Mg isotopic heterogeneity,Al‐Mg isochrons,and canonical 26Al/27Al in the early solar system

There is variability in the Mg isotopic composition that is a reflection of the widespread heterogeneity in the isotopic composition of the elements in the solar system at approximately 100 ppm. Measurements on a single calcium‐aluminum‐rich inclusion (CAI) gave a good correlation of ²⁶Mg/²⁴Mg with ²⁷Al/²⁴Mg, yielding an isochron corresponding to an initial (²⁶Al/²⁷Al)_o = (5.27 ± 0.18) × 10^?5 and an initial (²⁶Mg/²⁴Mg)_o = ?0.127 ± 0.032‰ relative to the standard. This isochron is parallel to that obtained by Jacobsen et al. (2008) , but is distinctively offset. This demonstrates that there are different initial Mg isotopic compositions in different samples with the same ²⁶Al/²⁷Al. No inference about uniformity/heterogeneity of ²⁶Al/²⁷Al on a macro scale can be based on the initial (²⁶Mg/²⁴Mg)_o values. Different values of ²⁶Al/²⁷Al for samples representing the same point in time would prove heterogeneity of ²⁶Al/²⁷Al. The important issue is whether the bulk solar inventory of ²⁶Al/²⁷Al was approximately 5 × 10^?5 at some point in the early solar system. We discuss ultra refractory phases of solar type oxygen isotope composition with ²⁶Al/²⁷Al from approximately 5 × 10^?5 to below 0.2 × 10^?5. We argue that the real issues are: intrinsic heterogeneity in the parent cloud; mechanism and timing for the later production of ¹⁶O‐poor material; and the relationship to earlier formed ¹⁶O‐rich material in the disk. ²⁶Al‐free refractories can be produced at a later time by late infall, if there is an adequate heat source, or from original heterogeneities in the placental molecular cloud from which the solar system formed.     

36Cl, 26Al,and O isotopes in an Allende type B2 CAI: Implications for multiple secondary alteration events in the early solar system

Abstract— We measured ³⁶Cl‐³⁶S and ²⁶Al‐²⁶Mg systematics and O isotopes of secondary phases in a moderately altered type B2 CAI (CAI#2) from the Allende CV3 chondrite. CAI#2 has two distinct alteration domains: the anorthite‐grossular (An‐Grs) domain that mostly consists of anorthite and grossular, and the Na‐rich domain that mostly consists of sodalite, anorthite, and Fe‐bearing phases. Large ³⁶S excesses (up to ～400‰) corresponding to an initial ³⁶Cl/³⁵Cl ratio of (1.4 ± 0.3) × 10^?6 were observed in sodalite of the Na‐rich domain, but no resolvable 26Mg excesses were observed in anorthite and sodalite of the Na‐rich domain (the initial ²⁶Al/²⁷Al ratio < 4.4 × 10^?7). If we assume that the ³⁶Cl‐³⁶S and the ²⁶Al‐²⁶Mg systematics were closed simultaneously, the ³⁶Cl/³⁵Cl ratio would have to be on the order of ～10^?2 when CAIs were formed. In contrast to sodalite in Na‐rich domain, significant ²⁶Mg excesses (up to ～35‰) corresponding to an initial ²⁶Al/²⁷Al ratio of (1.2 ± 0.2) × 10^?5 were identified in anorthite of the An‐Grs domain. The ²⁶Al‐²⁶Mg systematics of secondary phases in CAI#2 suggest that CAIs experienced multiple alteration events. Some of the alteration processes occurred while ³⁶Cl (half‐life is 0.3 Myr) and ²⁶Al (half‐life is 0.72 Myr) were still alive, whereas others took place much later. Assuming that ²⁶Al was homogeneously distributed in the solar nebula, our study implies that alteration of CAIs occurred as early as within 1.5 Myr of CAI formation and as late as 5.7 Myr after.     

Light noble gases and cosmogenic radionuclides in Estherville,Budulan, and other mesosiderites: Implications for exposure histories and production rates

Abstract— We report measurements of ²⁶AI, ¹⁰Be, ⁴¹Ca, and ³⁶Cl in the silicate and metal phases of 11 mesosiderites, including several specimens each of Budulan and Estherville, of the brecciated meteorite Bencubbin, and of the iron meteorite Udei Station. Average production rate ratios (atom/atom) for metal phase samples from Estherville and Budulan are ²⁶Al/¹⁰Be = 0.77 ± 0.02; ³⁶Cl/¹⁰Be = 5.3 ± 0.2. For a larger set of meteorites that includes iron meteorites and other mesosiderites, we find ²⁶Al/¹⁰Be = 0.72 ± 0.01 and ³⁶Cl/¹⁰Be = 4.5 ± 0.2. The average ⁴¹Ca/³⁶Cl production rate ratio is 1.10 ± 0.04 for metal separates from Estherville and four small iron falls. The ⁴¹Ca activities in dpm/(kg Ca) of various silicate separates from Budulan and Estherville span nearly a factor of 4, from <400 to >1600, indicating preatmospheric radii of >30 cm. After allowance for composition, the activities of ²⁶Al and ¹⁰Be (dpm/kg silicate) are similar to values measured in most ordinary chondrites and appear to depend only weakly on bulk Fe content. Unless shielding effects are larger than suggested by the ³⁶Cl and ⁴¹Ca activities of the metal phases, matrix effects are unimportant for ¹⁰Be and minor for ²⁶Al. Noble gas concentrations and isotopic abundances are reported for samples of Barea, Emery, Mincy, Morristown, and Marjalahti. New estimates of ³⁶Cl/³⁶Ar exposure ages for the metal phases agree well with published values. Neon‐21 production rates for mesosiderite silicates calculated from these ages and from measured ²¹Ne contents are consistently higher than predicted for L chondrites despite the fact that the mesosiderite silicates have lower Mg contents than L chondrites. We suggest that the elevation of the ²¹Ne production rate in mesosiderite silicates reflects a “matrix effect,” that is, the influence of the higher Fe content of mesosiderites, which acts to enhance the flux of low‐energy secondary particles and hence the ²¹Ne production from Mg. As ¹⁰Be production is relatively insensitive to this matrix effect, ¹⁰Be/²¹Ne ages give erroneously low production rates and high exposure ages. By coincidence, standard ²²Ne/²¹Ne based “shielding” corrections give fairly reliable ²¹Ne production rates in the mesosiderite silicates.     

Cross-sections for the (4He, 3H) stripping reaction on Fe,Al, C and glass targets at an energy of 120 MeV

Fe, Al, C and Glass targets have been irradiated with 120 MeV helium ions. The cross sections for the stripping reaction (⁴He, ³H) on these target nuclei have been determined, with nuclear emulsions, as 85 ± 30, 65 ± 20, 38 ± 15 and 41 ± 15 mb, respectively.     

Search for extinct aluminum‐26 and titanium‐44 in nanodiamonds from the Allende CV3 and Murchison CM2 meteorites

Abstract– We report Mg‐Al and Ca‐Ti isotopic data for meteoritic nanodiamonds separated from the Allende CV3 and Murchison CM2 meteorites. The goal of this study was to search for excesses in ²⁶Mg and ⁴⁴Ca, which can be attributed to the in situ decay of radioactive and now extinct ²⁶Al and ⁴⁴Ti, respectively. Previous work on presolar SiC and graphite had shown that ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti ratios in presolar grains can be used to discriminate between different types of stellar sources. Aluminum and Ti concentrations are low in the meteoritic nanodiamonds of this study. Murchison nanodiamonds have higher Al and Ti concentrations than the Allende nanodiamonds. This can be attributed to contamination and the presence of presolar SiC in the Murchison nanodiamond samples. ²⁶Mg/²⁴Mg and ⁴⁴Ca/⁴⁰Ca ratios are close to normal in Allende nanodiamonds with upper limits on the initial ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti ratios of approximately 1 × 10^?3. These ratios are factors of 10–1000 and, respectively, 1–1000 lower than those of presolar SiC and graphite grains from supernovae. The ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti data for nanodiamonds are compatible with an asymptotic giant branch star or solar system origin, but not with a supernova origin of a major fraction of meteoritic nanodiamonds. The latter possibility cannot be excluded, though, as the diamond separates may contain significant amounts of contaminating Al and Ti, which would lower the inferred ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti ratios considerably.     

Cosmic‐ray exposure history of two Frontier Mountain H‐chondrite showers from spallation and neutron‐capture products

Abstract— We measured the concentrations of ¹⁰Be, ²⁶Al, ³⁶Cl, ⁴¹Ca and ¹⁴C in the metal and/or stone fractions of 27 Antarctic chondrites from Frontier Mountain (FRO), including two large H‐chondrite showers. To estimate the pre‐atmospheric size of the two showers, we determined the contribution of neutron‐capture produced ³⁶Cl (half‐life = 3.01 times 10⁵ years) and ⁴¹Ca (1.04 times 10⁵ years) in the stone fraction. The measured activities of neutron‐capture ³⁶Cl and ⁴¹Ca, as well as spallation produced ¹⁰Be and ²⁶Al, were compared with Monte Carlo‐based model calculations. The largest shower, FRO 90174, includes eight fragments with an average terrestrial age of (100 ± 30) × 10³ years; the neutron‐capture saturation activities extend to 27 dpm/kg stone for ³⁶Cl and 19 dpm/kg stone for ⁴¹Ca. The concentrations of spallation produced ¹⁰Be, ²⁶Al and ³⁶Cl constrain the radius (R) to 80–100 cm, while the neutron‐capture ⁴¹Ca activities indicate that the samples originated from the outer 25 cm. With a pre‐atmospheric radius of 80–100 cm, FRO 90174 is among the largest of the Antarctic stony meteorites. The large pre‐atmospheric size supports our hypothesis that at least 50 of the ～150 classified H5/H6‐chondrites from the Frontier Mountain stranding area belong to this single fall; this hypothesis does not entirely account for the high H/L ratio at Frontier Mountain. The smaller shower, FRO 90001, includes four fragments with an average terrestrial age of (40 ± 10) × 10³ years; they contain small contributions of neutron‐capture ³⁶Cl, but no excess of ⁴¹Ca. FRO 90001 experienced a complex exposure history with high shielding conditions in the first stage (150 < R < 300 cm) and much lower shielding in the second stage (R < 30 cm), the latter starting ～1.0 million years (Ma) ago. Based on the measured ¹⁰Be/²¹Ne and ²⁶Al/²¹Ne ratios, the cosmic‐ray exposure ages of the two showers are 7.2 ± 0.5 Ma for FRO 90174 and 8 ± 1 Ma for FRO 90001. These ages coincide with the well‐established H‐chondrite peak and corroborate the observation that the exposure age distribution of FRO H‐chondrites is similar to that of non‐Antarctic falls. In addition, we found that corrections for neutron‐capture ³⁶Ar (from decay of ³⁶Cl) result in concordant ²¹Ne and ³⁸Ar exposure ages.     

The plausible source(s) of 26Al in the early solar system: A massive star or the X‐wind irradiation scenario?

Abstract— A quantitative analysis is presented for the irradiation contributions of the short‐lived nuclides, specifically ²⁶Al, by the X‐wind scenario in the early solar system. The analysis is based on the comprehensive numerical simulations of the scenario that involves thermal processing of protoCAIs during the decades long X‐wind cycle. It would be difficult to explain the canonical value of ²⁶Al/²⁷Al in Ca‐Al‐rich inclusions on the basis of its inferred irradiation yields. Hence, the bulk inventory of ²⁶Al in the early solar system was not produced by the X‐wind scenario. We suggest the predominant occurrence of gradual flares compared to impulsive flares in the early solar system as in the case of the modern solar flares. One tenth of the bulk ²⁶Al was only produced by irradiation in case the entire solar inventory of ¹⁰Be was produced by local irradiation. The bulk ²⁶Al inventory along with ⁶⁰Fe was probably synthesized by a massive star. We present a qualitative model of the astrophysical settings for the formation of the solar system on the basis of a survey of the presently active star forming regions. We hypothesize that the formation of the solar system could have occurred almost contemporaneously with the formation of the massive star within a single stellar cluster. As the massive star eventually exploded as supernova Ib/c subsequent to Wolf‐Rayet stages, the short‐lived nuclides were probably injected into the solar proto‐planetary disc. The dynamically evolving stellar cluster eventually dispersed within the initial ?10 million years prior to the major planetary formation episodes.     

Whole‐rock 26Al‐26Mg systematics of amoeboid olivine aggregates from the oxidized CV3 carbonaceous chondrite Allende

Abstract– We report on mineralogy, petrography, and whole‐rock ²⁶Al‐²⁶Mg systematics of eight amoeboid olivine aggregates (AOAs) from the oxidized CV chondrite Allende. The AOAs consist of forsteritic olivine, opaque nodules, and variable amounts of Ca,Al‐rich inclusions (CAIs) of different types, and show evidence for alteration to varying degrees. Melilite and anorthite are replaced by nepheline, sodalite, and grossular; spinel is enriched in FeO; opaque nodules are replaced by Fe,Ni‐sulfides, ferroan olivine and Ca,Fe‐rich pyroxenes; forsteritic olivine is enriched in FeO and often overgrown by ferroan olivine. The AOAs are surrounded by fine‐grained, matrix‐like rims composed mainly of ferroan olivine and by a discontinuous layer of Ca,Fe‐rich silicates. These observations indicate that AOAs experienced in situ elemental open‐system iron‐alkali‐halogen metasomatic alteration during which Fe, Na, Cl, and Si were introduced, whereas Ca was removed from AOAs and used to form the Ca,Fe‐rich silicate rims around AOAs. The whole‐rock ²⁶Al‐²⁶Mg systematics of the Allende AOAs plot above the isochron of the whole‐rock Allende CAIs with a slope of (5.23 ± 0.13) × 10^?5 reported by Jacobsen et al. (2008) . In contrast, whole‐rock ²⁶Al‐²⁶Mg isotope systematics of CAIs and AOAs from the reduced CV chondrite Efremovka define a single isochron with a slope of (5.25± 0.01) × 10^?5 ( Larsen et al. 2011 ). We infer that the excesses in ²⁶Mg* present in Allende AOAs are due to their late‐stage open‐system metasomatic alteration. Thus, the ²⁶Al‐²⁶Mg isotope systematics of Allende CAIs and AOAs are disturbed by parent body alteration processes, and may not be suitable for high‐precision chronology of the early solar system events and processes.     

Spatial heterogeneity of 26Al/27Al and stable oxygen isotopes in the solar nebula

Abstract— The degree of isotopic spatial heterogeneity in the solar nebula has long been a puzzle, with different isotopic systems implying either large‐scale initial spatial homogeneity (e.g., ²⁶Al chronometry) or a significant amount of preserved heterogeneity (e.g., ratios of the three stable oxygen isotopes, ¹⁶O, ¹⁷O, and ¹⁸O). We show here that in a marginally gravitationally unstable (MGU) solar nebula, the efficiency of large‐scale mixing and transport is sufficient to spatially homogenize an initially highly spatially heterogeneous nebula to dispersions of ?10% about the mean value of ²⁶Al/²⁷Al on time scales of thousands of years. A similar dispersion would be expected for ¹⁷O/¹⁶O and ¹⁸O/¹⁶O ratios produced by ultraviolet photolysis of self‐shielded molecular CO gas at the surface of the outer solar nebula. In addition to preserving a chronological interpretation of initial ²⁶Al/²⁷Al ratios and the self‐shielding explanation for the oxygen isotope ratios, these solar nebula models offer a self‐consistent environment for achieving large‐scale mixing and transport of thermally annealed dust grains, shock‐wave processing of chondrules and refractory inclusions, and giant planet formation.     

Heterogeneous distribution of 26Al at the birth of the solar system: Evidence from refractory grains and inclusions

We review recent results on O‐ and Mg‐isotope compositions of refractory grains (corundum, hibonite) and calcium, aluminum‐rich inclusions (CAIs) from unequilibrated ordinary and carbonaceous chondrites. We show that these refractory objects originated in the presence of nebular gas enriched in ¹⁶O to varying degrees relative to the standard mean ocean water value: the Δ¹⁷O_SMOW value ranges from approximately ?16‰ to ?35‰, and recorded heterogeneous distribution of ²⁶Al in their formation region: the inferred (²⁶Al/²⁷Al)₀ ranges from approximately 6.5 × 10^?5 to <2 × 10^?6. There is no correlation between O‐ and Mg‐isotope compositions of the refractory objects: ²⁶Al‐rich and ²⁶Al‐poor refractory objects have similar O‐isotope compositions. We suggest that ²⁶Al was injected into the ²⁶Al‐poor collapsing protosolar molecular cloud core, possibly by a wind from a neighboring massive star, and was later homogenized in the protoplanetary disk by radial mixing, possibly at the canonical value of ²⁶Al/²⁷Al ratio (approximately 5 × 10^?5). The ²⁶Al‐rich and ²⁶Al‐poor refractory grains and inclusions represent different generations of refractory objects, which formed prior to and during the injection and homogenization of ²⁶Al. Thus, the duration of formation of refractory grains and CAIs cannot be inferred from their ²⁶Al‐²⁶Mg systematics, and the canonical (²⁶Al/²⁷Al)₀ does not represent the initial abundance of ²⁶Al in the solar system; instead, it may or may not represent the average abundance of ²⁶Al in the fully formed disk. The latter depends on the formation time of CAIs with the canonical ²⁶Al/²⁷Al ratio relative to the timing of complete delivery of stellar ²⁶Al to the solar system, and the degree of its subsequent homogenization in the disk. The injection of material containing ²⁶Al resulted in no observable changes in O‐isotope composition of the solar system. Instead, the variations in O‐isotope compositions between individual CAIs indicate that O‐isotope composition of the CAI‐forming region varied, because of coexisting of ¹⁶O‐rich and ¹⁶O‐poor nebular reservoirs (gaseous and/or solid) at the birth of the solar system, or because of rapid changes in the O‐isotope compositions of these reservoirs with time, e.g., due to CO self‐shielding in the disk.     

Nucleosynthesis of26Al in the early solar system and in cosmic rays

The nucleus²⁶Al(^1/2 = 7.4 × 10⁵ yr) has long been considered as a possible heat source during the formation of the solar system. Recent experimental work has found no evidence for²⁶Al at the time of final solidification of the meteorites. Due to the short half-life these measurements do not rule out the possibility that²⁶Al was a significant heat source a few million years prior to final solidification. For²⁶Al to be an effective heat source in the early solar system it is necessary for the ratio²⁶Al/Si to be 2×10^–7 at the time of a solidification. The nucleosynthetic yields of²⁶Al by silicon burning, carbon burning, and spallation are discussed. It is shown that²⁶Al can be synthesized in carbon and/or silicon-burning supernovae. However, time scales in the early solar system make it more likely that²⁶Al, if present in planets, was synthesized by a proton irradiation in the early solar system. An integrated proton flux >4×10¹⁸ cm^–2 is shown to be necessary in order for²⁶Al to be a significant heat source. No conclusive evidence has been observed for an irradiation of this magnitude. Therefore, unless such evidence is found, it should be assumed that²⁶Alwas not involved in the formation of the solar system. In addition, the production of²⁶Al in cosmic rays is discussed and it is shown that either resolution of the Al isotopes in the cosmic rays or accurate measurements of the variation with energy of the cosmic ray abundance ratios Al/Si and Mg/Si can be used to determine the age of the cosmic rays, _C.R.. Current abundance data are extremely uncertain; however, the trend tends toward values of _C.R. 10⁶ yr.Supported in part by the National Science Foundation [GP-19887, GP-28027, GP-27304].     

Noble gases and cosmogenic radionuclides in the Gold Basin L4 chondrite shower: Thermal history,exposure history,and pre‐atmospheric size

Abstract— We measured the concentrations of the cosmogenic radionuclides ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca in the stone and metal fractions of 15 fragments of the Gold Basin L4 chondrite shower, as well as noble gases in 18 Gold Basin fragments. A comparison of ¹⁰Be, ²⁶Al, and ⁴¹Ca concentrations with calculated production rates from two different models indicates that the Gold Basin samples came from depths of about 10 cm to more than 150 cm in an object with a radius of 3–5 m. As was predicted by recent model calculations, the noble gases show a reversal of the ²²Ne/²¹Ne ratio at very high shielding. The ²¹Ne/¹⁰Be and ²¹Ne/²⁶Al ratios in most samples are constant and correspond to a 4π exposure age of 18 ± 2 Myr. However, three Gold Basin samples show a 30–120% excess of ²¹Ne implying that they were previously exposed close to the surface of the parent body, whereas the other samples were buried several meters deeper. Concentrations of neutron‐capture ³⁶Ar in most samples are consistent with measured concentrations of neutron‐capture ³⁶Cl and an exposure age of 18 Myr. Large excesses of neutron‐capture ³⁶Ar were found in those samples with an excess of ²¹Ne, providing additional evidence of a first‐stage exposure on the parent body. The excess of spallation‐produced ²¹Ne and neutron‐capture‐produced ³⁶Ar in these samples indicate a first‐stage exposure of 35–150 Myr on the parent body. The radiogenic ⁴He and ⁴⁰Ar concentrations indicate a major impact on the parent body between 300 and 400 Myr ago, which must have preceded the impacts that brought the Gold Basin meteoroid to the surface of the parent body and then expelled it from the parent body 18 Myr ago.     

Numerical simulations of the production of extinct short‐lived nuclides by magnetic flaring in the early solar system

Abstract Using the X‐ray flare observations of low‐mass protostars, we developed numerical simulations of thermal processing and irradiation of protoCAIs in the magnetic reconnection ring within the X‐wind formulation. Observed X‐ray flare luminosities have been used to model various simulation flare characteristics. Several approximations have been made regarding the thermal evolution that involve condensation, evaporation, and coagulation of protoCAIs. Ensembles of refractory cores with ferromagnesian mantles were evolved for irradiation production of the short‐lived nuclides ⁷Be, ¹⁰Be, ⁴¹Ca, ³⁶Cl, ²⁶Al, and ⁵³Mn. Three distinct grain‐size distributions of protoCAIs with refractory cores in the ranges of 32μ m‐20 mm, 125 μ m‐16 mm, and 500 μ m‐13 mm were thermally evolved for irradiation. The latter two size distributions were found to result in the accumulation of protoCAIs in the reconnection ring during an X‐wind cycle, and hence can account for the total inventory of ²⁶Al in the early solar system. The canonical value of ?5 × 10^‐5 for ²⁶Al/²⁷ Al can be inferred from the impulsive flare simulations by a suitable choice of simulation parameters. However, in most of the remaining simulations, the irradiation of protoCAIs by superflare(s) with Lx > 10³² ergs s^‐1 subsequent to their thermal processing in the reconnection ring would be required to explain the experimental abundances of the short‐lived nuclides. These superflares have never been reliably observed in young stellar objects. If they are real, they would be extremely rare. The paucity of these superflares could impose stringent constraints on the validity of the X‐wind irradiation scenario as the source of the short‐lived nuclides.     

Short‐lived radioactivity in the early solar system: The Super‐AGB star hypothesis

Abstract– The composition of the most primitive solar system condensates, such as calcium‐aluminum‐rich inclusions (CAIs) and micron‐sized corundum grains, show that short‐lived radionuclides (SLR), e.g., ²⁶Al, were present in the early solar system. Their abundances require a local or stellar origin, which, however, is far from being understood. We present for the first time the abundances of several SLR up to ⁶⁰Fe predicted from stars with initial mass in the range approximately 7–11 M_⊙. These stars evolve through core H, He, and C burning. After core C burning they go through a “Super”‐asymptotic giant branch (Super‐AGB) phase, with the H and He shells activated alternately, episodic thermal pulses in the He shell, a very hot temperature at the base of the convective envelope (approximately 10⁸ K), and strong stellar winds driving the H‐rich envelope into the surrounding interstellar medium. The final remnants of the evolution of Super‐AGB stars are mostly O–Ne white dwarfs. Our Super‐AGB models produce ²⁶Al/²⁷Al yield ratios approximately 0.02–0.26. These models can account for the canonical value of the ²⁶Al/²⁷Al ratio using dilutions with the solar nebula of the order of 1 part of Super‐AGB mass per several 10² to several 10³ of solar nebula mass, resulting in associated changes in the O‐isotope composition in the range Δ¹⁷O from 3 to 20‰. This is in agreement with observations of the O isotopic ratios in primitive solar system condensates, which do not carry the signature of a stellar polluter. The radionuclides ⁴¹Ca and ⁶⁰Fe are produced by neutron captures in Super‐AGB stars and their meteoritic abundances are also matched by some of our models, depending on the nuclear and stellar physics uncertainties as well as the meteoritic experimental data. We also expect and are currently investigating Super‐AGB production of SLR heavier than iron, such as ¹⁰⁷Pd.     

Correlation between relative ages inferred from 26Al and bulk compositions of ferromagnesian chondrules in least equilibrated ordinary chondrites

Abstract— We have studied the relationship between bulk chemical compositions and relative formation ages inferred from the initial ²⁶Al/²⁷Al ratios for sixteen ferromagnesian chondrules in least equilibrated ordinary chondrites, Semarkona (LL3.0) and Bishunpur (LL3.1). The initial ²⁶Al/²⁷Al ratios of these chondrules were obtained by Kita et al. (2000) and Mostefaoui et al. (2002), corresponding to relative ages from 0.7 ± 0.2 to 2.4 ?0.4/+0.7 Myr after calcium‐aluminum‐rich inclusions (CAIs), by assuming a homogeneous distribution of ²⁶Al in the early solar system. The measured bulk compositions of the chondrules cover the compositional range of ferromagnesian chondrules reported in the literature and, thus, the chondrules in this study are regarded as representatives of ferromagnesian chondrules. The relative ages of the chondrules appear to correlate with bulk abundances of Si and the volatile elements (Na, K, Mn, and Cr), but there seems to exist no correlation of relative ages neither with Fe nor with refractory elements. Younger chondrules tend to be richer in Si and volatile elements. Our result supports the result of Mostefaoui et al. (2002) who suggested that pyroxene‐rich chondrules are younger than olivine‐rich ones. The correlation provides an important constraint on chondrule formation in the early solar system. It is explained by chondrule formation in an open system, where silicon and volatile elements evaporated from chondrule melts during chondrule formation and recondensed as chondrule precursors of the next generation.     

The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (II) Noble gases and cosmogenic radionuclides

Abstract– We measured cosmogenic radionuclides and noble gases in the L3–6 chondrite breccia Northwest Africa (NWA) 869, one of the largest meteorite finds from the Sahara. Concentrations of ¹⁰Be, ²⁶Al, and ³⁶Cl in stone and metal fractions of six fragments of NWA 869 indicate a preatmospheric radius of 2.0–2.5 m. The ¹⁴C and ¹⁰Be concentrations in three fragments yield a terrestrial age of 4.4 ± 0.7 kyr, whereas two fragments show evidence for a recent change in shielding, most likely due to a recent impact on the NWA meteoroid, approximately 10⁵ yr ago, that excavated material up to approximately 80 cm deep and exposed previously shielded material to higher cosmic‐ray fluxes. This scenario is supported by the low cosmogenic ³He/²¹Ne ratios in these two samples, indicating recent loss of cosmogenic ³He. Most NWA samples, except for clasts of petrologic type 4–6, contain significant amounts of solar Ne and Ar, but are virtually free of solar helium, judging from the trapped ⁴He/²⁰Ne ratio of approximately 7. Trapped planetary‐type Kr and Xe are most clearly present in the bulk and matrix samples, where abundances of ¹²⁹Xe from decay of now extinct ¹²⁹I are highest. Cosmogenic ²¹Ne varies between 0.55 and 1.92 × 10^?8 cm³ STP g^?1, with no apparent relationship between cosmogenic and solar Ne contents. Low cosmogenic (²²Ne/²¹Ne)_c ratios in solar gas free specimens are consistent with irradiation in a large body. Combined ¹⁰Be and ²¹Ne concentrations indicate that NWA 869 had a 4π cosmic‐ray exposure (CRE) age of 5 ± 1 Myr, whereas elevated ²¹Ne concentrations in several clasts and bulk samples indicate a previous CRE of 10–30 Myr on the parent body, most probably as individual components in a regolith. Unlike many other large chondrites, NWA 869 does not show clear evidence of CRE as a large boulder near the surface of its parent body. Radiogenic ⁴He concentrations in most NWA 869 samples indicate a major outgassing event approximately 2.8 Gyr ago that may have also resulted in loss of solar helium.     

Exposure history and terrestrial ages of ordinary chondrites from the Dar al Gani region,Libya

Abstract— We measured the concentrations of noble gases in 32 ordinary chondrites from the Dar al Gani (DaG) region, Libya, as well as concentrations of the cosmogenic radionuclides ¹⁴C, ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca in 18 of these samples. Although the trapped noble gases in five DaG samples show ratios typical of solar or planetary gases, in all other DaG samples, they are dominated by atmospheric contamination, which increases with the degree of weathering. Cosmic ray exposure (CRE) ages of DaG chondrites range from ?1 Myr to 53 Myr. The CRE age distribution of 10 DaG L chondrites shows a cluster around 40 Myr due to four members of a large L6 chondrite shower. The CRE age distribution of 19 DaG H chondrites shows only three ages coinciding with the main H chondrite peak at ?7 Myr, while seven ages are <5 Myr. Two of these H chondrites with short CRE ages (DaG 904 and 908) show evidence of a complex exposure history. Five of the H chondrites show evidence of high shielding conditions, including low ²²Ne/²¹Ne ratios and large contributions of neutron‐capture ³⁶Cl and ⁴¹Ca. These samples represent fragments of two or more large pre‐atmospheric objects, which supports the hypothesis that the high H/L chondrite ratio at DaG is due to one or more large unrecognized showers. The ¹⁴C concentrations correspond to terrestrial ages <35 kyr, similar to terrestrial ages of chondrites from other regions in the Sahara but younger than two DaG achondrites. Despite the loss of cosmogenic ³⁶Cl and ⁴¹Ca during oxidation of metal and troilite, concentrations of ³⁶Cl and ⁴¹Ca in the silicates are also consistent with ¹⁴C ages <35 kyr. The only exception is DaG 343 (H4), which has a ⁴¹Ca terrestrial age of 150 ± 40 kyr. This old age shows that not only iron meteorites and achondrites but also chondrites can survive the hot desert environment for more than 50 kyr. A possible explanation is that older meteorites were covered by soils during wetter periods and were recently exhumed by removal of these soils due to deflation during more arid periods, such as the current one, which started ?3000 years ago. Finally, based on the ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne systematics in 16 DaG meteorites, we derived more reliable estimates of the ¹⁰Be/²¹Ne production rate ratio, which seems more sensitive to shielding than was predicted by the semi‐empirical model of Graf et al. (1990) but less sensitive than was predicted by the purely physical model of Leya et al. (2000).     

Cosmic‐ray exposure history of the Norton County enstatite achondrite

Abstract– We report measurements of cosmogenic nuclides in up to 11 bulk samples from various depths in Norton County. The activities of ³⁶Cl, ⁴¹Ca, ²⁶Al, and ¹⁰Be were measured by accelerator mass spectrometry; the concentrations of the stable isotopes of He, Ne, Ar, and Sm were measured by electron and thermal ionization mass spectrometry, respectively. Production rates for the nuclides were modeled using the LAHET and the Monte Carlo N‐Particle codes. Assuming a one‐stage irradiation of a meteoroid with a pre‐atmospheric radius of approximately 50 cm, the model satisfactorily reproduces the depth profiles of ¹⁰Be, ²⁶Al, and ⁵³Mn (<6%) but overestimates the ⁴¹Ca concentrations by about 20%. ³He, ²¹Ne, and ²⁶Al data give a one‐stage cosmic‐ray exposure (CRE) age of 115 Ma. Argon‐36 released at intermediate temperatures, ³⁶Ar_n, is attributed to production by thermal neutrons. From the values of ³⁶Ar_n, an assumed average Cl concentration of 4 ppm, and a CRE age of 115 Ma, we estimate thermal neutron fluences of 1–4 × 10¹⁶ neutrons cm^?2. We infer comparable values from ε¹⁴⁹Sm and ε¹⁵⁰Sm. Values calculated from ⁴¹Ca and a CRE age of 115 Ma, 0.2–1.4 × 10¹⁶ neutrons cm^?2, are lower by a factor of approximately 2.5, indicating that nearly half of the ¹⁴⁹Sm captures occurred earlier. One possible irradiation history places the center of proto‐Norton County at a depth of 88 cm in a large body for 140 Ma prior to its liberation as a meteoroid with a radius of 50 cm and further CRE for 100 Ma.     

Irradiation phenomena in young solar-type stars and the early solar system: X-ray observations and γ-ray constraints

The high levels of X-ray flaring activity observed in young stars and protostars suggest correspondingly high levels of low-energy particle irradiation of their circumstellar disks, and hence of early solar system material like meteorites. We first briefly review the latest X-ray observational results obtained by Chandra and XMM-Newton on two ‘typical’ star-forming regions, Orion and ρ Ophiuchi. We then discuss a new ‘accretion–ejection–irradiation–transport’ model for young stars which, when scaled to the X-ray fluxes, accounts simultaneously for four extinct radioactivity ratios, in particular the purely spallogenic ¹⁰Be/⁹Be ratio, and the ²⁶Al/²⁷Al ratio. We point out the importance of the environment in which nearby star formation is taking place today, namely the Gould Belt, and the possible connection between Comptel detections of ²⁶Al γ-ray line emission from these regions, and new constraints on the origin of the solar system.