Evolution of molten material in iron cores of small planets

A parent body of the Lovina meteorite underwent processes which yielded dentritic structures of taenite in phosphide-sulfide-metal matrix unusual for iron meteorites. Similar dendritic structures can be found also in IIE meteorites as microinclusions but are unknown in other iron meteorites. The similarity between dendritic structures in the Lovina meteorite and metal-phosphide inclusions in IIE iron meteorites implies similar processes which led to their crystallization from molten materials in chambers of various sizes. Studying physical and chemical crystallization parameters of metal-phosphide inclusions in the Elga meteorite (IIE) makes it feasible to estimate the p-T conditions required for the unique Lovina meteorite to have formed. It is shown that dendrites in the Lovina meteorite may have been crystallized from molten materials close in composition to P-FeNi and P-S-FeNi that are produced when phosphides and sulfides melt locally in metals as a result of impact events with subsequent fast cooling. The temperature of homogeneous melting is likely to have been more than 1450°C, and the starting temperature of crystallization of such molten materials is estimated to have been between 1050 and 1150°C. The cooling rate of inclusions can be estimated to be 10⁻³ °C s⁻¹, based on the structural and chemical concordance between samples obtained experimentally (Chabot et al., 2000) and metal-phosphide inclusions (P-FeNi and P-S-FeNi) in the Elga meteorite. Large-sized dendrites in the Lovina meteorite imply cooling rates that are considerably less than 10⁻³ °C s⁻¹.     

Rhenium-187—osmium-187 in iron meteorites and the strange origin of the Kodaïkanal meteorite

Abstract— A set of iron meteorites was investigated for Re-Os isotopes and provides a well-defined isochron age of 4.624 ± 0.017 Ba and an initial ¹⁸⁷Os/¹⁸⁸Os ratio of 0.095636 ± 0.00009. Actual ages may be a few percent lower due to uncertainty on the ¹⁸⁷Re decay constant. Within the small sample number presented here, there is no evidence for age differences between classes. A more detailed study of the meteorite Kodaïkanal shows that the metal reservoir of this meteorite formed approximately at the same time as the other iron meteorites, in contrast with the silicate inclusions which display a formation age of 3.67 Ba with all other chronometers. A collisional origin is in agreement with the data on this meteorite. Major secondary events do not affect the Re-Os system at the bulk rock scale in metal as it is the sole significant reservoir of these two elements. A Re-Os and Rb-Sr investigation of meteoritic troilite exhibits disturbed chronometric systems, which we attribute to the terrestrial history of the meteorite.     

Uranium isotopic composition and absolute ages of Allende chondrules

A handful of events, such as the condensation of refractory inclusions and the formation of chondrules, represent important stages in the formation and evolution of the early solar system and thus are critical to understanding its development. Compared to the refractory inclusions, chondrules appear to have a protracted period of formation that spans millions of years. As such, understanding chondrule formation requires a catalog of reliable ages, free from as many assumptions as possible. The Pb‐Pb chronometer has this potential; however, because common individual chondrules have extremely low uranium contents, obtaining U‐corrected Pb‐Pb ages of individual chondrules is unrealistic in the vast majority of cases at this time. Thus, in order to obtain the most accurate ²³⁸U/²³⁵U ratio possible for chondrules, we separated and pooled thousands of individual chondrules from the Allende meteorite. In this work, we demonstrate that no discernible differences exist in the ²³⁸U/²³⁵U compositions between chondrule groups when separated by size and magnetic susceptibility, suggesting that no systematic U‐isotope variation exists between groups of chondrules. Consequently, chondrules are likely to have a common ²³⁸U/²³⁵U ratio for any given meteorite. A weighted average of the six groups of chondrule separates from Allende results in a ²³⁸U/²³⁵U ratio of 137.786 ± 0.004 (±0.016 including propagated uncertainty on the U standard [Richter et al. 2010]). Although it is still possible that individual chondrules have significant U isotope variation within a given meteorite, this value represents our best estimate of the ²³⁸U/²³⁵U ratio for Allende chondrules and should be used for absolute dating of these objects, unless such chondrules can be measured individually.     

Terrestrial ages of ordinary chondrites from the Lewis Cliff stranding area,East Antarctica

Abstract— We determined terrestrial ages of ordinary chondrites from the Lewis Cliff stranding area, East Antarctica, on the basis of the concentrations of cosmogenic ¹⁰Be (t_½; = 1.51 Ma), ²⁶Al (t_½; = 0.705 Ma), and ³⁶Cl (t_½; = 0.301 Ma). After an initial ²⁶Al γ-ray survey of 91 meteorites suggested that many have terrestrial ages >0.1 Ma, we selected 62 meteorites for ¹⁰Be and ²⁶Al measurements by accelerator mass spectrometry (AMS) and measured ³⁶Cl in twelve of those. Low terrestrial ages (<0.1 Ma) were found for ～60% of the meteorites, whereas all others have ages between 0.1 and 0.5 Ma, except for one exceptional age of >2 Ma (Welten et al., 1997). Our major conclusions are: (1) The Lewis Cliff H-chondrites show similar ages to those from the Allan Hills icefields, but the L-chondrites are about a factor of 2 younger than those from Allan Hills, which indicates that Lewis Cliff is a younger stranding area. (2) The terrestrial age distributions at different parts of the Lewis Cliff stranding area generally agree with simple meteorite concentration models, although differences in weathering rate may also play a role. (3) We confirm that meteorites with natural thermoluminescence (TL) levels >80 krad are associated with low terrestrial ages (Benoit et al., 1992) but conclude that natural TL levels <80 krad can not be used to calculate the terrestrial age of a meteorite. Natural TL levels do seem useful to estimate relative terrestrial ages of large groups of meteorites and to determine differences in the surface exposure age of paired meteorite fragments. (4) Of the 62 meteorites measured with AMS, 31 were assigned to 11 different pairing groups, mainly on the basis of their cosmogenic nuclide record. The meteorites are estimated to represent between 42 and 52 distinct falls.     

Molecular and isotopic analyses of Tagish Lake alkyl dicarboxylic acids

Abstract— The Tagish Lake meteorite soluble organic suite has a general composition that differs from those of both CI and CM chondrites. These differences suggest that distinct processes may have been involved in the formation of different groups of organics in meteorites. Tagish Lake alkyl dicarboxylic acids have a varied, abundant distribution and are, with carboxylated pyridines, the only compounds to have an occurrence comparable to that of the Murchison meteorite. This study has undertaken their molecular and isotopic characterization, with the aim to understand their origin and to gain insights into the evolutionary history of the meteorite parent body. Tagish Lake alkyl dicarboxylic acids are present as a homologous series of saturated and unsaturated species with three‐ through ten‐carbon atom chain length. Linear saturated acids are predominant and show decreasing amounts with increasing chain length. A total of 44 of these compounds were detected with the most abundant, succinic acid, present at ?40 nmol/g meteorite. Overall the molecular distribution of Tagish Lake dicarboxylic acids shows a remarkable compound‐to‐compound correspondence with those observed in the Murchison and Murray meteorites. In both Tagish Lake and Murchison, the imides of the more abundant dicarboxylic acids were also observed. The hydrogen and carbon isotopic compositions of individual Tagish Lake dicarboxylic acids were determined and compared to those of the corresponding acids in the Murchison meteorite. All δD and δ¹³C values for Tagish Lake acids are positive and show a substantial isotopic enrichment. δD values vary from, approximately, +1120%_o for succinic acid to +1530%_o for methyl glutaric acid. δ¹³C values ranged from +12.6%_o for methyl glutaric acid to +22.9%_o for glutaric acid, with adipic acid having a significantly lower value (+5.5%_o). Murchison dicarboxylic acid showed similar isotopic values: their δ5¹³C values were generally higher by an average 17% and δD values were lower for succinic and glutaric acids, possibly due to contamination. The molecular and isotopic data collected for these compounds restrict their possible origin to processes, either interstellar or of very cold nebular regions, that produced significant isotopic enrichments. Saturated or partially unsaturated nitriles and dinitriles appear to be good precursor candidates as their hydrolysis, upon water exposure, would produce dicarboxylic acids and other carboxylated species found in Tagish Lake. This evolutionary course could possibly include pre‐accretionary processes.     

Itawa Bhopji (L3–5) chondrite regolith breccia: Fall,classification, and cosmogenic records

Abstract— A stony meteorite fell at Itawa Bhopji, Rajasthan, India on 2000 May 30. This is the fifth recorded fall in a small area of Rajasthan during the past decade. The meteorite is an ordinary chondrite with light clasts in a dark matrix, consisting of a mixture of equilibrated (mainly type 5) and unequilibrated components. Olivine is Fa_24–26 and pyroxene Fs_20–22 but, within the unequilibrated components, olivine (Fa_5–29) and low calcium pyroxene (Fs_5–37) are highly variable. Based on petrographic studies and chemical analyses, it is classified as L(3–5) regolith breccia. Studies of various cosmogenic records, including several gamma‐emitting radionuclides varying in half‐life from 5.6 day ⁵²Mn to 0.73 Ma ²⁶Al, tracks and rare gases have been carried out. The exposure age of the meteorite is estimated from cosmogenic components of rare gases to be 19.6 Ma. The track density varies by a factor of ?3 (from 4 to 12 times 10⁶/cm²) within the meteorite, indicating a preatmospheric body of ?9 cm radius (corresponding to a meteoroid mass of ?11 kg) and small ablation (1.5 to 3.6 cm). Trapped components in various rare gases are high and the solar component is present in the dark portion of the meteorite. Large excess of neutron‐produced ⁸²Kr and ¹²⁸Xe in both the light and the dark lithology but very low ⁶⁰Co, indicating low neutron fluxes received by the meteoroid in the interplanetary space, are clear signatures of an additional irradiation on the parent body.     

The 410,000 year terrestrial age of eucrite Río Cuarto 001

Abstract— We have measured a surprisingly long terrestrial age of 410,000 ±_45,00^20,000 yr (410 ±₂₀⁴⁵ka) for basaltic eucrite Río Cuarto 001 using accelerator mass spectrometry of ²⁶Al, ³⁶Cl, and ⁴¹Ca. Though many meteorites are known to have survived for tens or hundreds of ka in Antarctica or hot deserts, the mean annual precipitation of 815 mm in Río Cuarto, Cordoba Province, Argentina, makes the long survival of this meteorite remarkable. We propose two explanations for the exceptional preservation of Río Cuarto 001. First, the meteorite contains only trace amounts of metal, so the weathering and oxidation of metallic Fe, which commonly destroys chondrites, is ineffective in this case. Second, the meteorite was found in a relatively young deflation basin, and may have been exhumed only recently from beneath a protective layer of soil. Insofar as the survival on Earth of Río Cuarto 001 is due to environmental factors, there may be other meteorites with comparably long terrestrial ages still to be discovered in the vicinity.     

Glass production differences for equal-diameter impact craters

A thermodynamic model of meteorite impact is applied to determine if craters of equal diameter were necessarily created by events of similar thermal regimes. The particular case considered is that of a spherical basalt meteorite hitting a basalt target, and only two parameters are varied: impact velocity and meteorite radius. It is found that, in producing craters of equal diameter (20 cm), a small fast meteorite produces less melted and vaporized material, or tends to yield less glass, than does a large slow meteorite. Above 10 km s^–1 the amount of melted material is a monotonically decreasing function of impact velocity; above 20 km s^–1 the amount of vaporized material is a monotonically decreasing function of impact velocity. At 70 km s^–1 only 23% as much melt and vapor is produced as at 10 km s^–1, for events yielding equal crater diameters of 20 cm. According to the model used, this effect can be explained by observing that a meteorite with a small contact surface will deposit more heat and will produce a hotter but smaller amount of liquid than will a larger slower meteorite. Implications include, in principle, the possibility of estimating impact velocities by means of ejecta sample analysis.     

Cosmic‐ray exposure ages of chondrules

If chondrules were exposed to cosmic rays prior to meteorite compaction, they should retain an excess of cosmogenic noble gases. Beyersdorf‐Kuis et al. (2015) showed that such excesses can be detected provided that the chemical composition of each individual chondrule is precisely known. However, their study was limited to a few samples as they had to be irradiated in a nuclear reactor for instrumental neutron activation analysis. We developed a novel analytical protocol that combines the measurements of He and Ne isotopic concentrations with a fast method to correct for differences in chemical composition using micro X‐ray computed tomography. Our main idea is to combine noble gas, nuclear track, and petrography data for numerous chondrules to understand the precompaction exposure history of the chondrite parent bodies. Here, we report our results for a total of 77 chondrules and four matrix samples from NWA 8276 (L3.00), NWA 8007 (L3.2), and Bjurböle (L/LL4). All chondrules from the same meteorite have within uncertainty identical ²¹Ne exposure ages, and all chondrules from Bjurböle have within uncertainty identical ³He exposure ages. However, most chondrules from NWA 8276 and a few from NWA 8007 show small but resolvable differences in ³He exposure age that we attribute to matrix contamination and/or gas loss. The finding that none of the chondrules has noble gas excesses is consistent with the uniform track density found for each meteorite. We conclude that the studied chondrules did not experience a precompaction exposure longer than a few Ma assuming present‐day flux of galactic cosmic rays. A majority of chondrules from L and LL chondrites thus rapidly accreted and/or was efficiently shielded from cosmic rays in the solar nebula.     

Purely physical separation of a small fraction of the Allende meteorite that is highly enriched in noble gases

Abstract— Fine material that floats during freeze-thaw disaggregation of the Allende meteorite is greatly enriched in noble gases compared to the bulk meteorite. Not only the elemental concentrations, but also most isotopic ratios of the noble gases in this fraction, strongly suggest that this material is very similar to the gas-rich carbonaceous residue isolated from the bulk meteorite by chemical treatment. The only significant difference in noble gas signature between our separated fraction and the chemical residues is that the ¹²⁹Xe/¹³²Xe ratio in the former is significantly lower than that in the latter, which suggests readsorption of ¹²⁹Xe released from the dissolved minerals during the chemical treatment. This is the first time that a gas-rich residue of a meteorite has been separated by a purely physical method alone. We also show that noble gases in phase Q and presolar diamond may be separable physically, although both are closely associated.     

Do stony meteorites come from comets?

The place of origin of stony meteorites can be determined from their trapped solar-wind gases. “Gas-rich” meteorites have only 10^?3?10^?4 the solar noble gas content and ?10^?2?10^?4 the surface exposure age of lunar soils. These differences suggest that the gas implantation took place between 1 and 8 AU from the Sun, in a region where the cratering rate was 10²?10³ times higher than at 1 AU. Both characteristics point to the asteroid belt. The predicted Ne²⁰ content a gas-rich meteorite formed at 2.5 AU is 1.2 × 10^?5 cc STP g^?1, compared to an observed mean for H-chondrites of 0.5 × 10^?5 cc STP g^?1. The observed prevalence of gas-rich meteorites (40–100% among carbonaceous chondrites, 2–33% among other classes) requires that the parent body remained long enough in the asteroid belt to develop a substantial regolith. This condition can be met by asteroids (～ 10% of mass converted to regolith.in 4.5 × 10⁹ yr), but not by short period comets (～0.04% converted in 10⁷ yr). It appears that a cometary origin can be ruled out for all stony meteorite clases that have gas-rich members. This includes carbonaceous chondrites.     

Meteorites from meteor showers: A case study of the Taurids

We propose that the Taurid meteor shower may contain bodies able to survive and be recovered as meteorites. We review the expected properties of meteorite‐producing fireballs, and suggest that end heights below 35 km and terminal speeds below 10 km s^?1 are necessary conditions for fireballs expected to produce meteorites. Applying the meteoroid strength index (PE criteria) of Ceplecha and McCrosky (1976) to a suite of 33 photographically recorded Taurid fireballs, we find a large spread in the apparent meteoroid strengths within the stream, including some very strong meteoroids. We also examine in detail the flight behavior of a Taurid fireball (SOMN 101031) and show that it has the potential to be a (small) meteorite‐producing event. Similarly, photographic observations of a bright, potential Taurid fireball recorded in November of 1995 in Spain show that it also had meteorite‐producing characteristics, despite a very high entry velocity (33 km s^?1). Finally, we note that the recent Maribo meteorite fall may have had a very high entry velocity (28 km s^?1), further suggesting that survival of meteorites at Taurid‐like velocities is possible. Application of a numerical entry model also shows plausible survival of meteorites at Taurid‐like velocities, provided the initial meteoroids are fairly strong and large, both of which are characteristics found in the Taurid stream.     

An interdisciplinary study of weathering effects in ordinary chondrites from the Acfer region,Algeria

Abstract— Weathering effects on meteorite finds from the Acfer region were studied by various analytical techniques and in dependence on the depth of sampling. In thin sections of weathered meteorites, weathering effects usually decrease from the outside to the interior of the meteorite. The results of evolved gas analysis indicate that variation in weathering between surface and core is not significant in respect to the formation of Fe-oxyhydroxides. The secondary alteration effects in the noble gases are distributed unevenly throughout the specimens, as seen in the nonsystematic differences observed for the heavy noble gases. Chemical analyses show significant enrichment of Ba and Sr in the outer parts of the weathered samples due to element contamination through aqueous solution. Iron, Ni, and Co are partly flushed from the system as the metal oxidation proceeds. Oxygen isotopes show increases in δ¹⁸O and δ¹⁷O with increasing terrestrial age. For a set of H3 chondrites, the degree of weathering determined from the water content was correlated with terrestrial ages and is discussed with respect to possible weathering mechanisms.     

Campo del Cielo iron meteorite: Sample shielding and meteoroid's preatmospheric size

Abstract— Long‐lived cosmogenic radioisotopes, ¹⁰Be, ²⁶Al, ³⁶Cl, ⁴¹Ca and ⁵⁹Ni, have been measured in five samples from the Campo del Cielo iron meteorite by accelerator mass spectrometry (AMS). The ³⁶Cl activities were significantly above the background. For the concentrations of the other four radioisotopes, only upper limits were obtained that were, however, consistent with the ³⁶Cl result. The measured ³⁶Cl activity allowed an estimate of the meteoroid's preatmospheric size: a radius larger than 300 cm and a mass of at least 840 000 kg. We conclude that this meteorite might be one of the largest meteorites to have been recovered.     

A gamma‐ray spectroscopy survey of Omani meteorites

The gamma‐ray activities of 33 meteorite samples (30 ordinary chondrites, 1 Mars meteorite, 1 iron, 1 howardite) collected during Omani‐Swiss meteorite search campaigns 2001–2008 were nondestructively measured using an ultralow background gamma‐ray detector. The results provide several types of information: Potassium and thorium concentrations were found to range within typical values for the meteorite types. Similar mean ²⁶Al activities in groups of ordinary chondrites with (1) weathering degrees W0‐1 and low ¹⁴C terrestrial age and (2) weathering degree W3‐4 and high ¹⁴C terrestrial age are mostly consistent with activities observed in recent falls. The older group shows no significant depletion in ²⁶Al. Among the least weathered samples, one meteorite (SaU 424) was found to contain detectable ²²Na identifying it as a recent fall close to the year 2000. Based on an estimate of the surface area searched, the corresponding fall rate is ~120 events/10⁶ km²*a, consistent with other estimations. Twelve samples from the large JaH 091 strewn field (total mass ~4.5 t) show significant variations of ²⁶Al activities, including the highest values measured, consistent with a meteoroid radius of ~115 cm. Activities of ²³⁸U daughter elements demonstrate terrestrial contamination with ²²⁶Ra and possible loss of ²²²Rn. Recent contamination with small amounts of ¹³⁷Cs is ubiquitous. We conclude that gamma‐ray spectroscopy of a selection of meteorites with low degrees of weathering is particularly useful to detect recent falls among meteorites collected in hot deserts.     

Acfer 094, a uniquely primitive carbonaceous chondrite from the Sahara

Abstract— The Saharan meteorite Acfer 094 is a unique type of carbonaceous chondrite. Mineralogical and petrological considerations and O isotopes are unable to distinguish unambiguously between a CO3 vs. CM2 classification. The other important light elements, C and N, have systematics that do not match any previously recognised meteorite group. Particularly important in this respect is the very low C/N ratio and δ¹³C of the macromolecular C. Acfer 094 has more diamond and SiC, especially X type grains, than any other specimen studied, suggesting minimal thermal or aqueous processing to decrease its very primitive status.     

Did iron meteorites form in the asteroid belt?—Evidence from thermodynamic models

The major iron meteorite groups are defined essentially by their Ga, Ge, and Ni contents. It now seems clear that the differences between their abundances of Ga and Ge were produced by the process of condensation and accretion in the primordial solar nebula. The simplest interpretation of the Ni abundance, and its variations between the groups, is also that it was fixed during condensation and accretion; more particularly, it reflects the oxidation state of the nebula during condensation and accretion. The abundance patterns of 17 other trace elements have been examined and are consistent with this model. It is believed to be the simplest model published and most consistent with analogous calculations for the chondrites. If it is correct, then the iron meteorite groups formed over a very wide range of pressures, 10^?4 to 10^?8 atm. Such a range could only be found in a restricted region of the nebula, such as the asteroid belt, if a complex accretion sequence inside a protoplanet occurred. More likely, the iron meteorites were formed in widely dispersed regions of the nebula and only one group formed in the asteroid belt, probably group IIIAB. Groups IAB and IIAB formed nearer the Sun, and group IVA formed much further out, say, beyond the orbit of Jupiter.     

Meteorite falls in China and some related human casualty events

Abstract— Statistics of witnessed and recovered meteorite falls found in Chinese historical texts for the period from 700 B.C. to A.D. 1920 are presented. Several notable features can be seen in the binned distribution as a function of time. An apparent decrease in the number of meteorite reports in the 18th century is observed. An excess of observed meteorite falls in the period from 1840 to 1880 seems to correspond to a similar excess in European data. A x² probability test suggests that the association between the two data sets are real. Records of human casualties and structural damage resulting from meteorite falls are also given. A calculation based on the number of casualty events in the Chinese meteorite records suggests that the probability of a meteorite striking a human is far greater than previous estimates. However, it is difficult to verify the accuracy of the reported casualty events.     

Ararki (L5) chondrite: The first meteorite find in Thar Desert of India

Abstract— We report here a chance find of a meteorite in the sand dunes of Ararki village of Hanumangarh district in the Rajasthan desert of northwest India. Chemical and petrological evidence in conjunction with isotopic composition of oxygen indicate that it is an L5 chondrite. The fayalite content of olivines is 26.3 mol%. The meteorite has some serpentinized olivines and 0.3% carbon having a terrestrial isotopic composition, indicating that it is moderately weathered. The absence of ²²Na indicate that the meteorite fell to Earth more than a decade ago. The cosmic‐ray exposure age based on cosmogenic ²¹Ne is 7.2 Ma. Low density of cosmic‐ray heavy nuclei tracks, low ²⁶A1 activity, the shielding parameter [(²²Ne/²¹Ne)_C = 1.094] and absence of neutron capture effects indicate cosmic‐ray shielding in a meteoroid having radius of about 16 cm, implying a meteoroid mass of about 60 kg and ablation of about 93%. The gas retention ages, based on U/Th‐⁴He and K‐⁴⁰Ar are 1.1 and 0.58 Ga, respectively, suggesting a heating and degassing event late in the history of this meteorite.     

High spatial resolution ion microprobe measurements refine chronology of carbonate formation in Orgueil

Abstract— Aqueous activity on meteorite parent bodies is indicated by the presence of carbonates. High spatial resolution ion microprobe analyses of nine individual carbonate grains (four dolomites, five breunnerites) from the Orgueil meteorite reveal linear correlations between ⁵³Cr excesses and Mn/Cr ratios in all grains, indicative of in situ decay of radioactive ⁵³Mn (half‐life 3.7 million years). The well‐defined isochrons appear to have chronological significance. If this is the case, then ⁵³Mn/⁵⁵Mn ratios between 2.1 and 4.7 × 10^?6 are inferred for the time of carbonate formation and absolute ages of between 4561 and 4565 Ma are calculated (systematic uncertainty of ±2 Ma). Dolomites tend to have formed slightly earlier than the breunnerites. Our data imply extensive aqueous activity on the Orgueil parent body over a period of several million years, starting ～3–4 Myr after formation of the solar system, that most likely was the result of impact heating and latent heat from the decay of radioactive ²⁶Al and ⁶⁰Fe.