Mining lakes as groundwater‐dominated hydrological systems: assessment of the water balance of Mining Lake Plessa 117 (Lusatia,Germany) using stable isotopes

In the present study, the stable isotopes δ¹⁸O and δ²H were used for assessment of the water balance in a heterogeneously structured catchment area in the Lusatian Lignite Mining District, in particular, for estimation of the annual groundwater inflow and outflow (I_GW and O_GW) of Mining Lake Plessa 117. The application of stable isotopes was possible since the water exchange in the catchment area had reached steady‐state conditions after the abandonment of mining activities in 1968 and the filling of the voids and aquifers by re‐rising groundwater in the years thereafter. Diverging slopes of the Evaporation Line and the Global Meteoric Water Line manifested as evaporation from the lake catchment area. The calculated isotope water balance was compared with the commonly used surface water balance, which is unable to differentiate between I_GW and O_GW, and with a local groundwater model. The groundwater model calculated an I_GW of about 811 000 m³ yr^?1 and an O_GW close to zero, whereas the isotope water balance showed fluxes of about 914 000 and 140 000 m³ yr^?1, respectively. Considering the contribution of the groundwater inflow to the total annual input into the lake (ΔI_T) and the mean residence time (τ), where the groundwater model and the isotope water balance calculated 42 and 47% for ΔI_T and 4·3 and 3·9 years for τ, respectively, it was shown that both water balance calculation methods led to comparable results despite the differences in I_GW and O_GW. Copyright © 2008 John Wiley & Sons, Ltd.     

Plant source water apportionment using stable isotopes: A comparison of simple linear,two‐compartment mixing model approaches

Plant source water identification using stable isotopes is now a common practice in ecohydrological process investigations. Notwithstanding, little critical evaluation of the approaches for source apportionment have been conducted. Here, we present a critical evaluation of the main methods used for source apportionment between vadose and saturated zone water: simple mass balance and Bayesian mixing models. We leverage new isotope stem water samples from a diverse set of tree species in a strikingly uniform terrain and soil conditions at the Christchurch Botanic Garden, New Zealand. Our results show that using δ²H alone in a simple, two‐source mass balance approach leads to erroneous results, particularly an apparent overestimation of groundwater contribution to xylem. Alternatively, using both δ²H and δ¹⁸O in a Bayesian inference framework improves the source water estimates and is more useful than the simple mass balance approach, particularly when soil and groundwater contributions are relatively disproportionate. We suggest that plant source water quantification methods should take into consideration the possible effects of ²H/¹H fractionation. The Bayesian inference approach used here may be less sensitive to ²H/¹H fractionation effects than simple mass balance methods.