Mercury remobilization in Saguenay Fjord (Quebec,Canada) sediments: Insights following a mass-flow event and its capping efficiency

A mass-flow event triggered by the 1996 flood in the Saguenay region buried the mercury-contaminated indigenous sediments at the head of the Saguenay Fjord under up to 50 cm of postglacial deltaic sediments. The vertical distributions of total mercury and methyl-mercury in the sediments and pore waters were measured in box cores recovered from the Saguenay Fjord within and outside the affected area prior to and on six consecutive years after the flood. The total solid mercury (THg_s) profiles show that remobilization was limited and most of the mercury remobilized from the contaminated, indigenous sediments was trapped below or slightly above the former sediment–water interface by authigenic acid-volatile sulfides (AVS). Nonetheless, a small fraction of the remobilized mercury diffused into the flood layer, some of it was methylated and/or scavenged by organic matter and AVS. Elevated solid-phase methyl-mercury concentrations, [MeHg_s], at depth in the sediment are correlated to peak AVS and THg_s but, in the absence of elevated dissolved methyl-mercury concentrations, [MeHg_d], the higher [MeHg_s] may reflect an earlier episode of Hg methylation, the product of which was scavenged by the AVS and buried. Throughout the sediment cores, sediment–water partitioning of MeHg and Hg(II) appears to be controlled in great part by the AVS and residual organic matter content of the sediment.     

Permo-Triassic hypabyssal mafic intrusions and associated tholeiitic basalts of the Kolyuchinskaya Bay,Chukotka (NE Russia): Links to the Siberian LIP

In order to test tectonic hypotheses regarding the evolution of the Arctic Alaska–Chukotka microplate prior to the opening of the Amerasian basin, we investigated rocks exposed near Kolyuchinskaya Bay, eastern Chukotka. Hypabyssal mafic rocks and associated basaltic flows enclose terrigenous sediments, minor cherts and limestones in pillow interstices. The hypabyssal mafic rock yields a U–Pb zircon age of 252 ± 4 Ma and indicates intrusion of basic magma at the Permo-Triassic boundary, contemporaneous with voluminous magmatism of the Siberian large igneous province (LIP). The lava flows and hypabyssal mafic rocks of the Kolyuchinskaya Bay region have trace elements, Sm–Nd and Rb–Sr isotope compositions identical to the tholeiitic flood basalts of the main plateau stage of the Siberian LIP, but differ from the latter in the major-element variations. We conclude that compositional variations in the hypabyssal rocks studied reflect their generation in an extensional environment that might be related to the Siberian super-plume activity at the time. Although the genetic and temporal links between intrusive mafic rocks and lavas are not well proved, compositional variations of the eruptive rocks still indicate their generation in an extensional environment.     

Dating recent floodplain sediments in the Hawkesbury‐Nepean River system,eastern Australia using single‐grain quartz OSL

Two fluvial sediment cores taken from a floodplain of the Hawkesbury‐Nepean River system in the Sydney region, eastern Australia are dated using Optically Stimulated Luminescence (OSL) to provide a reliable chronology essential for the management and planning of water resources. Nine charcoal ¹⁴C (AMS) dates constrain these OSL ages. Quartz extracted from seven OSL samples from each of the cores was measured using both single‐grain and multi‐grain OSL techniques. Three of the single‐grain natural dose distributions appear to be well bleached, but the others appear to be incompletely bleached to various degrees. Three minimum‐age models (MAM, MAM_UL and IEU) are applied to the single‐grain dose distributions. We conclude that these models give consistent age estimates. For one of the cores it appears to be necessary to use a minimum‐age model to obtain accurate ages, but in the other core incomplete bleaching is probably less important than postdepositional mixing and mixing during sampling. As a result, the burial age is probably best estimated using the weighted average of the individual single‐grain dose estimates. The application of multi‐grain OSL techniques to these samples results in an average apparent age overestimation of ～200 years, which is significant for these samples, but negligible for sediments older than a few thousand years. The intention is that the chronology obtained in this study will be used in conjunction with a proxy flood record, derived from floodplain sediments, to gain an understanding of the long‐term variability in periods of high and low rainfall in eastern Australia.     

黑龙江森林沼泽区超低密度 地球化学调查采样介质对比

黑龙江省中部的嘉荫地区为典型的森林沼泽景观,在该区进行了超低密度地球化学调查采样介质对比研究。通过河漫滩沉积物、活性水系沉积物进行对比研究,发现利用河漫滩表层沉积物所圈定的异常不仅能较好地反映矿化信息,而且能较好地反映该地区的地质背景。水系沉积物测量所圈定的异常很弱,只能反映出露矿信息。研究成果表明,河漫滩表层沉积物是森林超低密度地球化学调查的最佳采样介质。     

金沙江“11·3”白格堰塞湖溃决洪水事件在奔子栏—石鼓段的地貌作用和沉积特征

古堰塞湖溃决洪水事件的重建是当前地学研究的热点问题之一,寻找足够的可参考的现代溃决洪水事件案例是顺利开展这项工作的基础。2018年11月13日发生在金沙江干流的白格堰塞湖超万年一遇的溃决洪水事件(学术界称之为“11·3”白格堰塞湖溃决洪水事件)就是一个难得的样本。这次溃决事件发生在枯水期,洪峰完全由溃决洪水产生,没有叠加其他来源,对评估流域地貌和沉积体系对堰塞溃决事件的响应有很好的参考价值。本文以溃决洪水事件受灾最为严重的奔子栏—石鼓段为研究区,通过详细的野外调查和初步的水力学估算发现“11·3”白格堰塞湖溃决洪水事件在奔子栏—石鼓段的地貌作用主要表现为洪水淹没区的岸坡塌岸和沉积物堆积,未发现明显的基岩侵蚀。沉积物主要由分选良好的具水平纹层的砂组成。受金沙江较低的河床比降影响,洪水产生的基底剪切应力较弱在27~142 N/m²,不能悬浮和搬运直径5 cm以上的砾石,也不能产生明显的磨蚀和冲(撞)击作用。在发生塌岸的部分段落,洪水沉积物中有砾石坠入,甚至会出现类似浊流沉积的层序。这些现象的发现对深入理解堰塞湖溃决洪水的复杂地貌过程和沉积特征有重要参考意义。     

Heavy metal concentrations in sediment deposits on the Tar River floodplain following Hurricane Floyd

The relation between the magnitude of a flood event and the resulting environmental impacts remains unclear. This study examines the impact of the flood of record on heavy metal deposition on the Tar River floodplain in eastern North Carolina, USA. Samples of sediment deposited on the floodplain following Hurricane Floyd were collected from 85 sites along the lower Tar River basin and analyzed for heavy metal concentration. The Hurricane Floyd event is the flood of record for the Tar River basin. Despite the magnitude of the flood, little suspended sediment was deposited on the floodplain. In almost all cases the deposition was less than 0.2 cm. There was variability in heavy metal content from site to site, but the overall concentrations were lower than might be expected for a flood of the magnitude of Floyd. To aid in comparison of contamination levels, the heavy metal concentrations were normalized to two environmental standards; the EPA preliminary remediation goals for residential soil and the general background concentrations of stream sediments throughout the Tar River basin. Most samples were highly enriched in heavy metals relative to the background concentration of stream sediments. However, samples were generally not contaminated relative to EPA PRG regulations. Arsenic, which was significantly elevated in nearly all samples, was the only exception. This contradiction makes it clear that the standard to which contaminants are compared must be considered carefully. The overall low concentration of heavy metals was likely the result of smaller flooding from Hurricane Dennis, 10 days prior to Hurricane Floyd, moving most of the stored sediment out of the basin prior to wide-spread overtopping of the banks. The implication is that event sequencing is as important as flood magnitude when examining environmental impacts.     

Is a regional flood signal reproducible from lake sediments?

The evolution of flood activity with global warming remains uncertain. To better assess flood–climate relationships, lake sediments are increasingly being investigated because they could provide regional flood histories long enough to cover past climate changes. However, site‐specific sedimentary processes may bias flood reconstructions. The aim of this article is to investigate these effects through the reconstruction of two distinct flood records from independent, neighbouring sedimentary basins of the same lake (Lake Allos in the Mediterranean French Alps), i.e. under the same climate conditions. Understanding of sedimentary processes is crucial in order to adapt the sampling strategy and the flood‐intensity proxy to each sedimentary system and, thereby, reconstruct a complete and reliable flood history. Thanks to this detailed approach, the main trends of the regional flood variability can be reproduced; i.e. periods of high flood‐frequency, ranges of flood‐frequency values and timing of the most intense events. In detail, some differences appeared associated to the various stream capacities to erode and transport flood sediments to the lake system, implying variable sensitivity of sedimentary systems in recording floods. Comparing regional flood records based on independent sedimentary systems from similar environments could thus be a complementary approach to assessing past flood intensity. Such an approach could open particularly interesting perspectives because reconstructing the long‐term evolution of flood intensity is a key challenge in the geosciences.     

The Mechanism of Groundwater Salinization and Its Control in the Yaoba Oasis, Inner Mongolia

The arid area is one of the most concerned areas among the water resources researchers and economists. Northwest China will be an important developing region of China in the 21st century. Yaoba is a well-irrigation oasis within this arid area, which is located in the Alxa area west of the Helan Mountains and next to the Tengger desert in the east. It has contributed greatly to the local stock raising and agriculture since its development in 1970. However, the groundwater which the oasis depends on to survive has been getting salinized gradually and more serious in recent years.A comprehensive study was carried out using the methods of groundwater environment isotope analysis, lithofaci-es and palaeogeography, calculations of water-rock interaction and the existing form of chemical components in groundwater etc. It has been found that the salinization of groundwater is mainly caused by reinfiltration water solving the salt in soil which is deposited simultaneously with the sediments and accumulated in th     

Hohokam Canal Irrigation and the Formation of Irragric Anthrosols in the Middle Gila River Valley,Arizona, USA

Irragric anthrosols form as a result of prolonged deposition of fine sediments from irrigation water. Ancient irragric soils centuries to millennia old occur in several world regions, especially in arid environments of Asia and the Americas. This article presents evidence for an ancient irragric anthrosol in the North American Southwest, along the Snaketown Canal System in the Middle Gila River Valley, Arizona. This pedostratigraphic unit was formed as a result of a millennium of irrigation by Hohokam farmers from A.D. 450 to 1450. The irragric soil consists of a mantle of silty‐to‐loamy textures with minimal soil formation overlying a natural argillic horizon on a Pleistocene stream terrace. A soil mapped independently by the United States Department of Agriculture‐Natural Resources Conservation Service with these horizons corresponds closely with the canal system. Soil within the canal system tends to be lower in salt, sodium, and pH compared with external soils. This suggests that the irragric process improved soil for crop production through long‐term leaching and additions of fresh sediments with the irrigation water. This anthropogenic process of canal sedimentation has had a long‐lasting impact on the sedimentary record and soils in this arid environment.     

Paleohydraulic interpretation of Quaternary alluvium near Golden,Colorado

Quaternary terraces and pediments along Ralston Creek and Clear Creek, near Golden, Colorado, are associated with Verdos, Slocum, Louviers, and Broadway Alluviums. Terrace deposits can be locally correlated on the basis of elevation and relict paleosols. The terrace sediments probably represent aggradation by braided streams flowing from glaciated drainage basins. Engineering hydraulic calculation procedures suggest that flood flows were 2–3 m deep on steep gradients (0.008–0.01). Discharges were as great as 1400 m³/sec, nearly an order of magnitude greater than modern flood discharges. The most useful paleohydraulic calculation techniques were found to be the dimensionless shear approach applied to stream competence and bedload function theory applied to stream capacity.     

Climate and environment during the Younger Dryas (GS‐1) as reflected by composite stable isotope records of lacustrine carbonates at Torreberga,southern Sweden

Climatic and environmental changes during the Younger Dryas stadial (GS‐1) and preceding and following transitions are inferred from stable carbon and oxygen isotope records obtained from the sediments of ancient Lake Torreberga, southern Sweden. Event GS‐1 is represented in the sediment sequence by 3.5 m of clay containing lacustrine carbonates of various origins. Comparison of isotopic records obtained on mollusc shells, ostracod valves, and Chara encrustations precipitated during specific seasons of the year supports estimates of relative changes in both lake water and mean annual air temperatures. Variations in soil erosion rates can also be estimated from a simple isotope–mass‐balance model to separate allochthonous and autochthonous carbonate contributions to the bulk carbonate content of the sediments. The well‐known, rapid climatic shifts characterising the Last Termination in the North Atlantic region are clearly reflected in the isotopic data, as well as longer‐term changes within GS‐1. Following maximum cooling shortly after the Allerød–Younger Dryas (GI‐1–GS‐1) transition, a progressive warming and a slight increase in aquatic productivity is indicated. At the Younger Dryas–Preboreal (GS‐1–PB) transition mean annual air temperature rapidly increased by more than 5°C and summer lake‐water temperature increased by ca. 12°C. The subsequent Preboreal oscillation is characterised by an increase in soil erosion and a slight decrease in mean annual air temperature. These results are in harmony with recent findings about large‐scale climate dynamics during the Last Termination. Copyright © 1999 John Wiley & Sons, Ltd.     

Facies model of a mixed clastic–carbonate,wave‐dominated open‐coast tidal flat (Tithonian–Berriasian,north‐east Spain)

Detailed logging and analysis of the facies architecture of the upper Tithonian to middle Berriasian Aguilar del Alfambra Formation (Galve sub‐basin, north‐east Spain) have made it possible to characterize a wide variety of clastic, mixed clastic–carbonate and carbonate facies, which were deposited in coastal mudflats to shallow subtidal areas of an open‐coast tidal flat. The sedimentary model proposed improves what is known about mixed coastal systems, both concerning facies and sedimentary processes. This sedimentary system was located in an embayed, non‐protected area of a wide C‐shaped coast that was seasonally dominated by wave storms. Clastic and mixed clastic–carbonate muds accumulated in poorly drained to well‐drained, marine‐influenced coastal mudflat areas, with local fluvial sandstones (tide‐influenced fluvial channels and sheet‐flood deposits) and conglomerate tsunami deposits. Carbonate‐dominated tidal flat areas were the loci of deposition of fenestral‐laminated carbonate muds and grainy (peloidal) sediments with hummocky cross‐stratification. Laterally, the tidal flat was clastic‐dominated and characterized by heterolithic sediments with hummocky cross‐stratification and local tidal sandy bars. Peloidal and heterolithic sediments with hummocky cross‐stratification are the key facies for interpreting the wave (storm) dominance in the tidal flat. Subsidence and high rates of sedimentation controlled the rapid burial of the storm features and thus preserved them from reworking by fair‐weather waves and tides.     

Flow dynamics,sedimentation and erosion of glacial lake outburst floods along the Middle Pleistocene Scandinavian Ice Sheet (northern central Europe)

During the Middle Pleistocene late Saalian glaciation of northern central Europe numerous pro‐glacial lakes formed along the southwestern margin of the Scandinavian Ice Sheet. Little is known about the drainage history of these lakes, the pathways of glacial lake outburst floods and their impacts on erosion, sedimentation and landscape evolution. This study investigated the impact of the late Saalian Weser and Münsterland Lake (Germany) outburst floods. In particular, we reconstructed the routing and flow dynamics of the lake outburst flood and analysed the flood related sediments. We employed one‐dimensional hydraulic modelling to calculate glacial lake outburst flood hydrographs. We modelled the flow pathway and local flow conditions along the pathway based on the boundary conditions of two different hydrographs and two different ice‐margin positions. The modelling results were compared with geomorphological and sedimentological field data in order to estimate the magnitude and impact of the flood on erosion and sedimentation. Two major lake drainage events are reconstructed for the study area, during which approximately 90–50 km³ of water was released. Modelling results indicate that the lake outburst floods created a high‐energy flood wave with a height of 35–50 m in confined valley areas that rapidly spread out into the Lower Rhine Embayment eventually flowing into the North Sea basin. The sedimentary record of the outburst floods comprises poorly sorted coarse‐grained gravel bars, long‐wavelength bedforms and sandy bedforms deposited by supercritical and subcritical flows. Some parts of the sandy flood deposits are rich in reworked mammoth bones or mammoth and horse teeth, pointing to reworking of older fluvial sediments, hydraulic concentration and subsequent re‐sedimentation of vertebrate remains. These deposits are preserved in sheltered areas or at high elevations, well above the influence of postglacial fluvial erosion. The flood‐related erosional features include up to 80‐m‐deep scour pools, alluvial channels and streamlined hills.     

Sedimentological characteristics of small rivers with loessic headwaters in the Chaco,South America

Some sedimentological characteristics of fluvial environments located in the northeastern region of the Chaco–Pampa plain were analysed in order to determine the possible influence of the loessic headwaters of local basins. Concentrations of suspended sediments, as well as grain size of the river beds, were compared. Unexpectedly, it was found that the suspended load has an inverse relationship with the hydrometric levels, with the exception of highly saline streams (conductivity values between 4300 and 11,000 μS cm⁻¹). The mean concentration of suspended sediments was 63.1 and 206.3 mg l⁻¹ in flood and low water periods, respectively. The grain size of bed sediments was relatively homogeneous along the whole hydrological cycle. Sandy–silty bottoms predominate in channels, followed by silty–sandy and clayey–silty bottom types. Sediment transport mainly occurs in accelerating flow suspension, overcoming the critical erosion velocity. During flood periods, some parameters exceeded by 70% the values recorded during the low water phase.     

从沉积速率和沉积物粒度看冰后期海侵以来珠江三角洲西江大鳌沙的形成

大鳌沙处于珠江三角洲西江河口的近口段,洪季西江河口的潮区界西线在其顶端附近。冰后期海侵以来,大鳌沙顶端的PRD05和中部的PRD04两个钻孔的沉积速率和沉积物粒度有着极大的差别。7 630 a BP以前,PRD04孔的沉积速率小于PRD05孔的沉积速率;但7 630 a BP以来,PRD04孔的沉积速率大于PRD05孔的沉积速率。从粒度分析看,埋深12.28 m以下,PRD04孔沉积物比PRD05孔的粗,分选性比PRD05孔的差;埋深12.28 m以上,PRD04孔的沉积物比PRD05孔的细,分选性相对比PRD05孔的好。分析表明,9 000～4 200a BP, 沉积物由南（中部）向北（顶部）输运,涨潮流冲蚀老沉积物,在喷出磨刀门通道后,流速迅速降低,粗颗粒泥沙先沉积,而细颗粒泥沙被涨潮流搬运至更北的区域沉积。近3500年以来,河流动力占优势,沉积物由北（顶部）向南（中部）输运。大鳌沙的形成与涨潮射流密切相关。涨潮射流口的位置在蛇地山和右岸纵向山地之间,宽约2200 m。     

Holocene alluvial stratigraphy in the upper Susquehanna River Basin, New York

Two alluvial terraces and the present flood plain were studied at two locations along the Susquehanna and Unadilla Rivers in south-central New York state. They have formed since deglaciation and incision of the stream channels into the valley train deposits. The higher terrace has noncumulative soil profiles with well-developed color B horizons predominantly of silt loam and very fine sandy loam. The terrace is weathered to a degree similar to nearby glacial outwash terraces that have caps of similarly textured sediments. Incision that produced the terrace occurred before 9705 ± 130 yr B.P. The lower terrace is characterized by relatively thick, vertical-accretion deposits of silt loam that contain sequences of thin, buried A, color B, and C horizons. They were formed between about 3240 ± 110 (¹⁴C data of soil humin) and 235 ± 80 yr B.P. Deposits above the 235 ± 80 yr B.P. stratum are unweathered. The soil stratigraphy and ¹⁴C dates of soil humin from buried A horizons are surprisingly well correlated between sites. Most sediments of the present flood plain have been deposited since 1120 ± 80 yr B.P. Incipient A horizons and oxidation of inherited organic matter in the subsoil are the only evidence of pedogenesis in the flood-plain deposits that are older than 275 ± 80 yr B.P. The most recent flood-plain fill deposited since then is unaltered. These youngest sediments of the flood plain along with the youngest veneer of vertical-accretion deposits on the lowest terrace are associated with an increased rate of deposition largely attributable to clearing of the forests by settlers, beginning in the late 1700s. Comparison of the alluvial stratigraphy with the radiocarbon-dated pollen stratigraphy of southwestern New York (Miller 1973) reveals some apparent time correlations between alluvial events and vegetation changes. This gives reason to speculate that climatic change or forest catastrophes such as disease or drought are causes of some of the alluvial events.     

Chronology,stratigraphy and palaeoenvironmental interpretation of a Late Pleistocene to mid‐Holocene cave accumulation on Kangaroo Island,South Australia

Chronological, sedimentological and geochemical analyses of a clastic infill from Kelly Hill Cave (5K1), Kangaroo Island, document a palaeoenvironmental record that spans from the Late Pleistocene to the middle Holocene. We AMS radiocarbon‐dated bone collagen and U–Th‐dated speleothem to determine that fossiliferous sediments were deposited between >20 ka and 7 ka ago. Most of the 15 sedimentary layers are dominated by sand‐ and silt‐sized quartz that is physically and geochemically comparable with surface soils in the Kelly Hill area. Late Pleistocene and Last Glacial Maximum strata are represented primarily by homogeneous, poorly sorted quartz‐rich sediments that contain little organic matter, but include a thin layer composed largely of silt‐sized clay pellets that resemble sediments deflated from playa lakes. Microstructures observed in petrographic slides indicate that, with the exception of one layer, all sediments experienced little reworking once deposited in the cave. Some layers display pedogenic microstructures such as redeposited clays and opaline silica infilling that indicate postdepositional modification; that is, cave‐floor soil development. Overlying Holocene‐aged sediments also consist mainly of quartz but have much greater organic matter content. Some of these sediments have been strongly influenced by re‐precipitated organic matter that appears to have been transported into the cave via vadose drip water. The presence of dissolved organic matter in soil/vadose waters suggests a high vegetation density and acidic soils, which are congruent with the more equitable climatic conditions characteristic of the Holocene. The sediments described here provide a valuable palaeoenvironmental record that will facilitate future interpretation of associated vertebrate fossils.     

Iron in a post-glacial lake sediment core; a Mössbauer effect study

The distribution of iron in a 6-m core of post-glacial sediment from an oligotrophic lake (Connistonwater, England) was determined, principally by Mossbauer spectroscopy on dried samples. The immediate post-glacial deposits contain 4.8 wt. % of iron, with a Fe²⁺; Fe³⁺ ratio ～- 4. The iron there is predominantly in the form of chlorite, but there are small amounts in hematite and illite. The distribution of iron is different, and very variable in the recent sediments (~ < 13,000 BP), which contain 25–35 per cent organic matter and 5.2 wt. % of iron relative to the inorganic fraction. Typically half the iron is present there as chlorite, and the rest is ferric, mostly in the form of an amorphous gel which is also present in undried samples. To explain the observed ferrous:ferric profile, it is proposed that the latter includes iron which was once mobile, having been leached from the Fe²⁺-bearing clays under reducing conditions in the soils of the drainage basin, or in the sediment itself. It was subsequently precipitated as ferric hydroxide on contact with the oxic lake water. In contrast, the ferrous iron in the sediments is immobile iron, which remained locked in the chlorite phase of the clay particles as they were carried from soil to sediment intact.All the sediments are rather inhomogeneous. Chlorite, and especially hematite, are mechanically concentrated in pink varves in the immediate post-glacial deposits. In the partly inorganic sediments, the concentration of ferrous iron (chlorite) is approximately uniform, but the ferric content may differ by a factor of five between regions only a few millimeters apart.     

Variability of the metal content of flood deposits

Fresh flood deposits were sampled in the flood-plains of two river systems, the River Meuse, with a catchment area of 33,000 km² and the River Geul, with a catchment area of 3,000 km². As a result of industrial and mining activities, both rivers have a history of severe metal pollution, especially with zinc, lead, and cadmium. The flood deposits of both rivers are heterogeneous mixtures of contaminated bottom sediments (with relatively long residence times in the river) and clean sediments derived from soil erosion on agricultural cropland (with very short residence times). An additional source of sediment is formed by erosion of older, locally highly contaminated streambank deposits. These older sediments are polluted as a result of solid waste disposal containing metalliferous ore and tailings in the sand fraction. This is especially the case in the River Geul, which drains an old zinc and lead mining area. The metal content of the Meuse sediments, however, originates largely from liquid industrial wastes and occurs mainly in the clay fraction. For this reason, the positive correlation between textural composition, organic matter content, and heavy metal concentration, which is often reported, was not observed, and normalization of the metal content was not possible. Nevertheless, a clear decrease of contamination was noticed along the River Geul; this trend was absent along the River Meuse. An attempt has been made to model the longitudinal decay pattern for each of the investigated havey metals.