达里湖沉积粒度组分-湖面状况定量模型

湖泊碎屑沉积物的粒度分布可以提供与区域气候变化相关的湖泊水文变化信息。然而, 由于湖泊沉积物多峰分布固有的复杂性, 其粒度组分成因的解释仍存在很大的不确定性。本文利用对数正态分布函数对内蒙古达里湖36个表层沉积物样品的粒度组分进行了分离, 并探讨了各组分特性与特定沉积环境(包括每个采样点位的离岸距离和水深)之间的关系。结果表明, 达里湖现代碎屑沉积物包含5个截然不同的单峰粒度分布, 分别代表5个不同的粒度组分。虽然其相对百分含量随湖泊水动力条件而变化, 但每个组分均保留着各自的众数粒径、搬运方式、沉积环境等特性。这些组分自细而粗可分为: 长期悬移粘土组分、离岸带悬移细粉砂组分、离岸带悬移中粗粉砂组分、近岸带悬移细砂组分、近岸带跃移中砂组分。近岸带环境两个组分的百分含量与现今湖泊水深呈负相关, 揭示出沉积岩芯近岸带组分与地质历史时期湖面状况相关联的数值模型。该模型在达里湖沉积岩芯中的应用显示, 近岸带组分百分含量增加与同岩芯孢粉序列重建的区域降水减少相对应。两种独立的代用指标在时间上的一致性, 不仅展示了对数正态分布函数分离多峰沉积物的有效性, 而且揭示出利用粒度组分-湖面状况模型重建湖泊古水文的潜力。     

A grain size model for role of tectonics and climate on sedimentation in Siwaliks in Mohand area

The physical characteristics of sedimentary record are governed largely by grain size distribution in Mohand area where Middle and Upper Siwalik successions are investigated to characterize the sediments deposited in response to the prevailing tectonic activities and climatic conditions. Here we show with the help of cluster analysis that precipitation and tectonic perturbations generate characteristic patterns of grain sizes and stratigraphic succession. Previous studies suggested an increase in precipitation represented by the abrupt accumulation of sediments to foreland Siwalik basin around 11 to 10 Ma. First appearance of diagnostic minerals of the Great Himalayan complex in Siwalik sediments at 9.2 Ma implies the accelerated erosion of Himalaya during Middle to Late Miocene. The response of sedimentation to tectonic activity is resulted by the presence of coarse grained gravel units in Siwalik succession of Mohand area. Apatite fission-track dates and muscovite cooling ages confirm the strong activity on boundary thrusts during 8-6 Ma. Although the responses are non-linear and transient, we clusterize these non-linear responses to tectonics and climate and quantify them to find out the role of tectonics and climate in architecture of sedimentary succession.     

A comparison of stochastic and deterministic downscaling methods for modelling potential groundwater recharge under climate change in East Anglia, UK: implications for groundwater resource management

Groundwater resource estimates require the calculation of recharge using a daily time step. Within climate-change impact studies, this inevitably necessitates temporal downscaling of global or regional climate model outputs. This paper compares future estimates of potential groundwater recharge calculated using a daily soil-water balance model and climate-change weather time series derived using change factor (deterministic) and weather generator (stochastic) methods for Coltishall, UK. The uncertainty in the results for a given climate-change scenario arising from the choice of downscaling method is greater than the uncertainty due to the emissions scenario within a 30-year time slice. Robust estimates of the impact of climate change on groundwater resources require stochastic modelling of potential recharge, but this has implications for groundwater model runtimes. It is recommended that stochastic modelling of potential recharge is used in vulnerable or sensitive groundwater systems, and that the multiple recharge time series are sampled according to the distribution of contextually important time series variables, e.g. recharge drought severity and persistence (for water resource management) or high recharge years (for groundwater flooding). Such an approach will underpin an improved understanding of climate change impacts on sustainable groundwater resource management based on adaptive management and risk-based frameworks.     

Role of dynamics in the advection of aerosols over the Arabian Sea along the west coast of peninsular India during pre-monsoon season: A case study based on satellite data and regional climate model

The circulation dynamics of an event marked by the formation of an aerosol cluster off the coast of Maharashtra on April 22, 2006, its southward migration along the Indian west coast with a mean speed of ~200 km/day and its final dissipation after reaching the end of the peninsula by April 28, 2006 as revealed by MODIS (Moderate Resolution Imaging Spectroradiometer) against the pre-monsoon conditions of April 2006 are examined in this study. The maximum aerosol concentration in the cluster was found getting confined to lower and lower altitudes during its southward movement. The NCEP/NCAR (National Centers for Environmental Prediction/National Center for Atmospheric Research) reanalysis wind field indicates that the atmospheric circulation, especially the horizontal wind convergence is the major factor that guides the formation and the dynamics of the cluster. Fine mode fraction from MODIS suggests that the cluster mainly consists of coarse dust particles. The regional climate model, RegCM3 with an efficient dust generation module simulates the formation and movement of the cluster appreciably well. The simulations which also exhibit the altitudinally descending nature of the cluster during its southward movement confirm the mechanism which governs the cluster dynamics suggested based on MODIS and NCEP/NCAR reanalysis data.     

Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures

A revised regular solution-type thermodynamic model for twelve-component silicate liquids in the system SiO₂-TiO₂-Al₂O₃-Fe₂O₃-Cr₂O₃-FeO-MgO-CaO-Na₂O-K₂O-P₂O₅-H₂O is calibrated. The model is referenced to previously published standard state thermodynamic properties and is derived from a set of internally consistent thermodynamic models for solid solutions of the igneous rock forming minerals, including: (Mg,Fe²⁺,Ca)-olivines, (Na,Mg,Fe²⁺,Ca)^M2 (Mg,Fe²⁺, Ti, Fe³⁺, Al)^M1 (Fe³⁺, Al,Si)₂ ^TETO₆-pyroxenes, (Na,Ca,K)-feldspars, (Mg,Fe²⁺) (Fe³⁺, Al, Cr)₂O₄-(Mg,Fe²⁺)₂ TiO₄ spinels and (Fe²⁺, Mg, Mn²⁺)TiO₃-Fe₂O₃ rhombohedral oxides. The calibration utilizes over 2,500 experimentally determined compositions of silicate liquids coexisting at known temperatures, pressures and oxygen fugacities with apatite ±feldspar ±leucite ±olivine ±pyroxene ±quartz ±rhombohedral oxides ±spinel ±whitlockite ±water. The model is applicable to natural magmatic compositions (both hydrous and anhydrous), ranging from potash ankaratrites to rhyolites, over the temperature (T) range 900°–1700°C and pressures (P) up to 4 GPa. The model is implemented as a software package (MELTS) which may be used to simulate igneous processes such as (1) equilibrium or fractional crystallization, (2) isothermal, isenthalpic or isochoric assimilation, and (3) degassing of volatiles. Phase equilibria are predicted using the MELTS package by specifying bulk composition of the system and either (1) T and P, (2) enthalpy (H) and P, (3) entropy (S) and P, or (4) T and volume (V). Phase relations in systems open to oxygen are determined by directly specifying the f _{o 2} or the T-P-f _{o 2} (or equivalently H-P-f _{o 2}, S-P-f _{o 2}, T-V-f _{o 2}) evolution path. Calculations are performed by constrained minimization of the appropriate thermodynamic potential. Compositions and proportions of solids and liquids in the equilibrium assemblage are computed.     

FY-3 A/MERS I积雪制图中NDS I指标建立及积雪判识模型研究 ——以祁连山区为例

我国新型自主的极轨气象卫星风云3号A星（简称FY-3A）上搭载的中分辨率光谱成像仪（MERSI）为大面积雪监测提供了新的遥感数据源。以中国西北祁连山区为例,分析FY-3A/MERSI传感器积雪与其它地物的图谱特征差异,建立了适用于FY-3A/MERSI的归一化差分积雪指数（NDSI）,以此为基础,构建了综合利用多光谱判别指标及土地覆盖类型（LULC）定类辅助的积雪判识模型,生成250 m分辨率的日积雪制图产品。模型通过逐步逼近的树状判别结构,去除了易和积雪混淆的部分乔木林、云、云阴影、水体、湖冰、沙（盐）地等地物,并提出应考虑积雪下覆地表特性的影响,调整设定不同LULC类型的积雪判别阈值约束,实时结合区域LULC影像进行积雪的最终判定与优化。对祁连山区2010-2011年积雪季FY-3A/MERSI影像的积雪制图应用结果表明,该资料能够客观精细地反映积雪的空间分布与动态发展过程。同时利用气象台站积雪观测记录及Terra/MODIS积雪判识结果进行对比验证,结果表明基于FY-3A/MERSI建立的积雪判识模型具有较高的精度和稳定性,特别是提高了云雪区分的效能。     

A parameterized model for REE distribution between low-Ca pyroxene and basaltic melts with applications to REE partitioning in low-Ca pyroxene along a mantle adiabat and during pyroxenite-derived melt and peridotite interaction

Low-Ca pyroxenes play an important role in mantle melting, melt-rock reaction, and magma differentiation processes. In order to better understand REE fractionation during adiabatic mantle melting and pyroxenite-derived melt and peridotite interaction, we developed a parameterized model for REE partitioning between low-Ca pyroxene and basaltic melts. Our parameterization is based on the lattice strain model and a compilation of published experimental data, supplemented by a new set of trace element partitioning experiments for low-Ca pyroxenes produced by pyroxenite-derived melt and peridotite interaction. To test the validity of the assumptions and simplifications used in the model development, we compared model-derived partition coefficients with measured partition coefficients for REE between orthopyroxene and clinopyroxene in well-equilibrated peridotite xenoliths. REE partition coefficients in low-Ca pyroxene correlate negatively with temperature and positively with both calcium content on the M2 site and aluminum content on the tetrahedral site of pyroxene. The strong competing effect between temperature and major element compositions of low-Ca pyroxene results in very small variations in REE partition coefficients in orthopyroxene during adiabatic mantle melting when diopside is in the residue. REE partition coefficients in orthopyroxene can be treated as constants at a given mantle potential temperature during decompression melting of lherzolite and diopside-bearing harzburgite. In the absence of diopside, partition coefficients of light REE in orthopyroxene vary significantly, and such variations should be taken into consideration in geochemical modeling of REE fractionation in clinopyroxene-free harzburgite. Application of the parameterized model to low-Ca pyroxenes produced by reaction between pyroxenite-derived melt and peridotite revealed large variations in the calculated REE partition coefficients in the low-Ca pyroxenes. Temperature and composition of starting pyroxenite must be considered when selecting REE partition coefficients for pyroxenite-derived melt and peridotite interaction.