构造煤的动力变质作用及其演化规津

采用X射线衍射分析、电子顺磁共振等方法研究了构造煤的动力变质作用特征和演化规律。构造煤与煤层的变形变质历史有关,动力变质作用形成的构造煤,其结构特征与其它变质类型煤不同,演化途径也不同,但它们的演化规律一致。      

构造煤的动力变质作用及其演化规律

采用Ｘ射线衍射分析，电子顺磁共振等方法研究了构造煤的动力变质作用特征和演化规律。构造煤与煤层的变形变质历史有关，动力变质作用形成的构造煤，其结构特征与其它变质类型煤不同，演化途径也不同，但它们的演化规律一致。     

构造动力变质作用初探

构造动力变质作用初探王治顺，朱大岗（中国地质科学院地质力学研究所，北京１０００８１）关键词构造动力变质作用、阶段划分、主要类型、基本特征笔者提出的构造动力变质作用的基本概念是：在构造动力及其引发的动力热流共同作用下，岩石、矿物所发生的变形、变质作用，...     

构造动力变质作用初论

本文提出了构造动力变质作用的基本概念。即在构造动力及其引发的动力热流共同作用下,岩石、矿物在构造运动中发生的形变、相变而呈现的变质作用。按构造动力变质作用的物理化学条件,动力变质岩的结构构造、动态重结晶和混合岩化作用、应力矿物共生组合关系及其空间分布等特征,将构造动力变质作用由弱到强划分为4个发展阶段和相应的4种基本变质类型——脆性、脆-塑性、塑性和动力热流变形变质,并论述了它们各自的基本特征。      

构造附加动力对煤变质过程的影响

本文从固体力学、构造物理化学的角度分析了煤岩所受应力的来源、性质以及应力在煤变质过程中的影响方式。作者在前人研究基础上,阐述了构造动力影响过程中煤岩能量的转换形式,分析了应力在烟煤分子团聚过程中的影响。研究认为,煤岩所受的各种应力(压应力、拉应力、剪应力)为地层压力与构造动力所造成的附加内力。这种附加内力可以分解为构造附加静水压力与偏应力两部分。构造附加静水压力主要影响煤岩的物理性质,如孔隙度、颗粒性质与瓦斯吸附特征,并对煤的化学煤化过程有缓慢促进作用。偏应力主要使煤岩发生变形和位移。煤化过程中,由构造运动所产生的动能转化为各种形式的热能、表面能、弹性变形能以及声、光、电、磁等形态能量。     

煤变质作用研究

本文从4个方面扼要地讨论了煤变质作用的近期进展。在煤级参数方面对镜质体反射率及其缺点和弥补的方法做了介绍,简述了近来提出的新的煤级参数。在煤化作用机理与特点方面概述了涉及煤化作用的煤结构研究新进展及其在煤化过程的演变中与镜质体反射率、挥发份的内在联系;煤化作用跃变与沥青化作用;“惰性组的煤化径迹”——煤化作用的一个新的方面。新的煤变质作用类型探讨。煤变质因素和煤化作用平衡,煤变质作用研究应用于其它地质学科。最后提出了应进一步研究的煤变质问题。     

煤岩构造变形与动力变质作用

煤岩是一种对温度、压力等地质环境因素十分敏感的有机岩,地质演化过程中的各种构造-热事件必然导致煤岩发生一系列物理与化学结构的变化,并形成不同类型的构造煤。在构造应力作用下,煤岩不仅发生脆性和韧性变形,而且还产生不同程度的动力变质作用。因而,关于煤岩构造变形与动力变质作用的研究不仅具有重要的科学意义,而且在煤层气资源评价以及煤与瓦斯突出危险性预测方面也具有重要的实际意义。文中在已有研究成果基础上,通过对构造煤系列Ro,max、XRD和NMR(CP/MAS+TOSS)等测试和实验方法的对比研究,深入分析了煤岩不同构造变形和动力变质特征,进一步探讨了构造应力下煤岩动力变质作用的机理。研究成果表明,在构造应力作用下,煤岩脆性变形主要是通过破裂面上快速机械摩擦转化为热能而引起煤岩化学结构与其成分的改变;而韧性变形煤主要是通过局部区域应变能的积累而引起煤岩化学结构的破坏,从而发生不同机制的动力变质作用。     

构造物理化学条件对煤变质作用的控制

煤是对温度和压力等地质因素十分敏感的有机岩,各种构造-热事件控制下的物理化学条件,是促进煤岩演化的根本动力。本文对煤变质作用过程的研究现状进行了综述,着重讨论了煤岩在高煤阶-石墨演化阶段的控制因素、演化过程和演化机制。煤变质作用包括煤化作用阶段和石墨化作用阶段,共同构成一个连续的有机质演化过程,总体趋势是分子结构有序化、化学成分单一化,最终演变为以碳元素为主、三维有序结构的石墨。温度和压力(应力)是控制煤变质作用两大因素,在不同的演化阶段,这两大因素所起的作用和演变机理都有所差异。在低、中煤阶演化阶段,温度是煤化学结构演化的主要控制因素,为化学键断裂提供活化能,应力缩聚和应力降解则对煤化学结构演化具有催化作用。高煤阶-石墨化阶段的主要机制是导致基本结构单元BSUs之间相互联结使短程有序化范围增大的拼叠作用,构造应力在其中起到关键作用,BSUs定向和面网间距不断减小,促进大分子物理结构演化。加强煤变质作用的高级阶段-石墨演化过程的研究,将丰富和深化对煤-石墨物理化学结构完整演化序列的认识。煤系石墨成矿机制的高温高压模拟实验,则为煤变质作用构造物理化学条件研究提供了可行的技术手段。     

下花园煤矿层间滑动构造研究

在下花园煤矿十分发育的小构造是层间滑动构造,它是大型逆掩断层形成过程中派生的,研究和弄清其间的关系。对井田构造预测和指导煤层开采具有实际意义。     

Overview of UHP Metamorphism and Tectonics in Well-Studied Collisional Orogens

In Eurasia, the Qinling-Dabie-Sulu belt of eastern China, the Kokchetav Complex of northern Kazakhstan, the Maksyutov Complex of the southern Urals, the Dora-Maira massif of the Western Alps, and the Western Gneiss Region of Norway mark profound intracontinental collisional sutures. Adjacent regions exhibit scant evidence of contemporaneous calc-alkaline volcanism/plutonism. Each ultrahigh-pressure (UHP) metamorphic complex contains mineralogic and textural relics of coesite ± diamond as well as other very high P, moderate-T phases such as K-rich clinopyroxene, Mg-rich garnet, ellenbergerite, lawsonite, Al-rutile, glaucophane, high-Si phengite, and the phase assemblages coesite + dolomite, magnesite + diopside, and talc + kyanite, diopside, jadeite, or phengite. In each of these well-studied Eurasian complexes, maximum pressures approached or exceeded 2.8 GPa. Deep-seated recrystallization of old, cool continental crust took place during Phanerozoic time. Subduction zones constitute the only known plate-tectonic environment where such high-P, low-T conditions exist. Disaggregated, exhumed ultrahigh-pressure terranes consist of relatively thin sialic sheets 5 ± 3 km thick. After cessation of UHP recrystallization, tectonic slices ascended largely because of buoyancy to shallow depths along stress guides provided by the subduction zones themselves. Collisional sheets that retain UHP relics (micro-inclusions enclosed in strong, impermeable, unreactive mineralogic host grains) lost heat by conduction across both upper, normal-fault and lower, reverse-fault contacts. These sheets rose to mid-crustal levels rapidly at exhumation rates approaching 10 mm/yr. Backreaction attending decompression in all cases was nearly complete; where UHP relics survive, retrogression evidently was limited by the coarse grain size and relative impermeability of the rocks, as well as by declining temperature and lack of aqueous fluids.     

Metamorphism and Tectonics in Southern Madagascar: An Overview

The scope of this paper is to briefly summarize the general tectonic pattern and the metamorphic evolution of the continental crust from southern Madagascar. After a presentation of the main geophysical features of the Malagasy crust, the brittle and the ductile strain patterns are established at a crustal scale. The Pan-African metamorphic zonation is discussed and interpreted through a tectonic model related to a transpressive regime.     

煤岩演化程度对煤储层孔裂隙结构的控制作用

为研究煤岩演化程度对孔裂隙结构发育的影响,运用压汞、低温氮吸附/解吸、镜质组反射率测试和SEM、荧光显微观察等手段,分析煤岩变质程度对孔隙度、BET比表面积、BJH总孔体积、裂隙结构和密度等的影响。结果表明:随变质程度升高,煤岩孔隙度呈先增大后减小再略微增大的波动变化特征;微孔占比随煤岩镜质组反射率升高呈"U"形变化特征,小孔占比变化与之相反;煤岩BET比表面积和BJH总孔体积均随煤级升高呈"U"形变化特征;中高变质程度煤岩中B、C、D型裂隙密度随煤级的升高都呈"U"形变化,并在R_o,m=1.1%左右出现最小值,裂隙密度下降阶段中D型裂隙密度降低最快。结合镜质组反射率分析发现,煤岩孔(裂)隙的发育与煤岩演化的4次跃变有着密切关系。     

Extreme Dynamic Metamorphism and Earthquakes

<正>For 50+years after the discovery of deep earthquakes in the 1920s,their causal mechanism was one of the major unsolved problems of geophysics.It was clear that the physics that explains shallow earthquakes could not apply to deep ones because the pressure is too high at≥~50km to     

浅谈火山构造的分级分类体系

通过对前人有关火山构造分级分类方案的清理,归纳和总结,提出区域性火山构造分级分类体系及组合式火山构造分级分类体系,二者构成了一套较完整的火山构造分级分类系统。区域性火山构造体系划分的理论基础是火山作用的构造属性,火山活动与区域性全球性构造活化有关,共分四级四类;组合式火山构造体系是应用火山构造组合理论,低级火山构造通过并列式或叠置式组合方式,逐级组合归并为高级火山构造的分级分类方法,共分四级十五类     

Geobarmal Gradient in Orogenic Belt and Metamorphism Caused by Ultrahigh Pressure

The components and structures of lithosphere,inhomogeneous,are changing incessantly in different periods.Therefore,the state of load,called the pressure,in lithosphere is also incessantly changing.When the lithosphere volume remains the same,namely on the premise of isovolumes,the geobarmal gradient is:(dp/dh)v=(p/(e)h)v (p/(e)T)v(dT/dh)v.If β=(dp/dh)v/(p/(e)h)v is supposed,then β=1 rg-1Cv (dT/dh)v.When the geothermal degree in (dT/dh)v is zero,then the pressure grade of lithosphere is equal to the lithostatic grade,which is the minimum value in the pressure grade of lithosphere.Suppose that the lithosphere is made only up of quartz,Cv≌Cp=0.782 5.718×10-4 T-1.883×104T-2 (J·g-1·K-1) is obtained,which is the minimum one in lithospheric rock,and then the geothermal grade value of 20 ℃/km is calculated according to the geophysical transection data of Qinling Mountain orogeny.The results show that the high-pressure and ultrahigh-pressure eclogites in Jiangsu Province and Huangzhen,Dabie may,on the condition of incompletely isovolumes,occur in the depths of 17-40 km with the increase in geothermal temperature,whose values of β do not correspond to the theoretic value of 3.08.     

宁夏韦州煤田煤变质作用探讨

韦州煤田位于宁夏回族自治区的中部同心县境内。为一石炭二叠纪含煤向斜,轴向近南北,向北倾伏,两翼倾角20—30°,西翼稍陡,南端翘起。向斜中部煤层埋藏过深,现阶段勘探局限于垂深不超过1000米的两翼及南端。经普查,发现本煤田的煤种自东翼北端的气煤至西翼的无烟煤呈有规律地分布。在这样一个不算大的含煤向斜内同时赋存六种牌号的煤,这在国内较少见,探讨其煤变质作用,对进一步查明本区煤质将有裨益。     

Petrological Data Allow Estimating the Amplitudes of Crustal Uplifts Caused by Retrograde Metamorphism

Analysis of the morphology of the recent uplifts on Precambrian cratons and geological–geophysical data on the structure of the crust and mantle indicate that these structures were formed due to expansion of the crustal rocks as a result of retrograde metamorphism. This occurred due to the contribution of large volumes of deep fluids to the complexes of the Early Proterozoic rocks, which underwent high-grade metamorphism in the lower crust. Later, these complexes were moved to the shallower depths after denudation of thick overlap sequences from the craton’s surfaces. The calculation of the volumetric expansion effects using P–T diagrams for the main types of metamorphic rocks shows that this mechanism could have prompted the uplifts of the Precambrian crust in recent time with amplitudes from 100–200 to 1000–1500 m.     

新郑矿区煤变质规律探讨

新郑矿区C-P系煤层具有煤类较多，变质程度偏高和北高南低、带状分布的特征。本文着重探讨其变质作用类型，计算主要影响因素的变质温度，模拟其变质演化过程。