漠河盆地中侏罗统漠河组泥岩元素地球化学特征及其地质意义:以MK-3井为例

为了研究漠河盆地中侏罗统漠河组泥岩中微量元素和稀土元素的地球化学特征及其地质意义,采用ICP-MS对研究区内33个泥岩样品进行了微量元素和稀土元素分析,分析结果表明,该地区样品微量元素中Cr、B、Ba等元素的纵向变化较明显,而Ni、Co、Sr、V、Nb、Ta、Th等元素的差异不大,纵向变化不明显;稀土元素总量(∑REE)较低,LREE/HREE、(La/Yb)_N、(La/Sm)_N、(Gd/Yb)_N等值均表明轻重稀土元素分异明显;REE配分模式图显示轻稀土元素(LREE)富集,重稀土(HREE)元素相对亏损,Eu为明显的负异常。对古盐度、Sr/Ba值、V/(V+Ni)值和Ce_anom值等特征参数及其垂向变化趋势的研究表明,研究区中侏罗统泥岩处于缺氧、还原、微咸水-半咸水的沉积环境,可以识别出4个层序界面;综合稀土元素组合特征和野外地质调查资料,表明漠河盆地中侏罗世的沉积物源具有多源性,以沉积岩、花岗岩和长英质的变质岩为主,可能混有部分外来的火山物质,这些结论对揭示盆地内物质的组成、古沉积环境的恢复等研究具有重要指示意义。      

Geochemical analysis of marine sediments using fused glass disc by X-ray fluorescence spectrometry

A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）.     

钇镧共存时利用一阶导数分光光度法进行钇的测定

在稀土元素钇、镧共存时 ,以变色酸双偶氮类试剂为显色剂 ,在 pH为 2的介质中 ,加入乙醇 ,利用溶剂化效应 ,提高Y ,La络合物性质的差异 ,从而可在一阶导数光谱上消除La的影响而直接测定Y。测定波长 675nm ,摩尔吸光系数ε为 1 .73× 1 0 4 L·mol- 1 ·cm- 1 ,九次测定变异系数为 1 .92 % ,Y3 含量在 0～ 40 0 μg/L范围内符合比耳定律 ,该方法快速简便 ,适合于矿物原料、钢铁、合金中钇的测定。     

GEOCHEMICAL STUDY OF THE CORE S01 IN THE SOUTH CHINA SEA

Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene.     

Inhibition of Aspergillus parasiticus and cancer cells by marine actinomycete strains

Ten actinomycete strains isolated from the Yellow Sea off China's coasts were identified as belonging to two genera by 16 S r DNA phylogenetic analysis: Streptomyces and Nocardiopsis. Six Streptomyces strains(MA10, 2SHXF01-3, MA35, MA05-2, MA05-2-1 and MA08-1) and one Nocardiopsis strain(MA03) were predicted to have the potential to produce aromatic polyketides based on the analysis of the KSα(ketoacyl-synthase) gene in the type II PKS(polyketides synthase) gene cluster. Four strains(MA03, MA01, MA10 and MA05-2) exhibited significant inhibitory effects on mycelia growth(inhibition rate 50%) and subsequent aflatoxin production(inhibition rate 75%) of the mutant aflatoxigenic Aspergillus parasiticus NFRI-95. The ethyl acetate extracts of the broth of these four strains displayed significant inhibitory effects on mycelia growth, and the IC50 values were calculated(MA03: 0.275 mg m L-1, MA01: 0.106 mg m L-1, MA10: 1.345 mg m L-1 and MA05-2: 1.362 mg m L-1). Five strains(2SHXF01-3, MA03, MA05-2, MA01 and MA08-1) were selected based on their high cytotoxic activities. The ethyl acetate extract of the Nocardiopsis strain MA03 was particularly noted for its high antitumor activity against human carcinomas of the cervix(He La), lung(A549), kidney(Caki-1) and liver(Hep G2)(IC50: 2.890, 1.981, 3.032 and 2.603 μg m L-1, respectively). The extract also remarkably inhibited colony formation of He La cells at an extremely low concentration(0.5 μg m L-1). This study highlights that marine-derived actinomycetes are a huge resource of compounds for the biological control of aflatoxin contamination and the development of novel drugs for human carcinomas.     

新疆塔里木南缘铁克里克东段晚奥陶世埃达克质岩的成因及地质意义

为厘定塔里木南缘铁克里克东段花岗闪长岩形成时代并探讨岩石成因,开展了地球化学、锆石 UＧPb年代学及 Hf同位素研究.LAＧICPＧMS锆石 UＧPb年代学的结果显示其形成于晚奥陶世(４４４Ma).地球化学数据表明其具有类似于 C型埃达克岩的高Sr及Sr/Y 和(La/Yb)N,低 Y 和 Yb地球化学特征,１７６Hf/１７７Hf和εHf(t)分别介于０．２８２３９７~０．２８２４９７和－３．７~＋０．１之间,富含暗色微粒包体以及高 Mg＃ ,指示其具有一定的幔源岩浆印记,可能是玄武质下地壳部分熔融过程中加入一定程度幔源物质,在角闪岩－榴辉岩相条件下部分熔融形成具壳－幔混源特征的富钠、钾 C型埃达克岩.结合区域地质资料认为,铁克里克岩体形成于活动大陆边缘环境。      

宁蒗地区中泥盆统大槽子组页岩地球化学特征及地质意义

为评价宁蒗地区中泥盆统大槽子组页岩气资源潜力,选择4条典型泥盆系剖面(大槽子剖面、三股水剖面、野麻地剖面、岩口剖面),在地质调查基础上,对页岩样品进行矿物、微量元素分析和有机地球化学测试。结果表明:宁蒗地区中泥盆统大槽子组富有机质页岩为陆棚沉积,岩性主要为黑色富有机质页岩,主要矿物成分为石英及黏土矿物。研究区大槽子组页岩TOC质量分数多数大于1.0%,镜质体反射率介于1.23%～2.31%,有机质类型表现为Ⅱ_1型—Ⅱ_2型。V/(V+Ni)、V/Cr及U/Th指示研究区大槽子组页岩形成于缺氧—厌氧环境沉积。在宁蒗地区4个剖面控制区域中,野麻地剖面—岩口剖面一线具有较好的勘探潜力,大槽子剖面—三股水剖面一线勘探潜力较差。     

TraceeElements in Leccinum scabrum mushrooms and topsoils from Kłodzka Dale in Sudety Mountains, Poland

In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.     

安徽张八岭地区管店岩体成因及其与上成金矿床的关系

管店岩体位于安徽东部张八岭隆起北段,主要由二长岩和石英二长岩组成。该岩体为一中酸性侵入岩体,富钾、准铝
质,属于高钾钙碱性I型花岗岩类,同时显示出与中国东部众多中生代高Ba-Sr花岗岩相类似的地球化学特征:具有高Ba、Sr和
LREE含量,高Sr/Y比值、La_N/Yb_N 比值,低Y和HREE含量,低Rb/Sr比值。结合岩体的岩石学、岩石地球化学及区域构造演
化,推测管店岩体的形成与下地壳基性岩石的部分熔融有关。此外,管店岩体与张八岭地区的脉状金矿床有着密切的时空联系。
对上成金矿床的同位素研究显示:矿床早阶段成矿流体为岩浆水,成矿物质中硫的来源可能与管店侵入岩体有关。该矿床属于典
型的岩浆期后热液型脉状金矿床.      

西藏冈底斯带北缘波果日则地区A型花岗岩年代学、地球化学特征及其地质意义

波果日则地区位于西藏冈底斯带北缘的班公湖—怒江缝合带中段,目前有关班公湖—怒江洋盆的闭合时间存在争议。在波果日则地区出露的A型花岗岩以岩株侵位于卧荣沟组一段,岩性为中—细粒黑云花岗斑岩。岩石具有富SiO_2(含量(质量分数,下同)为70.61%～74.94%)、K_2O(4.96%～7.48%),贫Al_2O_3(11.90%～13.79%),较高FeO~T/MgO值(7.47～25.88),较低TiO_2(含量为0.16%～0.25%)的特征,属弱过铝质—准铝质碱性系列(A/CNK值为0.90～1.12,A/NK值为1.10～1.34)。稀土元素总含量为(179.80～370.29)×10~(-6),(La/Yb)_N值为5.36～8.70,Eu异常为0.28～0.61,球粒陨石标准化稀土元素配分模式表现为右倾的"海鸥"型,属于典型的铝质A型花岗岩。在原始地幔标准化微量元素蛛网图上,大离子亲石元素和高场强元素Rb、Th、U、K、Zr、Hf明显富集,而Ba、Sr、Nb、Ta、Ti明显亏损。较高的Zr、Nb、Ce和Y含量及较高的Y/Nb、Yb/Ta和Ce/Nb值显示波果日则地区A型花岗岩为A_2型花岗岩。岩相学、地球化学和区域地质资料综合显示,波果日则地区A型花岗岩形成于碰撞后岩石圈伸展背景,是下地壳拆沉导致软流圈物质上涌并加热上覆地壳,致使上覆地壳变质泥岩发生部分熔融并经历了一定程度分离结晶作用的产物。A型花岗岩LA-ICP-MS锆石U-Pb年龄为(110.8±1.3)Ma,表明其形成于早白垩世晚期,推测班公湖—怒江洋盆至少在早白垩世晚期就已闭合。     

Thermohaline structure inhomogeneity associated with polynia at the northern margin of Emery Ice-shelf

Based on the hydrographic data in austral summer during the 22nd Antarctic Expedition of China(2005/2006),some features can be found about the northern margin of Emery ice shelf as follows.The heat content in the surface layer(0-50 m) at the eastern end and the western end of the ice-shelf margin is much higher than that at the middle.The upper mixing-layer depth and the seasonal thermocline depth at the middle of the ice-shelf northern margin are much shallower than those at the both ends.However there is much less difference between the middle and the ends in the bottom layer.The remote sensing photos show that the inhomogeneity in the surface-layer water is closely related to the spatial distribution of the floes and polynia in the area.     

Phylogenetic analysis of cultivable bacteria isolated from Arctic sea-ice

Phylogenetic analysis based on 16S rDNA of 8 strains of cultivable bacteria isolated from Arctic sea-ice was studied.The results showed that strain BJ1 belonged to genus Planococcus,which was a genus of low mole percent G C gram-positive bacteria;strain BJ6 belonged to genus Burkholderia of β-proteobacteria and the rest 6 strain all belonged to γ-proteobacteria,of which strain BJ8 was a species of Pseudoalteromonas,strain BJ2-BJ5 and BJ7 were members of genus Psychrobacter.Phylogenetic analysis also indicated that bacteria of genus Psychrobacter of the isolates formed a relatively independent phylogenetic cluster in comparison with other bacteria belonged to genus Psychrobacter.     

Information for authors

正1 Aims and Scope Advances in Polar Science(APS)is an international,peer-reviewed journal jointly sponsored by the Polar Research Institute of China and the Chinese Arctic and Antarctic Administration.APS is a comprchensive academic journal dedicated to presentation of multi-disciplinary achievements in Arctic and Antarctic expeditions and research.Its primary purpose is to publish achievements in fundamental research,applied     

Advances in Polar Science CONTENTS(Volume 25,2014)

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Guide to Authors： Journal of Mountain Science

<正>AIMS AND SCOPE(Editorial Policy)The Journal of Mountain Science(JMS)is devoted to mountains and their surrounding lowlands-ecoregions of particular global importance,with a particular emphasis on the important highlands/mountains in the world,such as the Tibetan Plateau,the Himalayas,the Alps,the Andes,the Rockies and many other mountain ranges of our planet.     

Journal of Mountain Science(JMS)

<正>The Journal of Mountain Science(JMS),founded in2004,is an international English-language journal on mountain sciences.JMS is supervised by the Chinese Academy of Sciences(CAS),sponsored by the Chengdu Institute of Mountain Hazards and Environment,CAS,published by Science Press China,and distributed by Springer exclusively throughout the world(excluding Mainland China).The JMS is published bimonthly,fulltexted in SpringerLink and CNKI,indexed/abstracted by     

Influence of livestock soil eutrophication on floral composition in the Pyrenees mountains

Livestock behaviour in the Pyrenees includes free grazing and a long resting period that provokes the accumulation of dung and urine in some places,so-called camping areas. The aims of this study were （i） to analyze any change in floral composition,and in nutritional and chemical contents of plants in a livestock camping area; and （ii） to relate the floral composition with soil chemical properties. In a linear transect,five sampling zones were established,from the centre of the camping area to the surrounding Nardus stricta-dominant pasture. The above ground plant biomass and the topsoil were sampled in each zone with 6 replicates per zone. Plant species were classified and weighed to calculate above ground biomass,nutritional and chemical contents,and Shannon diversity and evenness indices. Additionally,soils were sampled in two periods,at the beginning and at the end of grazing period. Soil available nutrients （nitrate,ammonium,phosphorus,potassium,calcium and magnesium）,total nitrogen,organic carbon and pH were measured.
Plant chemical contents （protein,lignin and others） were significantly related to the proportions of grasses,legumes and other plants; so,the protein content is positively correlated with legumes plant biomass while lignin content is negatively correlated with grasses. Both plant and soil nutrients increased linearly towards the centre of the camping area. However,the relationship among plant species richness,diversity and evenness relative to its position along the studied transect was bell-shaped. From the outskirts to the centre of the camping area,plants with low nutrient demand were progressively replaced by those with medium and high nutrients demand and by pioneers.
Nardus stricta-dominant pasture has low plant diversity and plant nutrient content as well as a poor soil nutrient availability. The presence of the camping area introduced patches with more soil nutrients and new species in the large spatial scale. However at a small spatial scale,the strong soil nutrien     

General Table of Contents(Vol.11,2014)

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介绍GPS定位中的几个概念

文章概略介绍了利用卫星进行定位的原理 ;由卫星信号传播、信号接收和SA政策等引起的理论误差 ;给出了多种快速、高精度定位的工作模式和观测点选择的原则 ;列出了将WGS - 84坐标转换为我国坐标的公式及解算参数的具体方法 ,供读者在GPS工作中参考。