Distinction between amorphous and healed planar deformation features in shocked quartz using composite color scanning electron microscope cathodoluminescence (SEM‐CL) imaging

Planar deformation features (PDFs) in quartz are one of the most reliable and most widely used forms of evidence for hypervelocity impact. PDFs can be identified in scanning electron microscope cathodoluminescence (SEM‐CL) images, but not all PDFs show the same CL behavior: there are nonluminescent and red luminescent PDFs. This study aims to explain the origin of the different CL emissions in PDFs. Focused ion beam (FIB) thin foils were prepared of specific sample locations selected in composite color SEM‐CL images and were analyzed in a transmission electron microscope (TEM). The FIB preparation technique allowed a direct, often one‐to‐one correlation between the CL images and the defect structure observed in TEM. This correlation shows that composite color SEM‐CL imaging allows distinction between amorphous PDFs on one hand and healed PDFs and basal Brazil twins on the other: nonluminescent PDFs are amorphous, while healed PDFs and basal Brazil twins are red luminescent, with a dominant emission peak at 650 nm. We suggest that the red luminescence is the result of preferential beam damage along dislocations, fluid inclusions, and twin boundaries. Furthermore, a high‐pressure phase (possibly stishovite) in PDFs can be detected in color SEM‐CL images by its blue luminescence.     

Experimental reproduction of tectonic deformation lamellae in quartz and comparison to shock‐induced planar deformation features

Abstract— Planar features can develop in quartz during comparatively slow tectonic deformation and during very fast dynamic shock metamorphism. Despite their very different structural nature, tectonically induced deformation lamellae have sometimes been mistaken as shock‐induced planar deformation features (PDFs). To understand the formation of deformation lamellae and to address the substantial differences between them and PDFs, we have conducted deformation experiments on single crystals of quartz in a Griggs‐type apparatus, at a temperature of 800 °C, a confining pressure of 12 kbar, and a strain rate of 0.7–1.1 · 10^?6. The deformed samples were analyzed with transmission electron microscopy (TEM) and compared to natural PDFs from the Ries Crater, Germany. TEM revealed that tectonic deformation lamellae are associated with numerous sub‐parallel curved subgrain walls, across which the orientation of the crystal changes slightly. The formation of deformation lamellae is due to glide‐ and climb‐controlled deformation in the exponential creep regime. In contrast, the PDFs in shocked quartz from the Ries are perfectly planar, crystallographically controlled features that originally represented amorphous lamellae. Due to post‐shock annealing and hydrothermal activity they are recrystallized and decorated with fluid inclusions.     

Identification of shocked quartz by scanning cathodoluminescence imaging

Abstract— Quartz grains subjected to high‐strain‐rate shock waves owing to meteorite or cometary impact on Earth's surface commonly display shock lamellae. These lamellae appear as remarkably straight, thin, planar features (microstructures) in sets within which lamellae are essentially parallel to each other and spaced ≤ 20 μm apart. Two or more intersecting sets are typically present. Shock lamellae are commonly recognized and identified by optical methods, by use of the transmission electron microscope (TEM), and by etching polished sections and subsequent examination with a scanning electron microscope (SEM) operated in the secondary electron mode. We present here a method for observing planar microstructures in shocked quartz by using a cathodoluminescence (CL) detector attached to a SEM. The method relies on the fact that planar microstructures in quartz arising as a result of shock display no CL whatever; thus, they show up as distinct, thin, black lines on otherwise luminescent quartz grains. We used scanning CL imaging to study shocked quartz from the Ries Crater, Germany, a well‐known impact crater of Miocene age. We demonstrate that shock‐produced planar microstructures are clearly displayed in SEM‐CL images and can be distinguished from microfractures generated by tectonism, and subsequently filled with quartz, and other similar features not related to impact events. The SEM‐CL method provides a powerful supplement to other methods of identifying shocked quartz. It commonly provides better spatial resolution than does standard optical methods, and does not require etching of quartz grains. Further, it is easier and faster to use than are TEM methods, although it is not capable of the fine‐scale defect analysis possible with TEM.     

Progressive deformation of feldspar recording low‐barometry impact processes,Tenoumer impact structure,Mauritania

The Tenoumer impact structure is a small, well‐preserved crater within Archean to Paleoproterozoic amphibolite, gneiss, and granite of the Reguibat Shield, north‐central Mauritania. The structure is surrounded by a thin ejecta blanket of crystalline blocks (granitic gneiss, granite, and amphibolite) and impact‐melt rocks. Evidence of shock metamorphism of quartz, most notably planar deformation features (PDFs), occurs exclusively in granitic clasts entrained within small bodies of polymict, glass‐rich breccia. Impact‐related deformation features in oligoclase and microcline grains, on the other hand, occur both within clasts in melt‐breccia deposits, where they co‐occur with quartz PDFs, and also within melt‐free crystalline ejecta, in the absence of co‐occurring quartz PDFs. Feldspar deformation features include multiple orientations of PDFs, enhanced optical relief of grain components, selective disordering of alternate twins, inclined lamellae within alternate twins, and combinations of these individual textures. The distribution of shock features in quartz and feldspar suggests that deformation textures within feldspar can record a wide range of average pressures, starting below that required for shock deformation of quartz. We suggest that experimental analysis of feldspar behavior, combined with detailed mapping of shock metamorphism of feldspar in natural systems, may provide critical data to constrain energy dissipation within impact regimes that experienced low average shock pressures.     

Resolution of impact‐related microstructures in lunar zircon: A shock‐deformation mechanism map

Abstract– The microstructures of lunar zircon grains from breccia samples 72215, 73215, 73235, and 76295 collected during the Apollo 17 mission have been characterized via optical microscopy, cathodoluminescence imaging, and electron backscatter diffraction mapping. These zircon grains preserve deformation microstructures that show a wide range in style and complexity. Planar deformation features (PDFs) are documented in lunar zircon for the first time, and occur along {001}, {110}, and {112}, typically with 0.1–25 μm spacing. The widest PDFs associated with {112} contain microtwin lamellae with 65°/<110> misorientation relationships. Deformation bands parallel to {100} planes and irregular low‐angle (<10°) boundaries most commonly have <001> misorientation axes. This geometry is consistent with a dislocation glide system with <100>{010} during dislocation creep. Nonplanar fractures, recrystallized domains with sharp, irregular interfaces, and localized annealing textures along fractures are also observed. No occurrences of reidite were detected. Shock‐deformation microstructures in zircon are explained in terms of elastic anisotropy of zircon. PDFs form along a limited number of specific {hkl} planes that are perpendicular to directions of high Young’s modulus, suggesting that PDFs are likely to be planes of longitudinal lattice damage. Twinned {112} PDFs also contain directions of high shear modulus. A conceptual model is proposed for the development of different deformation microstructures during an impact event. This “shock‐deformation mechanism map” is used to explain the relative timing, conditions, and complexity relationships between impact‐related deformation microstructures in zircon.     

Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.     

A search for shocked quartz grains in the Allerød‐Younger Dryas boundary layer

The Younger Dryas impact hypothesis suggests that multiple airbursts or extraterrestrial impacts occurring at the end of the Allerød interstadial resulted in the Younger Dryas cold period. So far, no reproducible, diagnostic evidence has, however, been reported. Quartz grains containing planar deformation features (known as shocked quartz grains), are considered a reliable indicator for the occurrence of an extraterrestrial impact when found in a geological setting. Although alleged shocked quartz grains have been reported at a possible Allerød‐Younger Dryas boundary layer in Venezuela, the identification of shocked quartz in this layer is ambiguous. To test whether shocked quartz is indeed present in the proposed impact layer, we investigated the quartz fraction of multiple Allerød‐Younger Dryas boundary layers from Europe and North America, where proposed impact markers have been reported. Grains were analyzed using a combination of light and electron microscopy techniques. All samples contained a variable amount of quartz grains with (sub)planar microstructures, often tectonic deformation lamellae. A total of one quartz grain containing planar deformation features was found in our samples. This shocked quartz grain comes from the Usselo palaeosol at Geldrop Aalsterhut, the Netherlands. Scanning electron microscopy cathodoluminescence imaging and transmission electron microscopy imaging, however, show that the planar deformation features in this grain are healed and thus likely to be older than the Allerød‐Younger Dryas boundary. We suggest that this grain was possibly eroded from an older crater or distal ejecta layer and later redeposited in the European sandbelt. The single shocked quartz grain at this moment thus cannot be used to support the Younger Dryas impact hypothesis.     

ANIE: A mathematical algorithm for automated indexing of planar deformation features in quartz grains

Abstract– Planar deformation features (PDFs) in quartz, one of the most commonly used diagnostic indicators of shock metamorphism, are planes of amorphous material that follow crystallographic orientations, and can thus be distinguished from non‐shock‐induced fractures in quartz. The process of indexing data for PDFs from universal‐stage measurements has traditionally been performed using a manual graphical method, a time‐consuming process in which errors can easily be introduced. A mathematical method and computer algorithm, which we call the Automated Numerical Index Executor (ANIE) program for indexing PDFs, was produced, and is presented here. The ANIE program is more accurate and faster than the manual graphical determination of Miller–Bravais indices, as it allows control of the exact error used in the calculation and removal of human error from the process.     

Planar deformation features in quartz from impact‐produced polymict breccia of the Xiuyan crater,China

Abstract– The 1.8 km‐diameter Xiuyan crater is an impact structure in northeastern China, exposed in a Proterozoic metamorphic rock complex. The major rocks of the crater are composed of granulite, hornblendite, gneiss, tremolite marble, and marble. The bottom at the center of the crater covers about 100 m thick lacustrine sediments underlain by 188 m thick crater‐fill breccia. A layer of polymict breccia composed of clasts of granulite, gneiss, hornblendite, and fragments of glass as well as clastic matrix, occurs near the base, in the depth interval from 260 to 295 m. An investigation in quartz from the polymict breccia in the crater‐fill units reveals abundant planar deformation features (PDFs). Quartz with multiple sets of PDFs is found in clasts of granulite that consist of mainly quartz and feldspar, and in fine‐grained matrix of the impact‐produced polymict breccia. A universal stage was used to measure the orientation of PDFs in 70 grains of quartz from five thin sections made from the clasts of granulite of polymict breccia recovered at the depth of 290 m. Forty‐four percent of the quartz grains contain three sets of PDFs, and another 40% contain two sets of PDFs. The most abundant PDFs are rhombohedron forms of , , and with frequency of 33.5, 22.3, and 9.6%, respectively. A predominant PDF form of in quartz suggests a shock pressure >20 GPa. The occurrence of PDFs in quartz from the polymict breccia provides crucial evidence for shock metamorphism of target rocks and confirms the impact origin of this crater, which thus appears to be the first confirmed impact crater in China.     

Infrared,Raman, and cathodoluminescence studies of impact glasses

Abstract— We studied the infrared reflectance (IR), Raman, and cathodoluminescence (CL) spectroscopic signatures and scanning electron microscope‐cathodoluminescence (SEM‐CL) images of three different types of impact glasses: Aouelloul impact glass, a Muong Nong‐type tektite, and Libyan desert glass. Both backscattered electron (BSE) and CL images of the Muong Nong‐type tektite are featureless; the BSE image of the Libyan desert glass shows only weak brightness contrasts. For the Aouelloul glass, both BSE and CL images show distinct brightness contrast, and the CL images for the Libyan desert glass show spectacular flow textures that are not visible in any other microscopic method. Compositional data show that the SiO₂ composition is relatively higher and the Al₂O₃ content is lower in the CL‐bright areas than in the CL‐dark regions. The different appearance of the three glass types in the CL images indicates different peak temperatures during glass formation: the tektite was subjected to the highest temperature, and the Aouelloul impact glass experienced a relatively low formation temperature, while the Libyan desert glass preserves a flow texture that is only visible in the CL images, indicating a medium temperature. All IR reflectance spectra show a major band at around 1040 to 1110 cm^?1 (antisymmetric stretching of SiO₄ tetrahedra), with minor peaks between 745 and 769 cm^?1 (Si‐O‐Si angle deformation). Broad bands at 491 and 821 cm^?1 in the Raman spectra in all samples are most likely related to diaplectic glass remnants, indicating early shock amorphization followed by thermal amorphization. The combination of these spectroscopic methods allows us to deduce information about the peak formation temperature of the glass, and the CL images, in particular, show glass flow textures that are not preserved in other more conventional petrographic images.     

The Keurusselkä impact structure,Finland—Impact origin confirmed by characterization of planar deformation features in quartz grains

Abstract– Although the meteorite impact origin of the Keurusselkä impact structure (central Finland) has been established on the basis of the occurrence of shatter cones, no detailed microscopic examination of the impactites from this structure has so far been made. Previous microscope investigations of in situ rocks did not yield any firm evidence of shock features (Raiskila et al. 2008; Kinnunen and Hietala 2009). We have carried out microscopic observations on petrographic thin sections from seven in situ shatter cone samples and report here the discovery of planar fractures (PFs) and planar deformation features (PDFs) in quartz and feldspar grains. The detection and characterization of microscopic shock metamorphic features in the investigated samples substantiates a meteorite impact origin for the Keurusselkä structure. The crystallographic orientations of 372 PDF sets in 276 quartz grains were measured, using a universal stage (U‐stage) microscope, for five of the seven distinct shatter cone samples. Based on our U‐stage results, we estimate that investigated shatter cone samples from the Keurusselkä structure have experienced peak shock pressures from approximately 2 GPa to slightly less than 20 GPa for the more heavily shocked samples. The decoration of most of the PDFs with fluid inclusions also indicates that these originally amorphous shock features were altered by postimpact processes. Finally, our field observations indicate that the exposed surface corresponds to the crater floor; it is, however, difficult to estimate the exact diameter of the structure and the precise amount of material that has been eroded since its formation.     

Shock metamorphism in plagioclase and selective amorphization

Plagioclase feldspar is one of the most common rock‐forming minerals on the surfaces of the Earth and other terrestrial planetary bodies, where it has been exposed to the ubiquitous process of hypervelocity impact. However, the response of plagioclase to shock metamorphism remains poorly understood. In particular, constraining the initiation and progression of shock‐induced amorphization in plagioclase (i.e., conversion to diaplectic glass) would improve our knowledge of how shock progressively deforms plagioclase. In turn, this information would enable plagioclase to be used to evaluate the shock stage of meteorites and terrestrial impactites, whenever they lack traditionally used shock indicator minerals, such as olivine and quartz. Here, we report on an electron backscatter diffraction (EBSD) study of shocked plagioclase grains in a metagranite shatter cone from the central uplift of the Manicouagan impact structure, Canada. Our study suggests that, in plagioclase, shock amorphization is initially localized either within pre‐existing twins or along lamellae, with similar characteristics to planar deformation features (PDFs) but that resemble twins in their periodicity. These lamellae likely represent specific crystallographic planes that undergo preferential structural failure under shock conditions. The orientation of preexisting twin sets that are preferentially amorphized and that of amorphous lamellae is likely favorable with respect to scattering of the local shock wave and corresponds to the “weakest” orientation for a specific shock pressure value. This observation supports a universal formation mechanism for PDFs in silicate minerals.     

MicroRaman spectroscopy of anomalous planar microstructures in quartz from Mt. Oikeyama: Discovery of a probable impact crater in Japan

Abstract– Planar deformation features (PDFs) and planar fractures (PFs) have been found and confirmed by optical microscope observations and microRaman spectroscopy in quartz grains from Mt. Oikeyama (Akaishi Mountains, Central Japan), for which the semicircular topographic feature of the ridge suggests a crater formed by an impact event. According to the optical microscope observations, a low shock pressure (8–10 GPa) is estimated by the occurrence of basal or ω PDFs leading to lack of multiple sets of PDFs. In addition, a new type of planar microstructure was found in several quartz grains. The microRaman characteristics of PDFs in quartz from Mt. Oikeyama show the amorphous state indicating the presence of weak broad bands at 400 and 800 cm^?1 peak positions. These characteristics are indicative of PDFs that are limited to shocked quartz. This indicates an impact origin for distinct planar microstructures in quartz from Mt. Oikeyama.     

Shock‐metamorphic microfeatures in chert from the Jebel Waqf as Suwwan impact structure,Jordan

Abstract– The petrographic investigation of a shocked, chalcedony‐, quartzine‐, and quartz‐bearing allochthonous chert nodule (probably Upper Cretaceous) recovered from surficial wadi gravels in the inner parts of the central uplift of the approximately 6 km in diameter Jebel Waqf as Suwwan impact structure, Jordan, reveals new potential shock indicators in microfibrous–spherulitic silica, in addition to well‐established shock‐metamorphic effects in coarser crystalline quartz. The microcrystalline chert groundmass exhibits a macroscopic dendritic and suborthogonal fracture pattern commonly associated with thin “recrystallization bands” that intersect the pre‐existing diagenetic chert fabric. Fibrous aggregates of quartzine spherulites in chalcedony‐quartzine‐quartz veinlets locally have a shattered appearance and show conspicuous “curved fractures” perpendicular to the quartzine fiber direction (and parallel to [0001]) that commonly trend subparallel to planar fractures (PFs) in neighboring shocked quartz. Quartz exhibits PFs, feather features (FFs), and mainly single sets of planar deformation features (PDFs) parallel to the basal plane (0001) (Brazil twins) and, rarely, additional PDFs parallel to {101¯3}. Shock petrography indicates shock pressures of ≥10 GPa and high shock‐induced differential stresses that affected the chert nodule. The internal crosscutting relationships of primary diagenetic and impact‐related deformational features together with shockpressure estimates suggest that the curved fractures across quartzine spherulites might represent specific (low‐ to medium‐pressure) shock‐metamorphic features, possibly in structural analogy to basal plane PFs in quartz. The dendritic–suborthogonal fractures in the microcrystalline chert groundmass and recrystallization bands are likely related to impact‐induced shear deformation and recrystallization, respectively, and cannot be considered as definite shock indicators.     

Fluid inclusions in microstructures of shocked quartz from the Keurusselkä impact site,Central Finland

Granitoid rock samples from the assumed center of the Keurusselkä impact site were subjected to a systematic study of fluid‐inclusion compositions and densities in various microstructures of the shocked quartz. The results are consistent with the following impact‐induced model of formation. After cessation of all major regional tectonic activity and advanced erosional uplift of the Fennoscandian shield, a meteorite impact (approximately 1.1 Ga) caused the formation of planar fractures (PFs) and planar deformation features (PDFs) and the migration of shock‐liberated metamorphic fluid (CO₂ ± H₂O) to the glass in the PDFs. Postimpact annealing of the PDFs led to the formation of CO₂ (±H₂O) fluid‐inclusion decorated PDFs. The scarce fluid‐inclusion implosion textures (IPs) suggest a shock pressure of 7.6–10 GPa. The postimpact pressure release and associated heating initiated hydrothermal activity that caused re‐opening of some PFs and their partial filling by moderate‐salinity/high temperature (>200 °C) H₂O (+ chlorite + quartz) and moderate‐density CO₂. The youngest postimpact endogenic sub‐ and nonplanar microfractures (MFs) are characterized by low‐density CO₂ and low‐salinity/low‐temperature (<200 °C) H₂O.     

Fine‐structures of planar deformation features in shocked olivine: A comparison between Martian meteorites and experimentally shocked basalts as an indicator for shock pressure

We performed shock recovery experiments on an olivine‐phyric basalt at shock pressures of 22.2–48.5 GPa to compare with shock features in Martian meteorites (RBT 04261 and NWA 1950). Highly shocked olivine in the recovered basalt at 39.5 and 48.5 GPa shows shock‐induced planar deformation features (PDFs) composed of abundant streaks of defects. Similar PDFs were observed in olivine in RBT 04261 and NWA 1950 while those in NWA 1950 were composed of amorphous lamellae. Based on the present results and previous studies, the width and the abundance of lamellar fine‐structures increased with raising shock pressure. Therefore, these features could be used as shock pressure indicators while the estimated pressures may be lower limits due to no information of temperature dependence. For Martian meteorites that experienced heavy shocks, the minimum peak shock pressures of RBT 04261 and NWA 1950 are estimated to be 39.5–48.5 GPa and 48.5–56 GPa, respectively, which are found consistent with those estimated by postshock temperatures expected by the presence of brown olivine. We also investigated shock‐recovered basalts preheated at 750 and 800 °C in order to check the temperature effects on shock features. The results indicate a reduction in vitrifying pressure of plagioclase and a pressure increase for PDFs formation in olivine. Further temperature‐controlled shock recovery experiments will provide us better constraints to understand and to characterize various features found in natural shock events.     

WIP: A Web‐based program for indexing planar features in quartz grains and its usage

Planar deformation features (PDFs) in quartz are the most important diagnostic features that allow the unambiguous identification of impact structures on Earth. In order to confirm that these features (that are characterized by planar character and form along specific crystallographic planes) are indeed PDFs, they need to be properly investigated and indexed. Following universal‐stage measurements, the process of indexing is usually performed manually, using a Wulff stereonet and following a strict procedure, which is time consuming and error prone. In this article, we present WIP, a new Web‐based program for indexing planar deformation features in quartz. The correctness of our program is shown by its application to measurements that had previously been indexed manually. The observed minor differences, especially in the absolute frequency percentage of PDFs, are negligible and not significant enough to influence the estimation of shock pressure that could be calculated from the indexed results. Usability of this program is shown using the spatial relationships between a statistically significant number of 278 quartz grains with 409 sets of PDFs analyzed within the area (~35 mm²) of a single thin section of a meta‐greywacke from the Bosumtwi impact structure. Our program is not only more accurate and faster than the manual (graphical) method but also removes the human error from the plotting process and allows control of several parameters, such as the value of estimated measurement error used in the indexing calculation or method of aggregated error handling. The program also provides information about the angles between the planes of the measured PDF sets present in a grain, which allows determination of the angles between (for example) indexed {} and {} sets.     

Shock effects in plagioclase feldspar from the Mistastin Lake impact structure,Canada

Shock metamorphism, caused by hypervelocity impact, is a poorly understood process in feldspar due to the complexity of the crystal structure, the relative ease of weathering, and chemical variations, making optical studies of shocked feldspars challenging. Understanding shock metamorphism in feldspars, and plagioclase in particular, is vital for understanding the history of Earth's moon, Mars, and many other planetary bodies. We present here a comprehensive study of shock effects in andesine and labradorite from the Mistastin Lake impact structure, Labrador, Canada. Samples from a range of different settings were studied, from in situ central uplift materials to clasts from various breccias and impact melt rocks. Evidence of shock metamorphism includes undulose extinction, offset twins, kinked twins, alternate twin deformation, and partial to complete transformation to diaplectic plagioclase glass. In some cases, isotropization of alternating twin lamellae was observed. Planar deformation features (PDFs) are notably absent in the plagioclase, even when present in neighboring quartz grains. It is notable that various microlites, twin planes, and compositionally different lamellae could easily be mistaken for PDFs and so care must be taken. A pseudomorphous zeolite phase (levyne‐Ca) was identified as a replacement mineral of diaplectic feldspar glass in some samples, which could, in some instances, also be potentially mistaken for PDFs. We suggest that the lack of PDFs in plagioclase could be due to a combination of structural controls relating to the crystal structure of different feldspars and/or the presence of existing planes of weakness in the form of twin and cleavage planes.     

Shock metamorphism of quartz in nature and experiment: II. Significance in geoscience*

Abstract— The occurrence of shock metamorphosed quartz is the most common petrographic criterion for the identification of terrestrial impact structures and lithologies. Its utility is due to its almost ubiquitous occurrence in terrestrial rocks, its overall stability and the fact that a variety of shock metamorphic effects, occurring over a range of shock pressures, have been well documented. These shock effects have been generally duplicated in shock recovery experiments and, thus, serve as shock pressure barometers. After reviewing the general character of shock effects in quartz, the differences between experimental and natural shock events and their potential effects on the shock metamorphism of quartz are explored. The short pulse lengths in experiments may account for the difficulty in synthesizing the high-pressure polymorphs, coesite and stishovite, compared to natural occurrences. In addition, post-shock thermal effects are possible in natural events, which can affect shock altered physical properties, such as refractive index, and cause annealing of shock damage and recrystallization. The orientations of planar microstructures, however, are unaffected by post-impact thermal events, except if quartz is recrystallized, and provide the best natural shock barometer in terms of utility and occurrence. The nature of planar microstructures, particularly planar deformation features (PDFs), is discussed in some detail and a scheme of variations in orientations with shock pressure is provided. The effect of post-impact events on PDFs is generally limited to annealing of the original glass lamellae to produce decorated PDFs, resulting from the exsolution of dissolved water during recrystallization. Basal (0001) PDFs differ from other PDF orientations in that they are multiple, mechanical Brazil twins, which are difficult to detect if not partially annealed and decorated. The occurrence and significance of shock metamorphosed quartz and its other phases (namely, coesite, stishovite, diaplectic glass and lechatelierite) are discussed for terrestrial impact structures in both crystalline (non-porous) and sedimentary (porous) targets. The bulk of past studies have dealt with crystalline targets, where variations in recorded shock pressure in quartz have been used to constrain aspects of the cratering process and to estimate crater dimensions at eroded structures. In sedimentary targets, the effect of pore space results in an inhomogeneous distribution in recorded shock pressure and temperature, which requires a different classification scheme for the variation of recorded shock compared to that in crystalline targets. This is discussed, along with examples of variations in the relative abundances of planar microstructures and their orientations, which are attributed to textural variations in sedimentary target rocks. Examples of the shock metamorphism of quartz in distal ejecta, such as at the K/T boundary, and from nuclear explosions are illustrated and are equivalent to that of known impact structures, except with respect to characteristics that are due to long-term, post-shock thermal effects. Finally, the differences between the deformation and phase transformation of quartz by shock and by endogenic, tectonic and volcanic processes are discussed. We confirm previous conclusions that they are completely dissimilar in character, due to the vastly different physical conditions and time scales typical for shock events, compared to tectonic and volcanic events. Well-characterized and documented shock effects in quartz are unequivocal indicators of impact in the natural environment.     

Shock metamorphic features in quartz grains from the Saarijärvi and Söderfjärden impact structures,Finland

Shock metamorphic features at the Saarijärvi (D > 2 km) and Söderfjärden (D = 6.5 km) structures in Finland have so far only been studied tentatively, although both are considered to be proven impact structures. This work presents the first detailed universal stage study of planar deformation features (PDFs), feather feature lamellae (FFL), and planar fractures (PFs) in quartz grains from a polymict impact breccia dike from Söderfjärden, and from sedimentary crater‐fill rocks from Saarijärvi. Planar microstructures, particularly PDFs, are very rare and poorly developed or preserved in Saarijärvi, whereas in Söderfjärden they are much more common and well defined. Miller–Bravais indices of the planar microstructures in both Saarijärvi and Söderfjärden are indicative of relatively low‐shock pressure but high shear conditions, only compatible with an impact origin for these structures. Although a Proterozoic age for Saarijärvi cannot be ruled out, the observations of shock features throughout the sedimentary crater‐fill sequence and a brecciated sedimentary dike below the crater floor are more consistent with a Lower Cambrian (or younger) impact age.