重工业区高脆弱岩溶含水层中多环芳烃污染的初步研究

以西南岩溶地区某市重工业区为研究对象,采集水文地质单元内地下水和土壤样品,利用气相色谱-质谱法（GC-MS)测试美国环保署16 种多环芳烃（PAHs）优控物。初步研究表明,研究区地下水16种PAHs均被检出,浓度为1 135.79～1 361.26 ng/L,以菲、蒽、萘、屈、芘为主;地下水处于中等污染程度,其中苯并[a]蒽、屈、苯并[b]荧蒽、苯并[k]荧蒽4种浓度超过美国EPA2009《国家推荐的优先有毒污染物水质标准》标准;PAHs特征比值显示含水层中的PAHs来源于燃煤和炼焦污染源,与钢铁厂和化肥厂排放的特征有机污染物一致。研究区污染源下游大面积区域地下水已经受到PAHs污染,且出现排泄区PAHs浓度高于径流区的现象,岩溶含水层PAHs的污染主要受两方面影响:一是洼地、裂隙发育,断层破碎带和强风化白云岩等为PAHs在含水层中的运移提供了有利条件,同时污染源区内地下水大量开采加速了污染物向地下水的入渗;二是水电站建坝蓄水发电,江水水位抬高,河岸地下水排泄速度减慢,可能致使岩溶含水层中PAHs的自净能力减弱。生态风险评价显示地下水中菲、蒽、芘、苯并[a]蒽、苯并[b]荧蒽处于重污染风险,应采取措施降低污染风险。      

明月峡背斜南部张关—排花洞岩溶水系统地下水径流模式解析

川东明月峡背斜地下岩溶发育的强烈非均质性造就了独特的地下水径流模式,孕育出区域复杂的岩溶工程水文地质问题,查明明月峡背斜南段地下水径流模式对指导区内隧道工程选址及建设具有重要意义。文章在已有研究基础上,以“张关—排花洞”岩溶水系统为研究区,通过系统厘清区内水文地质条件,深入剖析区内地下水水文地球化学特征及水动力条件,明确区内岩溶含水介质不均一性控制下的地下水小尺度径流规律。结果显示:研究区地下水在平面上表现为形似“扫帚状”的径流模式:在补给、径流区,三叠系下统嘉陵江组一段（T₁j1）、嘉陵江组三段(T₁j3)地层（强岩溶化）与嘉陵江组二段（T₁j2）、嘉陵江组四段 （T₁j4）地层（弱岩溶化）呈间互状分布的特点导致相邻地层之间水力联系较弱,以地层为单位形成多个相对独立的岩溶水子系统;在研究区排泄区,受控于势汇最强的T₁j3内部管道流对其他地层地下水持续的袭夺效应,地下水统一汇聚至排花洞暗河出口向御临河排泄,各岩溶水子系统最终整合为一个岩溶水系统。      

岩溶地下水位对降雨响应的时空变异特征及成因探讨——以广西桂林甑皮岩为例

岩溶地下水位对降雨响应具有时空变异性,甑皮岩遗址地下水动力系统结构的认识存在分歧。利用高分辨率降雨水位数据,将研究区分割为不同含水体,通过水位动态、相关分析、滑动窗口采样相关分析等方法,探讨岩溶地下水对降雨响应时空变异特征及成因。结果表明,岩溶强发育、扩散流导水的含水体水位对降雨的响应表现为缓升缓降,水位自相关性强;发育岩溶管道的含水体水位表现为陡升陡降,水位自相关系数衰减速率快,对降雨响应的滞后时间短,互相关函数图呈多峰型;岩溶发育的极不均匀性是造成空间响应差异的主要原因。雨季地下水位对降雨响应的滞后时间远小于枯季;雨季累积降雨量大、水位埋深浅、包气带长期处于饱和或者近饱和状态,降雨垂直入渗补给历时短;雨季暴雨频繁导致含水体地下水短期内形成较大水力梯度,径流补给速度加快。综合分析认为,甑皮岩遗址地下水动力系统由NE向岩溶管道、NS向管道-裂隙以及NE向强径流带3个子径流系统组成。     

Karst flash flooding in a Mediterranean karst, the example of Fontaine de Nîmes

Karst flash flooding, identified as one of the hazards in karst terrains, is directly linked to the structure and hydraulic properties of karst aquifers. Due to the characteristics of flow within karst aquifers, characterized by a dual flow – diffuse flow within fissured limestone and conduit flow within karst conduits networks – flash flooding may be important in volume and dynamics. Such phenomenon may cause serious damages including loss of lives, as it occurred on 3rd October 1988 in Nîmes (Gard, South France). Flash floods there have been considered to be the result of very intensive rainfall events conjugated to runoff due to the geomorphologic context of the city located down hill. However, preliminary results of recent studies of the hydrologic behaviour of groundwater and surface water for a specific event (September 2005) show that the karst plays an important role in the flood genesis. The main characteristics of the Nîmes karst system leading to karst flash flooding are presented in this paper. A methodology comprising modelling of the karst system allowed proposing simple warning thresholds for various part of the karst (water level threshold for the karst conduits and cumulative rainfall threshold for the overflowing fissured karst). These thresholds can be included in the flash flood warning system of the Nîmes city.     

西南地区隧道工程条件下岩溶地下水系统变化特征分析

岩溶山区越岭长大隧道的施工不可避免地会使当地的岩溶水系统发生改变,如地下水水位的下降、地表泉点的漏失等。基于隧道工程对岩溶地下水系统边界条件、排泄状况等天然特征的影响,依据西南地区岩溶地下水系统主要特征及隧道工程特点,考虑隧道工程条件下影响岩溶地下水系统特征的主要因素,对岩溶类型(岩溶含水岩组的埋藏条件)、构造特征、补给特征、岩溶水径流方式与隧道工程特点相组合的模式下的岩溶地下水系统的变化进行特征分析,并将岩溶地下水系统的变化归纳为3种类型。据此,选择研究区金汁河地下水系统作为典型研究对象,假设3种隧道穿越方案,将不同隧道穿越方案下的岩溶地下水系统与天然岩溶地下水系统进行对比分析,归纳概述其变化特征,最后对各隧道方案下的涌水量及其涌水危险性进行初步预测及评价。     

Karst groundwater protection in the Kupa River catchment area and sustainable development

One of the most significant water resources in the Republic of Croatia is the catchment area of the Kupa River, located in the region bordering the Republic of Slovenia. About 88% of the total amount of water in this catchment originates in Croatia and just 12% from Slovenia; therefore, the largest part of the catchment area (about 1000 km²) is on the Croatian side of the border. It is a typical karst area of the Dinarides with aquifers characterized by a relatively rapid water exchange, high groundwater flow velocities and aquifers open to human impact from the surface. Consequently, the aquifers are highly vulnerable and at risk. Due to the availability of large quantities of high-quality spring water (about 6 m³/s), the entire area has a strategic importance within the context of any future development strategy pertaining to the western part of Croatia. The catchment area on the Croatian side was investigated using a wide range of research methods that included a classical hydrogeological approach, the detailed hydrologic calculation of water balance to the hydrogeochemical analyses and modelling. The objective was to determine protection zones and protection measures for the whole area. The difficulties are increased due to the fact that the karst catchment area is crossed by major traffic corridors, oil pipelines and a railway and that many settlements and a highly developed wood industry are present. The combination of protecting water resources with adequate prevention measures and necessary remedial activities that should satisfy the very strict requirements necessary for the protection of the karst aquifers while still allowing for present and future human activities is difficult – but not impossible – to achieve. One good example is the present highway with a closed dewatering system and waste water treatment before the water passes into the karst underground system.     

南方小型岩溶流域与非岩溶流域的释水过程及径流组分差异

我国南方岩溶流域和非岩溶流域下垫面条件和含水介质结构的差异造成了不同的产汇流过程及机制,进而导致不同释水时段径流组分的开发利用价值不同。为深入理解岩溶流域的产汇流机制并探索岩溶流域的水资源评价方法,文章对鄂西庙沟岩溶流域和高家坪非岩溶流域共31次洪水过程进行了流量衰减分析,对比分析了两个流域的标准衰减方程、典型次降雨的释水过程以及不同洪峰流量下的径流组分差异。结果表明:岩溶流域的释水过程快于非岩溶流域,其衰减系数比非岩溶流域大40％;两个流域的河流基流均来自裂隙介质释水,裂隙介质为流域的主要储水空间,但非岩溶流域的裂隙介质比例比岩溶流域高8.8％;随洪峰流量增加,两个流域的地表径流占比均呈对数形式增大,地下径流占比均呈对数形式减小;岩溶流域径流组分随洪峰流量变化比非岩溶流域更为敏感,其地表径流占比变幅为4％~40％,而非岩溶流域则始终小于10％。文章定量评价了管道和裂隙介质在流域中的导水及储水功能,在进一步刻画岩溶流域产汇流过程及机制方面进行了有益的探索,研究结果可为岩溶山区水资源评价和流域水文模型的改进提供科学依据。     

邯峰矿区岩溶含水层特征及富水性分区

邯峰矿区岩溶含水层主要是寒武系、奥陶系厚层灰岩、石炭系薄层石灰岩,其中以奥陶系中统含水层富水性最为丰富,具有随埋藏深度增大而岩溶发育减弱的特性。根据岩溶水补、径、排条件,邯峰矿区岩溶水可分为黑龙洞、白龙洞、紫泉岩三个子系统,各子系统又根据岩溶发育程度、钻孔单位涌水量、水井单井出水量等富水性特征划分为四个区,研究了地下水动态特征,提出了保护岩溶地下水资源的建议。     

KARSTIC: a sensitivity method for carbonate aquifers in karst terrain

. Groundwater in karstic aquifers can be dangerously sensitive to contamination. Many cities in the western USA rely on karstic carbonate aquifers for municipal water supplies. For example, Rapid City, South Dakota, pumps more than half of its drinking water from wells in the Madison Limestone. This work examined the sensitivity of karstic aquifers to surface contamination in mountainous terrain. Where karstic carbonate aquifers are exposed at their outcrop areas, they are particularly susceptible to the introduction of contamination through diffuse recharge or through point recharge at swallow holes along streams. Residential developments in mountainous regions of the western USA are encroaching on the recharge areas of karstic aquifers. Many of these residential developments are served by onsite wastewater disposal systems such as septic tanks and drain fields, with the attendant danger of introduction of pathogens from malfunctioning treatment systems above fractured limestone which offers little filtering. Where streams disappear into karstic aquifers at swallow holes, microbial contaminants such as Giardia or Cryptosporidium are a concern, as well as potential spills, leaks, or accidents along roads near these streams. The KARSTIC method developed and modified in this work puts greater emphasis on karst features than previous sensitivity procedures such as the US Environmental Protection Agency's DRASTIC method. The modified method gives increased attention to highly sensitive areas of karstic carbonate aquifers by weighting the synergistic effects of fracturing, karst development, and swallow holes of recharging streams. In a field application, hydrogeologic maps of a watershed in the Black Hills, USA, were digitized into a geographic information system. The resulting sensitivity map and report can be used by planners, managers, and the public as a screening tool for assessing groundwater sensitivity in regions which include karstic aquifers.     

北京岩溶水系统划分及特征分析

岩溶水是北京市重要的战略后备水源,在城市供水方面发挥了重大作用,岩溶水系统划分对于掌握岩溶水资源、合理开发利用岩溶水是至关重要的。本文结合地质构造、地形地貌、水文地质条件,考虑含水岩组的连续性、不同级别地表水分水岭、地质构造的水文地质性质,将北京地区划分为3个一级岩溶水系统、7个二级岩溶水系统、16个三级岩溶水系统。其中隐伏型岩溶水系统无裸露的可溶岩或零星分布,天然资源少,地下水径流方向主要受开采影响,与上覆孔隙水有密切的水力联系。山前型岩溶水系统可溶岩分布于山区和平原,岩溶水天然补给资源丰富,含水层厚度大、分布广,调蓄能力强,开发利用程度高,排泄区有明显的阻水边界,储水能力强。山区型岩溶水系统可溶岩分布于山区,地下水向河谷、低洼处径流,排泄速度快,储存能力差,开采井零星分布,开发利用程度低。     

岩溶地下水脆弱性评价研究

岩溶地下水脆弱性评价是基于保护岩溶含水层从而有效地管理和利用地下水提出的有效方法和手段。岩溶含水层的特殊性导致污染物极易进入地下含水层,并在岩溶管道中快速、远距离地运移。与其他基岩第四系含水层相比,岩溶含水层的保护面临更大的挑战。介绍了地下水脆弱性的概念;以及岩溶地下水脆弱性的相关问题,并讨论了岩溶区脆弱性评价应考虑的一些问题。     

北京西山岩溶水中硝酸盐来源及迁移特征

西山岩溶水作为北京市重要的供水水源,在区域水文地质调查过程中发现西山岩溶水补给区一些样品硝酸盐浓度偏高,然而其周围岩溶水中硝酸盐浓度并未见明显变化（浓度均值为18.81 mg/L）,具点状硝酸盐源特征。岩溶含水层中硝酸盐分布特征和影响因素具有重要的研究意义。文章利用岩溶水化学和同位素分析结果研究了岩溶水硝酸盐分布和来源,利用IsoSource软件计算各来源的贡献率。结果表明:军庄—永丰屯径流区和军庄—古城—玉泉山泉径流区岩溶水中硝酸盐主要来源于生活废水、土壤有机氮矿化和大气沉降,贡献率值分别为37.1%、36.3%、26.6%;潭柘寺—四季青岩溶水中硝酸盐在潭柘寺补给区有养殖场废水下渗影响,径流区中硝酸盐含量低并发生反硝化降解作用。永定河水源硝酸盐不是岩溶水硝酸盐的主要来源。研究成果对西山岩溶水中硝酸盐的控制具有重要参考价值。     

Transformations and hydraulic captures of petrochemical contaminants in a karst-fractured aquifer

 The development of a petrochemical industry may be responsible for petrochemical contamination of karst-fractured aquifers in an urban water supply system. In the Dawu Well Field, a karst-fractured aquifer in Zibo City, in the east of China, has been seriously polluted by petrochemicals from the operation of petrochemical plants. More than 60 species of organic contaminants have been detected in the water supply wells of the Liuhang-Hougao zone, in the west part of Dawu Well Field. Investigations indicate that contaminants are transported from the petrochemical plants to the karst-fractured aquifer along karst fractures and the Jinling Fault. In the groundwater, concentrations of pollutants vary with depth. Concentrations are greater with depth because of the transmissibility of the Jinling fault. The local convective flow field has a significant influence on transportation of contaminants. Hydraulic barriers can prevent the transportation of contaminants and they can be removed by extraction. Received: 22 October 1999 · Accepted: 14 February 2000     

Increase of vulnerability of karst aquifers due to leakage from landfills

Karst aquifers are very vulnerable to various pollution sources. Among these, landfills can contribute contaminants over long periods. Groundwater quality monitoring is required to assess the impact of a landfill leachate on underlying aquifer water or spring discharge. Tracer tests are useful for selecting the location and frequency of sampling. Three landfill sites in karst areas were studied with tracer tests. Additional insight was accomplished by the comparison of the tracer transfer and the breakthrough curves obtained from these tests with the results of two other tracer tests carried out in the same period in karst areas without a landfill. To explain the differences observed, the hypothesis of increased permeability below the landfill due to the presence of inorganic acids in leachates was further tested. The results of detailed, long-term monitoring of contaminated drip water in the Postojna Cave were used to verify the hypothesis. The analysis of the simultaneously increased content of calcium, magnesium, and contaminants in the drip water indicates a direct correlation between limestone dissolution and contaminants. Increased dissolution increases secondary porosity and thus permeability of the vadose zone resulting in higher vulnerability of underlying aquifers and springs in the vicinity landfills.     

水化学特征在岩溶水系统分析中的应用——以山西晋城长河流域岩溶水系统为例

通过对长河流域岩溶水矿化度、Ca^2＋／Mg^2＋、Ca／Sr及Mg／Sr等的特征分析,长河流域岩溶水系统从补给区到径流区、排泄区矿化度、Can／Mgn、Ca／Sr及Mg／Sr变化具有明显的规律性,岩溶水的流动方向则与以上各水化学指标质量浓度的变化方向一致,即研究区在东、北部灰岩裸露区直接接受大气降雨补给渗漏及部分半裸露区间接补给渗漏,向西以泉水形式排泄到沁河河谷地带,形成沁河河谷排泄带,地下水径流方向为南西西方向。并分析岩溶地下水的径流特征,富水强弱,水岩作用强弱及岩溶裂隙发育规律特征。     

穿透曲线反演管壁溶质通量的实验研究

泉口穿透曲线提供了一个便捷有效的方法来研究岩溶含水层中污染物的运移。在旱季,滞留在石灰岩中的污染物通 过岩壁释放入管道,与管道水相混合并运输到下游泉口,因此,泉口穿透曲线能够反演出污染物释放时的管壁溶质通量。 笔者利用一个基于运移稀释模型的解析解,由40条实验室测量的穿透曲线来反演出相应的管壁溶质通量。结果表明,其基 本形状与穿透曲线相似,管壁透水的非均匀性在穿透曲线上明显表现出来,而在管壁溶质通量上表现为强振荡。因此,管 壁溶质通量比泉口穿透曲线对管壁透水的非均匀性有更高的分辨率。该通量是一个连接泉口穿透曲线和污染物在岩石中早 期分布的中间量,本文提供了一种研究管壁污染物释放过程的新方法。     

广东地区某公路岩溶隧道水害分析及其数值模拟研究

结合岩溶区公路隧道的实际情况,研究隧道涌水量计算的关键因素,并通过降水量、降水强度和入渗强度定量分析隧道涌水量。文章根据大宝山的实际情况,采用降水入渗法和地下径流模数法计算隧道两侧洞口段雨季涌水量,针对强降水过程,分析隧道可能出现的最大涌水量。研究结果表明:隧道排水能力理论上可满足降雨的排水要求,但实际排水能力受工程施工材料、工程的不均匀性以及长期的淤堵等因素影响。文章明确了广东地区公路岩溶隧道水害影响因素,考虑临界状态和破坏状态的水压力建立岩溶隧道涌水模拟模型,水压力临界值随隧道衬砌结构厚度的增加逐渐增大。      

西南某岩溶区地下水系统示踪试验与解析

以西南某典型岩溶区为例,解析示踪试验在岩溶管道连通性以及获取水文地质参数中的应用。选择落水洞为投放点,分别从落水洞西侧和东侧寻找地下水出露点作为接收点,判别落水洞地下径流的实际去向以及落水洞与接收点之间的水力联系。结合Qtracer2软件对示踪试验成果进行定量解析,确定示踪剂回收率、地下水平均流速、最快流速,估算出岩溶管道结构特征和水文地质参数。结果表明:落水洞与接收点JS01、JS03之间不存在直接水力联系;落水洞与接收点JS02存在水力联系且岩溶管道极为发育,含水介质不均匀,地下水运移路径较为通畅,为典型的紊流流态;落水洞地下径流的主要方向是由西向东,但在丰水期雨量较大期间,接收点JS04能够接收到荧光素钠,说明丰水期水位上涨后两者间会有水力联系,导致部分水量向落水洞西侧排泄。     

Characterizing groundwater flow in a faulted karst system using optical brighteners from septic systems as tracers

This study used optical brighteners (OB) released from septic systems to show that groundwater flow direction is largely controlled by the structural framework in a faulted karst groundwater system. Effective protection of groundwater resources requires that groundwater systems are adequately characterized and source water protection areas (SWPA) are developed for drinking water wells. Karst aquifers are among the most sensitive to contamination due to high recharge rates, and among the most difficult aquifers to characterize due to heterogeneity, and anisotropy. Because septic systems may be used to treat wastewater within SWPAs for karst aquifers there is a need to characterize these groundwater systems using tracers. The objective of this study was to characterize groundwater flow in a faulted portion of the Edwards aquifer in Bexar County, Texas using OB that are released as incidental tracers from septic systems. This study included measurement of water levels, sampling of groundwater and surface water, analysis for OB, and spatial analysis in a GIS. Results show that OB intensities were highest to the southwest of the septic area, a direction that is sub-parallel to the fault and fracture orientation and nearly perpendicular to the hydraulic gradient. This indicates that movement of OB, solutes, or non-aqueous liquids/solids in a faulted karst system can be largely controlled by fault/fracture orientation and structural relay ramps.     

沪蓉高速公路乌池坝隧道区岩溶发育特征及其涌水分析

乌池坝隧道区有6种岩溶地貌类型,涉及2个岩溶水系统（3条地下河）。其中白岩坝地下河发育受碳酸盐岩层组类型控制,管道结构单一,具有侧向补给、纵向排泄的水文地质特征;龙潭和毛田地下河发育受构造控制,具有多分支、多级排泄的特征。本文将乌池坝隧道分成3部分5个岩溶区段,评价了各区段岩溶发育对隧道涌水的影响,认为从ZK256＋300至ZK257＋000段,岩溶涌水可能性极大。采用大气降水入渗系数法和地下水疏干法,对各岩溶区段隧道涌水进行计算预测,其中ZK256＋300至ZK257＋500段涌水量达31．3×10^4m^3／d。[