Bedrock infiltration and mountain block recharge accounting using chloride mass balance

Mountain front catchment net groundwater recharge (NR) represents the upper end of mountain block recharge (MBR) groundwater flow paths. Using environmental chloride in precipitation, streamflow and groundwater, we apply chloride mass balance (CMB) to estimate NR at multiple catchment scales within the 27 km² Dry Creek Experimental Watershed (DCEW) on the Boise Front, southwestern Idaho. The estimate for average annual precipitation partitioning to NR is approximately 14% for DCEW. In contrast, as much as 44% of annual precipitation routes to NR in ephemeral headwater catchments. NR in headwater catchments is likely routed to downgradient springs, baseflow, and MBR, while downgradient streamflow losses contribute further to MBR. A key assumption in the CMB approach is that the change in stored chloride during the study period is zero. We found that this assumption is violated in some individual years, but that a 5‐year integration period is sufficient. Copyright © 2011 John Wiley & Sons, Ltd.     

Estimating groundwater recharge for an arid karst system using a combined approach of time‐lapse camera monitoring and water balance modelling

Groundwater is the principal water resource in semi‐arid and arid environments. Therefore, quantitative estimates of its replenishment rate are important for managing groundwater systems. In dry regions, karst outcrops often show enhanced recharge rates compared with other surface and sub‐surface conditions. Areas with exposed karst features like sinkholes or open shafts allow point recharge, even from single rainfall events. Using the example of the As Sulb plateau in Saudi Arabia, this study introduces a cost‐effective and robust method for recharge monitoring and modelling in karst outcrops. The measurement of discharge of a representative small catchment (4.0 · 10⁴ m²) into a sinkhole, and hence the direct recharge into the aquifer, was carried out with a time‐lapse camera. During the monitoring period of two rainy seasons (autumn 2012 to spring 2014), four recharge events were recorded. Afterwards, recharge data as well as proxy data about the drying of the sediment cover are used to set up a conceptual water balance model. The model was run for 17 years (1971 to 1986 and 2012 to 2014). Simulation results show highly variable seasonal recharge–precipitation ratios between 0 and 0.27. In addition to the amount of seasonal precipitation, this ratio is influenced by the interannual distribution of rainfall events. Overall, an average annual groundwater recharge for the doline (sinkhole) catchment on As Sulb plateau of 5.1 mm has estimated for the simulation period. Copyright © 2015 John Wiley & Sons, Ltd.     

The impact of climate change on groundwater recharge and runoff in a humid,equatorial catchment: sensitivity of projections to rainfall intensity

Abstract

Projected warming in equatorial Africa, accompanied by greater evaporation and more frequent heavy precipitation events, may have substantial but uncertain impacts on terrestrial hydrology. Quantitative analyses of climate change impacts on catchment hydrology require high-resolution (<50 km) climate data provided by regional climate models (RCMs). We apply validated precipitation and temperature data from the RCM PRECIS (Providing Regional Climates for Impact Studies) to a semi-distributed soil moisture balance model (SMBM) in order to quantify the impacts of climate change on groundwater recharge and runoff in a medium-sized catchment (2098 km²) in the humid tropics of southwestern Uganda. The SMBM explicitly accounts for changes in soil moisture, and partitions effective precipitation into groundwater recharge and runoff. Under the A2 emissions scenario (2070–2100), climate projections from PRECIS feature not only rises in catchment precipitation and modelled potential evapotranspiration by 14% and 53%, respectively, but also increases in rainfall intensity. We show that the common application of the historical rainfall distribution using delta factors to the SMBM grossly underestimates groundwater recharge (i.e. 55% decrease relative to the baseline period of 1961–1990). By transforming the rainfall distribution to account for changes in rainfall intensity, we project increases in recharge and runoff of 53% and 137%, respectively, relative to the baseline period.     

Isotopic variation in groundwater across the conterminous United States – Insight into hydrologic processes

Groundwater supplies a significant proportion of water use in the United States and is critical to the maintenance of healthy ecosystems and environmental processes, thus characterizing aquifer hydrology is important to managing and preserving these resources. While groundwater isotopes provide insight into hydrologic and ecologic processes, their application is limited to where measurements exist. To help overcome this limitation, we used the random forest algorithm to develop a predictive model for shallow groundwater isotopes in the conterminous United States. Our model uses environmental variables (e.g. temperature, elevation, precipitation isotopes) as predictors. We used our model to develop the first shallow groundwater isoscape of δ²H and δ¹⁸O for the conterminous United States. We describe the patterns in groundwater isotopes using both observations and our modelled isoscape. We find that throughout much of the Eastern United States, groundwater isotopes are close to annual amount weighted precipitation, while groundwater isotopes are significantly depleted relative precipitation across much of the High Plains and Western United States. Furthermore, we compare the observations compiled for this study to isotopes of precipitation, which allows us to determine the relative recharge efficiency (i.e. ratio of groundwater recharge to precipitation) between seasons and the proportion of annual recharge that occurs in a given season. Our findings suggest that winter recharge is generally more efficient than summer recharge; however, the dominant recharge season is more varied as it is the product of both seasonal recharge efficiency and the seasonal timing of precipitation. Parts of the central United States have summer dominant recharge, which is likely the result of heavy summer precipitation/nocturnal summer precipitation. Interestingly, parts of coastal California appear to have summer dominant recharge, which we suggest could be due to recharge from fog-drip. Our results summarize spatial patterns in groundwater isotopes across the conterminous United States, provide insight into the hydrologic processes affecting shallow groundwater, and are valuable information for future ecologic and hydrologic studies.     

Geochemistry and Provenance of Springs in a Baja California Sur Mountain Catchment

Fractured rock aquifers cover much of Earth's surface and are important mountain sites for groundwater recharge but are poorly understood. To investigate groundwater systematics of a fractured-dominated aquifer in Baja California Sur, Mexico, we examined the spatial patterns of aquifer recharge and connectivity using the geochemistry of springs. We evaluate a range of geochemical data within the context of two endmember hypotheses describing spatial recharge patterns and fracture connectivity. Hypothesis 1 is that the aquifer system is segmented, and springs are fed by local recharge. Hypothesis 2 is that the aquifer system is well connected, with dominant recharge occurring in the higher elevations. The study site is a small <15 km² catchment. Thirty-four distinct springs and two wells were identified in the study area, and 24 of these sites were sampled for geochemical analyses along an elevation gradient and canyon transect. These analyses included major ion composition, trace element and strontium isotopes, δ¹⁸O and δ²H isotopes, radiocarbon, and tritium. δ¹⁸O and δ²H isotopes suggest that the precipitation feeding the groundwater system has at least two distinct sources. Carbon isotopes showed a change along the canyon transect, suggesting that shorter flowpaths feed springs in the top of the transect, and longer flowpaths discharge near the bottom. Geochemical interpretations support a combination of the two proposed hypotheses. Understanding of the connectivity and provenance of these springs is significant as they are the primary source of water for the communities that inhabit this region and may be impacted by changes in recharge and use.     

Improved understanding of spring and stream water responses in headwaters of the Indian Lesser Himalaya using stable isotopes,conductivity and temperature as tracers

Stable isotope data are presented for precipitation, spring and stream water in a headwater catchments in the Indian Lesser Himalaya. Isotopic contents of phreatic groundwater followed the local meteoric water line and showed minimal alteration by evaporation, suggesting fast recharge. Mean isotopic values for springs and the stream were close to the weighted annual mean for precipitation, indicating recharge was in synchrony with seasonal rainfall distribution. Precipitation exhibited isotopic declines of ?0.6‰ and ?0.2‰ δ¹⁸O per 100 m rise in elevation in July and August (monsoon), respectively. The time lag of one month between rainfall and spring discharge, combined with the isotopic lapse rate indicated a recharge elevation of 70–165 m above the spring outflow point, implying the water originated within the catchment. Time series of electrical conductivity and temperature of spring, seepage and stream waters confirmed the rapid recharge and limited storage capacity of the shallow aquifers.     

A tracer‐based assessment of hydrological pathways at different spatial scales in a mesoscale Scottish catchment

Geochemically based hydrograph separation techniques were used in a preliminary assessment to infer how runoff processes change with landscape characteristics and spatial scale (1–233 km²) within a mesoscale catchment in upland Scotland. A two‐component end‐member mixing analysis (EMMA) used Gran alkalinity as an assumed conservative tracer. Analysis indicated that, at all scales investigated, acidic overland flow and shallow subsurface storm flows from the peaty soils covering the catchment headwaters dominated storm runoff generation. The estimated groundwater contribution to annual runoff varied from 30% in the smallest (ca 1 km²) peat‐dominated headwater catchment with limited groundwater storage, to >60% in larger catchments (>30 km²) with greater coverage of more freely draining soils and more extensive aquifers in alluvium and other drift. This simple approach offers a useful, integrated conceptualization of the hydrological functioning in a mesoscale catchment, which can be tested and further refined by focused modelling and process‐based research. However, even as it stands, the simple conceptualization of system behaviour will have significant utility as a tool for communicating hydrological issues in a range of planning and management decisions. Copyright © 2002 John Wiley & Sons, Ltd.     

Factors controlling seasonal groundwater and solute flux from snow‐dominated basins

Critical zone influences on hydrologic partitioning, subsurface flow paths and reactions along these flow paths dictate the timing and magnitude of groundwater and solute flux to streams. To isolate first‐order controls on seasonal streamflow generation within highly heterogeneous, snow‐dominated basins of the Colorado River, we employ a multivariate statistical approach of end‐member mixing analysis using a suite of daily chemical and isotopic observations. Mixing models are developed across 11 nested basins (0.4 to 85 km²) spanning a gradient of climatological, physical, and geological characteristics. Hydrograph separation using rain, snow, and groundwater as end‐members indicates that seasonal contributions of groundwater to streams is significant. Mean annual groundwater flux ranges from 12% to 33% whereas maximum groundwater contributions of 17% to 50% occur during baseflow. The direct relationship between snow water equivalent and groundwater flux to streams is scale dependent with a trend toward self‐similarity when basins exceed 5.5 km². We find groundwater recharge increases in basins of high relief and within the upper subalpine where maximum snow accumulation is coincident with reduced conifer cover and lower canopy densities. The mixing model developed for the furthest downstream site did not transfer to upstream basins. The resulting error in predicted stream concentrations points toward weathering reactions as a function of source rock and seasonal shifts in flow path. Additionally, the potential for microbial sulfate reduction in floodplain sediments along a low‐gradient, meandering portion of the river is sufficient to modify hillslope contributions and alter mixing ratios in the analysis. Soil flushing in response to snowmelt is not included as an end‐member but is identified as an important mechanism for release of solutes from these mountainous watersheds. End‐member mixing analysis used in combination with high‐frequency observations reveals important aspects of catchment hydrodynamics across scale.     

Definition of catchment area in karst: case of the rivers Krčić and Krka,Croatia

Abstract

The study area consists of the spring zones of the Kr?i?, Krka and Cetina river catchments located in the Dinaric karst, Croatia. Classical hydrological approaches and some newer time and frequency domain methods are used in order to validate the existing hypotheses both qualitatively and quantitatively, and these contribute to factual information about the hydrological behaviour of the catchments. The groundwater recharge rates are calculated by a mathematical model based on Palmer's soil-moisture balance method. The values of parameters of the groundwater recharge model are estimated by the spectral method. The calculated monthly and annual groundwater recharge rates form the basis for estimating the hydrological catchment areas of the spring zones and also for the determina-tion of quantitative relationships between the catchments.     

Effects of Changing Meteoric Precipitation Patterns on Groundwater Temperature in Karst Environments

Climate predictions indicate that precipitation patterns will change and average air temperatures will increase across much of the planet. These changes will alter surface water and groundwater temperatures which can significantly affect the local and regional environment. Here, we examine the role of precipitation timing in changes to groundwater temperature in carbonate‐karst aquifers using measured groundwater level and temperature data from the Konza Prairie Long‐Term Ecological Research Site, Kansas. We demonstrate that shifts to increased cool‐season precipitation may mitigate the increases in groundwater temperature produced by increases in average annual air temperature. In karst, the solution‐enlarged conduits allow faster and focused recharge, and the recharge‐event temperature can strongly influence the groundwater temperature in the aquifer. Our field data and analysis show that predictions of future groundwater conditions in karst aquifers need to consider changes in precipitation patterns, in addition to changes to average annual air temperature.     

Isotopic evidence for widespread cold‐season‐biased groundwater recharge and young streamflow across central Canada

Transformations of precipitation into groundwater and streamflow are fundamental hydrological processes, critical to irrigated agriculture, hydroelectric power generation, and ecosystem health. Our understanding of the timing of groundwater recharge and streamflow generation remains incomplete, limiting our ability to predict fresh water, nutrient, and contaminant fluxes, especially in large basins. Here, we analyze thousands of rain, snow, groundwater, and streamflow δ¹⁸O and δ²H values in the Nelson River basin, which covers 1.2 million km² of central Canada. We show that the fraction of precipitation that recharges aquifers is ~1.3–5 times higher for precipitation falling during cold months with subzero mean monthly temperatures than for precipitation falling during warmer months. The near‐ubiquity of cold‐season‐biased groundwater recharge implies that changes to winter water balances may have disproportionate impacts on annual groundwater recharge rates. We also show that young streamflow—defined as precipitation that enters a river in less than ~2.3 months—comprises ~27% of annual streamflow but varies widely among tributaries in the Nelson River basin (1–59%). Young streamflow fractions are lower in steep catchments and higher in flatter catchments such as the transboundary Red River basin. Our findings imply that flat, lower permeability, heavily tiled landscapes favor more rapid transmission of precipitation into rivers, possibly mobilizing excess soluble fertilizers and exacerbating eutrophication events in Lake Winnipeg.     

Water use strategies of two co‐occurring tree species in a semi‐arid karst environment

The flow of precipitation from the surface through to groundwater in karst systems is a complex process involving storage in the unsaturated zone and diffuse and preferential recharge pathways. The processes associated with this behaviour are not well understood, despite the prevalence of karst aquifers being used as freshwater supplies. As a result, uncertainty regarding the ecohydrological processes in this geological setting remains large. In response to the need to better understand the impact of woody vegetation on groundwater recharge, annual evapotranspiration (ET) rates and tree water sources were measured for two years above a shallow, fresh karst aquifer. Water use strategies of the co‐occurring Eucalyptus diversifolia subsp. diversifolia Bonpl. and Allocasuarina verticillata (Lam.) L. Johnson were investigated using a monthly water balance approach, in conjunction with measurement of the stable isotopes of water, leaf water potentials and soil matric potentials. The results suggest that it is unlikely groundwater resources are required to sustain tree transpiration, despite its shallow proximity to the soil surface, and that similarities exist between ET losses and the estimated long‐term average rainfall for this area. Irrespective of stand and morphological differences, E. diversifolia and A. verticillata ET rates showed remarkable convergence, demonstrating the ability of these co‐occurring species to maximise their use of the available precipitation, which avoids the requirement to differentiate between these species when estimating ET at a landscape scale. We conclude that the water holding capacity of porous geological substrates, such as those associated with karst systems, will play an important role in equilibrating annual rainfall variability and should be considered when assessing ecohydrological links associated with karst systems. Copyright © 2013 John Wiley & Sons, Ltd.     

Water balance estimation under the challenge of data scarcity in a hyperarid to Mediterranean region

Water budget analyses are important for the evaluation of the water resources in semiarid and arid regions. The lack of observed data is the major obstacle for hydrological modelling in arid regions. The aim of this study is the analysis and calculation of the natural water resources of the Western Dead Sea subsurface catchment, one which is highly sensitive to rainfall resulting in highly variable temporal and spatial groundwater recharge. We focus on the subsurface catchment and subsequently apply the findings to a large‐scale groundwater flow model to estimate the groundwater discharge to the Dead Sea. We apply a semidistributed hydrological model (J2000g), originally developed for the Mediterranean, to the hyperarid region of the Western Dead Sea catchment, where runoff data and meteorological records are sparsely available. The challenge is to simulate the water budget, where the localized nature of extreme rainstorms together with sparse runoff data results in few observed runoff and recharge events. To overcome the scarcity of climate input data, we enhance the database with mean monthly rainfall data. The rainfall data of 2 satellites are shown to be unsuitable to fill the missing rainfall data due to underrepresentation of the steep hydrological gradient and temporal resolution. Hydrological models need to be calibrated against measured values; hence, the absence of adequate data can be problematic. Therefore, our calibration approach is based on a nested strategy of diverse observations. We calculate a direct surface runoff of the Western Dead Sea surface area (1,801 km²) of 3.4 mm/a and an average recharge (36.7 mm/a) for the 3,816 km² subsurface drainage basin of the Cretaceous aquifer system.     

Modelling the effects of land‐use change on water and salt delivery from a catchment affected by dryland salinity in south‐east Australia

A comprehensive framework for the assessment of water and salt balance for large catchments affected by dryland salinity is applied to the Boorowa River catchment (1550 km²), located in south‐eastern Australia. The framework comprised two models, each focusing on a different aspect and operating on a different scale. A quasi‐physical semi‐distributed model CATSALT was used to estimate runoff and salt fluxes from different source areas within the catchment. The effects of land use, climate, topography, soils and geology are included. A groundwater model FLOWTUBE was used to estimate the long‐term effects of land‐use change on groundwater discharge. Unlike conventional salinity studies that focus on groundwater alone, this study makes use of a new approach to explore surface and groundwater interactions with salt stores and the stream. Land‐use change scenarios based on increased perennial pasture and tree‐cover content of the vegetation, aimed at high leakage and saline discharge areas, are investigated. Likely downstream impacts of the reduction in flow and salt export are estimated. The water balance model was able to simulate both the daily observed stream flow and salt load at the catchment outlet for high and low flow conditions satisfactorily. Mean leakage rate of about 23·2 mm year^?1 under current land use for the Boorowa catchment was estimated. The corresponding mean runoff and salt export from the catchment were 89 382 ML year^?1 and 38 938 t year^?1, respectively. Investigation of various land‐use change scenarios indicates that changing annual pastures and cropping areas to perennial pastures is not likely to result in substantial improvement of water quality in the Boorowa River. A land‐use change of about 20% tree‐cover, specifically targeting high recharge and the saline discharge areas, would be needed to decrease stream salinity by 150 µS cm^?1 from its current level. Stream salinity reductions of about 20 µS cm^?1 in the main Lachlan River downstream of the confluence of the Boorowa River is predicted. The FLOWTUBE modelling within the Boorowa River catchment indicated that discharge areas under increased recharge conditions could re‐equilibrate in around 20 years for the catchment, and around 15 years for individual hillslopes. Copyright © 2004 John Wiley & Sons, Ltd.     

Influence of bedrock groundwater on streamflow characteristics in a volcanic catchment

Groundwater movements in volcanic mountains and their effects on streamflow discharge and representative elementary area (REA) have remained largely unclear. We surveyed the discharge and chemical composition of spring and stream water in two catchments: the Hontani river (NR) catchment (6.6 km²) and the Hosotani river (SR) catchment (4.0 km²) at the southern part of Daisen volcano, Japan. Daisen volcano is a young volcano (17 × 10³ years) at an early stage of erosion. Our study indicated that deep groundwater that moved through thick lava and pyroclastic flows and that could not be explained by shallow movements controlled by surface topography contributed dominantly to streamflow at larger catchment areas. At the NR catchment, the deep groundwater contribution clearly increased at a catchment boundary defined by an area of 3.0 km² and an elevation of 800 m. At the SR catchment, the contribution deep groundwater to the stream also increased suddenly at a boundary threshold of 2.0 and 700 m. Beyond these thresholds, the contributions of deep bedrock groundwater remained constant, indicating that the REA is between 2 and 3 km² at the observed area. These results indicate that the hydrological conditions of base flow were controlled mainly by the deep bedrock groundwater that moved through thick lava and pyroclastic flows in the undissected volcanic body of the upper part of the catchment. Our study demonstrates that deep and long groundwater movements via a deep bedrock layer including thick deposits of volcanic materials at the two catchments on Daisen volcano strongly determined streamflow discharge instead of the mixing of small‐scale hydrological conditions. Copyright © 2015 John Wiley & Sons, Ltd.     

Groundwater for People and the Environment: A Globally Threatened Resource

The intensity of global groundwater use rose from 124 m³ per capita in 1950 to 152 m³ in 2021, for a 22.6% rise in the annual per capita use. This rise in global per capita water use reflects rising consumption patterns. The global use of groundwater, which provides between 21% and 30% of the total freshwater annual consumption, will continue to expand due to the sustained population growth projected through most of the 21st century and the important role that groundwater plays in the water-food-energy nexus. The rise in groundwater use, on the other hand, has inflicted adverse impacts in many aquifers, such as land subsidence, sea water intrusion, stream depletion, and deterioration of groundwater-dependent ecosystems, groundwater-quality degradation, and aridification. This paper projects global groundwater use between 2025 and 2050. The projected global annual groundwater withdrawal in 2050 is 1535 km³ (1 km³ = 10⁹ m³ = 810,713 acre-feet). The projected global groundwater depletion, that is, the excess of withdrawal over recharge, in 2050 equals 887 km³, which is about 61% larger than in 2021. This projection signals probable exacerbation of adverse groundwater-withdrawal impacts, which are worsened by climatic trends and the environmental requirement of groundwater flow unless concerted national and international efforts achieve groundwater sustainability.     

Using hydrochemical,stable isotope,and river water recharge data to identify groundwater flow paths in a deeply buried karst system

The deeply buried river‐connected Xishan karst aquifer (XKA) in western Beijing, China, has been suffering from diminishing recharge for several decades, which in turn leads to the disappearing of spring water outflows and continuously lowering of groundwater level in the area. Thus, it is important to correctly recognize the groundwater recharge and flow paths for the sustainable development of the XKA. To investigate these issues, the hydrochemical and isotopic compositions are analysed for both surface water and groundwater samples collected over an area of about 280 km². Results show that (a) the river water is characterized by high Na contents; (b) the δ²H and δ¹⁸O values in the river water are distinctively higher than those of groundwater samples, after experiencing the long‐time evaporative enrichment in the upstream reservoir; (c) the Sr concentrations and ⁸⁷Sr/⁸⁶Sr ratios of groundwater clearly indicated the interaction between water and carbonate minerals but excluded the water–silicate interaction; and (d) the groundwater samples in the direct recharge area of the XKA have the lowest Na concentrations and the δ²H and δ¹⁸O values. Based on the large differences in the Na contents and ¹⁸O values of groundwater and surface water, a simple two‐component mixing model is developed for the study area and the fractions of the river water are estimated for groundwater samples. We find that the distribution pattern of the river water fractions in the XKA clearly shows a change of directions in the preferential flow path of the groundwater from its source zone to the discharge area. Overall, our results suggest that the recharged surface water can be a useful evidence for delineating the groundwater flow path in river‐connected karst aquifer. This study improves our understanding of the heterogeneity in karst groundwater systems.     

Quantifying Modern Recharge and Depletion Rates of the Nubian Aquifer in Egypt

Egypt is currently seeking additional freshwater resources to support national reclamation projects based mainly on the Nubian aquifer groundwater resources. In this study, temporal (April 2002 to June 2016) Gravity Recovery and Climate Experiment (GRACE)-derived terrestrial water storage (TWS_GRACE) along with other relevant datasets was used to monitor and quantify modern recharge and depletion rates of the Nubian aquifer in Egypt (NAE) and investigate the interaction of the NAE with artificial lakes. Results indicate: (1) the NAE is receiving a total recharge of 20.27 ± 1.95 km³ during 4/2002?2/2006 and 4/2008–6/2016 periods, (2) recharge events occur only under excessive precipitation conditions over the Nubian recharge domains and/or under a significant rise in Lake Nasser levels, (3) the NAE is witnessing a groundwater depletion of ? 13.45 ± 0.82 km³/year during 3/2006–3/2008 period, (4) the observed groundwater depletion is largely related to exceptional drought conditions and/or normal baseflow recession, and (5) a conjunctive surface water and groundwater management plan needs to be adapted to develop sustainable water resources management in the NAE. Findings demonstrate the use of global monthly TWS_GRACE solutions as a practical, informative, and cost-effective approach for monitoring aquifer systems across the globe.     

Estimating mean residence time of karst groundwater in mountainous catchments of Western Himalaya,India

The mean residence time (MRT) of karst groundwater in three mountainous catchments of the Western Himalaya was estimated using multiple approaches: the tritium method, the sine wave model and tracer tests. Water samples were collected from precipitation, glacier melt, streams and karst springs for δ²H and tritium analysis during 2012 and 2013. High tritium values were observed in winter precipitation and low values in summer precipitation. The variation of tritium in karst springs was similar to that of the streams, whereas glacier melt showed lower tritium values. The MRT of cold karst springs was shorter than that of warm karst springs. The tracer breakthrough curves (TBC) retrieved for different springs suggested a short travel time for groundwater and possibly conduit flow. Deterioration of water quality and variation in flux magnitude are the two main practical consequences of the short travel time of karst groundwater in the region.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR K. Heal     

Groundwater monitoring at the watershed scale: An evaluation of recharge and nonpoint source pollutant loading in the Clear Creek Watershed,Iowa

Determining the groundwater contribution of nonpoint source pollution at a watershed scale is a challenging issue. In this study, we utilized a top‐down approach to characterize representative groundwater response units (GRUs) based on land use and landscape position (e.g., upland, sideslope, or floodplain) in the 275‐km² Clear Creek Watershed, Iowa. Groundwater monitoring wells were then established along downslope transects in representative GRUs. This unique combination of top‐down/bottom‐up approaches allowed us to estimate groundwater pollutant loads at the watershed scale with minimal monitoring. For the 2015 study period, results indicated that more groundwater recharge occurred in the floodplain (404 mm) compared to the uplands or sideslopes (281 and 165 mm, respectively), irrespective of land use. Recharge in the floodplains consisted of 37% of the annual precipitation, whereas upland wells averaged 26% and sideslopes averaged 15% of the annual precipitation. Less recharge was found to occur beneath perennial grass compared to row crop and urbanized areas. Baseflow discharge accounted for 69% of the total NO₃‐N exported from the Clear Creek Watershed, with row crop areas contributing approximately 95% of the annual load. Orthophosphorus (OP) yields were approximately 0.72 kg/ha beneath urban and suburban areas, three times higher than those in row crop or perennial areas. Urban and suburban areas accounted for 21.4% of groundwater orthophosphorus and chloride loads in the watershed compared to only 8.5% of the land area. Overall, the groundwater load allocation model for baseflow nutrient discharge to Clear Creek can be used to target future nonpoint source load reduction strategies at the watershed scale. The use of GRUs can pinpoint better areas of concern for controlling nutrient loads.