我国北方典型岩溶地下水位对降水及气象指数的响应特征——以鲁中地区为例

我国北方岩溶水资源是其经济社会发展的重要资源基础,表征水资源赋存特征的岩溶地下水位动态及其影响因素分析能够为岩溶水资源管理及合理开发利用提供重要支撑。本文选取鲁中地区3个典型水文地质单元,基于2010-2017年月值降水、地下水位及NPI气象指数数据,采用小波分析方法对上述指标的周期性、响应特征及遥相关特征进行了分析。结果表明:（1）各岩溶地下水位动态、降水与NPI的主波动周期均为1 a,其显著周期与分布时段等的异同是受自然条件和人类活动共同作用的结果。（2）各水文地质单元岩溶水位对降水的响应时滞为95.81~146.64 d,其差异主要源于观测站所处的地下水流系统的位置的不同。（3）NPI与降水存在一定的遥相关,与受降水影响的岩溶水位动态也存在遥相关。各岩溶水位对NPI的遥相关时滞为111.75~169.77 d,相比水位对降水时滞有所增加。鲁中岩溶地区地下水位对降水与NPI存在规律性的响应时滞,此种特征可为我国北方岩溶地下水位的预警预报提供帮助。      

近50年济南岩溶泉域地下水位对降水响应的时滞差异

依据近50年降水及年均水位等的差异,将1959-2011年济南岩溶泉域地下水位与降水观测数据划分为若干时段。采用小波变换方法定量分析了泉域地下水位对降水的响应时滞,并采用相关分析讨论了时滞与地下水开采量等的关系。结果表明,(1)泉域地下水位与降水的主周期均为1 a。(2)两种划分方式下,泉域排泄区水位时滞分别为83.44~161.24 d、88.62~150.56 d,径流区水位时滞分别为67.87~81.66 d、76.58~82.21 d,径流区水位时滞明显小于排泄区。(3)依据降水划分的时段,排泄区与径流区均有随年降水减少,水位时滞增加的趋势。(4)依据水位划分的时段,排泄区有随水位降低,时滞增加的趋势,而径流区不明显。(5)泉域水位时滞与泉域地下水开采量、泉群流量等存在相关关系,泉域开采量越大,泉群流量越小,则水位时滞相对越大。上述时滞差异分析,有助于增加地下水位与降水之间的非线性耦合过程的认识,可为地下水位的预报预警提供帮助。      

运用水文时间序列分析识别济南泉域岩溶发育特征

岩溶含水层具有高度的非均质性和各向异性,为定量识别济南泉域岩溶含水层发育状况,通过选取泉域岩溶水补给区和排泄区的地下水位动态数据,采用相关分析和频谱分析,研究其对降雨补给的响应特征.地下水位-降雨量的自相关和互相关分析表明,系统对降雨输入信号的敏感程度自补给区至排泄区逐渐降低,但记忆作用逐渐增强.相位分析结果表明泉域地下水位对降雨信号的响应存在滞后现象,自补给区至排泄区滞后时间逐渐延长,补给区地下水位与降雨具有更好的线性相关性.交叉振幅分析结果表明补给区地下水流中快速流约占20%~30%,而在排泄区快速流占比减少至2.5%~10.0%.岩溶含水系统地下水动力条件主要受岩溶发育程度等介质内部结构影响,济南泉域岩溶含水层岩溶发育程度较低,含水介质和水流通道以岩溶裂隙为主,地下水运动以基质流为主.      

基于小波分析与Mann-Kendall法的岩溶大泉动态研究

研究地下水动态是认识地下水资源的有效手段。根据1956－2013年济南岩溶泉域大气降水及地下水水位动态监测资料,采用小波分析法、Mann-Kendall趋势检验、突变检验法研究了58个水文年泉水位对大气降水的响应,可以看出:（1）大气降水和泉水位呈现出多尺度的变化特征,长时间尺度上两者的变化周期基本相同,变化周期为16年和12年,说明大气降水对泉水位有直接影响;（2）在1956—2013年,济南泉域地下水水位具有0.65 m·（10a）-1的年际显著下降趋势,但降水具有12.65 mm·（10a）-1的不显著上升趋势,说明在人为因素影响下泉水动态的影响因素的权重发生了变化;（3）大气降水在1999年发生突变,1999年之后年降水为增加趋势;而地下水水位突变年份为1967年,1967年以后水位持续降低,2004年以后水位快速上升,泉水位未来趋势应与降水保持一致,呈上升趋势,说明大气降水并非泉水动态的唯一影响因素;（4）通过建立不同时段的多元回归模型,表明近58年来地下水水位的主要影响因素由大气降水到人工开采之间的转换,同时验证了小波分析和Mann-Kendall法研究地下水动态的适宜性和可靠性,也为济南市的保泉提供了参考依据。      

济南泉域地下水位动态及其对降水响应的交叉小波分析

利用1988—2009年济南泉域8个地下水位动态观测点不同时段观测资料及1998—2009年降水数据,采用连续小波变换、交叉小波变换方法对济南泉域地下水位动态的多时间尺度特征、相互关系及其对降水的响应进行了分析。结果表明:①济南泉域地下水位动态存在显著的0.82～1.16 a的主振荡周期,低频部分仅在部分年份存在1.95～3.09 a的振荡周期;②含水岩组富水性对地下水位动态存在影响,研究区主径流方向上弱富水性地段地下水位动态时滞较强富水性地段长,强富水性地段4个观测孔地下水位波动时序基本一致;③地下水位动态对降水的响应滞后明显,为73.06～134.42 d,总体表现为地下水径流路径越长,响应越滞后;④基于地下水位动态与基于降水—地下水位动态交叉小波变换得到的观测点对水位动态的滞后时间多数一致,同一径流路径上局部点对滞后时间之和与全局点对有很好的对应关系。交叉小波分析可定量评价泉域地下水位动态及其与降水的相关关系。     

济南泉域边界条件、水循环特征及水环境问题

济南泉域是市区泉水的汇流及蓄水范围,在其北部城区中心地带出露趵突泉、黑虎泉、五龙潭和珍珠泉四大泉群。为更好地保护和利用济南泉域内岩溶地下水,文章对济南泉域的边界条件、岩溶主径流通道、地下水循环特征及水质变化几个敏感问题进行探讨。利用泉群流量相关分析、流场特征分析、回灌补源分析及自备井调查等手段,重新界定了济南泉域的东边界,将其北部透水段向东扩展至原边界以东约4 km。通过对钻孔岩溶分层统计及缓冲区分析,在山前地带沿党家庄－十六里河－千佛山断裂泉城公园方向地下埋深100~150 m发现一条补给四大泉群的岩溶地下水集中径流带。研究发现,五龙潭和珍珠泉以深循环为主,补给主要来自岩溶地下水,而趵突泉和黑虎泉同时受深循环和浅循环影响较大,趵突泉主要补给来自西部和南部岩溶地下水和地表水,除此以外黑虎泉在东南方向上还有一定量的岩溶地下水补给。目前岩溶水水质变差,南部岩溶裸露区,尤其水库河道周边地带,生态环境亟待治理。      

地下水环境容量初探——以济南泉域为例

分析了水环境容量的内涵和地下水资源开发利用产生的环境效应,探讨了地下水环境容量的概念,认为地下水环境容量是用来表征一定目标约束下,地下水系统对自然或人类活动影响所能承受能力的最大阙值,其评价指标可采用地下水临界水位、可持续开采量、TDS、水温、纳污能力等单项指标或多项综合指标。以济南泉域为例,采用地下水位与泉流量作为济南泉域岩溶地下水环境容量的阙值,论证了地下水环境容量的动态可变性。最后指出了地下水环境容量研究的发展趋势。     

大气降水与济南泉水动态变化的定量关系研究

济南保泉历经40多年历史,历年枯水期泉水一直受到断流威胁。针对济南泉水动态变化现状,采用相关分析法,研究不同时间尺度下大气降水与泉水动态的关系。研究表明:济南泉域岩溶地下水的主要的补给来源是大气降水,泉水位高低主要受降雨大小的影响;大气降水对泉水位的影响具有滞后性特点;不同时间尺度下累计降水量回归分析得出兴隆雨量站、燕子山雨量站对泉水位影响滞后时间较短;在现状开采条件下,当旬降雨量累计值大于17.58 mm时对泉水位回升有积极的影响。综合济南泉域岩溶水流向、各雨量站距泉的距离、降雨对泉水位影响的滞后时间、各雨量站降水大小与泉水位变幅的关系程度等方面,得出兴隆雨量站所在区域降雨对泉水位的影响较大,是适宜的保泉补源地,能达到科学补源保泉的目的。     

水化学特征揭示的济北地热水与济南泉水关系

以济南北部地热田地热水及济南泉域岩溶地下水、泉水为研究对象,通过分析常规离子、微量元素及同位素,探讨了地热水的成因机理、补径排及地热水与上游泉域岩溶地下水、泉水的水力联系。研究认为,研究区地热水与岩溶地下水、泉水为同源补给,地热水属海相含盐沉积岩溶滤水。通过对氢氧稳定同位素和氚同位素法测年结果的分析,初步判定现代大气降水为地热水的主要补给来源。14C法测年结果分析表明,地热水接受更新世古降水补给,地热水为古降水和现代大气降水的混合水。      

雄安新区地下水水位与降水及北太平洋指数的小波分析

基于1991—2016年雄安新区4个地下水监测孔的长时间序列水位数据、降水数据及北太平洋指数（North.Pacific.Index,NPI）,采用连续小波、交叉小波变换等方法,分析了三者的周期性变化及其之间的相互关系。结果表明:（1）雄安新区地下水水位、降水与NPI的主波动周期及各序列间共振周期均为1.a。（2）丰水年的地下水水位时滞小于全时段的地下水水位时滞,高降水量对潜水-承压水水位时滞的影响大于对承压水的影响。（3）地下水水位对NPI的时滞大于对降水的时滞;在丰水年,地下水水位对NPI的响应更快;地下水对降水和NPI的响应速度,明确反映了研究区地下水水位动态变化的主要气候影响因素是降水。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.