40Ar/39Ar dating on volcanic rocks of the Deccan Traps,India

⁴⁰Ar/³⁹Ar dating results on seven volcanic rocks from four areas of the Deccan Traps, India, suggest that volcanic activity more than 70 Ma ago might have occurred at least in limited areas.In the Igat Puri area, the uppermost flow shows an⁴⁰Ar/³⁹Ar age of 63 Ma, whereas a lower flow has an age of around 82–84 Ma.⁴⁰Ar/³⁹Ar ages of samples from the Bombay area also seem to favor the occurrence of volcanic activity more than 70 Ma ago. One rhyolite dyke from the Osam Hill in the Girnar Hill area shows a well-defined plateau age of 68 Ma, whereas two tholeiitic basalts from the Mahabaleshwar area indicate a total⁴⁰Ar/³⁹Ar age of around 63–64 Ma, though they show the effect of secondary disturbance in the age spectra.The volcanic activity(ies) more than 70 Ma ago may correspond to precursory one(s) for the main volcanic activity around 65 Ma ago in the Deccan Traps.     

40Ar/39Ar incremental-release ages of biotite from a progressively remetamorphosed Archean basement terrane in southwestern Labrador

Gneisses within an Archean basement terrane adjacent to the southwestern portion of the Labrador Trough were variably retrograded during a regional metamorphism of Grenville age (ca. 1000 Ma). Biotites from non-retrograded segments of the gneiss terrane record⁴⁰Ar/³⁹Ar plateau and isochron ages which date times of cooling following an episode of the Kenoran orogeny (2376–2391 Ma). A suite of gneiss samples displaying varying degrees of retrograde alteration was collected across the Grenville metamorphic gradient. Biotites in these samples show no petrographic evidence of retrograde alteration, however they do record internally discordant⁴⁰Ar/³⁹Ar age spectra. Although the extent of internal discordance is variable, the overall character of the release patterns is similar with younger apparent ages recorded in intermediate-temperature gas fractions. The total-gas dates range from 2257±27 Ma (northwest) to 1751±23 Ma (southeast), suggesting that variable quantities of radiogenic argon were lost from the Archean biotites during Grenville metamorphism. The “saddle-shaped” nature of the discordant spectra indicates that argon loss was not accomplished through single-stage, volume diffusion processes.Biotites in portions of the gneiss terrane which were completely recrystallized during Grenville metamorphism are petrographically and texturally distinct. A representative of this phase records a⁴⁰Ar/³⁹Ar plateau age of 2674±28 Ma. This date is markedly inconsistent with regional constraints on the timing of Grenville metamorphism, and indicates the presence of extraneous argon components. Both the extraneous and radiogenic argon components must have been liberated in constant proportions during experimental heating because the argon isotopic data yield a well-defined⁴⁰Ar/³⁶Ar vs.³⁹Ar/³⁶Ar isochron corresponding to an age (2658±23 Ma) similar to that defined by the plateau portion of the spectrum.The⁴⁰Ar/³⁹Ar biotite dates suggest that the effects of Grenville metamorphism extent 15–20 km northward into the Superior Province. The limit of this overprint is approximately coincident with the northernmost development of Grenville age thrust faults in the Archean terrane. Therefore, it is proposed that the northern margin of the Grenville Province in southwestern Labrador should be located along the northernmost Grenville thrust fault because this represents both a structural and a thermal discontinuity.     

Excess40Ar in metamorphic rocks from Broken Hill,New South Wales: implications for40Ar/39Ar age spectra and the thermal history of the region

⁴⁰Ar/³⁹Ar age spectrum analyses of samples from Broken Hill, New South Wales, indicate that the region has experienced a complex thermal history following high-grade metamorphism, 1660 Ma ago. The terrain cooled slowly (～3°C Ma^?1) until about 1570 Ma ago, when the temperature fell below about 500°C. Following granitoid emplacement ～1500 Ma ago, the region remained relatively cold until affected by a thermal pulse 520±40Ma ago, causing temperatures to rise to～350°C in some places. During this event, accumulated⁴⁰Ar was released from minerals causing a significant Ar partial pressure to develop. Laboratory Ar solubility data combined with the⁴⁰Ar/³⁹Ar age spectra gives a local estimate of this partial pressure of ～10^?4atm. The region finally cooled below 100°C about 280 Ma ago.⁴⁰Ar/³⁹Ar age spectrum analyses of hornblende, plagioclase and clinopyroxene containing excess⁴⁰Ar are characterized by saddle-shaped age spectra. Detailed analysis of plagioclase samples reveals a complex diffusion behaviour, which is controlled by exsolution structures. This effect, in conjunction with the presumed different lattice occupancy of excess⁴⁰Ar with respect to radiogenic⁴⁰Ar, appears to be responsible for the saddle-shaped age spectra.     

40Ar/39Ar ages for the alkaline volcanism and the basement of Gorringe Bank,North Atlantic ocean

Gorringe Bank is situated on the Europe-Africa plate boundary at the eastern end of the Azores-Gibraltar fracture zone. It has two summits, Gettysburg Bank to the Southwest and Ormonde Bank to the northeast.We applied the⁴⁰Ar/³⁹Ar stepwise heating method to date six samples of the alkaline volcanic rocks, two gabbros from the Ormonde Bank and a dolerite from the Gettysburg Bank. The results that the alkaline volcanism lasted probably for less than 6 Ma(66-60 Ma).Although the nature of this volcanism precludes any subduction feature during its setting, the alkaline volcanism of Ormonde is probably linked to Upper Cretaceous/Eocene compressive tectonic events.The basement rocks of Gorringe Bank reveal distrubed⁴⁰Ar/³⁹Ar age spectra. One plagioclase and one biotite from a gabbro give evidence for a thermic event whose age is tentatively estimated at about 75 Ma, and related to a variation in the direction of the relative movement between Europe and Africa. The more probable age given by a plagioclase of another gabbro and by a dolerite (110 Ma) corresponds to tilting northeastward of the Gorringe massif.     

40Ar/39 Ar isotopic ages of Qitianling granite and their geologic implications

This paper has reported the first application of ⁴⁰Ar/³⁹ Ar dating to orthoclase from Qitianling granite. The resultant plateau ages yielded by three orthoclase specimens 2KL-17, 99LQ-2 and 2KL-31 (Note: The last one was taken from the part of granite which had been attributed to Cailing super-unit of the Indosinian Period by the former researchers) collected from the said granite are (139.57±2.79) Ma, (140.55±2.81) Ma and (144.91±2.90) Ma respectively. The above-mentioned ages represent the closed ⁴⁰Ar/³⁹ Ar age of the orthoclase. The consistency in age dating results, the similarity in geochemical characteristics and rock textures, and the NW-SE orientation of orthoclase phenocrysts almost throughout the granite, provide evidence for the intimate relationship between the Furong super-unit and the Cailing super-unit that form the main part of the granite, suggesting that they are products of comagmatic conjugate differentiation during the Late Jurassic. This paper also makes a comparison between the Qitianling granite and the Qianlishan granite.

     

Intercalibration of international and domestic 40Ar/39Ar dating standards

Four international standards, Ga1550, MMhb-1, Lp-6, Bem 4M, and one domestic standard BT-1 have been intercalibrated. The repeated measurements on MMhb-1 with different mass demonstrate that MMhb-1 is inhomogeneous in age and its average age is 519.8 Ma. The results of Bern 4M and Lp-6 reflect that they have an invariable value of ⁴⁰Ar*/³⁹Ar_k (F) and the ages we obtained are consensus with their K-Ar age: Lp-6=127.7Ma; Bern 4M=18.2 Ma. Analyses of BT-1 age spectra, Ca/K and Cl/K spectra as well as inverse isochrons indicate that the sample is homogeneous and invariable and keeps close chemically, with its trapped argon isotope composition close to the atmosphere. The dating results show that age values are reproducible and steady, total fusion age, step-heating age, plateau age and isochron age are in accord with each other within the error range (2σ). Therefore, we recommend 28.7 Ma as the calibrated age of BT-1. We also discuss the variation in neutron flux gradients of Beijing 49-2 reactor. It was found that the neutron flux gradient varies considerably, and more monitors (standard samples) are needed to fix the trend of variation. The coefficient of the 49-2 reactor that transfers the ratio of production rate of ³⁷Ar_Ca/³⁹Ar_K into Ca/K ratio is 1.78. This is different from that reported earlier, 2.0, which may be caused by the reconstruction of the reactor.     

Identification of excess 40Ar by the 40Ar/39Ar age spectrum technique

⁴⁰Ar/³⁹Ar incremental heating experiments on igneous plagioclase, biotite, and pyroxene that contain known amounts of excess⁴⁰Ar indicate that saddle-shaped age spectra are diagnostic of excess⁴⁰Ar in igneous minerals as well as in igneous rocks. The minima in the age spectra approach but do not reach the crystallization age. Neither the age spectrum diagram nor the⁴⁰Ar/³⁶Ar versus³⁹Ar/³⁶Ar isochron diagram reliably reveal the crystallization age in such samples.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript> Ar isotopic ages of Qitianling granite and their geologic implications

This paper has reported the first application of ⁴⁰Ar/³⁹ Ar dating to orthoclase from Qitianling granite. The resultant plateau ages yielded by three orthoclase specimens 2KL-17, 99LQ-2 and 2KL-31 (Note: The last one was taken from the part of granite which had been attributed to Cailing super-unit of the Indosinian Period by the former researchers) collected from the said granite are (139.57±2.79) Ma, (140.55±2.81) Ma and (144.91±2.90) Ma respectively. The above-mentioned ages represent the closed ⁴⁰Ar/³⁹ Ar age of the orthoclase. The consistency in age dating results, the similarity in geochemical characteristics and rock textures, and the NW-SE orientation of orthoclase phenocrysts almost throughout the granite, provide evidence for the intimate relationship between the Furong super-unit and the Cailing super-unit that form the main part of the granite, suggesting that they are products of comagmatic conjugate differentiation during the Late Jurassic. This paper also makes a comparison between the Qitianling granite and the Qianlishan granite.     

40Ar-39Ar age determinations on the Owyhee basalt of the Columbia Plateau

⁴⁰Ar/³⁹Ar step-heating analyses have been performed on 11 samples of basalt from sites near Owyhee Reservoir of southeastern Oregon, U.S.A. These rocks were extruded during the great flood basalt episode of the Pacific Northwest. The whole-rock points are highly correlated on a plot of⁴⁰Ar/³⁶Ar versus³⁹Ar/³⁶Ar, corresponding to a common age of the samples of 14.3 ± 0.3 m.y. Inspite of this, individual “plateau” plots of the age versus fraction of³⁹Ar released do not give good plateaux. These age spectra exhibit to varying degrees a common structure in which lower age values are found at higher temperatures. This pattern may result from a closed-system redistribution of the argon isotopes. The usefulness of grinding the basalts in removing a loosely held atmospheric argon component is confirmed.     

Studies on40Ar/39Ar thermochronology of strike-slip time of the Tan-Lu fault zone and their tectonic implications

Samples of mylonite, ultramylonite and phyllonite were collected from 5 localities in the Anhui part of the Tan-Lu fault zone for⁴⁰Ar/³⁹Ar chronological studies. Among them 4 samples from 3 localities on the eastern margin of the Dabie orogenic belt yielded⁴⁰Ar/³⁹Ar plateau ages of 128 —132 Ma; and 2 samples from the western margin of the Zhangbalin uplift and eastern margin of the Bengbu uplift gave the same⁴⁰Ar/³⁹Ar plateau ages of 120 Ma. Isochron analyses and other lines of evidence suggest that the data are reliable. The data are interpreted as cooling ages of sinistral strike-slip deformation of the Tan-Lu fault zone. The younger ages from the north might be related to slower strike-slip rising. These results indicate that the large-scale left-lateral displacement in the Tan-Lu fault zone took place in the Early Cretaceous, rather than in Late Triassic (Indosinian) as proposed by some geologists. Therefore, this fault zone is an intracontinental wrench fault rather than a transform fault or suture line developed during formation of the Dabie orogenic belt.     

40Ar/ 39Ar and K–Ar geochronological age constraints for the inception and early evolution of the Izu–Bonin – Mariana arc system

K–Ar and ⁴⁰Ar/³⁹Ar dates are presented for locations in the Izu–Bonin – Mariana (IBM) forearc (Ocean Drilling Program (ODP) sites 786 & 782, Chichijima, Deep Sea Drilling Program (DSDP) sites 458 & 459, Saipan), and Palau on the remnant arc of the Kyushu–Palau Ridge. For a number of these locations, the ⁴⁰Ar/³⁹Ar plateau and ³⁶Ar/⁴⁰Ar versus ³⁹Ar/⁴⁰Ar isochrons give older ages than the K–Ar results. The most important results are: (i) at site 786, initial construction of the proto-IBM (now forearc) basement occurred at least by ca 47–45 Ma, consistent with the age of the immediately overlying sediments (middle Eocene nannofossil Zone CP13c); the younger pulse of construction dated at ca 35 Ma by K–Ar could not be confirmed by ⁴⁰Ar/³⁹Ar analysis; (ii) ⁴⁰Ar/³⁹Ar ages for the initial construction of the Mariana portion of the IBM system are as old as those of the Izu–Bonin portion, for example at site 458, initial construction commenced at least by ca 49 Ma and at ca 47 Ma at Saipan (Sankakayuma Formation); and (iii) a combination of K–Ar and ⁴⁰Ar/³⁹Ar ages indicate continued boninite magmatism in the Izu–Bonin forearc (and remnant arc at Palau) until ca 35 Ma. Subduction inception including boninite series rocks along most of the exposed length of the IBM system, clearly preceded by some 5 million years the Middle Eocene (ca 43.5 Ma) change in Pacific plate motion. Boninitic series magmatism persisted at locations now exposed in the forearc for ～ 15 million years after arc inception concurrently with low-K tholeiitic series eruptions from a subaerial arc system, established at ≥ 40 Ma, on the Kyushu–Palau Ridge. For the Mariana portion of the IBM system, reconstruction of the proto-arc places this activity adjacent to the concurrent but orthogonally spreading Central Basin Ridge of the West Philippine Basin. It is possible that a combination of subduction of a young North New Guinea Plate beneath newly created back-arc basin crust may account for some of the features of the Mariana system. It is clear, however, that the understanding of the processes of subduction initiation and early IBM arc development is incomplete.     

40Ar-39Ar chronology of isolated phases from Bununu and Malvern howardites

High resolution⁴⁰Ar-³⁹Ar age spectra have been measured on plagioclase and glass from two howardites. Both the plagioclase and glass from the gas-rich Bununu howardite show well-defined age plateaux, yielding distinct ages of 4.42 ± 0.04 and 4.24 ± 0.05 AE, respectively. These age patterns are rather well behaved and are interpreted as representing the distinct times of formation of plagioclase from igneous processes and of glass fragments produced by impact on the meteorite body. The release pattern for the glass from the heavily shocked Malvern howardite is undulating at low and intermediate temperatures but does have a high-temperature plateau. Its age spectrum indicates little apparent diffusion loss, but rather an extensive redistribution of either⁴⁰Ar during the shock event or of³⁹Ar during the neutron irradiation or both. The total K-Ar age of Malvern glass is 3.64 ± 0.04 AE and the high-temperature plateau is 3.73 ± 0.05 AE. The age spectrum of the Malvern plagioclase has an intermediate temperature “plateau” at 3.80 AE that represents 20% of the total⁴⁰Ar content and increases towards a high-temperature plateau at 4.29 ± 0.04 AE containing 26% of the total gas release. It seems likely that the event which formed the Malvern glass also reset part of the plagioclase. The distinct histories observed for the different phases of these howardites are consistent with their formation from a regolith. The present results along with similar young ages for igneous clasts from Kapoeta clearly show that the regoliths were extant on the parent bodies of howardites and that they were subjected to violent impact events at least as recently as 3.7 AE ago.     

40Ar/39Ar age and thermal history of the Kirin chondrite

The Kirin meteorite, a large (2800kg) H5 chondrite, fell in Kirin Province, China in 1976. A sample from each of the two largest fragments (K-1, K-2) yield⁴⁰Ar/³⁹Ar total fusion ages of 3.63 ± 0.02b.y. and 2.78 ± 0.02b.y. respectively.⁴⁰Ar/³⁹Ar age spectra show typical diffusional argon loss profiles. Maximum apparent ages of 4.36 b.y. (K-1) and ～4.0 b.y. (K-2) are interpreted as possible minimum estimates for the age of crystallization of the parent body.The⁴⁰Ar/³⁹Ar ages found for gas released at low temperature are about 2.2 b.y. for K-1 and about 0.5 b.y. for K-2, suggesting that this meteorite may have suffered two discrete collisional events that caused degassing of radiogenic argon. Modelling of possible thermal events in the parent body indicates that samples K-1 and K-2 were at a depth of less than 3 m from the base of an impact melt of a thickness less than 7 m and separated by no more than ～2 m from one another at the time of the heating event about 0.5 b.y. ago. Further, the duration of heating was probably less than a few years.Calculations from³⁸Ar data yield exposure ages for samples K-1 and K-2 of about 5 m.y., similar to that found for many other H chondrites.     

40Ar/39Ar and U-Th-Pb dating of separated clasts from the Abee E4 chondrite

Determinations of⁴⁰Ar/³⁹Ar and U-Th-Pb are reported for three clasts from the Abee (E4) enstatite chondrite, which has been the object of extensive consortium investigations. The clasts give⁴⁰Ar/³⁹Ar plateau ages and/or maximum ages of 4.5 Gy, whereas two of the clasts give average ages of 4.4 Gy. Within the range of 4.4–4.5 Gy these data do not resolve any possible age differences among the three clasts.²⁰⁶Pb measured in these clasts is only ～1.5–2.5% radiogenic, which leads to relatively large uncertainties in the Pb isochron age and in the²⁰⁷Pb/²⁰⁶Pb model ages. The Pb data indicate that the initial²⁰⁷Pb/²⁰⁶Pb was no more than 0.08±0.07% higher than this ratio in Can?on Diablo troilite. The U-Th-Pb data are consistent with the interpretation that initial formation of these clasts occurred 4.58 Gy ago and that the clasts have since remained closed systems, but are contaminated with terrestrial Pb. The⁴⁰Ar/³⁹Ar ages could be gas retention ages after clast formation or impact degassing ages. The thermal history of Abee deduced from Ar data appears consistent with that deduced from magnetic data, and suggests that various Abee components experienced separate histories until brecciation no later than 4.4 Gy ago, and experienced no appreciable subsequent heating.     

40Ar/39Ar analyses of phlogopite nodules and phlogopite-bearing peridotites in South African kimberlites

⁴⁰Ar/³⁹Ar analyses have been made on phlogopite-bearing peridotite nodules from Bultfontein and phlogopite nodules from Du Toitspan, Kimberley area, South Africa. Neither definite plateau nor isochron age could be obtained due to the occurrence of an excess⁴⁰Ar in phlogopite. However, the extrusion age of a phlogopite nodule from Du Toitspan has been estimated to be about 86 m.y. from the combination of the youngest⁴⁰Ar/³⁹Ar age in the intermediate temperature fraction with Rb/Sr age data reported for this area.Excess⁴⁰Ar correlates with K-derived³⁹Ar in some phlogopites suggesting that it is trapped in K- or K-similar sites and has been incorporated during phlogopite formation.The occurrence of large amounts of excess⁴⁰Ar in phlogopite suggests that it was not formed at a shallow depth.     

39Ar-40Ar ages of samples from the Apollo 17 station 7 boulder and implications for its formation

³⁹Ar-⁴⁰Ar ages and³⁷Ar-³⁸Ar exposure ages of samples representing four different lithologies of the Apollo 17 station 7 boulder were measured. The age of the dark veinlet material77015of3.98 ± 0.04AE is interpreted as representing the time of intrusion of this veinlet into the 77215 clast. The data obtained so far indicate that the vesicular basalt 77135 formed 100–200 m.y. later. However, this has to be confirmed by³⁹Ar-⁴⁰Ar investigations on separated mineral and/or grain-size fractions. A small clast enclosed in the 77135 basalt gives a well-defined high temperature age of3.99 ± 0.02AE. A sample of the noritic clast 77215 gave4.04 ± 0.03AE, the highest age found so far in this boulder. The³⁹Ar-⁴⁰Ar ages obtained are in agreement with the age relationships deduced from the stratigraphic evidence.Taking into account the shielding by the boulder itself, an average³⁷Ar-³⁸Ar exposure age of(27.5 ± 2.5)m.y. is obtained for the samples collected from the boulder.     

Age gap between the intrusion of gneissose granitoids and regional high‐temperature metamorphism in the Ryoke belt (Mikawa area), central Japan

The relationships between the intrusion of gneissose granitoids and the attainment of regional high‐T conditions recorded in metamorphic rocks from the Ryoke belt of the Mikawa area, central Japan, are explored. Seven gneissose granitoid samples (tonalite, granodiorite, granite) were collected from three distinct plutonic bodies that are mapped as the so‐called “Older Ryoke granitoids.” Based on bulk‐rock compositions and U–Pb zircon ages obtained by laser ablation inductively coupled plasma mass spectrometry, the analyzed granitoids can be separated into two groups. Gneissose granitoids from the northern part of the area give weighted mean ²⁰⁶Pb/²³⁸U ages of 99 ±1 Ma (two samples) and 95 ±1 Ma (one sample), whereas those from the southern part yield 81 ±1 Ma (two samples) and 78–77 ±1 Ma (two samples). Regional comparisons allow correlation of the northern granitoids (99–95 Ma) with the Kiyosaki granodiorite, and mostly with the Kamihara tonalite found to the east. The southern granitoids are tentatively renamed as “78–75 Ma (Hbl)?Bt granite” and “81–75 Ma Hbl?Bt tonalite” (Hbl, hornblende; Bt, biotite). and seem to be broadly coeval members of the same magmatic suite. With respect to available age data, no gneissose granitoid from the Mikawa area shows a U–Pb zircon age which matches that of high‐T metamorphism (ca 87 Ma). The southern gneissose granitoids (81–75 Ma), although they occur in the highest‐grade metamorphic zone, do not seem to represent the heat source which produced the metamorphic field gradient with a low dP/dT slope.     

40Ar intercept values and young apparent40K-40Ar ages of five Apollo 15 fines

Correlations between⁴⁰Ar and³⁶Ar from size fractions of three Apollo 15 fines (15071, 15421, 15501) have been obtained. The⁴⁰Ar intercept values of these fines and of 15091 and 15601 are generally lower than what one would expect for fines resulting from the comminution of rocks having ages of about 3.3 × 10⁹ yr, typical for basalts of the landing site. This is interpreted to be the result of contamination by ray material from the Copernican age (equal or less than ～10⁹ yr) craters, Autolycus and Aristillus, north of the landing site.     

40Ar-39Ar and Rb-Sr age determinations on Quaternary volcanic rocks

⁴⁰Ar-³⁹Ar and Rb-Sr ages have been measured on separated minerals from the potassic volcanics of the Roman Comagmatic Region to test the ability of these methods to accurately data Quaternary geological events. The very high K and Rb contents of the Roman magmas present particularly favorable situations in which the very high concentrations of the radioactive nuclides⁴⁰K and⁸⁷Rb result in well resolved in situ enrichments of the daughter isotopes despite the very young ages. Six leucite separates contained Ar with very high bulk40/36 ratios (above 1000) and in which the⁴⁰Ar and the³⁹Ar were very well correlated, yielding well-defined ages averaging3.38±0.08×10⁵ years. Two leucites contained Ar with lower bulk40/36 ratios (～400), and in at least two release steps from these leucites the⁴⁰Ar/³⁶Ar ratio was significantly lower than atmospheric. Despite the uncertainty in the composition of the trapped component, these two leucites have ages that do not differ significantly from the ages of the other leucites. For the biotites, it was not possible to obtain through stepwise degassing a good separation of in situ radiogenic⁴⁰Ar from trapped⁴⁰Ar and therefore the calculated ages are not as precise as those of the leucites. In three cases the biotite age agrees with the age of the cogenetic leucite, but in the remaining two cases discordant ages are obtained, suggesting caution when using biotites as Quaternary age indicators.Rb-Sr measurements on leucite, biotite, and pyroxene separates hand-picked from each of three tuff samples yielded a dispersion in⁸⁷Sr/⁸⁶Sr as large as 16 parts in 10⁴ and⁸⁷Rb/⁸⁶Sr as high as 218 for leucites, and permitted the determination of internal isochron ages. The ages obtained range from3.8±0.2×10⁵to3.3±0.2×10⁵ years and are in good agreement with the⁴⁰Ar-³⁹Ar ages on the leucites. The data for each tuff sample yield a well-defined uniform initial⁸⁷Sr/⁸⁶Sr. However, different tuffs show small differences in initial⁸⁷Sr/⁸⁶Sr pointing to distinct sources or to assimilation of different materials during the extrusion of the tuffs. These measurements demonstrate the possibility of dating Quaternary materials by both the⁴⁰Ar-³⁹Ar method and the Rb-Sr method. The observation of concordant ages with a precision of a few percent represents a powerful tool in Quaternary stratigraphy.     

Investigation of excess argon in ultramafic rocks from the Kola Peninsula by the40Ar/39Ar method

In several xenolithic ultramafic rocks from the Kola Peninsula, including a magnetic separate, abnormally high⁴⁰Ar/³⁹Ar ratios persisted at low and high temperatures. The lowest⁴⁰Ar/³⁹Ar ratio was consistently observed at intermediate temperatures (900–1100°C), indicating an apparent age of 2.8–3.1 b.y.; however, this may not indicate the formation age.The quantity of excess⁴⁰Ar was estimated at each temperature fraction, adopting ages inferred from published Rb-Sr ages or the minimum⁴⁰Ar/³⁹Ar age. Excess⁴⁰Ar is abundantly trapped both in mineral lattices and nonretentive trapping sites, but the trapping sites are different from those of in-situ radiogenic⁴⁰Ar. The high temperature component of excess⁴⁰Ar is considered to represent Ar dissolved during mineral formation in the upper mantle or the lower crust.A correlation between the amount of high temperature excess⁴⁰Ar and³⁶Ar exists for some samples. The⁴⁰Ar_excess/³⁶Ar ratios of the rocks of probable upper mantle or lower crust origin vary from about 10 000 to 35 000, which may suggest large fluctuations of this ratio in the deep interior of the earth. The high value implies that most³⁶Ar was already degassed from the earth's interior at least 2 or 3 b.y. ago.