Ore deposits associated with mafic magmas in the Kaapvaal craton

Mafic and ultramafic magmatism played an important role in the 3.5 Ga long history of the Kaapvaal craton. The oldest (3.5 Ga) greenstone belts contain mafic and ultramafic volcanics that erupted in an oceanic environment, probably in oceanic plateaus. Then followed a series of continental flood basalts, from the ∼3.4 Ga old Commondale and Nondweni sequences, to the 180 Ma Karoo basalts. The history was dominated, however, by the emplacement, 2.1 Ga ago, of the Bushveld complex, an enormous layered ultramafic-mafic-felsic intrusion. Three types of ore deposits might be found in such a sequence: Ni-Cu-Fe sulfides in komatiites of the greenstone belts; “Noril'sk-type” Ni-Cu-PGE deposits in the Karoo and other flood basalts; and deposits of Cr, platinum-group elements (PGE) and V in the Bushveld and other layered intrusions. Only the latter are present. It is tempting to attribute the absence of komatiite-hosted deposits to the specific character of the ultramafic rocks in Kaapvaal greenstone belts, which are older that the 2.7 Ga komatiites that host deposits in Australia, Canada and Zimbabwe, and are of the less-common “Al-depleted” type. However, a review of mantle melting processes found no obvious connection between the character of the mantle melts and their capacity to form ore deposits. The lack of this type of deposit may be due to differences in the volcanic environment, or it may be fortuitous (the Barberton and other belts are small and could fit into deposit-free parts of the much larger Australian or Canadian belts). Still more puzzling is the absence of Noril'sk-type deposits. The Karoo and older flood basalt sequences appear to contain all the important elements of the volcanic sequences that host the Siberian deposits. It is now recognised that these deposits formed through the segregation of sulfide from magma flowing rapidly through conduits en route from deeper magma chambers to the surface. An exploration approach aimed at understanding the fluid dynamics of such systems seems warranted. Although the Bushveld intrusion has been studied for decades and its deposits are taken as type examples of magmatic mineralisation, the origin of its PGE deposits remains unclear. Opinion is divided on the relative importance of sulfide segregation from magma filling a large chamber at the time of emplacement, and the scavanging of PGE from fluids circulating through cumulates at a late magmatic stage. Answers to these questions may come from studies designed to gain a better understanding of the mechanisms through which the magma chamber filled and solidified. Received: 15 September 1996 / Accepted: 7 January 1997     

Sn-polymetallic greisen-type deposits associated with late-stage rapakivi granites, Brazil: fluid inclusion and stable isotope characteristics

Tin-polymetallic greisen-type deposits in the Itu Rapakivi Province and Rondônia Tin Province, Brazil are associated with late-stage rapakivi fluorine-rich peraluminous alkali-feldspar granites. These granites contain topaz and/or muscovite or zinnwaldite and have geochemical characteristics comparable to the low-P sub-type topaz-bearing granites. Stockworks and veins are common in Oriente Novo (Rondônia Tin Province) and Correas (Itu Rapakivi Province) deposits, but in the Santa Bárbara deposit (Rondônia Tin Province) a preserved cupola with associated bed-like greisen is predominant. The contrasting mineralization styles reflect different depths of formation, spatial relationship to tin granites, and different wall rock/fluid proportions. The deposits contain a similar rare-metal suite that includes Sn (±W, ±Ta, ±Nb), and base-metal suite (Zn–Cu–Pb) is present only in Correas deposit. The early fluid inclusions of the Correas and Oriente Novo deposits are (1) low to moderate-salinity (0–19 wt.% NaCl eq.) CO₂-bearing aqueous fluids homogenizing at 245–450 °C, and (2) aqueous solutions with low CO₂, low to moderate salinity (0–14 wt.% NaCl eq.), which homogenize between 100 and 340 °C. In the Santa Bárbara deposit, the early inclusions are represented by (1) low-salinity (5–12 wt.% NaCl eq.) aqueous fluids with variable CO₂ contents, homogenizing at 340 to 390 °C, and (2) low-salinity (0–3 wt.% NaCl eq.) aqueous fluid inclusions, which homogenize at 320–380 °C. Cassiterite, wolframite, columbite–tantalite, scheelite, and sulfide assemblages accompany these fluids. The late fluid in the Oriente Novo and Correas deposit was a low-salinity (0–6 wt.% NaCl eq.) CO₂-free aqueous solution, which homogenizes at (100–260 °C) and characterizes the sulfide–fluorite–sericite association in the Correas deposit. The late fluid in the Santa Bárbara deposit has lower salinity (0–3 wt.% NaCl eq.) and characterizes the late-barren-quartz, muscovite and kaolinite veins. Oxygen isotope thermometry coupled with fluid inclusion data suggest hydrothermal activity at 240–450 °C, and 1.0–2.6 kbar fluid pressure at Correas and Oriente Novo. The hydrogen isotope composition of breccia-greisen, stockwork, and vein fluids (δ¹⁸O_quartz from 9.9‰ to 10.9‰, δD_H2O from 4.13‰ to 6.95‰) is consistent with a fluid that was in equilibrium with granite at temperatures from 450 to 240 °C. In the Santa Bárbara deposit, the inferred temperatures for quartz-pods and bed-like greisens are much higher (570 and 500 °C, respectively), and that for the cassiterite-quartz-veins is 415 °C. The oxygen and hydrogen isotope composition of greisen and quartz-pods fluids (δ¹⁸O_qtz-H2O=5.5–6.1‰) indicate that the fluid equilibrated with the albite granite, consistent with a magmatic origin. The values for mica (δ¹⁸O_mica-H2O=3.3–9.8‰) suggest mixing with meteoric water. Late muscovite veins (δ¹⁸O_qtz-H2O=−6.4‰) and late quartz (δ¹⁸O_mica-H2O=−3.8‰) indicate involvement of a meteoric fluid. Overall, the stable isotope and fluid inclusion data imply three fluid types: (1) an early orthomagmatic fluid, which equilibrated with granite; (2) a mixed orthomagmatic-meteoric fluid; and (3) a late hydrothermal meteoric fluid. The first two were responsible for cassiterite, wolframite, and minor columbite–tantalite precipitation. Change in the redox conditions related to mixing of magmatic and meteoric fluids favored important sulfide mineralization in the Correas deposit.     

Phyllosilicate and rutile compositions as indicators of Sn specialization in some southeastern Australian granites

Biotites from unaltered Sn granites in southeastern Australia are highly ferroan, Fe/(Fe+Mg+Mn) >0.75, whereas biotites from barren granites are less Ferich, Fe/(Fe+Mg+Mn)<0.65. Similar distinctions between Sn-specialized and barren granites can be observed in the other phyllosilicates, especially chlorite. Biotites and muscovites from Sn granites have greater Be, Cs, (F), Li, Mo, Rb, Sc, Sn, Tl, (Y) and Zn and lesser Ba abundances than corresponding micas from barren granites in the same district. Alteration of barren granites also results in similar enrichments in micas. Of these elements, Sn and Zn, because of their abundance and retention during degradation of biotite to chlorite, are the best trace element discriminants between barren granites and Sn granites/altered granites, with the Sn content of phyllosilicates being a better indicator than Zn. Rutile inclusions within phyllosilicates from unaltered Sn granites have Nb₂O₅ contents up to 26%. The Ta content tends to increase with Nb content but especially high Ta contents occur in the rutile inclusions of granites that give rise to pegmatitic deposits. The rutile inclusions in Sn granites may also have substantial Sn and W contents. The rutiles of barren granites have low Nb, Ta, Sn and W contents but Sn and W increase with alteration. Together, the ratio Fe/(Fe+Mg+Mn) and Sn contents in phyllosilicates and rutile compositions can be used to identify the Sn mineralization potential of a granite.     

Structural control of El Sela granites and associated uranium deposits, Southern Eastern Desert, Egypt

The El Sela area is a part of the basement complex of the Eastern Desert of Egypt and the Pan-African Shield. The area comprises outcrops of dismembered ophiolites thrust over arc volcano-sedimentary sequence and intruded by different syn- to post-tectonic granitoids. Structural analysis of the area enabled the separation and definition of four structural episodes: (E1) folding–thrusting episode associated with the cratonization of the arc/inter-arc rock association and the intrusion of the syntectonic (Older) granites. (E2) Upright folding episode associated with the compression and shortening to the ENE–WSW direction which is different from the NNW–SSE shortening direction during E1; at the end of E2, late tectonic granites were intruded. (E3) Post-tectonic granitic intrusion episode: two mica granite and granitic dikes were intruded during this episode. (E4) Fracturing, faulting, and post-granitic dike extrusion episodes caused different faults that took place after cratonization until the present. There are three generations of folds during ductile deformation (E1 and E2). The F2 folds are nearly coaxial (along ENE–WSW trend) with the F1 folds. The F3 folding is displayed by folds generally trending NNW–SSE. Therefore, the ENE–WSW and NNW–SSE trends can considered as preexisting discontinuities and mechanical anisotropy of the crust in the following structure episodes. Brittle deformation (E3 and E4) reveals the importance of those trends which control the multi-injections and many alteration features in the study area. During reactivation, a simple shear parallel to the inherited ductile fabrics was responsible for the development of mineralized structures along the ENE–WSW and NNW–SSE trends. So they can be considered as paleochannel trends for deep-seated structures and can act as a good trap for uranium and/or other mineral resources. Most of the uranium anomalies are delineated along ENE–WSW and NNW–SSE shear zones where quartz-bearing veins bounded the lamprophyre dike and microgranites and dissected them in relation to the successive fracturation and brecciation corresponding to the repeated rejuvenation of the structures. Therefore, the structural controls of the uranium mineralizations in the El Sela area appear to be related to the interaction between inherited ductile fabrics and overprinting brittle structures.     

Basaltic explosive volcanism: Constraints from deposits and models

Basaltic pyroclastic volcanism takes place over a range of scales and styles, from weak discrete Strombolian explosions (～10²–10³ kg s^?1) to Plinian eruptions of moderate intensity (10⁷–10⁸ kg s^?1). Recent well-documented historical eruptions from Etna, Kīlauea and Stromboli typify this diversity. Etna is Europe's largest and most voluminously productive volcano with an extraordinary level and diversity of Strombolian to subplinian activity since 1990. Kīlauea, the reference volcano for Hawaiian fountaining, has four recent eruptions with high fountaining (>400 m) activity in 1959, 1960, 1969 (–1974) and 1983–1986 (–2008); other summit (1971, 1974, 1982) and flank eruptions have been characterized by low fountaining activity. Stromboli is the type location for mildly explosive Strombolian eruptions, and from 1999 to 2008 these persisted at a rate of ca. 9 per hour, briefly interrupted in 2003 and 2007 by vigorous paroxysmal eruptions. Several properties of basaltic pyroclastic deposits described here, such as bed geometry, grain size, clast morphology and vesicularity, and crystal content are keys to understand the dynamics of the parent eruptions.The lack of clear correlations between eruption rate and style, as well as observed rapid fluctuations in eruptive behavior, point to the likelihood of eruption style being moderated by differences in the fluid dynamics of magma and gas ascent and the mechanism by which the erupting magma fragments. In all cases, the erupting magma consists of a mixture of melt and gaseous bubbles. The depth and rate of degassing, melt rheology, bubble rise and coalescence rates, and extent of syn-eruptive microlite growth define complex feedbacks that permit reversible shifts between fragmentation mechanisms and in eruption style and intensity. However, many basaltic explosive eruptions end after an irreversible shift to open-system outgassing and microlite crystallization in melt within the conduit.Clearer understanding of the factors promoting this diversity of basaltic pyroclastic eruptions is of fundamental importance in order to improve understanding of the range of behaviors of these volcanoes and assess hazards of future explosive events at basaltic volcanoes. The three volcanoes used for this review are the sites of large and growing volcano-tourism operations and there is a public need both for better knowledge of the volcanoes’ behavior and improved forecasting of the likely course of future eruptions.     

大别山沙村中生代A型花岗岩和基性岩的源区演化关系

A型花岗岩的成因虽存在不同的认识模式,但对大别山沙村A型花岗岩的岩石化学和地球化学研究结果表明,其物质源自大陆岩石圈地幔的部分熔融,含有古老地壳信息。结合被侵入基性岩的地球化学和年代学资料,推测大别造山带中生代岩石圈地幔的地球化学性质与下扬子地幔相似。花岗岩中锆石SHRIMP法U-Pb年龄为119.0±3.2Ma,说明其岩浆侵位于早白垩世,与邻近的基性岩侵位时间相近但稍晚。在三叠纪因大陆俯冲碰撞增厚的岩石圈在早白垩世被拉张减薄,含有古老地壳成分的扬子陆下岩石圈地幔及其上覆下地壳发生部分熔融,形成了不同成分的碰撞后岩浆岩。其中部分基性岩浆分异结晶成为辉长岩,而A型花岗岩可能是同一地幔源区物质小比例部分熔融后分异结晶的产物。     

Double injection events of mafic magma into supersolidus Yucheon granites to produce two types of mafic enclaves in the Cretaceous Gyeongsang Basin,SE Korea

Petrographic and geochemical features of the Cretaceous Yucheon granites and their mafic microgranular/magmatic enclaves (MMEs), SE Korea, reveal that the MMEs originated from magma mixing. Mesoscopic and microscopic features indicate that mechanical mixing operated heterogeneously to produce the MMEs with a wide range of sizes and textures. Chemical compositions of amphibole, biotite, and plagioclase rims of both the MMEs and host granites are almost identical, indicating that chemical homogenization took place to some extent after the mechanical mixing. Plagioclase cores, however, have various compositions depending on the host rocks and/or sampling locations, suggesting their sluggish re-equilibration. The MMEs are divided into Type A (low TiO₂, very fine-grained, chilled margins) and Type B (high TiO₂, fine- to medium-grained, no chilled margins). The lower TiO₂ MMEs cooled more rapidly and interacted with granitic magma for a shorter period of time than the higher TiO₂ MMEs. Additionally, the former are less enriched in HREEs than the latter. Zoned plagioclase has two zones of increased An content. These features are indicative of double injection events of mafic magma. A previous model explains the magma mixing as resulting from the generation of a slab window due to Kula-Pacific ridge subduction. The model cannot, however, explain the eastward younging of the granites in Korea, necessitating a new, more elaborate model of Cretaceous geodynamics and magmatism in East Asia.     

Seamount volcanism associated with the Xigaze ophiolite, Southern Tibet

Basaltic lavas at Renbu, Southern Tibet are associated with the Xigaze ophiolite in the Yarlung-Zangbo suture zone. They are alkaline lavas rich in large ion lithophile elements (LILE, Ba, Rb and Sr) and high field strength elements (HFSE, Nb, Ta, Zr and Hf), but poor in Cr, Co and Ni. All of the rocks have chondrite-normalized REE patterns enriched in light rare earth elements (LREE), comparable to modern basalts of the Society Islands, Kerguelen Plateau and Broken Ridge. Abundances of some immobile or moderately immobile elements (Nb, Ta, Zr, Hf, Y, Ti and REE) are also comparable to Kerguelen alkaline basalts. The Renbu basalts are geochemically similar to oceanic island basalts (OIB) and have some elemental ratios, such as Nb/Ta ratios = 15.7–18.1, Th/Nb =  0.06–0.10, La/Nb = 0.59–0.83 and Th/Ta = 1.03–1.52, similar to the primitive mantle. Their ⁸⁷Sr/⁸⁶Sr ratios (0.70453–0.70602) are relatively high, similar to OIB. In the ⁸⁷Sr/⁸⁶Sr vs. εNd(t) diagram, the Renbu basalts plot along a trend from N-MORB to EMII (enriched mantle II), suggesting the involvement of at least two mantle sources in their generation. The Renbu basalts represent seamount volcanism associated with the Xigaze ophiolite. They formed from an OIB-type mantle source within the Neo-Tethyan Ocean that had a composition similar to the modern Indian Ocean mantle.     

Biotites and associated minerals as markers of magmatic fractionation and deuteric equilibration in granites

Analyses of 80 biotite, alkali feldspar, oligoclase, hornblende, Fe-Ti oxide separates from the coarse-grained granites of a late-hercynian epizonal diapir, the Ploumanac'h complex, Brittany, show that these minerals display a regular concentric cryptic layering related to fractional crystallization. The Ca, Mg, Ba, Sr, Cr, V content of minerals decreases as the Na, Fe, and Rb content increases. Biotites become more dioctahedral towards the outer residual syenogranite, with a correlative K deficiency. Trioctahedral biotites from the inner accumulative monzogranite are secondarily oxidized with a gain of Fe³⁺ and a loss of OH. This alteration id due to the percolation of exsolved fluids rich in H₂O and containing a small amount of CO₂, F, S, Cl. During this autometamorphic stage, trace elements like Rb, Sr are completely redistributed on the scale of hand specimens, with a restricted range of partition coefficients between biotite, perthite and oligoclase. This equilibration occurred at a temperature about 550 ° C and a fluid pressure about 1,000 bars, with f _H2_O probably less than 500 bars. A later stage of fluid circulation along fractures brings up a slight Li metasomatism. Biotites are a sensitive marker of both magmatic and postmagmatic stages of subsolvus or ‘wet’ plutonites.     

Rare-earth patterns in peralkaline and associated granites

A study of selected rare earths, determined by non-destructive neutron activation analysis, in six Nigerian younger granites, together with previously publisded data on similar granites from northern Nigeria and Russia, reveals that anorogenic granites with peralkaline affinities develop an enrichment in the middle rare-earth group Sm, Gd, Tb and Dy with a corresponding Eu depletion. Such patterns may be related to the precipitation of earlier formed perthitic feldspar and late crystallizing alkaline amphibole from low temperature liquids enriched in volatiles (alkalis and fluorine).Progressively albitized peralkaline riebeckite granites exhibit rare earth enrichments towards Yb until the most albitized peralkaline granite is no longer depleted in Eu and there is a marked upward curvature of the relatively heavier rare-earth patterns. This change could be caused by residual albite-rich hydrothermal fluids which overprinted the earlier rare-earth distribution patterns.     

滤纸薄样片—X射线荧光光谱法测定钨和锡

本文用蜡环成形滤纸定量吸附由微量进样器分取的50μl试液,制成薄样进行X射线荧光光谱分析,实现了对样品中高含量WO_3、SnO_2的定量测定。被测组份的荧光强度与浓度在0—500μg/50μl范围内有良好线性关系。方法操作简单、制样速度快、成本低、稳定性好。     

Mineral chemistry and geochemical behavior of hydrothermal alterations associated with mafic intrusive-related Au deposits at the Atud area,Central Eastern Desert,Egypt

Vein-type gold deposits in the Atud area are related to the metagabbro–diorite complex that occurred in Gabal Atud in the Central Eastern Desert of Egypt. This gold mineralization is located within quartz veins and intense hydrothermal alteration haloes along the NW–SE brittle–ductile shear zone, as well as along the contacts between them. By using the mass balance calculations, this work is to determine the mass/volume gains and losses of the chemical components during the hydrothermal alteration processes in the studied deposits. In addition, we report new data on the mineral chemistry of the alteration minerals to define the condition of the gold deposition and the mineralizing fluid based on the convenient geothermometers. Two generations of quartz veins include the mineralized grayish-to-white old vein (trending NW–SE), and the younger, non-mineralized milky white vein (trending NE–SW). The ore minerals associated with gold are essentially arsenopyrite and pyrite, with chalcopyrite, sphalerite, enargite, and goethite forming during three phases of mineralization; first, second (main ore), and third (supergene) phases. Three main hydrothermal alteration zones of mineral assemblages were identified (zones 1–3), placed around mineralized and non-mineralized quartz veins in the underground levels. The concentrations of Au, Ag, and Cu are different from zone to zone having 25–790 ppb, 0.7–69.6 ppm, and 6–93.8 ppm; 48.6–176.1 ppb, 0.9–12.3 ppm, and 39.6–118.2 ppm; and 53.9–155.4 ppb, 0.7–3.4 ppm, and 0.2–79 ppm for zones 1, 2, and 3, respectively.The mass balance calculations and isocon diagrams (calculated using the GEOISO-Windows program) revealed the gold to be highly associated with the main mineralized zone as well as sericitization/kaolinitization and muscovitization in zone 1 more than in zones 2 and 3. The sericite had a higher muscovite component in all analyzed flakes (average X_Ms = 0.89), with 0.10%–0.55% phengite content in wall rocks and 0.13%–0.29% phengite content in mineralized quartz veins. Wall rocks had higher calcite (CaCO₃) contents and lower MgCO₃ and FeCO₃ contents than the quartz veins. The chlorite flakes in the altered wall rocks were composed of pycnochlorite and ripidolite, with estimated formation temperatures of 289–295 °C and 301–312 °C, respectively. Albite has higher albite content (95.08%–99.20%) which occurs with chlorite in zone 3.     

Compounds with mixed and intermediate sulfur valences as precursors of banded sulfides in carbonate-hosted Zn-Pb deposits in Belgium and Poland

Compounds of Fe, Pb and Zn with mixed and intermediate sulfur valences form ubiquitous inclusions and relics in banded sphalerite, pyrite-melnikovite and galena. Banded sulfides continuously grade into banded compounds with mixed and intermediate sulfur valences, the latter with a fibrous microtexture. A fibrous microtexture is also shown by banded sphalerite and pyrite from Zn-Pb deposits of Belgium and Poland. It is therefore suggested that the fibrous sphalerite inherited such a microtexture, unusual for cubic ZnS, by direct replacement of a fibrous precursor with mixed and/or intermediate sulfur valences. The last band of banded sphalerite is often overgrown by idiomorphic, isometric sphalerite precipitated directly from the solution as ZnS. The following Fe, Pb and Zn compounds with mixed and intermediate sulfur valences were found in carbonate-hosted Zn-Pb deposits of Belgium and Poland: sulfoxylanes (M²⁺SO₂; S²⁺), subsulfites (M²⁺S₂O₄; S³⁺), sulfites (M²⁺SO₃; S⁴⁺), pyrosulfites (M²⁺S₂O₅; S⁴⁺) and thiosulphates(M²⁺S₂O₃; S^2– and S⁶⁺).     

Thermal effects of massive CO2 emissions associated with subduction volcanism

Large volumes of CO₂ are emitted during volcanic activity at convergent plate boundaries, not only from volcanic centres. Their C isotopic signature indicates that this CO₂ is mainly derived from the decarbonation of subducted limestones or carbonated metabasalts, not as often admitted from magma degassing. On the example of Milos (Aegean Sea) it is argued that these fluids originate from intermediate depth in the mantle and carry sufficient heat to account for the generation of subduction-related magmas, as well as for the geothermal manifestations at the surface. The heat that is required for the decarbonation reactions is drawn by conduction from a wide zone surrounding the subducting slab and then rapidly transported upward by convection of the mixed CO₂–H₂O fluids that originate from the sediments in the slab. The transport takes place in a focused way through ‘chimneys’ in the upper mantle, where magmas are generated by the introduced heat and water. In the crust, the hot fluids cause thermal-dome-type metamorphism. In volcanic areas, magmas are commonly held responsible for the major part of heat transfer from the mantle to the surface. Here it is argued that most of the heat transfer is by hot gases. To cite this article: R.D. Schuiling, C. R. Geoscience 336 (2004).     

Ignimbritic cauldrons,alkali granites,and mineral deposits in fault-block mountains

The term fault-block mountains refers to an orogen, formed in an ensialic back arc by extension. The voluminous magmatism due to underplating of hot oceanic lithosphere, extrem thinning of the continental lithosphere and partial melting as well as mantle diapirs will be examplified by three ore provinces:

1. Southwestern North America (Middle Tertiary peralkaline ignimbrites and resurgent cauldrons)
2. Central Iran (Infracambrian ignimbrites and riebeckitegranite)
3. Arabian Shield (Infracambrian alkaligranites and rhyolites, 625-570 m.y.).

An overview of mineral deposits related to resurgent cauldrons will be given, encompassing disseminated deposits (Cu, Mo, Sn), skarns, massive magnetite ores, beryl pegmatites, sedimentary deposits (Pb-Zn; Hg, U, Li; Mn, borates, zeolites), mineralized vents (Au, U, apatite), vein type deposits (Au, Ag, Te, fluorite, U) and hydrothermal replacements (alunite). The value of several deposits exceeds 10 billion German Marks at current prices. The exploration concept based on resurgent cauldrons may also be applied successfully in other provinces.     

产于钨锡矿区与岩浆作用有关的金矿床

通过七个典型的产于著名钨锡矿讴的金矿床实例，论述了该类金矿床与中度氧化态的花岗岩类有关，其金属组合为Bi,W,As,Sn,Mo,Te,Sb,其产出的大地构造环境包括克拉通边缘、陆缘、弧后盆地或陆陆碰撞带，主要矿化形式表现为脉状至网脉状，亦可见似云英岩化的浸染状和角砾状，其围岩蚀变有钾长石化、钠长石化和绢云母化，其包裹体大多数是低盐度且富合含CO2，但极个别是高盐度的。该类金矿床属贫硫化物型（＜3％），且主要为黄铁矿和毒砂。由于金与铋矿物紧密共性，因此，Au与Bi,Te吴正相关，而通常与W、Sn,Mo,Sb不相关。     

Intrusion-related gold deposits associated with tungsten-tin provinces

An under-recognized and economically important class of intrusion-related gold deposits, which occur within magmatic provinces best known for tungsten and/or tin mineralization, is described with reference to seven major deposits (Fort Knox, Mokrsko, Salave, Vasilkovskoe, Timbarra, Kidston and Kori Kollo). These gold deposits contain a metal suite that includes some combination of bismuth, tungsten, arsenic, tin, molybdenum, tellurium and antimony, and contrasts with that found in the more widely-developed gold-rich porphyry copper and related deposits. The gold deposits associated with tungsten and/or tin provinces are located in cratonic margins, in a landward or back-arc position relative to continental margin arcs (where recognized), or within continental collisional settings. The deposits are related genetically to felsic domes, stocks or plutons of intermediate oxidation state, both magnetite- and ilmenite-series magmas are represented. The intrusion-hosted gold deposits are most commonly of sheeted vein/veinlet type, although greisen-like, disseminated and breccia deposits are also described. Gold may also be concentrated more distally (1–3 km) with respect to the intrusions, where deposits may be of skarn, disseminated replacement or vein types. K-feldspar, albite and/or sericitic alteration assemblages, commonly including carbonate, accompany the gold mineralization. In sheeted vein deposits, alteration is normally restricted to narrow envelopes around veins, whereas more pervasive alteration occurs in greisen-like, disseminated and shallow (<3 km) deposits. The gold mineralization is commonly present with low total sulphide contents (<3%), mainly pyrite and lesser arsenopyrite. In several deposits, bismuth minerals are closely associated with gold, and bismuth-gold and tellurium-gold correlations exist. Most deposits contain tungsten, tin, molybdenum and antimony, although generally these do not correlate with gold; tungsten and molybdenum concentrations may increase with depth or may occur in separate zones. Base metals generally are present in minor amounts (e.g. <100 ppm Cu). The distinct spatial association with felsic intrusions, combined with the consistent metal signature, suggests a magmatic-hydrothermal origin. Fluid inclusions studies indicate the presence of high-salinity fluids in some deposits, and low-salinity and carbonic fluids in most deposits, similar to the composition of fluids in intrusion-related tungsten deposits. Variations in mineralization style largely reflect depth of formation and location relative to the intrusive centre. Several deposits in this class contain >100 tonnes (3 million oz) of gold, thereby highlighting the gold potential of intrusion-related deposits beyond the more traditionally explored gold and copper provinces in arc terranes. Received: 13 March 1998 / Accepted 14 January 1999     

Empirical equations to predict the sulfur content of mafic magmas at sulfide saturation and applications to magmatic sulfide deposits

Empirical equations to predict the sulfur content of a mafic magma at the time of sulfide saturation have been developed based on several sets of published experimental data. The S content at sulfide saturation (SCSS) can be expressed as: