Development of engineering geology in western United States

Geologic concepts and scientific-technical guidance for the planning-design and construction of engineered works was recognized in Europe by the 1800s and by the early 1900s in North America. This early geologic knowledge and experience provided the rudimentary principles that guided practitioners of the 19th century in serving the emerging projects in western United States. Case studies review the scientific-technical lessons learned and the legacy of geologic principles established in the planning and construction of major civil, mining, and military engineered works in the western states. These contributions to GeoScience knowledge and engineering geology practice include:

• •Tunnels and aqueducts across active fault zones, beneath young volcanic features, groundwater-charged faults, and land subsidence mitigation.
• •Controversial foundation design, Folsom and Auburn dams, Golden Gate Bridge.
• •Protective underground construction chambers, safety dependent geologic setting.
• •Geologic mapping as database management leasing, maintenance railroad trackway.
• •Causeway Great Salt Lake, geo-risks calculated, mitigated ‘as-constructed’.
• •Nuclear powerplants seismic design.
• •Urban Land-Use, on-going processes, acceptable geo-risks.
• •Dwelling Insurance, insuree's responsibilities.
• •Selecting technique/method to mitigate risk, preferably based on extensive database, evaluation of characteristics and historical origin adverse features/conditions that constitute a geo-risk.

     

Seismic patterns in Northern China and the characteristics of the epicentral distribution of the medium strong earthquakes before the large events

In this paper, the seismic pattern in Northern China from 30 ° to 42 ° N latitude and 104 ° to 125 ° E longitude, and the characteristics of the epicentral distribution before large events are presented. The results suggest that:

• 1.(1) the earthquakes in the region are mainly located in the orthogonal curvilinear network formed by the seismic belts;
• 2.(2) the larger earthquakes (M ⩾6) occurred mainly in the nodal regions of this grid:
• 3.(3) the strike of the fracture planes of the earthquakes coincided with the directions of the seismic belts;
• 4.(4) the pattern of medium strong earthquakes (M ⩾ 4.7) prior to thirteen large earthquakes (M⩾ 7) are analysed to be of three types:
  • 4.1.(a) mainly arranged along the two intersecting belts,
  • 4.2.(b) randomly distributed,
  • 4.3.(3) forming seismic gaps.

A theoretical basis and rules for drawing the orthogonal grid is presented, and an idea for the prediction of the sites of future earthquakes in Northern China is suggested.     

Multivariate mixing and mass balance (M3) calculations,a new tool for decoding hydrogeochemical information

To support and help hydrochemical evaluation a multivariate mathematical tool named M3 (Multivariate Mixing and Mass balance calculations) has been created within the Äspö Hard Rock Laboratory Research Programme. The computer code can be used to trace the origin of the groundwater and calculate the mixing portions and mass balances from ambiguous groundwater data. Groundwater composition data used traditionally to describe the reactions taking place in the bedrock can now be used to trace the effect from present and past groundwater flow with increased accuracy. The M3 model consists of the following 3 steps:

• •Multivariate analysis, called Principal Component Analysis (PCA) is used to summarise the information from the data set. The summarised information shown in the PCA plots is used for finding relationships, patterns, extreme waters and for further M3 modelling.
• •From the PCA plot mixing calculations are used to calculate the effect of the groundwater mixing on the obtained groundwater composition. This so-called ideal mixing model is used to calculate the mixing proportions given in %, for all the groundwater samples.
• •The final step in M3 calculations is the mass balance calculations. Deviations from the ideal mixing model are used to trace the sources and sinks of elements, given in mg/l, which can be due to mass balance reactions.

The tested margin of error of the model is ±10% for the Äspö site data, but depends on the data to be modelled. A mixing portion of less than 10% is regarded as under the detection limit of the model and such calculations are therefore uncertain. This method can be used to trace the origin and calculate the mixing portions and effects from the reactions on the observed groundwater composition with a higher resolution and convenience compared to many standard methods.     

Ore mineralization related to geological evolution of the Karkonosze–Izera Massif (the Sudetes,Poland) — Towards a model

The Karkonosze–Izera Massif is a large tectonic unit located in the northern periphery of the Bohemian Massif. It includes the Variscan Karkonosze Granite (about 328–304 Ma) surrounded by the following four older units:

• -Izera–Kowary (the Early Paleozoic continental crust of the Saxothuringian Basin),
• -Ještĕd (the Middle Devonian to Lower Viséan sedimentary succession deposited on the NE passive margin of the Saxothuringian Terrane), out of the present study area,
• -Southern Karkonosze (metamorphosed sediments and volcanics filling the Saxothuringian Basin), out of the present study area,
• -Leszczyniec (Early Ordovician, obducted fragment of Saxothuringian Basin sea floor).

The authors present a genetic model of ore mineralization in the Karkonosze–Izera Massif, in which ore deposits and ore minerals occurrences are related to the successive episodes of the geological history of the Karkonosze–Izera Massif:

• -formation of the Saxothuringian Basin and its passive continental margin (about 500–490 Ma)
• -Variscan thermal events:
  • -regional metamorphism (360–340 Ma)
  • -Karkonosze Granite intrusion (328–304 Ma)
• -Late Cretaceous and Neogene-to-Recent hypergenic processes.

The oldest ore deposits and ore minerals occurrences of the Karkonosze–Izera Massif are represented by pyrite and magnetite deposits hosted in the Leszczyniec Unit as well as by magnetite deposit and, presumably, by a small part of tin mineralization hosted in the Izera–Kowary Unit. All these deposits and occurrences were subjected to the pre-Variscan regional metamorphism.Most of the Karkonosze–Izera Massif ore deposits and occurrences are related to the Karkonosze Granite intrusion. This group includes a spatially diversified assemblage of small ore deposits and ore mineral occurrences of: Fe, Cu, Sn, As, U, Co, Au, Ag, Pb, Ni, Bi, Zn, Sb, Se, S, Th, REE, Mo, W and Hg located within the granite and in granite-related pegmatites, in the close contact aureole of the granite and within the metamorphic envelope, at various distances from the granite. Assuming world standards, all these deposits are now uneconomic. Various age determinations indicated that ore formation connected with the Karkonosze Granite might have taken place mostly between about 326 and 270 Ma.The last ore-forming episode in the Karkonosze–Izera Massif is related to hypergenic processes, particularly important in the northern part of the massif, in the Izera–Kowary Unit where some uranium deposits and occurrences resulted from the infiltration of ore solutions that originated from the weathering of pre-existing accumulations of uranium minerals. A separate problem is the presence of oxidation zones of ore deposits and occurrences, both the fossil and the recent.A full list of ore minerals identified in described deposits and occurrences of the Karkonosze–Izera Massif together with relevant, key references is presented in the form of an appendix.     

Influence of upwelling Zechstein sulphate on the concentration and isotope signature of sedimentary sulphides in a fluvioglacial sand aquifer

Very low concentrations of total S, mainly sedimentary sulphides, were quantitatively extracted from Quaternary sands of the Elbe Basin, using HNO₃, Br₂ and HCl, to distinguish 3 aquifer zones:

• •an upper aerobic section, containing low concentrations (only a few ppm) of non-sulphidic S compounds,
• •the central and lower part of the aquifer, dominated by ³⁴S-depleted sedimentary Fe sulphides, formed by reduction of infiltrating SO₄, derived from groundwater recharge, and
• •the lowest 5–10 m of the aquifer, containing high concentrations of ³⁴S-enriched sulphides.

The latter originated from dissolved Zechstein SO₄, which was reduced during upwelling through the organic-rich Tertiary aquiclude. H₂S and HS⁻ reacted and precipitated with Fe and other metal ions shortly after migration into the C_org-poor Quaternary aquifer. The sulphides yield valuable information concerning the ascent of confined saline solutions from isolated Zechstein evaporites inside the “Mühlberger Graben”, which is covered by Cenozoic sediments and whose extension and boundaries are therefore not well defined. Only a few locations, close to faults and geological windows, show deep-water admixture sufficiently strong to cause visible changes in hydrochemistry and isotopic ratios of SO₄ and DIC directly above the base of the Quaternary. Sulphides showing different origins may possibly be used in other areas to provide information concerning underlying geology and hydrodynamics.     

A quantitative fluorescence technique for evaluating thermal maturity: Instrumentation and examples

Fluorescence microscopy is useful not only for identifying most of the oil-prone organic matter (macerals) in sedimentary rocks and coals but also for assessing their thermal maturities (ranks). This report introduces a violet-light excitation system which induces more than one order of magnitude stronger fluorescence intensity that the commonly used UV-light excitation system. The red/green quotient from violet-light excited fluorescence, Q_v, of sporinite can be easily measured using this system. Several examples using coal and cuttings samples are presented to demonstrate the use of this technique for evaluating the thermal maturities of coals and sedimentary rocks.From the results of our studies we conclude that:

• 1.(1) Violet-light excited fluorescence from sporinites can be routinely measured to assess thermal maturity.
• 2.(2) Spectral (Quantitative) fluorescence technique is useful for evaluating thermal maturity when samples are poorly polished or deficient in vitrinite.
• 3.(3) Visual (Strew-mounted) kerogen slides can not be used for fluorescence measurements unless a non-fluorescent mounting medium is used.

     

Chemical modelling of kerogens

Models of kerogens belonging to the three classical Types have been represented at the following evolution stages:

• •-beginning of diagenesis (sensu-stricto),
• •-beginning of catagenesis,
• •-end of catagenesis.

Chemical models are drawn, using analytical data obtained on natural samples: elemental analysis, electron microscopy, ¹³C NMR, thermogravimetry, functional analysis and pyrolysis.In order both to get a statistical representation and make comparisons easier, the same molecular weight of about 25,000 has been chosen for the different models of kerogens at the beginning of the diagenesis stage.     

Mineralogy and petrology of alkaline granophyric xenoliths from the Thorsmörk ignimbrite,southern Iceland

The Thorsmörk ignimbrite, southern Iceland, contains a suite of granophyre xenoliths displaying magmatic or high-temperature sub-solidus mineral assemblages. These granophyres are consanguineous with the erupting comenditic magma. Four types of mineral assemblages are distinguished:

• 1.(A) oligoclase, edenitic hornblende, salitic pyroxene, magnesian biotite, magnetite and sphene;
• 2.(B) oligoclase, manganoan to sodic ferro-augite, fayalite, richterite, ilmenite and magnetite;
• 3.(C) anorthoclase, ferrohedenbergite to aegirine hedenbergite, ilmenite, magnetite and (riebeckite);
• 4.(D) cryptoperthite, aegirine hedenbergite to (aegirine), aenigmatite, arfvedsonite, ilmenite and magnetite.

Geothermometry shows that the xenoliths have crystallized between 900°C and 500°C at moderate oxygen fugacities, just above the FMQ buffer. It is further demonstrated that a hot vapour phase heavily charged with sodium and halogens, played a major role in the late sub-solidus crystallization of the different types.     

Buckling loads of fully embedded vertical piles

Determination of critical buckling loads of columns in a medium which offers resistance to lateral deflections depend on:

• (a) Length of the pile, L.
• (b) Flexural stiffness of the pile, EI.
• (c) Stiffness of the soil, K, and
• (d) Boundary conditions of the pile, both at the top and the tip.

In this paper, solutions for buckling loads have been obtained in closed form by energy methods for fully embedded vertical piles for boundary conditions, pinned top-pinned tip, fixed top-fixed tip, and a linear variation of soil stiffness. The effects of pile length, soil stiffness, and boundary conditions on buckling loads and mode of buckling have been studied for pile lengths up to 24 m with EI of 477 tm², K₀ [A] from 0 to 2000 t/m² and N_h [B] from 0 to 2000 t/m³.     

Coprecipitation of alkali metal ions with calcium carbonate

The coprecipitation of alkali metal ions (Li⁺, Na⁺, K⁺ and Rb⁺) with calcium carbonate has been studied experimentally and the following results have been obtained:

• 1.(1) Alkali metal ions are more easily coprecipitated with aragonite than with calcite.
• 2.(2) The relationship between the amounts of alkali metal ions coprecipitated with aragonite and their ionic radii shows a parabolic curve with a peak located at Na⁺ which has approximately the same ionic radius as Ca²⁺.
• 3.(3) However, the amounts of alkali metal ions coprecipitated with calcite decrease with increasing ionic radius of alkali metals.
• 4.(4) Our results support the hypothesis that
  • 4.1.(a) alkali metals are in interstitial positions in the crystal structure of calcite and do not substitute for Ca²⁺ in the lattice, but
  • 4.2.(b) in aragonite, alkali metals substitute for Ca²⁺ in the crystal structure.
• 5.(5) Magnesium ions in the parent solution increase the amounts of alkali metal ions (Li⁺, Na⁺, K⁺ and Rb⁺) coprecipitated with calcite but decrease those with aragonite.
• 6.(6) Sodium-bearing aragonite decreases the incorporation of other alkali metal ions (Li⁺, K⁺ and Rb⁺) into the aragonite.

     

Nature of particulate organic matter in the River Indus,Pakistan

Suspended sediments from the Indus River collected during 1981 through 1983 were analyzed for POC and its constituent fractions including amino acids, amino sugars and sugars. Percentage of POC decreased with increasing suspended matter concentrations, which suggested dilution of organic matter by mineral matter.The concentrations of amino acids, amino sugars and sugars varied, respectively, between 180 and 2000 μg/l, 5 and 125 μg/l, and 60 and 1100 μg/l. Their contributions to POC varied between 2 and 60% for amino acids and amino sugars, and between 2 and 15% for sugars. They were high during low sediment discharge (February to June), and low during high sediment discharge (August and September). Suspended sediments associated with high sediment discharge periods were characterized by low ratios of:

• 1.(i) aspartic acid:β-alanine
• 2.(ii) glutamic acid:γ-aminobutyric acid
• 3.(iii) amino acids:amino sugars
• 4.(iv) hexoses:pentoses. These and the relative distribution pattern of the monosaccharides such as galactose, arabinose, mannose and xylose indicated that, not only dilution, but also differences in the sources and processes affect the POC transport in the Indus River. These result in transport of biodegraded organic matter during high sediment discharge periods: this appears to be common to other major rivers of the region, with depositional centers in deep sea areas. These rivers, with their high sediment loads, could contribute up to 8 to 11% of the global annual organic carbon burial in marine sediments.

     

Structural evolution of the Téfidet trough (East Aïr,Niger) in relation with the West African Cretaceous and Paleogene rifting and compression episodes

Located in northern Niger, the NW–SE Téfidet trough is the western branch of the Ténéré rift megasystem.Here we present a tectono-sedimentary analysis of the Téfidet trough, based on the combined use of satellite imagery, field observations and measures, and available literature. We use these data to analyse the sedimentary facies and the tectonic deformations (faults, folds, basins) in the Téfidet trough, and derive their relative chronology. Doing so, we characterize synrift and postrift deformations and their interactions with sedimentation.Altogether our analyses suggest that the Téfidet trough was affected from the Cretaceous to the Paleogene by three major tectonic periods.

• •The first period was a rifting stage with extension and transtension during the Albian–Aptian times. The mean extension was ∼N60° and dominantly produced NW–SE-trending normal faults, a few strike-slip faults locally associated with small folds with sigmoidal axis and small reverse faults, and progressive unconformities.
• •the second period was also a rifting time, which prevailed during the Upper Cretaceous. The regime was marked by transtensional to extensional tectonics, under a ∼N130° shortening and a ∼N60° trending stretching. The end of this period saw the closure of the Téfidet trough.
• •the third period was a postrift stage. It was characterized by a ∼N70° extensional to transtensional regime during the Oligocene–Pliocene. It mainly produced post-sedimentary extensional faults and fractures and alkaline volcanism. We eventually discuss these deformation phases in relation with the Cretaceous Gondwana breakup and its related rifting events in West and North Africa, and with the subsequent Africa–Europe collision.

     

The geothermal gradient map of Central Tunisia: Comparison with structural,gravimetric and petroleum data

Five hundred and fifty temperature values, initially measured as either bottom-hole temperatures (BHT) or drill-stem tests (DST), from 98 selected petroleum exploration wells form the basis of a geothermal gradient map of central Tunisia. A “global-statistical” method was employed to correct the BHT measurements, using the DST as references. The geothermal gradient ranges from 23° to 49°C/km. Comparison of the geothermal gradient with structural, gravimetric and petroleum data indicates that:

• 1.(1) the general trend of the geothermal gradient curves reflects the main structural directions of the region,
• 2.(2) zones of low and high geothermal gradient are correlated with zones of negative and positive Bouguer anomalies and
• 3.(3) the five most important oil fields of central Tunisia are located near the geothermal gradient curve of 40° C/km.

Such associations could have practical importance in petroleum exploration, but their significance must first be established through further investigation and additional data.     

Great earthquakes,seismicity gaps and potential for earthquake disaster along the Himalaya plate boundary

Analysis of the space-time patterns of seismicity in the Himalaya plate boundary has established the existence of three seismic gaps:

• 1.(1) The “Kashmir gap” lying west of the 1905 Kangra earthquake;
• 2.(2) the “Central gap”, situated between the 1905 Kangra and the 1934 Bihar earthquakes;
• 3.(3) the “Assam gap” between the 1897 and 1950 Assam earthquakes.

This study has shown that the above great earthquakes were preceded as well as followed by long periods (⩾ 19 years) of decreased levels of seismic activity in the epicentral regions. Remarkable decrease in the seismicity following the year 1970 has been observed in the western half of the Central gap as well as in the Assam gap. Local seismic investigation in the Assam gap confirms this feature and the seismicity suggests the existence there of an asperity.The local seismic investigations in Garhwal Himalaya have shown that the small earthquakes are confined to the upper 6–8 km of the crust and may have strike-slip motions. These earthquakes occur in a region where teleseismically recorded events were few.     

Evaluation of the thermal regime of the Valles Caldera,New Mexico,U.S.A., by downward continuation of temperature data

Downward continuation of temperature data from 73 wells extending to depths of 250 ft (76 m) provides constraints on the thermal regime of the Valles Caldera. Surface-temperature gradient data and bottom-hole temperatures were used as constraints in the downward continuation. Three factors were found to control the shallow thermal regime:

• 1.(1) heat associated with the main geothermal source;
• 2.(2) local topography; and
• 3.(3) west-southwest groundwater flow. Although the well density is relatively high, comparison with the topography shows that the wells are not randomly distributed and tend to be clustered in valleys. Many details in the thermal regime appear to be related to groundwater drainage in these valleys. Temperature gradients and temperatures generally increase in the same direction as the regional drainage of the caldera suggesting a long-wavelength, shallow component to this regional gradient trend. Inversion of gradient and temperature data show additional deep heat input in the west-southwest sector of the caldera which appears to be spatially associated to the youngest volcanism. A previously reported northeast displacement of the main heat source from the surface anomaly has not been confirmed.

     

The 1983, M 5.9 earthquake of Heze,Shandong Province,with its short-term and imminent precursory phenomena

An earthquake (M = 5.9) occurred on November 7, 1983 in the Heze area, Shandong Province (35°17′ N, 115°17∃, H = 12 km). This earthquake belongs to the isolated type of earthquakes. There were no foreshocks; the aftershocks were few in number with their energy decreasing quickly.Within the area surrounding the main shock and up to about 200 km from the epicenter, several types of short-term and imminent anomalies were observed. The major characteristics of the anomalies are as follows:The short-term and imminent anomalies are relatively few in number. The maximum radius of the area where the anomalies occur is about 150–200 km from the epicenter. The time durations of what have been called short-term and imminent anomalies here are small, being

• 1.(1) from 10–20 days to 3–4 months and
• 2.(2) from 1–2 hours to 2–3 days, respectively. The premonitory information was scanty.

Finally, the procedure to recognize the indications of a moderate earthquake is discussed.     

Geochemistry of uranium in sediments of the Bohai Gulf,China

The following conclusions can be drawn from the work reported in this paper:

1. Sixteen samples were determined for uranium by spectrophotometric method. The uranium content in the sea floor sediments of the Bohai Gulf ranges from 1.6 to 6.3 ppm, with an average of 4.3 ppm.
2. Statistical data show close relationship between U concentration and grain size. Relatively larger amount of uranium was found accumulated in mud than in sand. The bulk of uranium is assumed to be derived from terrestrial detrital minerals.
3. A positive correlation between U and Fe is recognized. Similar relation also can be seen between U and Al. The plot of U concentration vs. Fe is linear, and can be expressed by the linear regression equation:Y=?0.37+1.35X. The plot of U against Al gives an equation ofY=?2.48+1.01X.
4. The average U/C_org. ratio for these sediments is 7×10^?4, and the average ratios of U/P, U/Mn, and U/CaCO₃ are 100×10^?4, 50×10^?4 and 2×10^?4, respectively.
5. Compared with the abundances of other shelf sediments, the average concentration of U in the area under consideration is close to that of sediments on the selves of Japan and the Gulf of Mexico, and the Black Sea. Uranium concentration in the Bohai Gulf sediments is comparable to that of the continental crust, but differs from that of deep-sea clay.

     

Tectonoelectric zonation in the Hellenic Arc

The electrical (apparent) resistivities ρ were measured by means of the magnetotelluric effect at twenty sites in Greece and in two directions, E-W and N-S. In most of the sites, ρ_EW differs considerably from ρ_NS. These results allow the following three zones to be distinguished:

• 1.(1) an external zone along western Greece with ρ_EW >ρ_NS;
• 2.(2) an intermediate zone along the main mountain chain in continental Greece where ρ_Ns >ρ_EW and
• 3.(3) an internal zone in the northern Aegean where ρ_EW >ρ_NS.

The above resistivity zones are compared to data from geotectonic, neotectonic, seismotectonic and in situ stress measurements which all show a similar geometry of zonation almost parallel to the active Hellenic Arc.     

Chondrules in the Murray CM2 meteorite and compositional differences between CM-CO and ordinary chondrite chondrules

Bulk compositions were determined by broad-beam electron microprobe analysis for thirteen of the least aqueously altered chondrules in Murray (CM2). These and literature data reveal compositional differences between CM-CO and ordinary chondrite (OC) chondrules:

• 1.(a) CO chondrules are richer in refractory lithophiles and poorer in Cr, Mn and volatile lithophiles than OC chondrules; much lower refractory lithophile abundances in CM chondrules resulted from aqueous alteration,
• 2.(b) in CM-CO chondrites, abundances of refractory lithophiles are higher in nonporphyritic than porphyritic chondrules, whereas in H-L-LL3 chondrites the converse is true,
• 3.(c) Cr ranges are greater and Cr and Mn correlate more strongly in chondrules in CM-CO than in H-L-LL3 chondrites.

We find evidence for two important lithophile precursor components of CM-CO chondrite chondrules:

• 1.(1) pyroxene- and refractory-rich, FeO-poor;
• 2.(2) olivine-rich, refractory and FeO-poor.

The occurrence of a few FeO-rich chondrules attests to a third component similar to matrix: olivine- and FeO-rich, refractories not characterized. The first two components differ from those inferred for OC chondrules, consistent with formation at different locations. The pyroxene- and refractory-rich, FeO-poor lithophile precursor component probably formed by an incomplete evaporation of presolar silicates that brought these materials into the enstatite stability field.     

Aridification — Climate change in South-Eastern Europe

Climatic change in SE Europe can be characterized by the term aridification, which means increasing semi-aridity, manifested in an increase of mean annual temperature and at the same time in a decrease in the yearly precipitation.The paper deals with research results obtained within the framework of the MEDALUS II project (funded by the Commission of the European Communities). The project had the following objectives:

• 1.(i) Assessment of the impact of global change on the climate of the investigated area, including possible future climates.
• 2.(ii) Physical processes of aridification, including studies of groundwater level change, soil moisture profile dynamics, soil development, vegetation change and soil erosion.
• 3.(iii) Land use change, involving research on present land use and suggestions for the future.

Various methods were applied with respect to the different research objectives.

• 1.(i) Statistical analysis of climatic oscillations and computer runs of climatic scenarios,
• 2.(ii) Analysis of ground water data, mapping and analysis of soils and vegetation, assessment of present and future soil, and
• 3.(iii) Land capability assessment through ranking environmental conditions according to the demands of the most widely grown arable crops in Hungary.

According to our results i) the average annual warming during the last 110 years was +0.0105 °C, and precipitation decreased by 0.917 mm/year; ii) a decline of −2 to −4 m in the annual mean groundwater level can be detected in the most sensitive areas, with gradual lowering of the water table in alkali ponds; complete desiccation of some of them severs the direct contact between groundwater and salt-affected soils, the solonchak soil dynamics cease, helophile and hygrophile plant associations disappear, and consequent changes in the soil erosion regime are likely to lead to disastrous erosion in the future; iii) the climatic changes induce a transformation in land use from arable crops to plantations, starting with orchards.