Geochemistry and tectonic significance of altered basaltoids from the Pontic Ranges,Turkey

The basaltoids of the Küre area, Pontides of northern Turkey, associate with eugeosynclinal greywackes and black shales. They comprise massive flows, pillow lavas, and cutting diabase dikes. In the submarine environment and still more during the formation of the Küre copper ores, the basaltoids were severely altered, which affected particularly their alkali contents. In spite of variable proportions of main components, the study of stable trace elements permits a confident identification of the rocks as tholeiites of ocean floor affinity. The Küre basaltoids are considered to have been generated during the expansion of the marginal basin of the Anatolian troughs.     

A palaeomagnetic study of charnockites from Madras Block, Southern Granulite Terrain, India

The South Indian Craton is composed of low-grade and high-grade metamorphic rocks across different tectonic blocks between the Moyar–Bhavani and Palghat–Cauvery shear zones and an elongated belt of eastern margin of the peninsular shield. The Madras Block north of the Moyar–Bhavani shear zone, which evolved throughout the Precambrian period, mainly consists of high-grade metamorphic rocks. In order to constrain the evolution of the charnockitic region of the Pallavaram area in the Madras Block we have undertaken palaeomagnetic investigation at 12 sites. ChRM directions in 61 oriented block samples were investigated by Alternating Field (AF) and Thermal demagnetization. Titanomagnetite in Cation Deficient (CD) and Multi Domain (MD) states is the remanence carrier. The samples exhibit a ChRM with reverse magnetization of D_m = 148.1, I_m = + 48.6 (K = 22.2, α₉₅ = 9.0) and a palaeomagnetic pole at 37.5 °N, 295.6 °E (dp/dm = 7.8°/11.8°). This pole plots at a late Archaean location on the Indian Apparent Polar Wander Path (APWP) suggesting an age of magnetization in the Pallavaram charnockites as 2600 Ma. The nearby St. Thomas Mount charnockites indicate a period of emplacement at 1650 Ma (Mesoproterozoic). Thus the results of Madras Block granulites also reveal crustal evolution similar to those in the Eastern Ghats Belt with identical palaeopoles from both the areas.     

Neotectonic deformation in the western sector of tectonic escape in Anatolia: palaeomagnetic study of the Afyon region, central Turkey

Following final closure of the Neotethyan Ocean during the late Miocene, deformation in central Turkey has led to crustal thickening and uplift to produce the Anatolian Plateau followed by westward extrusion of terranes by strike–slip. Widespread volcanism has accompanied this latter (neotectonic) phase, and palaeomagnetic study of the volcanism shows a coherent record of differential block rotations, indicating that the Anatolian region is not a plate (or ‘platelet’) sensu stricto but is undergoing distributed internal deformation. To evaluate the scale of neotectonic rotations in the transition zone near the western limit of tectonic escape and the border of the extensional domain in central-west Turkey, we have studied the palaeomagnetism at 82 sites in volcanic suites distributed along a 140-km lineament with north–south trend and ranging in age from 18 to 8 Ma. Comparable deflection of magnetic remanence from the present field direction is identified along the full length of the lineament. A mean clockwise rotation of 12.3±4.2° is determined for this western sector of the Anatolian strike–slip province. Since similar rotations are observed in the youngest and oldest units, this cumulative rotation occurred after the late Miocene. When interpreted together with results elsewhere in Anatolia, it is inferred that the rotation is later than crustal thickening and uplift of the Anatolian Plateau and entirely a facet of the tectonic escape. Inclinations are mostly 10° shallower than the predicted Miocene field and are considered to reflect the presence of a persistent inclination anomaly in the Mediterranean region. Larger rotations departing from the regional trend are also observed within the study region, but are confined to the vicinity of major faults, notably those bounding the Afyon-Ak ehir Graben.The pattern of neotectonic declinations across Anatolia identifies strong anticlockwise rotation in the east near the Arabian pincer with progressive reduction in the amount of rotation towards the west; it becomes zero or slightly clockwise at the western extremity of the accreted terrane collage. Rotations also appear to become generally younger towards the south. Crustal deformation has therefore been distributed, and the net effect of terrane extrusion to the west and south has been to expand the curvature of the Tauride Arc. The westward radial expansion of the extruded terranes is inferred to combine with backroll on the Hellenic Arc to produce the contemporary extensional province in western Turkey.     

Magnetocrystalline anisotropy of rocks and massive ores: A mathematical model study and its fabric implications

A simple mathematical model has been used to evaluate the influence of grain magnetocrystalline anisotropy and the scatter of crystallographic axes of grains on the magnetic anisotropy of rocks and massive ores whose carrier of magnetism is a magnetically uniaxial mineral of the type of pyrrhotite or hematite. The variation in magnetic anisotropy of rocks and ores whose carrier of magnetism displays the magnetocrystalline anisotropy greater than 100 is due to the variation in the preferred orientations of crystallographic axes, while the influence of the variation in the grain anisotropy on the rock (ore) anisotropy can be neglected.     

Preliminary palaeomagnetic study of loess from the Wucheng section,North China

One hundred and seventeen oriented specimens of loess (in the form of cubes with an edge of 4 cm) were collected from the Wucheng loess section in Xixian County, Shanxi Province. After magnetic cleaning in an alternating field the remanent magnetization of specimens was measured with an astatic magnetometer (sensitivity 4×10^?3 emu/cm³). The normally magnetized zone of the Brunhes normal epoch is recorded in upper Pleistocene Malan loess and middle Pleistocene Lishi loess which contain typical Zhoukoudian fauna. The reversely magnetized zone of the Matuyama reversed epoch is observed in lower Pleistocene Wucheng loess, whose fossils are found corresponding to Villafranchian Nihowan fauna.     

A palaeomagnetic study of the Charnian,Caldecote, and Uriconian volcanics and plutons,central England

This palaeomagnetic study has investigated intrusive and extrusive calc-alkaline igneous rocks comprising the pre-Ordovician basement of central England and the Welsh Borderlands and dated ca. 560–530 Ma. Demagnetization studies resolve a range of magnetic components in both the older volcanic successions comprising the eastern Uriconian volcanics, and in the younger intrusive episodes comprising the Charnwood and South Leicestershire outcrops. Post-Ordovician overprinting is largely absent and the remanence record dates from ca. 560–420 Ma. Within this time interval field tests are inadequate to confirm a primary origin and some components may be overprints acquired in immediate post-Uriconian (Cadomian) or during late Ordovician (early Caledonian) thermotectonic events. A first order continuity is recognized on a palaeomagnetic scale between the data from the Midlands-Welsh Borderlands and the terranes exposed in Anglesey and Southwest Wales. The British terranes moved through low latitudes during the interval represented by the Uriconian episode; they crossed the palaeoequator during the folding of these rocks and prior to emplacement of the later intrusive suite. Collectively they had rotated through ca. 170° and moved into intermediate latitudes by mid-Lower Cambrian times. Post-Lower Cambrian movements on the Malvernian lineament are a possible explanation for second order differences between the palaeomagnetic records of the English Midlands and the Welsh Borderlands; the largest possible regional rotation here is a ca. 90° movement of the Charnwood block with respect to the other outcrops. Correlation with the Gondwana APW path places the Anglo-Welsh basement in the vicinity of a comparable calc-alkaline volcanic province linked to a subducting plate margin in the Afro-Arabian area. Subsequent continental breakup led to termination of this volcanic activity and establishment of a passive marine shelf environment later in Lower Cambrian times.     

Amelia Creek: a Proterozoic impact structure in the Davenport Ranges,Northern Territory

The Amelia Creek impact structure is located in Australia's Northern Territory in folded Palaeoproterozoic strata of the Davenport Ranges (20°51'S, 134°53′E). An impact origin is confirmed by presence of unequivocal shatter cones with apices that point upwards, and by planar microstructures in quartz grains from target sandstones of the Hatches Creek Group. Aeromagnetic, advanced spaceborne thermal emission and reflection radiometer (ASTER), and X-band synthetic aperture radar (X-SAR) images show an area of anomalous deformation in which smooth regional trends are disrupted by arcuate features at a 10 km radius to the north and south of the shock-metamorphosed rocks. However, no arcuate forms are apparent to the east and west of these shocked rocks, and instead, large south-southwest-trending faults are present about 6 km away on both sides. Despite pervasive shatter coning, typical of the central region of complex impact structures, no structural uplift is apparent, but instead the shocked rocks lie at the southern toe of a north-northeast-trending syncline. These shatter cones overprint and post-date the Palaeoproterozoic regional deformation, and thus, the impact structure has not been refolded and its abnormal form is likely due to pre-existing structure in the target rocks and/or an oblique impact. Small pockets of undeformed Late Neoproterozoic and Middle Cambrian strata are exposed in palaeovalleys in the central region of the structure, constraining the time of the impact to the Proterozoic.     

Geochemistry of eocene calc-alkaline volcanic rocks from the Kastamonu area,Northern Turkey

Analytical data for Sr, Rb, Cs, Ba, Pb, rare earth elements, Y, Th, U, Zr, Hf, Sn, Nb, Mo, Ni, Co, V, Cr, Sc, Cu and major elements are reported for eocene volcanic rocks cropping out in the Kastamonu area, Pontic chain of Northern Turkey. SiO₂% versus K₂O% relationship shows that the analyzed samples belong to two major groups: the basaltic andesitic and the andesitic ones. High-K basaltic andesites and low-K andesites occur too. Although emplaced on continental type basement (the North Anatolian Crystalline Swell), the Pontic eocene volcanics show elemental abundances closely comparable with typical island arc calc-alkaline suites, e.g. low SiO₂% range, low to moderate K₂O% and large cations (Cs, Rb, Sr, Ba, Pb) contents and REE patterns with fractionated light and almost flat heavy REE patterns. REE and highly charged cations (Th, U, Hf, Sn, Zr) are slightly higher than typical calc-alkaline values. Ferromagnesian elements show variable values. Within the basaltic andesite group the increase of K%, large cations, REE, La/Yb ratio and high valency cations and the decrease of ferromagnesian element abundances with increasing SiO₂% content indicate that the rock types making up this group developed by crystalliquid fractionation of olivine and clinopyroxene from a basic parent magma. Trace element concentration suggest that the andesite group was not derived by crystal-liquid fractionation processes from the basaltic andesites, but could represent a distinct group of rocks derived from a different parent magma.     

A palaeomagnetic and mineral magnetic study of the loess sequence at Liujiapo,Xian, China

Employing an average vertical sampling interval of 20 cm, oriented samples were collected from 26 m of the loess section at Liujiapo, near Xian, China in order to refine the existing magnetostratigraphic record. Palaeomagnetic results reveal two short reversed-polarity subzones within a profile of predominantly normally magnetised sediments, an interpretation that is at variance with previous results from this section and from other studies of Chinese loess. Investigation of sediment mineral-magnetic properties indicates a close correspondence between down-section variations in intensity of magnetisation, susceptibility and saturation isothermal Journal of Quaternary Science remanence (SIRM), and lithology. The ratios IRM_-100mT/SIRM and SIRM/ susceptibility appear to be particularly sensitive indicators of the degree of soil development and hence of palaeoclimate.     

Evidence of lacustrine sedimentation in the Upper Permian Bijori Formation, Satpura Gondwana basin: Palaeogeographic and tectonic implications

The Upper Permian Bijori Formation of the Satpura Gondwana basin comprising fineto coarse-grained sandstone, carbonaceous shale/mudstone and thin coal bands was previously interpreted as the deposits of meandering rivers. The present study documents abundance of wave ripples, hummocky and swaley cross-stratification and combined flow bedforms in the Bijori Formation, suggesting that a significant part of the formation was deposited in a wave-agitated environment. Evidence of near-emergent depositional conditions provided by repeated occurrence of rootlet beds and hydromorphic paleosols, local flooding surfaces denoting rapid fluctuation of water level, occurrences of temnospondyl vertebrate fossils, and absence of tidal signatures and marine fossils suggest a lacustrine rather than marine depositional regime. Five facies associations recognised within the Bijori Formation are inferred to represent fluvial channels and associated floodplains (FA1), lake shorelines (FA2), subaqueous distributary channels and associated levees (FA3), waveand storm-affected delta front (FA4), and open lacustrine/lower shoreface (FA5) deposits. The planoconcave fluvial channel-fill sandbodies with unidirectional cross-beds are clearly distinguishable from the delta front bars that show a convexo-plan or bi-convex sandbody geometry and dominance of wave and combined flow bedforms. Some of the distributary channels record interaction of fluvial and wave-dominated basinal processes. Major distributary sandbodies show a north to northwest flow direction while wave-affected delta front sandbodies show very complex flow patterns reflecting interaction between fluvial discharge and wave processes. Wave ripple crest trends show that the lake shoreline had an overall east-northeast to west-southwest orientation. The lack of documented contemporaneous lacustrine or marine sediments in the Satpura Gondwana basin posed a major problem of basin-scale palaeogeographic reconstruction. The existence of Bijori lake solves the problem and the lake is inferred to have acted as repository for the contemporaneous alluvial drainage. Development of the large Bijori lake body implies generation of accommodation space exceeding the rate of sediment supplied and thus represents locus of high tectonic subsidence. Transition of fluvial sediments with red mudstone and calcareous soil profile in the lower part of the succession to carbonaceous shale and coal-bearing lacustrine sediments in the upper part, denote a change from a warm semi-arid climate with seasonal rainfall to a more humid one.     

The Indus-Tsangpo suture zone in Ladakh, northwest Himalaya: Further palaeomagnetic data and implications

A total of 81 samples (244 specimens) from Upper Cretaceous Indus Molasse and Middle to Upper Cretaceous Dras Flyschoids of the Indus-Tsangpo suture zone in Ladakh (northwest Himalaya) has been studied by thermal demagnetization methods.Both formations showed a characteristic magnetization component indicative for equatorial to low northern palaeolatitudes of acquisition. Similar palaeolatitudes have been obtained before from secondary magnetization components of Early Tertiary age in the Ladakh Intrusives and in the Tibetan Sedimentary Series of central Nepal. The present characteristic components are interpreted likewise as secondary magnetizations which stabilized between 50 and 60 m.y. ago, during Greater India's collision with Asia's southern margin.The Dras Flyschoids show another magnetic component which, in case of primary origin, indicates acquisition at a low southern palaeolatitude. If correct, this interpretation supports recent suggestions for Late Cretaceous obduction of an island arc on Greater India's northern margin.     

Site selection for hazardous wastes: A case study from the GAP area, Turkey

The increase in the popularity of using environmental design criteria in town and country planning has brought about the need to fully identify the principles to determine the best location of hazardous wastes to be landfilled. This environmental management issue has received considerable attention because of its applications in urban and rural infrastructure planning, industrial development planning as well as health, housing, transportation and agricultural schemes. This paper explains a method to determine how to locate suitable sites for hazardous waste landfilling area by using the site screening study. It demonstrates how the criteria such as geology, topography, land use, climate, earthquake and other related factors can be introduced into the overlayer technique to determine the suitable site selection in a region. The research was undertaken in the Southeastern Anatolia Project (known as GAP in Turkey) region where identifying the land resources is crucial for agricultural and water management purposes. The paper also explains the validity of the method employed on the site selection process for hazardous wastes. The introduced method may enable more accurate design procedure for planning in environmental management in future.     

Ordovician metagranitoid from the Anatolide‐Tauride Block,northwest Turkey: geodynamic implications

We report a Middle Ordovician metagranitoid from the northern margin of the Anatolide‐Tauride Block, the basement of which is generally characterized by voluminous Latest Proterozoic to Early Cambrian granitoids. The Ordovician metagranitoid forms an ～400‐m‐thick body in the marbles and micaschists of the Tav?anl? Zone. The whole sequence was metamorphosed in the blueschist facies during the Late Cretaceous (c. 80 Ma). Zircons from the metagranitoid give a Middle Ordovician Pb‐Pb evaporation age of 467.0 ± 4.5 Ma interpreted as the age of crystallization of the parent granitic magma. The micaschists underlying the metagranitoid yield Cambro‐Ordovician (530–450 Ma) and Carboniferous (c. 310 Ma) detrital zircon ages indicating that the granitoid is a pre‐ or syn‐metamorphic tectonic slice. The Ordovician metagranitoid represents a remnant of the crystalline basement of the Anatolide‐Tauride Block and provides evidence for Ordovician magmatism at the northern margin of Gondwana. Prismatic Carboniferous detrital zircons in the micaschists indicate that during the Triassic, the northern margin of the Anatolide‐Tauride Block was close to Variscan terranes.     

Copper isotopes trace the evolution of skarn ores: A case study from the Hongshan-Hongniu Cu deposit,southwest China

Transition metal isotopes are sensitive geochemical tracers of ore genesis. Here we present MC-ICP-MS analytical data of Cu isotope compositions from the Hongshan-Hongniu Cu deposit in Yunnan province. The δ⁶⁵Cu values (δ⁶⁵Cu = [(⁶⁵Cu/⁶³Cu)_sample/(⁶⁵Cu/⁶³Cu)_NIST976 − 1] × 1000) of seven whole-rock quartz monzonite porphyries and twenty-two chalcopyrite samples from the skarn ore-bodies display relatively narrow ranges from −0.15‰ to 0.38‰ and from −0.02‰ to 0.77‰, respectively. The overlap of δ⁶⁵Cu values indicates a genetic relationship between the quartz monzonite porphyry and skarn ore-bodies. We also evaluate the spatial and temporal variations of Cu isotope compositions in the skarn ore-bodies by comparison with some well-documented porphyry deposits in the world. The quartz monzonite porphyry shows compositional zoning with the inner domain enriched in heavy Cu isotope and the skarn related to the porphyry depleted in heavy Cu isotope. The chalcopyrites that formed during the late stage of mineralization tend to be enriched in heavy Cu isotope, and this feature is analogous to porphyry deposits. The δ⁶⁵Cu values of the quartz monzonite porphyry show typical features of hypogene mineralization, suggesting a potential scope for deep exploration and development in this deposit.     

Neotectonic deformation in the transition zone between the Dead Sea Transform and the East Anatolian Fault Zone, Southern Turkey: a palaeomagnetic study of the Karasu Rift Volcanism

In southern Turkey ongoing differential impingement of Arabia into the weak Anatolian collisional collage resulting from subduction of the Neotethyan Ocean has produced one of the most complex crustal interactions along the Alpine–Himalayan Orogen. Several major transforms with disputed motions, including the northward extension of the Dead Sea Fault Zone (DSFZ), meet in this region. To evaluate neotectonic motion on the Amanos and East Hatay fault zones considered to be northward extensions of the DSFZ, the palaeomagnetism of volcanic fields in the Karasu Rift between these faults has been studied. Remanence carriers are low-Ti magnetites and all except 5 of 51 basalt lavas have normal polarity. Morphological, polarity and K–Ar evidence show that rift formation occurred largely during the Brunhes chron with volcanism concentrated at 0.66–0.35 Ma and a subsidiary episode at 0.25–0.05. Forty-four units of normal polarity yield a mean of D/I=8.8°/54.7° with inclination identical to the present-day field and declination rotated clockwise by 8.8±4.0°. Within the 15-km-wide Hassa sector of the Karasu Rift, the volcanic activity is concentrated between the Amanos and East Hatay faults, both with left lateral motions, which have rotated blocks bounded by NW–SE cross faults in a clockwise sense as the Arabian Block has moved northwestwards. An average lava age of 0.5 Ma yields a minimum cumulative slip rate on the system bounding faults of 0.46 cm/year according with the rate deduced from the Africa–Arabia Euler vector and reduced rates of slip on the southern extension of the DSFZ during Plio-Quaternary times. Estimates deduced from offsets of dated lavas flows and morphological features on the Amanos Fault Zone [Tectonophysics 344 (2002) 207] are lower (0.09–0.18 cm/year) probably because they are limited to surface fault breaks and do not embrace the seismogenic crust.Results of this study suggest that most strike slip on the DSFZ is taken up by the Amanos–East Hatay–Afrin fault array in southern Turkey. Comparable estimates of Quaternary slip rate are identified on other faults meeting at an unstable FFF junction (DSFZ, East Anatolian Fault Zone, Karatas Fault Zone). A deceleration in slip rate across the DSFZ and its northward continuation during Plio-Quaternary times correlates with reorganization of the tectonic regime during the last 1–3 Ma including tectonic escape within Anatolia, establishment of the North and East Anatolian Fault Zones bounding the Anatolian collage in mid–late Pliocene times, a contemporaneous transition from transpression to transtension and concentration of all basaltic magmatism in this region within the last 1 Ma.     

Geotechnical evaluation of Turkish clay deposits: a case study in Northern Turkey

Clay deposits in Oltu-Narman basins (Erzurum, northern Turkey) have been studied to determine their engineering properties and to evaluate their uses for geotechnical applications. These deposits are concentrated in two different stratigraphic horizons namely the Late Oligocene and the Early Miocene sequences. Clay-rich fine-grained sedimentary units are deposited in shallow marine and lagoonar mixed environments. Their clay minerals originated by the alteration of Eocene calc-alkaline island-arc volcanics, preferably from pyroclastics (trachite and andesite flow), which form the basement for the Oltu depression. Smectite group clay minerals are found abundant in clay deposits. The experimental results show that the clay soils have high plasticity behaviors and low hydraulic conductivity properties. The optimum water content, the free swell, and the swelling pressure of clay samples decreased and the maximum dry unit weight of clay samples increased under high temperature. Consequently, it is concluded that the expanding of clay soils is an important soil problem that cannot be avoided in the significant parts of Oltu city and its villages. However, the soils of clay-rich layers in the outcrops-section of clay deposits can be successfully used to build compacted clay liners for landfill systems and to construct vertical and horizontal barriers for protection of ground water and for preventing soil pollution in geotechnical applications.     

Geochemistry and geochronology of meta-igneous rocks from the Tokat Massif, north-central Turkey: implications for Tethyan reconstructions

Located in the eastern Pontides of the Sakarya Zone in north-central Turkey, the Tokat Massif records the closure of both the Paleo-Tethyan (Karakaya Complex) and Neo-Tethyan ocean basins. Meta-igneous samples collected from the region were studied to determine their sources and ages. We find significant geochemical differences between metagabbros of the Karakaya and Neo-Tethyan units in terms of their trace elements: Neo-Tethyan rocks are consistent with generation in an island arc setting, whereas Karakaya assemblages were likely generated in an oceanic spreading-center environment. Karakaya metagabbros also contain glaucophane, consistent with subduction subsequent to formation. Small (2–50 μm) zircon and baddeleyite grains from four Karakaya metagabbros were dated in thin section using an ion microprobe. The results demonstrate the reliability of the method to directly constrain the tectonomagmatic history of these types of assemblages. The rocks yield Late Permian/Early Triassic ²³⁸U/²⁰⁶Pb crystallization ages of 258 ± 14 Ma (±1σ, zircon) and 254 ± 8 Ma (±1σ, baddeleyite) and an Early Cretaceous minimum metamorphic age of 137 ± 8 Ma (±1σ, zircon). Some zircon grains and baddeleyite grains with zircon overgrowths yield Early to Middle Jurassic ages. Here we present a model in which metamorphism and deformation in this region occurred during northward subduction and closure of a Paleo-Tethyan ocean basin and accretion of the Karakaya units to the Laurasian continental margin. This was followed by the onset of closure of the Neo-Tethys during the Campanian-Paleocene and accretion of island arc units to the Tokat region.     

Rock geochemistry of an iron ore field in the Divrigi region, Central Anatolia, Turkey. A new exploration model for iron ores in Turkey

One hundred and sixty rock samples of iron ore deposits and their host rocks from the Divrigi iron ore region were analysed for ten major and 31 trace elements, and 30 samples were analysed for rare earth elements. Statistical analyses divide rock types into different units (discriminant analyses) and several element associations (cluster and factor analyses). Individual rock types were also treated statistically. Different element associations and the geochemistry of the REE point to a genetic relationship between ore and host rocks and later hydrothermal overprints.The interpretation suggests iron ores are closely associated with mafic ultramafic rocks. This exploration model has been applied iron ore deposits in central Anatolia, Turkey. The results stimulated first air-magnetic and later ground-magnetic field surveys leading to discovery of new iron ore occurrences which are currently being evaluated for their economic potential.