Continuous chemical monitoring of volcanic gas in Izu-Oshima volcano, Japan

A new continuous monitoring system has been developed for the measurement of volcanic gas from the steam well located 3 km north from the summit of Izu-Oshima volcano, Japan. After removing the water vapor using three sequential dehydration methods, CO₂ and SO₂ contents are measured using IR sensors, and O₂ and H₂ using a zirconia sensor and a semiconductor sensor, respectively. This system has been in operation without any significant trouble for 3 years.The dehydrated volcanic gas from the well consists of a mixture of CO₂, O₂ and N₂. A decreasing trend of the CO₂ content was observed from 1995 to 1998 together with a decrease of volcanic activity. Seasonal changes have also been observed in CO₂ and O₂ contents, CO₂ being higher and O₂ lower in summer, which suggests larger contribution of magmatic components in summer. While changes in short-term variation in CO₂ and O₂ are influenced by atmospheric pressure changes; the CO₂ content correlates inversely with atmospheric pressure unlike O₂ with some hours delay. In contrast, the H₂ content increased intermittently up to 1200 ppm one to several hours after a sudden drop in the atmospheric pressure and without any apparent correlation with seasonal changes.This system allows us to study temporal variation in chemical composition of volcanic gas during quiescent periods of volcanic activity of Izu-Oshima volcano, and might help us detect anomalous changes before future eruptive events.     

A 3D magnetic structure of Izu-Oshima Volcano and their changes after the eruption in 1986 as estimated from repeated airborne magnetic surveys

A 3D magnetic inversion method using a conjugate gradient method (CG method) was developed for constructing 3D magnetization models of a volcanic edifice and applied to aeromagnetic anomalies of Izu-Oshima Volcano surveyed in 1986 and in 1997. The calculated results of the 1986 data show that the volcanic edifice of Izu-Oshima Volcano has a mean magnetization intensity ranging from 10.4 to 12.1 A/m. The derived 3D magnetic structure shows low magnetization zones beneath the west-northwest of the western caldera rim, beneath the west-southwest of Mt. Mihara and beneath Mt. Shiroishi. These features may be related with demagnetizations, reflecting a high thermal state due to magma activities in the 1986 eruption. The comparison between 3D magnetization models in 1986 and in 1997, indicates meaningful changes beneath the C-craters erupted in 1986, suggesting a recovery process of demagnetizations and a considerable decrease of magnetization intensities in the foot of Mt. Futago, indicative of demagnetizations. A derived magnetization model including Izu-Oshima Volcano and its surrounding sea areas clarifies the submerged volcanic edifices around Izu-Oshima Island, and suggests that the old volcanic edifices of Fudeshima, Gyojyanoiwaya, and Okata Volcanoes have been affected by eastward migrations due to massive intrusions of a dike-like structure inferred at the base of Izu-Oshima Volcano.     

Formation of clastogenic lava flows during fissure eruption and scoria cone collapse: the 1986 eruption of Izu-Oshima Volcano, eastern Japan

The 1986 eruption of B fissure at Izu-Oshima Volcano, Japan, produced, among other products, one andesite and two basaltic andesite lava flows. Locally the three flows resemble vent-effused holocrystalline blocky or aa lava; however, remnant clast outlines can be identified at most localities, indicating that the flows were spatter fed or clastogenic. The basaltic andesite flows are interpreted to have formed by two main processes: (a) reconstitution of fountain-generated spatter around vent areas by syn-depositional agglutination and coalescence, followed by extensional non-particulate flow, and (b) syn-eruptive collapse of a rapidly built spatter and scoria cone by rotational slip and extensional sliding. These processes produced two morphologically distinct lobes in both flows by: (a) earlier non-particulate flow of agglutinate and coalesced spatter, which formed a thin lobe of rubbly aa lava (ca. 5 m thick) with characteristic open extension cracks revealing a homogeneous, holocrystalline interior, and (b) later scoria-cone collapse, which created a larger lobe of irregular thickness (<20 m) made of large detached blocks of scoria cone interpreted to have been rafted along on a flow of coalesced spatter. The source regions of these lava flows are characterized by horseshoe-shaped scarps (<30 m high), with meso-blocks (ca. 30 m in diameter) of bedded scoria at the base. One lava flow has a secondary lateral collapse zone with lower (ca. 7 m) scarps. Backward-tilted meso-blocks are interpreted to be the product of rotational slip, and forward-tilted blocks the result of simple toppling. Squeeze-ups of coalesced spatter along the leading edge of the meso-blocks indicate that coalescence occurred in the basal part of the scoria cone. This low-viscosity, coalesced spatter acted as a lubricating layer along which basal failure of the scoria cone occurred. Rotational sliding gave way to extensional translational sliding as the slide mass spread out onto the present caldera floor. Squeeze-ups concentrated at the distal margin indicate that the extensional regime changed to one of compression, probably as a result of cooling of the flow front. Sliding material piled up behind the slowing flow front, and coalesced spatter was squeezed up from the interior of the flow through fractures and between rafted blocks. The andesite flow, although morphologically similar to the other two flows, has a slightly different chemical composition which corresponds to the earliest stage of the eruption. It is a much smaller lava flow emitted from the base of the scoria cone 2 days after the eruption had ceased. This lava is interpreted to have been formed by post-depositional coalescence of spatter under the influence of the in-situ cooling rate and load pressure of the deposit. Extrusion occurred through the lower part of the scoria cone, and subsequent non-particulate flow of coalesced material produced a blocky and aa lava flow. The mechanisms of formation of the lava flows described may be more common during explosive eruptions of mafic magma than previously envisaged. Received: 30 May 1997 / Accepted: 19 May 1998     

Swelling of a lava plug associated with a Vulcanian eruption at Sakurajima Volcano,Japan, as revealed by infrasound record: case study of the eruption on January 2, 2007

In order to clarify the time relation of the expansion of a gas pocket and failure of its overlying plug of lava during Vulcanian eruptions, infrasound records and video images of the Vulcanian eruption that occurred at Sakurajima volcano on January 2, 2007 were analyzed with respect to their origin times. Weak (≤3 Pa) and slowly increasing air pressure preceded the impulsive compression phase by 0.25–0.32 s, and a longer-period rarefaction phase of infrasound waves was recognized at all microphone stations. The velocity of the compression phase was assumed to be supersonic (ca. 400 m/s) up to 850 m above the crater bottom from other recent explosions. On the other hand, the propagation velocity of the preceding weak signal was regarded to be similar to the air sound velocity because the lack of impulsiveness is unlikely to be related to the main compression phase. Therefore, the estimated origin time of the main compression phase was delayed by 0.5–0.7 s from the preceding phase. The origin time of the preceding phase coincided with the onset of the isotropic expansion process of the pressurized gas pocket, which was obtained by the waveform inversion of the explosion earthquake. In contrast, the origin time of the main impulsive phase coincided with the time when the expansion rate reached its peak. This observation suggests that the volumetric increase of the gas pocket caused swelling of the surface of the crater bottom and its subsequent failure. When the expansion velocity exceeded a threshold level, the main impulsive compression phase radiated with a high velocity by the sudden releases of the pressurized gases. The volumetric change at the source was estimated to be 280–560 m³ from the preceding phase of the infrasound. This volume change indicates that the vertical displacement of the swelling ground was on the order of 1.0 m, assuming the radius of the lava plug was ca. 10 m.     

Magnetic and electric field observations during the 2000 activity of Miyake-jima volcano, Central Japan

Magnetic and electric field variations associated with the 2000 eruption of Miyake-jima volcano are summarized. For about 1 week prior to the July 8 phreatic explosion, significant changes in the total intensity were observed at a few stations, which indicated uprising of a demagnetized area from a depth of 2 km towards the summit: this non-magnetic source can be regarded as a vacant space itself. Electric and magnetic field variations were observed simultaneously associated with the tilt-step event, which was the abrupt (∼50 s) inflation at a few km depth within the volcano followed by gradual recovery (∼several hours). The electric field is ascribed to the electrokinetic effect most probably due to forced injection of fluids from the source, while the magnetic field to the piezomagnetic effect due to increased pressure. Large magnetic variations amounting to a few tens of nT were observed at several stations since July 8, and they turned almost flat after the August 18 largest eruption. Magnetic changes are explained mostly by the vanishing of magnetic mass in the summit and additionally by the thermal demagnetization at a rather shallow depth. A large increase in the self-potential by 130 mV was also observed near the summit caldera associated with the August 18 eruption, which suggests that the hydrothermal circulation system sustained within the volcano for the past more than 10 years was destroyed by this eruption.     

腾冲火山地质研究述评

在综合分析前人有关腾冲火山研究成果的基础上，对该区火山活动的研究现状，火山活动特征，火山活动背景及火山活动与深部岩浆侵入活动的关系等进行了评述。认为腾冲火山群中存在全新世活火山，现今处于休眠状态，具有再次喷发的潜在危险性，因此，进一步深入研究腾冲火山在全新世活动的时间分布规律，对于在该区开展火山活动监测，减灾防灾等方面具有重要意义。     

Color measurements of volcanic ash deposits from three different styles of summit activity at Sakurajima volcano,Japan: Conduit processes recorded in color of volcanic ash

We measured quantitatively colors of volcanic ash deposits erupted from three different styles of summit activity (Strombolian activity, Vulcanian explosions and continuous ash venting activity) at Sakurajima volcano from 1974 to 1985. Colors of Strombolian ash samples have larger yellow components of their visible spectra (b^? values) than those of explosion and continuous venting ash samples. Colors of explosion ash samples show larger variation in both red and yellow components of their visible spectra (a^? and b^? values, respectively), while colors of continuous venting ash samples are in the narrow ranges within colors of explosion ash samples. Colors of components with lower densities than 3.1 g/cm³ (groundmass and phenocrystic plagioclase) obtained by magnetic and heavy liquid separation methods are similar to the unseparated bulk ash samples. This result suggests that the color variations of ash deposits are mainly originated from the particles composed of groundmass. The particles can be classified into three different types of particles with different vesicularity and crystallinity (vesicular particle [VP], dense particle with vesicles [DPV] and dense particle without vesicles [DP]). Analytical results of component proportions, chemical compositions of groundmass glasses, ferrous iron contents and surface ferric materials show that (1) VP has larger yellow components of the visible spectrum (b^? values) and high ferrous iron content, and is less crystallized than the DP and DPV, (2) DP has larger red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves ferric materials on the surfaces produced by oxidation process, and (3) DPV has smaller red and yellow components of its visible spectrum (a^? and b^? values, respectively) and involves less ferric materials on the ash surfaces. Color differences of ash deposits from three different activity styles can be explained by the different mixing ratios of VP, DPV and DP. During the Strombolian activity, the VP is a main component in the ash, which is formed from relatively less degassed and crystallized magma. In the Vulcanian explosion and continuous ash venting activity, the proportions of DPV and DP in ash are larger than that in the Strombolian activity. The highly crystallized DP may correspond to a vent cap, and DPV to a magma below the cap. The color measurements of ash deposits provide information on the pre-eruptive processes at the shallower levels of a conduit.     

A preliminary stable isotope study of volcanic ashes discharged by the 1979 eruption of Ontake Volcano,Nagano, Japan

Sulphur isotopic compositions of pyrite, anhydrite and native sulphur in volcanic ashes discharged by the 1979 eruption of Ontake volcano, Nagano, Japan were determined. The isotopic data indicate that sulphate in anhydrite and a part of native sulphur were produced by the disproportionation reaction of sulphite formed by dissolution of SO₂ in volcanic gases into water which filled a mud reservoir probably located just below the crater zone. Some part of H₂S in volcanic gases was fixed as pyrite and some was oxidised to form native sulphur. Hydrothermal alteration of country rocks to form pyrite, anhydrite and clay minerals had proceeded in the mud reservoir before eruption at temperatures ranging from 110° to 185°C which were estimated by oxygen isotopic fractionation between anhydrite and water.

     

Petrographic study of the Miocene Mizunami Group,Central Japan: Detection of unrecognized volcanic activity in the Setouchi Province

A petrographic study of sandstones from the Miocene Mizunami Group in Central Japan has been performed on core samples from a single borehole, in order to evaluate the provenance of the sedimentary rock. Evaluation of the provenance is based on bulk mineral, heavy mineral and plagioclase contents and on whole rock chemical compositions. The sandstones studied are divisible into three types; the first type is characterized by the occurrence of biotite and plagioclase ranging from albite to oligoclase, the second type is characterized by the dominance of amphibole and labradorite with pyroxene (clinopyroxene > orthopyroxene), and the third type is characterized by the dominance of pyroxene (orthopyroxene > clinopyroxene) and andesine with lesser labradorite, bytownite and anorthite. The first type is interpreted to be derived from the basement granite, whereas the others were derived mostly from volcanic ash, judging from their mineral compositions. The volcanic activity that supplied the volcanic ash to the Mizunami Basin occurred in two phases, distinguishable by variations in their mineralogical and geochemical compositions, an indication of change in character of the volcanic activity. This petrographic study of the sandstones in the Mizunami Group suggests that unrecognized volcanic activity occurred around the Mizunami Basin, even though potential provenance of the volcanic ash has not yet been identified.     

Sequence and eruptive style of the 1783 eruption of Asama Volcano, central Japan: a case study of an andesitic explosive eruption generating fountain-fed lava flow, pumice fall, scoria flow and forming a cone

The 3-month long eruption of Asama volcano in 1783 produced andesitic pumice falls, pyroclastic flows, lava flows, and constructed a cone. It is divided into six episodes on the basis of waxing and waning inferred from records made during the eruption. Episodes 1 to 4 were intermittent Vulcanian or Plinian eruptions, which generated several pumice fall deposits. The frequency and intensity of the eruption increased dramatically in episode 5, which started on 2 August, and culminated in a final phase that began on the night of 4 August, lasting for 15 h. This climactic phase is further divided into two subphases. The first subphase is characterized by generation of a pumice fall, whereas the second one is characterized by abundant pyroclastic flows. Stratigraphic relationships suggest that rapid growth of a cone and the generation of lava flows occurred simultaneously with the generation of both pumice falls and pyroclastic flows. The volumes of the ejecta during the first and second subphases are 0.21 km³ (DRE) and 0.27 km³ (DRE), respectively. The proportions of the different eruptive products are lava: cone: pumice fall=84:11:5 in the first subphase and lava: cone: pyroclastic flow=42:2:56 in the second subphase. The lava flows in this eruption consist of three flow units (L1, L2, and L3) and they characteristically possess abundant broken phenocrysts, and show extensive "welding" texture. These features, as well as ghost pyroclastic textures on the surface, indicate that the lava was a fountain-fed clastogenic lava. A high discharge rate for the lava flow (up to 10⁶ kg/s) may also suggest that the lava was initially explosively ejected from the conduit. The petrology of the juvenile materials indicates binary mixing of an andesitic magma and a crystal-rich dacitic magma. The mixing ratio changed with time; the dacitic component is dominant in the pyroclasts of the first subphase of the climactic phase, while the proportion of the andesitic component increases in the pyroclasts of the second subphase. The compositions of the lava flows vary from one flow unit to another; L1 and L3 have almost identical compositions to those of pyroclasts of the first and second subphases, respectively, while L2 has an intermediate composition, suggesting that the pyroclasts of the first and second subphases were the source of the lava flows, and were partly homogenized during flow. The complex features of this eruption can be explained by rapid deposition of coarse pyroclasts near the vent and the subsequent flowage of clastogenic lavas which were accompanied by a high eruption plume generating pumice falls and/or pyroclastic flows.Editorial responsibility: T. Druitt     

Ash layers in deep-sea sediments as tracers of arc volcanic activity: Japan and Central America as case studies

Abstract Arc volcanic activity on opposite sides of the Pacific Ocean (Japan and Central America) has been investigated by examining the number of volcanic ash layers recorded in Neogene and Quaternary deep-sea sediments. The data suggest that ash layers counted in deep-sea sediments may provide a reliable record of arc volcanism. The study is based on a quantitative analysis of arc volcanic activity using cores collected on DSDP (Deep-Sea Drilling Project) and ODP (Ocean Drilling Program) legs. Five distinct parameters which might affect ash distribution in marine sediments were reviewed: nature of the eruption, wind influence, settling conditions, diagenesis, and plate motion. Of these five, past atmospheric circulation was the most significant. The main constraint on the analysis is that temporal scattering of ash is not directly related to wind pattern variations. Results of this analysis are correlated with dating of terrestrial volcanic sequences. Although marine tephra records for individual regions reveal minor differences in the episodes of volcanic activity, a general correlation exists between activity of arc volcanism in Japan and in Central America. Two important pulses of arc volcanism occurred during Middle Miocene times (18–13 Ma) and Plio-Quaternary times (5–0 Ma). These episodes of intense volcanism are separated by a well recorded quiescent period during Late Miocene times. These correlating episodes of the volcanic record indicate a direct link between arc volcanism and the global tectonic evolution of the Pacific ocean margins.     

IDOAS: A new monitoring technique to study the 2D distribution of volcanic gas emissions

Imaging Differential Optical Absorption Spectroscopy (IDOAS) is an optical remote-sensing method using scattered sunlight as light source. It combines a “pushbroom” imaging spectrometer with the DOAS technique and thus allows imaging two-dimensional trace gas distributions, e.g., in volcanic plumes. The highly sensitive and specific detection of many trace gases simultaneously (specific molecules, not just elements, e.g. SO₂, BrO, NO₂, O₃, HCHO, etc.) is possible, and the temporal and spatial variation of these gases can be measured. The IDOAS system presented here enables the taking of two-dimensional images of trace gas distributions in a volcanic plume with a spatial resolution of 100 pixels horizontally × 64 pixels vertically, each with a field of view of 0.087° in horizontal and 0.208° in vertical directions. Therefore, IDOAS provides useful information about the chemical composition and chemical variability in a volcanic plume and allows studying plume dispersal and chemical transformations. The technique was applied to map the SO₂ distribution in the plume of Mt. Etna volcano for the first time in October 2003.     

海洋效应对中国沿海地磁观测影响——以广州台站为例

以广州台站为例,研究海洋效应对中国沿海地磁观测C-响应的影响.海洋效应的三维正演模拟采用球坐标系下交错网格有限差分方法,假设磁层环形电流源,正演电阻率结构模型采用"地表 3-D电导+1-D层状背景"复合模型.数值模拟结果表明,中国地区沿海C-响应受海洋效应影响明显.在空间上,沿海岸线方向,受海洋效应影响,单周期的C-响应由无海洋效应的常值变形为平行于海岸线的等值线密集梯度带;在垂直海岸方向,海洋效应影响向内陆减小,其影响可达哈尔滨-贵阳一线.海洋效应影响采用比值法进行校正,以广州台站为例,在比值曲线上发现海洋效应对C-响应的影响最大周期可达20天左右,并且就中国沿海而言,相对全球平均一维模型,利用中国地区平均一维电导率模型作为背景模型的海洋效应校正结果更加合理.进一步对广州台站海洋效应校正前后的C-响应进行了1-D反演,由于校正前的C-响应在小周期时受海洋效应特别大,直接反演无法拟合数据;但校正后反演拟合明显变好,得到的1-D导电模型表明广州地区上地幔及地幔转换带的电阻率比中国平均电阻率高约一个量级,推测中国华南地区南部的地幔转换带可能处于相对冷的环境,该模型可能成为菲律宾海板块西向俯冲并滞留到华南大陆下方地幔转换带的电性证据.     

A 3-d model of quaternary terrace development,simulations of terrace stratigraphy and valley asymmetry: A case study for the allier terraces (limagne,France)

The combined effects of climate and tectonism on general terrace stratigraphy and valley asymmetry during the last half million years in the Allier system (France) are simulated by a 3-D conceptual model (LIMTER). This model allows the formulation and evaluation of long term terrace formation scenarios for the Allier system. Simulation results suggest that terrace stratigraphy in the study area is mainly the result of internal dynamics and climatic change. Local tectonism contributed to the development of unpaired terraces while the general regional uplift played a dominant role in determining terrace formation and preservation in general.     

A distinction technique between volcanic and tectonic depression structures based on the restoration modeling of gravity anomaly: a case study of the Hohi volcanic zone, central Kyushu, Japan

In this study, we propose a numerical modeling technique which restores the gravity anomaly of tectonic origin and identifies the gravity low of caldera origin. The identification is performed just by comparing the restored gravity anomalies with the observed gravity anomalies, thus we do not need detailed geophysical and geological information around the buried caldera. The technique has been successfully applied to distinguish the gravity low originated in the buried Shishimuta caldera from other gravity lows in the Hohi volcanic zone, central Kyushu in Japan.     

The role of thermal viscous remanent magnetisation (TVRM) in magnetic changes associated with volcanic eruptions: Insights from the 2000 eruption of Mt Usu,Japan

Volcanic eruptions can produce large magnetic field changes by thermomagnetic effects, especially when magma cools from high temperatures and acquires a permanent magnetisation from the Earth's magnetic field. After the 2000 eruption of Mt Usu, Japan, significant magnetic field changes were observed not only in the vicinity of the magmatic intrusion but also in an area some distance away that was unlikely to be at a temperature near the Curie Point.     

Major and trace element geochemistry of neutral and acidic thermal springs at El Chichón volcano,Mexico: Implications for monitoring of the volcanic activity

Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH ≈ 6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH ≈ 2) saline (10 g/kg of Cl) water with a much lower outflow rate (< 10 l/s).     

A Hybrid Model for the Summit Region of Merapi Volcano,Java, Indonesia,Derived from Gravity Changes and Deformation Measured between 2000 and 2002

Three-dimensional displacements and gravity changes were measured at 20 points between 2000 and 2002 at Merapi volcano, Java, Indonesia. Former models focused on the modeling of a single magmatic source located in the summit region of the volcano. Such models do not fit to our measurements between 2000 and 2002. A new hybrid model approach is developed consisting of an elastic-gravitational source described by a mass and energy term as well as a combined dip-slip/strike-slip fault zone in the summit region. Both nonlinear optimization problems, given by the common inversion of three-dimensional displacements and gravity changes, are solved by applying a genetic algorithm. The hybrid model fits the measurements accurately, tested by Fisher test statistics. Furthermore, our model for Merapi volcano confirms previous structural models for this region so that the new model is statistically proven as well as physically reliable.     

The emplacement of intermediate volume ignimbrites: A case study from Roccamonfina Volcano,Southern Italy

A model is presented for the emplacement of intermediate volume ignimbrites based on a study of two 6 km³ volume ignimbrites on Roccamonfina Volcano, Italy. The model considers that the flows were slow moving, and quickly deflated from turbulent to non-turbulent conditions. Yield strength and density increased whereas fluidisation decreased with time and runout of the pyroclastic flows. In proximal locations, on the caldera rim, heterogeneous exposures including discontinuous lithic breccias, stratified and cross-stratified units interbedded with massive ignimbrite suggest deposition from turbulent flows. In medial locations thick, massive ignimbrite occurs associated with three types of co-ignimbrite lithic breccia which we interpret as being emplaced by non-turbulent flows. Multiple grading of different breccia/lithic concentration types within single flow units indicates that internal shear occurred producing overriding or overlapping of the rear of the flow onto the slower-moving front part. This overriding of different parts of non-turbulent pyroclastic flows could be caused by at least two different mechanisms: (1) changes in flow regime, such as hydraulic jumps that may occur at breaks in slope; and (2) periods of increased discharge rate, possibly associated with caldera collapse, producing fresh pulses of lithic-rich material that sheared onto the slower-moving part of the flow in front.We propose that ground surge deposits enriched in pumice compared with their associated ignimbrite probably formed by a flow separation mechanism from the top and front of the pyroclastic flow. These turbulent clouds moved ahead of the non-turbulent lower part of the flow to form stratified pumice-rich deposits. In distal regions well-developed coarse, often clast-supported, pumice concentrations zones and coarse intra-flow-unit lithic concentrations occur within the massive ignimbrite. We suggest that the flows were non-turbulent, possessed a relatively high yield strength and may have moved by plug flow prior to emplacement.