Synthesis of soil‐hydraulic properties and infiltration timescales in wildfire‐affected soils

We collected soil‐hydraulic property data from the literature for wildfire‐affected soils, ash, and unburned soils. These data were used to calculate metrics and timescales of hydrologic response related to infiltration and surface runoff generation. Sorptivity (S) and wetting front potential (Ψ_f) were significantly different (lower) in burned soils compared with unburned soils, whereas field‐saturated hydraulic conductivity (K_fs) was not significantly different. The magnitude and duration of the influence of capillarity during infiltration was greatly reduced in burned soils, causing faster ponding times in response to rainfall. Ash had large values of S and K_fs but moderate values of Ψ_f, compared with unburned and burned soils, indicating ash has long ponding times in response to rainfall. The ratio of S²/K_fs was nearly constant (~100 mm) for unburned soils but more variable in burned soils, suggesting that unburned soils have a balance between gravity and capillarity contributions to infiltration that may depend on soil organic matter, whereas in burned soils the gravity contribution to infiltration is greater. Changes in S and K_fs in burned soils act synergistically to reduce infiltration and accelerate and amplify surface runoff generation. Synthesis of these findings identifies three key areas for future research. First, short timescales of capillary influences on infiltration indicate the need for better measurements of infiltration at times less than 1 min to accurately characterize S in burned soils. Second, using parameter values, such as Ψ_f, from unburned areas could produce substantial errors in hydrologic modeling when used without adjustment for wildfire effects, causing parameter compensation and resulting underestimation of K_fs. Third, more thorough measurement campaigns that capture soil‐structural changes, organic matter impacts, quantitative water repellency trends, and soil‐water content along with soil‐hydraulic properties could drive the development of better techniques for numerically simulating infiltration in burned areas.     

Non‐stationary seismic response of tanks with soil interaction by wavelets

A wavelet‐based random vibration theory has been developed for the non‐stationary seismic response of liquid storage tanks including soil interaction. The ground motion process has been characterized via estimates of statistical functionals of wavelet coefficients obtained from a single time history of ground accelerations. The tank–liquid–soil system has been modelled as a two‐degree‐of‐freedom (2‐DOF) system. The wavelet domain equations have been formulated and the wavelet coefficients of the required response state are obtained by solving two linear simultaneous algebraic equations. The explicit expression for the instantaneous power spectral density function (PSDF) in terms of the functionals of the input wavelet coefficients has been obtained. The moments of this PSDF are used to estimate the expected pseudo‐spectral acceleration (PSA) response of the tank. Parametric variations are carried out to study the effects of tank height, foundation natural frequency, shear wave velocity of soil and ratio of the mass of tank (including liquid) to the mass of foundation on the PSA responses of tanks. Copyright © 2001 John Wiley & Sons, Ltd.     

Non‐linear system identification of the versatile‐typed structures by a novel signal processing technique

Non‐linear structural identification problems have raised considerable research efforts since decades, in which the Bouc–Wen model is generally utilized to simulate non‐linear structural constitutive characteristic. Support vector regression (SVR), a promising data processing method, is studied for versatile‐typed structural identification. First, a model selection strategy is utilized to determine the unknown power parameter of the Bouc–Wen model. Meanwhile, optimum SVR parameters are selected automatically, instead of tuning manually. Consequently, the non‐linear structural equation is rewritten in linear form, and is solved by the SVR technique. A five‐floor versatile‐type structure is studied to show the effectiveness of the proposed method, in which both power parameter known and unknown cases are investigated. Copyright © 2007 John Wiley & Sons, Ltd.     

Adsorption Kinetic Modeling of Safranin onto Rice Husk Biomatrix Using Pseudo‐first‐ and Pseudo‐second‐order Kinetic Models: Comparison of Linear and Non‐linear Methods

Batch kinetic studies were carried out for the removal of safranin from aqueous solution using a biomatrix prepared from rice husk. The adsorption kinetic data were modeled using the pseudo‐first‐order and pseudo‐second‐order kinetic equations. The linear and non‐linear forms of these two widely used kinetic models were compared in this study. In order to determine the best‐fitting equation, the coefficient of determination (r²), the sum of the squares of the errors (SSE), sum of the absolute errors (SAE), average relative error (ARE), hybrid fractional error function (HYBRID), Marquardt's percent standard deviation (MPSD), and the Chi‐squared test (χ²) were used as error analysis methods. Results showed that the non‐linear forms of pseudo‐first‐order and pseudo‐second‐order models were more suitable than the linear forms for fitting the experimental data. Non‐linear method is thus more appropriate for estimating the kinetic parameters and should primarily be used to describe adsorption kinetics.     

Characterisation of Fulvic Acids and Glycyrrhizic Acid by Time‐of‐Flight Secondary Ion Mass Spectrometry

Fulvic acids of different origin, spray deposited on polished silicon after dissolution in high‐purity water without any additives, were analysed by time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) in combination with oblique 24...36 keV SF₅⁺ ion bombardment. The observed, highly reproducible mass spectra cover more than five orders of magnitude in dynamic range, without background subtraction. Apart from lines due to atomic ions and low‐mass ion fragments, the mass spectra exhibit broad maxima between m/z 200...350, mainly due to a beat‐like superposition of lines at every single mass number, up to at least m/z 400. In the negative ion spectra the beats have a spacing of m/z 14, corresponding to a CH₂‐unit. The high‐mass tails of the spectra extend well beyond m/z 5000, with similar slopes in the positive and the negative ion mass spectra. The negative spectra appear to be less affected by fragmentation products than the positive spectra. Fulvic acids (FAs) of different origin show distinctly different spectra, with mean masses ranging between m/z ≈ 450 and 580 (for a low‐mass cut‐off m/z 150). To further verify the ability of TOF‐SIMS to detect molecules and clusters with masses significantly above the maxima of the FA spectra, samples of glycyrrhizic acid (GA, as GA ammonium salt with molecular weight 840) were also analysed. Parent ions as well as multimers (GA)_n were observed as positive and negative ions, up to n = 4 (m/z 3320). The results are compared with spectra recently obtained by other mass spectrometric techniques.     

Electrochemical Treatment of Dye Solution by Oxalate Catalyzed Photoelectro‐Fenton Process Using a Carbon Nanotube‐PTFE Cathode: Optimization by Central Composite Design

Decolorization of C.I. Basic Blue 3 (BB3) by oxalate catalyzed photoelectro‐Fenton process based on carbon nanotube‐polytetrafluoroethylene (CNT‐PTFE) electrode as cathode under visible light was studied. A comparison of electro‐Fenton, photoelectro‐Fenton, and photoelectro‐Fenton/oxalate processes for decolorization of the solution containing BB3 has been performed. The results showed that color removal follows the decreasing order: photoelectro‐Fenton/oxalate > photoelectro‐Fenton > electro‐Fenton. Response surface methodology (RSM) was employed to assess individual and interactive effects of the four main independent parameters on the decolorization efficiency. A central composite design (CCD) was employed for optimization of photoelectro‐Fenton/oxalate treatment of BB3. The analysis of variance (ANOVA) showed a high coefficient of determination value (R² = 0.958) and satisfactory prediction second‐order regression. This study clearly showed that RSM was one of the suitable methods to optimize the operating conditions.     

Removal of Various Phenoxyalkanoic Acid Herbicides from Water by Organo‐clays

Dodecylammonium bentonite (DB) and dodecylammonium sepiolite (DS) were used as sorbents for phenoxyalkanoic acid herbicides 2,4‐D ((2,4‐dichlorophenoxy)acetic acid), 2,4‐DP ((RS)‐2‐(2,4‐dichlorophenoxy)propionic acid), 2,4‐DB (4‐(2,4‐dichlorophenoxy)butyric acid), 2,4,5‐T ((2,4,5‐trichlorophenoxy)acetic acid), and MCPA ((4‐chloro‐2‐methylphenoxy)acetic acid). Langmuir, Freundlich, and the linear Henry’s Law isotherm adsorption parameters were calculated from the adsorption isotherms. Langmuir equation showed poor fit for both adsorbents. According to the evaluation using the Freundlich equation, the DS sample showed much higher and stronger sorption capacity than DB. Similar behaviour was also observed in the case of the linear Henry’s Law isotherm. The adsorption of the herbicides on both DB and DS decreased in the order of 2,4‐DB > 2,4,5‐T > 2,4‐DP > 2,4‐D > MCPA.     

Degradation of Textile Dyeing Wastewater by a Modified Solar Photo‐Fenton Process Using Steel Scrap/H2O2

This experimental research deals with using steel scrap as a heterogeneous catalyst. This catalyzes the oxidation reaction of real textile dye wastewater based on a modified solar photo‐Fenton oxidation process. Morphologic analysis and mapping of the elementary composition of the steel scrap have been carried out by scanning electron microscopy. The effects of concentration of H₂O₂, the pH of the solution and the catalyst loading on the degradation of textile dye wastewater are elucidated. Kinetic studies have been performed for the decolorization of wastewater under optimum conditions. It could be concluded that the steel scrap is a potential substitute for ferrous salts as a catalyst for the solar photo‐Fenton reaction.     

Experimental Designs Applied to Desorption of Dichromate Ions after Separation and Preconcentration from Natural and Industrial Water by Modified Nano‐Alumina

Nano‐alumina modified by 9‐aminoacridine was used as a sorbent for separation and determination of dichromate ions from water. Statistical method, based on surface response design, has been used for the optimization of dichromate ions elution from 9‐aminoacridine nano‐alumina. The adsorbed dichromate ions were found to be eluted quantitatively with 0.8 mol L^?1 KCl in 1.6 mol L^?1 NaOH which optimized by response surface design. Under optimum conditions, the accuracy, precision (relative standard deviation, RSD%) and R‐square of the method were calculated as >98, <3, and >94%, respectively. Remarkable agreement between experimental and theoretical data was confirmed the predicted assumption. The method was applied to the simultaneous determination of dichromate in natural and industrial water samples. We also examined the retention of dichromate anions in the presence of Cl^?, , and anions at pH 3.     

New Strategy to Reduce the Harmful Effects of Smoking: Reducing the Level of N‐nitrosamines in Mainstream Smoke by NaA Zeolite and In vitro and In vivo Investigations

A new effort to control the pollution caused by smoking by use of zeolite sieving the N‐nitrosamines in smoke is depicted and assessed in this paper, which is a first preliminary approach to demonstrate the performance characteristics of zeolite for the reduction of the concentration of N‐nitrosamines in the cigarette smoke. Smoking causes global pollution and is difficult to control because smoke is a complex system containing thousands of components. A new strategy is presented here for the reduction of the harmful effects of smoking through dispersion of zeolite into the tobacco rod of cigarettes to eliminate the N‐nitrosamines once they form in the smoke, and both in vitro and in vivo tests were employed to check the efficiency of this strategy. The impact of zeolite on the combustion of tobacco and the total toxicity of smoke are evaluated for the first time. Lower mutagenic activity and higher CHO cell livability were found for the test cigarette containing zeolite in comparison with the control, and no significant damage was detected in 30‐day animal experiments when exposed to the cigarette smoke. This confirms the feasibility of the new strategy and promotes the potential application of zeolite for protecting public health.