Fluids during diagenesis and sulfate vein formation in sediments at Gale crater,Mars

We model the fluids involved in the alteration processes recorded in the Sheepbed Member mudstones of Yellowknife Bay (YKB), Gale crater, Mars, as revealed by the Mars Science Laboratory Curiosity rover investigations. We compare the Gale crater waters with fluids modeled for shergottites, nakhlites, and the ancient meteorite ALH 84001, as well as rocks analyzed by the Mars Exploration rovers, and with terrestrial ground and surface waters. The aqueous solution present during sediment alteration associated with phyllosilicate formation at Gale was high in Na, K, and Si; had low Mg, Fe, and Al concentrations—relative to terrestrial groundwaters such as the Deccan Traps and other modeled Mars fluids; and had near neutral to alkaline pH. Ca and S species were present in the 10^?3 to 10^?2 concentration range. A fluid local to Gale crater strata produced the alteration products observed by Curiosity and subsequent evaporation of this groundwater‐type fluid formed impure sulfate‐ and silica‐rich deposits—veins or horizons. In a second, separate stage of alteration, partial dissolution of this sulfate‐rich layer in Yellowknife Bay, or beyond, led to the pure sulfate veins observed in YKB. This scenario is analogous to similar processes identified at a terrestrial site in Triassic sediments with gypsum veins of the Mercia Mudstone Group in Watchet Bay, UK.     

Detrital input and early diagenesis in sediments from Lake Baikal revealed by rock magnetism

A rock magnetic study was performed on sediment cores from six locations in Lake Baikal. For a comprehensive approach of the processes influencing the rock magnetic signal, additional data are presented such as total organic carbon (TOC), total sulphur (TS), opal, water content and relative variations in iron and titanium measured on selected intervals. In glacial sediments, the magnetic signal is dominated by magnetite, which is considered to be of detrital origin. This predominance of magnetite is interrupted by distinct horizons of authigenic greigite, probably confined to reductive microenvironments. In interglacial stages, besides dilution by biogenic silica and a decreasing detrital input, the weakness of the rock magnetic signal is also due to a reductive dissolution of magnetic particles. The magnetic assemblage is strongly linked to the redox history of interglacial sediment. In the oxidised bottom sediments of Lake Baikal, a biogenic magnetite is observed [Peck, J.A., King, J.W., 1996. Magnetofossils in the sediments of lake Baikal, Siberia. Earth Planet. Sci. Lett. 140 (1–4), 159–172]. After burial under the redox front, the magnetite is preferentially dissolved, and detrital hematite remains dominant when the sedimentation rate is low and when the residence time of the magnetite close to the redox boundary is long. During these low sedimentation rate conditions, the redox front is preserved [Granina, L., Müller, B. and Wehrli, B., 2004. Origin and dynamics of Fe and Mn sedimentary layers in Lake Baikal. Chem. Geol. 205 (1-2), 55-72]. At constant sedimentation rate and fast burial, the magnetite is preserved or transformed into greigite when sulphate-reducing conditions are reached in the sediment. In interglacial sediments, the magnetic assemblages depict changes in the sedimentation rate, which are traced using the ratio of magnetite over hematite (S-ratio). At the beginning of interglacials, the sedimentation rate is constant with an assemblage magnetite+greigite (high S-ratio), and at the end of some interglacials, the sedimentation rate decreases with a predominance of hematite (low S-ratio).     

Source, sea level and circulation effects on the sediment flux to the deep ocean over the past 15 ka off eastern New Zealand

The last post-glacial transgression and present highstand of sea level were accompanied by a reduction in the terrigenous flux to the deep ocean bordering the active convergent margin off the eastern North Island of New Zealand. Although in accord with long-established models of highstand shelf deposition, new data from giant piston core MD97 2121 (2314 m depth) reveal that the flux also varied with terrigenous supply and palaeocirculation. Between 15 and 9.5 ka, the flux reduced from 33 to 20 g/cm²/ka as supply declined with an expanding vegetation cover, and mud depocentres became established on the continental shelf. An increase from 20 to 27 g/cm²/ka during 9.5–3.5 ka coincided with a strengthened East Cape Current which probably introduced sediment from fluvial and shelf sources in the north. The flux profile shows no immediate response to the establishment of modern sea level 7 ka. However, accumulation decreased from 3.5 to 1 ka as more sediments were retained on the shelf, possibly under wind-strengthened, along-shelf currents. Over the last 1 ka, the flux decline halted under increased terrigenous supply during anthropogenic development of the land.Despite the proximity of the North Island's Central Volcanic Region, major eruptions caused only brief increases (centuries duration) in the terrigenous flux through direct deposition of airfall and possibly fluvial redistribution of onshore volcanic deposits. Frequent earthquakes also had little short-term effect on accumulation although such events, along with volcanism, probably contribute to the long-term high flux of the region.The other measured flux component, biogenic carbonate, reached maxima of 6 g/cm²/ka between 11 and 8.5 ka when nutrient-bearing waters of the East Cape Current dominated the palaeoceanography. After these peaks, carbonate accumulation declined gradually to modern levels of 3 g/cm²/ka.     

Potential of submarine-cave sediments and oxygen isotope composition of cavernicolous micro-bivalve as a late Holocene paleoenvironmental record

A sediment layer (43 cm thick) and surface sediments (5 cm thick) in a submarine limestone cave (31 m water depth) on the fore-reef slope of Ie Island, off Okinawa mainland, Japan, were examined by visual, mineralogical and geochemical means. Oxygen isotope analysis was performed on the cavernicolous micro-bivalve Carditella iejimensis from both cored sediments and surface sediments, and the water temperature within the cave was recorded for nearly one year. These data show that: (1) water temperature within the cave is equal to that at 30 m deep in the open sea; (2) the biotic and non-biotic environments within the cave have persisted for the past 2000 years; (3) mud-size carbonate detritus is a major constituent of the submarine-cave deposit, and may have come mainly from the suspended carbonate mud produced on the emergent Holocene reef flat over the past two millennia; (4) the δ¹⁸O-derived temperature (T_δ18_O) of C. iejimensis suggests that the species grows between April and July; (5) the T_δ18_O of C. iejimensis from cored sediments implies that there were two warmer intervals, at AD 340 ± 40 and AD 1000 ± 40, which correspond to the Roman Warm Period and Medieval Warm Period, respectively. These suggest that submarine-cave sediments provide unique information for Holocene reef development. In addition, oxygen isotope records of cavernicolous C. iejimensis are a useful tool to reconstruct century-scale climatic variability for the Okinawa Islands during the Holocene.     

Decadal to millennial cyclicity in varves and turbidites from the Arabian Sea: hypothesis of tidal origin

We have analyzed a Late Holocene record, almost 5000 years long, consisting of varved sediments deposited in the oxygen-minimum zone (OMZ) off Pakistan. We searched for cyclicity in the series of varve thickness (“varve” cycles), of unusually large excursions in varve thickness (“agitation” cycles), and of abundance of turbidites (“turbidite” cycles). We found the following high-frequency cycles (periods between 10 and 100 years) in one or several of the three types of series as follows: near 12.4, 14–15, 16.8, 18.6 (strong, agitation), 25–26 (strong, turbidite), 29–31 (strong, agitation), 39 (varve), 44 (strong, turbidite), 51–54 (strong, agitation), 56 (strong, varve), 64 (strong, turbidite), 69, 77 (strong, turbidite), 82 (very strong, agitation), and 95 years (strong, varve). Low-frequency cycles center around 99–115, 125 (very strong, varve), 164, 177, 202, 242–255 (strong, agitation and turbidite), 280 (strong, varve; doubled, turbidite), 340–370 and 460–490 years.Some cycles of varve thickness match the cyclicity of turbidite frequency (12.3, 14–15, 25–26, 245–255 years) but similarities between spectra are not striking. Taken as a whole, however, the sequence of cycles detected (by autocorrelation and standard Fourier analysis) seems to contain a large proportion of multiples of the basic tidal cycles 4.425 (lunar perigee cycle) and 9.3 years (lunar half-nodal cycle). This impression is supported by testing the three binned spectra for whole-number multiples and fractions as well as whole-number beat structure. We therefore propose that a large proportion of the cyclicity detected can be ascribed to tidal action. Our record also contains evidence for the presence of the 1470-year cycle previously reported from the glacial-age Greenland ice record. The main harmonics of this Greenland cycle can be tied to the pattern of periods seen in the varved sediments. We hypothesize that tidal action produces the cycle, and that the reason for its great length is the requirement that maximum tidal activity has to fall into a narrow seasonal window to be geologically effective.     

A qualitative assessment of the influence of bioturbation in Lake Baikal sediments

The impact of bioturbation in Lake Baikal sediments, particularly on rhythmic layering and mixing, was assessed by studying the actual vertical distribution of benthic animals in continuous accumulation zones selected by seismic survey (Vydrino Shoulder, Posolskoe Bank, Continent Ridge). To assess the influence of the bioturbation, animals were extracted from short cores and identified at the relevant taxonomic level. The faunal distribution is examined in parallel with the bioturbation tracks observed in thin section. Oligochaeta, Nematoda, Ostracoda, Copepoda, Gammaridae, Chironomidae and Hydrachnidia were found inhabiting the sediment. Among them, only oligochaete worms were assumed to have a significant impact on sediment mixing because of their “conveyor belt” feeding. The other two most abundantly sampled groups, nematods and copepods, belong to the interstitial fauna that has no significant impact on the vertical displacement of sediment particles and do not ingest the sediment. The presence of a benthic fauna as deep as 15 cm in the sediment indicates that the possibility of sediment disturbance by invertebrate activity cannot be dismissed in Lake Baikal. The effect of biological mixing is more limited in the deepest stations because the number of potential bioturbators is reduced, qualitatively as well as quantitatively. Located in the abyssal zone, Continent and Vydrino (but outside turbidites) deep stations appear to be most promising sediment records for tracking climate signal at high resolution.     

Geological indications for Palaeogene uplift in the eastern North Sea Basin

The timing and effect of the Cenozoic uplift of Scandinavia has been investigated using a multi-disciplinary approach involving sedimentological, seismic and biostratigraphic data from the Danish and the adjacent Norwegian parts of the North Sea Basin. It is concluded that significant uplift took place periodically throughout the Palaeogene possibly marking an earlier onset of the so-called “Neogene uplift” of Scandinavia. This conclusion is based on a number of sedimentological observations, including smectite content, grain-size variations, kaolinite thermal stabilities and T_max values supported by seismic reflection geometries and biostratigraphic data. These data indicate several phases of re-working of Palaeogene and older sediments situated further to the east and northeast during the middle to late Eocene and during the middle to late Oligocene. The tectonic patterns were similar during the late Paleocene and the Oligocene with some inversion taking place, whereas no inversion has been observed during the Eocene. Main provenance areas were to the north and northeast during the Paleocene and Oligocene, whereas the Eocene sediments originate mainly from the British Isles to the west. It is proposed that Palaeogene uplift of Scandinavia was associated with regional tectonic movements along crustal zones of weakness, which were reactivated as they accommodated strain induced by the Alpine Orogeny and the opening of the North Atlantic.     

Photochemistry of minor constituents in the troposphere

Altitude profiles for the number densities of NO, NO₂, NO₃, N₂O₅, HNO₂, CH₃O, CH₃O₂, H₂CO, OH, and HO₂ are calculated as a function of time of day with a steady-state photochemical model in which the altitude profiles for the number densities of H₂O, CH₄, H₂, CO, O₃, and the sum of NO and NO₂ are fixed at values appropriate to a summer latitude of 34°. Average daily profiles are calculated for the long-lived species, HNO₃, H₂O₂, and CH₃O₂H.The major nitrogen compound HNO₃ may have a number density approaching 5 × 10¹¹ molecules cm^?3 at the surface, although an effective loss path due to collisions with particulates could greatly reduce this value.The number density of OH remains relatively unchanged in the first 6 km and reaches 1 × 10⁷ molecules cm^?3 at noon, while the number density of HO₂ decreases throughout the lower troposphere from its noontime value of 8 × 10⁸ molecules cm^?3 at the surface.H₂O₂ and H₂CO both have number densities in the ppb range in the lower troposphere.Owing to decreasing temperature and water concentration, the production of radicals and their steady-state number densities decrease with altitude, reaching a noontime minimum of 1 × 10⁸ molecules cm^?3 for OH and 3 × 10⁷ molecules cm^?3 for HO₂ at the tropopause. The related minor species show even sharper decreases with increasing altitude.The primary path for interconverting OH and HO₂ serves as the major sink for CO and leads to a tropospheric lifetime for CO of ~0.1 yr.Another reaction cycle, the oxidation of CH₄, is quite important in the lower troposphere and leads to the production of H₂CO along with the destruction of CH₄ for which a tropospheric lifetime of ~2 yr is estimated.The destruction of H₂CO that was produced in the CH₄ oxidation cycle provides the major source of CO and H₂ in the atmosphere.     

Climate and carbon cycle changes under the overshoot scenario

The “overshoot scenario” is an emissions scenario in which CO₂ concentration in the atmosphere temporarily exceeds some pre-defined, “dangerous” threshold (before being reduced to non-dangerous levels). Support for this idea comes from its potential to achieve a balance between the burdens of current and future generations in dealing with global warming. Before it can be considered a viable policy, the overshoot scenario needs to be examined in terms of its impacts on the global climate and the environment. In, particular, it must be determined if climate change cause by the overshoot scenario is reversible or not, since crossing that “dangerous” CO₂ threshold could result in climate change from which we might not be able to recover. In this study, we quantify the change in several climatic and environmental variables under the overshoot scenario using a global climate model of intermediate complexity. Compared to earlier studies on the overshoot scenario, we have an explicit carbon cycle model that allows us to represent carbon-climate feedbacks and force the climate model more realistically with CO₂ emissions rates rather than with prescribed atmospheric pCO₂. Our standard CO₂ emissions rate is calculated on the basis of historical atmospheric pCO₂ data and the WRE S650 non-overshoot stabilization profile. It starts from the preindustrial year 1760, peaks in the year 2056, and ends in the year 2300. A variety of overshoot scenarios were constructed by increasing the amplitude of the control emissions peak but decreasing the peak duration so that the cumulative emissions remain essentially constant. Sensitivity simulations of various overshoot scenarios in our model show that many aspects of the global climate are largely reversible by year 2300. The significance of the reversibility, which takes roughly 200 years in our experiments, depends on the time horizon with which it is viewed or the number of future generations for whom equity is sought. At times when the overshoot scenario has emissions rates higher then the control scenario, the transient changes in atmospheric and oceanic temperatures and surface ocean pH can be significant, even for moderate overshoot scenarios that remain within IPCC SRES emissions scenarios. The large transient changes and the centennial timescale of climate reversibility suggest that the overshoot might not be the best mitigation approach, even if it technically follows the optimal economic path.     

Accumulation of particulate organic carbon at the Eurasian continental margin during late Quaternary times: controlling mechanisms and paleoenvironmental significance

Data on the amount and composition of organic carbon were determined in sediment cores from the Kara and Laptev Sea continental margin, representing oxygen isotope stages 1–6. The characterization of organic matter is based on hydrogen index (HI) values, n-alkanes and maceral composition, indicating the predominance of terrigenous organic matter through space and time. The variations in the amount and composition of organic carbon are mainly influenced by changes in fluvial sediment supply, Atlantic water inflow, and continental ice sheets. During oxygen isotope stage (OIS) 6, high organic carbon contents in sediments from the Laptev Sea and western East Siberian Sea continental margin were probably caused by the increased glacial erosion and further transport in the eastward-flowing boundary current along the continental margin. During OIS 5 and early OIS 3, some increased amounts of marine organic matter were preserved in sediments east of the Lomonosov Ridge, suggesting an influence of nutrient-rich Pacific waters. During OIS 2, terrigenous organic carbon supply was increased along the Barents and western Kara Sea continental margin caused by extended continental ice sheets in the Barents Sea (Svalbard to Franz Josef Land) area and increased glacial erosion. Along the Laptev Sea continental margin, on the other hand, the supply of terrigenous (organic) matter was significantly reduced due to the lack of major ice sheets and reduced river discharge. Towards the Holocene, the amount of total organic carbon (TOC) increased along the Kara and Laptev Sea continental margin, reaching average values of up to 0.5 g C cm⁻² ky⁻¹. Between about 8 and 10 ka (9 and 11 Cal ka), i.e., during times when the inner shallow Kara and Laptev seas became largely flooded for the first time after the Last Glacial Maximum, maximum supply of terrigenous organic carbon occurred, which is related to an increase in coastal erosion and Siberian river discharge. During the last 8000 years, the increased amount of marine organic carbon preserved in the sediments from the Kara and Laptev Sea continental margin is interpreted as a result of the intensification of Atlantic water inflow along the Eurasian continental margin.     

Volcaniclastic habitats for early life on Earth and Mars: A case study from ∼3.5 Ga-old rocks from the Pilbara, Australia

Within the context of present and future in situ missions to Mars to investigate its habitability and to search for traces of life, we studied the habitability and traces of past life in ∼3.5 Ga-old volcanic sands deposited in littoral environments an analogue to Noachian environments on Mars. The environmental conditions on Noachian Mars (4.1-3.7 Ga) and the Early Archaean (4.0-3.3 Ga) Earth were, in many respects, similar: presence of liquid water, dense CO₂ atmosphere, availability of carbon and bio-essential elements, and availability of energy. For this reason, information contained in Early Archaean terrestrial rocks concerning habitable conditions (on a microbial scale) and traces of past life are of relevance in defining strategies to be used to identify past habitats and past life on Mars.One such example is the 3.446 Ga-old Kitty’s Gap Chert in the Pilbara Craton, NW. Australia. This formation consists of volcanic sediments deposited in a coastal mudflat environment and is thus a relevant analogue for sediments deposited in shallow water environments on Noachian Mars. Two main types of habitat are represented, a volcanic (lithic) habitat and planar stabilized sediment surfaces in sunlit shallow waters. The sediments hosted small (<1 μm in size) microorganisms that formed colonies on volcanic particle surfaces and in pore waters within the volcanic sediments, as well as biofilms on stabilised sediment surfaces. The microorganisms included coccoids, filaments and rare rod-shaped organisms associated with microbial polymer (EPS). The preserved microbial community was apparently dominated by chemotrophic organisms but some locally transported filaments and filamentous mat fragments indicate that possibly photosynthetic mats formed nearby. Both microorganisms and sediments were silicified during very early diagenesis.There are no macroscopic traces of fossilised life in these volcanic sediments and sophisticated instrumentation and specialized sample preparation techniques are required to establish the biogenicity and syngenicity of the traces of past life. The fact that the traces of life are cryptic, and the necessity of using sophisticated instrumentation, reinforces the challenges and difficulties of in situ robotic missions to identify past life on Mars. We therefore recommend the return of samples from Mars to Earth for a definitive search for traces of life.     

“Stickiness” in mappings and dynamical systems

We present results of a study of the so-called “stickiness” regions where orbits in mappings and dynamical systems stay for very long times near an island and then escape to the surrounding chaotic region. First we investigated the standard map in the form x_i+1 = x_i+y_i+1 and y_i+1 = y_i+K/2π · sin(2πx_i) with a stochasticity parameter K = 5, where only two islands of regular motion survive. We checked now many consecutive points—for special initial conditions of the mapping—stay within a certain region around the island. For an orbit on an invariant curve all the points remain forever inside this region, but outside the “last invariant curve” this number changes significantly even for very small changes in the initial conditions. In our study we found out that there exist two regions of “sticky” orbits around the invariant curves: A small region I confined by Cantori with small holes and an extended region II is outside these cantori which has an interesting fractal character. Investigating also the Sitnikov-Problem where two equally massive primary bodies move on elliptical Keplerian orbits, and a third massless body oscillates through the barycentre of the two primaries perpendicularly to the plane of the primaries—a similar behaviour of the stickiness region was found. Although no clearly defined border between the two stickiness regions was found in the latter problem the fractal character of the outer region was confirmed.     

An interpretation of the rotational temperature of the airglow hydroxyl emissions

The rotational temperature of the airglow hydroxyl emissions arising from various schemes of vibrational transitions was obtained by using spectroscopic data from six observational sources. The rotational temperature was found to depend systematically on the quantum number (ν') of the upper vibrational level from which the relevant band originates. It has a doubly degrading characteristic with respect to ν' taking maximal values at ν' = 6 and 9, which exceed considerably the atmospheric temperature. It drops off quickly as ν' decreases from 9 to 7, and then from 6 to 3 after making an abrupt rise at ν' = 6. This ν'-dependence of the rotational temperature is in favor of the hypothesis that there are two routes of excitation of the hydroxyl airglow: O₃ + H = OH(ν ? 9) + O₂, and HO₂ + O = OH(ν ? 6) + O₂. The present result implies also that the relaxation time of rotation of OH in the upper mesosphere is as long as 0.1 sec; a value an order of magnitude larger than that inferred in earlier laboratory experiments.     

Nondestructive spectroscopic and petrochemical investigations of Paleoarchean spherule layers from the ICDP drill core BARB5, Barberton Mountain Land,South Africa

A Paleoarchean impact spherule‐bearing interval of the 763 m long International Continental Scientific Drilling Program (ICDP) drill core BARB5 from the lower Mapepe Formation of the Fig Tree Group, Barberton Mountain Land (South Africa) was investigated using nondestructive analytical techniques. The results of visual observation, infrared (IR) spectroscopic imaging, and micro‐X‐ray fluorescence (μXRF) of drill cores are presented. Petrographic and sedimentary features, as well as major and trace element compositions of lithologies from the micrometer to kilometer‐scale, assisted in the localization and characterization of eight spherule‐bearing intervals between 512.6 and 510.5 m depth. The spherule layers occur in a strongly deformed section between 517 and 503 m, and the rocks in the core above and below are clearly less disturbed. The μXRF element maps show that spherule layers have similar petrographic and geochemical characteristics but differences in (1) sorting of two types of spherules and (2) occurrence of primary minerals (Ni‐Cr spinel and zircon). We favor a single impact scenario followed by postimpact reworking, and subsequent alteration. The spherule layers are Al₂O₃‐rich and can be distinguished from the Al₂O₃‐poor marine sediments by distinct Al‐OH absorption features in the short wave infrared (SWIR) region of the electromagnetic spectrum. Infrared images can cover tens to hundreds of square meters of lithologies and, thus, may be used to search for Al‐OH‐rich spherule layers in Al₂O₃‐poor sediments, such as Eoarchean metasediments, where the textural characteristics of the spherule layers are obscured by metamorphism.     

Outgassing of ordinary chondritic material and some of its implications for the chemistry of asteroids, planets, and satellites

We used chemical equilibrium calculations to model thermal outgassing of ordinary chondritic material as a function of temperature, pressure, and bulk composition and use our results to discuss outgassing on asteroids and the early Earth. The calculations include ∼1000 solids and gases of the elements Al, C, Ca, Cl, Co, Cr, F, Fe, H, K, Mg, Mn, N, Na, Ni, O, P, S, Si, and Ti. The major outgassed volatiles from ordinary chondritic material are CH₄, H₂, H₂O, N₂, and NH₃ (the latter at conditions where hydrous minerals form). Contrary to widely held assumptions, CO is never the major C-bearing gas during ordinary chondrite metamorphism. The calculated oxygen fugacity (partial pressure) of ordinary chondritic material is close to that of the quartz-fayalite-iron (QFI) buffer. Our results are insensitive to variable total pressure, variable volatile element abundances, and kinetic inhibition of C and N dissolution in Fe metal. Our results predict that Earth's early atmosphere contained CH₄, H₂, H₂O, N₂, and NH₃; similar to that used in Miller—Urey synthesis of organic compounds.     

Periodicities in the occurrence rate of solar proton events

Power spectral analyses of the time series of solar proton events during the past three solar cycles reveal a periodicity around 154 days. This feature is prominent in all of the cycles combined, cycles 19 and 21 individually but is only weak in cycle 20. These results are consistent with the presence of similar periodicities between 152 and 155 days in the occurrence rate of major solar flares, the sunspot blocking function (P _s ), the 10.7 cm radio flux (F _10.7) and the sunspot number (R _z ). This suggests that the circa 154-days periodicity may be a fundamental characteristic of the Sun. Periods around 50–52 days are also found in the combined data set and in the three individual cycles in general agreement with the detection of this periodicity in major flares in cycle 19 and inP _s ,F _10.7, andR _z in cycle 21. The cause of the 155 day period remains unknown. The spectra contain lines (or show power at frequencies) consistent with a model in which the periodicity is caused by differential rotation of active zones and a model in which it is related to beat frequencies between solar oscillations, as proposed by Wolff.     

Photochemistry of the Martian atmosphere

A variety of models are explored to study the photochemistry of CO₂ in the Martian atmosphere with emphasis on reactions involving compounds of carbon, hydrogen, and oxygen. Acceptable models are constrained to account for measured concentrations of CO and O above 90 km, with an additional requirement that they should be in accord with observations of CO, O₂, and O₃ in the lower atmosphere. Dynamical mixing must be exceedingly rapid at altitudes above 90 km, with effective eddy diffusion coefficients in excess of 10⁷ cm² sec^?1. If recombination of CO₂ is to occur mainly by gas phase chemistry, catalyzed by trace quantities of H, OH, and HO₂, mixing must be rapid over the altitude interval 30 to 40 km. The value implied for the diffusion coefficient in this region is a function of assumptions made regarding the rates for reaction of OH with HO₂ to form H₂O and of the rate for reaction of HO₂ with itself to form H₂O₂. If rates for these reactions are taken to have values similar to rates used in current models for the Earth's stratosphere, the eddy diffusion coefficient at 40 km on Mars should be about 5 × 10⁷ cm² sec^?1, consistent with Zurek's (1976) estimate for this parameter inferred from tidal theory. Surface chemistry could have an influence on the abundances of atmospheric CO and O₂, but a major effect would imply sluggish mixing at all altitudes below 50 km and in addition would carry implications for the magnitude of the rates for reaction of OH with HO₂ and HO₂ with itself.     

Sources and sinks for atmospheric H2: A current analysis with projections for the influence of anthropogenic activity

Oxidation of CH₄ provides the major source for atmospheric H₂ which is removed mainly by reaction with OH. Biological activity at the Earth's surface appears to represent at most a minor sink for H₂. Anthropogenic activity is a significant source for both H₂ and CO in the present atmosphere and may be expected to exert a growing influence in the future. Models are presented which suggest a rise in the mixing ratio of H₂ from its present value of 5.6 × 10^?7 to about 1.8 × 10^?6 by the year 2100. The mixing ratio of CO should grow from 9.7 × 10^?8 to 2.3 × 10^?7 over the same time period and there should be a rise in CH₄ by about a factor of 1.5 associated with anthropogenically induced reductions in tropospheric OH.     

Stabilization and global climate policy

Academic and political debates over long-run climate policy often invoke “stabilization” of atmospheric concentrations of greenhouse gases (GHGs), but only rarely are non-CO₂ greenhouse gases addressed explicitly. Even though the majority of short-term climate policies propose trading between gases on a global warming potential (GWP) basis, discussions of whether CO₂ concentrations should be 450, 550, 650 or perhaps as much as 750 ppm leave unstated whether there should be no additional forcing from other GHGs beyond current levels or whether separate concentration targets should be established for each GHG. Here, we use an integrated modeling framework to examine multi-gas stabilization in terms of temperature, economic costs, carbon uptake and other important consequences. We show that there are significant differences in both costs and climate impacts between different “GWP equivalent” policies and demonstrate the importance of non-CO₂ GHG reduction on timescales of up to several centuries.     

Cs studies of dense cores in regions of high mass star formation: a survey of southern molecular masers

We searched for the CSJ = 2 – 1 emission towards 29 southern H₂O and H₂O/OH masers and 1 OH maser with the SEST radio telescope. We detected and mapped 24 CS emitting regions probably associated with 27 H₂O masers. The C³⁴SJ = 2 – 1 and COJ = 1 – 0 lines were also observed at the grid positions closest to the CS peaks. Four cores were mapped in the CSJ = 5 – 4 and C³⁴SJ = 2 – 1 lines.