The content of selenium and its chemical form in sea water

By using the new fluorometric method of determination of the total selenium ( Se), Se (IV) and Se (VI), the content of selenium in sea weter was determined in the western North Pacific. Results showed that the content of Se in surface water ranged from 0.06 to 0.12g l^–1, while in deeper layers, the content increased to 0.20g l^–1. It was found that Se (IV) showed rather uniform distribution with depth, while Se (VI) increased with depth to about three times that in the surface. The ratio of Se (IV) to the Se ranged from 0.5 to 0.8 in the surface and 0.4 to 0.6 in the deep. The coexistence of the hexa- and tetravalent ions of selenium was confirmed both in surface and deep layers. Some results of observations on the content of selenium in the coastal areas of Japan were also reported.     

A new coring method in deep water

The need for accurate and undisturbed core samples has led to the development of this new coring method with controlled penetration speed (Angel Descent), to minimize the sediment shortening and deformation. The results of the last campaign are herein discussed, analyzing recovery/penetration ratio, acceleration data of the corer during penetration, and logs of magnetic susceptibility on the samples obtained using two different methodologies in the same location. The purpose of this paper is to compare the performance of the two sampling methods, to identify which system allows for less axial deformation of soils and less distortion of the structures, to obtain a geometrically unaltered sedimentary sequence.     

A new expression for the production rate of sea water droplets on the sea surface

A new set of empirical formulas for the production rate and the number concentration of sea-water droplets on the sea surface are proposed, synthesizing past observation data of sea-salt particles in the sea and water droplets in wind-wave tanks. A new levelz _c is introduced as the effective wind-sea surface where seawater droplets are produced. The new formulas are expressed in linear functions in logarithmic scales ofu*²/v _p , a parameter to describe overall conditions of airsea boundary processes, whereu _* is the friction velocity of air,v the kinematic viscosity of air and _p the peak angular frequency of wind-wave part of wave spectra. A model of coexistence of spray droplets and suspended particles near the sea surface is proposed. As for the independent parameter, a comparison between the uses ofu*²/v _p and ofu _* ³ which was the traditional way of parameterization excluding wave measure, shows that the advantage of usingu*²/v _p is statistically significant with a confidence limit 89% in F-test.     

海水中胶体有机碳的测定──高温燃烧法和紫外/过硫酸钾法的比较

利用切向超滤(cross-flow ultrafiltration)技术对海水中胶体有机碳(COC)和真溶解有机碳(UOC)进行了分离,并分别用高温燃烧法和紫外/过硫酸钾法对胶体有机碳和真溶解有机碳进行了测定。测定结果表明,切向超滤能定量分离海水中的胶体有机碳,高温燃烧法和紫外/过硫酸钾法对胶体有机碳和真溶解有机碳的测定结果没有明显的系统误差,表明这两种方法的氧化效率基本相同,胶体粒子的存在,对紫外/过硫酸钾法的氧化效率没有显着影响。     

一种新的海滩地下水和地表水耦合计算方法

海滩地下水与地表水之间的质量和动量交换对于近岸海域的泥沙输运、盐水入侵以及地表水与地下水中污染物质的迁移扩散有重要的影响。通过对描述地下水和地表水运动的控制方程的有限差分离散格式进行重新组织,构造了一种新的地下水和地表水的耦合计算方法。作为地表水与地下水的分界面的海滩动边界在该模型中可以被隐式的模拟,无需特别处理。通过与解析解和实验数据的比较,证明本文方法可以有效地对斜坡海滩的地下水和地表水运动进行模拟。     

Silicate determination in sea water: Toward a reagentless electrochemical method

Silicate has been determined in sea water by four different electrochemical methods based on the detection of the silicomolybdic complex formed in acidic media by the reaction between silicate and molybdenum salts. The first two methods are based on the addition of molybdate and protons in a seawater sample in an electrochemical cell. Cyclic voltammetry presents two reduction and two oxidation peaks giving four values of the concentration and therefore increasing the precision. Then chronoamperometry is performed on an electrode held at a constant potential. A semi-autonomous method has been developed based on the electrochemical anodic oxidation of molybdenum, the complexation of the oxidation product with silicate and the detection of the complex by cyclic voltammetry. This method is tested and compared with the classical colorimetric one during ANT XXIII/3 cruise across Drake Passage (January–February 2006). The detection limit is 1 μM and the deviation between both methods is less than 3% for concentrations higher than 10 μM. Finally a complete reagentless method with a precision of 2.6% is described based on the simultaneous formation of the molybdenum salt and protons in a divided electrochemical cell. This latter method should be very useful for developing a reagentless sensor suitable for long term in situ deployments on oceanic biogeochemical observatories.     

一种计算有限水深波能功率的新方法

海洋波浪能平均功率的准确计算是波浪能开发和利用的基础。实践中,波浪能转换装置一般安装在有限水深区域。对于随机波,只有当详尽的波浪谱已知的时候,有限水深区的波能功率才能被准确计算出来。由于种种原因,实践中波浪的实测数据大多以散点图或有义波高和统计波周期的形式给出,而波浪谱信息有时则很难获得。基于这种情况,传统上人们利用无限水深条件下的相关公式来估算有限水深区域的波能功率,但这种做法会造成较大的误差。本研究显示,对于50 m水深的理论波谱JONSWAP谱来说该误差高达14.6%。为了提高波能功率计算的准确性,本文提出了一种基于能量频率的一阶和二阶近似算法,可以在未知波浪谱的情况下较为准确地计算不同水深时的波能功率。针对两种理论波浪谱的计算结果表明,本方法在计算有限带宽内的波能功率时计算误差低于2.8%。     

一种提高深远海全深度声速剖面重构精度的方法

开展多波束水深测量应同步进行声速剖面探测.因海上作业条件恶劣、作业时间受限及设备性能局限等影响,在深远海海域常获取不到全深度的实测声速剖面.尽管利用温盐场模型可将声速剖面直接延拓至实地水深的最大深度,但这种气候态平均声速剖面与实际的声速剖面间存在不可控的系统性偏差,会给声速改正及水深测量成果带来质量隐患.给出了一种提高...     

A numerically effective calculation of sea water density

Accurate density calculation that includes pressure effects is achieved with negligible computational cost in the context of three-dimensional ocean modelling. Local linear (or quadratic) fits to the full UNESCO (Anon, 1981) equation of state can be used in many model applications where the potential temperature and salinity at a model grid point vary slightly in each model time step. The local polynomial fit is achieved by computing a Taylor series expansion about a local reference state. The terms in the Taylor series are calculated analytically for optimal accuracy and minimal computational cost. All calculations can be done with single precision arithmetic, without compromising accuracy. In a three-dimensional nonhydrostatic ocean model applied to a deep convection problem, the local density calculation reduced the total computational cost of the model by 7% relative to that when the full UNESCO density calculation was used. The computational advantage is 15% for an application in which the nonhydrostatic part of the calculation is turned off. The computational advantage is, however, a function of the nature of both the model being used and the problem being solved.The principal algorithms are coded in Fortran 90, fortran 77, and as Matlab functions. The complete set of routines and test programs is coded in Fortran 90.     

海水中铁的测定方法

铁在地壳中的丰度为5.6% [1],但是在海水中的浓度却很低 ,特别是大洋中只有0.05～2nmol/L [2]。在整个海水体系的生物地球化学过程中 ,铁是一种举足轻重的元素。特别是对浮游植物 ,铁的重要性远远超过了其它微量元素 ,在植物的光合作用、电子呼吸链、氮的还原、叶绿素合成等方面有重要作用[3]。在类似南大洋[2]和赤道太平洋[4]的海域 ,同其中的主要营养盐 (氮、磷、硅 )的高浓度相比 ,其浮游植物的生物量却很低。近年来的研究表明这些区域的生物量是由铁限制的[5]。赤道太平洋海域(IronEX)[4]和极地南大洋(SORIREE)[6]的表层海水施铁实…     

一种利用SMOS卫星观测的海表面盐度反演海水盐度廓线的方法

This paper proposes a new method to retrieve salinity profiles from the sea surface salinity(SSS) observed by the Soil Moisture and Ocean Salinity(SMOS) satellite. The main vertical patterns of the salinity profiles are firstly extracted from the salinity profiles measured by Argo using the empirical orthogonal function. To determine the time coefficients for each vertical pattern, two statistical models are developed. In the linear model, a transfer function is proposed to relate the SSS observed by SMOS(SMOS_SSS) with that measured by Argo, and then a linear relationship between the SMOS_SSS and the time coefficient is established. In the nonlinear model, the neural network is utilized to estimate the time coefficients from SMOS_SSS, months and positions of the salinity profiles. The two models are validated by comparing the salinity profiles retrieved from SMOS with those measured by Argo and the climatological salinities. The root-mean-square error(RMSE) of the linear and nonlinear model are 0.08–0.16 and 0.08–0.14 for the upper 400 m, which are 0.01–0.07 and 0.01–0.09 smaller than the RMSE of climatology. The error sources of the method are also discussed.     

海水石油类物质吸收系数遥感化提取算法研究

Establishing the remote sensing algorithm of retrieving the absorption coefficient of seawater petroleum substances is an efficient way to improve the accuracy of retrieving a seawater petroleum concentration using a remote sensing technology. A remote sensing reflectance is a basic physical parameter in water color remote sensing. Apply it to directly retrieve the absorption coefficient of seawater petroleum substances is of potential advantage. The absorption coefficient of waters containing petroleum [ACWCP, a_o(λ)], consists of the absorption coefficient of pure water [ACPW, a_w(λ)], plankton [ACP, a_(ph)(λ)], colored scraps [ACCS, a_(d,g)(λ)], and petroleum substance [ACPS, a_(oil)(λ)]. Among those, ACCS consists of the absorption coefficient of nonalgal particle [ACNP, a_d(λ)] and colored dissolved organic matter [ACCDOM, a_g(λ)]. For waters containing petroleum, the retrieved ACCS using the existing method is a combination absorption coefficient of ACNP,ACCDOM and ACPA [CAC, a_(d,g,oil)(λ)]. Therefore, the principle question is how to extract ACPS from CAC.Through the analysis of the three proportion tests conducted between the year of 2013 and 2015 and the corresponding remote sensing data, an algorithm of retrieving the absorption coefficient of petroleum substances is proposed based on remote sensing reflectance. First of all, ACPS and CAC are retrieved from the reflectance using the quasi-analytical algorithm(QAA), with some parameter modified. Secondly, given the fact that the backscatter coefficient [BC, b_(bp)(555)] of total particles at 555 nm can be obtained completely from the reflectance, the relation between BC and ACNP in petroleum contaminated water can be established. As a result, ACNP can be calculated. Then, combining the remote sensing retrieving algorithm of a_g(440), the method of achieving the spectral slope of the absorption coefficient can be established, from which ACCDOM,can be calculated. Finally, ACPS can be computed as the residual. The accuracy of ACPS based on this algorithm is 86% compared with the in situ measurements.     

Chemical forms of zinc in sea water

Recent experimental evidence concerning the chemical forms of zinc occurring in sea water is reviewed in order to aid in the systematic understanding of zinc geochemistry in the marine environment. The review indicates the necessity of systematizing the results obtained by different methods for the determination of zinc in sea water with respect to the chemical nature of the zinc fractions measured. Analytical procedures for the zinc determinations in sea water by spectrophotometry with dithizone extraction and anodic stripping voltammetry with composite mercury graphite electrodes are described. By using these methods, various pre-treatment tests were carried out to relate the results of different modes of measurements to the chemical forms of zinc involved. The comparisons of the results of these tests lead to an estimation of the occurrence of the following categories of chemical forms of zinc in sea water: (1) ionic plus labile form, (2) inorganic complexes and colloids as well as weak organic complexes and (3) occuled fraction in large organic molecules and/or organic colloids. Capabilities of different analytical procedures for differentiating one category from another are discussed.     

Ionic medium effects in sea water — A comparison of acidity constants of carbonic acid and boric acid in sodium chloride and synthetic sea water

It is shown that the values of pK_1C and pK_2C for carbonic acid, pK_B for boric acid and the ionic product of water, pK_w, in sea water may be explained on the basis of their determination in 0.7 M_w sodium chloride and the formation of the following ion-pairs: NaSO₄^?, MgSO₄, CaSO₄, MgCO₃, CaCO₃, MgHCO₃⁺, CaHCO₃⁺, MgOH⁺, HSO₄^?, MgB(OH)₄⁺ and CaB(OH)₄⁺. On the whole the calculated stability constants are lower than those given by Garrels and Thompson (1962).     

Measurements of dissolved organic carbon (DOC) in sea water by high temperature combustion method

Dissolved organic carbon (DOC) is the largest organic carbon reservoir in sea water and plays an imporrant role in the marine carbon cycle and other biogeochemical processes in the ocean. Accurate and precise determinalion of the bOC concentration in sea water is thus a prerequisite for any interpretation of DOC biogeochemistry. A key factor in analytical quality control is an accurate determination of the blank. The assessment and distinction of DOC blanks are essential for the precise measurements of oceanic DOC. The total DOC blank includes instrument and water blanks in the high temperature catalytic oxidation (HTCO) method. DOC can be measured accurately using the HTCO method only when the instrument blank is correctly distinguished from the total DOC blank and corrected in the sample measurements. Low DOC blanks can be achieved by extensive conditioning of new catalysts and the whole instrument system, whereas instrument blanks can be quantified by subtracting the water blank from the total DOC blank. We have been able to produce low carbon nanopure water [≤2μmol/dm³(C)] and have a low instrumental blank [< 5-6 μmol/dm³(C)] when using the HTCO method. Results of concentrations and distributions of DOC in the Gulf of Mexico and the North Atlantic are oceanographically consistent. Results from DOC measurements on samples from the international DOC methods comparison program further confirmed our low values of both nenopure water and the instrument blank.     

A mid-depth front separating the South China Sea water and the Philippine sea water

In order to understand the influence of the South China Sea (SCS) water on the Kuroshio, and to study the dissolved carbonate system, we participated in six WOCE cruises aboard R/V Ocean Researcher 1. The areas studied were the northeast South China Sea and the West Philippine Sea near the Luzon Strait. Temperature, salinity, pH, alkalinity and total CO₂ were measured. Our data indicate that, although the Kuroshio and the SCS waters flow in and out of the Luzon Strait near surface, the SCS water seems mainly to flow out of the SCS at mid-depth. There exists a mid-depth front near 122°E between 350 and 1350 m in all seasons and years that we studied. The water mass between 350 and 1350 m east of the front belongs to the West Philippine Sea proper water, while on the west is the mixed water of the South China Sea and the West Philippine Sea.     

Indication of thiols in black sea deep water

Potentiometric titrations of deep Black Sea water give reasonably precise values of sulphide in the concentration range 30–300 μmol l⁻¹ and a strong indication of thiols in the concentration range 10–30 μmol l⁻¹. Organic analysis of Black Sea water should therefore include the search for compounds containing SH groups. A simple stoichiometric model indicates that sulphur-containing proteins might be the main source of thiols after hydrolysis and deamination. The alkalinity and total sulphide are simply related by A_t = 3287 ± 30 + (3.84 ± 0.10) [H₂ S]_t μmol kg⁻¹. The slope of 3.84 instead of the stoichiometric slope of 2.31 indicates a lack of reduced sulphate in the form of hydrogen sulphide.     

海水中溶解有机磷的测定方法

磷和氮一样,都是海洋环境中的重要生源要素,其在水环境中的时空分布控制着海洋生态系统中的初级生产过程.在大洋或深海区,氮的供应相对不足常是初级生产的制约因素,但在浅海区,特别是河口和海湾,由于农业施肥、城市污水及大气干湿沉降等的作用,氮/磷比值常远高于Redfield比值,从而使磷成为初级生产的制约因素^[1-6].