Thermo-hydro-mechanical process and damage mechanism of a cold-region canal under coupled wetting–drying and freezing–thawing cycles

Acta Geotechnica - In cold regions, periodic wetting–drying and freezing–thawing (WDFT) actions lead to frequent and heavy canal damage, weakening the water-conveyance capacities of...     

Western Indian Ocean marine and terrestrial records of climate variability: a review and new concepts on land–ocean interactions since AD 1660

We examine the relationship between three tropical and two subtropical western Indian Ocean coral oxygen isotope time series to surface air temperatures (SAT) and rainfall over India, tropical East Africa and southeast Africa. We review established relationships, provide new concepts with regard to distinct rainfall seasons, and mean annual temperatures. Tropical corals are coherent with SAT over western India and East Africa at interannual and multidecadal periodicities. The subtropical corals correlate with Southeast African SAT at periodicities of 16–30 years. The relationship between the coral records and land rainfall is more complex. Running correlations suggest varying strength of interannual teleconnections between the tropical coral oxygen isotope records and rainfall over equatorial East Africa. The relationship with rainfall over India changed in the 1970s. The subtropical oxygen isotope records are coherent with South African rainfall at interdecadal periodicities. Paleoclimatological reconstructions of land rainfall and SAT reveal that the inferred relationships generally hold during the last 350 years. Thus, the Indian Ocean corals prove invaluable for investigating land–ocean interactions during past centuries. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Experimental investigations on the elastic parameters and uniaxial compressive strength of slate under freeze–thaw cycles

ABSTRACT

In this study, uniaxial compression experiments with seven different bedding angles and six numbers of freeze–thaw cycles were conducted to investigate the influences of freeze–thaw cycles on the elastic parameters and the uniaxial compressive strength of slate. The laws of the elastic parameters, uniaxial compressive strength and failure characteristics were analysed, and a new uniaxial compressive strength prediction model that considers the bedding angle and the number of freeze–thaw cycles as control variables was established and verified using the experimental data. The results showed that the uniaxial compressive strength, elastic modulus and shear modulus decreased exponentially with an increasing number of freeze–thaw cycles. However, the Poisson’s ratio increased linearly with an increasing number of freeze–thaw cycles. The uniaxial compressive strength initially decreased and then increased with increasing bedding angle. There are three forms of failure occurred during the tests: when the bedding angle was 0°≤β ≤ 26.6°, the splitting failure and shear failure occurred at the same time; when the bedding angle was 26.6°≤β ≤ 83.0°, sliding failure occurred along the bedding plane; and when the bedding angle was 83.0°≤β ≤ 90°, splitting failure occurred along the axial direction of sample.     

Impact of wildfire in Russia between 1998–2010 on ecosystems and the global carbon budget

Verified estimates of wildfire area and related carbon emissions in territories of Russia are reported for the period of 1998–2010. It is shown that the average burnt area is estimated to be at 8.23 million hectares per year (uncertainty ±9.0%, confidence interval 0.9), and carbon emissions—121 Tg C yr⁻¹ (±23%), with a significant interannual variability of these indicators. A quantitative characteristic of fire emissions by species is reported. Forests are a source of three quarters of all carbon emissions caused by wildfires. A significant acceleration of fire regimes is expected during the 21st century as a result of climate change in the country.     

Dynamic cycles,ice streams and their impact on the extent,chronology and deglaciation of the British–Irish ice sheet

We present results from a suite of forward transient numerical modelling experiments of the British and Irish Ice Sheet (BIIS), consisting of Scottish, Welsh and Irish accumulation centres, spanning the last Glacial period from 38 to 10 ka BP. The 3D thermomechanical model employed uses higher-order physics to solve longitudinal (membrane) stresses and to reproduce grounding-line dynamics. Surface mass balance is derived using a distributed degree-day calculation based on a reference climatology from mean (1961–1990) precipitation and temperature patterns. The model is perturbed from this reference state by a scaled NGRIP oxygen isotope curve and the SPECMAP sea-level reconstruction. Isostatic response to ice loading is computed using an elastic lithosphere/relaxed asthenosphere scheme. A suite of 350 simulations were designed to explore the parameter space of model uncertainties and sensitivities, to yield a subset of experiments that showed close correspondence to offshore and onshore ice-directional indicators, broad BIIS chronology, and the relative sea-level record. Three of these simulations are described in further detail and indicate that the separate ice centres of the modelled BIIS complex are dynamically interdependent during the build up to maximum conditions, but remain largely independent throughout much of the simulation. The modelled BIIS is extremely dynamic, drained mainly by a number of transient but recurrent ice streams which dynamically switch and fluctuate in extent and intensity on a centennial time-scale. A series of binge/purge, advance/retreat, cycles are identified which correspond to alternating periods of relatively cold-based ice, (associated with a high aspect ratio and net growth), and wet-based ice with a lower aspect ratio, characterised by streaming. The timing and dynamics of these events are determined through a combination of basal thermomechanical switching spatially propagated and amplified through longitudinal coupling, but are modulated and phase-lagged to the oscillations within the NGRIP record of climate forcing. Phases of predominant streaming activity coincide with periods of maximum ice extent and are triggered by abrupt transitions from a cold to relatively warm climate, resulting in major iceberg/melt discharge events into the North Sea and Atlantic Ocean. The broad chronology of the modelled BIIS indicates a maximum extent at ～20 ka, with fast-flowing ice across its western and northern sectors that extended to the continental shelf edge. Fast-flowing streams also dominate the Irish Sea and North Sea Basin sectors and impinge onto SW England and East Anglia. From ～19 ka BP deglaciation is achieved in less than 2000 years, discharging the freshwater equivalent of ～2 m global sea-level rise. A much reduced ice sheet centred on Scotland undergoes subsequent retrenchment and a series of advance/retreat cycles into the North Sea Basin from 17 ka onwards, culminating in a sustained Younger Dryas event from 13 to 11.5 ka BP. Modelled ice cover is persistent across the Western and Central Highlands until the last remnant glaciers disappear around 10.5 ka BP.     

Effects of Mg and Si ions on the symmetry of δ-AlOOH

We conducted powder neutron diffraction for δ-AlOOH samples with and without Mg and Si ions under ambient conditions in order to investigate the long-standing problem of the symmetry of this phase. The observed reflection conditions clearly show that the space group of pure δ-AlOOH is P2₁ nm with ordered hydrogen bonds, whereas that of δ-(Al_0.86Mg_0.07Si_0.07)OOH is Pnnm or Pnn2 with disordered hydrogen bonds. It is more likely that the space group of δ-(Al_0.86Mg_0.07Si_0.07)OOH is Pnnm, because cation or hydrogen ordering that breaks the mirror plane perpendicular to c axis in the Pnnm structure would not occur. The previously reported inconsistency for the space group of this phase was caused by the substitution of Mg and Si ions to Al site, i.e., the disordered cations with different valences may fluctuate hydrogen positions, and the disordered hydrogen causes the symmetry change.     

Effect of freeze–thaw cycles on strength and ductility and microstructure of cement-treated silt with polypropylene fiber

Acta Geotechnica - In this paper, the strength, ductility and microstructure behavior of cement-treated silt with polypropylene fiber was studied by a host of experimental studies. The influence of...     

Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

Sedimentation and continental slope processes in the vicinity of an ocean waste‐disposal site,southeastern Tasmania

Digital echo sounding, SeaBeam swath bathymetry data and sediment cores were collected on the continental slope (1500–3700 m water depth) off southeastern Tasmania in order to study sedimentary processes in the vicinity of an ocean disposal site. The new bathymetry data show that the shallower limits of the disposal site are positioned on the seaward edge of a gently dipping (3°) mid‐slope shoulder, between 1200 and 2100 m water depth. The slope below the disposal site is relatively steep (6.5°) and is cut by submarine canyons which lead into the adjacent East Tasman Saddle. The SeaBeam bathymetry data show a small submarine canyon traversing the slope in 2400 m water depth directly downslope from the disposal site, with local slopes of up to 22°. The canyon feeds into a perched basin at 2450 m, which could be acting as a local sediment trap. Short (<90 cm) gravity cores indicate that indurated erosional surfaces characterise the slope environment. The cores contain Upper Cretaceous (upper Campanian) sandstones and siltstones, which in places crop out on the sea floor where they are locally draped by a thin (0–30 cm), modern layer of hemipelagic calcareous ooze. Five cores collected from the vicinity of the disposal site had lead and zinc concentrations in the surface 1 cm of 10.3 ± 5.0 and 39.5 ± 19.6 mg/kg, respectively, significantly greater than the background values (2.9 ± 1.4 for lead and 21.2 ± 5.4 for zinc) which characterise the underlying unit that is composed of the same hemipelagic calcareous ooze. Lead and zinc are constituents of the dumped material, jarosite, which, after mixing with slope sediments, can be used as sediment tracers. One core contains a fining‐upwards bed which is also elevated in lead and zinc. This is interpreted as evidence for dispersal of the jarosite from the disposal site downslope to depths >3000 m via turbidity flows sometime during the past 24 years. Current meter data collected from 30 m above the sea floor over one year at the disposal site show that bottom currents attain speeds of up to 0.46 m/s. The current events are attributed to eddies shed by the East Australia Current. The measured bottom currents are capable of transporting fine‐grained hemipelagic muds and could provide a trigger mechanism for turbidity flows.     

Distal “impact” layers and global acidification of ocean water at the Cretaceous-Paleogene boundary (KPB)

The KPB sections at Højerup in Denmark, Agost and Caravaca in Spain and El Kef in Tunisia and (elsewhere in the world) consists of a very thin reddish biogenic calcite-poor smectite-rich “impact” layer overlain by a thicker smectite-rich marl. The massive amount of impact-generated atmospheric CO₂ at KPB would have accumulated globally in the ocean surface, leading to acidification and CaCO₃ undersaturation. These chemical changes would have induced a low biocalcification of calcareous plankton and a high dissolution of their shells. The biocalcification/dissolution crises may have played a significant role for the low abundance of biogenic calcite in the “impact” layer of the marine boundary clays at Højerup, Agost, Caravaca and El Kef (and elsewhere in the world). Experimental data and observations indicate that the deposition of the “impact” layer probably lasted only a few decades at most.     

Timing and pace of ice-sheet withdrawal across the marine–terrestrial transition west of Ireland during the last glaciation

Understanding the pace and drivers of marine-based ice-sheet retreat relies upon the integration of numerical ice-sheet models with observations from contemporary polar ice sheets and well-constrained palaeo-glaciological reconstructions. This paper provides a reconstruction of the retreat of the last British–Irish Ice Sheet (BIIS) from the Atlantic shelf west of Ireland during and following the Last Glacial Maximum (LGM). It uses marine-geophysical data and sediment cores dated by radiocarbon, combined with terrestrial cosmogenic nuclide and optically stimulated luminescence dating of onshore ice-marginal landforms, to reconstruct the timing and rate of ice-sheet retreat from the continental shelf and across the adjoining coastline of Ireland, thus including the switch from a marine- to a terrestrially-based ice-sheet margin. Seafloor bathymetric data in the form of moraines and grounding-zone wedges on the continental shelf record an extensive ice sheet west of Ireland during the LGM which advanced to the outer shelf. This interpretation is supported by the presence of dated subglacial tills and overridden glacimarine sediments from across the Porcupine Bank, a westwards extension of the Irish continental shelf. The ice sheet was grounded on the outer shelf at ~26.8 ka cal bp with initial retreat underway by 25.9 ka cal bp. Retreat was not a continuous process but was punctuated by marginal oscillations until ~24.3 ka cal bp. The ice sheet thereafter retreated to the mid-shelf where it formed a large grounding-zone complex at ~23.7 ka cal bp. This retreat occurred in a glacimarine environment. The Aran Islands on the inner continental shelf were ice-free by ~19.5 ka bp and the ice sheet had become largely terrestrially based by 17.3 ka bp. This suggests that the Aran Islands acted to stabilize and slow overall ice-sheet retreat once the BIIS margin had reached the inner shelf. Our results constrain the timing of initial retreat of the BIIS from the outer shelf west of Ireland to the period of minimum global eustatic sea level. Initial retreat was driven, at least in part, by glacio-isostatically induced, high relative sea level. Net rates of ice-sheet retreat across the shelf were slow (62–19 m a⁻¹) and reduced (8 m a⁻¹) as the ice sheet vacated the inner shelf and moved onshore. A picture therefore emerges of an extensive BIIS on the Atlantic shelf west of Ireland, in which early, oscillatory retreat was followed by slow episodic retreat which decelerated further as the ice margin became terrestrially based. More broadly, this demonstrates the importance of localized controls, in particular bed topography, on modulating the retreat of marine-based sectors of ice sheets.     

Some new data on the genesis of the Linghou Cu–Pb–Zn polymetallic deposit—Based on the study of fluid inclusions and C–H–O–S–Pb isotopes

The Linghou deposit, located near Hangzhou City of Zhejiang Province, eastern China, is a medium-sized polymetallic sulfide deposit associated with granitic intrusion. This deposit is structurally and lithologically controlled and commonly characterized by ore veins or irregular ore lenses. In this deposit, two mineralization events were identified, of which the former produced the Cu–Au–Ag orebodies, while the latter formed Pb–Zn–Cu orebodies. Silicification and calc-silicate (skarn type), phyllic, and carbonate alternation are four principal types of hydrothermal alteration. The early Cu–Au–Ag and late Pb–Zn–Cu mineralizations are characterized by quartz ± sericite + pyrite + chalcopyrite + bornite ± Au–Ag minerals ± magnetite ± molybdenite and calcite + dolomite + sphalerite + pyrite + chalcopyrite + galena, respectively. Calcite clusters and calcite ± quartz vein are formed during the late hydrothermal stage.The NaCl–H₂O–CO₂ system fluid, coexisting with NaCl–H₂O system fluid and showing the similar homogenization temperatures (385 °C and 356 °C, respectively) and different salinities (16.89–21.68 wt.% NaCl eqv. and 7.70–15.53 wt.% NaCl eqv.), suggests that fluid immiscibility occurred during the Cu–Au–Ag mineralization stage and might have given rise to the ore-metal precipitation. The ore-forming fluid of the Pb–Zn–Cu mineralization mainly belongs to the NaCl–H₂O–CO₂ system of high temperature (~ 401 °C) and mid-high salinity (10.79 wt.% NaCl eqv.).Fluids trapped in the quartz-chalcopyrite vein, Cu–Au–Ag ores, Pb–Zn–Cu ores and calcite clusters yielded δ¹⁸O_H2O and δD values varying from 5.54‰ to 13.11‰ and from − 71.8‰ to − 105.1‰, respectively, indicating that magmatic fluids may have played an important role in two mineralization events. The δ¹³C_PDB values of the calcite change from − 2.78‰ to − 4.63‰, indicating that the CO₃^2 − or CO₂ in the ore-forming fluid of the Pb–Zn–Cu mineralization was mainly sourced from the magmatic system, although dissolution of minor marine carbonate may have also occurred during the ore-forming processes. The sulfide minerals have homogeneous lead isotopic compositions with ²⁰⁶Pb/²⁰⁴Pb ranging from 17.958 to 18.587, ²⁰⁷Pb/²⁰⁴Pb ranging from 15.549 to 15.701, and ²⁰⁸Pb/²⁰⁴Pb ranging from 37.976 to 39.052, indicating that metallic elements of the Linghou deposit came from a mixed source involving mantle and crustal components.Based on geological evidence, fluid inclusions, and H–O–C–S–Pb isotopic data, the Linghou polymetallic deposit is interpreted as a high-temperature, skarn-carbonate replacement type. Two types of mineralization are both related to the magmatic–hydrothermal system, with the Cu–Au–Ag mineralization having a close relationship with granodiorite.     

Characterization of C‐isotope variability in the Delhi Supergroup,northwestern India and the Mesoproterozoic ocean

Marine carbonate rocks of the Delhi Supergroup of northwestern India show little deviation in whole‐rock δ ¹³Ccarb and δ ¹⁸Ocarb values, which generally are around 0 and –10‰ respectively. These narrow ranges and almost constant δ ¹³Ccarb values persist despite close sampling through long sections. The data suggest that the global rate of organic carbon burial was probably constant during deposition of the Delhi Supergroup. The nearly invariant C isotopic profile of the Delhi Supergroup is similar to C isotopic profiles of Mesoproterozoic carbonates older than 1.3 Ga, as reported from different parts of world. Carbonate units on the western margin of the Delhi Supergroup however, have on average moderately positive δ ¹³C values (from 2 to +4.96‰). These high δ ¹³C carbonates may represent the Mesoproterozoic–Neoproterozoic transition (from ～1.25 to ～0.85 Ga), a period characterized by high positive δ ¹³C values globally.     

Pressure responses of portlandite and H–D isotope effects on pressure-induced phase transitions

The pressure responses of portlandite and the isotope effect on the phase transition were investigated at room temperature from single-crystal Raman and IR spectra and from powder X-ray diffraction using diamond anvil cells under quasi-hydrostatic conditions in a helium pressure-transmitting medium. Phase transformation and subsequent peak broadening (partial amorphization) observed from the Raman and IR spectra of Ca(OH)₂ occurred at lower pressures than those of Ca(OD)₂. In contrast, no isotope effect was found on the volume and axial compressions observed from powder X-ray diffraction patterns. X-ray diffraction lines attributable to the high-pressure phase remained up to 28.5 GPa, suggesting no total amorphization in a helium pressure medium within the examined pressure region. These results suggest that the H–D isotope effect is engendered in the local environment surrounding H(D) atoms. Moreover, the ratio of sample-to-methanol–ethanol pressure medium (i.e., packing density) in the sample chamber had a significant effect on the increase in the half widths of the diffraction lines, even at pressures below the hydrostatic limit of the pressure medium.     

Phase relations in the carbon-saturated C–Mg–Fe–Si–O system and C and Si solubility in liquid Fe at high pressure and temperature: implications for planetary interiors

The phase and melting relations of the C-saturated C–Mg–Fe–Si–O system were investigated at high pressure and temperature to understand the role of carbon in the structure of the Earth, terrestrial planets, and carbon-enriched extraterrestrial planets. The phase relations were studied using two types of experiments at 4 GPa: analyses of recovered samples and in situ X-ray diffractions. Our experiments revealed that the composition of metallic iron melts changes from a C-rich composition with up to about 5 wt.% C under oxidizing conditions (ΔIW = ?1.7 to ?1.2, where ΔIW is the deviation of the oxygen fugacity (fO₂) from an iron-wüstite (IW) buffer) to a C-depleted composition with 21 wt.% Si under reducing conditions (ΔIW < ?3.3) at 4 GPa and 1,873 K. SiC grains also coexisted with the Fe–Si melt under the most reducing conditions. The solubility of C in liquid Fe increased with increasing fO₂, whereas the solubility of Si decreased with increasing fO₂. The carbon-bearing phases were graphite, Fe₃C, SiC, and Fe alloy melt (Fe–C or Fe–Si–C melts) under the redox conditions applied at 4 GPa, but carbonate was not observed under our experimental conditions. The phase relations observed in this study can be applicable to the Earth and other planets. In hypothetical reducing carbon planets (ΔIW < ?6.2), graphite/diamond and/or SiC exist in the mantle, whereas the core would be an Fe–Si alloy containing very small amount of C even in the carbon-enriched planets. The mutually exclusive nature of C and Si may be important also for considering the light elements of the Earth’s core.     

Analysis of the pressure projection stabilization method for the Darcy and coupled Darcy–Stokes flows

In this paper, we systematically analyze the pressure projection stabilization method for the Darcy and coupled Darcy–Stokes flow problems in multiple dimensions. Stability results for this stabilization method are established. For the Darcy flow, optimal error estimates in the divergence norm for velocity and suboptimal error estimates in the $L^{2}$ -norm for pressure are obtained, and a superconvergence result for the pressure is derived; a local postprocessing scheme is constructed to generate optimal error estimates in the L ²-norm for pressure. For the coupled Darcy–Stokes flow, error estimates of optimal order are obtained in terms of the energy norm of velocity and pressure. Numerical results are presented to check the theory developed.     

Impact of wetting–drying cycles on the hydraulic conductivity of liners made of lime-stabilized sand–bentonite mixtures for sanitary landfills

In this study, an investigation was performed to determine if lime-stabilized sand–bentonite mixtures are appropriate for the construction of sanitary landfills liners. For this aim, the hydraulic conductivity tests were conducted in the laboratory on sand–bentonite mixtures and lime-stabilized sand–bentonite mixtures to evaluate the effect of wetting–drying cycles. The hydraulic conductivity tests were performed to see if their hydraulic conductivities are affected by wetting–drying cycles. First series of specimens have been prepared as a mixture of sand and bentonite only. In the first series of specimens, sand was mixed with bentonite in proportions of 20, 30, 40, and 50 %. In the second series of the specimens, lime in proportions of 1, 2 and 3 % by weight was added to the mixtures of sand–bentonite in proportions of 20, 30, 40, and 50 %. From the results of the tests, it was observed that while optimum water content increased, maximum dry density decreased with addition of lime to the sand–bentonite mixtures. Generally, the hydraulic conductivity increased with the addition of lime to the mixtures but at low percentages of lime (1–2 %), however, slight decreases in k were recorded. It was also observed that the wetting–drying cycles on the permeability test indicate cure effect on specimens with addition of lime which resulted in decreased the hydraulic conductivity.     

Zircon U–Pb geochronology of the Mesozoic metamorphic rocks and granitoids in the coastal tectonic zone of SE China: Constraints on the timing of Late Mesozoic orogeny

The coastal Changle-Nan’ao tectonic zone of SE China contains important geological records of the Late Mesozoic orogeny and post-orogenic extension in this part of the Asian continent. The folded and metamorphosed T₃–J₁ sedimentary rocks are unconformably overlain by Early Cretaceous volcanic rocks or occur as amphibolite facies enclaves in late Jurassic to early Cretaceous gneissic granites. Moreover, all the metamorphic and/or deformed rocks are intruded by Cretaceous fine-grained granitic plutons or dykes. In order to understand the orogenic development, we undertook a comprehensive zircon U–Pb geochronology on a variety of rock types, including paragneiss, migmatitic gneiss, gneissic granite, leucogranite, and fine-grained granitoids. Zircon U–Pb dating on gneissic granites, migmatitic gneisses, and leucogranite dyke yielded a similar age range of 147–135 Ma. Meanwhile, protoliths of some gneissic granites and migmatitic gneisses are found to be late Jurassic magmatic rocks (ca. 165–150 Ma). The little deformed and unmetamorphosed Cretaceous plutons or dykes were dated at 132–117 Ma. These new age data indicate that the orogeny lasted from late Jurassic (ca. 165 Ma) to early Cretaceous (ca. 135 Ma). The tectonic transition from the syn-kinematic magmatism and migmatization (147–136 Ma) to the post-kinematic plutonism (132–117 Ma) occurred at 136–132 Ma.