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1.
Peter I. Dorogokupets 《Physics and Chemistry of Minerals》2010,37(9):677-684
A simplest equation within the framework of the Mie-Grüneisen–Einstein approach is considered. Pressure estimation values
are presented that are derived by conventional arithmetic and algebraic calculations as a function of temperature and volume.
The equation under consideration complies with the Mie-Grüneisen–Debye model at high temperature. Different versions of an
equation of state (EoS) of MgO proposed by Speziale et al. (J Geophys Res 106B:515–528, 2001) as a pressure standard at high temperatures are subject to analyses. In the literature, at least four versions of Speziale
et al. EoS of MgO are discussed; the discrepancy between them reaching a few GPa at T > 2,000 K and P > 100 GPa. Our analyses of these equations suggest that the volume dependence of the Debye temperature is accepted arbitrarily
and does not agree with the definition of the Grüneisen parameter, γ = −(∂lnΘ/∂lnV)
T
. Pressure as a function of temperature and volume in the Mie-Grüneisen–Einstein approach or the Gao pressure calculator can
be used to estimate true pressure at compression x = V/V
0 < 1 with the Speziale et al. EoS of MgO. 相似文献
2.
A. S. Ivleva V. N. Podkovyrov V. B. Ershova O. A. Anfinson A. K. Khudoley P. V. Fedorov A. V. Maslov D. Yu. Zdobin 《Doklady Earth Sciences》2016,468(2):593-597
Here we present the results of U–Pb LA–ICP–MS dating of detrital zircons from the Ediacaran–Early Cambrian deposits of the eastern part of the Baltic monoclise (Leningrad Region). The obtained age spectra of the detrital zircons suggest that, in the Ediacaran–Early Cambrian, the main clastic material source to the northwest of the Russian Platform was the Baltic Shield. Then in the Early Cambrian along with the Baltic Shield provenance, a clastic source from the Timanian margin of Baltica (northeast in modern coordinates) contributed to the deposits. The obtained data either somewhat set limits of the Timanian orogen formation as older than the previously suggested Middle Cambrian (about 510 Ma), based on the “absence of a Proto–Uralian–Timanian provenance signal” in the Sablino Formation rocks in the south Ladoga, or suggest another rearrangement of detritus transportation paths at the end of Stage 3 (Atdabanian). 相似文献
3.
Simon A. Hunt Alex Lindsay-Scott Ian G. Wood Michael W. Ammann Takashi Taniguchi 《Physics and Chemistry of Minerals》2013,40(1):73-80
Orthorhombic post-perovskite CaPtO3 is isostructural with post-perovskite MgSiO3, a deep-Earth phase stable only above 100 GPa. Energy-dispersive X-ray diffraction data (to 9.4 GPa and 1,024 K) for CaPtO3 have been combined with published isothermal and isobaric measurements to determine its P–V–T equation of state (EoS). A third-order Birch–Murnaghan EoS was used, with the volumetric thermal expansion coefficient (at atmospheric pressure) represented by α(T) = α0 + α1(T). The fitted parameters had values: isothermal incompressibility, $ K_{{T_{0} }} $ = 168.4(3) GPa; $ K_{{T_{0} }}^{\prime } $ = 4.48(3) (both at 298 K); $ \partial K_{{T_{0} }} /\partial T $ = ?0.032(3) GPa K?1; α0 = 2.32(2) × 10?5 K?1; α1 = 5.7(4) × 10?9 K?2. The volumetric isothermal Anderson–Grüneisen parameter, δ T , is 7.6(7) at 298 K. $ \partial K_{{T_{0} }} /\partial T $ for CaPtO3 is similar to that recently reported for CaIrO3, differing significantly from values found at high pressure for MgSiO3 post-perovskite (?0.0085(11) to ?0.024 GPa K?1). We also report axial P–V–T EoS of similar form, the first for any post-perovskite. Fitted to the cubes of the axes, these gave $ \partial K_{{aT_{0} }} /\partial T $ = ?0.038(4) GPa K?1; $ \partial K_{{bT_{0} }} /\partial T $ = ?0.021(2) GPa K?1; $ \partial K_{{cT_{0} }} /\partial T $ = ?0.026(5) GPa K?1, with δ T = 8.9(9), 7.4(7) and 4.6(9) for a, b and c, respectively. Although $ K_{{T_{0} }} $ is lowest for the b-axis, its incompressibility is the least temperature dependent. 相似文献
4.
5.
Doklady Earth Sciences - New data on the minerals of the Fe–Ni–Co–Cu–S system in the differentiated intrusions of the Southern Urals are presented. Based on a detailed study... 相似文献
6.
Geology of Ore Deposits - The composition and interrelations of oxides (minerals of the spinel supergroup, corundum, ilmenite, rutile) and silicates (garnet, sillimanite, orthopyroxene, cordierite)... 相似文献
7.
In order to examine the precursory seismic quiescence of upcoming hazardous earthquakes, the seismicity data available in the vicinity of the Thailand–Laos–Myanmar borders was analyzed using the Region–Time–Length (RTL) algorithm based statistical technique. The utilized earthquake data were obtained from the International Seismological Centre. Thereafter, the homogeneity and completeness of the catalogue were improved. After performing iterative tests with different values of the \(r_{0}\) and \(t_{0}\) parameters, those of \(r_{0}\) = 120 km and \(t_{0}\) = 2 yr yielded reasonable estimates of the anomalous RTL scores, in both temporal variation and spatial distribution, of a few years prior to five out of eight strong-to-major recognized earthquakes. Statistical evaluation of both the correlation coefficient and stochastic process for the RTL were checked and revealed that the RTL score obtained here excluded artificial or random phenomena. Therefore, the prospective earthquake sources mentioned here should be recognized and effective mitigation plans should be provided. 相似文献
8.
The possibilities of using the average compositions of tonalite–trondhjemite–granodiorite association rocks (TTG), which make up a significant part of the Archaean continental crust, have been examined. The results of the TTG average compositions obtained by other researchers and the authors' data of the average compositions of TTG from the Baltic and Ukrainian shields and the entire Archaean crust are given. It is shown that the average compositions of the Archaean TTG of continental large crustal fragments (cratons or provinces) practically do not bear any information on their sources or conditions of their formation. The possibility of obtaining of such information by means of analysis of the average compositions of TTG, composing smaller fragments of the crust, exemplified by rocks of the Karelian subprovinces of the Baltic Shield has been demonstrated. 相似文献
9.
Please?refer?to?the?attachment(s)?for?more?details. 相似文献
10.
A. V. Maslov V. P. Shevchenko A. B. Kuznetsov R. Stein 《Geochemistry International》2018,56(8):751-765
The paper discusses the geochemical and Sr–Nd–Pb-isotope data on ice-rafted sediments (IRS) from different areas of the Arctic Ocean. Samples were collected during the Cruise of R/V Polarstern between Spitsbergen and North Pole, Yermak Plateau, as well as in Fram Strait. It is shown that the studied IRS samples in terms of LaN/YbN and εNd values are close to the composition of suspended particulate matter (SPM) from the mouth parts of large rivers and rivers transporting the sedimentary erosion products. This also follows from their Th/Sc, Th/Co, La/Sc, La/Sm, Sc/Th ratios and Sc content and from the position of their data points in the Sc–Th/Sc, La/Sc–Th/Co, and La/Sm–Sc/Th diagrams between the average SPM compositions of the Ob and Lena rivers. The values of 207Pb/206Pb and εNd in IRS samples give grounds to suggest that the rock complexes of the European, North American, and Asian continental margins could be potential sources for this sedimentary material. In the 207Pb/206Pb–εNd diagram, the IRS samples from all three studied areas define a compact cluster and are mainly confined to the triangle with corners represented by the Mackenzie River, Okhotsk–Chukotka volcanic area, and Lena River, being closer to the latter. In the Sm/Nd–εNd diagram, IRS points also form a compact field, being located almost in the middle between the average SPM compositions of the Yenisei and Ob rivers, on the one hand, and Lena River, on the other. In all diagrams, IRS samples from the different West Arctic areas show no significant scatter. With allowance for the fact that sediments are not subjected to significant homogenization during ice rafting, sediments from all three areas were obtained from a common source. As seen from the position of IRS data points in the 87Sr/86Sr–εNd diagram, this source was the Asian continental margin. 相似文献
11.
Numerical simulation of oil migration and accumulation is to describe the history of oil migration and accumulation in basin
evolution. It is of great value to the evaluation of oil resources and to the determination of the location and amount of
oil deposits. This thesis discusses the characteristics of petroleum geology and permeation fluid mechanics. For the three-dimensional
problems of Dongying hollow of Shengli Petroleum Oil Field, it puts forward a new model and a kind of modified method of upwind
finite difference fractional steps implicit interactive scheme. For the famous hydraulic experiment of secondary migration–accumulation,
the numerical simulation test has been done, and both the computational and experimental results are basically identical.
For the actual problem of Dongying hollow, the numerical simulation test and the actual conditions are basically coincident.
Thus, the well-known problem has been solved. 相似文献
12.
The discovery of layered, SO4-rich sediments on the Meridiani Planum on Mars has focused attention on understanding the formation of acid–saline lakes. Many salt lakes have formed in southern Australia where regional groundwaters are characterized by acidity and high salinity and show features that might be expected in the Meridiani sediments. Many (but not all) of the acid–saline Australian groundwaters are found where underlying Tertiary sediments are sulfide-rich. When waters from the formations come to the surface or interact with oxidised meteoric water, acid groundwaters result. In this paper examples of such waters around Lake Tyrrell, Victoria, and Lake Dey-Dey, South Australia, are reviewed. The acid–saline groundwaters typically have dissolved solids of 30–60 g/L and pH commonly <4.5. Many contain high concentrations of Fe and other metals, leached from local sediments. The combination of acidity and salinity also releases Ra. Around salt-lakes, these acidic waters often emerge at the surface in marginal spring zones where the low density (ρ ∼ 1.04) regional water flows out over the denser (ρ ∼ 1.16) lake brines. In the spring zones examined, large amounts of Fe are commonly precipitated. In a few places minerals of the alunite-jarosite family are formed which can trap many other metals, including Ra. The studied groundwater systems were discovered by U exploration programs following up radiometric anomalies related to this Ra. Evaporation concentrates the lesser soluble salts (gypsum and some halite) on the surface of the lakes. The lake brines contain most of the more soluble salts and form a column within the porous sediments which is held in place by hydrostatic forces around the salt-lake. These brines are near-neutral in pH. 相似文献
13.
The results of our study indicate that at the Late Cretaceous–Paleogene boundary in the southeastern part of the Amur–Zeya Basin, the sedimentation conditions changed drastically, namely, the change of provenance areas of debris. In the Maastrichtian, the clastic material was mainly transported from the Bureya–Jiamusi Superterrane and the volcanic–plutonic belts of Khingan–Okhotsk and East Sikhote–Alin located to the east: sedimentation occurred simultaneously with magmatic activity. During the Danian Stage, the major source of debris to the southern part of the basin was located to the south of the young mountain system of the Lesser Khingan (the uplifted part of the basement of the Songliao Block). 相似文献
14.
Ivanov K. S. Berzin S. V. Erokhin Yu. V. Ronkin Yu. L. Khiller V. V. 《Doklady Earth Sciences》2019,484(1):97-100
Doklady Earth Sciences - Dolerites of the parallel dikes formed in a back-arc spreading setting have been dated by Sm–Nd to the Silurian (426 ± 34 Ma) for Mount Azov in the Central... 相似文献
15.
Martina Bertelli Timothy Baker James S. Cleverley Thomas Ulrich 《Journal of Geochemical Exploration》2009
The Bismark deposit (northern Chihuahua, Mexico) is one of several base metal-rich high-temperature, carbonate-replacement deposits hosted in northern Mexico. Previous fluid inclusion studies based on microthermometry and PIXE have shown that the Zn-rich, Pb-poor Bismark deposit formed from a moderate salinity magmatic fluid [Baker, T. and Lang, J.R., 2003. Reconciling fluid inclusion types, fluid processes, and fluid sources in skarns: an example from the Bismark Deposit, Mexico. Mineralium Deposita 38(4), 474–495; Baker, T., van Achterberg, E., Ryan, C.G. and Lang, J.R., 2004. Composition and evolution of ore fluids in a magmatic-hydrothermal skarn deposit. Geology 32(2), 117–120]. The exact precipitation mechanisms are unclear and may have due to cooling, salinity decrease and wall rock reaction. Furthermore, PIXE data suggested that Pb and Zn concentrations were comparable and inconsistent with the Zn-rich nature of the ore. However, Pb was commonly below the limit of detection for PIXE and the data presented by Baker et al. [Baker, T., van Achterberg, E., Ryan, C.G. and Lang, J.R., 2004. Composition and evolution of ore fluids in a magmatic-hydrothermal skarn deposit. Geology 32(2), 117–120] are regarded as the maximum concentrations of Pb in the fluid. In this study new LA ICP MS analysis was carried out on the same fluid inclusion population to compare with the PIXE data in order to constrain the uncertainty related to the Pb data and the new results are used to model possible ore deposition mechanisms. The new laser ablation data reveal overall lower concentrations of Pb in the ore fluid (average value ~ 285 ppm) than previously indicated by PIXE analysis (average value ~ 713 ppm). Chemical modelling using the new laser ablation data tested the following ore deposition processes: 1) cooling; 2) fluid–rock reaction at constant temperature; 3) cooling and simultaneous fluid–rock interaction. Modelling results show that the gangue and ore minerals observed at Bismark are best reproduced by fluid–rock interaction and simultaneous cooling. Results from the simulations strongly indicate that ore deposition was mainly driven by a pH increase due to the neutralization of the acidic ore fluid (pH = 3.9) as the result of the reaction with the limestone. Modelling results also suggest that the deposit likely formed under cooling conditions, but do not support the hypothesis of a temperature decrease as the principal ore-forming process. 相似文献
16.
Acta Geotechnica - This paper presents a constitutive model for simulating the swelling–shrinkage volume change of expansive soils during wetting–drying cycles. Based on the concept of... 相似文献
17.
The Guanajuato epithermal district is one of the largest silver producers in Mexico. Mineralization occurs along three main vein systems trending dominantly northwest–southeast: the central Veta Madre, the La Luz system to the northwest, and the Sierra system to the east. Mineralization consists dominantly of silver sulfides and sulfosalts, base metal sulfides (mostly chalcopyrite, galena, sphalerite, and pyrite), and electrum. There is a broad zonation of metal distribution, with up to 10 % Cu+Pb+Zn in the deeper mines along the northern and central portions of the Veta Madre. Ore occurs in banded veins and breccias and as stockworks, with gangue composed dominantly of quartz and calcite. Host rocks are Mesozoic sedimentary and intrusive igneous rocks and Tertiary volcanic rocks. Most fluid inclusion homogenization temperatures are between 200 and 300 °C, with salinities below 4 wt.% NaCl equivalent. Fluid temperature and salinity decreased with time, from 290 to 240 °C and from 2.5 to 1.1 wt.% NaCl equivalent. Relatively constant fluid inclusion liquid-to-vapor ratios and a trend of decreasing salinity with decreasing temperature and with increasing time suggest dilution of the hydrothermal solutions. However, evidence of boiling (such as quartz and calcite textures and the presence of adularia) is noted along the Veta Madre, particularly at higher elevations. Fluid inclusion and mineralogical evidence for boiling of metal-bearing solutions is found in gold-rich portions of the eastern Sierra system; this part of the system is interpreted as the least eroded part of the district. Oxygen, carbon, and sulfur isotope analysis of host rocks, ore, and gangue minerals and fluid inclusion contents indicate a hydrothermal fluid, with an initial magmatic component that mixed over time with infiltrating meteoric water and underwent exchange with host rocks. Mineral deposition was a result of decreasing activities of sulfur and oxygen, decreasing temperature, increasing pH, and, in places, boiling. 相似文献
18.
During convergence of Gondwana-derived microplates and Laurussia in the Palaeozoic, subduction of oceanic and continental crusts and their sedimentary cover introduced material of regionally contrasting chemical and isotopic compositions into the mantle. This slab material metasomatised the local mantle, producing a highly heterogeneous lithospheric mantle beneath the European Variscides. The eastern termination of the European Variscides (Moldanubian and Saxo-Thuringian zones of Austria, Czech Republic, Germany and Poland) is unusual in that the mantle was modified by material from several subduction zones within a small area. Orogenic lamproites sampled this lithospheric mantle, which has a chemical signature reflecting extreme depletion (low CaO and Al2O3 contents and high Mg-number) followed by strong metasomatic enrichment, giving rise to crust-like trace element patterns, variable radiogenic 87Sr/86Sr(330) (0.7062–0.7127) and non-radiogenic Nd isotopic compositions (εNd(330) = − 2.8 to − 7.8), crustal Pb isotopic compositions, and a wide range of δ7Li values (− 5.1 to + 5.1). This metasomatic signature is variably expressed in the lamproites, depending on the extent of melting and the nature of the source of the metasomatic component. Preferential melting of the metasomatically enriched (veined) lithospheric mantle with K-rich amphibole resulted in lamproitic melts with very negative, crust-like δ7Li values, which correlate positively with peralkalinity, HFSE contents and lower εNd. Both the higher degree of melting and progressive consumption of the metasomatic component reduce the chemical and isotopic imprints of the metasomatic end member. The very positive δ7Li values of some lamproites indicate that the source of these lamproites may have been modified by subducted oceanic lithosphere. Fresh olivine from the Brloh (Moldanubian) lamproitic dyke shows very high Fo (up to 94%) and very high Li contents (up to 25 ppm), demonstrating that the extremely depleted and later enriched lithospheric mantle may have contributed significantly to the Li budget of the lamproites. The regional distribution of lamproites with contrasting chemical and isotopic fingerprints mimics the distribution of the different Variscan subduction zones. 相似文献
19.
A. A. Tomilenko E. I. Zhimulev T. A. Bul’bak V. M. Sonin A. I. Chepurov N. P. Pokhilenko 《Doklady Earth Sciences》2018,482(1):1207-1211
The first chromatography–mass spectroscopy data on volatiles in diamonds synthesized in the Fe–S–C system with 5 wt % S at 1400–1450°C and 5.0–5.5 GPa indicate the evolution of volatile composition during the diamond growth and, correspondingly, the variation in redox conditions of the reaction cell. A significant role is played by various hydrocarbons (HCs) and their derivatives, the content of which can reach 87%. Our data on possible abiogenic synthesis of HCs (components of natural gas and oil) can result in global recalculations (including climate) related to the global C cycle. 相似文献
20.
Doklady Earth Sciences - This paper presents the results of U–Pb (LA-ICP-MS) and Lu–Hf isotope studies of detrital zircons from the presumably Permian meta sedimentary rocks of the... 相似文献