Geochemistry of volcanic glass from Oligocene detrital sediments at DSDP Site 296, Kyushu Palau Ridge: Interpreting the magmatic evolution of the early northern Izu–Bonin–Mariana Island Arc

Understanding the petrologic and geochemical evolution of island arcs is important for interpreting the timing and impacts of subduction and processes leading to the formation of a continental crust. The Izu–Bonin–Mariana (IBM) Arc, western Pacific, is an outstanding location to study arc evolution. The IBM first arc (45–25 Ma) followed a period of forearc basalt and boninite formation associated with subduction initiation (52–45 Ma). In this study, we present new major and trace element data for the IBM first arc from detrital glass shards and clasts from DSDP Site 296, located on the northernmost Kyushu Palau Ridge (KPR). We synthesize these data with published literature for contemporaneous airfall ash and tephra from the Izu–Bonin forearc, dredge and piston core samples from the KPR, and plutonic rocks from the rifted eastern KPR escarpment, locations which lie within or correlate with KPR Segment 1 of Ishizuka, Taylor, Yuasa, and Ohara (2011). Our objective is to test ways in which petrologic and chemical data for diverse igneous materials can be used to construct a complete picture of this section of the Oligocene first arc and to draw conclusions about its evolution. Important findings reveal that widely varying primary magmas formed and differentiated at various depths at this location during this period. Changes in key trace element ratios such as La/Sm, Nb/Yb, and Ba/Th show that mantle sources varied in fertility and in the inputs of subducted sediment and fluids over time and space. Plutonic rocks appear to be related to early K‐poor dacitic liquids represented by glasses sampled both in the forearc and volcanic fronts. An interesting observation is that the variation in magma compositions in this relatively small segment encompasses that inferred for the IBM Arc as a whole, suggesting that sampling is a key factor in inferring temporal, across‐arc, and along‐strike geochemical trends.     

Early history of the Izu–Bonin – Mariana arc system: Evidence from Belau and the Palau Trench

Volcanic rocks of the Kyushu–Palau Ridge (KPR) from Deep Sea Drilling Project (DSDP) site 448 and from Belau comprise a low-to-medium-K arc tholeiitic series. Belau rocks include (probable) Mid-Eocene low-Ca type-3 boninite and pre-Early Oligocene–Early Miocene low-K arc tholeiitic basalt, basaltic andesite, andesite and dacite. Palau Trench samples include sparsely phyric high-Mg, -Cr and -Ni rocks which resemble the Belau boninite and Izu–Bonin – Mariana (IBM) system boninites. The high-Mg Palau Trench samples also resemble other primitive arc lavas (e.g. arc picrites). Their chemistry suggests an origin involving steep thermal gradients in multiply depleted mantle. Subduction of hot, young lithosphere under a young hot upper plate is postulated to explain this occurrence. The KPR is inferred to be the source of Eocene boninite and arc tholeiitic terranes presently in forearc regions of the IBM system. A model is presented here showing how many IBM boninites may have originated in a small area near Belau. These have migrated eastward by episodic back-arc opening accompanying eastward migration of arcs and trenches. Oldest known KPR rocks ( ca 47.5 Ma at DSDP site 296), and presumed KPR-derived exotic terranes of Guam ( ca 43.8 Ma), presage the postulated Eocene ( ca 42–43 Ma) change in Pacific plate motion invoked as the cause of subduction initiation at the KPR. The KPR has been rotated more than 40° clockwise since the Eocene, thus the age mismatch may indicate a different tectonic style, for example transtension or transpression, in earliest KPR history.     

U–Pb ages of granitoids around the Kofu basin: Implications for the Neogene geotectonic evolution of the South Fossa Magna region,central Japan

The Japanese archipelago underwent two arc–arc collisions during the Neogene. Southwest Honshu arc collided with the Izu‐Bonin‐Mariana arc and the northeast Honshu arc collided with the Chishima arc. The complicated geological structure of the South Fossa Magna region has been attributed to the collision between the Izu‐Bonin‐Mariana arc and the southwest Honshu arc. Understanding the geotectonic evolution of this tectonically active region is crucial for delineating the Neogene tectonics of the Japanese archipelago. Many intrusive granitoids occur around the Kofu basin, in the South Fossa Magna region. Although the igneous ages of these granitoids have been mainly estimated through biotite and hornblende K–Ar dating, here, we perform U–Pb dating of zircon to determine the igneous ages more precisely. In most cases, the secondary post‐magmatic overprint on the zircon U–Pb system was minor. Based on our results, we identify four groups of U–Pb ages: ca 15.5 Ma, ca 13 Ma, ca 10.5 Ma, and ca 4 Ma. The Tsuburai pluton belongs to the first group, and its age suggests that the granite formation within the Izu‐Bonin‐Mariana arc dates back to at least 15.5 Ma. The granitoids of the second group intruded into the boundary between the Honshu arc and the ancient Izu‐Bonin‐Mariana arc, suggesting that the arc–arc collision started by ca 13 Ma. As in the case of the Kaikomagatake pluton, the Chino pluton likely corresponds to a granodiorite formed in a rear‐arc setting in parallel with the other granodiorites of the third group. The U–Pb age of the Kogarasu pluton, which belongs to the fourth group, is the same as those of the Tanzawa tonalitic plutons. This might support a syncollisional rapid granitic magma formation in the South Fossa Magna region.     

Possible Miocene rifting of the Izu–Ogasawara (Bonin) arc deduced from magnetic anomalies

A magnetic anomaly map of the northern part of the Philippine Sea plate shows two conspicuous north–south rows of long-wavelength anomalies over the Izu–Ogasawara (Bonin) arc, which are slightly oblique to the present volcanic front. These anomalies are enhanced on reduced-to-pole and upward-continued anomaly maps. The east row is associated with frontal arc highs (the Shinkurose Ridge), and the west row is accompanied by the Nishi-Shichito Ridge. Another belt of long-wavelength anomalies very similar to the former two occurs over the Kyushu–Palau Ridge. To explain the similarity of the magnetic anomalies, it is proposed that after the spreading of the Shikoku Basin separated the Izu–Ogasawara arc from the Kyushu–Palau Ridge, another rifting event occurred in the Miocene, which divided the Izu–Ogasawara arc into the Nishi-Shichito and Shinkurose ridges. The occurrence of Miocene rifting has also been suggested from the geology of the collision zone of the Izu–Ogasawara arc against the Southwest Japan arc: the Misaka terrain yields peculiar volcanic rocks suggesting back-arc rifting at ～ 15 Ma. The magnetic anomaly belts over the Izu–Ogasawara arc do not extend south beyond the Sofugan Tectonic Line, suggesting a difference in tectonic history between the northern and southern parts of the Izu–Ogasawara arc. It is estimated that the Miocene extension was directed northeast–southwest, utilizing normal faults originally formed during Oligocene rifting. The direction is close to the final stage of the Shikoku Basin spreading. On a gravity anomaly relief map, northeast–southwest lineaments can be recognized in the Shikoku Basin as well as over the Nishi-Shichito Ridge. We thus consider that lines of structural weakness connected transform faults of the Shikoku Basin spreading system and the transfer faults of the Miocene Izu–Ogasawara arc rifting. Volcanism on the Nishi-Shichito Ridge has continued along the lines of weakness, which could have caused the en echelon arrangement of the volcanoes.     

Evolution of West Rota Volcano, an extinct submarine volcano in the southern Mariana Arc: Evidence from sea floor morphology, remotely operated vehicle observations and 40Ar–39Ar geochronological studies

Abstract West Rota Volcano (WRV) is a recently discovered extinct submarine volcano in the southern Mariana Arc. It is large (25 km diameter base), shallow (up to 300 m below sealevel), and contains a large caldera (6 × 10 km, with up to 1 km relief). The WRV lies near the northern termination of a major NNE‐trending normal fault. This and a second, parallel fault just west of the volcano separate uplifted, thick frontal arc crust to the east from subsiding, thin back‐arc basin crust to the west. The WRV is distinct from other Mariana Arc volcanoes: (i) it consists of a lower, predominantly andesite section overlain by a bimodal rhyolite‐basalt layered sequence; (ii) andesitic rocks are locally intensely altered and mineralized; (iii) it has a large caldera; and (iv) WRV is built on a major fault. Submarine felsic calderas are common in the Izu and Kermadec Arcs but are otherwise unknown from the Marianas and other primitive, intraoceanic arcs. ⁴⁰Ar–³⁹Ar dating indicates that andesitic volcanism comprising the lower volcanic section occurred 0.33–0.55 my ago, whereas eruption of the upper rhyolites and basalts occurred 37–51 thousand years ago. Four sequences of rhyolite pyroclastics each are 20–75 m thick, unwelded and show reverse grading, indicating submarine eruption. The youngest unit consists of 1–2 m diameter spheroids of rhyolite pumice, interpreted as magmatic balloons, formed by relatively quiet effusion and inflation of rhyolite into the overlying seawater. Geochemical studies indicate that felsic magmas were generated by anatexis of amphibolite‐facies meta‐andesites, perhaps in the middle arc crust. The presence of a large felsic volcano and caldera in the southern Marianas might indicate interaction of large normal faults with a mid‐crustal magma body at depth, providing a way for viscous felsic melts to reach the surface.     

Tectonothermal evolution of the Lesser Himalaya, Nepal: Constraints from 40Ar/39Ar ages from the Kathmandu Nappe

Abstract The Himalaya is a fold-and-thrust wedge formed along the northern margin of the Indian continent, and consists of three thrust-bounded lithotectonic units; the Sub-Himalaya, the Lesser Himalaya, and the Higher Himalaya with the overlying Tethys Himalaya from south to north, respectively. The orogen-scale, intracrustal thrusts which bound the above lithotectonic units are splays off an underlying subhorizontal dkcollement, and show a southward propagating piggy-back sequence with an out-of-sequence thrust. Among these thrusts, the Main Central Thrust zone (MCT zone) has played a major role in Himalayan tectonics. The MCT zone represents a shear zone which has accommodated southward thrusting of the Higher Himalayan crystalline thrust sheet over the Lesser Himalayan sequence for ～140 km. The Kathmandu Nappe in central Nepal has been transported over the Lesser Himalayan metasediments along the MCT zone, and is locally separated from the Higher Himalayan thrust sheet in the north by an out-of-sequence thrust. ⁴⁰Ar/³⁹Ar ages have been determined for one whole-rock phyllite and six muscovite concentrates from metasedimenta-ry rocks and variably deformed granites in the Kathmandu Nappe. These ages range from 44 Ma to 14 Ma, and suggest a record of both Eo-Himalayan (Eocene) and Neo-Himalayan (Miocene) tectonothermal events in the Tertiary Himalayan orogeny. The Miocene event was associated with translation along the MCT zone. No tectonothermal event of the Late Miocene to Early Pliocene ages have been reported near the MCT zone in southern Lesser Himalayan crystalline nappe or klippe, although such events have been documented within and around the MCT zone in the northern root zone of the Higher Himalaya. This suggests that out-of-sequence thrusting may have occurred between 14 Ma and 5 Ma, probably during the period 10-7.5 Ma. Since then the frontal MCT zone below the Kathmandu Nappe has been inactive, but the MCT zone in the northern root zone has remained active. The rapid increase in denudation rates of the Higher Himalaya since the Late Miocene may have been caused by ramping along the out-of-sequence thrust at depth.     

40Ar/39Ar dating on volcanic rocks of the Deccan Traps,India

⁴⁰Ar/³⁹Ar dating results on seven volcanic rocks from four areas of the Deccan Traps, India, suggest that volcanic activity more than 70 Ma ago might have occurred at least in limited areas.In the Igat Puri area, the uppermost flow shows an⁴⁰Ar/³⁹Ar age of 63 Ma, whereas a lower flow has an age of around 82–84 Ma.⁴⁰Ar/³⁹Ar ages of samples from the Bombay area also seem to favor the occurrence of volcanic activity more than 70 Ma ago. One rhyolite dyke from the Osam Hill in the Girnar Hill area shows a well-defined plateau age of 68 Ma, whereas two tholeiitic basalts from the Mahabaleshwar area indicate a total⁴⁰Ar/³⁹Ar age of around 63–64 Ma, though they show the effect of secondary disturbance in the age spectra.The volcanic activity(ies) more than 70 Ma ago may correspond to precursory one(s) for the main volcanic activity around 65 Ma ago in the Deccan Traps.     

Basalt and tonalite from the Amami Plateau, northern West Philippine Basin: New Early Cretaceous ages and geochemical results, and their petrologic and tectonic implications

Abstract Basalts and tonalites dredged from the Amami Plateau in the northern West Philippine Basin have the geochemical characteristics of intraoceanic island arc rocks: low ⁸⁷Sr/⁸⁶Sr (0.70297–0.70310), intermediate ¹⁴³Nd/¹⁴⁴Nd (0.51288–0.51292), moderate light rare earth element (LREE) enrichment (La/Yb = 4.1–6.6) and high La/Nb (1.4–4.3). The incremental heating of hornblende from tonalites yielded well‐defined plateaus and ⁴⁰Ar/³⁹Ar isochron ages of 115.8 ± 0.5 Ma and 117.0 ± 1.1 Ma, while plagioclase yielded disturbed Ar release patterns, with ages ranging from 70 to 112 Ma. Taken together, these results show that the Amami Plateau was formed by subduction‐related magmatism in the Early Cretaceous period, earlier than indicated by prior K/Ar results. The results support tectonic models in which the West Philippine Basin was opened within a complex of Jurassic–Paleocene island arc terranes, which are now scattered in the northern West Philippine Basin, the Philippine Islands and Halmahera. The Amami Plateau tonalites and basalts have higher Sr/Y and lower Y and ⁸⁷Sr/⁸⁶Sr compared with younger tonalitic rocks from the northern Kyushu–Palau Ridge and the Tanzawa complex, which were formed by the subduction of the Pacific Plate beneath the Philippine Sea Plate. Based on the geochemical characteristics of the basalts, the Early Cretaceous subduction zone that formed the Amami Plateau may have been the site of slab melting, which suggests that a younger and hotter plate was being subducted at that time. However, the Amami tonalites were probably formed from basaltic magma by fractional crystallization or by partial melting of basaltic arc crust, rather than by melting of the subducted slab.     

K–Ar and 40Ar/39Ar phengite ages of Sanbagawa schist clasts from the Kuma Group, central Shikoku, southwest Japan

Conglomerates of the Kuma Group, central Shikoku, southwest Japan contain Sanbagawa schist clasts with a variety of metamorphic grades and lithologies. K–Ar and ⁴⁰Ar/³⁹Ar dating of phengite show all the pelitic schist clasts from low- to high-grade zones have similar phengite ages (82–84 Ma) that are significantly older than those from the in situ Sanbagawa sequence of central Shikoku. This is because the Kuma–Sanbagawa sequence was exhumed earlier than the in situ Asemi sequence with an exhumation process intermediate between those for the Kanto Mountains and the in situ Asemi sequences. ⁴⁰A/³⁹Ar plateau ages (103 and 117 Ma) of phengite in amphibolites indicate the timing of the early stage of the exhumation of the metamorphic pile, probably close to the peak metamorphic age.     

Studies on40Ar/39Ar thermochronology of strike-slip time of the Tan-Lu fault zone and their tectonic implications

Samples of mylonite, ultramylonite and phyllonite were collected from 5 localities in the Anhui part of the Tan-Lu fault zone for⁴⁰Ar/³⁹Ar chronological studies. Among them 4 samples from 3 localities on the eastern margin of the Dabie orogenic belt yielded⁴⁰Ar/³⁹Ar plateau ages of 128 —132 Ma; and 2 samples from the western margin of the Zhangbalin uplift and eastern margin of the Bengbu uplift gave the same⁴⁰Ar/³⁹Ar plateau ages of 120 Ma. Isochron analyses and other lines of evidence suggest that the data are reliable. The data are interpreted as cooling ages of sinistral strike-slip deformation of the Tan-Lu fault zone. The younger ages from the north might be related to slower strike-slip rising. These results indicate that the large-scale left-lateral displacement in the Tan-Lu fault zone took place in the Early Cretaceous, rather than in Late Triassic (Indosinian) as proposed by some geologists. Therefore, this fault zone is an intracontinental wrench fault rather than a transform fault or suture line developed during formation of the Dabie orogenic belt.     

40Ar–39Ar analysis of phlogopite in the Horoman Peridotite Complex, Hokkaido, Japan and implications for its origin

Abstract ⁴⁰Ar–³⁹Ar analysis of phlogopite separated from a plagioclase lherzolite of the Horoman Peridotite Complex, Hokkaido, Japan, has yielded a plateau age of 20.6 ± 0.5 Ma in an environment where the metamorphic fluid was characterized by an almost atmospheric Ar isotopic ratio. The age spectrum is slightly saddle-shaped, implying some incorporation of excess ⁴⁰Ar during the formation of the phlogopite at a depth. As the phlogopite has been inferred to have formed in veins and/or interstitials during exhumation of the peridotite body, metasomatic fluids, to which ground- and sea water might have contributed, were probably involved in the formation of phlogopite in the crustal environment. A total ⁴⁰Ar–³⁹Ar age of 129 Ma of a whole rock sample of the plagioclase lherzolite, from which the phlogopite was separated and is representative of the main lithology of the Horoman Peridotite Complex, indicates the occurrence of excess ⁴⁰Ar. Hence, the age has no geological meaning.     

Submarine hydrothermal manganese deposits in the Izu–Bonin – Mariana arc: An overview

Submarine hydrothermal manganese deposits are relatively common along the Izu–Bonin – Mariana (IBM) arc but hydrothermal iron crusts are much less so. The hydrothermal manganese deposits show characteristics typical of submarine hydrothermal manganese deposits found worldwide. Recent hydrothermal manganese deposits associated with active hydrothermal systems occur on seamounts or rifts located ∼ 5–40 km behind the volcanic front on the Shichito-Iwojima Ridge, IBM. Fossil hydrothermal manganese deposits associated with older hydrothermal systems occur on inactive seamounts located on ridges running parallel to the volcanic front in both forearc and back-arc settings. These fossil hydrothermal manganese deposits are generally overlain by younger hydrogenetic manganese crusts. Differences in minor element composition and in the rare earth element pattern of hydrothermal manganese deposits from the forearc and back-arc settings may reflect differences in the nature of substrate rocks or temperature of the hydrothermal fluids at these locations.     

40Ar/39Ar incremental-release ages of biotite from a progressively remetamorphosed Archean basement terrane in southwestern Labrador

Gneisses within an Archean basement terrane adjacent to the southwestern portion of the Labrador Trough were variably retrograded during a regional metamorphism of Grenville age (ca. 1000 Ma). Biotites from non-retrograded segments of the gneiss terrane record⁴⁰Ar/³⁹Ar plateau and isochron ages which date times of cooling following an episode of the Kenoran orogeny (2376–2391 Ma). A suite of gneiss samples displaying varying degrees of retrograde alteration was collected across the Grenville metamorphic gradient. Biotites in these samples show no petrographic evidence of retrograde alteration, however they do record internally discordant⁴⁰Ar/³⁹Ar age spectra. Although the extent of internal discordance is variable, the overall character of the release patterns is similar with younger apparent ages recorded in intermediate-temperature gas fractions. The total-gas dates range from 2257±27 Ma (northwest) to 1751±23 Ma (southeast), suggesting that variable quantities of radiogenic argon were lost from the Archean biotites during Grenville metamorphism. The “saddle-shaped” nature of the discordant spectra indicates that argon loss was not accomplished through single-stage, volume diffusion processes.Biotites in portions of the gneiss terrane which were completely recrystallized during Grenville metamorphism are petrographically and texturally distinct. A representative of this phase records a⁴⁰Ar/³⁹Ar plateau age of 2674±28 Ma. This date is markedly inconsistent with regional constraints on the timing of Grenville metamorphism, and indicates the presence of extraneous argon components. Both the extraneous and radiogenic argon components must have been liberated in constant proportions during experimental heating because the argon isotopic data yield a well-defined⁴⁰Ar/³⁶Ar vs.³⁹Ar/³⁶Ar isochron corresponding to an age (2658±23 Ma) similar to that defined by the plateau portion of the spectrum.The⁴⁰Ar/³⁹Ar biotite dates suggest that the effects of Grenville metamorphism extent 15–20 km northward into the Superior Province. The limit of this overprint is approximately coincident with the northernmost development of Grenville age thrust faults in the Archean terrane. Therefore, it is proposed that the northern margin of the Grenville Province in southwestern Labrador should be located along the northernmost Grenville thrust fault because this represents both a structural and a thermal discontinuity.     

Arc–arc collision in the Izu collision zone, central Japan, deduced from the Ashigara Basin and adjacent Tanzawa Mountains

The Pleistocene Ashigara Basin and adjacent Tanzawa Mountains, Izu collision zone, central Japan, are examined to better understand the development of an arc–arc orogeny, where the Izu–Bonin – Mariana (IBM) arc collides with the Honshu Arc. Three tectonic phases were identified based on the geohistory of the Ashigara Basin and the denudation history of the Tanzawa Mountains. In phase I, the IBM arc collided with the Honshu Arc along the Kannawa Fault. The Ashigara Basin formed as a trench basin, filled mainly by thin-bedded turbidites derived from the Tanzawa Mountains together with pyroclastics. The Ashigara Basin subsided at a rate of 1.7 mm/year, and the denudation rate of the Tanzawa Mountains was 1.1 mm/year. The onset of Ashigara Basin Formation is likely to be older than 2.2 Ma, interpreted as the onset of collision along the Kannawa Fault. Significant tectonic disruption due to the arc–arc collision took place in phase II, ranging from 1.1 to 0.7 Ma in age. The Ashigara Basin subsided abruptly (4.6 mm/year) and the accumulation rate increased to approximately 10 times that of phase I. Simultaneously, the Tanzawa Mountains were abruptly uplifted. A tremendous volume of coarse-grained detritus was provided from the Tanzawa Mountains and deposited in the Ashigara Basin as a slope-type fan delta. In phase III, 0.7–0.5 Ma, the entire Ashigara Basin was uplifted at a rate of 3.6 mm/year. This uplift was most likely caused by isostatic rebound resulting from stacking of IBM arc crust along the Kannawa Fault which is not active as the decollement fault by this time. The evolution of the Ashigara Basin and adjacent Tanzawa Mountains shows a series of the development of the arc–arc collision; from the subduction of the IBM arc beneath the Honshu Arc to the accretion of IBM arc crust onto Honshu. Arc–arc collision is not the collision between the hard crusts (massif) like a continent–continent collision, but crustal stacking of the subducting IBM arc beneath the Honshu Arc intercalated with very thick trench fill deposits.     

Excess40Ar in metamorphic rocks from Broken Hill,New South Wales: implications for40Ar/39Ar age spectra and the thermal history of the region

⁴⁰Ar/³⁹Ar age spectrum analyses of samples from Broken Hill, New South Wales, indicate that the region has experienced a complex thermal history following high-grade metamorphism, 1660 Ma ago. The terrain cooled slowly (～3°C Ma^?1) until about 1570 Ma ago, when the temperature fell below about 500°C. Following granitoid emplacement ～1500 Ma ago, the region remained relatively cold until affected by a thermal pulse 520±40Ma ago, causing temperatures to rise to～350°C in some places. During this event, accumulated⁴⁰Ar was released from minerals causing a significant Ar partial pressure to develop. Laboratory Ar solubility data combined with the⁴⁰Ar/³⁹Ar age spectra gives a local estimate of this partial pressure of ～10^?4atm. The region finally cooled below 100°C about 280 Ma ago.⁴⁰Ar/³⁹Ar age spectrum analyses of hornblende, plagioclase and clinopyroxene containing excess⁴⁰Ar are characterized by saddle-shaped age spectra. Detailed analysis of plagioclase samples reveals a complex diffusion behaviour, which is controlled by exsolution structures. This effect, in conjunction with the presumed different lattice occupancy of excess⁴⁰Ar with respect to radiogenic⁴⁰Ar, appears to be responsible for the saddle-shaped age spectra.     

Age studies on slates: Applicability of the40Ar/39Ar stepwise outgassing method

Results of⁴⁰Ar/³⁹Ar stepwise outgassing experiments are reported for six slates, one hornfels and one metasilt-stone from the Lower Paleozoic Meguma Group of Nova Scotia, Canada. The age spectrum of the hornfels and of one slate collected from the vicinity of a granite contact have both been completely reset by the thermal effects of the intrusion. The latter, however, has not produced any recognizable mineralogical modification of the slate. Two samples in the collection contain potassium feldspar, possibly of detrital origin, and both have yielded discordant age spectra which cannot be unambiguously interpreted.Three apparently “clean” slates collected from localities well removed from the effects of the granite batholith have yielded quite well-defined age plateaus at ?415 Ma (revised decay and isotopic constants). The mean total gas⁴⁰Ar/³⁹Ar age or, equivalently, the mean K-Ar age is ?400 Ma. From these data we suggest a minimum value ?400–415 Ma for the time of initiation of the Acadian Orogeny in Nova Scotia which culminated with post-deformational “granitic” intrusion ?370–380 Ma ago.     

40Ar/39Ar ages of blueschist facies pelitic schists from Qingshuigou in the Northern Qilian Mountains, western China

Abstract   Pelitic schists from Qingshuigou in the Northern Qilian Mountains of China contain mainly glaucophane, garnet, white mica, clinozoisite, chlorite and piemontite. Isotopic age dating of these schists provides new constraints on the formation of the high-grade blueschists at Qingshuigou. White mica ⁴⁰Ar/³⁹Ar ages range from 442.1 to 447.5 Ma (total fusion age of single grain) and from 445.7 to 453.9 Ma (integrated age of white mica concentrates). These ages (442.1–453.9 Ma) represent the peak metamorphic ages or cooling ages of the blueschists during exhumation shortly after peak metamorphism. The ⁴⁰Ar/³⁹Ar dates in the present study are similar to ages previously reported for eclogites and blueschists in the area; this suggests that both the eclogites and pelitic sediments underwent high-grade metamorphism during the same subduction event. From this chronological evidence and the presence of well-developed Silurian remnant-sea flysch and Devonian molasse, it is concluded that the Northern Qilian Ocean had closed by the end of the Ordovician, and rapid orogenic uplift followed in the Devonian.     

Intercalibration of international and domestic 40Ar/39Ar dating standards

Four international standards, Ga1550, MMhb-1, Lp-6, Bem 4M, and one domestic standard BT-1 have been intercalibrated. The repeated measurements on MMhb-1 with different mass demonstrate that MMhb-1 is inhomogeneous in age and its average age is 519.8 Ma. The results of Bern 4M and Lp-6 reflect that they have an invariable value of ⁴⁰Ar*/³⁹Ar_k (F) and the ages we obtained are consensus with their K-Ar age: Lp-6=127.7Ma; Bern 4M=18.2 Ma. Analyses of BT-1 age spectra, Ca/K and Cl/K spectra as well as inverse isochrons indicate that the sample is homogeneous and invariable and keeps close chemically, with its trapped argon isotope composition close to the atmosphere. The dating results show that age values are reproducible and steady, total fusion age, step-heating age, plateau age and isochron age are in accord with each other within the error range (2σ). Therefore, we recommend 28.7 Ma as the calibrated age of BT-1. We also discuss the variation in neutron flux gradients of Beijing 49-2 reactor. It was found that the neutron flux gradient varies considerably, and more monitors (standard samples) are needed to fix the trend of variation. The coefficient of the 49-2 reactor that transfers the ratio of production rate of ³⁷Ar_Ca/³⁹Ar_K into Ca/K ratio is 1.78. This is different from that reported earlier, 2.0, which may be caused by the reconstruction of the reactor.     

40Ar/39Ar ages for the alkaline volcanism and the basement of Gorringe Bank,North Atlantic ocean

Gorringe Bank is situated on the Europe-Africa plate boundary at the eastern end of the Azores-Gibraltar fracture zone. It has two summits, Gettysburg Bank to the Southwest and Ormonde Bank to the northeast.We applied the⁴⁰Ar/³⁹Ar stepwise heating method to date six samples of the alkaline volcanic rocks, two gabbros from the Ormonde Bank and a dolerite from the Gettysburg Bank. The results that the alkaline volcanism lasted probably for less than 6 Ma(66-60 Ma).Although the nature of this volcanism precludes any subduction feature during its setting, the alkaline volcanism of Ormonde is probably linked to Upper Cretaceous/Eocene compressive tectonic events.The basement rocks of Gorringe Bank reveal distrubed⁴⁰Ar/³⁹Ar age spectra. One plagioclase and one biotite from a gabbro give evidence for a thermic event whose age is tentatively estimated at about 75 Ma, and related to a variation in the direction of the relative movement between Europe and Africa. The more probable age given by a plagioclase of another gabbro and by a dolerite (110 Ma) corresponds to tilting northeastward of the Gorringe massif.     

Emplacement processes of proto-arc basalt in the Izu–Bonin–Mariana arc system

Ascertaining the emplacement mechanism of oceanic basaltic lavas is important in understanding how ocean floor topography is produced and oceanic plates evolve, particularly during the early stages of crustal development of a supra-subduction zone. A detailed study of the volcanic stratigraphy at International Ocean Discovery Program (IODP) Site U1438 in the Amami Sankaku Basin, west of the Kyushu–Palau Ridge, has revealed the development of lava accretion and ridge topography on the Philippine Sea plate at about 49 Ma. Igneous basement rocks penetrated at Site U1438 are the uppermost 150 m of ~6 km-thick oceanic crust, and comprise, in a downhole direction, sheet flows (12.6 m), lobate sheet flows (61.3 m), pillow lavas (50.7 m), and thin sheet flows (25.3 m). The lowermost sheet flows are intercalated with layers of limestone and epiclastic tuff. Lithofacies analysis reveals that the lowermost sheet flows, limestone, and tuff formed on an axial rise, the pillow lavas were emplaced on a ridge slope, and the lobate sheet flows formed off ridge on an abyssal plain. The lithofacies of the basement basalt corresponds to the upper portions of fast-spreading oceanic crust, suggesting that subduction initiation was associated with intermediate to fast rates of seafloor spreading. The surface sheet flows are olivine–clinopyroxene-phyric basalt and differ from the lower basalt flows that contain phenocrysts of olivine and plagioclase, with or without clinopyroxene. The depleted chrome-spinel composition and olivine–clinopyroxene phenocryst assemblage in the surface sheet flows suggests a slight contribution of water for magma generation not present for the lower basalt flows. Considering the lithological difference between the backarc and forearc oceanic crust in the Izu–Bonin–Mariana arc, with sheet flow dominant in the former, seafloor spreading occurred faster in the later stage of subduction initiation.