Geochronological,geochemical and Pb isotopic compositions of Tasmanian granites (southeast Australia): Controls on petrogenesis,geodynamic evolution and tin mineralisation

Large volumes of Devonian-Carboniferous granites were emplaced across Tasmania in southeast Australia, which was along the easternmost boundary of mid-Palaeozoic Gondwana. Some of these granites are associated with world class Sn–W deposits. Previous studies have focused mainly on relationships between granite petrogenesis and source rocks, and rarely on geochemical controls on Sn mineralisation. New zircon U-Pb ages of 405 to 396 Ma reveal that the George River Granodiorite, Grant Point Granite and Mt. Pearson Granite from eastern Tasmania intruded prior to the Tabberabberan Orogeny. The Coles Bay Granite has a U-Pb age of 388 ± 7 Ma, implying that it was emplaced simultaneously with the Tabberabberan Orogeny in Tasmania. The western Tasmanian granites mostly intruded from 374 to 360 Ma, after the Tabberabberan Orogeny. Granites associated with Sn–W deposits are moderately to strongly fractionated, including the Housetop, Meredith, Pine Hill and Heemskirk granites. Lead isotopic compositions of K-feldspars from the analysed granites, combined with isotopic evidence from other studies, suggest that differentiated granites in Tasmania had been highly contaminated by a crustal (sedimentary) component, and that western Tasmanian granites had a crustal source with substantially different isotopic characteristics to that of eastern Tasmania, which has a character similar to the Lachlan Orogen in southeast Australia. Tin-mineralised granites in Tasmania formed in a post-collisional extensional margin, a favourable environment for the production of Sn-rich melts from the lower crust. Prolonged fractional crystallisation, low oxygen fugacity and enrichments of volatiles are crucial factors to promote Sn enrichment in magmatic-hydrothermal fluids exsolved from crystallised felsic magmas.     

Ages of sediment-hosted Himalayan Pb–Zn–Cu–Ag polymetallic deposits in the Lanping basin,China: Re–Os geochronology of molybdenite and Sm–Nd dating of calcite

The Lanping basin is a significant Pb–Zn–Cu–Ag mineralization belt of the Sanjiang Tethyan metallogenic province in China. Over 100 thrust-controlled, sediment-hosted, Himalayan base metal deposits have been discovered in this basin, including the largest sandstone-hosted Pb–Zn deposit in the world (Jinding), and several Cu ± Ag ± Co deposits (Baiyangping, Baiyangchang and Jinman). These deposits, with total reserves of over 16.0 Mt Pb + Zn, 0.6 Mt Cu, and 7000 t Ag, are mainly hosted in Meso-Cenozoic mottled clastic rocks, and strictly controlled by two Cenozoic thrust systems developed in the western and eastern segments of the Lanping basin.To define the metallogenic history of the study area, we dated nine calcite samples associated with copper sulfides from the Jinman Cu deposit by the Sm–Nd method and five molybdenite samples from the Liancheng Cu–Mo deposit by the Re–Os method. The calcite Sm–Nd age for the Jinman deposit (58 ± 5 Ma) and the molybdenite Re–Os age for the Liancheng deposit (48 ± 2 Ma), together with previously published chronological data, demonstrate (1) the Cu–Ag mineralization in the western Lanping basin mainly occurred in three episodes (i.e., ∼56–54, 51–48, and 31–29 Ma), corresponding to the main- and late-collisional stages of the Indo–Asian orogeny; and (2) the Pb–Zn–Ag (±Cu) mineralization in the eastern Lanping basin lacked precise and direct dating, however, the apatite fission track ages of several representative deposits (21 ± 4 Ma to 32 ± 5 Ma) may offer some constraints on the mineralization age.     

Tectono-sequence stratigraphy and U–Pb zircon ages of the Rincón Blanco Depocenter,northern Cuyo Rift,Argentina

Extensional processes that followed the Gondwanan Orogeny rise to the development of a series of rift basins along the continental margin over older accreted Eopaleozoic terranes. Stratigraphic, structural, paleontological, and isotopic studies are presented in this work in order to constrain the ages of the sedimentary infilling and to analyze the tectosedimentary evolution of one of the Cuyo basin depocenters, known as Rincón Blanco. This asymmetrical half-graben was filled by continental sediments under a strong tectonic control. The infilling was strongly controlled by tectonics which in term produced distinctive features along the whole sedimentary sequence. Using a combination of lithological and structural data the infilling was subdivided into packages of genetically linked units bounded by regional extended surfaces. Several tuffs and acid volcanic rocks have been collected across the whole section of the Rincon Blanco sub-basin for SHRIMP and LA-MC-ICPMS U–Pb zircon dating. The ages obtained range from 246.4 ± 1.1 Ma to 230.3 ± 1.5 Ma which is the time elapsed for the deposition of three tectono-sequence units separated by regional unconformities and mainly constrained to the Middle Triassic. They are interpreted as a result of a reactivation of the extensional system that has evolved along strike as segments of faults that linked together and/or as laterally propagating faults. Regional correlation with coeval rift basins permits to establish north-south propagation in the extensional regime along the western margin of SW Gondwana. This trending started in the lowermost Triassic and extended until the latest Triassic. Two of them were precisely correlated with Cerro Puntudo and Cacheuta half-graben systems. The new data indicate that the three sequences were mostly deposited during the Middle Triassic (246 to 230 Ma), with no evidence of sedimentation during Norian and Rhaetian, which is in conflict with some previous biostratigraphic studies.     

The Paleoproterozoic Wernecke Supergroup of Yukon,Canada: Relationships to orogeny in northwestern Laurentia and basins in North America,East Australia,and China

The Paleoproterozoic Wernecke Supergroup of Yukon was deposited when the northwestern margin of Laurentia was undergoing major adjustments related to the assembly of the supercontinent Columbia (Nuna) from 1.75 to 1.60 Ga. U–Pb detrital zircon geochronology coupled with Nd isotope geochemistry and major and trace element geochemistry are used to characterize the evolution of the Wernecke basin. The maximum depositional age of the Wernecke Supergroup is reevaluated and is estimated at 1649 ± 14 Ma. Detrital zircon age spectra show a bimodal age distribution that reflects derivation from cratonic Laurentia, with a prominent peak at 1900 Ma. Going upsection, the late Paleoproterozoic peak shifts from 1900 Ma to 1850–1800 Ma, and the proportion of Archean and early Paleoproterozoic zircon decreases. These modifications are a consequence of a change in the drainage system in western Laurentia caused by early phase of the Forward orogeny, several hundred km to the east. The exposed lower and middle parts of the Wernecke Supergroup are correlated with the Hornby Bay Group. Zircon younger than 1.75 Ga appear throughout the sedimentary succession and may have originated from small igneous suites in northern Laurentia, larger source regions such as magmatic arc terranes of the Yavapai and early Mazatzal orogenies in southern Laurentia, and possible arc complexes such as Bonnetia that may have flanked the eastern margin of East Australia. Basins with similar age and character include the Tarcoola Formation (Gawler Craton) and the Willyama Supergroup (Curnamona Province) of South Australia, the Isan Supergroup of North Australia, and the Dongchuan–Dahongshan–Hondo successions of southeast Yangtze Craton (South China). Nd isotope ratios of the Wernecke Supergroup are comparable with values from Proterozoic Laurentia, the Isan and Curnamona assemblages of east Australia, the Gawler Craton, and the Dahongshan–Dongchuan–Hondo successions of the Yangtze Craton of South China. These similarities are compelling evidence for a shared depositional system among these successions. Western Columbia in the Late Paleoproterozoic may have had a dynamic SWEAT-like configuration involving Australia, East Antarctica and South China moving along western Laurentia.     

Geodynamic setting of Mesozoic magmatism in NE China and surrounding regions: Perspectives from spatio-temporal distribution patterns of ore deposits

North-eastern China and surrounding regions host some of the best examples of Phanerozoic juvenile crust on the globe. However, the Mesozoic tectonic setting and geodynamic processes in this region remain debated. Here we attempt a systematic analysis of the spatio-temporal distribution patterns of ore deposits in NE China and surrounding regions to constrain the geodynamic milieu. From an evaluation of the available geochronological data, we identify five distinct stages of ore formation: 240–205 Ma, 190–165 Ma, 155–145 Ma, 140–120 Ma, and 115–100 Ma. The Triassic (240–205 Ma) magmatism and associated mineralisation occurred during in a post-collisional tectonic setting involving the closure of the Paleo-Asian Ocean. The Early-Mid Jurassic (190–165 Ma) events are related to the subduction of the Paleo-Pacific Ocean in the eastern Asian continental margin, whereas in the Erguna block, these are associated with the subduction of the Mongol–Okhotsk Ocean. From 155 to 120 Ma, large-scale continental extension occurred in NE China and surrounding regions. However, the Late Jurassic magmatism and mineralisation events in these areas evolved in a post-orogenic extensional environment of the Mongol–Okhotsk Ocean subduction system. The early stage of the Early Cretaceous events occurred under the combined effects of the closure of the Mongol–Okhotsk Ocean and the subduction of the Paleo-Pacific Ocean. The widespread extension ceased during the late phase of Early Cretaceous (115–100 Ma), following the rapid tectonic changes resulting from the Paleo-Pacific Oceanic plate reconfiguration.     

Genesis of the Dadonggou Pb–Zn deposit in Kelan basin,Altay, NW China: Constraints from zircon U–Pb and biotite 40Ar/39Ar geochronological data

The genesis of polymetallic deposits in southern Altay, NW China has been disputed between a syngenetic seafloor hydrothermal process and an epigenetic orogenic-type mineralization. The Dadonggou Pb–Zn deposit occurs as NW-trending veins in the Devonian Kangbutiebao Formation volcanic-sedimentary sequence in the Kelan basin, southern Altay. A set of integrated zircon U–Pb and biotite ⁴⁰Ar/³⁹Ar geochronological data were applied to constrain the forming ages of the ores and their country rocks. Three samples of host volcanic rocks yielded weighted mean ²⁰⁶Pb/²³⁸U ages of 397.1 ± 4.5 Ma, 391.7 ± 3.6 Ma and 391.1 ± 4.2 Ma, respectively, indicating that the Kangbutiebao Formation was deposited in a Devonian back-arc basin. Two biotite samples separated from the Pb–Zn-containing quartz veins yielded ⁴⁰Ar/³⁹Ar plateau ages of 205.9 ± 2.1 Ma and 204.3 ± 2.2 Ma, respectively, which represent the age of the Pb–Zn mineralization that is attributed to the closure of the Kelan back-arc basin and the Late Triassic orogeny. Combining the available geological and geochronological data, this contribution outlines the successive evolution from the development of a Devonian back-arc basin to the Late Triassic post-subduction orogeny, and proposes that the Dadonggou Pb–Zn deposit is an epigenetic orogenic-type deposit placed in the Late Triassic orogeny.     

Geochronological and isotopic constraints on Palaeoproterozoic skarn base metal mineralisation in the central Gawler Craton,South Australia

The mineralisation potential of Palaeoproterozoic strata from the central Gawler Craton, South Australia, is poorly known. This study defines the timing of Zn-rich skarn formation within Palaeoproterozoic calcsilicate and highlights this as a new mineralisation style for the Gawler Craton. Sulphides within the garnet–diopside skarn in the No. 17 Bore Prospect are predominantly in the form of sphalerite, associated with galena, minor chalcopyrite, pyrrhotite and pyrite. Sulphide is present in disseminated form and as a coarse-grained sulphide within a sericite-rich cavity-fill. Mineralisation is inferred to have formed at 1710 ± 16 Ma through a Sm–Nd isochron from garnet and diopside aliquots. A weakly mineralised and altered granite immediately below the calcsilicate skarn crystallised at 1729 ± 13 Ma (LA-ICPMS U–Pb zircon), within error of the skarn mineralisation. The skarn is interpreted to have formed through the initiation of fluid circulation as a result of high-level granite emplacement within the Palaeoproterozoic strata. Exploration for skarn Zn–Pb deposits such as the No. 17 Bore Prospect is assisted by their geophysical properties.     

Volcanism,mineralization and metamorphism at the Xitieshan Pb–Zn deposit,NW China: Insights from zircon geochronology and geochemistry

The footwall volcanic rocks of the Ordovician Tanjianshan Group in the world-class Xitieshan Pb–Zn deposit have experienced prolonged arc volcanism followed by strong metamorphism and deformation. This has resulted in a complex thermal history and led to ambiguity in interpretation of zircon geochronological results. An integrated study involving textural characterization, CL imaging, trace element analysis, Ti-in-zircon thermometry and LA-ICPMS U–Pb dating has provided tight constraints on the age and genesis of the zircon groups in the volcanic rocks. The temperature of metamorphism and deformation indicated by metacryst minerals and micro-structures in the volcanic rocks ranges from 550 to 650 °C, which partially overlaps with the lower temperature range of zircon crystallization (600–750 °C) calculated using the Ti-in-zircon thermometer. Cathodoluminescence images and trace element compositions confirm a magmatic origin for the zircons, which have also been variably altered by metamorphic fluids. Two ranges of U–Pb ages, 475–470 Ma and 460–450 Ma, have been obtained on typical magmatic zircons and are interpreted to represent pre-mineralization arc volcanism in the Xitieshan deposit. A younger age group of 440–430 Ma for the fluid-modified zircons is considered to record post-ore metamorphism during the North Qadaim Orogeny. Thus, we propose that the original exhalative ores at the Xitieshan Pb–Zn deposit formed at 450–440 Ma.     

Chronostratigraphic basin framework for Palaeoproterozoic rocks (1730–1575 Ma) in northern Australia and implications for base‐metal mineralisation

Sequence‐stratigraphic interpretations of outcrop, drillcore, wireline and seismic datasets are integrated with SHRIMP zircon and palaeomagnetic determinations to provide a detailed chrono‐stratigraphic basin framework for the base‐metal‐rich Palaeoproterozoic rocks of the southern McArthur, Lawn Hill and Mt Isa regions. The analysis forms a basis for future correlations across northern Australia. Nine second‐order unconformity‐bounded supersequences are identified. Supersequences have a duration of 10–20 million years; some hitherto‐unrecognised unconformity surfaces record up to 25 million years of missing rock record. The second‐order supersequences contain a series of nested third‐, fourth‐ and fifth‐order sequences many of which can be correlated across the Mt Isa, Lawn Hill and southern McArthur regions. The analysis relates accommodation history to major intraplate tectonic events evident on the apparent polar wander path for northern Australia. Major tectonic events at approximately 1735 Ma, 1700 Ma, 1670 Ma, 1650 Ma, 1640 Ma, 1615 Ma, 1600 Ma and 1575 Ma impacted on accommodation rates and basin shape in northern Australia. Sub‐basin depocentres, the hosts for major sulfide mineralisation, are attributed to reactivated faults that controlled local subsidence. Pb/Pb model ages of 1653 Ma, 1640 Ma and 1575 Ma for the Mt Isa, McArthur River and Century Pb–Zn–Ag deposits, suggest that changes to intraplate stresses at tectonic events of like age resulted in the migration of metal‐bearing fluids into the sub‐basins. A Pb/Pb model age of 1675 for the Broken Hill deposit suggests that intraplate stresses manifest in northern Australia also affected rocks of similar age further south. Magmatic events close to 1700 Ma (Weberra Granite) and 1675 Ma (Sybella Granite) coincide with times of regional incision and the formation of supersequence‐bounding unconformity surfaces.     

Re–Os and U–Pb geochronology of the Shazigou Mo polymetallic ore field,Inner Mongolia: Implications for Permian–Triassic mineralization at the northern margin of the North China Craton

The recently discovered polymetallic Shazigou Mo–W–Pb–Zn ore field is located at the northern margin of the North China Craton. This integrated metallogenic system is comprised of quartz vein mineralization in three deposits: Shazigou Mo–W, Jindouzishan Pb–Zn and Mantougou Pb–Zn. The total reserves are estimated to be 50 kt Mo, 626 t WO₃, 244 kt Pb and 150 kt Zn. Molybdenite Re–Os dating of five quartz vein-type ores yielded a mean model age of 243.8 ± 1.6 Ma (MSWD = 0.81) and hydrothermal zircons yielded a concordant U–Pb age of 245 ± 2.6 Ma (MSWD = 0.65). These results suggest that the mineralization was formed in the early Triassic and could be related to Paleo-Asian Ocean subduction. Microthermometry and quartz fluid inclusion compositions indicate that fluids related to the Mo–W mineralization were mainly derived from magmatic sources and precipitated under relatively high temperature (280–340 °C) and salinity conditions (6–9 wt% NaCl equiv.), whereas subsequent Pb–Zn mineralization-related fluids may have been modified by metamorphic and meteoric waters. The discovery of the Shazigou ore field suggests conditions may be favourable for more extensive mineralization in the western Xilamulun Mo metallogenic belt at the northern margin of the North China Craton.     

Detrital mineral age,radiogenic isotopic stratigraphy and tectonic significance of the Cuddapah Basin,India

The Cuddapah Basin is one of a series of Proterozoic basins that overlie the cratons of India that, due to limited geochronological and provenance constraints, have remained subject to speculation as to their time of deposition, sediment source locations, and tectonic/geodynamic significance.Here we present 21 new, stratigraphically constrained, U–Pb detrital zircon samples from all the main depositional units within the Cuddapah Basin. These data are supported by Hf isotopic data from 12 of these samples, that also encompass the stratigraphic range, and detrital muscovite ⁴⁰Ar/³⁹Ar data from a sample of the Srisailam Formation. Taken together, the data demonstrate that the Papaghni and lower Chitravati Groups were sourced from the Dharwar Craton, in what is interpreted to be a rift basin that evolved into a passive margin. The Nallamalai Group is here constrained to be deposited between 1659 ± 22 Ma and ~ 1590 Ma. It was sourced from the coeval Krishna Orogen to the east, and was deposited in its foreland basin. Nallamalai Group detrital zircon U–Pb and Hf isotope values directly overlap with similar data from the Ongole Domain metasedimentary rocks. Depositional age constraints on the Srisailam Formation are permissive with it being coeval with the Nallamalai Group and it was possibly deposited within the same basin. The Kurnool Group saw a return to Dharwar Craton derived provenance and is constrained to being Neoproterozoic. It may represent deposition in a long-wavelength basin forelandward of the Tonian Eastern Ghats Orogeny. Detrital zircons from the Gandikota Formation, which is traditionally considered a part of the Chitravati Group, constrain it to being deposited after 1181 ± 29 Ma, more than 700 Ma after the lower Chitravati Group. It is possible that the Gandikota Formation is correlative with the Kurnool Group.The new data suggest that the Nallamalai Group correlates temporally and tectonically with the Somanpalli Group of the Pranhita–Godavari Valley Basin, which is tightly constrained to being deposited at ~ 1620 Ma. These syn-orogenic foreland basin deposits firmly link the SE India Proterozoic basins to their orogenic hinterland with their discovery filling a ‘missing-link’ in the tectonic development of the region.     

Isotopic analysis of the super-large Shuangjianzishan Pb–Zn–Ag deposit in Inner Mongolia,China: Constraints on magmatism,metallogenesis, and tectonic setting

The super-large Shuangjianzishan Pb–Zn–Ag deposit is a newly discovered deposit located in the Huanggang–Ganzhuermiao polymetallic metallogenic belt of Inner Mongolia, NE China. The deposit's resource includes 0.026 Mt Ag, 1.1 Mt Pb, and 3.3 Mt Zn. The deposit is controlled by a NW-trending ductile shear zone and NE- and NW-trending faults in black pelite assigned to the lower Permian Dashizhai Formation. LREE enrichment, HREE depletion, Nb, Ta, P, and Ti depletion, and Zr and Hf enrichment characterize felsic magmatic rocks in the Shuangjianzishan Pb–Zn–Ag district. The ages of porphyritic monzogranite, rhyolitic crystal–vitric ignimbrite, and porphyritic granodiorite are 254–252, 169, and 130 Ma, respectively. Pyrite sampled from the mineralization has Re–Os isochron ages of 165 ± 7 Ma, which suggest the mineralization is associated with the ca. 169 Ma magmatism in the Shuangjianzishan district.Zircons extracted from the porphyritic granodiorite yield ε_Hf(t) values of − 11.34 to − 1.41, with t_DM2 dates of 1275–1901 Ma. The ε_Hf(t) values of zircons in the rhyolitic crystal–vitric ignimbrite and the ore-bearing monzogranite porphyry are 7.57–16.23 and 10.18–15.96, respectively, and their t_DM2 ages are 177–733 and 257–632 Ma, respectively. Partial melting of depleted mantle resulted in the formation of the ca. 254–252 Ma ore-bearing porphyritic monzogranite and the ca. 169 Ma rhyolitic crystal–vitric ignimbrite; dehydration partial melting of subducted oceanic crust resulted in the formation of the ca. 130 Ma porphyritic granodiorite. The porphyritic monzogranite was emplaced during the late stages of closure of the Paleo-Asian Ocean during the transformation from a collisional to extensional tectonic setting. The ca. 170 and ca. 130 Ma magmatism and mineralization in the Shuangjianzishan district are related to subduction of the Mongolia–Okhotsk Ocean and subduction of the Paleo-Pacific Ocean Plate, respectively.     

Duration of high-pressure metamorphism and cooling during the intraplate Petermann Orogeny

The Ediacaran–Cambrian Petermann Orogeny, central Australia, is an exceptional example of intraplate orogenesis. It involved sub-eclogite facies metamorphism and extreme basin inversion during the exhumation of Musgrave Province basement from beneath the formerly contiguous Centralian Superbasin. Sensitive High Resolution Ion Microprobe (SHRIMP) U–Pb geochronology of zircon, titanite and rutile, along with Ti-in-zircon thermometry from meta-igneous samples, have been used to determine the timing and duration of high-pressure metamorphism and subsequent cooling associated with this orogenic event. Peak metamorphic temperatures of 720–760 °C were attained at 544 ± 7 Ma (U–Pb zircon). Subsequent cooling to 600–660 °C by ~ 521 Ma occurred at a rate of ~ 2.6–7.0 °C Myr^− 1, as recorded by the closure of Pb diffusion in titanite. Further cooling to 585–560 °C by 498–472 Ma occurred at a rate of 0.9–4.8 °C Myr^− 1, as recorded by Pb closure in rutile. The duration of tectonism was long-lived (> 40 Myr) across the central and western parts of the orogenic system, and deformation occurred in a comparatively warm and weak portion of crust, characterised by regional thermal gradients of 17–26 °C km^− 1. This proposed duration of tectonism is much longer than that permitted by a shear heating mechanism, which requires an exceptionally short duration of tectonism, and additionally, an overall cold lithosphere characterised by geothermal gradients of ~ 9 °C km^− 1.     

The structure and stratigraphy of deepwater Sarawak,Malaysia: Implications for tectonic evolution

The structural-stratigraphic history of the North Luconia Province, Sarawak deepwater area, is related to the tectonic history of the South China Sea. The Sarawak Basin initiated as a foreland basin as a result of the collision of the Luconia continental block with Sarawak (Sarawak Orogeny). The foreland basin was later overridden by and buried under the prograding Oligocene-Recent shelf-slope system. The basin had evolved through a deep foreland basin (‘flysch’) phase during late Eocene–Oligocene times, followed by post-Oligocene (‘molasse’) phase of shallow marine shelf progradation to present day.Seismic interpretation reveals a regional Early Miocene Unconformity (EMU) separating pre-Oligocene to Miocene rifted basement from overlying undeformed Upper Miocene–Pliocene bathyal sediments. Seismic, well data and subsidence analysis indicate that the EMU was caused by relative uplift and predominantly submarine erosion between ∼19 and 17 Ma ago. The subsidence history suggests a rift-like subsidence pattern, probably with a foreland basin overprint during the last 10 Ma. Modelling results indicate that the EMU represents a major hiatus in the sedimentation history, with an estimated 500–2600 m of missing section, equivalent to a time gap of 8–10 Ma. The EMU is known to extend over the entire NW Borneo margin and is probably related to the Sabah Orogeny which marks the cessation of sea-floor spreading in the South China Sea and collision of Dangerous Grounds block with Sabah.Gravity modelling indicates a thinned continental crust underneath the Sarawak shelf and slope and supports the seismic and well data interpretation. There is a probable presence of an overthrust wedge beneath the Sarawak shelf, which could be interpreted as a sliver of the Rajang Group accretionary prism. Alternatively, magmatic underplating beneath the Sarawak shelf could equally explain the free-air gravity anomaly. The Sarawak basin was part of a remnant ocean basin that was closed by oblique collision along the NW Borneo margin. The closure started in the Late Eocene in Sarawak and moved progressively northeastwards into Sabah until the Middle Miocene. The present-day NW Sabah margin may be a useful analogue for the Oligocene–Miocene Sarawak foreland basin.     

The Ranger uranium deposit,northern Australia: Timing constraints,regional and ore-related alteration,and genetic implications for unconformity-related mineralisation

The Ranger 1 unconformity-related uranium deposit in the Northern Territory of Australia is one of the world's largest uranium deposits and has ranked in the top two Australian producers of uranium in recent years. Mineralisation at the Ranger, Jabiluka and other major unconformity-related deposits in the Alligator Rivers Uranium Field (ARUF) occurs in Paleoproterozoic metamorphic basement rocks immediately beneath the unconformity with the Paleo- to Mesoproterozoic McArthur Basin.The sites of uranium mineralisation and associated alteration at the Ranger 1 deposit (Number 3 orebody) were fundamentally controlled by reactivated shear zones that were initiated during the regional Nimbuwah tectonothermal event. The timing of shearing at medium metamorphic grade was constrained by ion microprobe U–Pb dating of zircons in two pegmatites, one weakly foliated (1867.0 ± 3.5 Ma) and another that is unfoliated and cuts the shear fabric (1862.8 ± 3.4 Ma). The younger age of ~ 1863 Ma represents the minimum age of D1 shearing during the Nimbuwah event at the Ranger 1 deposit (Number 3 orebody). Titanite within veins of amphibole-plagioclase-apatite yielded an ion microprobe U–Pb age of 1845.4 ± 4.2 Ma, which represents a previously unrecognised hydrothermal event in the ARUF. Based on previous data, retrograde hydrothermal alteration during D2 reactivation of D1 shear zones is interpreted to have occurred at ~ 1800 Ma during the regional Shoobridge tectonothermal event.Detailed paragenetic observations supported by whole-rock geochemical data from the Ranger 1 deposit (Number 3 orebody) reveal a sequence of post-D2 hydrothermal events, as follows. (1) Intense magnesium-rich chlorite alteration and brecciation, focussed within schists of the Upper Mine Sequence in the Cahill Formation. (2) Silicification of Lower Mine Sequence carbonate rock units and overlying schist units, comprising quartz ± Mg-foitite (tourmaline) ± muscovite ± pyrite ± marcasite, and rare uraninite (early U1). (3) Formation of main stage uranium ore and heterolithic breccias including clasts of olivine–phyric dolerite, with breccia matrix composed of uraninite (U1), Mg-chlorite ± Mg-foitite and minor pyrite and chalcopyrite. (4) A second generation of uraninite (U2) veinlets with disordered graphitic carbon and quartz of hydrothermal origin. (5) Late-stage veinlets of massive uraninite (U3). As inferred in a previous study and confirmed herein, olivine–phyric dolerite dykes at Ranger are mineralised and chloritised, and are geochemically similar to the regional Oenpelli Dolerite. A maximum age for uranium mineralisation at the Ranger 1 deposit is therefore set by the age of the Oenpelli Dolerite (~ 1723 Ma).In-situ ion microprobe U–Pb analysis of texturally oldest U1 uraninite yielded a discordia array with a ²⁰⁶Pb/²³⁸U-²⁰⁷Pb/²³⁵U upper intercept age of 1688 ± 46 Ma. The oldest individual ion microprobe ²⁰⁷Pb–²⁰⁶Pb age is 1684 ± 7 Ma whereas the oldest age determined by in-situ electron microprobe chemical dating of U1 uraninite is ~ 1646 Ma. Another sample containing both U1 and U2 uraninite yielded discordant data with a ²⁰⁶Pb/²³⁸U–²⁰⁷Pb/²³⁵U upper intercept age of 1421 ± 68 Ma. When the ²⁰⁷Pb/²⁰⁶Pb ages are considered the data are suggestive of U2 uraninite formation and possible resetting of the U1 age between ~ 1420 Ma and ~ 1040 Ma. All ion microprobe analyses of U1 and U2 uraninite indicate variable and possibly repeated lead loss. In contrast ion microprobe U–Pb dating of the third generation of uraninite (U3) yielded several near-concordant analyses and a ²⁰⁶Pb/²³⁸U–²⁰⁷Pb/²³⁵U upper intercept age of 474 ± 6 Ma. This age is supported by electron microprobe chemical ages of U3 uraninite between 515 Ma and 385 Ma.The new results constrain the timing of initial uranium mineralisation at the Ranger 1 deposit (Number 3 orebody) to the period ~ 1720 Ma to ~ 1680 Ma, which just overlaps with a previous U–Pb age of 1737 ± 20 Ma for uraninite-rich whole-rock samples. Our results are consistent with individual laser-ICPMS ²⁰⁷Pb/²⁰⁶Pb and chemical ages of uraninite as old as 1690–1680 Ma reported from other deposits and prospects in the ARUF.Whole-rock geochemical data in this study of the Ranger 1 deposit (Number 3 orebody) and in other studies in the ARUF demonstrate that zones of intense chloritisation associated with uranium mineralisation experienced large metasomatic gains of Mg, U, Co, Ni, Cu and S and losses of Si, Na, Ca, Sr, Ba, K, Rb, Y and the light REE. More broadly in the ARUF, a regionally extensive illite–hematite ± kaolinite-bearing ‘paleoregolith’ zone in basement beneath the McArthur Basin exhibits depletion of about half of its uranium as well as major losses in Na, Sr, Pb, Ba and minor losses of Mg. These features together with new petrographic observations suggest this zone is a regional sub-McArthur Basin alteration zone produced by interaction with diagenetic or hydrothermal fluids of primary basinal origin, rather than representing a low-temperature paleo-weathering zone before the deposition of the McArthur Basin, as previously suggested.Based on these results and a synthesis of previous work, a new multi-stage model is proposed for the Ranger 1 ore-forming mineral system that may apply to other major unconformity-related uranium deposits in the ARUF and which may be used for targeting new deposits in the region. As in most recent models, oxidised diagenetic brines within the McArthur Basin are envisaged as crucial in mobilising uranium. However, a different architecture of fluid flow is proposed involving the sub-unconformity regional basement alteration zone as a preferential source of leached uranium. Possibly driven by convection during regional magmatism at ~ 1725–1705 Ma, oxidised basinal brines were drawn downwards and laterally through fault networks and fractures in the regional sub-unconformity alteration zone, leaching uranium from hematite-altered basement rocks. Simultaneously within deeper and lateral parts of the hydrothermal system, Mg-metasomatism produced chloritic alteration and brines with increased acidity and silica content (from the desilicification of the basement rock), analogous to processes described in sub-seafloor hydrothermal systems. Silicification occurred locally (e.g., Ranger deposit) within upflow zones of convective systems due to decreases in temperature and/or pressure of the brines and/or CO₂ generation during carbonate dissolution. Interruptions to convection during transient regional extensional or strike-slip tectonic events resulted in generalised lateral and downwards flow of fluids from the McArthur Basin through deepened zones of sub-unconformity alteration, transferring leached uranium into reactivated shear zones within the basement. The main stage of uraninite precipitation at the Ranger deposit and elsewhere in the ARUF is proposed to have occurred between ~ 1720 Ma and ~ 1680 Ma as a result of reduction of oxidised and evolved basin-derived ore fluids during reaction with pre-existing Fe^2 +-bearing minerals and/or mixing of the ore fluids with basement-reacted silica-rich brines.A second, volumetrically minor but locally high-grade, stage of uraninite mineralisation was associated with hydrothermal disordered carbon and quartz of presently unknown origin. Available data suggest formation between ~ 1420 Ma and ~ 1040 Ma. Almost a billion years later at ~ 475 Ma, fluids capable of mobilising uranium again resulted in uraninite (U3) deposition as sparse veinlets in the Ranger deposit, representing the first documentation of uranium mineralisation of this age in the region.     

Linking uplift and mineralisation at the Mount Novit Zn-Pb-Ag Deposit,Northern Australia: Evidence from geology,U–Pb geochronology and sphalerite geochemistry

The subeconomic Mount Novit Zn-Pb-Ag deposit is located approximately 20 km south of Mount Isa, Queensland. In contrast to the nearby Mount Isa, Hilton and George Fisher Zn-Pb-Ag deposits, mineralisation at Mount Novit is situated to the west of the regional-scale Mount Isa Fault and is hosted in the Moondarra Siltstone as opposed to the Urquhart Shale. Lower-grade (<4 wt.% Zn + Pb) Zn-Pb-Ag mineralisation primarily replaces pre-existing carbonate alteration and veining and consists of pyrrhotite, pyrite and sphalerite with lesser galena. Higher-grade (>10 wt.% Zn + Pb) mineralisation occurs as a matrix supported breccia dominated by sphalerite and pyrrhotite with galena, pyrite, and magnetite. In-situ U–Pb geochronology was completed on apatite and two textural varieties of monazite. Fine-grained (<50 µm) subhedral to anhedral monazite is located within highly foliated biotite alteration directly adjacent Zn-Pb-Ag mineralisation and yields a mean weighted ²⁰⁷Pb/²⁰⁶Pb age of 1527 ± 18 Ma (MSWD = 1.06). This age is consistent with the formation of highly foliated biotite alteration during D₃ deformation of the Isan Orogeny. Apatite from the same fabric yields a lower intercept age of 1443 ± 29 Ma (MSWD = 1.30). Consistent with previous studies, this age is interpreted to represent the age of a major thrusting event along the Mount Isa Fault that resulted in the cooling of the Mount Novit area below ～375 °C. Coarse-grained monazite is coeval with Zn-Pb-Ag mineralisation and yields a mean weighted ²⁰⁷Pb/²⁰⁶Pb age of 1457 ± 11 Ma (MSWD = 0.28). Sphalerite from Mount Novit has low concentrations (<1 ppm) of Ge and Ga and a relatively high concentration of In (5 to >10 ppm), possibly reflecting the leaching of the metals from an underlying basement unit. The GGIMFis geothermometer (Frenzel et al., 2016) produced a mean formation temperature of 345 ± 52 °C. The timing and temperature of Zn-Pb-Ag mineralisation is consistent with the age and cooling temperature of apatite presented in this study. Based on these correlations, we suggest that Zn-Pb-Ag mineralisation at Mount Novit was emplaced during an episode of major thrusting along the Mount Isa Fault, with the precipitation of Zn-Pb-Ag mineralisation driven by the cooling of the Mount Novit area below ～375 °C. A key implication of this study is a new model for synorogenic Zn-Pb-Ag mineralisation to the south of Mount Isa, which contrasts with the widely accepted regional-scale syngenetic metallogenic model.     

The 1800–1100 Ma tectonic evolution of Australia

This paper presents a plate tectonic model for the evolution of the Australian continent between ca. 1800 and 1100 Ma. Between ca. 1800 and 1600 Ma episodic orogenesis occurred along the southern margin of the continent above a north-dipping subduction system. During this interval multiple orogenic events occurred. The West Australian Craton collided with the North Australian Craton (ca. 1790–1770 Ma), the Archaean nucleus of the Gawler Craton amalgamated with the North Australian Craton (ca. 1740–1690 Ma), and numerous smaller terranes accreted along the western Gawler Craton and the southern Arunta Inlier (ca. 1690–1640 Ma). The pattern of accretion suggests southward migration of the plate margin, which occurred due to a combination of slab rollback and back stepping of a subduction system behind the accreted continental blocks. Coeval with subduction a series of continental back-arc basins formed in the interior of the North Australian Craton and parts of the South Australian Craton, which were attached to the North Australian Craton prior to 1500 Ma. Extension of the North Australian Craton led to the opening of an oceanic basin along the eastern margin of the continent at ca. 1660 Ma. Continuing divergence was accommodated by oceanic spreading whereas the continental basins thermally subsided resulting in the development of sag-phase basins throughout the North Australian Craton. This oceanic basin was subsequently consumed during convergence, which ultimately led to development of a ca. 1600–1500 Ma orogenic belt along the eastern margin of Proterozoic Australia. Between ca. 1470 and 1100 Ma, the South Australian Craton, consisting of the Curnamona Province and the Gawler Craton rifted from the North Australian Craton and was re-attached in its present configuration during episodic ca. 1330–1100 Ma orogenesis, which is preserved in the Albany-Fraser Belt and the Musgrave Block.     

Application of pyrite trace element chemistry to exploration for SEDEX style Zn-Pb deposits: McArthur Basin,Northern Territory,Australia

Sedimentary pyrites in black shales contain abundant trace elements that provide information on the chemistry of the seawater at the time of sedimentation. This study focuses on the Barney Creek Formation (~ 1640 Ma) in the McArthur Basin in the Northern Territory of Australia, which is host to one of the world's largest SEDEX Zn-Pb-Ag deposits, and several smaller deposits. Fine-grained sedimentary pyrite has been sampled from three drill holes through the Barney Creek Formation at various distances from SEDEX mineralisation. Samples were selected through the stratigraphy of each hole and analysed by LA-ICPMS for a suite of 14 trace elements. The data show that sedimentary pyrite at the base of the Barney Creek Formation, closest (within 1 km) to SEDEX mineralisation, is strongly enriched in Zn and Tl by one to two orders of magnitude compared to the global average for sedimentary pyrite. In contrast sedimentary pyrite from the hole furthest from SEDEX mineralisation (~ 60 km) contains mean Zn and Tl values equal to, or less than, the global average. Based on the three drill hole pyrite data sets it is concluded that trace elements that are contributed to the basin during hydrothermal exhalation, and adsorbed into contemporaneous sedimentary pyrite, are principally Zn, Tl, Cu, Pb, Ag and As. In contrast, trace elements that are adsorbed into sedimentary pyrite from background seawater are principally Mo, Ni, Co, Se and As. These differences have enabled the development of a SEDEX fertility diagram for sedimentary basins, based on the composition of sedimentary pyrite, that distinguish high Zn, but barren shales, from high zinc SEDEX-related shales. In parallel with the increase in Zn and Tl in sedimentary pyrite approaching mineralisation there is a decrease in Ni, Co and Mo. This means that the ratios Zn/Ni and Tl/Co are particularly good pyrite vectors to SEDEX mineralisation in the McArthur Basin, varying over 4 to 6 orders of magnitude from barren shales to mineralised shales. It is speculated that the reason for the reverse relationship between Ni, Co and Zn, Tl may be caused by hydrothermal exhalations into the water column that effect the ion-exchange pyrite surface complexation processes that alter the uptake of these elements into sedimentary pyrite.Another important conclusion of this study is that hydrothermal exhalations into a sedimentary basin may affect the redox sensitive trace element chemistry of sedimentary pyrite and therefore the trace element chemistry of pyritic black shales. Nickel, Co and Mo all decrease in proximity to hydrothermal vents that form SEDEX deposits, whereas Zn, Tl and Pb increase. Selenium and bismuth are the only redox sensitive trace elements that appear to be unaffected by hydrothermal activity in the McArthur Basin. This has implications on how trace element concentrations of black shales and pyrite are used to reflect past global ocean chemistry.     

U–Pb detrital zircon data of the Rio Fuerte Formation (NW Mexico): Its peri-Gondwanan provenance and exotic nature in relation to southwestern North America

U–Pb detrital zircon studies in the Rio Fuerte Group, NW Mexico, establish its depositional tectonic setting and its exotic nature in relation to the North American craton. Two metasedimentary samples of the Rio Fuerte Formation yield major age clusters at 453–508 Ma, 547–579 Ma, 726–606 Ma, and sparse quantities of older zircons. The cumulative age plots are quite different from those arising from lower Paleozoic miogeoclinal rocks of southwestern North America and of Cordilleran Paleozoic exotic terranes such as Golconda and Robert Mountains. The relative age-probability plots are similar to some reported from the Mixteco terrane in southern Mexico and from some lower Paleozoic Gondwanan sequences, but they differ from those in the Gondwanan-affinity Oaxaca terrane. Major zircon age clusters indicate deposition in an intraoceanic basin located between a Late Ordovician magmatic arc and either a peri-Gondwanan terrane or northern Gondwanaland. The U–Pb magmatic ages of 151 ± 3 Ma from a granitic pluton and 155 ± 4 Ma from a granitic sill permit a revision of the stratigraphic and tectonic evolution of the Rio Fuerte Group. A regional metamorphism event predating the Late Jurassic magmatism is preliminarily ascribed to the Late Permian amalgamation of Laurentia and Gondwana. The Late Jurassic magmatism, deformation, and regional metamorphism are related to the Nevadan Orogeny.     

First evidence of the Cambrian basement in Upper Peninsula of Thailand and its implication for crustal and tectonic evolution of the Sibumasu terrane

Although the Sibumasu terrane in Asia was previously considered to be composed of Phanerozoic rocks with Cambrian crystalline basement, no reliable or direct radiometric dating evidences of such crystalline basement was ever reported. Our new in-situ zircon U/Pb dating of the Khao Tao orthogneiss yields a concordant age of 501.5 ± 7.5 Ma (2σ), which provides the first robust evidence for the Cambrian crust in Upper Peninsula of Thailand. The zircon εHf_(T) values range from + 3.7 to − 6.1 with model ages (T^C_DM) of 1244–1827 Ma, suggests a mixed crust-mantle source. The chemical similarity and spatial continuity of the Khao Tao orthogneiss with other pre-Neotethys marginal Eurasian and Sibumasu granitoids indicate the linear paleogeographic association under a similar magmatic arc-related regime along the Gondwana India–Australia margin as part of the Pan-African Orogeny system.