Neoarchean crust-mantle interactions in the Yishui Terrane,south-eastern margin of the North China Craton: Constraints from geochemistry and zircon U-Pb-Hf isotopes of metavolcanic rocks and high-K granitoids

The Neoarchean Yishui Terrane (YST) is situated in the east of Western Shandong Province (WSP), south-eastern margin of the North China Craton (NCC). The metavolcanic rocks of the YST are fine-grained hornblende plagioclase gneisses (Group #1) and fine-grained amphibolites (Group #2) in the Yangzhuangzhen area and fine- to medium-grained amphibolites (Group #3) in the Leigushan area. The high-K granitoids associated with Groups #1 and 2 are dominated by fine- to medium-grained monzogranitic gneisses. Zircon LA-ICP-MS U-Pb dating reveals that the magmatic precursors of Groups #1 and #2 were formed at 2641 Ma and the magmatic precursors of concomitant monzogranitic gneisses were emplaced from 2615 to 2575 Ma, whereas Group #3 represents a later 2500 Ma volcanic eruption, and all these metamorphic volcanic rocks and monzogranitic gneisses were subjected to subsequent 2470–2460 Ma metamorphism.The metamorphic volcanic rock samples in Group #1 exhibit the chemical compositions of calc-alkaline andesites, showing fractionated chondrite-normalized REE patterns ((La/Yb)_N = 10.48–19.30) and negative Nb, Ta and Ti anomalies ((Nb/La)_PM = 0.13–0.22), which are akin to those of typical high-Mg andesites (HMAs) in the subduction-related settings. The magmatic precursors of the Group #1 samples were derived from partial melting of a fluid- or melt-metasomatized depleted mantle wedge at deep levels in the upper mantle. Samples in Group #2 show calc-alkaline chemical compositions with less fractionated chondrite-normalized REE patterns ((La/Yb)_N = 2.24–3.34) and negative Nb, Ta and Ti anomalies ((Nb/La)_PM = 0.47–0.76), which are consistent with those of the volcanic rocks in the Aleutian island arc. The magmatic precursors of Group #2 were generated by partial melting of a fluid-metasomatized depleted mantle wedge at shallow levels in the upper mantle. The monzogranitic gneisses exhibit high SiO₂ and K₂O contents with high-K calc-alkaline affinities and peraluminous characteristics. Based on their distinct HREE contents and chondrite-normalized REE patterns, these granitoid samples are subdivided into low-Yb monzogranitic gneisses (LYMGs) and high-Yb monzogranitic gneisses (HYMGs). The LYMG magma was derived from partial melting of a mixed source of juvenile two-mica pelites and minor basic-intermediate igneous rocks at lower crustal levels with pyroxene + amphibole + garnet as the main residual phases, and the HYMG magma was derived from partial melting of multi-sourced juvenile two-mica pelites at middle to lower crustal levels with pyroxene + amphibole and subordinate plagioclase and garnet as the main residual phases. In addition, Group #3 resembles tholeiitic back-arc basalts in the Okinawa Trough and displays flat chondrite-normalized REE patterns ((La/Yb)_N = 1.22–2.08) and slightly negative Nb and Ta anomalies ((Nb/La)_PM = 0.35–0.59). This group was most likely derived from partial melting of a depleted mantle source that had been modified by the addition of subducted slab-derived fluids at shallow levels in the upper mantle. These metavolcanic rocks and concomitant high-K granitoids record important Neoarchean crust-mantle interactions involving the first modification and partial melting of the lithospheric mantle induced by oceanic crust subduction; then, upwelling and underplating of mantle-derived magmas triggered partial melting of the middle to lower crust and mixing between crust- and mantle-derived magmas. These processes imply that Neoarchean crust-mantle interaction played a crucial role in the evolution of the southeastern margin of the NCC.Available whole-rock Sm-Nd and zircon Lu-Hf isotopic data from metamorphic volcanic rocks and plutonic granitoids from this study and previous studies reveal that YST experienced three crucial juvenile crustal growth events from ~2.78–2.69 Ga, ~2.64–2.56 Ga and ~2.54–2.50 Ga.     

华北克拉通新太古代地壳增生:来自山西云中山地区TTG片麻岩和二长花岗片麻岩的证据

通过详细的野外地质工作,本文在山西云中山地区识别出一套岩石组合完整的TTG片麻岩岩系,与TTG片麻岩共生的还有后期发育的二长花岗片麻岩。LA-ICP-MS锆石U-Pb定年结果表明,花岗闪长质片麻岩的形成时间为2486±9Ma,二长花岗片麻岩的形成时间为2448±11Ma。地球化学特征显示研究区TTG片麻岩为高铝TTG。奥长花岗质片麻岩总体表现为高SiO_2(69.82%~73.54%)、富Na_2O(4.19%~5.16%)、高CaO(1.45%~3.03%)的特征,Al_2O_3含量为14.31%~15.74%,铝饱和指数(A/CNK)为1.00~1.03,属富钠过铝质系列岩石;英云闪长质片麻岩的特征与奥长花岗片麻岩基本相似,但K_2O含量更低,CaO含量更高;花岗闪长质片麻岩SiO_2(61.23%~61.97%)含量相对偏低,Na_2O/K_2O为1.00~1.32,Al2O3含量为15.03%~15.73%,铝饱和指数(A/CNK)为0.96~1.05,为准铝质或过铝质系列岩石。与上述TTG片麻岩不同的是,本区出露的二长花岗片麻岩表现为富钾(K_2O/Na_2O=1.22~1.44)、贫Al_2O_3(12.81%~14.27%)的特征。岩石稀土总量较低(∑REE=52.71×10~(-6)~262.0×10~(-6)),轻稀土富集,重稀土亏损,轻、重稀土强烈分馏。微量元素具有富集K、Rb、Th等大离子亲石元素,亏损Nb、Ta、Sr、P、Ti等元素的特点,Cr、Ni等相容元素含量也较低,表现出岛弧岩浆的特征。花岗闪长片麻岩和二长花岗片麻岩εHf(t)值均为正值,前者成岩年龄与二阶段模式年龄较为接近,暗示其来源为2.5~2.6Ga的新生地壳,而后者成岩年龄与二阶段模式年龄则相差较多,其测点大都落在2.7~2.8Ga地壳演化线的区域内,表明二长花岗片麻岩来自于2.7~2.8Ga的古老地壳。根据上述地球化学特征,并结合区域地质特征,推测研究区高Al的TTG片麻岩是"平俯冲"状态下洋壳部分熔融的产物,而二长花岗片麻岩为底侵古老地壳部分熔融的产物,形成于大陆边缘弧的构造环境,代表云中山地区一次重要的以水平增生为主的地壳生长事件,同时也表明在新太古代末期,云中山地区已完成克拉通化,进入陆内演化阶段。     

华北克拉通东北部新太古代晚期岩浆作用和地壳增生:锆石U-Pb-Hf同位素、微量元素和地球化学制约

辽西-辽南地区新太古代花岗质岩石的锆石LA-ICP-MS U-Pb年代学和微量元素及全岩地球化学和锆石Hf同位素研究为探讨华北克拉通东北部前寒武纪地壳生长和演化提供了制约。结果表明,辽西地区钓鱼台二长花岗岩和辽南地区城子坦片麻状石英闪长岩、安波花岗质片麻岩中锆石均发育岩浆生长环带,结合相对高的Th/U比值(0.24~1.75)和锆石稀土元素特征,暗示它们均为岩浆锆石。定年结果显示,钓鱼台二长花岗岩、城子坦片麻状石英闪长岩和安波花岗质片麻岩的原岩分别形成于2519±9Ma、2505±10Ma和2519±11Ma,即它们均形成于新太古代晚期。辽西-辽南地区新太古代花岗质岩石均具有高SiO2(61.85%~73.38%)、低MgO(0.36%~2.83%)、富Na2O+K2O(7.64%~10.86%)的特征,为准铝质-弱过铝质的高钾钙碱性系列岩石;富集轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素,发育弱的Eu负异常和Sr、P、Ti的亏损。岩浆锆石均具有正的εHf(t)值,介于0.4~5.9之间,tDM1变化于2595~2798Ma之间,峰值年龄为2740Ma,与华北克拉通最重要的一次地壳增生事件相一致。辽西-辽南地区新太古代花岗质岩石形成于板块俯冲的弧构造环境下新增生下地壳物质的部分熔融。     

阿尔金北缘新太古代TTG片麻岩的成因及其构造意义

塔里木克拉通前寒武纪构造演化,特别是早前寒武纪构造演化一直是地质学家讨论的焦点。本文通过对阿尔金北缘新太古代TTG片麻岩进行详细的野外调查、岩相学观察、地球化学分析以及锆石SHRIMP U-Pb定年来揭示该岩石的成因以及探讨塔里木克拉通早前寒武纪构造演化。锆石SHRIMP U-Pb定年结果显示阿尔金北缘TTG片麻岩的形成年龄为2740±19Ma,而后经历了新太古代(2494±53Ma)混合岩化作用和古元古代(1962±78Ma)麻粒岩相变质作用。阿尔金北缘英云闪长质片麻岩显示低的MgO含量(1.33%~3.08%)和Mg^#(37~52),具有高Sr(469×10^-6~764×10^-6)含量、低Y(4.72×10^-6~13.5×10^-6)和Yb(0.37×10^-6~0.99×10^-6)含量的特点,它们的Sr/Y比值可达到41~99。岩石的这些特征与基性下地壳部分熔融形成的TTG相同。并且,该新太古代TTG片麻岩还具有正的ε_Nd(t)值(0.2~3.6)、高的Nd同位素初始值(0.509088~0.509260)和古太古代两阶段模式年龄(3.62~3.70Ga)。因此,阿尔金北缘新太古代TTG片麻岩可能来源于基性下地壳部分熔融,并且岩浆源区有石榴石、角闪石和金红石的残留。综合前人的研究成果,对比相邻区域TTG的形成时代,变质事件的记录以及太古宙地壳增生差异都指示阿尔金北缘和敦煌-库鲁塔格地区可能来源于不同的大陆块体。

     

Late Neoarchean volcanic rocks in the southern Liaoning Terrane and their tectonic implications for the formation of the eastern North China Craton

The late Neoarchean metamorphosed volcanic rocks in the southern Liaoning Terrane (SLT) of the eastern North China Craton (NCC) are mainly composed of amphibolites and felsic gneisses and can be chemically classified as basalt (Group#1), basaltic andesite (Group#2), dacite (Group#3) and rhyodacite (Group#4). LA-ICP-MS zircon U–Th–Pb dating reveals that they formed at ~2.53–2.51 ​Ga. Group#1 samples are characterized by approximately flat chondrite-normalized rare earth element (REE) patterns with low (La/Yb)_N ratios and a narrow range of (Hf/Sm)_N ratios, and their magmatic precursors were generated by partial melting of a depleted mantle wedge weakly metasomatized by subducted slab fluids. Compared to Group#1 samples, Group#2 samples display strongly fractionated REE patterns with higher (La/Yb)_N ratios and more scattered (Hf/Sm)_N ratios, indicative of a depleted mantle wedge that had been intensely metasomatized by slab-derived melts and fluids. Group#3 samples are characterized by high MgO and transition trace element concentrations and fractionated REE patterns, which resemble typical high-Si adakites, and the magmatic precursors were derived from partial melting of a subducted oceanic slab. Group#4 samples have the highest SiO₂ and the lowest MgO and transition trace element contents, and were derived from partial melting of basaltic rocks at lower crust levels. Integrating these tholeiitic to calc-alkaline volcanic rocks with the mass of contemporaneous dioritic-tonalitic-trondhjemitic-granodioritic gneisses, the late Neoarchean volcanic rocks in the SLT were most likely produced in an active continental margin. Furthermore, the affinities in lithological assemblages, metamorphism and tectonic regime among SLT, eastern Hebei to western Liaoning Terrane (EH–WLT), northern Liaoning to southern Jilin Terrane (NL–SJT), Anshan-Benxi continental nucleus (ABN) and Yishui complex (YSC) collectively indicate that an integral and much larger continental block had been formed in the late Neoarchean and the craton-scale lateral accretion was a dominantly geodynamic mechanism in the eastern NCC.     

胶-辽-吉带辽东宽甸地区古元古代二长(正长)花岗质片麻岩的锆石U-Pb年代学、地球化学及成因

古元古代二长(正长)花岗质片麻岩在胶-辽-吉构造带广泛出露,是构成胶-辽-吉带的最主要物质组成。2件中细粒二长花岗质片麻岩样品及1件正长花岗质片麻岩样品的LA-ICP-MS锆石U-Pb年代学分析表明,它们分别形成于2.17Ga和2.33Ga,代表两期花岗质岩浆事件,并经历了约1.89Ga的变质作用。这些花岗质岩石具高硅(SiO_2=71.68%~76.38%),富铁(Fe_2O_3+FeO=1.61%~4.35%)及全碱(K_2O+Na_2O=7.57%~9.3%),K_2O/Na_2O比值大于1,贫钙(CaO=0.2%~1.6%)、镁(MgO=0.05%~0.24%,Mg#=3.82~13.0)、磷(P_2O_5=0.01%~0.06%)及钛(TiO_2=0.12%~0.4%)的特征;它们具有较高的稀土元素总量(ΣREE=104×10~(-6)~440×10~(-6)),具有轻微的轻重稀土分异,(La/Yb)_N比值在2~11之间,具明显的铕负异常(Eu/Eu*=0.30~1.18,平均值为0.56),具有低Sr(大部分100×10~(-6))、Rb(62.8×10~(-6)~187×10~(-6))、Cr及Ni含量,高的Zr(250×10~(-6))及Yb(2×10~(-6))含量,Zr+Nb+Ce+Y平均值为506×10~(-6),10000×Ga/Al值大于2.7;微量元素原始地幔标准化蛛网模式图显示,富集Rb、U、K、Zr、Hf等元素,亏损Nb、Ta、Sr及Ti等元素;它们属铁质、准铝质至弱过铝质、碱钙-钙碱性系列,全岩锆饱和温度大于800℃,属A2型花岗岩;结合胶-辽-吉带内古元古代花岗质片麻岩的全岩Nd及锆石Hf同位素研究结果,指示这些古元古代A型花岗岩可能形成于高温低压的伸展构造背景下,大陆物质(TTG岩石)的部分熔融。暗示胶-辽-吉带可能经历了古元古代早期多阶段的陆壳伸展拉张,并形成初始洋盆,然后再到洋-陆俯冲、陆(弧)-陆碰撞的演化过程。     

辽东清河地区晚三叠世侵入岩锆石U-Pb年龄、地球化学特征及其对华北克拉通东部构造演化的指示

辽东清河地区发育二长闪长岩和二长花岗岩2类侵入岩, 通过对其开展系统的LA-ICP-MS锆石U-Pb测年及地球化学研究, 探讨晚三叠世辽东清河地区的岩浆侵位机制及大地构造背景。二长闪长岩和二长花岗岩的LA-ICP-MS锆石U-Pb年龄加权平均值分别为212±2 Ma和221±2 Ma, 时代为晚三叠世。地球化学分析结果显示: 二长闪长岩SiO2含量(50.44%~55.18%, 平均52.20%)中等, MgO(3.18%~6.2%, 平均5.20%)、TFe2O3(7.83%~8.85%, 平均8.37%)和总碱(7.04%~8.00%, 平均7.50%)含量较高, 表明清河地区二长闪长岩属于准铝质钾玄岩系列岩石; 岩石富集大离子亲石元素(LILE), 相对亏损高场强元素(HFSE), 中等的Nd/Th(3.70~9.75, 平均5.83)和Rb/Sr值(0.07~0.12, 平均值为0.09), 较高的Nb/U值(9.11~13.2, 平均10.8), 显示了主要由壳源物质组成, 同时有少量幔源物质的加入。二长花岗岩具有富SiO2(76.10%~76.80%, 平均77.12%)、贫MgO和TFe2O3的特征, 其岩浆成分以地壳中的硅铝质成分为主, 属于过铝质的Ⅰ型花岗岩, 同时亏损高场强元素Nb、Ta、P、Ti, Nd/Th值(0.62~1.73, 平均1.23)接近壳源岩石值, 暗示其原始岩浆应是起源于陆壳物质的部分熔融。通过岩石学、年代学、岩石地球化学、构造环境分析, 并结合辽东半岛区域构造演化研究, 认为二长闪长岩为扬子克拉通深俯冲与华北克拉通后伸展作用的结果, 二长花岗岩花岗岩为同碰撞挤压环境。     

华北克拉通新太古代末期的克拉通化: 冀东昌黎碱性花岗质岩石的岩石学、锆石年代学和元素地球化学

冀东地区是华北克拉通早前寒武纪地质研究的经典地区, 赋存有丰富的地球早期地壳演化和太古宙板块构造信息。本文对出露于冀东昌黎地区的一套新太古代碱性花岗质岩石进行了系统的研究。其主要矿物组成为碱性长石、石英和霓辉石, 以及榍石、磷灰石等副矿物, 偶见紫苏辉石。LA-ICP-MS锆石U-Pb同位素测年显示其成岩年龄为2531~2518Ma。该套碱性花岗质岩石具有高SiO₂(70.2%~73.0%)、K₂O+Na₂O(10.1%~11.0%)、Sr/Y值(44.3~103.5), 低CaO(0.48%~0.94%)、MgO(0.14%~0.33%)、Cr (4.96×10^-6~10.9×10^-6)、Ni(2.46×10^-6~4.62×10^-6)的特征, 稀土元素配分模式与冀东-辽西地区闪长质及二长-正长花岗质岩石相似, 同时显示Eu的正异常(Eu/Eu^*=1.02~1.49)以及岩浆分异的稀土元素分布特征。根据以上元素地球化学特征以及微量元素的模拟计算, 本文认为这套岩石来自增厚镁铁质下地壳的部分熔融, 并经历了以磷灰石为主同时包括榍石、褐帘石等副矿物的分离结晶。结合前人对区域内同时代变质表壳岩岩石地球化学以及变质作用的研究, 认为增厚下地壳的部分熔融与岩石圈地幔镁铁质岩浆的底垫和侵入有关。陆块发生碰撞后, 岩石圈包括下地壳不断增厚, 岩石圈地幔下部沉入软流圈, 引起了软流圈的上涌以及残余岩石圈地幔的部分熔融。昌黎碱性花岗质岩石形成于新太古代末期碰撞后的拉张环境, 暗示了华北克拉通新太古代末期的克拉通化。

     

Archean granulite gneisses from eastern Hebei Province,China: rare earth geochemistry and tectonic implications

The granulite gneisses and their retrograded products of the Qianxi Group from eastern Hebei Province, China, have been investigated for their isotope and trace element geochemistry. A consistent age of about 2.5 AE has been obtained by the Rb-Sr and Sm-Nd whole-rock isochron methods, in agreement with the zircon U-Pb data (Pidgeon 1980; D.Y. Liu, unpubl.). Geochemical arguments from initial isotopic ratios (I_Sr and I_Nd) and elemental distribution patterns have led us to conclude that this age of about 2.5 AE represents the time of granulite facies metamorphism, which must have followed closely the primary emplacement of their protoliths. Previous claims for early Archean ages (>3.5 AE) of these granulites are not substantiated. The mineral isotope systematics register an important thermal event at about 1.7 AE, roughly corresponding to the time of the widespread Luliang Orogeny (Ma and Wu 1981) or Chungtiao Movement (Huang 1978).The granulites of the Qianxi Group have diverse compositions ranging from ultrabasic through basic-intermediate to acid. Discriminant function calculations suggest that most analyzed samples have igneous parentage. Only a few show characteristics of metasedimentary rocks. The igneous protoliths apparently belong to two series — tholeiitic and calc-alkaline, with the latter dominating in abundance. The majority of the acid granulites have compositions corresponding to tonalite-granodiorite.Except for ultrabasic and metasedimentary rocks, all REE patterns are significantly fractionated with LREE enrichment. The degree of fractionation, as measured by the (La/Yb)_N ratios, is most important in the acid granulites. These rocks often show positive Eu anomalies and HREE depletions that are typical of Archean TTG rocks (tonalitetrondhjemite-granodiorite).The existence of komatiites has been previously reported in this region. Although a few rocks have a major element chemistry similar to that for peridotitic komatiites, the lack of associated members in a komatiitic series and the scarcity of REE data have not confirmed the true komatiite occurrence in this region.Many Qianxi granulites are highly depleted in Rb relative to K and Sr. This preferential Rb depletion during granulite facies metamorphism has led to very high K/Rb and very low Rb/Sr ratios. The most comparable case is found in Lewisian granulites.Although the fractionated REE patterns of the basic granulites somewhat resemble those of continental flood basalts, the highly different abundances in other incompatible elements (Ti, Zr, and Ba) readily distinguish them from each other. Nevertheless, the LREE enriched patterns of the basic granulites may suggest an origin of their protoliths by partial melting of LREE-enriched mantle sources. On the other hand, the REE patterns of acid granulites suggest that their protoliths could be derived by partial melting of quartz eclogite, amphibolite or basic granulite.The close time relationship for a series of geologic events, namely, from initial melting of mantle peridotites, through fractional crystallisation of basaltic magmas, to granulite facies metamorphism, seems to occur in many granulite terrains. This relationship, together with the juxtaposition of lithologies of different origins and the exceptionally high pressure conditions (>10 Kb) can be best explained by crustal underplating combined with intracrustal thin-skinned thrusting and stacking of crustal slices. The andesitic or island arc model for the formation of the lower continental crust is not in good agreement with the present geochemical data.     

乌拉山地区早古元古代花岗质片麻岩的锆石U-Pb年代学、地球化学及成因

早古元古代花岗质片麻岩类在华北克拉通孔兹岩带乌拉山地区广泛出露,是记录该区陆壳增生及构造演化的主要物质载体。4件代表性花岗质片麻岩样品的LA-ICP-MS锆石U-Pb年代学分析表明,它们形成于～2.45Ga,并经历了～2.45Ga及约1.89～1.95Ga多期变质热事件;它们的岩石地球化学分析结果显示,稀土元素含量较高(∑REE=301×10-6～909×10-6),富集轻稀土元素、亏损重稀土元素,(La/Yb)N比值在13～56之间,无明显Eu异常(Eu/Eu*=0.76～1.81,平均为1.18),具有较高的Sr含量(在495×10-6～895×10-6之间),低的Yb含量(在0.5×10-6～2.61×10-6之间);微量元素原始地幔标准化蛛网模式图显示,强烈亏损Nb,Ta,Th,U及Ti等高场强元素,富集Ba,K,Rb及Sr等大离子亲石元素;它们为镁质、准铝质至弱过铝质、高钾钙——碱性系列,指示其可能形成于活动大陆边缘岛弧环境玄武质下地壳的部分熔融。暗示该区早古元古代时期的弧陆增生作用,并经历了从弧陆增生、陆——陆碰撞造山到造山后伸展的构造演化历史。     

Late Jurassic granitoids in the Xilamulun Mo belt,Northeastern China: geochronology,geochemistry, and tectonic implications

ABSTRACT

The Xilamulun Mo belt of Northeastern China, located in the southeastern segment of the Central Asia Orogenic Belt (CAOB), is composed of large deposits of porphyry Mo and quartz-vein-type Mo, which are related to Mesozoic granitoids. Previous studies led to the conclusion that all granitoids in the region formed during the Cretaceous and Triassic, but our new laser ablation inductively coupled plasma mass spectrometry U–Pb zircon dating of magmatic zircons from five samples of four mineralized plutons (Nailingou, Longtoushan, and Hashitu granites and Erbadi and Hashitu granite porphyries) reveals that these range in age from 143.8 ± 1.2 to 149.5 ± 1.0 Ma. These granites show post-collisional (A-type) geochemical characteristics (e.g. enrichment in total alkali, LILE, and LREE and depletion in Eu, Ba, P, and Nb). The Erbadi, Longtoushan, Hashitu, and Longtoushan granitoids exhibit moderately positive Hf isotopic compositions (ε_Hf(t) = ?0.3 to 10.2), indicating that granitic magmas may reflect mixtures of mantle melts and continental crust. These mineralized granites were all emplaced along a major fault over a time span of ~6 million years during the Late Jurassic. We conclude that igneous activity and mineralization resulted from the rollback of the subducted Palaeo-Pacific plate beneath Eurasia. Confirming that the Late Jurassic granitic intrusives are related to the Mo mineralization is useful for understanding the Mesozoic tectonic evolution of the Xilamulun Mo belt and also has significant implications for the regional exploration of ores.     

冀北康保晚古生代花岗质岩浆作用年龄数据及构造意义

冀北康保位于华北克拉通北缘中段,北靠古亚洲洋构造域（中亚造山带）。区内出露有小西沟、前孟家地、石柱梁、三老虎、新村和西五福堂等6个晚古生代花岗岩体,它们的锆石U-Pb年龄分别为260.6±1.6 Ma、264.1±1.7 Ma、269.5±2.7 Ma、276.3±1.9 Ma、280.4±2.0 Ma和284.7± 1.7 Ma等,表明这些花岗岩体形成于早-中二叠世。晚古生代（早-中二叠世）花岗岩体在冀北康保有规律地出露,应该与古亚洲洋的构造演化有关,可能反映了古亚洲洋的俯冲消减作用具有多期次的特点。     

华北克拉通新太古代早期构造热事件的响应:来自左权地区ca.2.7Ga TTG片麻岩的证据

新太古代早期是全球地质历史上一个重要的地壳生长时期,世界众多克拉通中广泛存在2. 7Ga左右的岩浆年龄记录。华北克拉通最主要的岩浆事件发生在新太古代晚期,这与世界其他克拉通广泛存在～2. 7Ga的构造热事件明显不同。但全岩Nd和锆石Hf同位素研究表明,华北克拉通～2. 5Ga的岩石主体来自于中太古代晚期-新太古代早期大陆物质的重熔或再造。因此,厘定～2. 7Ga地质事件在华北克拉通的空间分布对深入理解新太古代地壳形成与演化具有重要科学意义。华北克拉通已识别出的～2. 7Ga的花岗质岩石主要分布在胶东、鲁西、武川、赞皇和太华等少数杂岩区,中部带的恒山、阜平和中条杂岩中亦有零星出露。左权变质杂岩位于中部带中南段,赞皇杂岩西南,初步地球化学和锆石年代学研究表明,该地区有多种岩石类型记录了～2. 7Ga的年龄信息,包括副片麻岩、长英质浅色体、磁铁矿角闪片麻岩和TTG片麻岩。其中,TTG片麻岩的原岩为英云闪长岩,锆石发育明显的核边结构,核部具有清晰的岩浆环带,两个不同LA-ICP-MS实验室获得的不一致线上交点年龄分别为2727±14Ma和2731±12Ma,代表了TTG岩浆岩的结晶年龄。同时,左权变质岩石中较好地保存了新太古代晚期的岩浆和变质年龄记录,推测其所代表的构造热事件与华北克拉通～2. 5Ga所经历的大规模幔源岩浆的底侵作用有关。     

华北克拉通中东部新太古代晚期变质火山岩及动力学体制

热状态和壳幔岩浆作用是理解早期地壳形成演化动力学机制的关键。华北克拉通是世界范围内为数不多的保存有大量新太古代晚期（约26~25亿年）变质火山岩记录的克拉通之一,对揭示全球新太古代晚期壳-幔动力学演化过程具有重要的指示意义。在我们研究组近期关于华北克拉通中东部中新太古代热状态和地壳厚度研究基础上,本文收集并整理了726个华北克拉通中东部（包括中部带）新太古代晚期变质火山岩样品的有效地球化学资料。按照现代通用岩石地球化学标准来分类,这些样品主要包括超铁镁质岩石（其中含苦橄岩、苦橄质玄武岩和科马提岩,~7%）、稀土未分异型玄武岩（~14%）、稀土分异型玄武岩（~27%）、玻安岩（~4%）、高镁安山岩（~12%）、低镁安山岩（~26%）和英安岩-流纹岩（~10%）。然而不同区块之间火山岩岩石组合及其量比存在较大差异,其中吉林南部和赞皇等地区以大量稀土分异型玄武岩、高镁和低镁安山岩为主,含有少量的长英质火山岩;胶东、登封和阜新等地区以稀土未分异和稀土分异型玄武岩占有绝对优势,存在少量安山岩和长英质火山岩;冀北、冀东北部、冀东南部（迁安-滦县）、五台-云中山、辽北、辽南和鲁西等地区岩石组合比较复杂,最突出的特点是出现不同比例的玻安岩,组合有稀土未分异和大量稀土分异型玄武岩、高镁和低镁安山岩,出现少量超铁镁质岩石和长英质火山岩。岩石成因研究揭示稀土未分异型和分异型玄武岩、高镁安山岩和玻安岩主要形成于俯冲板片流体、熔体和沉积物熔体交代地幔的部分熔融,而低镁安山岩、英安岩和其它长英质火山岩则大都经历了上述俯冲相关初始岩浆的结晶分异或地壳物质熔融和地壳混染等过程。新太古代晚期胶东地区表现为相对较薄的地壳厚度和较高的地热梯度（18℃/km）,而冀东地区表现为厚的地壳厚度和低的地热梯度（最低8.7℃/km）,满足现代俯冲地热梯度需求,其它区域的地温梯度介于热俯冲和现代冷俯冲之间。综合以上资料,我们认为新太古代晚期板块构造体制已经是最主要的壳-幔动力学体制,地幔柱构造体制和板块构造-地幔柱联合作用体制可能仍然在局部地区存在,但其作用范围和强度已经明显减小。因此,随着地幔温度的下降,中太古代到新太古代晚期地幔柱和板片俯冲的转化可能是相互关联、此消彼长的动力学过程,而不是一个突变过程。

     

Delineation of the ca. 2.7 Ga TTG gneisses in the Zanhuang Complex,North China Craton and its geological implications

Through detailed studies we have delineated a suite of banded TTG gneisses from the Zanhuang Complex. The protolith of the gneisses, predominantly tonalite, has undergone intensive metamorphism, deformation and anatexis and in a banded structure is intimately associated with melanocratic dioritic gneiss and leucocratic trondhjemitic veins. SHRIMP Zircon U–Pb data show that the tonalite was formed ca. 2692 ± 12 Ma ago. The tonalitic gneiss has the features of high SiO₂ (67.76–73.31%), high Al₂O₃ (14.38–15.83%), rich in Na₂O (4.48–5.07%) and poor in K₂O (0.77–1.93%). The gneiss is strongly fractioned in REE ((La/Yb)_N = 12.02–24.65) and shows a weak positive Eu anomaly (Eu/Eu^* = 1.05–1.64). It has high contents of Ba (199–588 ppm) and Sr (200–408 ppm), low contents of Yb (0.32–1.00 ppm) and Y (3.41–10.3 ppm) with high Sr/Y ratios (21.77–96.77) and depletion in HFSE Nb, Ta and Ti. These characteristics are similar to those of the high-Si adakitic rocks. The melanocratic dioritic gneiss has low SiO₂ (59.81%), high MgO (6.34%), high Al₂O₃ (14.02%) contents, rich in Na₂O (3.7%) and poor in K₂O (1.79%), with high Mg index (Mg^# = 67). REE and trace elements are on the whole similar to that of the tonalitic gneiss, but compatible element abundances V (116 ppm), Cr (249 ppm), Co (37 ppm) and Ni (179 ppm) are higher. The leucocratic felsic bands (approximating trondhjemite in composition) have major oxides similar to that of the TTG gneisses but the REE and compatible elements are extremely low, which are indicative of the products of anatexis. The tonalitic gneiss has positive ε_Nd(t) (2.37–3.29) and low initial Sr (0.69719–0.70068) values with depleted mantle Nd model age of ca. 2.8 Ga, suggesting its generation from partial melting of mantle-derived juvenile crust. The dioritic gneiss was also derived from subduction environment, but has undergone significant metasomatism of mantle wedge. The delineation of the ca. 2.7 Ga TTG gneisses in the Zanhuang Complex further proves that the North China Craton experienced large-scale continental crustal accretion in early Neoarchean, and gives new constraints on the subdivision of the early blocks and greenstone belts of the craton.     

豫西宜阳地区TTG质片麻岩锆石U-Pb定年和Hf同位素地质学

本文报道对华北地块南缘、豫西宜阳穆册TTG质片麻岩的地球化学、锆石U-Pb定年及Hf同位素研究.宜阳穆册TTC质片麻岩SiO2含量为59～73%,Al2O3＞15%、CaO、MgO、Al2O3、TiO2、Na2O/K2O与SiO2的含量呈负相关,表明在岩浆演化中有镁铁矿物和斜长石的分离,岩浆成分随着分异而富钾.P2O5与SiO2含量呈正相关,反映出磷灰石的分离.轻重稀土分异明显（（La/Yb）N=9～23）;重稀土相对于轻稀土轻度分异;无明显的Eu异常（Eu＊=0.95～1.07）.岩石富Rb、Sr、Ba、K等大离子亲石元素,亏损Nb、Ta等高场强元素.低Y（13.25～25.27 μg/g）和Yb（1.27～1.98 μg/g）;高Sr（507.14～606.85 μg/g）及Sr/Y（34.15～39.97）,上述地球化学特征一致表明,研究区片麻岩为一套高铝的TTG质岩石.这套片麻岩可能是在角闪岩相条件下部分熔融的产物.利用LA-ICP-MS锆石U-Pb法测得TTG质片麻岩的年龄为2.3 Ga.片麻岩中的锆石大部分具负εHf（t）值（最高达-4.95）,揭示其源区可能主要为古老陆壳物质;部分锆石的εHf（t）为正值,说明在其形成过程中有一定比例的亏损地幔物质的加入.宜阳TTG质片麻岩的Hf同位素数据表明,其两阶段模式年龄主要2.57～3.01 Ga之间,平均值为2.82 Ga,所以说穆册灰色片麻的源区可能存在年龄为2.8 Ga左右（或更老）的地壳物质,说明代表该区基底的太华杂岩形成时代可能为2.8Ga（或更老）.虽然华北地块陆壳最主要的增生时代被认为发生在2500 Ma,但宜阳TTG质片麻岩的研究结果和其他研究者的研究成果都说明华北地块大陆地壳在古元古代早期仍然存在相当规模的陆壳增生.     

Chronology and geochemistry of Mesozoic granitoids in the Bengbu area,central China: Constraints on the tectonic evolution of the eastern North China Craton

We performed zircon U–Pb dating and analyses of major and trace elements, and Sr–Nd–Pb isotopes for granitoids in the Bengbu area, central China, with the aim of constraining the magma sources and tectonic evolution of the eastern North China Craton (NCC). The analyzed zircons show typical fine-scale oscillatory zoning, indicating a magmatic origin. Zircon U–Pb dating reveals granitoids of two ages: Late Jurassic and Early Cretaceous (²⁰⁶Pb/²³⁸U ages of 160 Ma and 130–110 Ma, respectively). The Late Jurassic rocks (Jingshan intrusion) consist of biotite-syenogranite, whereas the Early Cretaceous rocks (Huaiguang, Xilushan, Nushan, and Caoshan intrusions) are granodiorite, syenogranite, and monzogranite. The Late Jurassic biotite-syenogranites and Early Cretaceous granitoids have the following common geochemical characteristics: SiO₂ = 70.35–74.56 wt.%, K₂O/Na₂O = 0.66–1.27 (mainly < 1.0), and A/CNK = 0.96–1.06, similar to I-type granite. The examined rocks are characterized by enrichment in light rare earth elements, large ion lithophile elements, and U; depletion in heavy rare earth elements, Nb, and Ta; and high initial ⁸⁷Sr/⁸⁶Sr ratios (0.7081–0.7110) and low ε_Nd (t) values (? 14.40 to ? 22.77), indicating a crustal origin.The occurrence of Neoproterozoic magmatic zircons (850 Ma) and inherited early Mesozoic (208–228 Ma) metamorphic zircons within the Late Jurassic biotite-syenogranites, together with the occurrence of Neoproterozoic magmatic zircons (657 and 759 Ma) and inherited early Mesozoic (206–231 Ma) metamorphic zircons within the Early Cretaceous Nushan and Xilushan granitoids, suggests that the primary magmas were derived from partial melting of the Yangtze Craton (YC) basement. In contrast, the occurrence of Paleoproterozoic and Paleoarchean inherited zircons within the Huaiguang granitoids indicates that their primary magmas mainly originated from partial melting of the NCC basement. The occurrence of YC basement within the lower continental crust of the eastern NCC indicates that the YC was subducted to the northwest beneath the NCC, along the Tan-Lu fault zone, during the early Mesozoic.     

华北克拉通东部古太平洋板块俯冲与回撤作用:来自辽西兴城地区晚中生代花岗质岩石的记录与启示

目前对于华北克拉通东部晚中生代花岗质岩石的成因仍存在地幔柱、加厚/拆沉下地壳部分熔融、俯冲板片脱水导致地壳熔融等不同认识。辽西兴城地区晚中生代花岗质岩石主要由二长花岗岩、石英闪长岩、花岗斑岩和石英正长岩组成,岩浆成因锆石U-Pb同位素定年结果显示岩浆活动主要发生于晚侏罗世(156Ma)、早白垩世早期(139Ma)、早白垩世中期(130～125Ma)。岩石地球化学测试分析结果显示岩石属于高钾钙碱性系列且具有富集K、Pb等大离子亲石元素而相对亏损Nb、Ta、Ti等高场强元素等活动陆缘岩浆岩特点,表明辽西地区晚中生代岩浆活动的发生与俯冲作用有关。晚侏罗世-早白垩世早期(156～139Ma)花岗质岩石地球化学特征与I型花岗岩类似,同时具有富集的Hf同位素组成(εHf(t)=-22.70～-18.66)和古老的Hf同位素二阶段模式年龄(tDM2=2387～2767Ma),其初始岩浆可能来源于古老中上地壳的部分熔融;形成于130Ma的花岗质岩石同样具有与I型花岗岩相类似的岩石地球化学特征,但其Hf同位素组成突变为亏损(εHf(t)=+3.64～+6.22、tDM1=537～969Ma),其初始岩浆起源于新元古代新生地壳物质的部分熔融并混入少量亏损地幔物质组分;形成于125Ma的花岗质岩石为碱性A型花岗岩,岩石地球化学特征与其他岩石有所不同,具有负的εHf(t)值(-17.30～-11.56)和相对古老的Hf同位素二阶段年龄(tDM2=1917～2278Ma),初始岩浆可能起源于较为古老的中下地壳部分熔融并有幔源物质的参与。华北克拉通东部形成于160～139Ma的花岗质岩石具有I型、高钾钙碱性、与埃达克质岩石类似的高Sr/Y、低Y含量特征和富集的Hf同位素组成,而形成于130～120Ma的花岗质岩石具有A型、碱性、与典型岛弧岩浆岩类似的岩石地球化学特征和相对亏损的Hf同位素组成,同时晚中生代岩浆活动具有向洋年轻化的特点,表明华北克拉通东部156～139Ma期间可能受到古太平洋板块的持续俯冲作用,而139～130Ma古太平洋俯冲板片开始回撤,130～125Ma进入古太平洋俯冲板片持续回撤导致的强烈区域伸展作用阶段。古太平洋俯冲板片脱水交代岩石圈地幔并形成幔源岩浆,幔源岩浆不断底侵作用于古老/新生地壳使其发生部分熔融为花岗质岩石提供岩浆来源。     

Petrogenesis and tectonic implications of early Paleozoic granitoids in East Kunlun belt: Evidences from geochronology,geochemistry and isotopes

The East Kunlun Orogenic Belt(EKOB) provides an important link to reconstruct the evolution of the Proto-Tethys and Paleo-Tethys realm. The EKOB is marked by widespread Early Paleozoic magmatism.Here we report the petrology, bulk geochemistry, zircon Ue Pb dating and, Lue Hf and SreN d isotopic data of the Early Paleozoic granitic rocks in Zhiyu area of the southern EKOB. Based on the zircon U-Pb dating, these granitoids, consisting of diorite, granodiorite and monzogranite, were formed during 450 -430 Ma the Late Ordovician to Middle Silurian. The diorite and granodiorite are high Sr/Y ratio as adakitic affinities, and the monzogranite belongs to highly fractionated I-type. Their(~(87)Sr/~(86)Sr)ivalues range from 0.7059 to 0.7085, εNd(t) values from -1.6 to -6.0 and the zircon εHf(t) values show large variations from +9.1 to -8.6 with Hf model ages(T_(DM2)) about 848 Ma and 1970 Ma. The large variations of whole-rock Nd and zircon Hf isotopes demonstrate strong isotopic heterogeneity of the source regions which probably resulted from multi-phase underplating of mantle-derived magmas. Geochemical and isotopic studies proved that the diorite and granodiorite had been derived from partial melting of heterogeneous crustal source with variable contributions from ancient continental crust and juvenile components, and the monzogranites were representing fractional crystallization and crustal contamination for arc magma. The Early Paleozoic adakitic rocks and high-K calc-alkaline granitoids in the southern EKOB were likely emplaced in a continental marginal arc setting possibly linked to the southwards subduction of the Paleo Kunlun Ocean and the magma generation is linked to partial melting of thickened continental crust induced by underplating of mantle-derived magmas.