义敦岛弧晚白垩世斑岩成矿系统

义敦岛弧晚白垩世花岗(斑)岩及其相关成矿系统发育,呈南北向展布,且由北向南呈规律性变化,形成北段昌台弧、中段乡城弧和南段中甸弧3个子系统:(1)北段昌台弧发育97~93Ma的斑状二长花岗岩岩基和矽卡岩型锡矿床,岩体侵位于乡城-格咱断裂与甘孜-理塘断裂的交汇地带,表现了较宽的主量元素变化范围,属于高钾钙碱性-钾玄质的过铝质系列,稀土配分模式较平坦、具有负Eu异常,锡矿化多发育于岩体与上三叠统图姆沟组碳酸盐岩的接触带上;(2)中段乡城弧乡城-格咱断裂两侧发育大量85~77Ma的花岗(斑)岩及斑岩-矽卡岩型Sn-Pb-Zn-Ag多金属矿床,主体岩相为斑状黑云二长花岗岩,是碱性、分异程度高的酸性岩,具典型钾质演化系列,多金属矿化主要发生在岩体与上三叠统图姆沟组碳酸盐岩和变质碎屑岩接触带中,从花岗岩向外为Sn→Pb-Zn,垂向上由深部到浅部依次为含Sn磁铁矿→Sn→Sn-Pb-Zn-Ag;(3)南段中甸弧发育呈岩株出露的88~78Ma的二长花岗斑岩及斑岩-矽卡岩型Cu-Mo-W多金属矿床,休瓦促和热林花岗斑岩体侵入上三叠统喇嘛亚组、拉纳山组砂板岩中,主要发育蚀变花岗岩型和热液石英脉型矿体;红山花岗斑岩体侵入上三叠统图姆沟组碳酸盐岩和变质碎屑岩中,主要发育矽卡岩型矿体。斑岩体中发育角闪石斑晶,铝饱和指数小于1.1,Zr、P与SiO 2呈显著负相关,具有I型花岗岩特征。与晚三叠世同俯冲的弧花岗岩相比,晚白垩世花岗(斑)岩明显偏酸性(SiO 2含量范围为65.06%~76.30%)、富碱质(K2O+Na2O含量范围为6.55%~10.77%)和铝饱和(A/CNK=0.72~1.13);岩浆源区深度变浅,且花岗(斑)岩源区从昌台弧(Eu/Eu*=0.20~0.66,εNd(t)=-6.90~-5.30,εHf(t)=-0.6~1.9)→乡城弧(Eu/Eu*=0.04~0.18,(87Sr/86Sr)i=0.7110~0.7250,εNd(t)=-8.40~-5.54)→中甸弧(Eu/Eu*=0.14~0.88,(87Sr/86Sr)i=0.7075~0.7092,εNd(t)=-8.50~-5.76,εHf(t)=-9.5~-2.2)呈现由中-酸性变沉积地壳到中-基性地壳的变化趋势。这表明义敦岛弧由北向南成矿系统多样性的变化可能与晚白垩世花岗质岩浆的源区有关,即控制花岗岩氧逸度的主要因素是源区性质,岩浆型地壳通常形成氧化型花岗岩及相关的Cu、Mo成矿系统;而沉积型地壳形成还原型花岗岩及相关的Sn、W、Pb、Zn成矿系统。     

Zircon U–Pb geochronology,geochemistry and Hf isotopes of the Late Cretaceous Hongshan intrusion,western Yunnan,SW China

The Hongshan quartz monzonite porphyry is one of the Yanshanian intrusions in the southern part of the Yudun Arc. Detailed zircon U–Pb data of four samples yielded ages of 78.8–80.7 Ma, indicating that the Hongshan intrusion was emplaced during the late stage of Late Cretaceous. The Hongshan intrusion shows shoshonitic and high‐K calc‐alkaline, with A/CNK = 0.64–1.14. The rocks show an obvious fractionation between light and heavy rare‐earth elements (average [La/Yb]_N = 38.85), with negative Eu anomalies (Eu/Eu* = 0.60–0.87), enrichment in large‐ion lithophile elements (Rb, Th, U and K) and depletion in high field‐strength elements (Nb, Ta and P). Rocks have high Sr and low Y content which are characteristics of adakitic rocks, suggesting magma derivation from thickened lower crust. In order to evaluate the nature of the source region, Hf isotope data of zircons were acquired through LA‐MC‐ICPMS. The negative and variable ε_Hf(t) values demonstrate that the Hongshan intrusion was derived from ancient crust, without mantle‐derived components and is significantly different from the Triassic intrusions in the southern part of the Yudun Arc. The three Yanshanian intrusions in Hongshan, Relin and Tongchangou are remarkably similar in terms of geochronology, geochemistry and Hf isotopes. We therefore infer that these intrusions had the same magmatic source and we correlate the tectonics with northward subduction of Tethys underneath the Asian continent. Copyright © 2015 John Wiley & Sons, Ltd.     

Geology,geochemistry and petrogenesis of post-collisional adakitic intrusions and related dikes in the Khoynarood area,NW Iran

The Khoynarood area is located in the northwest of Iran, lying at the northwestern end of the Urumieh–Dokhtar volcano-plutonic belt and being part of the Qaradagh–South Armenia domain. The main intrusive rocks outcropped in the area have compositions ranging from monzonite–quartz monzonite, through granodiorite, to diorite–hornblende diorite, accompanied by several dikes of diorite–quartz diorite and hornblende diorite compositions, which were geochemically studied in order to provide further data and evidence for the geodynamic setting of the region. The SiO₂, Al₂O₃ and MgO contents of these rocks are about 58.32–68.12%, 14.13–18.65% and 0.68–4.27%, respectively. They are characterized by the K₂O/Na₂O ratio of 0.26–0.58, Fe₂O₃ + MnO + MgO + TiO₂ content about 4.27–13.13%, low Y (8–17 ppm) and HREE (e.g., 1–2 ppm Yb) and high Sr contents (750–1330 ppm), as well as high ratios of Ba/La (13.51–50.96), (La/Yb)_N (7–22), Sr/Y (57.56–166.25), Rb/La (1.13–2.96) and La/Yb (10–33.63), which may testify to the adakitic nature of these intrusions. Their chemical composition corresponds to high-silica adakites, displaying enrichments of LREEs and LILEs and preferential depletion of HFSEs, (e.g., Ti, Ta and Nb). The REE differentiation pattern and the low HREE and Y contents might be resulted from the presence of garnet and amphibole in the solid residue of the source rock, while the high Sr content and the negative anomalies of Ti, Ta and Nb may indicate the absence of plagioclase and presence of Fe and Ti oxides in it. As a general scenario, it may be concluded that the adakitic rocks in the Khoynarood were most likely resulted from detachment of the subducting Neo-Tethyan eclogitic slab after subduction cessation between Arabian and Central Iranian plates during the upper Cretaceous–early Cenozoic and partial melting of the detached slab, followed by interactions with metasomatized mantle wedge peridotite and contamination with continental crust.     

Geology and vein tin mineralization in the Dadoushan deposit,Gejiu district,SW China

Vein-type tin mineralization in the Dadoushan deposit, Laochang ore field, Gejiu district, SW China, is predominantly hosted in Triassic carbonate rocks (Gejiu Formation) over cupolas of the unexposed Laochang equigranular granite intrusion. The most common vein mineral is tourmaline, accompanied by skarn minerals (garnet, diopside, epidote, phlogopite) and beryl. The main ore mineral is cassiterite, accompanied by minor chalcopyrite, pyrrhotite, and pyrite, as well as scheelite. The tin ore grade varies with depth, with the highest grades (~1.2 % Sn) prevalent in the lower part of the vein zone. Muscovite ⁴⁰Ar–³⁹Ar dating yielded a plateau age of 82.7 ± 0.7 Ma which defines the age of the vein-type mineralization. Measured sulfur isotope compositions (δ ³⁴S = −4.1 to 3.9 ‰) of the sulfides (arsenopyrite, chalcopyrite, pyrite, and pyrrhotite) indicate that the sulfur in veins is mainly derived from a magmatic source. The sulfur isotope values of the ores are consistent with those from the underlying granite (Laochang equigranular granite, −3.7 to 0.1 ‰) but are different from the carbonate wall rocks of the Gejiu Formation (7.1 to 11.1 ‰). The calculated and measured oxygen and hydrogen isotope compositions of the ore-forming fluids (δ ¹⁸O_H2O = −2.4 to 5.5 ‰, δD = −86 to −77 ‰) suggest an initially magmatic fluid which gradually evolved towards meteoric water during tin mineralization.     

东昆仑野马泉铁矿相关花岗质岩体年代学、地球化学及Hf同位素特征

野马泉大型铁多金属矿床位于东昆仑造山带祁漫塔格地区,矿区发育大量与铁多金属成矿关系密切的花岗质岩体。LA-ICP-MS锆石U-Pb定年表明北矿带隐伏二长花岗岩、花岗闪长岩年龄分别为393±2Ma、386±1Ma;南矿带斑状石英二长闪长岩、正长花岗岩年龄为219±1Ma、213±1Ma,分别为早-中泥盆世和晚三叠世岩浆活动的产物。早-中泥盆世花岗闪长岩与二长花岗岩均为高钾钙碱性,A/CNK值（0.92~1.01）<1.1,具中等强度的负Eu异常（δEu为0.60~0.81）,明显亏损P、Nb、Ta、Ti、Sr、Ba等,富集LREE、Rb、Th、U、K等,显示了I型花岗岩的特征。晚三叠世斑状石英二长闪长岩含有少量角闪石,A/CNK值（0.88~0.95）<1,轻稀土富集,具中等负Eu异常（δEu为0.49~0.67）,富集Rb、U、Th、K等大离子亲石元素,亏损P、Nb、Ta、Ti、Sr、Ba等,具有I型花岗岩的特征;正长花岗岩高硅（SiO₂=77.20%~78.13%）、富碱（K₂O+Na₂O=7.91%~8.27%）、贫铝（Al₂O₃=11.71%~12.18%）、贫钙（CaO=0.90%~1.01%）,富集LREE、Y、Zr、Hf、Th、U、Ga等,强烈亏损Ba、Sr、P、Ti、Eu,具强烈的负Eu异常（δEu为0.08~0.13）,显示弱过铝质A型花岗岩的特征。锆石Hf同位素组成表明,早-中二叠世岩体的ε_Hf（t）为-3.3~6.2,晚三叠世岩体的ε_Hf（t）为-6.3~5.5,显示在成岩过程中有地幔组分的参与。综合研究认为,野马泉矿区早-中泥盆世、晚三叠世岩体分别形成于早古生代构造-岩浆旋回的碰撞-后碰撞阶段和晚古生代-早中生代构造-岩浆旋回的碰撞-后碰撞阶段,可能是由地幔底侵古老陆壳,幔源基性岩浆与壳源花岗质岩浆发生不同程度混合作用而生成,壳幔物质交换为区内大规模铁铜铅锌多金属矿化提供大量成矿物质。     

都龙锡锌矿床锡石和锆石U-Pb年代学：滇东南白垩纪大规模花岗岩成岩-成矿事件

都龙锡锌矿床是我国最大的锡石硫化物矿床之一.由于缺少可靠的年代学数据,对该矿床的成因尚存在较大争议.本文报道了利用锡石和锆石U-Pb法,首次获得的都龙锡锌矿床及相关的燕山晚期老君山花岗岩的年龄.其中,锡石TIMS法^206Pb/^238U年龄加权平均值为79.8±3.2Ma（MSWD=3.16）,^238U/^204Pb-^206Pb/^204Pb等时线年龄为82.0±9.6Ma（MSWD=4.81）;隐伏花岗岩的锆石SHRIMP法^206Pb/^238U年龄加权平均值为92.9±1.9Ma（N=10,MSWD=0.71）,花岗斑岩的锆石SHRIMP法^206Pb/^238U年龄加权平均值为86.9±1.4Ma（N=9,MSWD=3.70）,表明锡（铜）矿化主要与晚白垩世岩浆热液活动有关.结合个旧、白牛厂两个超大型矿床和相关花岗岩体的年代学资料,指示滇东南地区于白垩纪存在以锡矿化为特色的大规模花岗岩成岩-成矿事件,可能与晚中生代以来华南地块岩石圈伸展有关.     

Geology,geochronology, geochemistry and ore genesis of the Wangu gold deposit in northeastern Hunan Province,Jiangnan Orogen,South China

The Wangu gold deposit in northeastern Hunan, South China, is one of many structurally controlled gold deposits in the Jiangnan Orogen. The host rocks (slates of the Lengjiaxi Group) are of Neoproterozoic age, but the area is characterized by a number of Late Jurassic–Cretaceous granites and NE-trending faults. The timing of mineralization, tectonic setting and ore genesis of this deposit and many similar deposits in the Jiangnan Orogen are not well understood. The orebodies in the Wangu deposit include quartz veins and altered slates and breccias, and are controlled by WNW-trending faults. The principal ore minerals are arsenopyrite and pyrite, and the major gangue minerals are quartz and calcite. Alteration is developed around the auriferous veins, including silicification, pyritic, arsenopyritic and carbonate alterations. Field work and thin section observations indicate that the hydrothermal processes related to the Wangu gold mineralization can be divided into five stages: 1) quartz, 2) scheelite–quartz, 3) arsenopyrite–pyrite–quartz, 4) poly-sulfides–quartz, and, 5) quartz–calcite. The Lianyunshan S-type granite, which is in an emplacement contact with the NE-trending Changsha-Pingjiang fracture zone, has a zircon LA-ICPMS U–Pb age of 142 ± 2 Ma. The Dayan gold occurrence in the Changsha-Pingjiang fracture zone, which shares similar mineral assemblages with the Wangu deposit, is crosscut by a silicified rock that contains muscovite with a ca. 130 Ma ⁴⁰Ar–³⁹Ar age. The gold mineralization age of the Wangu deposit is thus confined between 142 Ma and 130 Ma. This age of mineralization suggests that the deposit was formed simultaneously with or subsequently to the development of NE-trending extensional faults, the emplacement of Late Jurassic–Cretaceous granites and the formation of Cretaceous basins filled with red-bed clastic rocks in northeastern Hunan, which forms part of the Basin and Range-like province in South China. EMPA analysis shows that the average As content in arsenopyrite is 28.7 atom %, and the mineralization temperature of the arsenopyrite–pyrite–quartz stage is estimated to be 245 ± 20 °C from arsenopyrite thermometry. The high but variable Au/As molar ratios (>0.02) of pyrite suggest that there are nanoparticles of native Au in the sulfides. An integration of S–Pb–H–O–He–Ar isotope systematics suggests that the ore fluids are mainly metamorphic fluids originated from host rocks, possibly driven by hydraulic potential gradient created by reactivation of the WNW-trending faults initially formed in Paleozoic, with possible involvement of magmatic and mantle components channeled through regional fault networks. The Wangu gold deposit shares many geological and geochemical similarities as well as differences with typical orogenic, epithermal and Carlin-type gold deposits, and may be better classified as an “intracontinental reactivation” type as proposed for many other gold deposits in the Jiangnan Orogen.     

Incremental growth and origin of the Cretaceous Renjiayingzi pluton,southern Inner Mongolia,China: Evidence from structure,geochemistry and geochronology

The Renjiayingzi intermediate-acid pluton is located along a pre-existing ENE–WSW-trending dextral shear zone that forms part of the Xar Moron suture zone that marks the final closure of the Paleo-Asian Ocean. The pluton is composed of three small intrusions, which from northwest to southeast, are named the Shuangjianshan (SI), the Qianweiliansu (QI) and the Xingshuwabeishan (XI) intrusions. LA-ICPMS zircon U–Pb dating of a pyroxene diorite from the SI yields an age of 138 ± 1 Ma; the SHRIMP zircon U–Pb age of a tonalite from the QI records an age of 134 ± 2 Ma, whereas LA-ICPMS zircon U–Pb dating of a monzogranite from the XI has an age of 126 ± 1 Ma, suggesting the entire pluton was built up by three separate emplacement events that young to the ESE: this is further supported by the contact relations. Incremental growth of plutons by amalgamation of repeated small magma pulses is the most viable emplacement model. The pluton was probably emplaced by updoming of the roof along previous tensile fractures and by upward stacking of the three intrusions. The SI and QI have similar U–Pb ages and geochemical characteristics, and most likely had the same magma source and underwent similar petrogenetic processes. They have high MgO concentrations at low silica contents, are enriched in large ion lithophile elements, depleted in high field strength elements, have negative ε_Nd(t) values of −1.8 to −3.7, with Nd model ages of 1.07–1.19 Ga. Pyroxene diorites of the SI also have variable zircon ε_Hf(t) values (from −0.8 to +6.1), indicating that they were mainly derived from juvenile crust with minor crustal contamination and clinopyroxene-dominated fractional crystallization. The late monzogranites from the XI show weak negative ε_Nd(t) values of −2.3 to −2.5, young Nd model ages of 0.99–1.00 Ga, positive zircon ε_Hf(t) values (+1.3 to +4.6) and higher SiO₂ and K₂O contents, with strong depletion in Eu, P and Ti, indicating derivation from a distinct petrogenetic process from the two earlier intrusions. The monzogranites were the result of partial melting of juvenile crust in response to mantle-derived magma underplating, together with plagioclase-dominated fractional crystallization.     

西藏浦桑果铜多金属矿床中酸性岩石成因及动力学背景:年代学、地球化学及Sr-Nd-Pb-Hf同位素约束

浦桑果矿床位于拉萨地块冈底斯成矿带中段,为侵入岩体与钙质围岩接触带内形成的矽卡岩型高品位铜多金属矿床(Cu@1. 42%,Pb+Zn@2. 83%),是冈底斯成矿带目前唯一一个大型富铜铅锌(钴镍)矿床。本文以浦桑果矿床相关中酸性侵入岩体(黑云母花岗闪长岩和闪长玢岩)为主要研究对象,开展LA-ICP-MS锆石U-Pb年代学、全岩主微量元素、全岩SrNd-Pb及锆石Lu-Hf同位素研究,旨在厘定侵入岩体的形成时代、岩石成因及成岩成矿的动力学背景。LA-ICP-MS锆石U-Pb定年结果表明,黑云母花岗闪长岩和闪长玢岩侵位年龄分别为13. 6～14. 4Ma和13. 6～14. 6Ma,岩体形成时代均属中新世。岩石地球化学特征表明,闪长玢岩和黑云母花岗闪长岩均属高钾钙碱性I型花岗质岩石;岩石普遍具高Sr含量(599×10~(-6)～1616×10~(-6))、高Sr/Y(48. 2～132. 3)和高(La/Yb)N(19. 6～25. 4)比值特征,具低Y(10. 38×10~(-6)～12. 70×10~(-6))和Yb含量(0. 79×10~(-6)～1. 17×10~(-6))特征,表现出埃达克质岩的地球化学属性。全岩稀土元素表现为明显富集轻稀土元素(LREEs)和大离子亲石元素(LILEs),而相对亏损重稀土元素(HREEs)和高场强元素Nb、Ta、P、Ti等(HFSE)。全岩Sr-Nd-Pb及锆石Hf同位素分析结果表明,浦桑果矿床相关中酸性岩石与冈底斯成矿带中新世大多斑岩-矽卡岩矿床紧密相关的埃达克质侵入岩体具相似的同位素组成特征,指示岩石具同源岩浆特征且埃达克质岩浆主要起源于拉萨地块加厚新生下地壳。浦桑果矿床中酸性岩体主要形成于后碰撞伸展的构造背景,因碰撞挤压向后碰撞伸展背景的构造转换,引起印度大陆岩石圈发生拆沉(42～25Ma)及拉萨地块中富集岩石圈地幔发生部分熔融,从而形成富含Cu、Co等基性岩浆熔体底侵加厚新生下地壳(25～18Ma),导致拉萨地块加厚新生下地壳中部分石榴子石角闪岩相发生部分熔融,最终形成闪长质熔体于浦桑果矿区有利构造部位形成具埃达克质属性的中酸性侵入岩体(13～14Ma)和矽卡岩型铜多金属矿体。     

华南板块西缘和腾冲-保山地块晚白垩世岩浆活动及Sn成矿作用对比:年代学、地球化学和动力学背景

华南板块西缘和西南三江腾冲-保山地块发育我国两个重要的Sn成矿带。两个带大规模岩浆活动和Sn成矿作用在年代学和地球化学特征等方面具有相似性。它们的成岩-成矿年龄时限均在晚白垩世,分别为78.9~60.0Ma和108.0~74.1Ma,分别集中在76.0~62.0Ma和98.0~82.0Ma,自西向东总体显示逐渐变老的趋势。晚白垩世成矿相关的岩浆岩均属于花岗质岩类,表现出高硅、富铝、富钾,富集轻稀土而亏损重稀土,相对富集Rb、Th、U而相对亏损Ba、Nb、Sr、Ti,具明显的Eu负异常,初始锶值(~(87)Sr/~(86)Sr)_i集中在0.7038~0.7283,同时具有低的ε_(Nd)(t)值(-11.6~-6.9)和ε_(Hf)(t)值(-18.1~1.2),反映岩浆岩主要起源于地壳。本文分析结果联合区域地质证据表明,腾冲-保山地块晚白垩世处于新特提斯洋俯冲环境;华南板块西缘岩石圈伸展可能受控于东侧太平洋俯冲回撤的远程效应,也可能系西侧新特提斯洋俯冲回撤的响应,抑或二者联合作用的结果。基于华南板块西缘和腾冲-保山地块的成岩-成矿年龄和岩体地球化学特征的类似性和空间差异变化,本文提出新特提斯洋俯冲联合作用模型:即华南板块西缘晚白垩世成岩-成矿活动也可能受控于特提斯构造域,为新特提斯洋俯冲后在板块逐渐回撤的过程中自东向西逐渐诱发晚白垩世广西西缘、云南东南部软流圈上涌和腾冲、保山地壳减压熔融,进而导致岩浆活动和大规模Sn成矿作用。该模型对于丰富晚白垩世西南三江-华南西缘跨区域成岩成矿构造环境提供了新认识。     

内蒙古甲乌拉铅锌银矿区岩浆岩年代学、地球化学特征及其对成矿的约束

内蒙古满洲里地区的甲乌拉铅锌银矿区的成岩、成矿事件及其相互关系目前仍有很大争议。文中对矿区内与成矿密切相关的石英斑岩、闪长玢岩开展详细研究。锆石SHRIMP U Pb年代学研究表明：矿区致矿侵入体之一石英斑岩形成于(129±4.8) Ma,成矿晚(或后)期的闪长玢岩形成于约(124±2.5) Ma;认为铅锌银等成矿作用应发生于(129±4.8)~(124±2.5) Ma,为早白垩世末期。岩石地球化学特征显示石英斑岩具有高硅、高钾、贫钙等特征,TAS图上属于亚碱性系列,硅铁镁图上属于钙碱系列,硅钾图上属于高钾钙碱系列。轻重稀土分馏明显,具有明显的负铕异常。相对富集大离子亲石元素(LILE),而亏损高场强元素(HFSE),且具有低Sr、高Y等特征。闪长玢岩同样展现出高钾、高铝、贫钙特征,TAS图上属于亚碱性系列,硅铁镁图上属于拉斑系列;轻、重稀土分馏明显,具明显负铕异常,但稀土总量较高;相对富集大离子亲石元素(LILE),亏损高场强元素(HFSE),同具有低Sr、高Y等特征。这些研究结果表明：石英斑岩具有火山弧的特征,主要来源于壳源的熔融;闪长玢岩具有活动大陆边缘弧的特征,主要来源于地幔的熔融,但经历了壳源的混染上述岩浆与甲乌拉的铅锌银矿;推测应为蒙古-鄂霍次克洋由俯冲向陆陆转换阶段产物。     

Age,petrogenesis, and tectonic setting of granitic gneiss and amphibolite from the Weizigou gold deposit,Heilongjiang Province,NE China: Constraints from geochronology and geochemistry

The Weizigou gold deposit is located in the western Jiamusi Massif, Northeast China. Gold mineralization is hosted in the amphibolite, which intruded the granitic gneiss. Although the deposit shows similarities to iron-oxide–copper–gold deposits, the detailed ore-forming process remains uncertain. To determine the formation age, petrogenesis, and tectonic setting of the granitic gneiss and amphibolite, LA–ICP–MS zircon, titanite, and monazite UPb dating, whole-rock major- and trace-element analyses, and LA–ICP–MS in situ zircon Hf isotope analyses were conducted on samples from these rocks. The granitic gneiss yielded two age populations of 951–882 Ma, and ca. 500 Ma, with a monazite UPb concordia age of 501.5 ± 5.1 Ma. The amphibolite yielded a crystallization age of 292 Ma, consistent with the results for magmatic titanite UPb dating, and a metamorphic age of 272–258 Ma. The granitic gneiss contains typical aluminum-rich minerals, such as garnet and muscovite, mean SiO₂ = 73.31 wt%, and molar ratio Al₂O₃/(CaO + K₂O + Na₂O) values of 1.02–1.07, indicating an S-type granite protolith. The amphibolite belongs to the tholeiitic basalt series and has low SiO₂ and high MnO contents. These results, together with ε_Hf(t) values and two-stage model ages ranging from ?9.5 to 2.3 and ? 0.3 to 5.7, and from 2010 to 1659 Ma and from 1331 to 947 Ma, respectively, allow us to infer that the parental magmas of the granitic gneiss and amphibolite were derived from the partial melting of Paleoproterozoic lower crust and the partial melting of metasomatized depleted mantle, respectively. The granitic gneiss is characterized by positive Th and Hf anomalies, and negative Nb, Ta, Sr and Ti anomalies, whereas the amphibolite is enriched in K, Rb, and depleted in Ba, Nb, Ti, and Zr. These geochemical features suggest that the S-type granite was formed in an active continental margin during the Neoproterozoic and underwent granulite-facies metamorphism during the early Paleozoic. The protolith of the amphibolite was gabbro that formed in an extensional setting (e.g., a backarc basin) associated with westward subduction of the Paleo-Pacific oceanic plate beneath the eastern Jiamusi Massif during the early Permian. The gold mineralization can most likely be attributed to contact metasomatic metamorphism of gabbro during the middle–late Permian.     

三江地区澜沧江带南段南林山基性岩体锆石U-Pb年龄及岩石地球化学特征

南林山基性岩体位于西南三江地区,岩体主要由辉长岩和闪长岩组成。通过ID-TIMS锆石U-Pb年代学方法对南林山岩体中闪长岩进行精确定年,获得其结晶年龄为（298.44±0.33）Ma,表明南林山基性岩体的形成时代为早二叠世。全岩主量、微量元素与稀土元素等研究表明,辉长岩和闪长岩总体上均呈现轻稀土元素（LREEs）相对于...     

Geology,geochemistry and ore genesis of the Wenyu gold deposit,Xiaoqinling gold field,Qinling Orogen,southern margin of North China Craton

The Wenyu giant gold deposit is hosted in the Precambrian Taihua Supergroup metamorphic rocks within the Xiaoqinling terrane (Qinling Orogen), on the southern margin of the North China Craton. The mineralization can be divided into three stages: quartz–pyrite veins early, quartz–sulfide veins middle (main), and carbonate–quartz veinlets late, with gold being mainly introduced in main stage. Quartz formed in two earlier stages contains three compositional types of fluid inclusions, i.e. pure CO₂, CO₂–H₂O and NaCl–H₂O, but the late-stage minerals only contain the NaCl–H₂O inclusions. The inclusions in quartz formed in the early, main and late stages yield total homogenization temperatures of 262–417 °C, 236–407 °C and 114–239 °C, respectively, with salinities no higher than 13 wt.% NaCl equiv. Trapping pressures estimated from CO₂–H₂O inclusions are 139–399 MPa and 111–316 MPa in the early and main stages, corresponding to mineralization depths of 14 km and 11 km, respectively. Fluid boiling and mixing caused rapid precipitation of sulfides and native Au. Through boiling and inflow of meteoric water, the ore-forming fluid system evolved from CO₂-rich to CO₂-poor in composition, and from metamorphic to meteoric, as indicated by decreasing δ¹⁸O_water values from early to late. The carbon, sulfur and lead isotope compositions suggest the hostrocks within the Taihua Supergroup to be a significant source of ore metals. Integrating the data obtained from the studies including regional geology, ore geology, fluid inclusion and C–H–O–S–Pb isotope geochemistry, we conclude that the Wenyu gold deposit was an orogenic-type system formed in the tectonic transition from compression to extension during the Jurassic–Early Cretaceous continental collision between the North China and Yangtze Cratons.     

内蒙古化德地区二叠纪—三叠纪侵入岩年代学及地球化学特征：对古亚洲洋东段构造演化的制约

本文对华北克拉通北缘中段内蒙古化德地区二叠纪—三叠纪5个花岗质侵入体进行了岩相学、地球化学、锆石U Pb年代学以及Sr Nd Hf同位素研究。结果表明本次所研究的岩体主要起源于华北克拉通古老下地壳的部分熔融,八音察汗岩体形成于早二叠世（276±1 Ma）,在岩浆上升过程中发生了岩浆混合作用;白音特拉岩体形成于中二叠世（270±1 Ma）,为地壳加厚作用下变质杂砂岩部分熔融形成的S型花岗岩;毛忽庆岩体形成于晚二叠世（254±1 Ma）,为I型花岗岩;张万良岩体与康家地岩体分别形成于早三叠世（248±1 Ma）和晚三叠世（229±1 Ma）,两者均为A型花岗岩。综合前人研究,本文认为研究区在早二叠世—晚三叠世经历了古亚洲洋向华北板块俯冲、俯冲 同碰撞、持续碰撞以及造山后的伸展4个阶段,古亚洲洋东段在研究区的闭合时间应为中二叠世晚期。     

拉萨地块南缘晚白垩世角闪辉长岩、花岗斑岩副矿物微量元素特征对成岩成矿的指示

拉萨地块南缘记录了新特提斯洋俯冲到印度-欧亚大陆碰撞及碰撞后的岩浆作用,其中晚白垩世的岩浆作用对研究印度-欧亚大陆碰撞前成岩成矿作用具有重要的意义。本文以拉萨地块南缘100Ma的角闪辉长岩和68Ma花岗斑岩的锆石、磷灰石、榍石为研究对象,利用背散射、阴极发光(CL)、电子探针(EPMA)和LA-ICP-MS原位微区分析等方法,查明锆石、磷灰石、榍石的主、微量元素特征,进一步反演岩石源区性质、结晶历史及结晶条件,并对岩体含矿性进行评价,有助于探讨冈底斯成矿带晚白垩世岩浆成因机制和成矿潜力。研究结果表明,角闪辉长岩锆石初始饱和温度为598～626℃,锆石Ti结晶温度为645～758℃,磷灰石饱和温度为690～819℃,榍石Zr温度为602～778℃;磷灰石具有中等-弱的负铕异常(δEu=0. 67)、富集LREE,早期高温阶段锆石的结晶主要受到磷灰石结晶影响,随着温度降低,受到少量榍石结晶的影响;角闪辉长岩中的锆石在低的Hf、温度较高时却具有较高的Th、U含量显示岩浆源区受到更多俯冲板片出溶流体的影响,磷灰石具有较高的(La/Sm)N值以及Sr含量低于主岩,显示岩浆源区均一、熔体富Cl特征。花岗斑岩的锆石初始饱和温度为704～736℃,锆石Ti温度为630～799℃,磷灰石饱和温度为846～891℃,结合锆石的Ce/Sm、Yb/Gd以及磷灰石较大的负铕异常(δEu=0. 29),显示花岗斑岩中的锆石从高温到低温阶段都受到磷灰石和榍石的共同结晶影响,磷灰石的结晶受到斜长石影响;花岗斑岩中大部分锆石Ti结晶温度高于其初始饱和温度,磷灰石Sr-Ap/Sr-WR为0. 78～1. 45,具有较高的F/Cl(32. 87～67. 60)、低的(La/Sm)N,指示花岗斑岩岩浆源区不均一,受到多期岩浆熔体的脉冲式灌入并加入了更多镁铁质的岩浆熔体,其熔体具有低的Cl。此外,花岗斑岩锆石具有较高的Ce~(4+)/Ce~(3+)、磷灰石具有较高的SO_3、熔体中更富S,指示花岗斑岩具有高的氧逸度和成矿潜力。本文研究结果表明结合锆石、磷灰石和榍石微量元素特征可有效指示岩浆岩的源区组成、结晶历史、结晶条件以及成矿潜力,为岩石学的研究提供了一个新的思路。     

Geology,fluid inclusion geochemistry,and 40Ar/39Ar geochronology of the Wulasigou Cu deposit,and their implications for ore genesis,Altay, Xinjiang,China

The Wulasigou Cu deposit occurs as veins controlled by a NW-trending structure in a Devonian volcano-sedimentary basin of the Altay orogenic belt, Xinjiang, China. Igneous and sedimentary rocks exposed in the area have undergone greenschist-facies metamorphism. The ore-forming process can be divided into early, middle, and late stages, represented by, respectively, pyrite-quartz, polymetallic sulfide-quartz, and carbonate–quartz veins, veinlets, and/or replacement bodies. The early veins were deformed and brecciated during a compressional or transpressional event. The middle-stage veinlets filled fractures in the early-stage vein and alteration assemblages, and are undeformed, suggesting a tensional shear setting. The late-stage veinlets are mainly open-space fissure fillings that cut veins and replacement bodies formed in the earlier stages.Four types of fluid inclusions (FIs), including aqueous (W-type), mixed carbonic-aqueous (M-type), purely carbonic (C-type) and daughter mineral-bearing (S-type), have been identified in copper-related quartz and calcite from the Wulasigou deposit. The early-stage quartz contains M- and W-type primary FIs that completely homogenized at temperatures of 322–412 °C with low salinities of 0.9–6.5 wt.% NaCl equiv. In contrast, the late-stage quartz or calcite contains only the W-type FIs with homogenization temperatures of 101–234 °C, and salinities of 0.9–2.9 wt.% NaCl equiv. This indicates that the metallogenic system evolved from CO₂-rich, metamorphic to CO₂-poor, through input of meteoric fluids. All four types of FIs can only be observed in the middle-stage minerals, where they show evidence of vein formation during an episode of fluid immiscibility. These FIs homogenized at temperatures ranging mainly from 230 to 347 °C, with salinities clustering 2.7–10.2 wt.% NaCl equiv for the W-, M- and C-types, and 34.7–38.2 wt.% NaCl equiv for the S-type, respectively. The metal precipitation resulted from a decrease in copper solubility during the fluid immiscibility episode. The estimated trapping pressures for the middle-stage fluids are 1.55–3.55 kbar, suggesting an alternating lithostatic-hydrostatic fluid-system, controlled by fault-valve activity at a depth of 13–15.5 km.Muscovite separates from the middle-stage polymetallic-quartz veinlets yield a well-defined ⁴⁰Ar/³⁹Ar isotopic plateau age of 219.41 ± 2.10 Ma, and an ³⁹Ar/³⁶Ar - ⁴⁰Ar/³⁶Ar isochron age of 219.73 ± 2.17 Ma. This age postdates the final Paleo-Asia Ocean closure (at ca. 250 Ma) by about 30 Ma, and indicates that the Cu mineralization at Wulasigou has occurred in the Triassic continental collision setting. Hence, the Wulasigou Cu deposit may be the first example of orogenic lode Cu deposits formed in accretionary orogeny or continental collision.     

The genetic relationship between the large Guanfang W deposit and granitic intrusions,in Yunnan Province,southwest China: Evidence from UPb and ReOs geochronology and Pb and Sr isotopic characteristics

The recently discovered Guanfang large W deposit, in Yunnan Province, southwest China, is located in the Diandongnan thrust-nappe fold belt in the western part of the Cathaysia Block. The orebodies occur at the contacts between the Suozuodi granite and Middle Cambrian marbles. LA-ICP-MS zircon UPb dating of the ore-bearing Suozuodi granite yields a crystallization age of 91.6 ± 1.0 Ma (MSWD = 0.56). An isochron age of 91.6 ± 1.3 Ma (MSWD = 0.24) was obtained by ReOs dationg of five molybdenite samples separated from sulfide-bearing ores. Scheelite at the Guanfang deposit is characterized by broad rangs of Pb isotopic ratios (²⁰⁷Pb/²⁰⁴Pb = 15.568 to 15.735, ²⁰⁶Pb/²⁰⁴Pb = 17.912 to 18.390, ²⁰⁸Pb/²⁰⁴Pb = 38.491 to 38.730) and high initial ⁸⁷ Sr/⁸⁶ Sr ratios (Isr = 0.7118 to 0.7140), which consistent with the isotopic characteristics of the Suozuodi granite. Pb and Sr isotopic results indicate that the ore-forming materials were derived from a crustal source, without addition of mantle materials. The Guanfang tungsten deposit was formed in a syn-collision tectonic setting during the late stage of the Yanshanian tectonism.     

Pyrite Re-Os isotope systematics at the Zijinshan deposit of SW Fujian,China: Constraints on the timing and source of Cu-Au mineralization

Zijinshan is the largest high-sulfidation epithermal Cu–Au deposit on mainland China. The primary mineralization at the deposit is characterized by pyrite, digenite and covellite. Although some RbSr isochron ages of the fluid inclusions in quartz and the apparent K-Ar age of the Cu-bearing alunite alteration zone have been previously interpreted as the ore-forming age, the Rb-Sr and K-Ar dating systems are usually readily reset due to their closure temperature, and thus document the latest thermal event. In order to precisely determine the age of the Cu mineralization, eight-pyrite separates were Re-Os dated, and seven yielded an isochron age of 103 ± 4 Ma with an initial ¹⁸⁷Os/¹⁸⁸Os ratio of 0.45 ± 0.14. This date is interpreted as the age of Cu mineralization, which is in agreement with geochronological data from molybdenite and the porphyritic granodiorite that hosts Cu-Mo mineralization at Luoboling (located 2 km NE of Zijinshan), suggesting that these two deposits were formed during the same metallogenic event. The relatively low initial ¹⁸⁷Os/¹⁸⁸Os ratio indicates that the source of the Cu at Zijinshan is predominantly the crust with input from the mantle.