Implications of correlated Nd and Sr isotopic variations for the chemical evolution of the crust and mantle

Published data showing a linear correlation between initial Nd and Sr isotope compositions in young basalts indicate the existence of a spectrum of isotopically distinct reservoirs in the mantle which represent either (1) mixtures of two homogeneous endmember reservoirs, one of which may be undifferentiated material or (2) fractionated reservoirs all derived from a homogeneous initial reservoir with the same ratio of enrichment factors for Sm/Nd and Rb/Sr. The slope of the correlation, which can be described approximately by (⁸⁷Sr/⁸⁶Sr) = ?3.74114 (¹⁴³Nd/¹⁴⁴Nd) + 2.61935orε_Nd = ?2.7 ε_Sr, places constraints on the origin of these reservoirs and hence on the chemical evolution of the crust-mantle system. The reservoirs could be residual regions of the mantle left after ancient partial melting events. If so, the requirement of constant relative fractionation of Sm/Nd and Rb/Sr in refractory residues is a strong constraint on partial melting models. Calculations suggest that batch melting models are more compatible with this constraint than are fractional melting models, but models incorporating currently accepted distribution coefficients and residual phase assemblages cannot reproduce the observed isotope effects except under highly specific conditions. The slope of the correlation is not consistent with the hypotheses that chemical structure in the mantle is due to accretional heterogeneity or variable loss of elements to the core. If the mantle reservoirs are complementary in composition to the continental crust, and if the crust + mantle has ε_Nd = 0andε_Sr = 0 and chondritic Sr/Nd, then Rb/Sr in the crust is calculated to be less than 0.10, suggesting that the crust may be more mafic in composition and contain a smaller proportion of the earth's Rb and heat-producing elements than previously estimated.     

Geochemistry of Cenezoic volcanic rocks, Baja California, Mexico: Implications for the petrogenesis of post-subduction magmas

Late Cenozoic volcanism in Baja California records the effects of cessation of subduction at a previously convergent, plate margin. Prior to 12.5 m.y., when subduction along the margin of Baja ceased, the predominant volcanic activity had a calc-alkaline signature, ranging in composition from basalt to rhyolite. Acidic pyroclastic activity was common, and possibly represented the westermost, distal edge of the Sierra Madre Occidental province. After 12.5 m.y., however, the style and composition of the magmatic products changed dramatically. The dominant rock type within the Jaraguay and San Borja volcanic fields is a magnesian andesite, with up to 8% MgO at 57% SiO₂, low Fe/Mg ratios, and high Na/K ratios. These rocks have unusual trace-element characteristics, with high abundances of Sr (up to 3000 ppm), low contents of Rb; K/Rb ratios are very high (usually over 1000, and up to 2500), and Rb/Sr ratios are low (less than 0.01). Furthermore, La_n/Yb_n ratios are high, consistent with derivation from a mantle source with fractionated REE patterns. ⁸⁷Sr/⁸⁶Sr ratios are less than 0.7048, and usually less than 0.7040, whereas the pre-12.5 m.y. lavas have ⁸⁷Sr/⁸⁶Sr ratios between 0.7038 and 0.7063. We have previously termed these rocks bajaites, in order to distinguish them from other magnesian andesites. Bajaites also occur in southernmost Chile and the Aleutian Islands, areas which also have histories of attempted or successful ridge subduction.It is proposed that the bajaite series is produced during the unusual physico-chemical conditions operating during the subduction of young oceanic lithosphere, or subduction of a spreading centre. During normal subduction, the oceanic crust dehydrates, releasing volatiles (water, Rb and other large-ion lithophile elements) into the overlying wedge. Subduction of younger crust will result in a progressive decrease, and eventual cessation of the transfer of volatiles when subduction stops. Thermal rebound of the mantle may cause the slab to melt, perhaps under eclogitestable conditions. The resulting melt will be heavy-REE-depleted, perhaps dacitic, but will otherwise inherit MORB-like Rb/Sr and K/Rb ratios. The ascending melt will react with the mantle to form the source of the bajaitic rocks. Furthermore, any amphibole in the mantle, stabilised during the higher PH₂O conditions of earlier subduction, will break down and contribute a high-K/Rb ratio component.The implications of this study are that firstly, the subducted slab does not contribute a highly fractionated REE component in most modern arcs (i.e. the slab does not melt); secondly, Rb has a very short residence time in the mantle, and its abundance in arc rocks is a direct reflection of the input from the dehydrating slab; and thirdly, bajaitelike rocks may provide recognition of attempted or successful ridge subduction in the geologic past.     

U-Pb isotopic geochemistry of the post-collisional mafic-ultramafic rocks from the Dabie Mountains——Crust-mantle interaction and LOMU component

Geochronological studies of mafic-ultramafic intrusions occurrence in the northern Dabie zone (NDZ) suggest that these pyroxenite-gabbro intrusions formed 120—130 Ma ago should be post-collisional magmatic rocks[1—4]. These mafic-ultramafic rocks provid…     

Low- and high-TiO2 flood basalts of southern Brazil: origin from picritic parentage and a common mantle source

The Serra Geral (Paraná) continental flood-basalt province of southern Brazil has two main basalt types: low-TiO₂ ( 1 wt.%) basalts occupy the southern portion, and high-TiO₂ (> 3 wt.%) basalts are largely in the northern part. Low-Ti basalts are less evolved (Mg# 60) and more radiogenic (e.g., ⁸⁷Sr/⁸⁶Sr 0.708) than high-Ti basalts (Mg# 35; ⁸⁷Sr/⁸⁶Sr 0.705). This is consistent with a model that invokes variable melting of a single mantle source to produce picritic magmas that have relatively lower and higher incompatible element contents. Varying percentages of melting can be related to varying proximity to the early Tristan da Cunha hotspot. The Mg-rich magmas fractionated 60–75% olivine, clinopyroxene, and plagioclase to yield low- or high-Ti flood basalts, assimilating more or less crust in the process. The extent of fractionation and assimilation depended on crustal “warmth” (also tied to location relative to hotspot): (1) above zones of 25% melting, warm crust relatively easily contaminated crystallizing picritic magma that originated by a high degree of melting (i.e., magma with lower incompatible element contents); additionally, high degrees of melting sustained replenishment of magma with low-Ti magma characteristics; (2) above 10% melting zones, cooler crust comparatively restricted assimilation during crystallization (of magma with higher incompatible element contents) and permitted magma evolution to high-Ti derivatives; lesser degrees of melting also limited replenishment magma and thereby allowed greater evolution of existing magma. This model refers all diagnostic geochemical and isotopic features of Serra Geral basalts to percentages of partial melting of an essentially homogeneous mantle material.     

Late collision rhyolitic volcanism in the north-eastern part of the Armenian Highland

Plio-Pleistocene acidic volcanism of the northeastern part of the Armenian highland is related to a continental collision zone as a result of convergence between Eurasia and Arabia lithosphere plates. The development of volcanism is divided into three stages of 10–17, 4.5–7.5 and 0.1–2.8 Ma. A crustal origin model is proposed to explain the geochemical and petrogenetic aspects of the acidic volcanism formation. Spatially separated Ba-rich and Rb-rich geochemical types of rhyolites were revealed, indicating more evolved and primitive rhyolitic magma types, respectively. The variation interval of the primary ⁸⁷Sr/⁸⁶Sr ratio was found to be from 0.70438 to 0.70636. Age and lateral variation of geochemical and isotopic parameters were determined by differences of initial substrates and degrees of their partial melting. The mechanisms of rhyolitic magma evolution were the remelting of heterogeneous sialitic materials and low-pressure fractional crystallization in isolated magmatic chambers. These facts confirm the model of crustal anatexis origin of the eutectic melts. The eutectic rhyolitic magma was generated by an open-system melting in the presence of deep-horizon mobile K–Rb fluids, initiated by mantle resources.     

The influence of crustal structure on compositions of subduction-related magmas

A survey of Sr isotopic ratios and other compositional features of subduction-related magma suites reveals significant correlations between these averaged parameters and characteristics of the underlying crust (i.e., thickness, composition, and age). These observations lead to the conclusion that crust and(or) mantle rocks in the hanging walls of subduction zones are involved in modification of primary mafic magmas (typically basalt or basaltic andesite). It is proposed that mafic magmas will stagnate within the crust or uppermost mantle where they may differentiate and react with wall rocks. The extent to which such processes manifest themselves will depend upon details of the local crustal structure. In particular, the composition and age of the crust will strongly influence such parameters as Sr, Nd and Pb isotopic compositions. Such data strongly indicate the involvement of crustal rocks in locales underlain by old sialic crust (e.g., central Andes). Depending upon the level of magma stagnation and evolution within the crust, different trends in isotopic composition may result. These isotopic trends may be enhanced by partial melting of the wall rocks to produce relatively silicic anatectic magmas, and locally they may reflect subduction of continental sediments. Interpretation of the isotopic data may be more ambiguous in locales underlain by younger and more mafic continental crust (Cascades, E Eleutians) and those underlain by oceanic crust owing to the similarity in isotopic composition of primary magmas and the latter crustal materials. Yet some degree of crustal involvement in magmatic evolution seems highly probable even in these more primitive terranes. Consequently, most island arc magmas, and especially those more evolved than basalt, are probably not primary in the sense that they do not represent direct melts of the upper mantle. Studies of arc volcanic rocks may yield misleading conclusions concerning processes of magma generation related to subduction unless evolutionary processes are defined and their effects considered. It appears that modern volcanic arcs provide a poor analog for models of early crustal development because the modern mantle-derived magmatic components are more mafic in composition than average continental crust.     

Strontium isotope geochemistry of late cretaceous granodiorites,Jamaica and Haiti,greater Antilles

Initial⁸⁷Sr/⁸⁶Sr ratios have been determined for a representative suite of Upper Cretaceous granodiorites and associated rocks from the Above Rocks composite stock in central Jamaica and the Terre-Neuve pluton in northwestern Haiti. The average initial⁸⁷Sr/⁸⁶Sr ratio for severn samples of the Terre-Neuve intrusion is 0.7036, with a range of 0.7026–0.7047. For two samples of the Above Rocks the initial ratios are 0.7033 and 0.7034. A third sample from this intrusive has an initial ratio of 0.7084, which is tenatively attributed to contamination. The initial⁸⁷Sr/⁸⁶Sr ratios indicate that neither ancient sialic crust nor sediments carried down a Benioff zone can be the primary source of the granodioritic magma. K/Rb ratios for these rocks range from 178 to 247, which are much lower than the average values (≥1000) for tholeiitic basalts. It is concluded that the magmas originated primarily by melting of downthrust oceanic crust or adjacent mantle material.     

Chemical structure and evolution of the mantle and continents determined by inversion of Nd and Sr isotopic data,I. Theoretical methods

While the chemical structure of the earth's mantle is probably rather complex, multi-box models have been used as a first approximation to evaluate this structure. Most commonly, a three-box model is used, involving the continental crust, the upper mantle and the lower mantle. The depleted upper mantle and the continental crust are assumed to represe1nt complementary reservoirs, related by crust formation processes occurring during geologic history.Here we investigate the Rb/Sr and Sm/Nd isotopic systematics of several three-box models, using mass balance equations and the definition of the mean age of the reservoirs. The geochemical uniqueness of the models, chosen from a large family of possible models, is evaluated from elementary graph theory, and these models are then solved using a total inversion approach. This paper (Part I) describes the methodology of the procedure; the companion paper (Part II) discusses the application of this approach to multi-box mantle models.     

Evidence for crustal assimilation by turbulently convecting,mafic alkaline magmas: Geochemistry of mantle xenolith-bearing lavas from northern Sardinia

Alkali basalt, trachybasalt and basanite magmas, containing abundant xenoliths of upper mantle origin, were erupted during the Plio-Pleistocene (2.4-0.14 Ma) in northern Sardinia. The magmas are enriched in K, Rb, Th and Ba relative to mid-ocean ridge basalts (MORB) and most ocean island basalts (OIB), resulting in high K/Nb, Th/Nb, Ba/Nb and Rb/Nb ratios. The large number of spinel peridotite inclusions in these lavas suggests that these chemical features cannot be explained by combined assimilation and fractional crystallization within the continental crust. However, volcanic rock chemistry can be explained by the assimilation of sialic rocks by turbulently convecting, mafic magmas during their ascent to the surface. Fractionation of Ba and K from the light rare earth elements (LREE) is required to explain the positive correlation of K/La and Ba/La with ⁸⁷Sr/⁸⁶Sr_(i). Consequently, bulk assimilation of crystalline basement rocks by rising, hot basaltic magmas cannot explain the observed chemical trends, and preferential melting of a low melting quartzo-feldspathic crustal component probably occurred, leaving the REE in residual phases such as apatite, zircon, sphene and amphibole. Alternatively, large ion lithophile element (LILE) enrichment may have been related to interaction of rising mafic lavas with metasomatized lithospheric mantle or enriched asthenosphere.     

RbSr systematics and crustal contamination models for calc-alkaline igneous rocks

New strontium isotopic data of calc-alkaline Pliocene-to-Quaternary lavas (southern Peru) confirm their anomalous isotopic composition compared to those of calc-alkaline rocks from active margins where continental crust is not involved. Gradual enrichment of radiogenic Sr occurs during fractional crystallization of calc-alkaline magma. The variation of the isotopic composition of these lavas as well as⁸⁷Sr/⁸⁶Sr versus 1/(⁸⁶Sr) diagrams form the basis for a model involving processes of fractional crystallization combined with mixing and addition of radiogenic Sr that originated in continental crust and was transported by a fluid phase.     

U-Pb isotopic geochemistry of the post-collisional mafic-ultramafic rocks from the Dabie Mountains

The U-Pb isotope geochemical study of the pyroxenite-gabbro intrusion in the Dabie Mountains shows that the post-collisional mafic-ultramafic rocks of the Dabie Mountains are characterized by relative high Pb contents, low U contents and low U/Pb ratios. These characters may be results of interaction between lithosphere or depleted asthenospheric mantle (DMM) and lower crust, but have nothing to do with mantle plume and subducted continental crust. It was first observed that some samples with lower ²⁰⁶Pb/²⁰⁴Pb and higher ²⁰⁷Pb/²⁰⁴Pb ratios show typical characters of the LOMU component. The Pb, Sr, and Nd isotopic tracing shows that three components are needed in the source of the Zhujiapu pyroxenite-gabbro intrusion. They could be old enriched sub-continental lithospheric mantle (LOMU component), lower crust and depleted asthenospheric mantle. The crust-mantle interaction process producing primitive magma of post-collisional mafic-ultramafic rocks in the Dabie Mountains could be described by a lithospheric delamination and magma underplating model. After continent-continent collision, delamination of the thickened lithosphere induced the upwelling of depleted asthenospheric mantle, which caused partial melting of asthenospheric mantle and residual sub-continental lithospheric mantle. The basaltic magma produced in this process underplated in the boundary between the crust and mantle and interacted with lower crust resulting in the geochemical characters of both enriched lithospheric mantle and lower crust.     

Composition of island arcs and continental growth

Island arc volcanism has contributed and is still contributing to continental growth, but the composition of island arcs differs from that of the upper continental crust in its lower abundance of Si, K, Rb, Ba, Sr and light rare earth elements. In their advanced stage of evolution, island arcs contain more than 80% of tholeiitic and 15% of ‘island arc’ calc-alkaline rocks with varied SiO₂ contents. The larger proportion of tholeiitic rocks is in the lower crustal levels. The high stratigraphical levels of the island arcs are composed of tholeiitic plus calc-alkaline and/or high potash (shoshonitic) associations with higher abundances of K, Rb, Sr, and Ba. Stratification of the island arc crust is accentuated by another type of calc-alkaline volcanism (Andean type) originating at a late stage of arc evolution, probably by partial melting at the base of the crust. This causes enrichment of the upper crust in K, Rb, Ba and REE and accounts for upper crustal abundances of these elements as well as of SiO₂.     

Petrological variation of large-volume felsic magmas from Hakkoda-Towada caldera cluster: Implications for the origin of high-K felsic magmas in the Northeast Japan Arc

Abstract The Hakkoda‐Towada caldera cluster (HTCC) is a typical Late Cenozoic caldera cluster located in the northern part of the Northeast Japan Arc. The HTCC consists of five caldera volcanoes, active between 3.5 Ma and present time. The felsic magmas can be classified into high‐K (HK‐) type and medium‐ to low‐K (MLK‐) type based on their whole‐rock chemistry. The HK‐type magmas are characterized by higher K₂O and Rb contents and higher ⁸⁷Sr/⁸⁶Sr ratios than MLK‐type magmas. Both magmas cannot be derived from fractional crystallization of any basaltic magma in the HTCC. Assimilation‐fractional crystallization model calculations show that crustal assimilation is necessary for producing the felsic magmas, and HK‐type magmas are produced by higher degree of crustal assimilation with fractional crystallization than MLK‐type magmas. Although MLK‐type magmas were erupted throughout HTCC activity, HK‐type magmas were erupted only during the initial stage. The temporal variations of magma types suggest the large contribution of crustal components in the initial stage. A major volcanic hiatus of 3 my before the HTCC activity suggests a relatively cold crust in the initial stage. The cold crust probably promoted crustal assimilation and fractional crystallization, and caused the initial generation of HK‐type magmas. Subsequently, the repeated supply of mantle‐derived magmas raised temperature in the crust and formed relatively stable magma pathways. Such a later system produced MLK‐type magmas with lesser crustal components. The MLK‐type magmas are common and HK‐type magmas are exceptional during the Pliocene–Quaternary volcanism in the Northeast Japan Arc. This fact suggests that exceptional conditions are necessary for the production of HK‐type magmas. A relatively cold crust caused by a long volcanic hiatus (several million years) is considered as one of the probable conditions. Intensive crustal assimilation and fractional crystallization promoted by the cold crust may be necessary for the generation of highly evolved HK‐type felsic magmas.     

Isotope geochemistry and origin of calc-alkaline lavas from a caledonian continental margin volcanic arc

Analyses for major and trace elements, including REE, and Sr, Nd and Pb isotopes are reported from a suite of Siluro-Devonian lavas from Fife, Scotland. The rocks form part of a major calc-alkaline igneous province developed on the Scottish continental margin above a WNW-dipping subduction zone. Within the small area (ca. 15 km²) considered, rock types range from primitive basalts and andesites (high Mg, Ni and Cr) to lavas more typical of modern calc-alkaline suites with less than 30 ppm Ni and Cr. There is a marked silica gap between these rocks (< 62%) and the rare rhyolites (> 74%), yet the latter can be generated by fractional crystallization from the more mafic lavas. In contrast, variation in incompatible element concentrations and ratios in the mafic lavas can not be generated by fractional crystallization processes. Increasing SiO₂ is accompanied by increasing Rb, K, Pb, U and Ba relative to Sr and high field strength elements, increasing LREE enrichment and increasing _Sr calculated at 410 Ma, and by decreasing HREE, Eu/Eu*, Sm/Nd and _Nd (410). _Nd and _Sr are roughly anticorrelated and have more radiogenic compositions than the mantle array, in common with data reported elsewhere from this part of the arc. The correlation extrapolates up to cross the mantle array within the composition field of the contemporary MORB source, and extrapolates down towards the probable compositional range of Lower Palaeozoic greywackes, which may form the uppermost 8 km of the crust, or may be supplied to the source by subduction. One sample, however, lies within the mantle array, and closely resembles lavas from northwestern parts of the arc, where a mantle source with mild time-integrated Rb/Sr and LREE enrichment has been inferred. The lavas have relatively high initial ²⁰⁷Pb/²⁰⁴Pb for their ²⁰⁶Pb/²⁰⁴Pb, a feature which has been interpreted elsewhere as the result of incorporation of a sediment component into arc magmas. The systematic changes with increasing SiO₂ in isotopic and chemical parameters can be explained by mixing of a greywacke-derived component with depleted mantle. The various possible mixing mechanisms are discussed, and it is considered most likely that mixing occurred in the mantle source through greywacke subduction. The bulk of the Rb, K, Ba and Pb in the lavas is probably recycled from the crust, whereas less than some 40% of the Sr and Nd is recycled. The calc-alkaline chemical trends are solely a function of mixing with the sediment component.     

Siderophile and chalcophile element abundances in oceanic basalts, Pb isotope evolution and growth of the Earth''s core

We have investigated the hypothesis that mantle Pb isotope ratios reflect continued extraction of Pb into the Earth's core over geologic time. The Pb, Sr and Nd isotopic compositions, and the abundance of siderophile and chalcophile elements (W, Mo and Pb) and incompatible lithophile elements have been determined for a suite of ocean island and mid-ocean ridge basalt samples. Over the observed range in Pb isotopic compositions for oceanic rocks, we found no systematic variation of siderophile or chalcophile element abundances relative to abundances of similarly incompatible, but lithophile, elements. The high sensitivity of theMo/Pr ratio to segregation of Fe-metal or S-rich metallic liquid (sulfide) and the observed constantMo/Pr ratio rules out the core formation model as an explanation for the Pb paradox. The mantle and crust have the sameMo/Pr and the sameW/Ba ratios, suggesting that these ratios reflect the ratio in the Earth's primitive mantle.

Our data also indicate that thePb/Ce ratio of the mantle is essentially constant, but the presentPb/Ce ratio in the mantle ( 0.036) is too low to represent the primitive value ( 0.1) derived from Pb isotope systematics. HigherPb/Ce ratios in the crust balance the lowPb/Ce of the mantle, and crust and mantle appear to sum to a reasonable terrestrialPb/Ce ratio. The constancy of thePb/Ce ratio in a wide variety of oceanic magma types from diverse mantle reservoirs indicates this ratio is not fractionated by magmatic processes. This suggests crust formation must have involved non-magmatic as well as magmatic processes. Hydrothermal activity at mid-ocean ridges may result in significant non-magmatic transport of Pb from mantle to crust and of U from crust to mantle, producing a higherU/Pb ratio in the mantle than in the total crust. We suggest that the lower crust is highly depleted in U and has unradiogenic Pb isotope ratios which balance the radiogenic Pb of upper crust and upper mantle. The differences between thePb/Ce ratio in sediments, this ratio in primitive mantle, and the observed ratio in oceanic basalts preclude both sediment recycling and mixing of primitive and depleted reservoirs from being important sources of chemical heterogeneities in the mantle.     

Chemical structure and evolution of the mantle and continents determined by inversion of Nd and Sr isotopic data,II. Numerical experiments and discussion

Application of the inversion technique described in Part I [1] to models in which the depleted (MORB) mantle is created by extraction of continental crust results in a stable and self-consistent set of model data, including estimates of uncertainties on all the parameters. The inversion shows that the mean age of the continents (and of the depleted mantle) is 2.14–2.46 b.y., and that the lower crust must be depleted in Rb by a factor of ～ 4 relative to the upper crust. The fraction of total mantle which has been depleted ranges over wide limits (30–90%) depending on: (a) whether the lower mantle is considered to be virgin, or somewhat depleted; (b) whether the depleted reservoir is represented in Sm/Nd and Rb/Sr systematics by average values of MORB, or by extreme values of MORB, and (c) whether the bulk earth Nd content is presumed to be similar to E or H chondrites, or is higher than all known meteorite classes. The usefulness of crust-mantle budget models in constraining such questions as whole mantle versus two-layer mantle convection will be enhanced by better data and understanding in these three key areas of geochemistry.     

Recycling of the continental crust

In order to understand the evolution of the crust-mantle system, it is important to recognize the role played by the recycling of continental crust. Crustal recycling can be considered as two fundamentally distinct processes: 1) intracrustal recycling and 2) crust-mantle recycling. Intracrustal recycling is the turnover of crustal material by processes taking place wholly within the crust and includes most sedimentary recycling, isotopic resetting (metamorphism), intracrustal melting and assimilation. Crust-mantle recycling is the transfer of crustal material to the mantle with possible subsequent return to the crust. Intracrustal recycling is important in interpreting secular changes in sediment composition through time. It also explains differences found in crustal area-age patterns measured by different isotopic systems and may also play a role in modeling crustal growth curves based on Nd-model ages. Crustal-mantle recycling, for the most part, is a subduction process and may be considered on three levels. The first is recycling with only short periods of time in the mantle (<10 m.y.). This may be important in explaining the origin of island-arc and related igneous rocks; there is growing agreement that 1–3% recycled sediment is involved in their origin. Components of recycled crustal material, with long-term storage (up to 2.5 b.y.) in the mantle as distinct entities, has been suggested for the origin of ocean island and ultrapotassic volcanics but there is considerably less agreement on this interpretation. A third proposal calls for the return of crustal material to the mantle with efficient remixing in order to swamp the geochemical and isotopic signature of the recycled component by the mantle. This type of recycling is required for steady-state models of crustal evolution where the mass of the continents remains constant over geological time. It is unlikely if crust-mantle recycling has exceeded 0.75 km³/yr over the past 1–2 Ga.Good evidence exists that selective recycling is an important process. Sedimentary rocks preserved in different tectonic settings are apparently recycled at different rates, resulting in a bias in the sediment types preserved in the geologic record. Selective recycling has important implications for the interpretation of Nd model ages of old sedimentary rocks and in the analysis of accreted terranes. Although there is evidence that continental crust was formed prior to 3.8 Ga, the oldest preserved rocks do not exceed this age. It is likely that the intense meteorite bombardment, which affected the earth during the period 4.56–3.8 Ga, coupled with rapid mantle convection, which resulted from greater heat production, caused the destruction and probable recycling into the mantle of any early formed crust.Although crust-mantle recycling is seen as a viable process, it is concluded that crustal growth has exceeded crust-mantle recycling since at least 3.8 Ga. Intracrustal recycling has not been given adequate consideration in models of crustal growth based on isotopic data (particularly Nd model ages). It is concluded that crustal growth curves based on Nd model ages, while vastly superior to those based on K/Ar or Rb/Sr, tend to underestimate the volume of old crust, due to crust-mantle and/or intracrustal recycling.     

Possible origin of K-rich volcanic rocks from Virunga,East Africa,by metasomatism of continental crustal material: Pb,Nd and Sr isotopic evidence

The isotopic compositions of Sr, Nd and Pb together with the abundances of Rb, Sr, U and Pb have been determined for mafic and felsic potassic alkaline rocks from the young Virunga volcanic field in the western branch of the East African rift system.⁸⁷Sr/⁸⁶Sr varies from 0.7055 to 0.7082 in the mafic rocks and from 0.7073 to 0.7103 in the felsic rocks. The latter all come from one volcano, Sabinyo. Sabinyo rocks have negative ε_Ndvalues ofε_Nd = ?10. Nd and Sr isotopic variations in the basic potassic rocks are correlated and plot between Sabinyo and previously reported [1] compositions (ε_Nd = +2.5;⁸⁷Sr/⁸⁶Sr≈ 0.7047) for Nyiragongo nephelinites. The Pb isotopic compositions for Sabinyo rocks are nearly uniform and average²⁰⁶Pb/²⁰⁴Pb≈ 19.4,²⁰⁷Pb/²⁰⁴Pb= 15.79–15.84,²⁰⁸Pb/²⁰⁴Pb≈ 41.2. The basic potassic rocks have similar²⁰⁶Pb/²⁰⁴Pb values but range in²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb from the Sabinyo values to less radiogenic compositions.Excellent correlations of⁸⁷Sr/⁸⁶Sr with Rb/Sr, 1/Sr and²⁰⁷Pb/²⁰⁶Pb for Sabinyo rocks suggest these to be members of a hybrid magma series. However, the nearly uniform Pb compositions for this series points to radiogenic growth of⁸⁷Sr in the magma source region following an event which homogenized the isotopic compositions but not Rb/Sr. The Rb-Sr age derived from the erupted Sabinyo isochron-mixing line is consistent with the ～500 Myr Pb-Pb age from Nyiragongo [1], which suggests that this event affected all Virunga magma sources. The event can again be traced in the Pb-Pb, Pb-Sr and Nd-Sr isotopic correlations for all Virunga rocks, including Nyiragongo, when allowances are made for radiogenic growth subsequent to this mixing or incomplete homogenization event. Inferred parent/daughter element fractionations point to a metasomatic event during which a mantle fluid invaded two lithospheric reservoirs: a +ε_Nd reservoir sampled by the Nyiragongo nephelinites and suggested to be the subcontinental mantle and a ?ε_Nd reservoir sampled by the mafic and felsic potasssic volcanism. Whether this ?ε_Nd reservoir is the crust, continental crustal material in the mantle or anomalous mantle cannot be decided from the data. The simplest answer, that this reservoir is the continental crust, seems to be at variance with experimental evidence suggesting a subcrustal origin for basic potassic magmas. Partial melting of the ancient metasomatised lithospheric domains and ensuing volcanism seems to be entirely a response to decompression and rising geotherms during rifting and thinning of the lithosphere.     

Gabbro and related rock emplacement beneath rifting continental crust: UPb geochronological and geochemical constraints for the Galicia passive margin (Spain)

The thinned continental crust of the west Galicia margin is bound by a belt of serpentinized peridotites (‘peridotite ridge’) lying about 300 km off the coast in the North Atlantic ocean. From this ridge, a gabbro and a chlorite rock were studied in an attempt to substantiate rift-related subcontinental magmatism, occurring prior to sea-floor spreading. U-Pb dating of 13 different zircon fractions yields a precise age of 122.1 ± 0.3 Ma (2σ) for the emplacement of the chlorite rock protolith, from which more than 50% of Si and alkali-calc-alkali elements were lost during greenschist facies tectonometamorphism. Sr and Nd isotope signatures suggest that the gabbro and chlorite rock protoliths were derived from mantle sources that were moderately depleted in LILE, relative to a chondritic reservoir. No evidence for the presence of continental material in the magma source regions can be observed. From the new zircon age of 122.1 ± 0.3 Ma, and earlier determined³⁹Ar⁴⁰Ar age of 122.0 ± 0.6 Ma for amphibole from the same locality, it can be documented that magma formation, solidification and unroofing of the mantle rocks occurred during a short period of time of about 3.4 Ma, which means that the peridotite ridge detached from the continent and rose to the surface immediately after, or even coevally with mantle melting.     

Numerical modeling of mantle diapirism as a cause of intracontinental rifting

The numerical model of mantle diapirism and active rifting is developed. The model describes the possibility of extension and thinning of the Earth’s crust under the action of a local 100-km long heat source in the sublithospheric mantle, which causes melting and rising of the magmatic diapir through the cratonic lithosphere. The model combines the mechanisms of the uplifting of the anomalously hot material due to its gravitational instability, underplating of magma beneath the continental crust, and its extension by the forces of the convective flows at the base of the plate. The obtained results shed light on some geological features of the joint formation of the large Vilyui igneous province and Vilyui sedimentary basin.