内蒙古白云鄂博矿床的稀土矿化时代与期次

内蒙古白云鄂博REE-Fe-Nb矿床是世界罕见的超大型多金属矿床, 但矿床成因一直没有解决, 而年代学研究是解决矿床成因的基础。本文结合矿床地质特征, 系统地分析了前人的年代学研究成果, 并对白云鄂博矿床的Sm-Nd同位素体系进行了深入的分析和讨论。结果表明, 白云鄂博稀土的成矿时代约为1.3 Ga, 与碳酸岩墙的形成时间一致, 成矿物质来源于地幔。加里东期的热事件(约0.44 Ga)导致了白云鄂博矿床晚期稀土矿脉的形成和原有矿体中部分稀土矿物的重结晶, 但成矿物质主要来源于矿体内部的稀土再循环, 外源物质的贡献不明显。约1.3 Ga到约0.44 Ga间的一系列中间年龄为后期热扰动的结果, 并不代表成矿事件。简言之, 白云鄂博矿床只在中元古代发生过一次实质性的稀土矿化作用, 地幔是稀土物质的单一源区。     

The Liqhobong kimberlite cluster: an update on the geology

The Cretaceous Liqhobong kimberlite cluster comprises six known diamondiferous Group 1 kimberlite bodies: the Main Pipe (8.5 ha), the Satellite Pipe (1.6 ha), the Discovery Blow (0.15 ha), the Blow (0.1 ha), the Main Dyke, and the East Dyke. Emplaced along a strike length of about 2.5 km, the kimberlites intruded Jurassic Drakensberg lavas and outcrop at altitude ranging from 2970 to 2670 m above sea level (masl) in the rugged Maluti Mountain terrain of Lesotho. The cluster’s intrusion was structurally controlled and emplacement occurred in at least three pulses. The dykes and the two blows (which are dyke enlargements emplaced ~900 m apart) comprise the earliest event and the Main and Satellite Pipes were emplaced during two separate, subsequent events. Each pipe has steep contacts with the country rock basalt. The two Blows have inward dipping contacts and narrow considerably at depth. Each of the Main and Satellite Pipes comprises multiple phases which range from largely volcaniclastic to marginally coherent kimberlites. The volume of the volcaniclastic kimberlite is always much more (>three times) than that of the coherent kimberlite. The larger Main and Satellite Pipes are diluted by country rock up to 40 vol% whereas the smaller Blows and Dykes typically have less than 10 vol% dilution. The degree of mantle sampling is highest (up to 40 vol%) in the smaller Blows and lower (~25 vol%) in the larger Pipes.

     

Mesozoic alkaline dykes in the Sunnhordland region, western Norway: ages, geochemistry and regional significance

The coast-parallel, alkaline, dyke suite in the Sunnhordland region of Norway comprises the youngest igneous event documented in this country. K---Ar measurements on amphibole and whole-rock samples demonstrate at least three episodes of dyke intrusion along recurrently opened fractures at around 275 m.y. 220 m.y. and 160 m.y. There is a progressive trend towards increasing alkalinity and rare earth content and the younger dykes may represent a more fractionated stage or a smaller degree of partial melting at deeper level. The occurrence of ultramafic inclusions and xenocrysts indicates the presence of upper mantle derived material. Intrusion of the dykes is related to rifting, fracturing and differential movement along the margin of the North Sea. The earliest dykes may have been associated with the formation of the West Norway Trough in Permo-Carboniferous time, the main igneous activity with the Hardegsen Pulse in the Early Triassic and the mid-Jurassic activity, which is identical in age to the North Sea volcanic episode, with mid-Cimmerian movements.     

Occurrence and Dispersal of Magmas in the Jurassic Ferrar Large Igneous Province, Antarctica

Tholeiitic rocks of the Ferrar Large Igneous Province (FLIP) occur in a linear belt from the Theron Mountains to Horn Bluff in the Transantarctic Mountains and extend into southeastern Australasia. The FLIP was emplaced during the initial stages of Gondwana break-up from a source suggested to be in the proto-Weddell Sea region. Magma transport from its source (Weddell triple junction) was controlled by an Early Jurassic zone of extension. The FLIP comprises the Dufek intrusion, Ferrar Dolerite sills and dykes (sheet intrusions), and extrusive rocks consisting of pyroclastic strata overlain by Kirkpatrick Basalt lavas. The Dufek intrusion occurs in deformed supracrustal rocks of the foldbelt along the paleo-Pacific Gondwana margin. A few sills were emplaced in basement rocks, but the majority of the sheet intrusions occur in flat-lying Devonian to Triassic Beacon strata. Only in the central Transantarctic Mountains (CTM) and south and north Victoria Land (SVL, NVL) are extrusive rocks preserved overlying Beacon strata. The greatest cumulative thicknesses of magmatic rocks (ca. 2 km) occur in areas where lavas are preserved (CTM and SVL). Sheet intrusions have complex relationships. Dyke swarms (sensu stricto) are unknown and dykes cutting basement rocks are uncommon. Nevertheless, these dykes, including a 30-m-wide dyke in SVL, suggest that some magmas locally migrated up through basement rocks. In CTM and NVL the outcrop belt has a width of about 160 km. Sills originally extended farther toward the plate margin but have been cut out by erosion and Cenozoic faulting, most clearly in CTM; geophysical data suggest extension under the East Antarctic ice sheet for at least 100 km. Although Early Jurassic extension is documented in CTM, major rift-bounding faults have not been observed. Models for magma emplacement include transport along the axis of the Transantarctic Mountains and off-axis transport from major rift-bounding faults. Contrasts in geochemistry between lavas of NVL (MgO=67%) and CTM (MgO=24%) and the presence of massive dolerite bodies (CTM, SVL) suggest discrete episodes and locations of magma emplacement, and that there was no long range interconnection along the mountain range in supracrustal rocks.     

SHRIMP geochronology for the 1450 Ma Lakhna dyke swarm: Its implication for the presence of Eoarchaean crust in the Bastar Craton and 1450–517 Ma depositional age for Purana basin (Khariar), Eastern Indian Peninsula

Zircon U–Pb ages of the Mesoproterozoic dyke swarms (Lakhna dyke swarm) at the interface between the Eastern Ghats Mobile Belt and Bastar Craton of the Indian Peninsula are reported here to decipher the tectonic evolution of the region. The dyke swarm, which is dominantly N–S in orientation, has intruded the Bastar Craton at ca. 1450 Ma. The dykes vary in composition from dolerite to trachyte and rhyolite and have been emplaced in a continental anorogenic setting. The above age puts a lower time constraint on the sedimentary sequences of the Purana basin (Khariar basin) that have been deposited unconformably over the Bastar Craton. The shale member of the Khariar basin shows evidence of synsedimentary shearing suggesting that the sedimentation probably continued up to 517 Ma, the age of shearing and overthrusting of the granulite nappes of the Eastern Ghats Mobile Belt on the Craton. Further, the compression accompanying thrusting of the nappes, uplifted the Purana basins during inversion.     

Fission track dating,thermal histories and tectonics of igneous intrusions in East Greenland

Fission track ages have been measured for 12 sphenes, 18 zircons and 25 apatites separated largely from Lower Tertiary magmatic rocks of East Greenland, with a few examples from Caledonian rocks. The sphene and zircon ages of Caledonian rocks agree with other radiometric ages but apatite is strongly discordant indicating that these rocks cooled very slowly over a 200 m.y. period. It was not until the Permian/Lower Jurassic that they finally cooled below 100 ° C, possibly as a consequence of uplift and erosion at this time in connection with extensive rifting. No evidence of a Tertiary imprint has been found in these rocks.Layered gabbros, such as Skaergaard, were emplaced at about the same time (ca. 54 m.y.) as the latest plateau basalts. Some evidence of syenitic activity from this period occurs in the Angmagssalik area ca. 400 km to the south but the syenites of Kangerdlugssuaq cluster around 50 m.y. The Gardiner ultramafic alkaline complex and some of the offshore gabbros apparently also were emplaced at about 50 m.y. Late dykes in the Kangerdlugssuaq area were emplaced over a considerable time span (43-34 m.y.) in keeping with their variable petrographic character, and the Kialineq centre was formed at 36.2±0.4 m.y.Intrusions of the Masters Vig area differ in age. Kap Simpson and Kap Parry to the northeast were emplaced around 40 m.y. whereas the Werner Bjerge complex is the youngest igneous activity so far identified in Greenland with an age of 30.3±1.3 m.y.Many apatites give strongly discordant ages of about 36 m.y. and these are concentrated in the area of a major domal uplift centred on Kangerdlugssuaq. The uplift is older than these ages but on field evidence post-dates the basalts. It probably formed in conjunction with alkaline magmatism at ca. 50 m.y. Cooling below ca. 200 ° was slow for these intrusions and was probably controlled by a number of factors including erosion of the dome, high heat flow caused by continuing dyke injection and regional plateau uplift. The last is believed to have taken place about 35 m.y. ago at the time of emplacement of the Kialineq plutons and last dykes. Renewed rapid erosion and declining heat flow at this time led to rapid cooling of the rocks now at the surface to below 100 °.     

Geochemistry and geochronology of proterozoic tholeiite dykes of east antarctica: evidence for mantle metasomatism

Two episodes of tholeiite dyke emplacement have been identified in Archaean high-grade metamorphics of the Napier Complex in Enderby Land. Middle Proterozoic Amundsen dykes are typical continental tholeiites and most of the chemical variation in individual suites can be explained in terms of different degrees of partial melting and low-pressure crystal fractionation. Group I Amundsen tholeiites were derived from a relatively homogeneous source region 1,190±200 m.y. ago, whereas that of the group II Amundsen tholeiites was chemically and isotopically heterogeneous. Group II dykes have various degrees of enrichment in incompatible elements, and commonly show normalised trace element abundance patterns with negative Nb anomalies. These features imply variable metasomatism of the source region by a volatile-rich fluid phase (rather than a melt of any observed igneous composition) enriched in K, Rb, Ba, Th, and possibly La and Ce.Early Proterozoic (2,350±48 m.y.) tholeiites were emplaced at considerable depths in the crust during the waning stages of granulite-facies metamorphism and include a high-Mg suite of possible komatiitic affinity, ranging in composition from hypersthene-rich tholeiite (norite) to quartz-rich tholeiite. They tend to have higher ratios of highly to moderately incompatible elements (e.g., K/Zr, K/Ce), and larger Nb anomalies (i.e., higher K/Nb) compared with middle Proterozoic tholeiites, suggesting derivation from more enriched source regions. Isotopic data are not compatible with significant crustal contamination, but constrain source metasomatism to a time immediately before emplacement. Metasomatism of the source region of the much younger group I tholeiites may have been contemporaneous with that of the high-Mg suite.     

A review of the 2500 Ma span of alkaline-ultramafic, potassic and carbonatitic magmatism in West Greenland

Kimberlites, carbonatites and ultramafic, mafic and potassic lamprophyres have been produced in West Greenland in recurrent events since the Archaean. Five distinct age groups are recognised: Archaean (>2500 Ma). Early Proterozoic (1700–1900 Ma), Middle Proterozoic (Gardar, c. 1100–1300 Ma), Late Proterozoic (600 Ma) and Mesozoic-Tertiary (200-30 Ma) The rocks comprise two large and four small carbonatite occurrences, four kimberlite dyke swarms, one lamproite dyke swarm and one lamproite pipe, one dyke swarm of potassic lamprophyre (shonkinite) and some ten dyke swarms of ultramafic lamprophyre and monchiquite. Geochemical data for the various rock groups are presented. Some of the carbonatites may represent relatively unmodified mantle-derived melts. The kimberlites range from primitive to differentiated compositions, and there are regional differences between kimberlites within Archaean and Proterozoic basement. The ultrapotassic lamproites and shonkinites have strong negative Nb spikes in their trace element spectra. The ultramafic and monchiquitic lamprophyres encompass a large compositional variation; however, several of the dyke swarms have individual chemical characters.

The rocks are very unevenly distributed in West Greenland, indicating a lithospheric control, probably by old weakness zones providing access to the surface. The kimberlites are considered to be mainly of asthenospheric derivation. The regional differences are interpreted in terms of melting with phlogopite as a residual phase, with smaller degrees of melting at deeper levels beneath the Archaean lithosphere than beneath the Proterozoic. The ultrapotassic lamproites and shonkinites occur almost exclusively within a continental collision zone with possible two-way subduction and they are interpreted as mainly of lithospheric derivation, with a contribution from a subducted slab. Data for the other rock types are equivocal.

Except for the Archaean rocks, the age groups can be related to major geotectonic events. The Early Proterozoic group is related to continental collision at 1850 Ma and subsequent rifting; the Middle Proterozoic group is related to continental rifting (Gardar) and the Mesozoic group is likewise related to continental rifting prior to continental break-up in the Tertiary. The 600 Ma kimberlites and carbonatite are envisaged as cratonic, extra-rift activity in relation to continental break-up and formation of the Iapetus ocean further south, perhaps with a common cause in a broad, impinging mantle plume.     

A 2.44 Ga syn-tectonic mafic dyke swarm in the Kolvitsa Belt,Kola Peninsula,Russia: implications for early Palaeoproterozoic tectonics in the north-eastern Fennoscandian Shield

The Kolvitsa Belt in the south-western Kola Peninsula formed coeval with the earliest Palaeoproterozoic rift-belts in the Fennoscandian Shield. The Palaeoproterozoic history of this belt comprises the deposition of the 2.47 Ga Kandalaksha amphibolite (metabasalt) sequence onto 2.7 Ga granitoid gneisses, the intrusion of the 2.45–2.46 Ga Kolvitsa Massif of gabbro-anorthosite and the subsequent multiple injection of mafic dykes and magmatic brecciation, followed by the intrusion of 2.44 Ga dioritic dykes, and extensive shearing at 2.43–2.42 Ga. The gabbro-anorthosite and dykes contain high-pressure garnet-bearing assemblages that have previously been considered as evidence for metamorphism in a compressional setting of the Kolvitsa Belt at 2.45–2.42 Ga, i.e. coeval with the formation of the Imandra–Varzuga rift-belt and layered mafic intrusions in an extensional setting. The Kochinny Cape study area on the White Sea coast presents an unique remnant of a 2.44 Ga mafic dyke swarm that endured ca. 1.9 Ga collision but preserved its primary structural pattern well. All these dykes were intruded along numerous NW-trending shear zones within the Kolvitsa Massif and contain angular xenoliths of sheared gabbro-anorthosite. Every new batch of mafic melt underwent shearing during or immediately after solidification, and later dykes intruded into already sheared dykes. Thus, rocks of the Kolvitsa Massif and its dyke complex were successively injected into a large-scale shear zone which was active from ca. 2.46 to 2.42 Ga. Multiple injection of mafic melts, the presence of mutually intruding, composite, sheared mafic dykes, of magmatic breccias with gabbroic groundmass, and of host rocks fragments (showing no evidence of tectonic stacking at the time of brecciation), all indicate an extensional setting. Shearing was also extensional as it occurred simultaneously with the multistage magmatism. The asymmetric morphology of deformed dykes, and asymmetric flexures within weakly deformed lenses show that all these extensional shear zones, apart from a few exceptions, are dextral, were formed in a transtensional setting and are attributed to general W–E to WSW–ENE extension. Structural data available for 2.4–2.5 Ga magmatic rocks elsewhere in the Kola region suggest that the same kinematics operated on a regional scale. The presence of the garnet-bearing assemblages in gabbro-anorthosite and dykes may be explained by crystallisation and shearing of the magmatic rocks at deep crustal levels. Alternatively, corona development might have occurred much later as a result of tectonic loading due to the juxtaposition and overthrusting of the Umba Granulite Terrane onto the Kolvitsa Belt at ca. 1.9 Ga. In view of the field evidence and published ages, an overall extensional setting rather than a combination of compressional and extensional zones is preferable for Palaeoproterozoic tectonics in the north-eastern Fennoscandian Shield at 2.5–2.4 Ga.     

The Yungul carbonatite dykes associated with the epithermal fluorite deposit at Speewah, Kimberley, Australia: carbon and oxygen isotope constraints on their origin

The Yungul carbonatite dykes at Speewah in the Kimberley region of Western Australia were emplaced along a north-trending splay from the northeast-trending Greenvale Fault located at the western boundary of the Halls Creek Orogen. The Yungul carbonatite dykes intrude a thick composite sill of the Palaeoproterozoic Hart Dolerite (~1,790 Ma), consisting of tholeiitic dolerite and gabbro with its felsic differentiates that form the Yilingbun granophyres and associated granites. The carbonatite dykes consist of massive, calcite carbonatite that host very coarse, pegmatitic veins and pods of calcite, and have largely replaced (carbonatitized) and fenitized the country rock Hart Dolerite suite in a zone up to 150 m wide. Dykes of red-brown siliceous fluidized-breccia and epithermal-textured veins consisting of bladed quartz, adularia and fluorite are closely associated with the carbonatite dykes. The Yungul carbonatites are closely associated with fluorite occurrences with resources currently reported as 6.7 Mt at 24.6% CaF₂. The precise age of the Yungul carbonatite is not known, although it is believed to be post early Cambrian. The total REE content of the Yungul carbonatite is low (174.0–492.8 ppm; La/Yb 2.28–10.74) and thus atypical for calciocarbonatite. Chondrite-normalized REE patterns for the carbonatite are relatively flat compared to average calciocarbonatite, and show small negative Eu anomalies. These unusual geochemical features may have been acquired from the Hart Dolerite suite during emplacement of the carbonatite, a process that involved extensive replacement and fenitization of country rocks. Carbon and oxygen isotope compositions of massive calcite carbonatite and the coarse calcite veins and pods from the carbonatite suggest a deep-seated origin. The C and O isotope compositions show an overall positive correlation that can be attributed to both magmatic and magmatic-hydrothermal processes in their evolution. The magmatic δ¹³C-δ¹⁸O trend is also indicative of crustal contamination and/or low-temperature water/rock exchange. The carbon isotopic compositions have δ¹³C values that range from about ?5.2‰ to ?6.3‰ that support a mantle-derived origin for the Yungul carbonatites and are consistent with earlier conclusions based on whole-rock geochemistry and radiogenic isotopes studies.     

Petrogenesis of the Greenhills Complex,Southland, New Zealand: magmatic differentiation and cumulate formation at the roots of a Permian island-arc volcano

A Permian (~265 Ma) intrusive complex which formed as a magmatic feeder reservoir to an immature island-arc volcano is fortuitously exposed in southern New Zealand. Known as the Greenhills Complex, this intrusion was emplaced at shallow crustal levels and consists of two layered bodies which were later intruded by a variety of dykes. Cumulates, which include dunite, olivine clinopyroxenite, olivine gabbro, and hornblende gabbro-norite, are related products of parent-magma fractionation. Both primary (magmatic) and secondary platinum-group minerals occur within dunite at one locality. Using the composition of cumulus minerals, mafic dykes and melt inclusions, we have determined that the parent magmas of the complex were hydrous, low-K island-arc tholeiites of ankaramitic affinities. Progressive magmatic differentiation of this parent magma generated fractionated melt of high-alumina basalt composition which is now preserved only as dykes which cut the Complex. Field evidence and cumulus mineral profiles reveal that the magma chambers experienced turbulent magmatic conditions during cumulate-rock formation. Recharge of the chambers by primitive magma is likely to have coincided with eruption of residual melt at the surface. Similar processes are inferred to account for volcanic-rock compositions in other parts of this arc terrane and in modern island-arc systems.     

Carbonatite diversity in the Central Andes: the Ayopaya alkaline province,Bolivia

The Ayopaya province in the eastern Andes of Bolivia, 100 km NW of Cochabamba, hosts a Cretaceous alkaline rock series within a Palaeozoic sedimentary sequence. The alkaline rock association comprises nepheline-syenitic/foyaitic to ijolitic intrusions, carbonatite, kimberlite, melilititic, nephelinitic to basanitic dykes and diatremes, and a variety of alkaline dykes. The carbonatites display a wide petrographic and geochemical spectrum. The Cerro Sapo area hosts a small calciocarbonatite intrusion and a multitude of ferrocarbonatitic dykes and lenses in association with a nepheline-syenitic stock. The stock is crosscut by a spectacular REE-Sr-Th-rich sodalite-ankerite-baryte dyke system. The nearby Chiaracke complex represents a magnesiocarbonatite intrusion with no evidence for a relationship to igneous silicate rocks. The magnesiocarbonatite ( REE up to 1.3 wt%) shows strong HREE depletion, i.e. unusually high La/Yb ratios (520–1,500). Calciocarbonatites ( REE up to 0.5 wt%) have a flatter REE distribution pattern (La/Yb 95–160) and higher Nb and Zr contents. The sodalite-ankerite-baryte dyke system shows geochemical enrichment features, particularly in Na, Ba, Cl, Sr, REE, which are similar to the unusual natrocarbonatitic lavas of the recent volcano of Oldoinyo Lengai, Tanzania. The Cerro Sapo complex may be regarded as an intrusive equivalent of natrocarbonatitic volcanism, and provides an example for carbonatite genesis by late-stage crystal fractionation and liquid immiscibility. The magnesiocarbonatite intrusion of Chiaracke, on the other hand, appears to result from a primary carbonatitic mantle melt. Deep seated mantle magmatism/metasomatism is also expressed by the occurrence of a kimberlite dyke. Neodymium and strontium isotope data (_Nd 1.4–5.4, ⁸⁷Sr/⁸⁶ Sr<Bulk Earth) indicate a depleted mantle source for the alkaline magmatism. The magmatism of the Ayopaya region is attributed to failed rifting of western South America during the Mesozoic and represents the only occurrence of carbonatite and kimberlite rocks in the Andes.     

Geological observations in high‐grade mid‐Proterozoic rocks from Else Platform,northern Prince Charles mountains region,east Antarctica

Granulite facies rocks on Else Platform in the northern Prince Charles Mountains, east Antarctica, consist of metasedimentary gneiss extensively intruded by granitic rocks. The dominant rock type is a layered garnetbiotite‐bearing gneiss intercalated with minor garnet‐cordierite‐sillimanite gneiss and calc‐silicate. Voluminous megacrystic granite intruded early during a mid‐Proterozoic (ca 1000 Ma) granulite event, M₁, widely recognized in east Antarctica. Peak metamorphic conditions for M₁ are in the range of 650–750 MPa at ～800°C and were associated with the development of a gneissic foliation, S₁ and steep east‐plunging lineation, L₁. Strain partitioning during progressive non‐coaxial deformation formed large D₂ granulite facies south‐dipping thrusts, with a steep, east‐plunging lineation. In areas of lower D₂ strain, large‐scale upright, steep east‐plunging fold structures formed synchronously with the D₂ high‐strain zones. Voluminous garnet‐bearing leucogneiss intruded at 940 ±20 Ma and was deformed in the D₂ high‐strain zones. Textural relationships in pelitic rocks show that peak‐M2 assemblages formed during increasing temperatures via reactions such as biotite + sillimanite + quartz ± plagioclase = spinel + cordierite + ilmenite + K‐feldspar + melt. In biotite‐absent rocks, re‐equilibration of deformed M₁ garnet‐sillimanite‐ilmenite assemblages occurred through decompressive reactions of the form, garnet + sillimanite + ilmenite = cordierite + spinel + quartz. Pressure/temperature estimates indicate that peak‐M₂ conditions were 500–600 MPa and 700±50°C. At about 500 Ma, north‐trending granitic dykes intruded and were deformed during D₃‐M₃ at probable upper amphibolite facies conditions. Cooling from peak D₃‐M₃ conditions was associated with the formation of narrow greenschist facies shear zones, and the intrusion of pegmatite. Cross‐cutting all features are abundant north‐south trending alkaline mafic dykes that were emplaced over the interval ca 310–145 Ma, reflecting prolonged intrusive activity. Some of the dykes are associated with steeply dipping faults that may be related to basin formation during Permian times and later extension, synchronous with the formation of the Lambert Graben in the Cretaceous.     

Titanochondrodite and titanoclinohumite derived from the upper mantle in the Buell Park Kimberlite,Arizona, USA

Kimberlite from Buell Park, Arizona, which was intruded into Permian sediments about 30 m.y. ago, is characterized by the hydrous silicates titanochondrodite and titanoclinohumite. Titanochondrodite is the first finding in kimberlites. Optical properties, chemical compositions and cell dimensions of these two minerals are determined.Titanochondrodite and titanoclinohumite are considered to crystallize from kimberlite magma at a depth of about 100 km and at 1,000° C, on the basis of kimberlite mineralogy, petrography and high pressure experimental work. Although there is no direct evidence, the importance of these two minerals in peridotite wedges above sinking lithosphere at the continental margins is also discussed.     

http://www.sciencedirect.com/science/article/pii/S1674987115001310

Bayan Obo ore deposit is the largest rare-earth element(REE) resource,and the second largest niobium(Nb) resource in the world.Due to the complicated element/mineral compositions and involving several geological events,the REE enrichment mechanism and genesis of this giant deposit still remains intense debated.The deposit is hosted in the massive dolomite,and nearly one hundred carbonatite dykes occur in the vicinity of the deposit.The carbonatite dykes can be divided into three types from early to late:dolomite,co-existing dolomite-calcite and calcite type,corresponding to different evolutionary stages of carbonatite magmatism based on the REE and trace element data.The latter always has higher REE content.The origin of the ore-hosting dolomite at Bayan Obo has been addressed in various models,ranging from a normal sedimentary carbonate rocks to volcano-sedimentary sequence,and a large carbonatitic intrusion.More geochemical evidences show that the coarse-grained dolomite represents a Mesoproterozoic carbonatite pluton and the fine-grained dolomite resulted from the extensive REE mineralization and modification of the coarse-grained variety.The ore bodies,distributed along an E-W striking belt,occur as large lenses and underwent more intense fluoritization and fenitization.The first episode mineralization is characterized by disseminated mineralization in the dolomite.The second or main-episode is banded and/or massive mineralization,cut by the third episode consisting of aegirinerich veins.Various dating methods gave different mineralization ages at Bayan Obo,resulting in long and hot debates.Compilation of available data suggests that the mineralization is rather variable with two peaks at~1400 and 440 Ma.The early mineralization peak closes in time to the intrusion of the carbonatite dykes.A significant thermal event at ca.440 Ma resulted in the formation of late-stage veins with coarse crystals of REE minerals.Fluids involving in the REE-Nb-Fe mineralization at Bayan Obo might be REE-F-C02-NaCI-H20 system.The presence of REE-carbonates as an abundant solid in the ores shows that the original ore-forming fluids are very rich in REE,and therefore,have the potential to produce economic REE ores at Bayan Obo.the Bayan Obo deposit is a product of mantle-derived carbonatitic magmatism at ca.1400 Ma,which was likely related to the breakup of Columbia.Some remobilization of REE occurred due to subduction of the Palaeo-Asian oceanic plate during the Silurian,forming weak vein-like mineralization.     

Observations on the processes of sedimentary basin formation at the margins of Southern Africa

Three variants of Atlantic-type continental margin border Southern Africa. On the west is a rifted margin with a rift phase no more than 50 m.y. in length (180–130 m.y. ago). Sedimentary basin formation was by upbuilding of a sediment terrace during the rift phase and the 30 m.y. following, with outbuilding of the terrace dominant during the Cainozoic. Little downwarping of the oceanic crust occurred but the continent—ocean transition zone appears to be wide.To the south of South Africa is an extensive sheared margin. Basin formation began here in mid-Triassic times with intermontane deposition. Local increase in lower crustal density appears to have accompanied subsidence. Truncation of the basins occurred 130–2100 m.y. ago and in places detrital influx was trapped behind a marginal fracture ridge. No continental rise sedimentary apron and characteristic deep structure were formed in these places. A ‘welding’ of the continental edge appears to have taken place.East of 30° E a complex continental margin with a protracted rift phase exists. From Triassic to Cretaceous times sedimentary basin formation was controlled by an E-W tensional stress regime resulting in N-S horsts and grabens. This was accompanied by vol-canicity and crustal thinning. Other stress systems may have prevailed during continental break-up in the Cretaceous while today the region is seismically active and the tensional stress assumed to be E-W. Following break-up sedimentary basins in Natal Valley and Mozambique Channel encroached southwards.     

Passive kimberlite intrusion into actively dilating dyke–fracture arrays: evidence from fibrous calcite veins and extensional fracture cleavage

Calcite veins are invariably associated with en-echelon kimberlite dyke–fracture arrays. A detailed microstructural study of veining indicates four vein types. Type I stretched or ataxial veins are defined by high aspect ratio calcite fibers that are crystallographically continuous with calcite of the kimberlite matrix wall rock, by elongated phenocrystic phlogopite with sharp crystal terminations centered on contacts between adjacent calcite fibers and by phenocrystic phlogopite that grows or extends across these veins. Type I vein mineralogy indicates syn-dilational crystallization of vein minerals in local tensional areas within the kimberlite. Vein Types II (stretched to syntaxial elongate-blocky) and III (antitaxial) indicate late crystallization vein mineral growth during subsequent or repeated dilation. Calcite fibers in Type I to Type III veins are orthogonal to the contacts of their host dykes regardless of the orientation of vein margins. Type IV calcite veins, with blocky or mosaic/polycrystalline textures, are attributed to minor post-intrusion extension, which was potentially accompanied by repeated kimberlite intrusion within a given dyke array. Syn-crystallization/syn-intrusion Type I veins and an ubiquitous dyke-parallel fracture cleavage, in a zone up to 4 m on either side of dyke contacts, suggest that en-echelon kimberlite dyke–fracture arrays occupied the approximate center of zones of active dilation within the brittle carapace of the upper crust. Type II and III veins indicate that extension or dilation continued, independently of an occupying kimberlite fluid phase, after initial intrusion. Arrested mobile hydrofracturing, under low differential stress within the upper brittle or seismic carapace of the continental crust, followed by repeated dilation of the dyke–fracture system, is proposed as a mechanism for producing the features observed in this study. The conditions constrained in this study indicate passive dyke intrusion into dilating fracture arrays during crustal extension.     

Evolution of the Mayo Kebbi region as revealed by zircon dating: An early (ca. 740 Ma) Pan-African magmatic arc in southwestern Chad

The Mayo Kebbi region in SW Chad is part of the NNE-SSW trending Neoproterozoic Central African Fold Belt (CAFB) and is made up of three calc-alkaline granitoid suites emplaced into a metavolcanic–metasedimentary sequence. The first suite is represented by mafic to intermediate rocks (gabbro-diorite and metadiorite) emplaced between 737 and 723 Ma during early Pan-African convergence. The second consists of the Mayo Kebbi batholith and includes tonalites, trondhjemites and granodiorites, emplaced during several magmatic pulses between 665 and 640 Ma. The third suite includes porphyritic granodiorite and hypersthene monzodiorite dated at ca. 570 Ma. The Mayo Kebbi domain extends southward into Cameroon and is interpreted as a middle Neoproterozoic arc stabilized at ca. 650 Ma. This study also revealed a diachronous evolution between Mayo Kebbi and western Cameroon (e.g., the Poli region). The overall evolution of this part of the CAFB is interpreted as the result of successive development of magmatic arcs, since ca. 740 Ma, and tectonic collage of three different domains (Adamawa-Yade, Mayo Kebbi, and West Cameroon) which, after suturing, were intruded by post-collisional granitoids (<600 Ma).     

Shoshonitic lamprophyre dykes and their relation to mesothermal Au---Sb veins at Hillgrove, New South Wales, Australia

The Hillgrove mineral field, in the southern part of the New England Orogen of northeastern New South Wales, Australia, contains numerous mesothermal Au---Sb vein systems. Calc-alkaline (shoshonitic) lamprophyre (CAL) dykes are also associated with mineralisation with dilational lode structures acting as conduits for dyke intrusion, which has occurred before and after major quartz-stibnite veining. Dykes include minette and vogesite compositions and were emplaced in the late Permian (247–255 Ma), at the same time as regionally extensive I-type magmatism in the New England Orogen. Least-altered dykes are enriched in Mg, K, Ba, Rb, Sr, Zr, Th, Cr and Ni relative to I-type intrusives although chemical affinities are evident between lamprophyres and the more mafic members of the high-K Moonbi Plutonic Suite.

Hillgrove lamprophyres are commonly enriched in Sb, As, Hg, Au, W and Bi with respect to average CAL compositions. Evidence indicates this is most likely due to contamination of magma during intrusion through mineralised structures, rather than a primary magmatic feature. Partially resorbed xenocrystic stibnite occurs in dykes which have intruded lode structures, probably facilitated by the low melting point of stibnite (550°C) and its incorporation into the magma. Carbon and oxygen isotopic data from carbonates in least-altered, post-lode lamprophyres are indistinguishable from carbonate in altered dykes and veins, implying that hydrothermal interaction continued after dyke intrusion. Although it is unlikely that lamprophyre dykes have been a direct source for mineralisation at Hillgrove, the close temporal and spatial relation of dykes, mesothermal Au---Sb veins and I-type intrusions are interpreted to be manifestations of the post-collisional setting and influx of mantle-derived heat and partial melts into the New England Orogen during the late Permian.     

论“牛岚构造体系”特征及其对蒙阴金伯利岩带的控制

鲁西地区作为华北克拉通的一部分,自古元古代早期（约2400Ma）二长花岗质岩石侵位以后至晚古生代（约250Ma）,一直处于板内稳定地块状态,在这漫长的2150Ma年里仅形成了两期脉岩,即四堡期侵位的基性辉绿岩（牛岚单元）与中晚奥陶世侵位的超基性金伯利岩（常马庄单元）。经对控制辉绿岩侵位的构造特征进行研究发现,该构造体系不仅控制了鲁西辉绿岩的侵位,还控制了金伯利岩的侵位。在此基础上,对蒙阴金伯利岩带的控制规律进行了分析,并对金伯利岩带向南延伸的区域进行了初步的预测。