Application of a step-by-step fingerprinting identification method on a spilled oil accident in the Bohai Sea area

In recent years, oil spill accidents occur frequently in the marine area of China. Finding out the spilled oil source is a key step in the relevant investigation. In this paper, a step-by-step fingerprinting identification method was used in a spilled oil accident in the Bohai Sea in 2002. Advanced chemical fingerprinting and data interpretation techniques were used to characterize the chemical composition and determine the possible sources of two spilled oil samples. The original gas chromatography -flame ionization detection (GC-FID) chromatogram of saturated hydrocarbons was compared. The gas chromatography-mass spectrometry (GC/MS) chromatograms of aromatic hydrocarbons terpane and sterane, n-alkane and poly-aromatic hydrocarbons (PAHs) were analyzed. The correlation analysis on diagnostic ratios was performed with Student’s t-test. It is found that the oil fingerprinting of the spilled oil (designated as sz1) from the polluted sand beach was identical with the suspected oil (designated as ky1) from a nearby crude oil refinery factory. They both showed the fingerprinting character of mixed oil. The oil fingerprinting of the spilled oil (designated as ms1) collected from the port was significantly different from oil ky1 and oil sz1 and was with a lubricating oil fingerprint character. The identification result not only gave support for the spilled oil investigation, but also served as an example for studying spilled oil accidents.     

WIND WAVES SIMULATION IN THE NORTH AREA OF THE SOUTH CHINA SEA

A third generation wave model was developed to simulate wind waves in the South China Sea near Hong Kong. The model solves the energy conservation equation of the two dimensional wave spectrum by directly computing the nonlinear energy interaction among waves of different frequencies, thus avoiding the imposition of restrictions on the shape of the predicted spectra. The use of an upwind difference scheme in the advective terms produces an artificial diffusion which partly compensates the dispersive effect due to the phase velocity differences among various wave components. The use of a semi-implicit scheme for the source terms together with a special treatment of the high frequency tail of the spectrum allows a large time integration step. Verification of the model was done for wave hindcasting studies under conditions of two typhoons and two cold fronts in the north part of the South China Sea near Hong Kong . The model results agree well with the field measurements except that the presence of a dista     

Kuroshio intrusion into the South China Sea with an anticyclonic eddy: evidence from underwater glider observation

In this study,high-resolution temperature and salinity data obtained from three Sea-Wing underwater gliders were used together with satellite altimeter data to track the vertical thermohaline structure of an anticyclonic eddy that originated from the loop current of the Kuroshio southwest of Taiwan,China.One of the gliders crossed the entire eddy and it observed a remarkable warm anomaly of as much as 3.9℃ extending to 500 dbar from the base of the mixed layer.Conversely,a positive salinity anomaly was found to be above 200 dbar only in the anticyclonic eddy,with a maximum value of 0.5 in the mixed layer.Below the mixed layer,water of higher salinity(34.7)was found,which could have been preserved through constrained vertical mixing within the anticyclonic eddy.The salinity in the upper layer of the anticyclonic eddy was much similar to that of the northwestern Pacific Ocean than the northern South China Sea,reflecting Kuroshio intrusion with anticyclonic eddy shedding from the loop current.     

Modeling seasonal variations of subsurface chlorophyll maximum in South China Sea

In the South China Sea(SCS), the subsurface chlorophyll maximum(SCM) is frequently observed while the mechanisms of SCM occurrence have not been well understood. In this study, a 1-D physical-biochemical coupled model was used to study the seasonal variations of vertical profiles of chlorophyll-a(Chl-a) in the SCS. Three parameters(i.e., SCM layer(SCML) depth, thickness, and intensity) were defined to characterize the vertical distribution of Chl-a in SCML and were obtained by fitting the vertical profile of Chl-a in the subsurface layer using a Gaussian function. The seasonal variations of SCMs are reproduced reasonably well compared to the observations. The annual averages of SCML depth, thickness, and intensity are 75 ± 10 m, 31 ± 6.7 m, and 0.37 ± 0.11 mg m-3, respectively. A thick, close to surface SCML together with a higher intensity occurs during the northeastern monsoon. Both the SCML thickness and intensity are sensitive to the changes of surface wind speed in winter and summer, but the surface wind speed exerts a minor influence on the SCML depth; for example, double strengthening of the southwestern monsoon in summer can lead to the thickening of SCML by 46%, the intensity decreasing by 30%, and the shoaling by 6%. This is because part of nutrients are pumped from the upper nutricline to the surface mixed layer by strong vertical mixing. Increasing initial nutrient concentrations by two times will increase the intensity of SCML by over 80% in winter and spring. The sensitivity analysis indicates that light attenuation is critical to the three parameters of SCM. Decreasing background light attenuation by 20% extends the euphotic zone, makes SCML deeper(~20%) and thicker(12% – 41%), and increases the intensity by over 16%. Overall, the depth of SCML is mainly controlled by light attenuation, and the SCML thickness and intensity are closely associated with wind and initial nitrate concentration in the SCS.     

珠江口盆地白云-荔湾深水区幔源CO2充注的黏土矿物成岩响应

珠江口盆地白云-荔湾深水区油气勘探中钻遇大量高含量CO₂气层,使得如何规避高CO₂风险成为当前面临的挑战。通过工区充注CO₂的储层砂岩黏土矿物X射线衍射（XRD）、流体包裹体显微测温和稀有气体同位素组成等分析,明确了幔源无机CO₂的成因,并运用黏土矿物特征讨论高温幔源无机CO₂充注的黏土矿物成岩响应:有序带倒转和大量自生高岭石的生成。依据CO₂气井的XRD全定量分析数据剖面图将幔源无机CO₂气层段的黏土矿物组合分为3类:Ⅰ类为I/S混层黏土矿物中S体积分数介于10%~25%之间,有序度处于R₂~R₃带,高岭石体积分数高;Ⅱ类为I/S混层黏土矿物中S体积分数介于10%~15%,有序度为R₂~R₃带,自生高岭石体积分数低;Ⅲ类为I/S混层黏土矿物中S体积分数介于50%~60%,有序度为R₀带,高岭石体积分数低。总结出幔源CO₂在珠江组和珠海组中存在2种运聚模式:一是幔源CO₂通过与基性岩浆连通的深大断裂垂直向上运聚;二是垂直向上运移后通过连通砂体侧向长距离运聚。研究结果对珠江口盆地白云-荔湾深水区下一步油气勘探规避高含量CO₂风险具有指导作用。      

Sediment compaction and pore pressure prediction in deepwater basin of the South China Sea: Estimation from ODP and IODP drilling well data

Overpressure in deepwater basins not only causes serious soft sediment deformation, but also significantly affects the safety of drilling operations. Therefore, prediction of overpressure in sediments has become an important task in deepwater oil exploration and development. In this study, we analyze the drilling data from ODP Leg 184 Sites 1144, 1146, and 1148, and IODP Leg 349 Sites U1431, U1432, U1433, and U1435 to study the sediment compaction and controls in the northern South China Sea. Sedimentation rate, sediment content, distribution area, and buried depth are the factors that influence sediment compaction in the deepwater basin of the South China Sea. Among these factors, the sediment content is the most important. The fitted normal compacted coefficients and mudline porosity for an interval of 50 m shows disciplinary variation versus depth. The pore pressure predicted from different fitted results shows varying overpressure situations. The normal compaction trend from Site 1144 reflects the porosity variation trend in stable deposition basins in the northern South China Sea. The predicted pore pressure shows overpressure at Site 1144, which is attributed to compaction disequilibrium. Nevertheless, the mixed lithology column may influence the predicted over-pressure at Site 1148, which is responsible for the confusing result. Above all, we find that sediment compaction should serve as a proxy for pore pressure in the deepwater basin of the South China Sea.     

Dimethylsulfide in the South China Sea

ＩＮＴＲＯＤＵＣＴＩＯＮＧｒｅａｔｅｆｆｏｒｔｓｗｅｒｅｄｅｖｏｔｅｄｒｅｃｅｎｔｌｙｔｏｓｔｕｄｙｉｎｇｄｉｍｅｔｈｙｌｓｕｌｆｉｄｅ(ＤＭＳ)ｄｉｓｔｒｉｂｕｔｉｏｎｉｎｓｅａｗａｔｅｒ,ａｓｉｔａｃｃｏｕｎｔｓｆｏｒｔｈｅｍａｊｏｒｐａｒｔｏｆｔｈｅｓｕｌｆｕｒｆｌｕｘｆｒｏｍｔｈｅｏｃｅａｎｓｔｏｔｈｅａｔｍｏｓｐｈｅｒｅ.Ｍｏｒｅｏｖｅｒ,ｉｔｓｏｘｉｄａｔｉｏｎｐｒｏｄｕｃｔｓｉｎｔｈｅａｔｍｏｓｐｈｅｒｅｍａｙｉｎｆｌｕｅｎｃｅｅｎｖｉｒｏｎｍｅｎｔａｌａｃｉｄｉｆｉｃａｔｉｏｎａｎｄ…     

Role of Ekman transport versus Ekman pumping in driving summer upwelling in the South China Sea

Relative roles of Ekman transport and Ekman pumping in driving summer upwelling in the South China Sea (SCS) are examined using QuikSCAT scatterometer wind data. The major upwelling regions in the SCS are the coastal regions east and southeast of Vietnam (UESEV), east and southeast of Hainan Island (UESEH), and southeast of Guangdong province (USEG). It is shown that the Ekman transport due to alongshore winds and Ekman pumping due to offshore wind stress curl play different roles in the three upwelling systems. In UESEV, Ekman pumping and Ekman transport are equally important in generating upwelling. The Ekman transport increases linearly from 0.49 Sv in May to 1.23 Sv in August, while the Ekman pumping increases from 0.36 to 1.22 Sv during the same period. In UESEH, the mean estimates of Ekman transport and Ekman pumping are 0.14 and 0.07 Sv, respectively, indicating that 33% of the total wind-driven upwelling is due to Ekman pumping. In USEG, the mean Ekman transport is 0.041 Sv with the peak occurring in July, while Ekman pumping is much smaller (0.003 on average), indicating that the upwelling in this area is primarily driven by Ekman transport. In the summers of 2003 and 2007 following El Niño-Southern Oscillation (ENSO) events, both Ekman transport and Ekman pumping decrease in UESEV due to the abnormally weak southwest monsoon. During the same events, however, Ekman transport is slightly enhanced and Ekman pumping is weakened in UESEH and USEG.     

Water masses in the South China Sea and water exchange between the Pacific and the South China Sea

Water masses in the South China Sea (SCS) were identified and analyzed with the data collected in the summer and winter of 1998. The distributions of temperature and salinity near the Bashi Channel (the Luzon Strait) were analyzed by using the data obtained in July and December of 1997. Based on the results from the data collected in the winter of 1998, waters in the open sea areas of the SCS were divided into six water masses: the Surface Water Mass of the SCS (S), the Subsurface Water Mass of the SCS (U), the Subsurface-Intermediate Water Mass of the SCS (UI), the Intermediate Water Mass of the SCS (I), the Deep Water Mass of the SCS (D) and the Bottom Water Mass of the SCS(B). For the summer of 1998, the Kuroshio Surface Water Mass (KS) and the Kuroshio Subsurface Water Mass (KU) were also identified in the SCS. But no Kuroshio water was found to pass the 119.5°E meridian and enter the SCS in the time of winter observations. The Sulu Sea Water (SSW) intruded into the SCS through the Mindoro Channel between 50–75 m in the summer of 1998. However, the data obtained in the summer and winter of 1997 indicated that water from the Pacific had entered the SCS through the northern part of the Luzon Strait in these seasons, but water from the SCS had entered the Pacific through the southern part of the Strait. These phenomena might correlate with the 1998 El-Niño event.     

Deep-sea geohazards in the South China Sea

Various geological processes and features that might inflict hazards identified in the South China Sea by using new technologies and methods.These features include submarine landslides,pockmark fields,shallow free gas,gas hydrates,mud diapirs and earthquake tsunami,which are widely distributed in the continental slope and reefal islands of the South China Sea.Although the study and assessment of geohazards in the South China Sea came into operation only recently,advances in various aspects are evolving at full speed to comply with National Marine Strategy and‘the Belt and Road’Policy.The characteristics of geohazards in deep-water seafloor of the South China Sea are summarized based on new scientific advances.This progress is aimed to aid ongoing deep-water drilling activities and decrease geological risks in ocean development.     

Some new species of radiolaria from surface sediments of the East China Sea and the South China Sea

Fourteen species of Radiolaria described in this paper were discovered from surface sediments of the East China Sea, the South China Sea and the cores of the Okinawa Trough. Type specimens are deposited in the Second Institute of Oceanography, SOA.     

Empirical Equations of P-Wave Velocity in the Shallow and Semi-Deep Sea Sediments from the South China Sea

Three-hundred and thirty-one sediment cores, including six sediment types(clayey-and sandy-silt, silty-and sandy-clay, clayey-and silty-sand) were collected from the shallow and semi-deep seas of the South China Sea, and the P-wave velocities and physical properties of core sediments were measured under standard laboratory conditions. To eliminate the influence of environmental factors, the empirical sound speed ratio equations were established. Compared with several equations from literature, the porosity and wet bulk density empirical equations established in this paper agree well with Richardson and Briggs(2004)'s in-situ equations, which implies that our empirical equations can be used in the similar region of world's oceans under certain conditions and will be useful in areas lacking first-hand P-wave speed data. However, the mean grain size equations established in this study, similar to the previous studies, have low accuracy, which may be due to the different particle arrangements and degrees of compaction in sediments. The results also show that for different sediment types, the equation based on all sediment data is in good agreement with the measured data in the study area, as there are both siliciclastic and carbonate sediments on the studied seabed. It is suggested that appropriate empirical equations should be selected according to sediment types and sedimentary environment in future works, and the empirical equation of porosity or the two-parameter equation of porosity and grain size should be preferred.     

Mass transport of a mesoscale eddy in the South China Sea identified by a simulated passive tracer

Journal of Oceanology and Limnology - To quantitatively investigate the water mass transport of mesoscale eddies, the mass transport induced by a simulated anticyclonic eddy in the South China Sea...     

SEAWATER FLUX OF THE SOUTH CHINA SEA

The South China Sea water can be divided according to depth into three boxes by the pycnoclineand a sill.Using a box model with matter balance,the net seawater fluxes were calculated to be317.9×10~4 m~3/s in box Ⅰ for the upper homogeneous layer outflowing to the adjoining oceans;67×10~4 m~3/s in box Ⅲ for the water entering the basin;240×10~4 m~3/s in box Ⅱ for water entering theSouth China Sea.The upward speed of basin water was calculated to be 8.4×10~(-5) cm/s and that ofseawater flowing up along the pycnocline was calculated to be 8.9×10~(-5) cm/s.     

Planaxidae (Mollusca,Gastropoda) from the South China Sea

Planaxidae is a family of tropical and subtropical marine gastropods that are adapted to an intertidal, rocky environment. The present study deals with three species in the family Planaxidae from the South China Sea: P lanaxis sulcatus(von Born, 1778), Angiola longispira(Smith, 1872), and S upplanaxis niger(Quoy and Gaimard, 1833), based on specimens deposited in the Marine Biodiversity Collections of the South China Sea, Chinese Academy of Sciences. The taxonomic status, main morphological characteristics of the shell and radula, distribution, and habitat of these three planaxid species are presented. We also briefly discuss their morphological dif ferences and the biogeographic distribution.     

On the sources of the Taiwan Warm Current from the South China Sea

Historical hydrographic data across several sections in the South China Sea (SCS) and Taiwan Strait have been reconsidered. The year-around existence of the South China Sea Warm Current (SCSWC) along the shelf break off the Guangdong coast and the seemingly year-around southwestward current to the east of SCSWC are both evident in the data. The data also showed that the northward current in the Taiwan Strait seemed to be the extension of SCSWC. A barotropic numerical model is employed to explain some of the observed features. Reasonable simulation of the circulation in the northeast part of SCS has been found.     

CHARACTERIZATION OF FINE-GRAINED TURBIDITE DEPOSITS FROM THE SOUTH CHINA SEA SEDIMENT CORES

Two depositional processes controlled the muddy sediments in the South China Sea Basin. Bathyal sediments depositional rate was 7.66 cm/la in the northern continental slope of the Basin where turbidity current was almost nonexistent. In the northern margin of the Basin, abyssal sediment depositional rate was 5.05cm/ka and turbidity current occurrence averaged 0.22 per 1000 years. Turbidite was found in the middle of the Basin. Over half of the muddy sediments in the deep sea basin were deposited by turbidity currents, and had typically graded bedding, and contents of organic matter, calcareous material and micropaleontologic species inconsistent with the environment.     

Diatom assemblages in surface sediments from the South China Sea as environmental indicators

We studied diatom distribution from 62 samples from the uppermost 1 cm of sediment in the South China Sea (SCS), using grabs or box corers in three cruises between 2001–2007. Fifty six genera, 256 species and their varieties were identified. Dominating species included Coscinodiscus africanus, Coscinodiscus nodulifer, Cyclotella stylorum, Hemidiscus cuneiformis, Melosira sulcata, Nitzschia marina, Roperia tesselata, Thalassionema nitzschioides, Thalassiosira excentrica, and Thalassiothrix longissima. Most surface sediments in the SCS were rich in diatoms, except for a few coarse samples. Average diatom abundance in the study area was 104 607 valve/g. In terms of the abundance, ecology, and spatial distribution, seven diatom zones (Zones 1–7) were recognized. Zone 1 (northern continental shelf) is affected by warm currents, SCS northern branch of the Kuroshio, and northern coastal currents; Zone 2 (northwestern continental shelf) is affected by intense coastal currents; Zone 3 (Xisha Islands sea area) is a bathyal environment with transitional water masses; Zone 4 (sea basin) is a bathyal-to-deep sea with stable and uniform central water masses in a semi-enclosed marginal sea; Zone 5 (Nansha Islands marine area) is a pelagic environment with relatively high surface temperature; Zone 6 (northern Sunda Shelf) is a tropical shelf environment; and Zone 7 (northern Kalimantan Island shelf area) is affected by warm waters from the Indian Ocean and coastal waters. The data indicate that these diatom zones are closely related to topography, hydrodynamics, temperature, nutrients and especially the salinity. Better understanding of the relationship between diatom distribution and the oceanographic factors would help in the reconstruction of the SCS in the past.     

THE NOMENCLATURE OF THE SOUTH CHINA SEA ISLANDS IN ANCIENT CHINA

ＴＨＥＮＯＭＥＮＣＬＡＴＵＲＥＯＦＴＨＥＳＯＵＴＨＣＨＩＮＡＳＥＡＩＳＬＡＮＤＳＩＮＡＮＣＩＥＮＴＣＨＩＮＡ￥ＬｉｕＮａｎｗｅｉ（刘南威）（ＤｅｐａｒｔｍｅｎｔｏｆＧｅｏｇｒａｐｈｙ，ＳｏｕｔｈＣｈｉｎａＮｏｒｍａｌＵｎｉｖｅｒｓｉｔｙ，Ｇｕａｎｇｚ...     

Pathways of mesoscale variability in the South China Sea

The propagation of oceanic mesoscale signals in the South China Sea (SCS) is mapped from satellite altimetric observations and an eddy-resolving global ocean model by using the maximum cross-correlation (MCC) method. Significant mesoscale signals propagate along two major bands of high variability. The northern band is located west of the Luzon Strait, characterized by southwestward eddy propagation. Although eddies are the most active in winter, their southwestward migrations, steered by bathymetry, occur throughout the year. Advection by the mean flow plays a secondary role in modulating the propagating speed. The southern eddy band lies in the southwest part of the SCS deep basin and is oriented in an approximately meridional direction. Mesoscale variability propagates southward along the band in autumn. This southward eddy pathway could not be explained by mean flow advection and is likely related to eddy detachments from the western boundary current due to nonlinear effects. Our mapping of eddy propagation velocities provides important information for further understanding eddy dynamics in the SCS.