Numerical simulation of groundwater flow in regional rock aquifers, southwestern Quebec, Canada

The St. Lawrence Lowlands platform, Quebec, Canada, is a densely-populated area, heavily dependent on groundwater resources. In 1999, the Geological Survey of Canada initiated a large-scale hydrogeological assessment study over a 1,500 km² region northwest of Montreal. The objectives were to define the regional groundwater flow, and to give quantitative estimates of the groundwater dynamic parameters and of the available groundwater resources. The applied approach consisted of defining the hydrogeologic framework, hydraulic properties of the aquifer units, and groundwater dynamic components. Lower Paleozoic sedimentary rocks represent regional aquifer units. Coarse Quaternary fluvio-glacial sediments locally overlay the rock sequence and constitute an interface aquifer unit. Fine marine sediments confine most of the regional aquifers. Collected GIS based information was synthesized in a finite element numerical model. The regional saturated steady-state flow was calibrated under current stress conditions assuming an equivalent porous medium approach. Water budget calculations show that the total groundwater flow in regional aquifers amounts to 97.7 Mm³/y. Infiltration from precipitation provides 86.6% of the groundwater supply, while 9.6% comes from subsurface inflow and the remaining 3.8% is induced recharge from surface waters. Discharge from regional aquifers occurs through flow to streams (76.9%), groundwater withdrawal (18.4%), and underground outflow (4.7%).

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Resumen La plataforma de Tierras Bajas San Lorenzo, Quebec, Canadá, es un área densamente poblada que depende fuertemente de recursos de agua subterránea. En 1999 el Servicio Geológico de Canadá inició un estudio de evaluación hidrogeológica a gran escala sobre un área de 1,500 km² en la región noroeste de Montreal. Los objetivos fueron definir el flujo regional de agua subterránea y aportar estimados cuantitativos de los parámetros dinámicos de agua subterráne y de los recursos disponibles de agua subterránea. El enfoque aplicado consistió en definir el marco hidrogeológico, propiedades hidráulicas de las unidades acuíferas, y los componentes dinámicos de agua subterránea. Rocas sedimentarias del Paleozoico Inferior representan unidades regionales de acuíferos. Sedimentos fluvio-glaciares Cuaternarios gruesos sobreyacen localmente la secuencia rocosa y constituyen una unidad acuífera interfacial. Sedimentos marinos finos confinan la mayoría de acuíferos regionales. Información colectada basada en SIG se sintetizó en un modelo numérico de elemento finito. El flujo regional saturado en régimen permanente se calibró bajo condiciones de stress asumiendo un enfoque de medio poroso equivalente. Los cálculos de balance hídrico muestran que el flujo total de agua subterránea en acuíferos regional alcanza 97.7 Mm³/año. Infiltración a partir de lluvia aporta el 86.6% del abastecimiento al agua subterránea, mientras que el 9.6% proviene de entradas subsuperficiales y el restante 3.8% consiste de recarga inducida a partir de aguas superficiales. La descarga proveniente de acuíferos regionales ocurre a través de flujo a ríos (76.9%), utilización de agua subterránea (18.4%), y salida subterránea (4.7%).

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Résumé La plateforme Lowllands du Saint-Laurent, Québec, Canada, est une aire densément peuplée, dépendant grandement des ressources en eau souterraine. En 1999, le Service Géologique du Canada a initié une étude hydrogéologique à grande-échelle sur 1500 km² au Nord-Ouest de Montréal. Le sobjectifs ont été de définir la dynamique de lécoulement régional, et de donner des estimations quantitatives des paramètres dynamiques des ressources disponibles en eau souterraine. Lapproche utilisée consista à définir le cadre hydrogéologique de travail, les propriétés hydrauliques des unités aquifères, et les composantes dynamiques des eaux souterraines. Les roches sédimentaires du Paléozoïque Inférieur représentent les unités aquifères régionales. Les sédiments marins fins confinent la plus grande partie des aquifères régionaux. Les informations de base, collectées dans un SIG, ont été synthétisées dans un modèle numérique aux éléments finis. Lécoulement permanent régional, en zone saturée, a été calibré en conditions de stress en assumant une approche de milieu poreu équivalent. Les calculs du bilan hydrologique montrent que lécoulement total des eaux souterraines dans les aquifères régionaux atteind 97,7 Mm³/an. Linfiltration à partir des précipitations apporte 86.6% de leau souterraine exploitée; sachant que 9,6% proviennent découlement de subsurfaces, et que les 3,8% restants proviennent de la recharge via les eaux de surface. Le débit pompé des aquifères régionaux apparaît à travers lécoulement des cours deau, le rabattement des eaux souterraines (18.4%), et lécoulement ascendant (4.7%).

     

Identifying trends in groundwater quality using residence time indicators: an example from the Permian aquifer of Dumfries, Scotland

The Permian sandstone and breccia aquifer of Dumfries has an important role in supplying water to the principal town in southwest Scotland. The area comprises mainly pastoral farmland with some industry and fish farming. Ongoing development of the aquifer has revealed the existence of complex groundwater flow through fractures and increasing nitrate concentrations. To further investigate these issues, the age and quality of groundwater throughout the aquifer has now been assessed using standard hydrogeochemical techniques together with CFCs and SF₆ as residence time indicators. The aquifer consists of sandstone- and breccia-dominated units: the Locharbriggs Sandstone in the east and the Doweel Breccia in the west. Groundwater throughout the aquifer is of Ca–Mg–HCO₃ type and moderately mineralised; pH is near neutral. The observed groundwater chemistry is the product of maritime rainfall modified by the dissolution of carbonate material in the breccia, sandstone and surficial deposits. CFC and SF₆ concentrations are interpreted on the basis of mixing between older (>50 years) and recent (1990s) components. Although there is generally a higher proportion of older water within the Locharbriggs Sandstone compared to the Doweel Breccia, stable isotope evidence suggests that the older water component in the interbedded sandstones of the breccia is of much greater antiquity, possibly containing an element of palaeowater. Concentrations of nitrate across the aquifer can be directly related to the amount of recent recharge. Modern groundwater contains approximately 9 mg l^–1 NO₃-N and pre-1950s groundwater has approximately 2 mg l^–1 NO₃-N. Nitrate concentrations measured at individual boreholes are explained by the relative proportions of modern and pre-1950s groundwater. If current practices continue, the concentrations of nitrate measured across the Dumfries Basin will rise as the proportion of pre-1950s groundwater diminishes.

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Resumen El acuífero de areniscas y brechas Pérmicas de Dumfries desempeña un papel importante en el abastecimiento a la ciudad principal del Sudoeste de Escocia. El área comprende sobretodo tierras de pastoreo y granjas, junto con algunas industrias y piscifactorías. El desarrollo iniciado en el acuífero ha revelado la existencia de un complicado flujo subterráneo a través de las fracturas y de un aumento progresivo en la concentración de nitrato. Con el fin de profundizar en el conocimiento de estos temas, se ha determinado la edad y calidad de las aguas subterráneas en todo el acuífero por medio de técnicas hidrogeoquímicas estándar y de indicadores del tiempo de residencia como los clorofluorcarbonados (CFCs) y el fluoruro de azufre (SF₆). El acuífero está formado por las areniscas de Locharbriggs, al Este, y las brechas de Doweel, hacia el Oeste. Las aguas subterráneas son de tipo bicarbonatadas cálcico-magnésicas y presentan una mineralización moderada, mientras que el pH es prácticamente neutro. La química de las aguas subterráneas es el resultado del aerosol marino modificado por la disolución de materiales carbonatados en las brechas, areniscas y depósitos superficiales. Las concentraciones de CFCs y SF₆ se interpretan a partir de una mezcla de aguas entre una componente antigua (más de 50 años) y una reciente (de la década de 1990). Aunque en general se da una mayor proporción de aguas antiguas en las areniscas de Locharbriggs que en las Brechas de Doweel, los isótopos estables sugieren que la componente de aguas antiguas en las intercalaciones de areniscas que aparecen en la formación de brechas es mucho más antigua, y que, posiblemente, se trate de paleoaguas. Las concentraciones de nitrato en el acuífero pueden ser relacionadas directamente con la aportación de recarga reciente. Las aguas subterráneas modernas contienen aproximadamente 9 mg l^–1 de nitrato, mientras que las aguas subterráneas anteriores a 1950 tienen unos 2 mg l^–1. Se puede explicar las concentraciones de nitrato en pozos individuales por las proporciones relativas de aguas subterráneas modernas y anteriores a 1950. Si las prácticas actuales continúan, se producirá un aumento de las concentraciones de nitrato en la cuenca de Dumfries debido a la disminución de la proporción de aguas antiguas.

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Résumé L'aquifère des grès et brèches du Permien de Dumfries joue un rôle important dans l'alimentation en eau de la principale ville du sud-ouest de l'Écosse. La région est principalement soumise à de l'élevage pastoral avec quelques industries et des piscicultures. La progression de l'exploitation de cet aquifère a révélé l'existence d'un écoulement souterrain complexe en fractures et des concentrations en nitrate croissantes. Dans le but d'étudier ces deux points plus en détail, l'âge et la qualité de l'eau souterraine dans tout l'aquifère ont été évalués en utilisant des techniques hydrogéochimiques conventionnelles avec les CFC et SF₆ comme marqueurs du temps de séjour. L'aquifère est constitué par des unités dominées par des brèches et des grès: les grès de Locharbriggs à l'est et les brèches de Doweel à l'ouest. L'eau souterraine dans tout l'aquifère a un faciès bicarbonaté calcique et magnésien et est moyennement minéralisée; le pH est proche de la neutralité. Le chimisme observé de l'eau souterraine résulte des apports marins par la pluie modifiés par la dissolution du matériau carbonaté des brèches, des grès et des formations superficielles. Les concentrations en CFC et SF₆ sont interprétées sur la base d'un mélange entre des composantes ancienne (>50 ans) et récente (années 1990). Bien qu'il y ait en général une plus forte proportion d'eau ancienne dans les grès de Locharbriggs que dans la brèche de Doweel, les isotopes stables suggèrent que la composante d'eau ancienne dans les grès interstratifiés des brèches est beaucoup plus ancienne, contenant probablement un élément d'eau fossile. Les concentrations en nitrate dans l'aquifère peuvent être directement reliées au taux de recharge récente. L'eau souterraine moderne contient approximativement 9 mg l^–1 en NO₃-N et l'eau souterraine d'avant 1950 environ 2 mg l^–1 en NO₃-N. Les concentrations en nitrate mesurées dans des forages individuels sont expliquées par des proportions relatives d'eaux souterraines moderne et antérieure à 1950. Si les pratiques actuelles continuent, les concentrations en nitrate mesurées dans le bassin de Dumfries augmenteront alors que la part de l'eau souterraine d'avant 1950 diminuera.

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断层内部结构及其对封闭性的影响

先前的研究多考虑断层封堵和开启的2种极端状态,近来的研究认为,在多数情况下断层处于2种之间的状态,只有在静止期具有封闭能力的断层,才有可能对油气起封堵作用。分析断层对流体运移的影响,需要分析断层在演化过程中的内部结构特征。断层可以划分出破碎带、诱导裂缝带和围岩3部分,断层岩和伴生裂缝构成破碎带的主体部分。常见的断层岩包括断层角砾岩、断层泥和部分碎裂岩,它们充填在断层裂缝空间中,断层内部结构受断层形成时的构造应力性质、断层活动强度和围岩岩性因素的控制。从动态角度看,随着断距增加,断层活动伴随着裂缝的发育和岩石的破碎混杂,可用泥质源岩层厚度和断距的比值来划分不同的发育阶段。断层活动期为油气运移通道,在静止时表现出差异性的封闭,通常用断层渗透率和排替压力2个参数来定量评价断层的封闭程度。断层岩渗透率主要受断距、泥质含量、埋深等因素的控制;断层排替压力的预测方法有2种:一种是从断层岩成岩角度分析的"等效埋深法",另一种是分析实测排替压力与主控地质因素的"拟合法"。通过简化的断层模型,建立了渗透率、排替压力与主控因素的预测关系。和储层类似,流体在断层中的运移遵循多孔介质的渗流特征。利用断层两侧的流体压力和油气柱高度并不能直接评价封闭性能,还必须考虑油气充注史和流体压力变化历史。     

Processes of normal fault evolution in a siliciclastic sequence: a case study from Miri, Sarawak, Malaysia

Detailed field observations of normal faults formed at shallow depth in a deltaic sand–clay sequence near Miri, Sarawak are used to study the main structural elements during the early stages of fault development. We studied over 450 segmented faults, many of which contain clay smear, in an excellent outcrop exposing a collapsed crest structure.In agreement with previous studies we find that important elements of fault zone evolution are: (i) clay smear, (ii) telescoping on parallel strands, and (iii) preferred deformation of fault-bounded lenses. We model the consequences of telescoping on parallel strands and conclude that the reliability of juxtaposition diagrams can decrease dramatically in the presence of undetected multiple fault strands. The across fault connectivity can either increase or decrease depending on small variations in many of the input parameters.All the faults studied have a continuous clay smear over the interval studied, except for the places where a sand bed has an offset smaller than its thickness, and therefore has not moved past clay. Although on average the clay content observed correlates well with the average clay content of the faulted section, there are large variations in clay content controlled by local complexity in deformation. Understanding of this local complexity is a prerequisite for further improvement of clay smear in the subsurface.     

黔北后槽下石炭统含铝岩系的粘土矿物

为揭示黔北下石炭统含铝岩系的沉积环境,本文利用贵州遵义县后槽TC718剖面系统试样的粘土矿物进行X-射线衍射测试及特征分析.含铝岩系粘土岩与下伏桐梓组粘土页岩在矿物组合和成分上均有明显的差异,水云母的结晶度指数、开形指数在剖面纵向上有三个变化拐点一是含铝岩系与下伏桐梓组粘土页岩分界处;二是含铝岩系上、下段的接触带;三是含铝岩系顶部含炭质粘土岩出现的临界面.其变化特征表明,本区下石炭统含铝岩系粘土岩段为海相或海陆过渡相,铝质岩段为残积-坡积相,顶部为大陆湖沼相;下奥陶统桐梓组页岩段为海相.     

Hydraulic properties and scale effects investigation in regional rock aquifers,south-western Quebec,Canada

This paper reports on the characterization of hydraulic properties of regional rock aquifers carried out within a groundwater resources assessment project in the St. Lawrence Lowlands of south-western Quebec. To understand the aquifer behavior at both the fracture level and at field scale, hydraulic investigations were carried out using various aquifer tests. The groundwater flow at the local scale is controlled mostly by the fracture system. Results of the constant-head injection tests show a weak decreasing trend of hydraulic conductivity with depth indicating that a major part of the groundwater flow occurs in the first meters of the rock sequence. At the regional scale, the equivalent porous media approach is applicable. The hydraulic conductivity measurements were correlated to the scale of the aquifer tests expressed with the investigated aquifer volume. A simple interpolation procedure for the hydraulic conductivity field was developed based on the distance between field measurements and the tested aquifer volumes. The regional distribution of the hydraulic conductivity for the major fractured aquifer units indicates that dolostone is the most permeable whereas sandstone and crystalline rocks are the least permeable units.

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Resumen Este artículo trata de la caracterización de las propiedades hidráulicas en acuíferos regionales rocosos, la cual se llevó a cabo dentro del proyecto de evaluación de los recursos de agua subterránea en St. Lawrence Lowlands al suroeste de Quebec. Para entender el comportamiento del acuífero tanto a nivel de fractura como a escala del campo, se ejecutaron investigaciones hidráulicas usando varias pruebas de acuífero. El flujo del agua subterránea a escala local está controlado principalmente por el sistema de fracturas. Los resultados de las pruebas de inyección con cabeza constante muestran una tendencia decreciente débil de la conductividad hidráulica con la profundidad, indicando que la mayor parte del flujo de agua subterránea sucede en los primeros metros de la secuencia rocosa. A escala regional se puede aplicar la aproximación equivalente de medios porosos. Las medidas de la conductividad hidrálica fueron comparadas con la escala de las pruebas del acuífero, expresadas con el volumen investigado del acuífero. Se desarrolló un proceso de interpolación simple para la conductividad hidráulica de campo, con base en la distancia entre las medidas de campo y los volúmenes probados del acuífero. La distribución regional de la conductividad hidráulica, para las unidades acuíferas fracturadas mayores, indica que la dolomita es más permeable mientras que la arenisca y las rocas cristalinas son las unidades menos permeables.

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Résumé Larticle présente les propriétés hydrauliques dun aquifère régional rocheux qui ont été mesurées dans le cadre dun projet concernant lestimation de la ressource en eau de la plaine de St. Lawrence située dans la partie sud-ouest de Quebec. Affin de comprendre le comportement de l› aquifère tant à l› échelle de fracture qu› à l› échelle régionale on a mené des investigations hydrauliques en utilisant des essais differents. À l› échelle locale lécoulement est déterminé en principal par le système des fractures. Les résultats des essais dinjection au niveau constant ont montré une tendence de décroissance de la conductivité hydraulique avec la profondeur ce qui indique que l› écoulement ait lieu en principal dans les premiers mètres de la structure rocheuse. À l› échelle règionale on peut appliquer lapproche de milieux poreux equivalent. Les mesures de conductivité hydraulique ont été corrélées avec l› échelle des essais de pompage exprimée en termes de volume investigué de l› aquifère. On a mis au point une méthode simple dinterpolation pour le champ de la conductivité hydraulique basée sur la distance entre les essais in situ et les volume investigués de l› aquifère. La distribution règionale de la conductivité hydraulique montre que pour la majorité des unités de roche fracturé les plus perméable sont les roches dolomitiques alors que les grés et les roches cristalines presentent la plus faible perméabilité.

     

沉积盆地中地质流体运动与油气成藏

沉积盆地内地质流体运动的驱动力主要有压实作用、地下水重力作用、构造作用和进入盆地中的热流。在不同的驱动力作用下,地质流体可有离心流、向心流、穿越流以及幕式和集中式等不同的运动特征,对油气成藏的影响亦存在差异。在压实作用驱动下,油气藏围绕盆地生油中心成环状分布。在重力作用驱动下,油气主要聚集在地下水的低势区,如盆地的斜坡和中心,或地下水中下游的靠盆地一侧。构造作用驱动下的油气运移比较复杂,油气主要聚集在冲断层一侧,但也可以长距离运移到斜坡带聚集。     

On the radiogenic heat production of metamorphic,igneous, and sedimentary rocks

Sedimentary rocks cover-73% of the Earth's surface and metamorphic rocks account for approximately91% of the crust by volume. Understanding the average behavior and variability of heat production for these rock types are vitally important for developing accurate models of lithospheric temperature. We analyze the heat production of ～204,000 whole rock geochemical data to quantify how heat production of these rocks varies with respect to chemistry and their evolution during metamorphism. The heat production of metaigneous and metasedimentary rocks are similar to their respective protoliths. Igneous and metaigneous samples increase in heat production with increasing SiO_2 and K_2 O, but decrease with increasing FeO, MgO and CaO. Sedimentary and metasedimentary rocks increase in heat production with increasing Al_2 O_3, FeO, TiO_2, and K_2 O but decrease with increasing CaO. For both igneous and sedimentary rocks, the heat production variations are largely correlated with processes that affect K_2 O concentration and covary with other major oxides as a consequence. Among sedimentary rocks,aluminous shales are the highest heat producing(2.9 μW~(-3)) whereas more common iron shales are lower heat producing(1.7 μW m~(-3)). Pure quartzites and carbonates are the lowest heat producing sedimentary rocks. Globally, there is little definitive evidence for a decrease in heat production with increasing metamorphic grade. However, there remains the need for high resolution studies of heat production variations within individual protoliths that vary in metamorphic grade. These results improve estimates of heat production and natural variability of rocks that will allow for more accurate temperature models of the lithosphere.     

Structural and statistical characterization of joints and multi-scale faults in an alternating sandstone and shale turbidite sequence at the Santa Susana Field Laboratory: Implications for their effects on groundwater flow and contaminant transport

This paper describes the properties of faults and fractures in the Upper Cretaceous Chatsworth Formation exposed at Santa Susana Field Laboratory and its surroundings (Simi Hills, California), where groundwater flow and contamination have been studied for over three decades.The complex depositional architecture of this turbidite consisting of alternating sandstones and shales, interacting with formative stress conditions are responsible for multi-scale fault hierarchies and permeable fractures in which nearly all groundwater flow occurs.Intensity and distribution of background fractures and their relation to bedding thickness are established for sandstones, the dominant lithology. The architecture of faults with increasing displacement is described, and relationships among fault dimensional parameters captured.Data from ∼400 boreholes and piezometers reveal the effect of faults and fractures on groundwater flow. Large hydraulic head differences, observed across fault zones with shale-rich cores, indicate these structures as cross-flow barriers. Moreover, hydraulic head profiles under ambient conditions, and pumping tests suggest strong hydraulic connectivity in all directions to depth of hundreds of meters.This outcrop-based structural characterization relates the horizontal hydraulic conductivity to the observed well-connected fracture network, and explains the strong vertical connectivity across low-hydraulic conductivity shales as faults and sheared fractures provide flow pathways.     

Development of fluid conduits in the auriferous shear zones of the Hutti Gold Mine, India: evidence for spatially and temporally heterogeneous fluid flow

The gold mineralization of the Hutti Mine is hosted by nine parallel, N–S trending, steeply dipping, 2–10 m wide shear zones, that transect Archaean amphibolites. The shear zones were formed after peak metamorphism during retrograde ductile D₂ shearing in the lower amphibolite facies. They were reactivated in the lower to mid greenschist facies by brittle–ductile D₃ shearing and intense quartz veining. The development of a S₂–S₃ crenulation cleavage facilitates the discrimination between the two deformation events and contemporaneous alteration and gold mineralization. Ductile D₂ shearing is associated with a pervasively developed distal chlorite–sericite alteration assemblage in the outer parts of the shear zones and the proximal biotite–plagioclase alteration in the center of the shear zones. D₃ is characterized by development of the inner chlorite-K-feldspar alteration, which forms a centimeter-scale alteration halo surrounding the laminated quartz veins and replaces earlier biotite along S₃. The average size of the laminated vein systems is 30–50 m along strike as well as down-dip and 2–6 m in width.Mass balance calculations suggest strong metasomatic changes for the proximal biotite–plagioclase alteration yielding mass and volume increase of ca. 16% and 12%, respectively. The calculated mass and volume changes of the distal chlorite–sericite alteration (ca. 11%, ca. 8%) are lower. The decrease in δ¹⁸O values of the whole rock from around 7.5‰ for the host rocks to 6–7‰ for the distal chlorite–sericite and the proximal biotite–plagioclase alteration and around 5‰ for the inner chlorite-K-feldspar alteration suggests hydrothermal alteration during two-stage deformation and fluid flow.The ductile D₂ deformation in the lower amphibolite facies has provided grain scale porosities by microfracturing. The pervasive, steady-state fluid flow resulted in a disseminated style of gold–sulfide mineralization and a penetrative alteration of the host rocks. Alternating ductile and brittle D₃ deformation during lower to mid greenschist facies conditions followed the fault-valve process. Ductile creep in the shear zones resulted in a low permeability environment leading to fluid pressure build-up. Strongly episodic fluid advection and mass transfer was controlled by repeated seismic fracturing during the formation of laminated quartz(-gold) veins. The limitation of quartz veins to the extent of earlier shear zones indicate the importance of pre-existing anisotropies for fault-valve action and economic gold mineralization.     

Petroleum inclusions in sedimentary basins: systematics, analytical methods and applications

Fluid dynamics in sedimentary basins is of tremendous interest, both from a scientific and an economic point of view. Integration between fluid inclusion and present-day fluid data provides the time aspect necessary for reconstruction of fluid flow paths, and can be used for mapping fluid dynamics both on a regional basin scale or on the more local scale of petroleum reservoirs. This paper presents a review of analytical and modelling methods for petroleum in fluid inclusions. Essentially, four types of data for petroleum inclusions can be established through analysis and modelling: (1) textures (which give indirect information of the time aspect), (2) fluid composition, (3) fluid properties and (4) pressure–temperature of trapping. During the last decade, development of analytical methods for determination of inclusion fluid compositions has taken place. Traditional correlation studies for characterisation of maturity and source facies may now therefore include fluid inclusion data. The development has also been directed towards an improved understanding of the physical properties of petroleum inclusions. Although these methods are in their early stages concerning precision and accuracy, data necessary for fluid flow modelling, such as fluid densities, viscosities, pressure and temperature, can be estimated.     

Influence of carbonate facies on fault zone architecture

Normal faults on Malta were studied to analyse fault propagation and evolution in different carbonate facies. Deformation of carbonate facies is controlled by strength, particle size and pore structure. Different deformation styles influence the damage characteristics surrounding faults, and therefore the fault zone architecture. The carbonates were divided into grain- and micrite-dominated carbonate lithofacies. Stronger grain-dominated carbonates show localised deformation, whereas weaker micrite-dominated carbonates show distributed deformation. The weaker micrite-dominated carbonates overlie stronger grain-dominated carbonates, creating a mechanical stratigraphy. A different architecture of damage, the ‘Fracture Splay Zone’ (FSZ), is produced within micrite-dominated carbonates due to this mechanical stratigraphy. Strain accumulates at the point of juxtaposition between the stronger grain-dominated carbonates in the footwall block and the weaker micrite-dominated carbonates in the hanging wall block. New slip surfaces nucleate and grow from these points, developing an asymmetric fault damage zone segment. The development of more slip surfaces within a single fault zone forms a zone of intense deformation, bound between two slip surfaces within the micrite-dominated carbonate lithofacies (i.e., the FSZ). Rather than localisation onto a single slip surface, allowing formation of a continuous fault core, the deformation will be dispersed along several slip surfaces. The dispersed deformation can create a highly permeable zone, rather than a baffle/seal, in the micrite-dominated carbonate lithofacies. The formation of a Fracture Splay Zone will therefore affect the sealing potential of the fault zone. The FSZ, by contrast, is not observed in the majority of the grain-dominated carbonates.     

Effects of magnetic interactions in anisotropy of magnetic susceptibility: Models, experiments and implications for igneous rock fabrics quantification

Besides granites of the ilmenite series, in which the anisotropy of magnetic susceptibility (AMS) is mainly controlled by paramagnetic minerals, the AMS of igneous rocks is commonly interpreted as the result of the shape-preferred orientation of unequant ferromagnetic grains. In a few instances, the anisotropy due to the distribution of ferromagnetic grains, irrespective of their shape, has also been proposed as an important AMS source. Former analytical models that consider infinite geometry of identical and uniformly magnetized and coaxial particles confirm that shape fabric may be overcome by dipolar contributions if neighboring grains are close enough to each other to magnetically interact. On these bases we present and experimentally validate a two-grain macroscopic numerical model in which each grain carries its own magnetic anisotropy, volume, orientation and location in space. Compared with analytical predictions and available experiments, our results allow to list and quantify the factors that affect the effects of magnetic interactions. In particular, we discuss the effects of (i) the infinite geometry used in the analytical models, (ii) the intrinsic shape anisotropy of the grains, (iii) the relative orientation in space of the grains, and (iv) the spatial distribution of grains with a particular focus on the inter-grain distance distribution. Using documented case studies, these findings are summarized and discussed in the framework of the generalized total AMS tensor recently introduced by Cañon-Tapia (Cañon-Tapia, E., 2001. Factors affecting the relative importance of shape and distribution anisotropy in rocks: theory and experiments. Tectonophysics, 340, 117–131.). The most important result of our work is that analytical models far overestimate the role of magnetic interaction in rock fabric quantification. Considering natural rocks as an assemblage of interacting and non-interacting grains, and that the effects of interaction are reduced by (i) the finite geometry of the interacting clusters, (ii) the relative orientation between interacting grains, (iii) their heterogeneity in orientation, shape and bulk susceptibility, and (iv) their inter-distance distribution, we reconcile analytical models and experiments with real case studies that minimize the role of magnetic interaction onto the measured AMS. Limitations of our results are discussed and guidelines are provided for the use of AMS in geological interpretation of igneous rock fabrics where magnetic interactions are likely to occur.     

Evidence of multi-stage faulting by clay mineral analysis: Example in a normal fault zone affecting arkosic sandstones (Annot sandstones)

Fault affecting silicoclastic sediments are commonly enriched in clay minerals. Clays are sensitive to fluid–rock interactions and deformation mechanisms; in this paper, they are used as proxy for fault activity and behavior. The present study focuses on clay mineral assemblages from the Point Vert normal fault zone located in the Annot sandstones, a Priabonian-Rupelian turbidite succession of the Alpine foredeep in SE France. In this area, the Annot sandstones were buried around 6–8 km below the front of Alpine nappes soon after their deposition and exhumed during the middle-late Miocene. The fault affects arkosic sandstone beds alternating with pelitic layers, and displays throw of about thirty meters. The fault core zone comprises intensely foliated sandstones bounding a corridor of gouge about 20 cm thick. The foliated sandstones display clay concentration along S–C structures characterized by dissolution of K-feldspar and their replacement by mica, associated with quartz pressure solution, intense microfracturation and quartz vein precipitation. The gouge is formed by a clayey matrix containing fragments of foliated sandstones and pelites. However, a detailed petrographical investigation suggests complex polyphase deformation processes. Optical and SEM observations show that the clay minerals fraction of all studied rocks (pelites and sandstones from the damage and core zones of the fault) is dominated by white micas and chlorite. These minerals have two different origins: detrital and newly-formed. Detrital micas are identified by their larger shape and their chemical composition with a lower Fe–Mg content than the newly-formed white micas. In the foliated sandstones, newly-formed white micas are concentrated along S–C structures or replace K-feldspar. Both types of newly formed micas display the same chemical composition confirmed microstructural observations suggesting that they formed in the same conditions. They have the following structural formulas: Na_0.05 K_0.86 (Al _1.77 Fe_0.08 Mg_0.15) (Si_3.22 Al_0.78) O₁₀ (OH)_2. They are enriched in Fe and Mg compared to the detrital micas. Newly-formed chlorites are associated with micas along the shear planes. According to microprobe analyses, they present the following structural formula: (Al_1,48 Fe_2,50 Mg_1,84) (Si_2,82 Al_1,18) O₁₀ (OH)₈. All these data suggest that these clay minerals are synkinematic and registered the fault activity. In the gouge samples, illite and chlorite are the major clay minerals; smectite is locally present in some samples.In the foliated sandstones, Kubler Index (KI) ((001) XRD peak width at half height) data and thermodynamic calculations from synkinematic chlorite chemistry suggest that the main fault deformation occurred under temperatures around 220 °C (diagenesis to anchizone boundary). KI measured on pelites and sandstones from the hanging and footwall, display similar values coherent with the maximal burial temperature of the Annot sandstones in this area. The gouge samples have a higher KI index, which could be explained by a reactivation of the fault at lower temperatures during the exhumation of the Annot sandstones formation.     

Geochemical characterisation, provenance, source and depositional environment of ‘Roches Argilo-Talqueuses’ (RAT) and Mines Subgroups sedimentary rocks in the Neoproterozoic Katangan Belt (Congo): Lithostratigraphic implications

The chemical characteristics of sedimentary rocks provide important clues to their provenance and depositional environments. Chemical analyses of 192 samples of Katangan sedimentary rocks from Kolwezi, Kambove–Kabolela and Luiswishi in the central African Copperbelt (Katanga, Congo) are used to constrain (1) the source and depositional environment of RAT and Mines Subgroup sedimentary rocks and (2) the geochemical relations between the rocks from these units and the debate on the lithostratigraphic position of the RAT Subgroup within the Katangan sedimentary succession. The geochemical data indicate that RAT, D. Strat., RSF and RSC are extremely poor in alkalis and very rich in MgO. SD are richer in alkalis, especially K₂O. Geochemical characteristics of RAT and Mines Subgroups sedimentary rocks indicate deposition under an evaporitic environment that evolved from oxidizing (Red RAT) to reducing (Grey RAT and Mines Subgroup) conditions. There is no chemical difference between RAT and fine-grained clastic rocks from the lower part of the Mines Subgroup. The geochemical data preclude the genetic model that RAT are syn-orogenic sedimentary rocks originating from Mines Group rocks by erosion and gravity-induced fragmentation in front of advancing nappes.     

Compartmentalisation of fluid migration pathways in the sub-Andean Zone, Bolivia

Numerous observations indicate that faults play a major role on the migration pathways of fluids in the Bolivian sub-Andean Zone. Most oil seeps in the foothills are located on faults, but oil fields in the foredeep are closed by faults. In the foothills, analysis of cements in fractures inside and around fault zones indicates that the faults act as barriers for transversal migration but can be preferential lateral migration pathways for both hydrocarbons and water. A detailed study of these apparent contradictions suggests that the hydraulic behaviour of faults changes with depth in relation with sandstone diagenesis, but it is strain-independent. From microstructural analyses of fault zones, we suggest that the main controlling factor is temperature, which facilitates or inhibits quartz precipitation. This result implies that the same fault is a barrier for lateral and transversal migration at depths >3 km, due to sealing of fractures by authigenic quartz at T>80 °C, and is a lateral drain in its shallower parts. As a result, the various thrust sheets are isolated from a hydraulic point of view, whereas migration in the foreland may take place over long distances (>100 km).     

Deformation features within an active normal fault zone in carbonate rocks: The Gubbio fault (Central Apennines, Italy)

The Gubbio fault is an active normal fault defined by an important morphological scarp and normal fault focal mechanism solutions. This fault truncates the inherited Miocene Gubbio anticline and juxtaposes Mesozoic limestones in the footwall against Quaternary lacustrine deposits in the hanging wall. The offset is more than 2000 m of geological throw accumulated during a poly-phased history, as suggested by previous works, and has generated a complex zone of carbonate-rich fault-related structures. We report the results of a multidisciplinary study that integrates detailed outcrop and petrographic analysis of two well-exposed areas along the Gubbio fault zone, geochemical analysis (fluid inclusions, stable isotopes, and trace elements) of calcite-sealed fault-related structures and fault rocks, and biostratigraphic controls. Our aims are: (i) the characterization of the deformation features and their spatial–temporal relationships, and (ii) the determination of the P/T conditions and the fluid behaviour during deformation to achieve a better understanding of fluid–rock interaction in fault zones.We show that few of the observed structures can be attributed to an inherited shortening phase while the most abundant structures and fault rocks are related to extensional tectonics. The outcropping extensional patterns formed at depths less than 2.5–3 km, in a confined fluid system isolated from meteoric water, and the fault structures are the response to a small amount of cumulated displacement, 12–19% of the total geological throw.     

K-Ar dating of episodic Mesozoic fluid migrations along the fault system of Gernsbach between the Moldanubian and Saxothuringian (Northern Black Forest,Germany)

Along the SW-NE trending fault zone of Gernsbach (northern Black Forest), over a distance of about 45 km between Baden-Baden and Pforzheim, basal series of the sedimentary cover are extensively altered by hydrothermal solutions. The fluids were conveyed in the fault zone and because of favourable permeabilities they spread out along the unconformity between the basement and sedimentary cover. K-Ar dates on authigenic white micas (illites) and hydrothermally altered detrital micas point to the occurrence of two major episodes of fluid migration. The extensive alteration along the entire fault system occurred about 150 Ma ago during the Jurassic. In relation to these hydrothermal activities, the epigenetic strata-bound uranium deposit of Müllenbach originated in Upper Carboniferous sediments near the fault and the fluorite-quartz vein-type mineralization of Käfersteige was formed along the fault about 100 Ma ago during the Cretaceous. The results indicate various geological processes of the fault system of Gernsbach, which is located between the Saxothuringian and Moldanubian zone. The mobilization of the fluids and the formation of the ore deposits were probably caused by and connected with tectonic activities in mid-Europe.     

Reaction textures in Proterozoic calcsilicates from northern Guinea: a record of the fluid evolution

Proterozoic calcsilicate rocks in contact with the different types of granite from the granitic belt of northern Guinea show particular mineral assemblages, recording different steps of the tectono-metamorphic and magmatic evolution of the area. Petrological study provides evidence of a clockwise metamorphic P–T path with a metamorphic peak at temperature around 800 °C and pressure of 4–6 kb, corresponding to the emplacement of both generations of massive granite between 2115 and 2075 Ma. Retrograde metamorphism is characterized by decompression to 2–3 kb, associated with the emplacement of late small granite stocks and followed by cooling until 450–600 °C. Hydrothermal alteration involved by late fluid circulation is only weakly developed and limited to calcsilicate/granite contact (specially small stocks) and shear zones. Early fluids were essentially metamorphic and magmatic fluids, largely buffered by calcsilicate mineral assemblages, whereas surface-derived fluids were introduced at the end of the tectonic evolution via shear-zones.     

冷水碳酸盐岩研究现状与展望

长期以来,海相碳酸盐沉积物被广泛认为是温暖浅海沉积环境中的产物,然而近年来国外研究表明,在冷水陆架环境中,也可以形成规模的碳酸盐沉积,即冷水碳酸盐岩。通过对大量文献的调研,综述了冷水碳酸盐岩的概念、地质特征、沉积模式等方面的研究进展,并展望了该研究领域未来的发展方向。研究表明,冷水碳酸盐沉积是指在(古)纬度约30°~35°以上的温带及寒带地区、温度约20℃以下的沉积水体中,或是在富营养的寒冷上升流水体中形成的碳酸盐沉积物或岩石,其沉积特征与暖水碳酸盐岩不同。冷水碳酸盐沉积物中的生物颗粒组合以底栖有孔虫、软体动物、苔藓虫等异养生物和钙质红藻为主,缺乏造礁珊瑚和钙质绿藻以及鲕粒、集合颗粒等非骨架颗粒,而且沉积物中灰泥基质含量较少,矿物成分以方解石为主,氧同位素较重,胶结作用弱,以破坏性成岩作用为主。冷水碳酸盐沉积形态以缓坡为主,波浪磨蚀和再沉积作用较强。古代冷水碳酸盐岩的沉积特征、识别标志及其作为储层的油气资源潜力尚处于探索阶段,仍需进一步深入研究。