Distribution of major and minor constituents between mica and host ultrabasic rocks,and between zoned mica and zoned spinel

Ultrabasic rocks with Niggli values for si between 26 and 100, and k between 0.6 and 1 have been chosen for the study of the distribution of 23 major and minor constituents between phlogopite and the host rock. The rocks include kimberlites, carbonatites and lamprophyres which contain abundant zoned micas and a few zoned spinels. Chemical variations in zoned mica and spinel were determined by electron probe microanalysis, and distribution coefficients for Al, Ti, Fe, Cr, Mg, Mn, and Ni were calculated between mica and spinel for the average composition of the mica and spinel, and for chemically-related and adjacent zones. The spinel changes from chromite in the centre to chromian ulvöspinel in the rim, and the mica from chromian phlogopite, through titaniferous biotite to chromium-poor phlogopite. Distribution coefficients for Cr and Fe between adjacent zones in spinel (0.8 and 0.02 for Cr; 1.1 and 3.1 for Fe) and in mica (0.4 and 0.1 for Cr; 2 and 0.3 for Fe) show more variation than the distribution coefficients between the cogenetic phlogopite and chromite (0.04 for Cr, 0.2 for Fe), and biotite and ulvöspinel (0.08 for Cr; 0.2 for Fe). It is concluded that distribution coefficients for major and minor constituents between related zones are more meaningful than those calculated from the average chemical composition of zoned minerals.The results indicate that phlogopite is the principal carrier of potassium, rubidium, aluminium, fluorine and primary water in kimberlite and carbonatite. Minor elements, such as chlorine, lithium, barium, nickel, chromium, titanium and zinc are present mainly in the mica, whereas sodium, strontium, calcium, carbon and manganese are more abundant in other minerals.     

Bond length and radii variations in fluoride and oxide molecules and crystals

Molecular orbital calculations completed on fluoride molecules containing first and second row cations have generated bond lengths, R, that match those observed for coordinated polyhedra in crystals to within ～0.04 Å, on average. The calculated bond lengths and those observed for fluoride crystals can be ranked with the expression R=Kp ^?0.22, where p=s/r, s is the Pauling strength of the bond, r is the row number of the cation and K=1.34. The exponent -0.22 (≈ -2/9) is the same as that observed for oxide, nitride and sulfide molecules and crystals. Bonded radii for the fluoride anion, obtained from theoretical electron density maps, increase linearly with bond length. Those calculated for the cations as well as for the fluoride anion match calculated promolecule radii to within ～0.03 Å, on average, suggesting that the electron density distributions in the vicinity of the minima along the bond paths possess a significant atomic component despite bond type. Bonded radii for Si and O ions provided by experimental electron density maps measured for the oxides coesite, danburite and stishovite match those calculated for a series of monosilicic acid molecules. The resulting radii increase with bond length and coordination number with the radius of the oxide ion increasing at a faster rate than that of the Si cation. The oxide ion within danburite exhibits several distinct radii, ranging between 0.9 and 1.2 Å, rather than a single radius with each exhibiting a different radius along each of the nonequivalent bonds with B, Si and Ca. Promolecule radii calculated for the coordinated polyhedra in danburite match procrystal radii obtained in a structure analysis to within 0.002 Å. The close agreement between these two sets of radii and experimentally determined bonded radii lends credence to Slater's statement that the difference between the electron density distribution observed for a crystal and that calculated for a procrystal (IAM) model of the crystal “would be small and subtle, and very hard to determine by examination of the total charge density.”     

红藻石和蓝藻石概念及分类归属的综述和修订

在分析和总结前人对红藻石和蓝藻石研究成果基础上,结合岩石薄片显微镜下观察实例,发现在以往碳酸盐岩颗粒分类中没有红藻石和蓝藻石的合适位置。鉴于红藻石重要的成因意义和造礁作用,有必要明确红藻石的概念和归属。珊瑚藻本身极易钙化,经生物矿化作用最终保存下来的珊瑚藻屑一直放在生物碎屑中,而红藻石是由非固着的珊瑚藻构成的钙质独立结核,因此也可以被划分到生物碎屑中。蓝藻石作为蓝细菌钙化作用的产物,同时鉴于蓝藻石的广泛存在,把钙化蓝细菌形成的核形石命名为蓝藻石,这一重要概念从提出到现在一直被使用。然而蓝绿藻概念已变更为蓝细菌,蓝藻石的形成与藻类无关,显然将其称作蓝菌石更加确切。因此,应将红藻石和蓝藻石分别归为生物碎屑和核形石当中,并用新的术语蓝菌石替代蓝藻石。其意义在于使红藻石和蓝藻石的概念及归属更为规范,并为碳酸盐岩颗粒的深入研究提供有益线索。     

Saturated and aromatic diterpenoids and triterpenoids in Eocene coals and mudstones from China

Several series of saturated, diaromatic, triaromatic C-ring cleaved and triaromatic diterpenoids and triterpenoids have been detected in 4 immature coal and mudstone samples. A number of these compounds appear to represent intermediates in a series of postulated pathways for progressive aromatization of biogenic diterpenoids and triterpenoids. Diagenetic pathways for the formation of tricyclic aromatic hydrocarbons from abietane and pimarane type diterpenoid precursors and for the formation of diaromatic, triaromatic C-cleaved and triaromatic hydrocarbons from β-amyrin and other triterpenoid precursors are proposed. Saturated and aromatized abietanes, pimaranes and phyllocladanes, which are the most abundant compounds in all 4 samples, indicate a predominant higher plant input which can be related to the Coniferales group but not to individual plant families. β-Amyrin and other triterpenoid-derived triaromatic and triaromatic C-ring cleaved hydrocarbons with triterpenoid structures are thought to be characteristic for angiosperms. The relative concentrations of the triaromatic and triaromatic C-ring cleaved hydrocarbons are higher in samples 9602 (mudstone) and 9603 (coal) than samples 9601 (coal) and 9604 (mudstone) indicating samples 9602 (mudstone) and 9603 (coal) contain relatively more angiosperm derived organic matter than samples 9601 (coal) and 9604 (mudstone). The distribution patterns and the relative concentrations of saturated and aromatic diterpenoids and triterpenoids thus are valuable markers for the determination of the relative contents of biological sources of organic material in geological samples.     

Compositional variation within some glauconites and illites and implications for their stability and origins

Textural, mineralogical and chemical data are presented for glauconites and illites from the Lower Cretaceous Glauconitic Sand Formation, Alberta, Canada. Single crystal analyses by scanning transmission electron microscopy (STEM) indicate that both glauconite (29 analyses) and illite (44 analyses) correspond very closely to ideal dioctahedral structures. Al dominates the octahedral sheet in illite. Very extensive A1 for Fe^III substitution was also found in some of the glauconites, much more than previously recorded. The dioctahedral mica structure is clearly very stable and flexible with respect to A1 for Fe^III substitution. Iron-poor glauconites were found associated with pyrite. We believe that glauconites tend to lose iron progressively during burial diagenesis, especially where pore water iron activities are low (high HS^? activity and low Eh). It seems probable that A1 for Si tetrahedral substitution also takes place during diagenesis with consequent loss of swelling properties. This is the same trend which is responsible for conversion of smectite to illite. Glauconite forms only where sediments reside for lengthy periods at the interface between oxidizing and reducing environments, where Fe³⁺ is transiently available in solution. Related marine and terrestrial nontronites also form only in similar ‘interface’ environments.     

Scandium in rocks,minerals and sediments and its relations to iron and aluminium

Scandium, aluminium and iron contents of a considerable number of rocks, minerals and sediments for various origin are given. They have been obtained by instrumental neutron activation analysis.The concentrations of these elements in rocks and minerals are very variable. However the Fe/Sc and Al/Sc ratios for the finer particles of sediments from different origins are fairly constant. At a spec. surf. of 100 m²/g is found 0.2 to 0.3 × 10⁴ for Fe/Sc and 0.60 to 0.95 × 10⁴ for Al/Sc (mol).In the coarser sediments there is a considerable influence of particle size. Consequently when Sc-contents of sediments are compared for classification purposes, their spec. surf. or granulometric composition should be determined as well.     

Transient and spatial modeling and simulation of polybrominated diphenyl ethers reaction and transport in air, water and soil

The release of the wastes containing polybrominated diphenyl ethers into the environment is a worldwide major concern. Investigation of spatial and temporal variations of polybrominated diphenyl ethers concentrations due to different factors, especially the transport of these species between air and water as well as between air and soil is the purpose of present research. A model was developed and solved using the methods of finite difference and lines. Simulations were implemented for three dimensions of width, length, and height and also time for the air compartment, whereas for the soil and water compartments, variations were considered only with respect to height and time. Transport between water and soil was disregarded for simplicity at this stage. Vancouver’s landfill was considered as a case study. Lower concentrations in air and higher concentrations in water at the interface show that these pollutants tend to diffuse from air to water. Concentrations of all four pollutants decrease near the interface in soil as time passes, but they are predicted to be almost constant at other levels.     

中国西部环境与生态科学数据中心：面向西部环境与生态科学的数据集成与共享

国家自然科学基金委员会“中国西部环境与生态科学研究计划”自2001年启动以来,有力地推动了西部区域环境演化、陆地生态过程和人类活动对环境的影响等方面的研究,积累了丰富的基础数据。国家自然科学基金委员会“中国西部环境与生态科学数据中心”承担“西部计划”项目数据产出的收集、管理、集成,并面向西部环境与生态科学的各个领域提供科学数据服务。“西部数据中心”的总体框架是以“西部计划”和地球系统科学发展的科学需求为导向,建成以数据共享、知识积累、合作交流和数据科学为主要内容的集成平台,为“西部计划”多学科的交叉研究和成果的综合集成及地球科学发展的长远目标服务。以共建共享的指导思想集成针对西部环境与生态现状与变化的基础背景数据、环境与生态观测数据、模型数据集、数据工具及数据文档;并以完全与开放的数据共享原则为用户提供推送式数据服务。目前,“西部数据中心”已完成了数据共享平台、知识积累平台与合作交流平台的开发和集成,初步形成了科学数据平台,整理并发布了大量的西部环境生态科学所需的关键数据集。     

Growth and change and the innovative firm

Regional economic development is largely influenced by technical progress, and innovative manufacturing firms are important in this context. Large, fast growing, innovative firms contribute significantly to growth by direct and indirect employment and income-generating impacts, and these are likely to be extended through time if the firms are capable of developing new product lines and markets. Unfortunately, ‘orthodox’ theories of the firm provide a poor basis for understanding ‘how’ and ‘why’ innovative firms come into existence, grow, change, and operate over time and geographic space. Behavioral—managerial notions, on the other hand, do appear to provide a useful basis for conceptualization. This paper examines some of these concepts and goes on to provide a framework for understanding growth and change in innovative, multiproduct, multiregional firms.     

Periglacial phenomena and their significance as climatic and edaphic indicators

As formed by frost-action and the presence of intensely frozen ground periglacial phenomena, especially microrelief features, are good examples for geomorphic phenomena as being clearly dependent upon specific climatic conditions. Whereas climate controls and delimits the formation and occurrence of periglacial phenomena at a zonal and regional scale, non-climatic vegetational, topographical and edaphic factors are significant within the climatically defined boundary conditions at a smaller scale. It can be shown that each type of periglacial phenomenon is dependent on specific climatic and edaphic conditions. Data on these conditions are compiled in several tables. On the other hand, because of this dependence on specific environmental conditions periglacial phenomena are at the same time diagnostic indicators for such conditions. As to climate they are indicators for specific climatically defined types of frozen ground and for thermal conditions in terms of mean values, such as mean air temperatures, freezing and thawing indexes. Spatial associations of genetically different types of periglacial phenomena indicate the extent and regional subdivision of the periglacial environment and its climatic limits. The definition of the climate-diagnostic value of present periglacial phenomena is an essential perequisite for the palaeoclimatic interpretation phenomena are sensitive to climatic variations of small amplitude and as such they are also indicators of recent short-term climatic changes. As to edaphic conditions they indicate frost-action potential of the groud and various soil properties which have practical implications. As edaphic indicators periglacial phenomena are of significance for terrain evaluation programmes in the Arctic for practical purposes.     

Dry and wet laboratory tests and thermal fatigue of rocks

Investigation of the weathering and weatherability of three types of igneous rocks (granite, nepheline syenite and lamprophyric-minette dyke) was carried out by means of laboratory tests.For this purpose an experimental device was developed to obtain hot conditions alternating with room temperature and also with wet conditions, by immersion in two types of liquids (distilled water and a solution simulating “seawater”).Beyond qualitative effects emphasized in the text and in a photographic documentary, some quantitative determinations were made (weight loss and chemical decay of main cations of rock-minerals), which enable the authors to present an attempt at an alterability index for classification of the rocks. The research-program outlined on quantitative determinations is suitable for application in problems of engineering geology such as in determining suitability of rocks for use as breakwater stone or riprap for dams or in the stone deterioration measurements of the deterioration of stone used for buildings and ornamental facing stones.     

Single-crystal absorption and reflection infrared spectroscopy of forsterite and fayalite

Polarized single-crystal absorption and reflection spectra of fundamental modes in both the mid- and far-infrared are presented for microscopic crystals of forsterite and fayalite. All modes predicted by symmetry were observed for forsterite, but two B_3u modes were not observed for fayalite. Consideration of previously determined frequency shifts for isotopically and chemically substituted olivines, along with symmetry analysis, produced a complete set of band assignments satisfying all constraints for forsterite. A plausible assingment was derived for fayalite by analogy. The frequency shifts from forsterite to fayalite are consistently small for bands assigned to SiO₄ stretching and bending, moderate for rotations, and large for translations of M-site ions, suggesting that in olivine, SiO₄ groups vibrate separately from the lattice. Allocating the bending and external modes among multiple continua in Kieffer's (1979c) model considerably improves prediction of quasiharmonic heat capacityC _v and entropy for forsterite (～1% discrepancy from 200–1000 K). The experimental entropy of fayalite is closely accounted for (1.8 to 0.1%) by summing lattice, electronic (from Burns' (1985) optical band assignment), and constant magnetic contributions above 200 K.S _magnetic determined from the difference of the experimental and model lattice entropies shows inflection points at the two magnetic transition temperatures (23 and 66 K) and indicates that complete spin disorder is not achieved below 680 K.     

风险分析实践的感悟

考虑到我国水资源短缺、水灾害频发和水环境恶化的情势,在水利建设和管理中,突出风险意识是非常必要的和十分及时的。我们多年从事风险分析实践的感悟是：水利风险模拟分析完全不同于建筑结构物的可靠度计算,更不是模拟设计洪水的淹没范围和水深,其真谛是在于如实模拟出当地的水旱灾害的不确定性,是对传统思维模式的重大的突破。有些传统理念也有必要作调整,如：工程水文学科的内涵,可持续发展的不确定性和风险分析的风险。     

景观格局与水土流失的尺度特征与耦合方法

景观格局与生态过程的耦合研究是景观生态学研究的核心科学问题,也是综合自然地理学深化和发展的关键.尺度广泛存在于生态学现象中,尺度效应与尺度转换是景观生态学研究面临的挑战,探讨格局与过程之间相互作用机理与尺度特征是为解决尺度问题提供理论依据的必然途径.水土流失作为一种生态过程,是国内外颇为关注的生态问题.依据多种研究手段,在不同尺度上开展景观格局与水土流失的相互关系与尺度特征的研究,在分析景观格局的时空异质性、水土流失的影响因子与尺度效应的基础上,揭示流域景观格局与水土流失的耦合机理,发展尺度转换方法和景观格局-水土流失过程耦合模型,是完善景观生态学的理论基础,是为水土流失区生态建设提供科学依据的重要途径.     

Geoconservation for science and society: challenges and opportunities

Well managed and accessible geological and geomorphological sites are important to both science and society, for research, education, and, in some cases, for recreation. In this viewpoint paper we celebrate achievements in the field of geoconservation over the last 60 years since the first geological Sites of Special Scientific Interest were designated in the UK following the passing of the National Parks and Access to the Countryside Act in 1949. With a range of new political, social, economic and environmental challenges and opportunities coming to the fore, geoconservation now needs to innovate and adapt in order to sustain and enhance its influence and effectiveness. In advance of the 2011 Geologists’ Association Annual Meeting, Geoconservation for Science and Society: An Agenda for the 21st Century, we give our view on the challenges and opportunities facing geoconservation and the areas in which new approaches and partnerships are required to secure the long-term conservation of our geological and geomorphological heritage.     

煤与瓦斯突出的激发和发生条件

从影响煤与瓦斯突出的地应力、瓦斯、煤岩物理力学性质和地质构造因素出发,提出把煤与瓦斯突出的过程划分为突出源的形成发展、突出的激发和发生三个阶段。以南桐煤矿典型突出事故为例,用演绎法探讨了突出激发与发生的条件。结果表明,一切由振动产生的岩体裂隙和冲击载荷是导致煤与瓦斯突出的激发条件,并根据充瓦斯煤的损伤蠕变方程,得到了预测延期突出的时间。根据突出过程中的能量转换关系,得到了突出的起动速度和瓦斯临界压力表达式,对煤与瓦斯突出发生涉及的几个难点问题进行了讨论。揭示了煤与瓦斯突出的主要能量是瓦斯膨胀能,突出时喷出的瓦斯由多个来源的瓦斯组成,且地质构造区在采矿过程中容易形成有利于突出的源。     

Bedload transport and bed resistance associated with density and turbidity currents

Turbidity currents in the ocean are driven by suspended sediment. Yet results from surveys of the modern sea floor and turbidite outcrops indicate that they are capable of transporting as bedload and depositing particles as coarse as cobble sizes. While bedload cannot drive turbidity currents, it can strongly influence the nature of the deposits they emplace. This paper reports on the first set of experiments which focus on bedload transport of granular material by density underflows. These underflows include saline density flows, hybrid saline/turbidity currents and a pure turbidity current. The use of dissolved salt is a surrogate for suspended mud which is so fine that it does not settle out readily. Thus, all the currents can be considered to be model turbidity currents. The data cover four bed conditions: plane bed, dunes, upstream‐migrating antidunes and downstream‐migrating antidunes. The bedload transport relation obtained from the data is very similar to those obtained for open‐channel flows and, in fact, is fitted well by an existing relation determined for open‐channel flows. In the case of dunes and downstream‐migrating antidunes, for which flow separation on the lee sides was observed, form drag falls in a range that is similar to that due to dunes in sand‐bed rivers. This form drag can be removed from the total bed shear stress using an existing relation developed for rivers. Once this form drag is subtracted, the bedload data for these cases collapse to follow the same relation as for plane beds and upstream‐migrating antidunes, for which no flow separation was observed. A relation for flow resistance developed for open‐channel flows agrees well with the data when adapted to density underflows. Comparison of the data with a regime diagram for field‐scale sand‐bed rivers at bankfull flow and field‐scale measurements of turbidity currents at Monterey Submarine Canyon, together with Shields number and densimetric Froude number similarity analyses, provide strong evidence that the experimental relations apply at field scale as well.     

试论陆相层序地层学及其在油气勘探开发中的意义

根据陆相层序地层的自身特点,对其层序界线、层序级别、层序界面等特征进行了分析,并把陆相层序地层分成断陷和坳陷两种盆地层序模式。最后根据层序模式特征阐述了陆相层序地层学在油气勘探开发中的实际意义。     

Analysis and characterization of the synergistic AIRS and MODIS cloud-cleared radiances

The Atmospheric Infrared Sounder (AIRS) and MODerate-Resolution Imaging Spectroradiometer (MODIS) on board NASA Earth Observing System (EOS) Aqua spacecraft measure the upwelling infrared radiance used for numerous remote-sensing- and climate-related applications. AIRS provides high spectral resolution infrared radiances, while MODIS provides collocated high spatial resolution radiances at 16 broad infrared bands. An optimal algorithm for cloud-clearing has been developed for AIRS cloudy soundings at the University of Wisconsin-Madison, where the spatially and spectrally collocated AIRS and MODIS data has been used to analyze the characteristic of this algorithm. An analysis and characterization of the global AIRS cloud-cleared radiances using the bias and the standard deviation between the cloud-cleared and the nearby clear measurements are studied. Scene inhomogeneity for both land- and water-surface types has been estimated to account for the assessed error. Both monthly and seasonal changes of global AIRS/MODIS cloud-clearing performance also have been analyzed.