Three-dimensional groundwater flow modeling approach for the groundwater management options for the Dakhla oasis,Western Desert,Egypt

In Dakhla oasis, Western Desert of Egypt, groundwater is the only resource for all anthropogenic activities. During the last 50 years, the Nubian Sandstone Aquifer System (NSAS) has been undergoing serious stress through withdrawing its storage. Plans for expanding the agricultural areas in Dakhla oasis were given by the government. This article is an attempt to investigate the best management option that meets development ambitions and groundwater availability. Based on a calibrated regional three-dimensional groundwater flow model for the NSAS using FEFLOW, a refined (high resolution) local scale model was developed to simulate and predict the impact of applying the actual and planned extractions rates on Dakhla oasis. Five management scenarios were suggested. The application of the actual extraction rate of 1.2 × 10⁶ m³/day for the oasis for the next 90 years resulted in a drawdown of 75 m and a depth to groundwater up to 75 m with an annual change in hydraulic head of 0.57 m. At the end of this simulation, only a few wells at the west of the oasis will still be free flowing. The application of the planned extraction rate (1.7 × 10⁶ m³/day) resulted in great depths to groundwater (>100 m) and formed huge cones of depressions that connected together to cover the whole oasis and extend further beyond its borders. It was found that the best option for groundwater management in the oasis is the implementation of an extraction rate of 1.46 × 10⁶ m³/day, as the depths to groundwater will never exceed the 100 m limit.     

Groundwater flow in a transboundary fault-dominated aquifer and the importance of regional modeling: the case of the city of Querétaro,Mexico

The city of Querétaro, located near the political boundary of the Mexican states of Querétaro and Guanajuato, relies on groundwater as it sole water supply. Groundwater extraction in the city increased from 21?×?10⁶ m³/yr in 1970 to 104?×?10⁶ m³/yr in 2010, with an associated drawdown of 100 m in some parts of the aquifer. A three-dimensional numerical groundwater-flow model has been developed that represents the historical evolution of the aquifer’s potentiometric levels and is used to simulate the effect of two scenarios: (1) a 40 % reduction in the extraction rate from public water supply wells in early 2011 (thus reducing the extraction to 62?×?10⁶ m³/yr), and (2) a further reduction in 2021 to 1?×?10⁶ m³/yr. The modeling results project a temporary recovery of the potentiometric levels after the 40 % reduction of early 2011, but a return to 2010 levels by 2020. If scenario 2 is implemented in 2021, the aquifer will take nearly 30 years to recover to the simulated levels of 1995. The model also shows that the wells located in the city of Querétaro started to extract water from part of the aquifer beneath the State of Guanajuato in the late 1970s, thus showing that the administrative boundaries used in Mexico to study and develop water resources are inappropriate, and consideration should be given to physical boundaries instead. A regional approach to studying aquifers is needed in order to adequately understand groundwater flow dynamics.     

Review: Groundwater development and management in the Deccan Traps (basalts) of western India

The Deccan Traps or the basalts of western India are the largest exposure of basic lava flows covering about 500,000 km². Groundwater occurrence in the Deccan Traps is in phreatic condition in the weathered zone above the hard rock and in semi-confined condition in the fissures, fractures, joints, cooling cracks, lava flow junctions and in the inter-trappean beds between successive lava flows, within the hard rock. Dug wells, dug-cum-bored wells and boreholes or bore wells are commonly used for obtaining groundwater. The yield is small, usually in the range of 1–100 m³/day. The average land holding per farming family is only around 2 ha. Recently, due to the ever increasing number of dug wells and deep bore wells, the water table has been falling in several watersheds, especially in those lying in the semi-arid region of the traps, so that now the emphasis has shifted from development to sustainable management. Issues like climatic change, poverty mitigation in villages, sustainable development, rapid urbanization of the population, and resource pollution have invited the attention of politicians, policy makers, government agencies and non-governmental organizations towards watershed management, forestation, soil and water conservation, recharge augmentation and, above all, the voluntary control of groundwater abstraction in the Deccan Traps terrain.     

RETRACTED ARTICLE: Development prospects of groundwater resources in an elliptical shape island,Union Territory of Lakshadweep,India

A major problem of the islanders is the availability of fresh water for drinking purpose. Groundwater is the only source of fresh water for the islanders. The demand for groundwater is increasing very year due to growing population and urbanization. A proper understanding of the groundwater condition is important in order to meet this increasing demand and to formulate future development and management strategies. It is in this context, principal hydrogeologic units; water table fluctuation pattern, general groundwater potential, existing groundwater withdrawal structures and draft, water quality, etc. have been studied in an elliptical shape Andrott Island of Union Territory of Lakshadweep, India, through field investigation and secondary data collection. Groundwater occurs under phreatic condition and seawater is in hydraulic continuity with the groundwater as evidenced by the tidal influence in almost all the wells. Groundwater level fluctuation due to seasonal variation varies from 0 to 0.542 m depending on the distance of the well from the coast. Depth to groundwater level varies from less than 1.234 to 3.520 m depending on the topography. Groundwater level fluctuation is due to the combination of factors like rainfall, tidal activities, sub-surface runoff, and draft. Large diameter dug wells are the main groundwater extraction structures in this island. There are 2,143 dug wells with almost each family having its own well and the density of the dug wells is about 437/km². The stage of groundwater development is estimated as 37% and hence “Safe” for further groundwater development in this island. However, considering the very limited fresh-water resources and also the growing demand for groundwater, various management strategies such as rainwater harvesting, artificial recharge of groundwater, public participation in water conservation and wise use of groundwater, etc., have been suggested.     

Groundwater balance in the Khor Arbaat basin, Red Sea State, eastern Sudan

The Khor Arbaat basin is the main source of potable water supply for the more than 750,000 inhabitants of Port Sudan, eastern Sudan. The variation in hydraulic conductivity and storage capacity is due to the heterogeneity of the sediments, which range from clay and silt to gravely sand and boulders. The water table rises during the summer and winter rainy seasons; it reaches its lowest level in the dry season. The storage capacity of the Khor Arbaat aquifer is estimated to be 21.75?×?10⁶ m³. The annual recharge through the infiltration of flood water is about 1.93?×?10⁶ m³. The groundwater recharge, calculated as underground inflow at the ‘upper gate’, is 1.33?×?10⁵ m³/year. The total annual groundwater recharge is 2.06?×?10⁶ m³. The annual discharge through underground outflow at the ‘lower gate’ (through which groundwater flows onto the coastal plain) is 3.29?×?10⁵ m³/year. Groundwater discharge due to pumping from Khor Arbaat basin is 4.38?×?10⁶ m³/year on average. The total annual groundwater discharge is about 4.7?×?10⁶ m³. A deficit of 2.6?×?10⁶ m³/year is calculated. Although the total annual discharge is twice the estimated annual recharge, additional groundwater flow from the fractured basement probably balances the annual groundwater budget since no decline is observed in the piezometric levels.     

A groundwater flow model for overexploited basaltic aquifer and Bazada formation in India

Recent changes in land use practices, such as increase in orange orchards in central India, has put undue pressure on the groundwater resources. Excess withdrawal from the aquifers has resulted in groundwater table decline. The stage of groundwater development in some watersheds has reached 155.85 %, converting these into overexploited watersheds. In the present research paper, a groundwater flow model has been developed to evaluate the groundwater system in a basaltic terrain with Bazada formation. A conceptual model has been developed and calibrated for steady and transient states and the sensitivity analysis was carried out. Future predictions, for current scenario where present practices are continued and for scenario with 20 % reduction in groundwater draft have been made, to select the best strategy for mitigating the problem. The modeling results show that the decline in groundwater level in basaltic and Bazada unconfined aquifers will result into drying up (water level more than 15 m bgl) of 243 km² area by 2020. To restore the groundwater level, it is simulated that the groundwater draft rate must be reduced by 20 % for next 10 years. It may be achieved by adopting groundwater management strategies, particularly for irrigation sector.     

Groundwater simulation using a numerical model under different water resources management scenarios in an arid region of China

Groundwater plays an important role in the economic development and ecological balance of the arid area of northwest China. Unfortunately, human activity, for example groundwater extraction for irrigation, have resulted in excessive falls in groundwater level, and aquifer overdraft in the oasis, disrupting the natural equilibrium of these systems. A groundwater numerical model for Minqin oasis, an arid area of northwest China, was developed using FEFLOW software to simulate regional groundwater changes under transient conditions. The vertical recharge and discharge (source/sink terms) of the groundwater models were determined from land-use data and irrigation systems for the different crops in the different sub-areas. The calibrated model was used to predict the change for the period from 2000 to 2020 under various water resources management scenarios. Simulated results showed that under current water resources management conditions groundwater levels at Minqin oasis are in a continuous drawdown trend and groundwater depth will be more than 30 m by 2020. Reducing the irrigation area is more effective than water-saving irrigation to reduce groundwater decline at Minqin oasis and the annual groundwater budget would be −0.978 × 10⁸ m³. In addition, water-diversion projects can also reduce the drawdown trend of groundwater at Minqin oasis, and the groundwater budget in the Huqu sub-area would be in zero equilibrium if the annual inflow into the oasis was enhanced to 2.51 × 10⁸ m³. Furthermore, integrative water resources management including water-diversion projects, water-saving irrigation, and reducing the irrigation area are the most effective measures for solving groundwater problems at Minqin oasis.     

Assessing seasonal variations and aquifer vulnerability in coastal aquifers of semi-arid regions using a multi-tracer isotopic approach: the case of Grombalia (Tunisia)

The Grombalia aquifer (NE Tunisia) is an example of an important source of water supply for regional and national development, where the weak controls over abstraction, fertilizer application and waste disposal, coupled with limited knowledge of aquifer dynamics, is causing aquifer over-exploitation and water quality degradation. Assessing the key role of groundwater in water-resources security is therefore of paramount importance to support new actions to preserve water quality and quantity in the long-run. This study presents one of the first investigations targeted at a complete assessment of aquifer dynamics in the Grombalia aquifer. A multi-tracer hydrogeochemical and isotopic (δ²H, δ¹⁸O and ³H) approach was used to study the influence of seasonal variation on piezometric levels, chemical and isotopic compositions, and groundwater recharge. A total of 116 samples were collected from private wells and boreholes during three periods in a 1 year monitoring campaign (February–March 2014, September 2014 and February 2015). Results revealed the overall unsuitability of groundwater for drinking and irrigation purposes (NO₃?>?50 mg/L in 51% of the wells; EC >1,000 μS/cm in 99% of the wells). Isotopic balance coupled to piezometric investigation indicated the contribution of the shallow aquifer to deep groundwater recharge. The study also revealed the weakness of ‘business as usual’ management practices, highlighting possible solutions to tackle water-related challenges in the Grombalia region, where climate change, population growth and intensive agricultural activities have generated a large gap between demand and available water reserves, hence becoming a possible driver for social insecurity.     

Sources of low-arsenic groundwater in the Bengal Basin: investigating the influence of the last glacial maximum palaeosol using a 115-km traverse across Bangladesh

Pollution of groundwater in the Bengal Basin (Bangladesh and West Bengal, India) by arsenic (As) puts at risk the health of more than 100 million consumers. Using 1,580 borehole lithological logs and published hydrochemistry on 2,387 wells, it was predicted that low-As (<10 μg/L) groundwater exists, in palaeo-interfluvial aquifers of brown sand capped by a protective palaeosol, beneath at least 45,000 km² of the Bengal Basin. The aquifers were predicted to be at a depth of as little as 25 m below ground level (mbgl), and typically no more than 50 mbgl. The predictions were confirmed along an east–west traverse 115 km in length (i.e. across half of Bangladesh) by drilling 28 new boreholes to 91-m depth to reveal subsurface sedimentology, and by mapping As distribution in groundwater. The aquifers identified occur at typically <40 mbgl and so are accessible with local drilling methods. A protective palaeosol that caps the palaeo-interfluvial aquifers prevents downward movement into them of As-polluted groundwater present in shallower palaeo-channel aquifers and ensures that the palaeo-interfluvial aquifers will yield low-As groundwater for the foreseeable future. Their use, in place of the shallower As-polluted palaeo-channel aquifers, would rapidly mitigate the health risks from consumption of As-polluted groundwater.     

Groundwater sustainability and groundwater/surface-water interaction in arid Dunhuang Basin,northwest China

The Dunhuang Basin, a typical inland basin in northwestern China, suffers a net loss of groundwater and the occasional disappearance of the Crescent Lake. Within this region, the groundwater/surface-water interactions are important for the sustainability of the groundwater resources. A three-dimensional transient groundwater flow model was established and calibrated using MODFLOW 2000, which was used to predict changes to these interactions once a water diversion project is completed. The simulated results indicate that introducing water from outside of the basin into the Shule and Danghe rivers could reverse the negative groundwater balance in the Basin. River-water/groundwater interactions control the groundwater hydrology, where river leakage to the groundwater in the Basin will increase from 3,114?×?10⁴ m³/year in 2017 to 11,875?×?10⁴ m³/year in 2021, and to 17,039?×?10⁴ m³/year in 2036. In comparison, groundwater discharge to the rivers will decrease from 3277?×?10⁴ m³/year in 2017 to 1857?×?10⁴ m³/year in 2021, and to 510?×?10⁴ m³/year by 2036; thus, the hydrology will switch from groundwater discharge to groundwater recharge after implementing the water diversion project. The simulation indicates that the increased net river infiltration due to the water diversion project will raise the water table and then effectively increasing the water level of the Crescent Lake, as the lake level is contiguous with the water table. However, the regional phreatic evaporation will be enhanced, which may intensify soil salinization in the Dunhuang Basin. These results can guide the water allocation scheme for the water diversion project to alleviate groundwater depletion and mitigate geo-environmental problem.     

Geochemical,isotopic and hydrological mass balance approaches to constrain the lake water–groundwater interaction in Dal Lake,Kashmir Valley

It is important to have qualitative as well as quantitative understanding of the hydraulic exchange between lake and groundwater for effective water resource management. Dal, a famous urban fresh water lake, plays a fundamental role in social, cultural and economic dynamics of the Kashmir Valley. In this paper geochemical, isotopic and hydrological mass balance approaches are used to constrain the lake water–groundwater interaction of Dal Lake and to identify the sources of lake water. Water samples of precipitation (n = 27), lake water (n = 18) and groundwater (n = 32) were collected across the lake and its catchment for the analysis of δ¹⁸O and δ²H. A total of 444 lake water samples and 440 groundwater samples (springs, tube wells and dug wells) were collected for the analysis of Ca²⁺, Mg²⁺, HCO₃ ^?, SO₄ ^2?, Cl^?, NO₃ ^?, Na⁺ and K⁺. Water table and lake water level were monitored at 40 observation locations in the catchment. Water table map including pH and EC values corroborate and verify the gaining nature of the Dal Lake. Stable isotopes of lake water in Boddal and Gagribal basins showed more deviation from the global meteoric water line than Hazratbal and Nigeen basins, indicating the evaporation of lake water. The isotopic and geochemical mass balance suggested that groundwater contributes a significant proportion (23–40%) to Dal Lake. The estimated average groundwater contribution to Dal Lake ranged from 31.2 × 10³ to 674 × 10³ m³ day^?1 with an average of 276 × 10³ m³ day^?1. The study will be useful to delineate the possible sources of nutrients and pollutants entering the lake and for the management of lake water resources for sustainable development.     

Groundwater budget for the upper and middle parts of the River Gash Basin, eastern Sudan

The River Gash Basin is filled by the Quaternary alluvial deposits, unconformably overlying the basement rocks. The alluvial deposits are composed mainly of unconsolidated layers of gravel, sand, silt, and clays. The aquifer is unconfined and is laterally bounded by the impermeable Neogene clays. The methods used in this study include the carry out of pumping tests and the analysis of well inventory data in addition to the river discharge rates and other meteorological data. The average annual discharge of the River Gash is estimated to be 1,056?×?10⁶ m³ at El Gera gage station (upstream) and 587?×?10⁶ m³ at Salam-Alikum gage station (downstream). The annual loss mounts up to 40% of the total discharge. The water loss is attributed to infiltration and evapotranspiration. The present study proofs that the hydraulic conductivity ranges from 36 to 105 m/day, whereas the transmissivity ranges from 328 to 1,677 m²/day. The monitoring of groundwater level measurements indicates that the water table rises during the rainy season by 9 m in the upstream and 6 m in the midstream areas. The storage capacity of the upper and middle parts of the River Gash Basin is calculated as 502?×?10⁶ m³. The groundwater input reach 386.11?×?10⁶ m³/year, while the groundwater output is calculated as 365.98?×?10⁶ m³/year. The estimated difference between the input and output water quantities in the upper and middle parts of the River Gash Basin demonstrates a positive groundwater budget by about 20?×?10⁶ m³/year     

Quantification of the water balance and hydrogeological processes of groundwater–lake interactions in the Pampa Plain, Argentina

This paper gives an account of the assessment and quantification of the water balance and the hydrogeological processes related to lake–groundwater interaction in the Pampa Plain by using hydrogeochemical, isotopic and flow numerical modeling techniques. La Salada is a permanent shallow lake, with an area of 5.8 km², located on the SE of Buenos Aires Province. A total of 29 lake water samples and 15 groundwater samples were collected for both hydrochemical analysis and environmental stable isotope determination. Water table depths were measured in wells closed to the lake. Groundwater samples appear grouped on the Local Meteoric Water Line, suggesting a well-mixed system and that rainfall is the main recharge source to the aquifer. Water evaporation process within La Salada is also corroborated by its isotopic composition. The model that best adjusts to La Salada Lake hydrochemical processes includes evaporation from groundwater, calcite precipitation with CO₂ release and cationic exchange. The annual water balance terms for the lake basin indicates for each hydrological component the following values: 1.16 E⁰⁸ m³ rainfall, 8.15 E⁰⁷ m³ evapotranspiration, 1.90 E⁰⁶ m³ runoff, 1.55 E⁰⁷ m³ groundwater recharge, 6.01 E⁰⁶ m³ groundwater discharge to the lake, 9.54 E⁰⁶ m³ groundwater discharge to the river, 5.00 E⁰⁵ m³ urban extraction and 4.90 E⁰⁶ m³ lake evaporation. Integrated analysis of hydrochemical and isotopic information helped to calibrate the groundwater flow model, to validate the conceptual model and to quantitatively assess the basin water balance.     

Analysis of groundwater mining in two carbonate aquifers in Sierra de Estepa (SE Spain) based on hydrodynamic and hydrochemical data

The carbonate aquifers of Lora and Mingo form part of the hydrogeological unit of Sierra de Estepa (SE Spain). By means of time series analysis and a 1D numerical groundwater model, groundwater exploitation was quantified and the mean annual recharge in both systems was estimated (2001–2004). During this period, the Lora and Mingo aquifers received an average groundwater recharge of 0.29 × 10⁶ m³/year and 0.14 × 10⁶ m³/year, respectively, whereas an average of 0.34 × 10⁶ m³/year and 0.21 × 10⁶ m³/year, respectively, was extracted. These conditions led to a conspicuous lowering of the water table in both systems. In addition, the analysis of the evolution of the main hydrogeochemical parameters of the groundwater showed that the increased pumping rates produced an increase in total dissolved solids, and chloride and sodium ions in both aquifers. In the case of the Lora aquifer, the only ion that presented decreased levels was nitrate. The results show that groundwater pumping in both aquifers should not exceed the mean annual recharge of 0.29 × 10⁶ m³/year and 0.14 × 10⁶ m³/year in the Lora and Mingo aquifers, respectively. Nevertheless, it would be advisable to reduce pumping rates to below these values in order to restore piezometric levels and improve groundwater quality for different uses in the future.     

Study of the water saving potential of an irrigation area based on a remote sensing evapotranspiration model

To estimate the water saving potential of an irrigation area and create a scientific water saving plan, the irrigation water use efficiency and water productivity of the Hulanhe irrigation area for 2007–2014 were calculated, and the water saving potentials of different water saving plans were determined from the perspectives of engineering and crop water saving. The results showed that the evapotranspiration calculated from the surface energy balance algorithm for land model (SEBAL) agreed well with the measured results. The irrigation water use efficiency in the Hulanhe irrigation area was positively correlated with precipitation of irrigated land and was negatively correlated with the net irrigation water volume. The engineering water saving potential ranges for periods of 5, 8, 11, and 15 years were (1.702?×?10⁸, 5.103?×?10⁸) m³, (1.783?×?10⁸, 5.184?×?10⁸) m³, (1.865?×?10⁸, 5.266?×?10⁸) m³, and (2.301?×?10⁸, 5.702?×?10⁸) m³, respectively, and the water saving potential increased year over year. Low amounts of precipitation of irrigated land corresponded with small amounts of net irrigation water and greater water saving potential. Based on the cumulative frequency of the water productivity calculated for the Hulanhe irrigation area from 2007 to 2014, the target water productivity for short (50% of the multi-year average cumulative water productivity) and long (70% of the multi-year average cumulative water productivity) terms were 1.03 kg/m³ and 1.22 kg/m³, respectively, and the cumulative crop water saving potentials for short and long terms were 1.18?×?10⁸ and 2.74?×?10⁸ m³, respectively. These results provided a theoretical reference for creating water saving plans for irrigation areas.     

Modeling of groundwater draft based on satellite-derived crop acreage estimation over an arid region of northwest India

Over-exploitation of groundwater for agricultural crops puts stress on the sustainability of natural resources in the arid region of Rajasthan state, India. Hydrogeological study of groundwater levels of the study area during the pre-monsoon (May to June), post-monsoon (October to November) and post-irrigation (February to March) seasons of 2004–2005 to 2011–2012 shows a steady decline of groundwater levels at the rate of 1.28–1.68 m/year, mainly due to excessive groundwater draft for irrigation. Due to the low density of the groundwater observation-well network in the study area, assessment of groundwater draft, and thus groundwater resource management, becomes a difficult task. To overcome the situation, a linear groundwater draft model (LGDM) has been developed based on the empirical relationship between satellite-derived crop acreage and the observed groundwater draft for the year 2003–2004. The model has been validated for a decade, during three year-long intervals (2005–2006, 2008–2009 and 2011–2012) using groundwater draft, estimated through a discharge factor method. Further, the estimated draft was validated through observed pumping data from random sampled villages (2011–2012). The results suggest that the developed LGDM model provides a good alternative to the estimation of groundwater draft based on satellite-based crop area in the absence of groundwater observation wells in arid regions of northwest India.     

Evidence for deep groundwater flow and convective heat transport in mountainous terrain, Delta County, Colorado, USA

The Tongue Creek watershed lies on the south flank of Grand Mesa in western Colorado, USA and is a site with 1.5 km of topographic relief, heat flow of 100 mW/m², thermal conductivity of 3.3 W m^–1 °C^–1, hydraulic conductivity of 10^-8 m/s, a water table that closely follows surface topography, and groundwater temperatures 3–15°C above mean surface temperatures. These data suggest that convective heat transport by groundwater flow has modified the thermal regime of the site. Steady state three-dimensional numerical simulations of heat flow, groundwater flow, and convective transport were used to model these thermal and hydrological data. The simulations provided estimates for the scale of hydraulic conductivity and bedrock base flow discharge within the watershed. The numerical models show that (1) complex three-dimensional flow systems develop with a range of scales from tens of meters to tens of kilometers; (2) mapped springs are frequently found at locations where contours of hydraulic head indicate strong vertical flow at the water table, and; (3) the distribution of groundwater temperatures in water wells as a function of surface elevation is predicted by the model.     

Vertical geochemical variations and arsenic mobilization in the shallow alluvial aquifers of the Chapai-Nawabganj District, northwestern Bangladesh: implication of siderite precipitation

Core sediments from three disturbed boreholes (JOR, GHAT, and RAJ) and two undisturbed boreholes (DW1 and DW2) were collected in the study area of the Chapai-Nawabganj district of northwestern Bangladesh for geochemical analyses. In the study area, groundwater samples from fourteen As-contained private wells and five nested piezometers at both the DW1 and DW2 boreholes were also collected and analyzed. The groundwater arsenic concentrations in the uppermost aquifer (10–40 m of depth) range from 3 to 315 μg/L (mean 47.73 ± 73.41 μg/L), while the arsenic content in sediments range from 2 to 14 mg/kg (mean 4.36 ± 3.34 mg/kg). An environmental scanning electron microscope (ESEM) with an energy dispersive X-ray spectrometer was used to investigate the presence of major and trace elements in the sediments. Groundwaters in the study area are generally the Ca–HCO₃ type with high concentrations of As, but low levels of Fe, Mn, NO₃ ^? and SO ₄ ^?2 . The concentrations of As, Fe, Mn decrease with depth in the groundwater, showing vertical geochemical variations in the study area. Statistical analysis clearly shows that As is closely associated with Fe and Mn in the sediments of the JOR core (r = 0.87, p < 0.05 for Fe and r = 0.78, p < 0.05 for Mn) and GHAT core (r = 0.95, p < 0.05 for Fe and r = 0.93, p < 0.05 for Mn), while As is not correlated with Fe and Mn in groundwater. The comparatively low Fe and Mn concentrations in some groundwater and the ESEM image revealed that siderite precipitated as a secondary mineral on the surface of the sediment particles. The correlations along with results of sequential extraction experiments indicated that reductive dissolution of FeOOH and MnOOH represents a mechanism for releasing arsenic into the groundwater.     

Aquifer system response to intensive pumping in urban areas of the Gangetic plains,India: the case study of Patna

A significant component of domestic demand for water of urban areas located in the Gangetic plains is met by heavy pumping of groundwater. The present study is focused on the Patna municipal area, inhabited by 17 million people and spanning over 134 km², where entire urban water demand is catered from pumping by wells of various capacities and designs. The present study examines the nature of the aquifer system within the urban area, the temporal changes in the water/piezometric level and the recharge mechanism of the deeper aquifers. The aquifer system is made up of medium-to-coarse unconsolidated sand, lying under a ~40-m-thick predominantly argillaceous unit holding 8- to 13-m-thick localised sand layers and continues up to 220 m below ground. Groundwater occurs under semi-confined condition, with transmissivity of aquifers in 5,500–9,200 m² day^?1 range. Hydraulic head of the deeper aquifer remains in 9–19 m range below ground, in contrast to 1–9 m range of that of the upper aquitard zone. The estimated annual groundwater extraction from the deeper aquifer is ~212.0 million m³, which has created a decline of 3.9 m in the piezometric level of the deeper aquifer during the past 30 years. Unregulated construction of deep tube wells with mushrooming of apartment culture may further exacerbate the problem. The sand layers within the aquitard zone are experiencing an annual extraction of 14.5 million m³ and have exhibited stable water level trend for past one and half decades. This unit is recharged from monsoon rainfall, besides contribution from water supply pipe line leakage and seepage from unlined storm water drains.     

Characterisation of groundwater recharge conditions and flow mechanisms in bedrock aquifers of the Johannesburg area,South Africa

Groundwater is the major source of water and a critical resource for socioeconomic development in semi-arid environments like the Johannesburg area. Environmental isotopes are employed in this study to characterise groundwater recharge and flow mechanisms in the bedrock aquifers of Johannesburg, which is known for polluted surface water. With the exception of boreholes near the Hartbeespoort Dam, groundwater in the study area was derived from meteoric water that has undergone some degree of evaporation before recharge, possibly via diffuse mechanisms. Boreholes that tap groundwater from the Transvaal Supergroup Formation show depletion in δ¹⁸O and δ²H values. This is attributed to diffuse recharge through weathering fractures at high elevation that are undergoing deep circulation or recharge from depleted rainfall from the high-latitude moisture sources. The influence of focused recharge from the Hartbeespoort Dam was observed in the boreholes north of the dam, possibly as a result of the north–south trending fault lines and the north-dipping fractures in the bedding planes of quartzites. This is also supported by a reservoir water budget method which indicated a mean annual net flux of 2,084,131 m³ from Hartbeespoort Dam recharging groundwater per annum. Using tritium in the dam and boreholes located at 750 m and 5400 m downstream, average groundwater flow velocity was estimated as 202 m/year. An open system was observed in shale, andesite and granitic-gneiss aquifers indicating soil CO₂ as a dominant source of carbon (δ¹³C) in groundwater. A closed system was also observed in dolomitic aquifers indicating carbonate dissolution as the predominant source of carbon.