A scanning electron microscope study of surface textures of quartz grains from glacial environments

Surface textures of quartz sand grains from several glacial environments at the Feegletscher, Switzerland examined by means of scanning electron microscopy are described. The difference between supraglacial and subglacial material is very slight. At the moment the interpretation of these textures must be done with care until the full statistical relation to environments can be ascertained. This does not necessarily invalidate earlier investigations although it does mean that glacial and extraglacial environments in the vicinity of glaciers are apparently not distinguishable. Examination of surface precipitation features suggests a sequence of events which can be used to help discriminate between different ages of deposits in an area. A similarity between some of the surface debris from moraine samples and those seen in loess and quickclay deposits is also suggested.     

Scanning electron microscopy of Pleistocene tills in Estonia

Tills from four Pleistocene glaciations were recovered from drill cores in Estonia and subjected to particle size and microtexture analyses by Scanning Electron Microscope (SEM). All tills were deposited by thick continental ice-sheets following the transport of, at most, several hundred kilometers during four Fennoscandian glaciations. The main problem is to determine if the type and range of microtextures present on the grain surfaces are diagnostic of transport in continental ice. The frequency of occurrence of microtextures including fractures, abrasion, and relief features are used to test the ability of continental ice to damage quartz particles emplaced as till. The range of quartz dissolution and presence of coatings on grains are also used to reconstruct the paleoenvironment that existed prior to transport as well as to estimate diagenetic effects that occurred following emplacement. The available data indicate a high degree of reworking of quartz grains from one glaciation to another. While the shapes and microtextures of grains from source rocks are not known, the great range of fracture and abrasion microfeatures, and high frequency of occurrence on grains in all tills, indicate that glaciers are effective crushing agents. An increase in the prevalence of chemically etched grains from older to younger tills suggests that some grains ( c . 50%) escape crushing, either because of preservation in the ice and lack of grain-to-grain contact, or as a result of massive reworking of weathered grains following interglaciations.     

Scanning electron microscopy of quartz grains in supraglacial debris, Adishy Glacier, Caucasus Mountains, USSR

The surface microtopography of quartz grains in glacial depostis has often been attributed to mechanical release from source rocks during weathering and prior to entrainment by glaciers. Fractures on quartz particles, including subparallel and conchoidal features, often attributed to cryostatic pressure in ice and stick-slip processes at the base of glaciers, have been considered, in part, to result from mechanical weathering of source rocks. To test this hypothesis we studied 15 samples of supraglacial debris from the Adishy Glacier in the central Caucasus Mountains, USSR. Clasts in transport on the surface of the glacier originate primarily from the cirque headwall by weathering and mass wasting processes; a minor amount is presumed to have been derived from aeolian influx following reworking of older sediments down valley. The results show unequivocally that mechanical weathering is only likely to produce grains with pronounced fracture faces that lack subparallel and conchoidal fracture features. No fresh glacial-crushing type features were observed on these samples. Grains that had been glacially crushed, weathered and retransported, presumably by aeolian processes, were observed in four samples of the data set.     

The formation and significance of irregularly shaped quartz grains in till

Thin sections and scanning electron microscopy of quartz sand grains from till show clearly that a number of grains have been modified in place. The irregular grains result from the action of circulating alkaline groundwater, episodically concentrated by evaporation on fracture surfaces within grains and on concave surfaces produced by fracture during glacial transport. Evaporation increases the pH of the pore water and localizes its effect in small pores with a high capillary potential. Subsequent dilution by rainwater or snow meltwater flushes the system so that evaporation can repeat the process again. Solution rounding in terrigenous sediments has a number of ramifications for any interpretation based on textural maturity of the sediment.     

A local clay-varve chronology and proglacial sedimentary environment in glacial Lake Peipsi, eastern Estonia

Ten cores consisting of varved clay from the northern part of Lake Peipsi in eastern Estonia have been correlated using varve thickness variations and specific marker varves into a 375-year floating varve chronology. Continuous sedimentation during gradual ice recession is concluded from a clear transition from proximal to distal varves. Cyclic variations in varve thickness are caused mainly by thickness changes of clayey winter layers. This is interpreted to indicate increased influx of finer material due to faster melting of the glacier. The cyclic pattern of thickness change is explained by alternating periods of increased and decreased melting of the ice. Simultaneous accumulation of varved clay in glacial Lake Peipsi and in the Luga and Neva basins of Russia is concluded from the good visual correlation between the mean varve thickness diagrams for the three chronologies. Because the varve chronologies from northwestern Russia have been tentatively correlated to the Swedish varve chronology, the timing of the clay accumulation in glacial Lake Peipsi is placed between c . 13 500 and 13 100 varve years BP.     

Size, form and composition of gold grains in glacial drift in Ilomantsi, eastern Finland

Gold grains were studied in 102 till and gravel samples from an area with Au anomalies in the fine fraction of till. The form and size of gold nuggets were studied under the microscope, and the composition of selected grains was determined on a microprobe. The number of visible nuggets per sample was less than 10 per 81. In size, the nuggets were between 0.07 and 1 mm. Most of them were indefinite but flat in form, although idiomorphic gains were also observed. In composition, the gold grains in bedrock differed somewhat from those in till and gravel. Some of the nuggets found in gravel and in till were probably secondary in origin. The possibility that all the grains are not primary is emphasized in the interpretation of geochemical results.     

Subglacial bed deformation and dynamics of the Apriķi glacial tongue,W Latvia

Saks, T., Kalvans, A. & Zel?s, V. 2012 (January): Subglacial bed deformation and dynamics of the Apri?i glacial tongue, W Latvia. Boreas, Vol. 41, pp. 124–140. 10.1111/j.1502‐3885.2011.00222.x. ISSN 0300‐9483. We evaluate the glacial dynamics and subglacial processes of the Apri?i glacial tongue in western Latvia during the Northern Lithuanian (Linkuva) oscillation of the last Scandinavian glaciation. The spatial arrangement of glacial bedforms and deformation structures are used to reconstruct the ice dynamics in the study area. The relationship between geological structures at the glacier bed and the spatial distribution of drumlins and glacigenic diapirs, on the one hand, and the permeability of sediment and bedrock, on the other, is ascertained. Drumlins are found in the upper part of the Apri?i glacial tongue area and are composed of soft deformable sediments overlying highly permeable Devonian dolomite. The soft deformable clayey silty bed with low hydraulic conductivity is conducive to the development of diapirs. The occurrence of diapirs and drumlins is controlled by the fluctuation of pore‐water pressure at the glacier bed and is considered to be an indicator of fast ice flow of the Apri?i glacial tongue during its reactivation at the end of the Oldest Dryas (18–15 ka BP).     

Nature and origin of bubble structures in borehole samples of glacial sands from Caldy, Wirral, United Kingdom

Borehole samples of glacial sands from Caldy, Wirral contained bubble structures which have not been found in in situ exposures of the corresponding materials. It is believed that the sands liquefied during driving of the sampler, destroying previous structures and developing a bubble structure by release of pore-air during liquefaction. The sands conform generally to the grading characteristics previously defined for sands prone to liquefaction. Their propensity to liquefy was confirmed by laboratory tests.     

Distribution and dispersion of gold in glacial till associated with gold mineralization in the Canadian shield

The results described relate to an investigation into the nature of Au dispersion in glacial till, undertaken to identify optimum search techniques for use in exploration for Au mineralization.The diversity of Au mineralization, in terms of the host rock lithologies, mineralogy and grain size of the Au, would be expected to give rise to differences in the secondary response in the associated overburden. Common exploration procedures involve the analyses of the heavy-mineral fraction or a particular size fraction of the tills. However, having regard to the expected variable response of Au in associated glacial till, attributed to variations in primary mineralization, effective exploration requires that the methodology employed is capable of locating all types of Au mineralization.Bulk till samples were collected from various sites associated with the Owl Creek deposit near Timmins and the Hemlo deposits. Grain size analyses were carried out on the till samples and on the heavy-mineral concentrates. The concentration of the Au in the various fractions was determined by Instrumental Neutron Activation Analysis.Preliminary results allow a number of provisional conclusions to be drawn:

1. (1) Grain size analysis of the −2 mm fraction of tills indicates that the silt and clay fraction constitutes 20–50%, whereas, in contrast, the equivalent heavy-mineral concentrates are dominantly composed of the coarser −500 + 63 μm material.

2. (2) The amount of Au present in the heavy-mineral concentrates of tills represents only a minor proportion of the total Au in the original till samples. In addition, the proportion of the total Au recovered in the heavy-mineral concentrate varies from 4 to 15%. Both factors indicate that caution is necessary in interpreting the significance of heavy-mineral Au data.

3. (3) Examination of the size distribution of Au within the heavy-mineral concentrate indicates that the majority of the Au is contained in the −125 μm fraction.

4. (4) The concentration factor (the original sample weight divided by the heavy-mineral concentrate weight) varies up to 7-fold between samples due presumably to the differing proportions of heavy minerals. Hence, in Au deposits of equivalent economic significance this gives rise to varying Au concentrations in heavy-mineral concentrates according to the quantity of heavy minerals present. Significant interpretation can only be achieved by re-expressing the Au contents of heavy-mineral concentrates in terms of the absolute amount of Au in heavy-mineral concentrates.

5. (5) A comparison of the heavy-mineral concentrates produced by different laboratories indicates marked differences in the weight of the heavy-mineral concentrate, the Au concentration of the heavy-mineral concentrate, the total weight of Au in the heavy-mineral concentrate and the size distribution of the Au in the heavy-mineral concentrate.

6. (6) Analysis of the −63 μm silt and clay size fraction indicates anomalous Au contents within this fraction of the tills collected from Owl Creek and Hemlo, extending over 500 m down-ice from mineralization at Hemlo.

7. (7) Analysis of the −63 μm silt and clay size fraction is suitable for the detection of fine-grained Au deposits that are not amenable to detection on the basis of heavy-mineral concentrate analyses.

8. (8) The analysis of the silt and clay fraction reduces the sample representativity problems associated with analyzing coarser fractions.

9. (9) A comparison of the Au distribution in heavy-mineral concentrates and the −63 μm fraction of till down-ice from the Owl Creek deposit indicates broadly similar dispersion patterns.

In conclusion, although the results are based on relatively few samples, their consistency permits some general conclusions to be drawn. The silt and the heavy-mineral concentrate analyses provide different information and in view of the diversity of exploration targets and surface environments exploration reliability can be increased by analyzing both the −63 μm silt and clay fraction and the heavy-mineral concentrate.     

Comparative study of striations and basal till clast fabrics, Malpeque—Bedeque region, Prince Edward Island, Canada

Coastal erosion has resulted in exposure of a succession of basal till deposits and striation localities along the Malpeque and Bedeque Bays, PEI, Canada, permitting repetitive determinations of clast fabrics and investigation of recently exhumed striations. Striations indicate initial eastward ice flow, followed by a second glacial event with flow towards the south and southwest from the Gulf of St. Lawrence. The degree of local inconsistency and the variations with striation assemblages indicate that the orientations of individual striations cannot be regarded as 'absolute' indicators of ice flow directions. Diamictons identified as basal tills using sedimentological criteria have clast fabrics typical of basal till deposition. Local deviations of fabric trend within individual outcrops are common. A comparative analysis of the data obtained from striation and clast fabric orientations indicates that the ice flow directions independently suggested by each are in general agreement. Differences are present between the orientations of striations and clast fabrics at individual sites. The orientations of the fabrics lie within 20° of the modal striation orientations in only 28% of the cases, and the median deviation between the suggested ice flow directions was 29°. In 40%, of the cases, the azimuth deviation between the two methods exceeded 40°, and the maximum deviation recorded was 84°. At many sites, the deviations are so severe as to potentially result in the misinterpretation of the modal ice flow direction, based on the use of either striation orientation or clast fabric in isolation. Variations in glacial flow can readily produce striations and clast fabrics which record different phases of glacial activity associated with the same glacial event at an individual site.     

Multigroup discrimination of river, beach, and dune sands using axial-ratio sample statistics of quartz grains

Optimal discrimination among several groups can be achieved by simultaneous diagonalization of pooled within-group, W, and among-group, A, sums of squares and cross-product matrices formed by utilizing axial-ratio sample statistics of quartz grains belonging to different sieve grades. This method maximizes the ratio of among-group cross products to within-group cross product quadratic forms (V'AV/V'WV)and simultaneously yields discriminant scores whose correlation coefficients are zero for group means as well as for within each group. This procedure enables a simple Euclidean distance measure for partitioning the discriminant space for assignment. Although W^–1 and Amatrices are symmetric, the W^–1 Amatrix needed for multigroup discrimination is asymmetric and hence the eigenstructure of W^–1 Ais obtained by simultaneous diagonalization of Wand Amatrices. The first four sample statistics (mean, standard deviation, skewness, kurtosis) of normalized axial-ratios are required for discrimination, although the mean and standard deviation are the most important discriminators.     

新疆罗布泊含钾地层矿物扫描电镜研究

运用扫描电子显微镜对采自ZK1200B钻孔1.12～53.00 m处岩芯的部分样品进行了分析研究。据此,较精确地划分出了4层含钾岩层,发现有钾石盐、光卤石、杂卤石、泻利盐、硫锶钾石、天青石等固体盐类矿物,其中的硫锶钾石和天青石矿物在新疆罗布泊地区属首次发现。钙芒硝岩层中含有硫锶钾石、天青石,推断其锶可能来源于深部地层水（或油田水）的补给,对罗布泊地区钾盐矿的成因研究具有重要意义。     

K-Ar dating,X-Ray diffractometry,optical and scanning electron microscopy of glauconies from the early Cretaceous Kurnub Group of Jordan

The glaucony of the early Cretaceous Kurnub Group in Jordan has been isotopically dated using the K–Ar method. The glaucony occurs in an arenaceous dolomite unit, referred to here to as glaucony marker unit (GMU), located in the upper part of the Kurnub Group, that persists throughout Jordan. The glaucoliths of the heavy fraction are dark green in colour, ovoidal or mammilated, with a mainly cracked smooth surface, whereas the light fraction glaucoliths are light green in colour, irregular in shape and have a rough or porous surface. Both fractions exhibit boxwork and rosette microstructure, whereas lamellar microstructure is restricted to the heavy glaucoliths. X-ray diffraction and chemical analysis placed the glauconies of the GMU of the Kurnub Group in Odin and Matter's evolved to highly evolved class corresponding to glauconitic mica and suggested that they should be well-closed chronometers. On the other hand, petrographic investigation proved these glauconies to be unaltered, whereas the other altered ones are discarded from the age determination. The unweathered, highly evolved, heavy glauconies that are neither tectonized nor deeply buried best fulfil recommendations regarding appropriate samples for K–Ar dating. The apparent age constrained, within the analytical uncertainty limits, from the most evolved glaucony is 96·1±1·1 Ma and suggests that the GMU is of Albian age. The other less evolved glauconies, which are still within the evolved to highly evolved class of Odin and Matter, yield a mean apparent age of 93·6±1·0 Ma, which is probably slightly younger than the true depositional age by 2–3 Ma due to genetic and historical uncertainties, as indicated by the petrographic and sedimentological data. Thus the upper part of the Kurnub Group, where the GMU is located, is of Albian age. © 1998 John Wiley & Sons, Ltd.     

Fate and transport of volatile organic compounds in glacial till and groundwater at an industrial site in Northern Ireland

Volatile organic compound (VOC) contamination of subsurface geological material and groundwater was discovered on the Nortel Monkstown industrial site, Belfast, Northern Ireland. The objectives of this study were to (1) investigate the characteristics of the geological material and its influences on contaminated groundwater flow across the site using borehole logs and hydrological evaluations, and (2) identify the contaminants and examine their distribution in the subsurface geological material and groundwater using chemical analysis. This report focuses on the eastern car park (ECP) which was a former storage area associated with trichloroethene (TCE) degreasing operations. This is where the greatest amount of volatile organic compounds (VOCs), particularly TCE, were detected. The study site is on a complex deposit of clayey glacial till with discontinuous coarser grained lenses, mainly silts, sands and gravel, which occur at 0.45–7.82 m below ground level (bgl). The lenses overall form an elongated formation that acts as a small unconfined shallow aquifer. There is a continuous low permeable stiff clayey till layer beneath the lenses that performs as an aquitard to the groundwater. Highest concentrations of VOCs, mainly TCE, in the geological material and groundwater are in these coarser lenses at ∼4.5–7 m bgl. Highest TCE measurements at 390,000 μg L⁻¹ for groundwater and at 39,000 μg kg⁻¹ at 5.7 m for geological material were in borehole GA19 in the coarse lens zone. It is assumed that TCE gained entrance to the subsurface near this borehole where the clayey till was thin to absent above coarse lenses which provided little retardation to the vertical migration of this dense non-aqueous phase liquid (DNAPL) into the groundwater. However, TCE is present in low concentrations in the geological material overlying the coarse lens zone. Additionally, VOCs appear to be associated with poorly drained layers and in peat <3.0 m bgl in the ECP. Some indication of natural attenuation as VOCs degradation products vinyl chloride (VC) and dichloromethane (DCM) also occur on the site.     

Complex speleothem growth processes revealed by trace element mapping and scanning electron microscopy of annual layers

Closely-spaced transects measured by excimer laser ablation inductively-coupled plasma mass spectrometry (ELA-ICPMS) at 5 and 32 μm spatial resolution are used to generate trace element composition maps (Ba, Sr, Mg, U, Na, P and Al) from MND-S1, a previously studied modern stalagmite from southwest Australia (Treble et al., 2003: EPSL216: 141). Rainfall at the site is highly seasonal, and trace elements in MND-S1 show strong seasonal variation. Trace element maps show that Ba, Sr, U and Na concentrations coherently follow annual growth layers identified from Scanning Electron Microscopy (SEM) images. The SEM images also reveal that stalagmite growth did not proceed uniformly: growth layers vary in thickness and locally pinch out. Highly preferential crystal growth, determined by nucleation sites left by the previous year’s growth, may be responsible for this uneven growth layering. Differential crystal growth apparently causes variability of trace element concentrations along each annual layer, although additional disequilibrium processes affect Mg, which is less distinctly banded than Ba, Sr, U and Na. Uneven and discontinuous growth layers influence the number of annual cycles, their wavelengths and seasonal amplitudes measured in any one transect. This has clear implications for studies that use annual trace element cycles as chronological markers, growth rate or seasonality proxies.     

Environmental scanning electron microscopy (ESEM) and nanoindentation investigation of the crack tip process zone in marble

This study explores the interaction between crack initiation and nanomechanical properties in the crack-tip fracture process zone of Carrara marble. Specimens with preexisting cracks were loaded in a uniaxial testing machine until the process zone appeared at the tips of the preexisting cracks. ESEM analysis reveals an increase in microcrack density in the process zone with increased loading of the specimen. Nanoindentation testing comprised of lines and grids of single nanoindentations located both near and far from the process zone shows a decrease in both indentation modulus and indentation hardness near grain boundaries in intact material, and with closeness to the process zone. Ultimately, the study confirms that the crack-tip process zone manifests itself as an area of reduced indentation hardness and indentation modulus in marble.     

Autoradiography and scanning electron microscopy combined with energy-dispersive spectrometry (SEM-EDS) in the service of geochemical exploration

The importance of the identification of the mineral phases in the heavy fractions of geochemical samples is emphasized. A knowledge of the chemical composition with information about the anomalous contents of the economically interesting metals in the samples is not sufficient, it is also essential to know the mineralogical source of the metals especially when the exploitation possibilities of the searched-for deposits are being estimated. A version of autoradiography suitable for the location and quantitative determination of radioactive minerals in the heavy fractions of geochemical samples is described. Furthermore, the use of a scanning electron microscope (SEM) equipped with an energy-dispersive spectrometer (EDS) in the identification of the heavy minerals is also described. An example of the use of SEM-EDS identification of radioactive minerals, located by the autoradiography, is described.     

Distribution of the glass phase in hot-pressed,olivine-basalt aggregates: An electron microscopy study

Samples of olivine mixed with small amounts of tholeiitic basalt which were hot-pressed above the solidus temperature were examined by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) techniques. Two sets of samples were compared. One set was hot-pressed for approximately 1 h near 1,300° C at 0.2 GPa, and the other set was held for approximately 200 h near 1,250° C at 1.0 GPa. SEM observations reveal that, in samples which were hot-pressed for 1 h, the glass phase occurs in irregular pockets surrounded by four or five olivine grains as well as in triple junctions. The crystal-glass interfaces show both positive and negative curvature. These observations and the presence of voids suggest that the microstructure is far from textural equilibrium. In contrast, in samples which were hot-pressed for 200 h, glass is largely confined to triple junctions of uniform size and the crystal-glass interfaces have uniform curvature indicating a much greater degree of textural equilibrium. TEM images reveal layers of glass 10–50 nm thick along most of the grain boundaries in the samples annealed for short times. However, within the limit of resolution, 2 nm, virtually all of the grain boundaries in the samples hot-pressed for long times appear to contain no glass. These observations indicate that segregation of melt from grain boundaries to triple junctions is an integral part of the process of textural equilibration.     

A study by electron microscopy of gold and associated minerals from Round Mountain,Nevada

Details regarding the mineralization patterns of gold in epithermal systems are poorly understood. A refined understanding of gold microtextures, the interface between gold and associated minerals, and the role that nanoparticles play in gold mineralization could provide insight into the details of gold growth and may contain indicators of gold ore concentration mechanisms. Furthermore, a refined understanding of the interface also may explain variation in cyanide leaching extraction efficiency and may enable enhancement of recovery methods. Macrocrystalline gold samples from Round Mountain, Nevada were analyzed using field emission scanning electron microscopy and transmission electron microscopy. This study suggests that gold nanoparticles are common in Round Mountain gold and associated mineral phases, and may play an important role in the formation of macrocrystalline gold in this deposit. Microtopographic evidence indicates that the two dimensional nucleation and growth mechanism is dominant and nanotextural evidence suggests that nanoparticulate gold was the first stage of growth in the formation of these macrocrystalline samples that grew rapidly at high degrees of supersaturation. Results suggest that the interface between gold and quartz and other related minerals is far more complex than previously thought, and that textures present at the interface and in the bulk gold can help explain mineralization history and can also have implications for gold recovery efficiency for macrocrystalline bearing ore.     

Lodgement till deposition and deformation investigated by macroscopic observation, thin-section analysis and electron microscope study at site Dçbe, central Poland

Macroscopic observation, thin-section analysis and electron microscope study were used in a detailed examination of till exposed in a valley escarpment. The till displays two kinds of bedding: (1) beds of different colour (lithology) that are not separated from one another by distinct boundaries, and (2) beds that are separated by distinct subhorizontal planes of discontinuity, commonly consisting of several beds of the first type. Beds showing no clear separation are interpreted as having been deposited through continuous lodgement, while the distinct discontinuities most probably record sliding planes of the glacier sole during breaks in till deposition. These features, along with the qualitative and quantitative microscopic evidence, indicate that the lower and middle parts of the till were deposited by hard lodgement. The process of deposition was interrupted several times by episodes of non-deposition, some of them accompanied by glacial erosion. The upper part of the till was deposited by continuous lodgement that was transitional between hard and soft lodgement processes. Such a succession indicates the prevalence of a cooler subglacial thermal regime which changed upwards into a milder one. The till examined displays mainly brittle deformation - namely Riedel shears that are primarily concentrated between the subhorizontal discontinuities characteristic of the lower and middle parts of the section. A dense set of Riedel shears also cuts thicker portions of the upper part of the till and, in some places, such shears combine along additional subhorizontal (discrete) shear planes. The direction of the fractures, as well as the strong fabric orientation of stone a-axes within the till, indicate an ice flow in the studied area from NW to SE.