Laser probe argon-40/argon-39 dating of coesite- and stishovite-bearing pseudotachylytes and the age of the Vredefort impact event

Abstract— Age determinations have been made on pseudotachylytic rocks from the controversial Vredefort structure of South Africa using the laser microprobe ⁴⁰Ar/³⁹Ar dating technique. Coesite- and stishovitebearing veins in a quartzite from the Central Rand Group of the collar rocks were dated using a 10-μm diameter focused ultra-violet laser beam. These yielded a weighted mean age of 2027 ± 18 Ma (2σ). Six pseudotachylytes, sampled from four different locations within the Outer Granite Gneiss of the core, were dated using an 50–100-μm diameter focused infrared laser beam. These pseudotachylytes exhibit altered vein margins with apparent ages considerably younger than ages obtained from the fresher centres of veins. The best weighted mean pseudotachylyte matrix age obtained was 2018 ± 14 Ma (2σ). Most of the clasts within the pseudotachylyte matrices retain significantly older (e.g., Archean) ages, indicative of their parent rock history. Our results show that five of the seven dated samples possess matrix ages of ～2000 Ma, similar to the age of the Granophyre (Walraven et al., 1990), a supposed impact melt rock (French and Nielsen, 1990). The dating of coesite- and stishovite-bearing veins equates the shock event with pseudotachylyte formation, generation of the Granophyre and creation of the Vredefort structure. The results affirm that the Vredefort Dome is a meteorite impact structure and show that it formed at 2018 ± 14 Ma (2σ).     

Argon-40/argon-39 analyses of samples from the Gardnos impact structure,Norway

Abstract— We have conducted ⁴⁰Ar/³⁹Ar age dating on a sample of impact melt from the Gardnos impact structure in Norway in an attempt to better constrain the formation age of the crater. Current estimates of the age of the Gardnos crater cover a wide range and are as old as 900 Ma (Dons and Naterstad, 1992; French et al., 1997). The age spectra that we obtained from three samples are consistent with a thermal event at 385 ± 5 Ma (1σ). Because this differs greatly from the best stratigraphic age of ～600 Ma, and because the minerals present in the dated sample are a metamorphic assemblage, we believe we have not dated the formation age of the crater. Instead we have probably dated the effect of the early Devonian collapse of the late Caledonian (Scandian) orogeny on these materials (Dons and Naterstad, 1992; French et al., 1997). Although it may be possible, it will be difficult to determine the age of the impact by isotopic means alone because of this widespread metamorphism. Detailed stratigraphic analyses of the crater fill sediments may be the most promising method for constraining the crater age.     

40Ar/39Ar laser probe dating of the Central European tektite‐producing impact event

Abstract— A new ⁴⁰Ar/³⁹Ar data set is presented for tektites from the Central European strewn field (moldavites). This is the only strewn field that is entirely situated in a continental environment and still characterized by scattered ages (14–15.3 Myr). The main objectives of the study were to define more precisely the moldavite formation age and provide a good calibration for a glass standard proposed for fission‐track dating. The laser total fusion ages obtained on chips from 7 individual specimens from the Southern Bohemian and Moravian subfields are restricted to a narrow interval of time, with an average of 14.34 ± 0.08 Myr relative to the 27.95 ± 0.09 Myr of the Fish Canyon Tuff biotite. This result gives a more precise age not only for the tektite field but also for its producing impact. If the genetic link between the moldavites and the Nördlinger Ries impact crater is maintained, then this new age has to be considered a reliable estimate for the Ries crater also. This new value places the formation of Central European tektites within the Lower Serravallian period in the latest geologic timescales. Evidence of their impact products, such as glass spherules or shocked minerals, can, therefore, be sought in sedimentary marine formations in a more precisely defined age interval.     

The Basal Onaping Intrusion in the North Range: Roof rocks of the Sudbury Igneous Complex

The 1.85 Ga Sudbury impact structure is one of the largest impact structures on Earth. Igneous bodies—the so‐called “Basal Onaping Intrusion”—occur at the contact between the Sudbury Igneous Complex (SIC) and the overlying Onaping Formation and occupy ~50% of this contact zone. The Basal Onaping Intrusion is presently considered part of the Onaping Formation, which is a complex series of breccias. Here, we present petrological and geochemical data from two drill cores and field data from the North Range of the Sudbury structure, which suggests that the Basal Onaping Intrusion is not part of the Onaping Formation. Our observations indicate that the Basal Onaping Intrusion crystallized from a melt and has a groundmass comprising a skeletal intergrowth of feldspar and quartz that points to simultaneous cooling of both components. Increasing grain size and decreasing amounts of clasts with increasing depth are general features of roof rocks of coherent impact melt rocks at other impact structures and the Basal Onaping Intrusion. Planar deformation features within quartz clasts of the Basal Onaping Intrusion are indicators for shock metamorphism and, together with the melt matrix, point to the Basal Onaping Intrusion as being an impact melt rock, by definition. Importantly, the contact between Granophyre of the SIC and Basal Onaping Intrusion is transitional and we suggest that the Basal Onaping Intrusion is what remains of the roof rocks of the SIC and, thus, is a unit of the SIC and not the Onaping Formation. We suggest henceforth that this unit be referred to as the “Upper Contact Unit” of the SIC.     

The South Range Breccia Belt of the Sudbury Impact Structure: A possible terrace collapse feature

Abstract— The South Range Breccia Belt (SRBB) is an arcuate, 45 km long zone of Sudbury Breccia in the South Range of the 1.85 Ga Sudbury Impact Structure. The belt varies in thickness between tens of meters to hundreds of meters and is composed of a polymict assemblage of Huronian Supergroup (2.49–2.20 Ga), Nipissing Diabase (2.2 Ga), and Proterozoic granitoid breccia fragments ranging in size from a few millimeters to tens of meters. The SRBB matrix is composed of a fine‐grained (～100 μm) assemblage of biotite, quartz, and ilmenite, with trace amounts of plagioclase, zircon, titanite, epidote, pyrite, chalcopyrite, pyrrhotite, and occasionally chlorite. The SRBB hosts the Frood‐Stobie, Vermilion, and Kirkwood quartz diorite offset dykes, the former being associated with one of the largest Ni‐Cu‐PGE sulphide deposits in the world. Optical petrography and whole‐rock geochemistry concur with previous studies that have suggested that the matrix of the SRBB is derived from comminution and at least partial frictional melting of the wall rock Huronian Supergroup lithologies. Rare earth element (REE) data from all sampled lithologies associated with the SRBB exhibit crustal signatures when normalized to C1 chondrite values. Additionally, REE data from the quartz diorites, disseminated sulphides in Sudbury Breccia, and a sample of an aphanitic biotite‐hornblende tonalite dyke exhibit flat slopes when compared to the mafic and felsic norites, quartz gabbro, and granophyre units of the Sudbury Igneous Complex (SIC), which suggests that these lithologies are representative of bulk SIC melt. We suggest that the SRBB was formed by high strain‐rate (>1 m/s), gravity‐driven seismogenic slip of the inner ring of the Sudbury Impact Structure during postimpact crustal readjustment (crater modification stage). Failure of the hanging wall may have facilitated the injection of bulk SIC melt into the SRBB, along with the Ni‐Cu‐PGE sulphides of the Frood‐Stobie deposit. Postimpact Penokean (1.9–1.7 Ga) tectonism, particularly northwest‐directed shearing along the South Range Shear Zone and associated thrust faulting, could account for the present subvertical orientation of the SRBB, and the apparent lack of a connection at depth with the SIC.     

40Ar/39Ar dating of the Araguainha impact structure,Mato Grosso,Brazil

Abstract— Pursuing the exploration of the Araguainha impact structure (Engelhardt et al., 1992), we present ⁴⁰Ar/³⁹Ar ages (1) of biotite samples from the granite, which forms the central uplift of the structure, and (2) of a melt rock, formed by the impact. Total degassing ages of biotites from granite samples range from 326 to 481 Ma. The variation is explained by Ar losses due to the oxidation of divalent Fe and by removal of K. The K loss depends on the time that the granite was exposed to weathering at particular outcrops. The oldest age of the least oxidized biotite from a granite sample, collected at a site most recently exposed, signifies that the ascending granite passed the 300° isotherm earlier than 481 Ma ago. Early Devonian Furnas sandstones, the oldest sediments exposed by the impact, were deposited on this granite basement 410–396 Ma ago. The ⁴⁰Ar/³⁹Ar analyses of two size fractions of an impact melt rock, resulting in plateau ages of 245.5 ± 3.5 Ma and 243.3 ± 3.0 Ma, respectively, indicate that the Araguainha impact occurred close to the Permian-Triassic boundary.     

An acid-etch study of the Kapoeta achondrite: Implications for the argon-36/argon-38 ratio in the solar wind

Abstract— Noble gases were measured in the Kapoeta achondrite by means of step-wise closed-system acid-etching with H₂SO₃. Isotopic ratios indicate that He, Ne and Ar are primarily solar in origin, although elemental abundance ratios indicate that the He and Ne have been significantly depleted relative to the Ar. Xenon is dominated by a typical trapped meteoritic component, and the same is probably true for Kr. The initial 11% of the Ar released from the sample by acid etching has a cumulative ³⁶Ar/³⁸Ar ratio of 5.58 ± 0.03, which indicates that the solar wind at some time in the past had a ³⁶Ar/³⁸Ar ratio significantly above previous values suggested for this ratio.     

39Ar‐40Ar dating of the Zagami Martian shergottite and implications for magma origin of excess 40Ar

Abstract— The Zagami shergottite experienced a complex, petrogenetic formation history (McCoy et al. 1992, 1999). Like several shergottites, Zagami contains excess ⁴⁰Ar relative to its formation age. To understand the origin of this excess ⁴⁰Ar, we made ³⁹Ar‐⁴⁰Ar analyses on plagioclase and pyroxene minerals from two phases representing different stages in the magma evolution. Surprisingly, all these separates show similar concentrations of excess ⁴⁰Ar, ?1 × 10^?6 cm³/g. We present arguments against this excess ⁴⁰Ar having been introduced from the Martian atmosphere as impact glass. We also present evidence against excess ⁴⁰Ar being a partially degassed residue from a basalt that actually formed ?4 Gyr ago. We utilize our experimental data on Ar diffusion in Zagami and evidence that it was shock‐heated to only ?70 °C, and we assume this heating occurred during an ejection from Mars ?3 Myr ago. With these constraints, thermal considerations necessitates either that its ejected mass was impossibly large, or that its shock‐heating temperature was an order of magnitude higher than that measured. We suggest that this excess ⁴⁰Ar was inherited from the Zagami magma, and that it was introduced into the magma either by degassing of a larger volume of material or by early assimilation of old, K‐rich crustal material. Similar concentrations of excess ⁴⁰Ar in the analyzed separates imply that this magma maintained a relatively constant ⁴⁰Ar concentration throughout its crystallization. This likely occurred through volatile degassing as the magma rose toward the surface and lithostatic pressure was released. These concepts have implications for excess ⁴⁰Ar in other shergottites.     

Shock-induced melting and vaporization of shatter cone surfaces: Evidence from the Sudbury impact structure

Abstract— Analytical scanning electron microscopy has been used to investigate the surface textures and compositions of newly exposed shatter cones from the 1.85 Ga Sudbury impact structure, Canada. Unusual surface microstructures are observed at the micron scale, including silicate melt smears, melt fibres and melt splats. Silicate and Ni-rich spherules up to 5 μm in diameter adorn earlier-formed surface features, and we interpret these to be condensates formed due to shock-induced vaporization of the shatter cone surfaces. The development of striations on the shatter cones is attributed to shock-related fracture and slip. Formation of melts and spherules indicates that the highest ranks of shock metamorphism (Stages IV and V) were realized, but only on a very localized scale. Shatter cone surfaces are, therefore, likely sites for the development of high-pressure polymorphs and, if the chemistry is appropriate, fullerenes. As such, they may be equivalent to “Type A” pseudotachylytes and shock veins in meteorites.     

Floor-fractured crater models of the Sudbury Structure,Canada: Implications for initial crater size and crater modification

Abstract The pattern of radial and concentric offset dikes at Sudbury strongly resembles fracture patterns in certain volcanically modified craters on the Moon. Since the Sudbury dikes apparently formed shortly after the impact event, this resemblance suggests that early endogenic modification at Sudbury was comparable to deformation in lunar floor-fractured craters. Although regional deformation has obscured many details of the Sudbury Structure, such a comparison of Sudbury with lunar floor-fractured craters provides two alternative models for the original size and surface structures of the Sudbury basin. First, the Sudbury date pattern can be correlated with fractures in the central peak crater Haldane (36 km in diameter). This comparison indicates an initial Sudbury diameter of between 100 and 140 km but requires loss of a central peak complex for which there is little evidence. Alternatively, comparison of the Sudbury dikes with fractures in the two-ring basin Schrödinger indicates an initial Sudbury diameter of at least ～ 180 km, which is in agreement with other recent estimates for the size of the Sudbury Structure. In addition to constraining the size and structure of the original Sudbury crater, these comparisons also suggest that crater modification may reflect different deformation mechanisms at different sizes. Most lunar floor-fractured craters are attributed to deformation over a shallow, crater-centered intrusion; however, there is no evidence for such an intrusion at Sudbury. Instead, melts from the evolving impact melt sheet probably entered fractures formed by isostatically-induced flexure of the crater floor. Since most of the lunar floor-fractured craters are too small (<100-km diameter) to induce significant isostatic adjustment, crater modification by isostatic uplift apparently is limited to only the largest of craters, whereas deformation over igneous intrusions dominates the modification of smaller craters.     

40Ar‐39Ar studies of whole rock nakhlites: Evidence for the timing of formation and aqueous alteration on Mars

Abstract— 20–25 mg whole rock samples of the nakhlites Lafayette and Nakhla have been analyzed via the ⁴⁰Ar‐³⁹Ar technique, in part to verify their formation ages, but primarily, in an attempt to determine the timing of aqueous alteration in these martian meteorites. As in previous studies, plateaus in apparent age are observed at about 1300 Ma (1322 ± 10 for Lafayette, 1332 ± 10 and 1323 ± 11 for Nakhla), presumably corresponding to crystallization ages. The plateaus are not entirely flat, perhaps reflecting the effects of recoil during creation of ³⁹Ar in the nuclear irradiation. The first 5–20% of the K‐derived Ar released from all three samples give apparent ages <1300 Ma. Coupled with the fact that chronometric isotopic studies of nakhlites typically show some disturbance, we believe the low temperature pattern represents more recent (than 1300 Ma) formation of martian aqueous alteration products such as iddingsite. No low temperature plateaus are observed. This is consistent with petrographic evidence for multiple formation events, although the lack of low temperature plateaus is far from conclusive. On the other hand, if there was a single time of alteration, we believe that it will be difficult, if not impossible, to determine it using the K‐Ar system.     

40Ar/39Ar dating and cosmic‐ray exposure time of desert meteorites: Dhofar 300 and Dhofar 007 eucrites and anomalous achondrite NWA 011

Abstract— We performed high‐resolution ⁴⁰Ar‐³⁹Ar dating of mineral separates and whole‐rock samples from the desert meteorites Dhofar 300, Dhofar 007, and Northwest Africa (NWA) 011. The chronological information of all samples is dominated by plagioclase of varying grain size. The last total reset age of the eucrites Dhofar 300 and Dhofar 007 is 3.9 ± 0.1 Ga, coeval with the intense cratering period on the Moon. Some large plagioclase grains of Dhofar 007 possibly inherited Ar from a 4.5 Ga event characteristic for other cumulate eucrites. Due to disturbances of the age spectrum of NWA 011, only an estimate of 3.2–3.9 Ga can be given for its last total reset age. Secondary events causing partial ⁴⁰Ar loss ≤3.4 Ga ago are indicated by all age spectra. Furthermore, Ar extractions from distinct low temperature phases define apparent isochrons for all samples. These isochron ages are chronologically irrelevant and most probably caused by desert alterations, in which radiogenic ⁴⁰Ar and K from the meteorite and occasionally K induced by weathering are mixed, accompanied by incorporation of atmospheric Ar. Additional uptake of atmospheric Ar by the alteration phase(s) was observed during mineral separation (i.e., crushing and cleaning in ultrasonic baths). Consistent cosmic‐ray exposure ages were obtained from plagioclase and pyroxene exposure age spectra of Dhofar 300 (25 ± 1 Ma) and Dhofar 007 (13 ± 1 Ma) using the mineral's specific target element chemistry and corresponding ³⁸Ar production rates.     

Origin and emplacement of Offset Dykes in the Sudbury impact structure: Constraints from Hess

Abstract— The Hess Offset is a steeply dipping dyke located 12–15 km north of the 1.85 Ga Sudbury igneous complex (SIC) within the 200–250 km diameter Sudbury impact structure. It is up to 60 m wide and strikes subconcentrically to the SIC for at least 23 km. The main phase of the dyke is granodioritic, but it conforms with what is locally referred to as Quartz Diorite: a term used for all the Offset Dykes of the Sudbury impact structure. Rare earth element data shows that the Hess Offset is genetically related to the SIC. Hess is most closely affiliated with an evolved Felsic Norite component of SIC and not bulk impact melt. This indicates that Hess was emplaced during fractionation of the impact melt sheet, rather than immediately following impact. The main Quartz Diorite phase of the dyke comprises a quartz + plagioclase + hornblende + biotite ± clinopyroxene ± orthopyroxene assemblage. Critically, the Hess Offset occupies a concentric fault system that marks the northern limit of a pseudotachylyte-rich, shatter cone-bearing annulus about the SIC. This fault system was active during the modification stage of the impact process.     

A Late Mesoproterozoic 40Ar/39Ar age for a melt breccia from the Keurusselkä impact structure,Finland

Field investigations in the eroded central uplift of the ≤30 km Keurusselkä impact structure, Finland, revealed a thin, dark melt vein that intersects the autochthonous shatter cone‐bearing target rocks near the homestead of Kirkkoranta, close to the center of the impact structure. The petrographic analysis of quartz in this melt breccia and the wall rock granite indicate weak shock metamorphic overprint not exceeding ~8–10 GPa. The mode of occurrence and composition of the melt breccia suggest its formation as some kind of pseudotachylitic breccia. ⁴⁰Ar/³⁹Ar dating of dark and clast‐poor whole‐rock chips yielded five concordant Late Mesoproterozoic miniplateau ages and one plateau age of 1151 ± 10 Ma [± 11 Ma] (2σ; MSWD = 0.11; P = 0.98), considered here as the statistically most robust age for the rock. The new ⁴⁰Ar/³⁹Ar age is incompatible with ~1.88 Ga Svecofennian tectonism and magmatism in south‐central Finland and probably reflects the Keurusselkä impact, followed by impact‐induced hydrothermal chloritization of the crater basement. In keeping with the crosscutting relationships in the outcrop and the possible influence of postimpact alteration, the Late Mesoproterozoic ⁴⁰Ar/³⁹Ar age of ~1150 Ma should be treated as a minimum age for the impact. The new ⁴⁰Ar/³⁹Ar results are consistent with paleomagnetic results that suggested a similar age for Keurusselkä, which is shown to be one of the oldest impact structures currently known in Europe and worldwide.     

Coeval argon‐40/argon‐39 ages of moldavites from the Bohemian and Lusatian strewn fields

Abstract— ⁴⁰Ar/³⁹Ar ages of four tektites (moldavites) from southern Bohemia (near ?eské Budějovice, Czech Republic) and a tektite from Lusatia (near Dresden, Germany) have been determined by 11 step‐degassing experiments. The purpose of the study was to enlarge the ⁴⁰Ar/³⁹Ar data base of moldavites and to check the age relations of the Bohemian and Lusatian samples. The mean plateau‐age of the Bohemian samples, which range from 14.42 to 14.70 Ma, is 14.50 ± 0.16 (0.42) (2σ) Ma (errors in parentheses include age error and uncertainty of standard monitor age). The plateau age of the Lusatian sample of 14.38 ± 0.26 (0.44) (2σ) Ma confirms the previously published ⁴⁰Ar/³⁹Ar age of 14.52 ± 0.08 (0.40) (2σ) Ma, and demonstrates that the fall of Lusatian and Bohemian tektites were contemporaneous. Because of their geochemistry and their ages there is no doubt that the Lusatian tektites are moldavites. Accepting that moldavites are ejecta from the Nördlinger Ries impact, the new ages also date the impact event. This age is slightly younger (about 0.2–0.3 Ma) than the age suggested by earlier K‐Ar determinations.     

Laser argon dating of melt breccias from the Siljan impact structure,Sweden: Implications for a possible relationship to Late Devonian extinction events

Abstract— In earlier studies, the 65‐75 km diameter Siljan impact structure in Sweden has been linked to the Late Devonian mass extinction event. The Siljan impact event has previously been dated by K‐Ar and Ar‐Ar chronology at 342‐368 Ma, with the commonly quoted age being 362.7 ± 2.2 Ma (2 s?, recalculated using currently accepted decay constants). Until recently, the accepted age for the Frasnian/Famennian boundary and associated extinction event was 364 Ma, which is within error limits of this earlier Siljan age. Here we report new Ar‐Ar ages extracted by laser spot and laser step heating techniques for several melt breccia samples from Siljan (interpreted to be impact melt breccia). The analytical results show some scatter, which is greater in samples with more extensive alteration; these samples generally yield younger ages. The two samples with the least alteration yield the most reproducible weighted mean ages: one yielded a laser spot age of 377.2 ± 2.5 Ma (95% confidence limits) and the other yielded both a laser spot age of 376.1 ± 2.8 Ma (95% confidence limits) and a laser stepped heating plateau age over 70.6% ³⁹Ar release of 377.5 ± 2.4 Ma (2 s?). Our conservative estimate for the age of Siljan is 377 ± 2 Ma (95% confidence limits), which is significantly different from both the previously accepted age for the Frasnian/Famennian (F/F) boundary and the previously quoted age of Siljan. However, the age of the F/F boundary has recently been revised to 374.5 ± 2.6 Ma by the International Commission for Stratigraphy, which is, within error, the same as our new age. However, the currently available age data are not proof that there was a connection between the Siljan impact event and the F/F boundary extinction. This new result highlights the dual problems of dating meteorite impacts where fine‐grained melt rocks are often all that can be isotopically dated, and constraining the absolute age of biostratigraphic boundaries, which can only be constrained by age extrapolation. Further work is required to develop and improve the terrestrial impact age record and test whether or not the terrestrial impact flux increased significantly at certain times, perhaps resulting in major extinction events in Earth's biostratigraphic record.     

New Evidence for the Complex Structure of the Red Giant Branch in omega Centauri

We report on the complex structure of the red giant branch (RGB) of omega Centauri, based on a new wide-field and wide-color baseline B and I photometry. Our color-magnitude diagram (CMD) shows the presence of multiple populations along this branch; in particular, we discovered an anomalous branch (RGB-a), which appears to be well separated from the bulk of the RGB stars. On the basis of our CMD and from the previous literature, we conclude that (1) these stars, clearly identified as a separate population in our CMD, represent the extreme metal-rich extension (&sqbl0;Ca&solm0;H&sqbr0;>-0.3) of the stellar content of omega Cen and show anomalous abundances of s-process elements (as Ba and Zr) as well; (2) they are physical members of the omega Cen system; (3) they comprise approximately 5% of the stars of the whole system; and (4) this component and the metal intermediate one (-0.4>&sqbl0;Ca&solm0;H&sqbr0;>-1) have been found to share the same spatial distribution, both of them differing significantly from the most metal-poor one (&sqbl0;Ca&solm0;H&sqbr0;<-1). This last piece evidence supports the hypothesis that metal-rich components could belong to an independent (proto?) stellar system captured in the past by omega Cen.     

Dark inclusions in the Mokoia CV3 chondrite: Evidence for aqueous alteration and subsequent thermal and shock metamorphism

Abstract— Mokoia is a CV3 chondrite that contains abundant phyllosilicate mineralization. We present a detailed petrographic and scanning electron microscopic study of 24 dark inclusions (DIs) that we found in Mokoia. The overall texture and constituent minerals of the DIs resemble those in the host meteorite. Fe‐bearing saponite and Na‐rich phlogopite, the same phyllosilicates as in the host meteorite, occur in the DIs, which strongly suggests that the DIs have a similar alteration history to the host meteorite. However, the DIs show several distinct differences from the host meteorite. Olivine grains in the DI matrices are more homogeneous in Fe/(Fe + Mg) ratio than those in the host meteorite matrix. Phyllosilicates in the DIs are less abundant than in the host meteorite, and they have been dehydrated to various extents. These characteristics suggest that the DIs have experienced higher degree of thermal metamorphism than the host meteorite. In addition, the matrices in the DIs are more compacted than those in the host meteorite. Most olivine grains in the DIs show undulatory extinction in transmitted crossed‐polarized light and some show planar fractures, while such olivine grains are rare in the host meteorite. Two of the DIs contain Si‐, Mg‐, Fe‐ and O‐rich melt veins. These characteristics indicate that most DIs have been shocked to shock stage S3‐S4, while the host meteorite is shock stage S1 (virtually unshocked). Thermal metamorphism of the DIs was likely caused by shock heating. These results are consistent with the contention previously proposed for the DIs in CV3 chondrites (i.e., the DIs have experienced aqueous alteration and subsequent dehydration on the CV parent body). We suggest that thermal and shock metamorphism occurred locally to various extents after pervasive aqueous alteration in the Mokoia parent body.     

The Ar‐Ar age and petrology of Miller Range 05029: Evidence for a large impact in the very early solar system

Abstract– Miller Range (MIL) 05029 is a slowly cooled melt rock with metal/sulfide depletion and an Ar‐Ar age of 4517 ± 11 Ma. Oxygen isotopes and mineral composition indicate that it is an L chondrite impact melt, and a well‐equilibrated igneous rock texture with a lack of clasts favors a melt pool over a melt dike as its probable depositional setting. A metallographic cooling rate of approximately 14 °C Ma^?1 indicates that the impact occurred at least approximately 20 Ma before the Ar‐Ar closure age of 4517 Ma, possibly even shortly after accretion of its parent body. A metal grain with a Widmanstätten‐like pattern further substantiates slow cooling. The formation age of MIL 05029 is at least as old as the Ar‐Ar age of unshocked L and H chondrites, indicating that endogenous metamorphism on the parent asteroid was still ongoing at the time of impact. Its metallographic cooling rate of approximately 14 °C Ma^?1 is similar to that typical for L6 chondrites, suggesting a collisional event on the L chondrite asteroid that produced impact melt at a minimum depth of 5–12 km. The inferred minimum crater diameter of 25–60 km may have shattered the 100–200 km diameter L chondrite asteroid. Therefore, MIL 05029 could record the timing and petrogenetic setting for the observed lack of correlation of cooling rates with metamorphic grades in many L chondrites.     

Petrogenetic models for magmatism on the eucrite parent body: Evidence from orthopyroxene in diogenites

Abstract— Diogenites are recognized as a major constituent of the howardite, eucrite and diogenite (HED) meteorite group. Recently, several papers (Mittlefehldt, 1994; Fowler et al, 1994, 1995) have identified trace-element systematics in diogenites that appeared to mimic simple magmatic processes that involved large degrees of crystallization (up to 95% orthopyroxene) of basalt with extremely high normative hypersthene. Such a crystallization scenario linking all the diogenites is highly unlikely. The purpose of this study is to explore other possible models relating the diogenites. Computational major-element melting models of a variety of different potential bulk compositions for the eucrite parent body (EPB) mantle indicate that these compositions show a similar sequence in residuum mineral assemblage with increasing degrees of partial melting. Numerous bulk compositions would produce melts with Mg# appropriate for diogenitic parent magmas at low to moderate degrees of partial melting (15% to 30%). These calculations also show that melts with similar Mg# and variable incompatible element concentrations may be produced during small to moderate degrees of EPB mantle melting. The trace-element characteristic of the orthopyroxene in diogenites does not support a model for large amounts of fractional crystallization of a single “hypersthene normative” basaltic magma following either small-scale or large-scale EPB mantle melting. Small degrees of fractional crystallization of a series of distinct basaltic magmas are much more likely. Only two melting models that we considered hold any promise for producing different batches of “diogenitic magmas.” The first model involves the fractional melting of a homogeneous source that produces parental magmas to diogenites with an extensive range of incompatible elements and limited variations in Mg#. There are several requirements for this model to work. The first requirement of this model is that the D^{orthopyroxene/melt} must change during melting or crystallization to compress the range of incompatible elements in the calculated diogenitic magmas. The second prerequisite is that either some of the calculated diogenitic magmas are parental to eucrites or the Mg# in diogenitic magmas are influenced by slight changes in oxygen fugacity during partial melting. The second model involves batch melting of a source that reflects accretional heterogeneities capable of generating diogenitic magmas with the calculated Mg# and incompatible element contents. Both of these models require small to moderate degrees of partial melting that may limit the efficiency of core separation.