The Canyon Diablo impact event: Projectile motion through the atmosphere

Abstract— Meteor Crater is one of the first impact structures systematically studied on Earth. Its location in arid northern Arizona has been ideal for the preservation of the structure and the surviving meteoric material. The recovery of a large amount of meteoritic material in and around the crater has allowed a rough reconstruction of the impact event: an iron object 50 m in diameter impacted the Earth's surface after breaking up in the atmosphere. The details of the disruption, however, are still debated. The final crater morphology (deep, bowl‐shaped crater) rules out the formation of the crater by an open or dispersed swarm of fragments, in which the ratio of swarm radius to initial projectile radius C_d is larger than 3 (the final crater results from the sum of the craters formed by individual fragments). On the other hand, the lack of significant impact melt in the crater has been used to suggest that the impactor was slowed down to 12 km/s by the atmosphere, implying significant fragmentation and fragments' separation up to 4 initial radii. This paper focuses on the problem of entry and motion through the atmosphere for a possible Canyon Diablo impactor as a first but necessary step for constraining the initial conditions of the impact event which created Meteor Crater. After evaluating typical models used to investigate meteoroid disruption, such as the pancake and separated fragment models, we have carried out a series of hydrodynamic simulations using the 3D code SOVA to model the impactor flight through the atmosphere, both as a continuum object and a disrupted swarm. Our results indicate that the most probable pre‐atmospheric mass of the Meteor Crater projectile was in the range of 4.10⁸to 1.2.10⁹kg (equivalent to a sphere 46–66 m in diameter). During the entry process the projectile lost probably 30% to 70% of its mass, mainly because of mechanical ablation and gross fragmentation. Even in the case of a tight swarm of particles (C_d < 3), small fragments can separate from the crater‐forming swarm and land on the plains (tens of km away from the crater) as individual meteorites. Starting from an impactor pre‐atmospheric velocity of ?18 km/s, which represents an average value for Earth‐crossing asteroids, we find that after disruption, the most probable impact velocity at the Earth's surface for a tight swarm is around 15 km/s or higher. A highly dispersed swarm would result in a much stronger deceleration of the fragments but would produce a final crater much shallower than observed at Meteor Crater.     

The effect of target lithology on the products of impact melting

Abstract— Impact cratering is an important geological process on the terrestrial planets and rocky and icy moons of the outer solar system. Impact events generate pressures and temperatures that can melt a substantial volume of the target; however, there remains considerable discussion as to the effect of target lithology on the generation of impact melts. Early studies showed that for impacts into crystalline targets, coherent impact melt rocks or “sheets” are formed with these rocks often displaying classic igneous structures (e.g., columnar jointing) and textures. For impact structures containing some amount of sedimentary rocks in the target sequence, a wide range of impact‐generated lithologies have been described, although it has generally been suggested that impact melt is either lacking or is volumetrically minor. This is surprising given theoretical constraints, which show that as much melt should be produced during impacts into sedimentary targets. The question then arises: where has all the melt gone? The goal of this synthesis is to explore the effect of target lithology on the products of impact melting. A comparative study of the similarly sized Haughton, Mistastin, and Ries impact structures, suggests that the fundamental processes of impact melting are basically the same in sedimentary and crystalline targets, regardless of target properties. Furthermore, using advanced microbeam analytical techniques, it is apparent that, for the structures under consideration here, a large proportion of the melt is retained within the crater (as crater‐fill impactites) for impacts into sedimentary‐bearing target rocks. Thus, it is suggested that the basic products are genetically equivalent but they just appear different. That is, it is the textural, chemical and physical properties of the products that vary.     

Carbonate-silicate liquid immiscibility upon impact melting: Ries Crater,Germany

Abstract— The 24 km diameter Ries impact crater in southern Germany is one of the most studied impact structures on Earth. The Ries impactor struck a Triassic to Upper Jurassic sedimentary sequence overlying Hercynian crystalline basement. At the time of impact (14.87 × 0.36 Ma; Storzer et al., 1995), the 350 m thick Malm limestone was present only to the south and east of the impact site. To the north and west, the Malm had been eroded away, exposing the underlying Dogger and Lias. The largest proportion of shocked target material is in the impact-melt-bearing breccia suevite. The suevite had been believed to be derived entirely from the crystalline basement. Calcite in the suevite has been interpreted as a postimpact hydrothermal deposit. From optical inspection of 540 thin sections of suevite from 32 sites, I find that calcite in the suevite shows textural evidence of liquid immiscibility with the silicate impact melt. Textural evidence of liquid immiscibility between silicate and carbonate melt in the Ries suevite includes carbonate globules within silicate glass, silicate globules embedded in carbonate, deformable and coalescing carbonate spheres within silicate glass, sharp menisci or cusps and budding between silicate and carbonate melt, fluidal textures and gas vesicles in carbonate schlieren, a quench crystallization sequence of the carbonate, spinifex textured quenched carbonate, separate carbonate spherules in the suevite mineral-fragment matrix, and inclusions of mineral fragments suspended in carbonate blebs. Given this evidence of liquid immiscibility, the carbonate in the suevite therefore has—like the silicate melt—a primary origin by impact-shock melting. Evidence of carbonate-silicate liquid immiscibility is abundant in the suevites from the southwest to east of the Ries crater. The rarer suevites to the west to northeast of the crater are nearly devoid of carbonate melts. This correspondence between the occurrence of outcropping limestones at the target surface and the formation of carbonate melt indicates that the Malm limestones are the source rocks of the carbonate impact melt. This correspondence shows that the suevites preserve a compositional memory of their source rocks. From the regional distribution of suevites with or without immiscible carbonate melts, it is inferred that the Ries impactor hit the steep Albtrauf escarpment at its toe, in an oblique impact from the north.     

Cratering and modification of wet‐target craters: Projectile impact experiments and field observations of the Lockne marine‐target crater (Sweden)

Abstract— Marine impacts are one category of crater formation in volatile targets. At target water depths exceeding the diameter of the impactor, the zones of vaporization, melting, and excavation of the standard land‐target cratering model develop partially or entirely in the water column. The part of the crater that has a potential of being preserved (seafloor crater) may to a great extent be formed by material emplacement and excavation processes that are very different from land‐target craters. These processes include a high‐energy, water‐jet‐driven excavation flow. At greater water depths, the difference in strength of the target layers causes a concentric crater to evolve. The crater consists of a wide water cavity with a shallow excavation flow along the seabed surrounding a nested, deeper crater in the basement. The modification of the crater is likewise influenced by the water through its forceful resurge to fill the cavity in the water mass and the seafloor. The resurge flow is strongly erosive and incorporates both ejecta and rip‐up material from the seabed surrounding the excavated crater. A combination of field observations and impact experiments has helped us analyze the processes affecting the zone between the basement crater and the maximum extent of the water cavity. The resurge erosion is facilitated by fragmentation of the upper parts of the solid target caused by a) spallation and b) vibrations from the shallow excavation flow and, subsequently, c) the vertical collapse of the water cavity rim wall. In addition, poorly consolidated and saturated sediments may collapse extensively, possibly aided by a violent expansion of the pore water volume when it turns into a spray during passage of the rarefaction wave. This process may also occur at impacts into water‐saturated targets without an upper layer of seawater present. Our results have implications for impacts on both Earth and Mars, and possibly anywhere in the solar system where volatiles exist/have existed in the upper part of the target.     

Scouring the surface: Ejecta dynamics and the LCROSS impact event

The Lunar CRater Observation and Sensing Satellite mission (LCROSS) impacted the moon in a permanently shadowed region of Cabeus crater on October 9th 2009, excavating material rich in water ice and volatiles. The thermal and spatial evolution of LCROSS ejecta is essential to interpretation of regolith properties and sources of released volatiles. The unique conditions of the impact, however, made analysis of the data based on canonical ejecta models impossible. Here we present the results of a series of impact experiments performed at the NASA Ames Vertical Gun Range designed to explore the LCROSS event using both high-speed cameras and LCROSS flight backup instruments. The LCROSS impact created a two-component ejecta plume: the usual inverted lampshade “low-angle” curtain, and a high speed, high-angle component. These separate components excavated to different depths in the regolith. Extrapolations from experiments match the visible data and the light curves in the spectrometers. The hollow geometry of the Centaur led to the formation of the high-angle plume, as was evident in the LCROSS visible and infrared measurements of the ejecta. Subsequent ballistic return of the sunlight-warmed ejecta curtain could scour the surface out to many crater radii, possibly liberating loosely bonded surface volatiles (e.g., H₂). Thermal imaging reveals a complex, heterogeneous distribution of heated material after crater formation that is present but unresolved in LCROSS data. This material could potentially serve as an additional source of energy for volatile release.     

The Late Ordovician (Sandbian) Glasford structure: A marine‐target impact crater with a possible connection to the Ordovician meteorite event

The Glasford structure in Illinois (USA) was recognized as a buried impact crater in the early 1960s but has never been reassessed in light of recent advances in planetary science. Here, we document shatter cones and previously unknown quartz microdeformation features that support an impact origin for the Glasford structure. We identify the 4 km wide structure as a complex buried impact crater and describe syn‐ and postimpact deposits from its annular trough. We have informally designated these deposits as the Kingston Mines unit (KM). The fossils and sedimentology of the KM indicate a marine depositional setting. The various intervals within the KM constitute a succession of breccia, carbonate, sandstone, and shale similar to marine sedimentary successions preserved in other craters. Graptolite specimens retrieved from the KM place the time of deposition at approximately 455 ± 2 Ma (Late Ordovician, Sandbian). This age determination suggests a possible link between the Glasford impact and the Ordovician meteorite shower, an increase in the rate of terrestrial meteorite impacts attributed to the breakup of the L‐chondrite parent body in the main asteroid belt.     

Scaling impact melting and crater dimensions: Implications for the lunar cratering record

Abstract— The dimensions of large craters formed by impact are controlled to a large extent by gravity, whereas the volume of impact melt created during the same event is essentially independent of gravity. This “differential scaling” fosters size-dependent changes in the dynamics of impact-crater and basin formation as well as in the final morphologies of the resulting structures. A variety of such effects can be observed in the lunar cratering record, and some predictions can be made on the basis of calculations of impact melting and crater dimensions. Among them are the following: (1) as event magnitude increases, the volume of melt created relative to that of the crater will grow, and more will be retained inside the rim of the crater or basin. (2) The depth of melting will exceed the depth of excavation at diameters that essentially coincide with both the inflection in the depth-diameter trend and the simple-to-complex transition. (3) The volume of melt will exceed that of the transient cavity at a cavity diameter on the order of the diameter of the Moon; this would arguably correspond to a Moon-melting event. (4) Small lunar craters only rarely display exterior flows of impact melt because the relatively small volumes of melt created can become choked with clasts, increasing the melt's viscosity and chilling it rapidly. Larger craters and basins should suffer little from such a process. (5) Deep melting near the projectile's axis of penetration during larger events will yield a progression in central-structure morphology; with growing event magnitude, this sequence should range from single peaks through multiple peaks to peak rings. (6) The minimum depth of origin of central-peak material should coincide with the maximum depth of melting; the main central peak in a crater the size of Tycho should have had a preimpact depth of close to 15 km.     

Shock metamorphism and impact melting in small impact craters on Earth: Evidence from Kamil crater,Egypt

Kamil is a 45 m diameter impact crater identified in 2008 in southern Egypt. It was generated by the hypervelocity impact of the Gebel Kamil iron meteorite on a sedimentary target, namely layered sandstones with subhorizontal bedding. We have carried out a petrographic study of samples from the crater wall and ejecta deposits collected during our first geophysical campaign (February 2010) in order to investigate shock effects recorded in these rocks. Ejecta samples reveal a wide range of shock features common in quartz‐rich target rocks. They have been divided into two categories, as a function of their abundance at thin section scale: (1) pervasive shock features (the most abundant), including fracturing, planar deformation features, and impact melt lapilli and bombs, and (2) localized shock features (the least abundant) including high‐pressure phases and localized impact melting in the form of intergranular melt, melt veins, and melt films in shatter cones. In particular, Kamil crater is the smallest impact crater where shatter cones, coesite, stishovite, diamond, and melt veins have been reported. Based on experimental calibrations reported in the literature, pervasive shock features suggest that the maximum shock pressure was between 30 and 60 GPa. Using the planar impact approximation, we calculate a vertical component of the impact velocity of at least 3.5 km s^?1. The wide range of shock features and their freshness make Kamil a natural laboratory for studying impact cratering and shock deformation processes in small impact structures.     

Shock-induced melting and vaporization of shatter cone surfaces: Evidence from the Sudbury impact structure

Abstract— Analytical scanning electron microscopy has been used to investigate the surface textures and compositions of newly exposed shatter cones from the 1.85 Ga Sudbury impact structure, Canada. Unusual surface microstructures are observed at the micron scale, including silicate melt smears, melt fibres and melt splats. Silicate and Ni-rich spherules up to 5 μm in diameter adorn earlier-formed surface features, and we interpret these to be condensates formed due to shock-induced vaporization of the shatter cone surfaces. The development of striations on the shatter cones is attributed to shock-related fracture and slip. Formation of melts and spherules indicates that the highest ranks of shock metamorphism (Stages IV and V) were realized, but only on a very localized scale. Shatter cone surfaces are, therefore, likely sites for the development of high-pressure polymorphs and, if the chemistry is appropriate, fullerenes. As such, they may be equivalent to “Type A” pseudotachylytes and shock veins in meteorites.     

Cratering on Titan: impact melt, ejecta, and the fate of surface organics

We conduct three-dimensional hydrodynamical simulations of hypervelocity impacts into the crust of Titan to determine the fraction of liquid water generated, under the reasonable assumption that the crust is largely water ice, and to track the fate of the organic-rich layer that is thought to overlie the ice over much of the surface. Impactors larger than a kilometer in diameter are only slightly affected by the atmosphere, while those well under that size are strongly decelerated and broken up before reaching the surface. Impact of a 2 km diameter icy projectile into the crust at velocities of 7 km per second or higher, and angles of impact between 30° and 45°, generate about 2-5% melt by volume within the crater. Our results for the amount of aqueous melt generated in impacts on Titan are broadly consistent with the analytic model developed by Thompson and Sagan (1992) although our numerical model allows us to more precisely quantify the fraction of melt, and fate of the organics, as a function of the impact parameters. While much of the organic surface layer is heavily shocked and ejected from the immediate region of the crater, a significant fraction located behind the oblique impact trajectory is only lightly shocked and is deposited in the liquid water at the crater base. Simple calculations suggest that the resulting aqueous organic phase may remain liquid for hundreds of years or longer, enough time for the synthesis of simple precursor molecules to the origin of life.     

Strontium and neodymium isotope systematics of target rocks and impactites from the El'gygytgyn impact structure: Linking impactites and target rocks

The 3.6 Ma El'gygytgyn structure, located in northeastern Russia on the Chukotka Peninsula, is an 18 km diameter complex impact structure. The bedrock is formed by mostly high‐silica volcanic rocks of the ~87 Ma old Okhotsk‐Chukotka Volcanic Belt (OCVB). Volcanic target rocks and impact glasses collected on the surface, as well as drill core samples of bedrock and impact breccias have been investigated by thermal ionization mass spectrometry (TIMS) to obtain new insights into the relationships between these lithologies in terms of Nd and Sr isotope systematics. Major and trace element data for impact glasses are added to compare with the composition of target rocks and drill core samples. Sr isotope data are useful tracers of alteration processes and Nd isotopes reveal characteristics of the magmatic sources of the target rocks, impact breccias, and impact glasses. There are three types of target rocks mapped on the surface: mafic volcanics, dacitic tuff and lava of the Koekvun’ Formation, and dacitic to rhyolitic ignimbrite of the Pykarvaam Formation. The latter represents the main contributor to the impact rocks. The drill core is divided into a suevite and a bedrock section by the Sr isotope data, for which different postimpact alteration regimes have been detected. Impact glasses from the present‐day surface did not suffer postimpact hydrothermal alteration and their data indicate a coherent alteration trend in terms of Sr isotopes with the target rocks from the surface. Surprisingly, the target rocks do not show isotopic coherence with the Central Chukotka segment of the OCVB or with the Berlozhya magmatic assemblage (BMA), a late Jurassic felsic volcanic suite that crops out in the eastern part of the central Chukotka segment of the OCVB. However, concordance for these rocks exists with the Okhotsk segment of the OCVB. This finding argues for variable source magmas having contributed to the build‐up of the OCVB.     

Summanen structure: Further geological and geophysical evidence of a meteorite impact event in Central Finland

The Summanen structure is located in Central Finland and is one of Finland's 12 known meteorite impact structures. In 2017, the discovery of Summanen was based on numerous shatter cone boulders with planar deformation features (PDFs) and a circular electromagnetic anomaly, which is 2.6 km in diameter. The site was revisited in 2020 and 2022, and shatter cone-bearing outcrops were discovered. PDFs and feather features were identified in samples from these outcrops. A total of 38 PDF sets in 27 quartz grains resulted in rational crystallographic orientations concentrating on {10$\overline{1}$4}, {10$\overline{1}$3}, {10$\overline{1}$2}, and {11$\overline{2}$2}, implying shock pressures of 2–20 GPa. Gravity measurements were taken, and the electrical conductivity of the structure was studied. The gravimetric results revealed a circular negative anomaly of about 4 km in diameter, with an amplitude of −3.5 mGal. Excluding the gravitational effect of water and Quaternary sediments reduces the anomaly to −1.6 mGal. A bowl-shaped conductive layer, likely containing relict saline water in the impact-fractured bedrock, was identified to a depth of 240 m. Topographic and bathymetric data were combined to determine the impact's effect and interpret the level of erosion. Cobbles of sedimentary sand- and siltstones were found on the coastline of Lake Summanen. Based on their similarity to those found in the Söderfjärden impact crater with a Cambrian age, it is likely that these rocks and post-impact infill are also of a similar age.     

Brownish inclusions and dark streaks in Libyan Desert Glass: Evidence for high‐temperature melting of the target rock

Abstract– Dark streaks and different types of inclusions in Libyan Desert Glass (LDG) collected from the LDG strewn field in Egypt were investigated. Rare transparent spherules enclosed in the glassy matrix are characterized by concentric cracks, irregular internal cracks, intense twinning, and considerable amounts of Ti and Al. Raman spectra show that the spherules are α‐cristobalite. Their occurrence together with lechatelierite indicates quick heating of the source rock to at least 1550 °C, followed by rapid quenching leading to crystallization of β‐cristobalite, which upon cooling inverted into α‐cristobalite. Brownish inclusions are irregularly shaped, elongated objects with smooth contacts to the surrounding glass. They contain small roundish to elliptical droplets, and a few larger angular grains, which compositionally and according to their Raman spectra most closely resemble low‐Ca, Al‐rich orthopyroxene. Composition and texture of the orthopyroxene suggest that the brownish inclusions formed by incomplete melting of an Al‐rich orthopyroxene bearing precursor, e.g., mafic phases present in desert surface sands or also of orthopyroxene‐bearing granulite dykes in the LDG target. Experimental data on Ca‐poor enstatite also support that the inclusions were heated to about 1550 °C. Analyses of dark streaks in LDG reveal high abundances of Al, Ti, Mn, Cr, Fe, and Ni and a pronounced correlation between the abundances of Cr, Mn, Fe, and Ni. As the Fe/Ni, Mn/Ni, and Cr/Ni ratios are all clearly nonchondritic, the source of this material is most likely terrestrial and the dark streaks studied here represent a different type of schlieren compared to those which contain a meteoritic component. These findings suggest LDG formation during a short high‐temperature event. Melting of Al‐rich orthopyroxene bearing target material seems to suggest an asteroid impact rather than a near‐surface airburst.     

The preservation of fossil biomarkers during meteorite impact events: Experimental evidence from biomarker‐rich projectiles and target rocks

Abstract– A Devonian siltstone from Orkney, Scotland, shows survival of biomarkers in high‐velocity impact experiments. The biomarkers were detected in ejecta fragments from experiments involving normal incidence of steel projectiles at 5–6 km s^?1, and in projectile fragments from impact experiments into sand and water at 2–5 km s^?1. The associated peak shock pressures were calculated to be in the range of 110–147 GPa for impacts of the steel projectiles into the siltstone target, and hydrocode simulations are used to show the variation of peak pressure with depth in the target and throughout the finite volume projectiles. Thermally sensitive biomarker ratios, including ratios of hopanoids and steranes, and the methylphenanthrene ratio, showed an increase in thermal maturity in the ejecta, and especially the projectile, fragments. Measurement of absolute concentrations of selected biomarkers indicates that changes in biomarker ratios reflect synthesis of new material rather than selective destruction. Their presence in ejecta and projectile fragments suggests that fossil biomarkers may survive hypervelocity impacts, and that experiments using biomarker‐rich rock have high potential for testing survival of organic matter in a range of impact scenarios.     

TiO2 II: The high-pressure Zr-free srilankite endmember in impact rocks

TiO₂II, a high-pressure polymorph of titanium dioxide, is a diagnostic indicator of shock metamorphism in impact rocks. Due to its typical micro-to-nanometer scale, there are no ab initio structure solutions of natural TiO₂II, thereby generating uncertainty about its crystal structure and its known similarity with srilankite (Ti_0.67,Zr_0.33)O₂. Nanoscale electron diffraction investigation of TiO₂II from the Australasian tektite strewn field provides the first ab initio structure solution revealing a primitive orthorhombic lattice with cell parameters a = 4.547 Å, b = 5.481 Å, c = 4.891 Å, and space group Pbcn, that is, the same as srilankite and scrutinyite α-PbO₂. The linear a and c decrease, and b increase with Ti content indicate TiO₂II as Zr-free srilankite endmember in the binary system ZrO₂-TiO₂. Thereby the name srilankite should be used referring to TiO₂II, according to the International Mineralogical Association recommendations. We provide the first evidence for a topotactic subsolidus rutile-to-TiO₂II transition, founding their finely intermixing nanocrystals in the same TiO₂ crystal, where TiO₂II is within the crystal and surrounded by rutile in direct contact. They also show recurrent iso-orientation, with TiO₂II [100] parallel to rutile [100], TiO₂II [010] parallel to rutile [011], and TiO₂II [001] parallel to rutile (0–11). The rutile-TiO₂II iso-orientation suggests the compression of rutile (0–11) planes as a possible transition mechanism from rutile to TiO₂II, with a consequent shortening of ~0.5 Å per cell. The presence of TiO₂II in the distal (~1200 km) impact ejecta from the Australasian tektite strewn field indicates shock pressures of ~12–15 GPa and post-shock temperatures below 500°C followed by rapid quenching.     

The reaction of carbonates in contact with laser-generated,superheated silicate melts: Constraining impact metamorphism of carbonate-bearing target rocks

We simulated entrainment of carbonates (calcite, dolomite) in silicate impact melts by 1-bar laser melting of silicate–carbonate composite targets, using sandstone, basalt, calcite marble, limestone, dolomite marble, and iron meteorite as starting materials. We demonstrate that carbonate assimilation by silicate melts of variable composition is extremely fast (seconds to minutes), resulting in contamination of silicate melts with carbonate-derived CaO and MgO and release of CO₂ at the silicate melt–carbonate interface. We identify several processes, i.e., (1) decomposition of carbonates releases CO₂ and produces residual oxides (CaO, MgO); (2) incorporation of residual oxides from proximally dissociating carbonates into silicate melts; (3) rapid back-reactions between residual CaO and CO₂ produce idiomorphic calcite crystallites and porous carbonate quench products; (4) high-temperature reactions between Ca-contaminated silicate melts and carbonates yield typical skarn minerals and residual oxide melts; (5) mixing and mingling between Ca- or Ca,Mg-contaminated and Ca- or Ca,Mg-normal silicate melts; (6) precipitation of Ca- or Ca,Mg-rich silicates from contaminated silicate melts upon quenching. Our experiments reproduce many textural and compositional features of typical impact melts originating from silicate–carbonate targets. They reinforce hypotheses that thermal decomposition of carbonates, rapid back-reactions between decomposition products, and incorporation of residual oxides into silicate impact melts are prevailing processes during impact melting of mixed silicate–carbonate targets. However, by comparing our results with previous studies and thermodynamic considerations on the phase diagrams of calcite and quartz, we envisage that carbonate impact melts are readily produced during adiabatic decompression from high shock pressure, but subsequently decompose due to heat influx from coexisting silicate impact melts or hot breccia components. Under certain circumstances, postshock conditions may favor production and conservation of carbonate impact melts. We conclude that the response of mixed carbonate–silicate targets to impact might involve melting and decomposition of carbonates, the dominant response being governed by a complex variety of factors.     

The fate of moderately volatile elements in impact events—Lithium connection between the Ries sediments and central European tektites

Lithium abundances and isotope compositions are presented for a suite of sediments from the surroundings of the Ries Impact structure, paralleled by new Li data for central European tektites (moldavites) from several substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia), including a specimen from the newly discovered substrewn field in Poland. The data set was supplemented by three clay fractions isolated from sedimentary samples. Moldavites measured in this study show a very narrow range in δ⁷Li values (?0.6 to 0.3‰ relative to L‐SVEC) and Li contents (23.9–48.1 ppm). This contrasts with sediments from the Ries area which show remarkable range in Li isotope compositions (from ?6.9 to 13.4‰) and Li contents (0.6–256 ppm). The OSM sediments which, based on chemical similarity, formed the major part of moldavites, show a range in δ⁷Li values from ?2.0 to 7.9‰ and Li contents from 5.8 to 78.9 ppm. Therefore, the formation of moldavites was apparently accompanied by large‐scale mixing, paralleled by chemical and isotope homogenization of their parent matter. The proposed Li mixing model indicates that sands, clayey sediments, and low volumes of carbonates are the major components for tektite formation whereas residual paleokarst sediments could have been a minor but important component for a subset of moldavites. Striking homogenization of Li in tektites, combined with limited Li loss during impacts, may suggest that moderately volatile elements are not scavenged and isotopically fractionated during large‐scale collisions, which is consistent with recent models. In general, whether homogenization of bodies with distinct Li isotope systematics takes place, or collision of bodies with similar Li systematics operates cannot be resolved at present stage but Li isotope homogeneity of solar system planets and asteroidal bodies tentatively implies the latter.     

Bosumtwi impact structure,Ghana: Geochemistry of impactites and target rocks,and search for a meteoritic component

Abstract— Major and trace element data, including platinum group element abundances, of representative impactites and target rocks from the crater rim and environs of the Bosumtwi impact structure, Ghana, have been investigated for the possible presence of a meteoritic component in impact‐related rocks. A comparison of chemical data for Bosumtwi target rocks and impactites with those for Ivory Coast tektites and microtektites supports the interpretation that the Bosumtwi structure and Ivory Coast tektites formed during the same impact event. High siderophile element contents (compared to average upper crustal abundances) were determined for target rocks as well as for impactites. Chondrite‐normalized (and iron meteorite‐normalized) abundances for target rocks and impactites are similar. They do not, however, allow the unambiguous detection of the presence, or identification of the type, of a meteoritic component in the impactites. The indigenous siderophile element contents are high and possibly related to regional gold mineralization, although mineralized samples from the general region show somewhat different platinum‐group element abundance patterns compared to the rocks at Bosumtwi. The present data underline the necessity of extensive target rock analyses at Bosumtwi, and at impact structures in general, before making any conclusions regarding the presence of a meteoritic component in impactites.     

Aorounga and Gweni Fada impact structures,Chad: Remote sensing,petrography, and geochemistry of target rocks

Abstract— Shuttle Radar Topography Mission data was used to investigate the Aorounga and Gweni Fada impact structures in Chad as part of a new remote sensing study. We believe the results of various data treatments provide extensive new perspective on the macro‐structural and topographic divisions for these two impact structures. Our remote sensing studies indicate revised diameters of Aorounga and Gweni Fada of 16 and 22 km, respectively. We selected samples from these two structures for their petrographic, geochemical, and Rb‐Sr and Sm‐Nd isotopic characteristics. In samples from both structures, evidence for shock metamorphism was found in the form of single or multiple sets of planar deformation features in quartz, which confirms the impact origin for both the Aorounga and Gweni Fada structures. The crystallographic orientations of PDFs indicate maximum shock levels of 20–30 GPa for samples from the central parts of both structures. The PDF orientations are characteristic for the orientations observed elsewhere in shocked sandstones, with the higher angles in the orientation histograms being fairly abundant. Geochemically, the rocks are typical upper‐crustal sandstones.