐use impacts on nutrient yields, a nested‐scale experimental watershed study design (n = 5) was applied in a 303(d), clean water act impaired urbanizing watershed of the lower Missouri River Basin, USA. From 2010 to 2013, water samples (n = 858 sample days per site) were analysed for total inorganic nitrogen (TIN‐N), nitrite (NO₂–N) nitrate (NO₃–N), ammonia (NH₃–N), and total phosphorus (TP‐P). Annual, seasonal, and monthly flow‐weighted concentrations (FWCs) and nutrient yields were estimated. Mean nutrient concentrations were highest where agricultural land use comprised 58% of the drainage area (NH₃ = 0.111 mg/l; NO₂ = 0.045 mg/l; NO₃ = 0.684 mg/l, TIN = 0.840 mg/l; TP = 0.127 mg/l). Average TP‐P increased by 15% with 20% increased urban land use area. Highly variable annual precipitation was observed during the study with highest nutrient yields during 2010 (record setting wet year) and lowest nutrient yields during 2012 (extreme drought year). Annual TIN‐N and TP‐P yields exceeded 10.3 and 2.04 kg ha^?1 yr^?1 from the agricultural dominated headwaters. Mean annual NH₃–N, NO₂–N, NO₃–N, TIN‐N, and TP‐P yields were 0.742, 0.400, 4.24, 5.38, and 0.979 kg ha^?1 yr^?1, respectively near the watershed outlet. Precipitation accounted for the majority of the explained variance in nutrient yields (R² values from 0.68 to 0.85). Nutrient yields were also dependent on annual precipitation of the preceding year (R² values from 0.87 to 0.91) thus enforcing the great complexity of variable mixed‐land‐use mediated source‐sink nutrient yield relationships. Study results better inform land managers and best management practices designed to mitigate nutrient pollution issues in mixed‐land‐use freshwater ecosystems. Copyright © 2015 John Wiley & Sons, Ltd.     

Soil CO2 flux baseline in an urban monogenetic volcanic field: the Auckland Volcanic Field, New Zealand

The Auckland Volcanic Field (AVF) is a dormant monogenetic basaltic field located in Auckland, New Zealand. Though soil gas CO₂ fluxes are routinely used to monitor volcanic regions, there have been no published studies of soil CO₂ flux or soil gas CO₂ concentrations in the AVF to date or many other monogenetic fields worldwide. We measured soil gas CO₂ fluxes and soil gas CO₂ concentrations in 2010 and 2012 in varying settings, seasons, and times of day to establish a baseline soil CO₂ flux and to determine the major sources of and controlling influences on Auckland's soil CO₂ flux. Soil CO₂ flux measurements varied from 0 to 203 g m^?2 day^?1, with an average of 27.1 g m^?2 day^?1. Higher fluxes were attributed to varying land use properties (e.g., landfill). Using a graphical statistical approach, two populations of CO₂ fluxes were identified. Isotope analyses of δ¹³CO₂ confirmed that the source of CO₂ in the AVF is biogenic with no volcanic component. These data may be used to assist with eruption forecasting in the event of precursory activity in the AVF, and highlight the importance of knowing land use history when assessing soil gas CO₂ fluxes in urban environments.     

The Bay of Bengal — A major nutrient source for the deep Indian Ocean

The distribution of nutrient elements and dissolved oxygen in the deep Indian Ocean suggests that the Bay of Bengal Fan sediment serves as a major nutrient element source and oxygen sink. The distribution of nutrient element excesses and oxygen deficiences away from the fan is consistent with diffusion along isopycnal surfaces with circumpolar deep water acting as a sink for nutrient elements and source for dissolved oxygen. In the course of the entire GEOSECS program only at the Bengal Fan station were nutrient element excesses and oxygen deficiencies (relative to the overlying water column) observed in the benthic mixed layer. The unique aspect of this station is likely the result of very high rates of respiration and particle dissolution coupled with a high stability of the water column overlying the benthic mixed layer.The chemical data show that for each mole of organic carbon oxidized 1.5 moles of CaCO₃ must dissolve and that for each mole of CaCO₃ dissolved about one mole of silica go into solution. The NO₃ and PO₄ excesses are about two thirds those predicted from the Redfield ratios (i.e., O₂ : NO₃ : PO₄ = 135 : 15 : 1).     

Determination of aquifer parameters based on measurements of tidal effects on a coastal aquifer near Beihai,China

Measurements of the tide and groundwater levels in coastal zones are of importance in determining the properties of coastal aquifers. The solution to a one‐dimensional unsteady groundwater flow model in a coastal confined aquifer with sinusoidal fluctuation of the tide shows that the tidal efficiency decreases exponentially with distance and the time lag increases linearly with distance from the coast. The aquifer property described by the ratio of storage coefficient to transmissivity is determined if the damping constant of the tidal efficiency or the slope of the time lag with distance are obtained on the basis of tidal measurements. Hourly observations of the tide and groundwater levels at 10 wells on the northern coast near Beihai, China show that with distance from the coast, tidal efficiency decreases roughly exponentially and the time lag increases roughly linearly. The estimated ratio of storage coefficient to transmissivity of the confined aquifer ranges from 1·169 × 10^?6 d m^?2 to 1·83 × 10^?7 d m^?2. For a given transmissivity of 750 m² d^?1, the storage coefficient of the aquifer is 8·7675 × 10^?4 with the tidal efficiency method and 1·3725 × 10^?4 with the time lag method. The damping constant of the tidal efficiency with distance can be defined as the tidal propagation coefficient. The value of the confined aquifer is determined as 0·0018892 m^?1. Copyright © 2007 John Wiley & Sons, Ltd.     

The effects of sample scheduling and sample numbers on estimates of the annual fluxes of suspended sediment in fluvial systems

Since the 1970s, there has been both continuing and growing interest in developing accurate estimates of the annual fluvial transport (fluxes and loads) of suspended sediment and sediment‐associated chemical constituents. This study provides an evaluation of the effects of manual sample numbers (from 4 to 12 year^?1) and sample scheduling (random‐based, calendar‐based and hydrology‐based) on the precision, bias and accuracy of annual suspended sediment flux estimates. The evaluation is based on data from selected US Geological Survey daily suspended sediment stations in the USA and covers basins ranging in area from just over 900 km² to nearly 2 million km² and annual suspended sediment fluxes ranging from about 4 Kt year^?1 to about 200 Mt year^?1. The results appear to indicate that there is a scale effect for random‐based and calendar‐based sampling schemes, with larger sample numbers required as basin size decreases. All the sampling schemes evaluated display some level of positive (overestimates) or negative (underestimates) bias. The study further indicates that hydrology‐based sampling schemes are likely to generate the most accurate annual suspended sediment flux estimates with the fewest number of samples, regardless of basin size. This type of scheme seems most appropriate when the determination of suspended sediment concentrations, sediment‐associated chemical concentrations, annual suspended sediment and annual suspended sediment‐associated chemical fluxes only represent a few of the parameters of interest in multidisciplinary, multiparameter monitoring programmes. The results are just as applicable to the calibration of autosamplers/suspended sediment surrogates currently used to measure/estimate suspended sediment concentrations and ultimately, annual suspended sediment fluxes, because manual samples are required to adjust the sample data/measurements generated by these techniques so that they provide depth‐integrated and cross‐sectionally representative data. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.