Geochemical processes controlling silica concentrations in groundwaters of the Salado River drainage basin, Argentina

Chemical analyses of dissolved silica in the shallow groundwater of the lower part of the Salado River drainage basin indicate that silica values averaged 60 ppm. The groundwaters are oversaturated in relation to quartz, Na-plagioclase, K-feldspar, and the weathering of quartz and aluminosilicates appear to have little control on silica concentrations in solution. Groundwater is undersaturated with respect to amorphous silica present in the loessic sediments, and these sediments are specially important in the control of the groundwater composition. The sources of amorphous silica are volcanic glass shards and biogenic silica derived from plant (silicophytoliths, diatom frustules) or animal remains (sponge spicules) also present in the Pampean loess. Silicophytoliths and diatoms have also been reported in A soil horizon samples. The dissolution of amorphous silica most likely controls the high dissolved silica concentrations in groundwater.     

The origin of fluoride in the granitic aquifer of Porto Alegre, Southern Brazil

The Porto Alegre region, Southern Brazil, comprises a fractured aquifer system constituted by pre-Cambrian granitic and gneissic rocks, and a porous aquifer system formed by Cenozoic muddy–sandy to sandy sediments. A model is presented for the origin of the fluoride in the groundwater of the fractured aquifer system, based on ionic interrelations, a statistical analysis of physicochemical parameters and geochemical modeling. The fluoride is present at levels of up to 6.13 mg/L in groundwater and it arises due to the dissolution of secondary fluorite filling fractures in the granitic and gneissic rocks. The dissolution of fluorite occurs at the same time as calcite and dolomite solubilization. The statistical analysis identified three chemically distinct groups (named 1, 2 and 3) and two subgroups (1A and 1B) of groundwater in the fractured aquifer. The most significant differences between these groups are the different concentration ranges of fluoride, calcium, bicarbonate, magnesium, total dissolved solids and chloride and pH values, as well as the correlations between them. The compositional evolution of each groundwater group is governed mainly by how much high-salinity groundwater from the porous aquifer system is mixed with them and the different thermodynamic equilibrium conditions of calcite, dolomite and fluorite.     

Geochemical characteristics of shallow groundwater in Datong basin, northwestern China

Located in semi-arid regions of northwestern China, Datong basin is a Quaternary sedimentary basin, where groundwater is the most important source for water supply. It is very important to study groundwater characteristics and hydrogeochemical processes for better management of the groundwater resource. We have identified five geochemical zones of shallow groundwater (between 5 and 80 m) at Datong: A. Leaching Zone (Zone I); B. Converging Zone (Zone II); C. Enriching Zone (Zone III); D. Reducing Zone (Zone IV); E. Oxidizing Zone (Zone V). In Zones I, II, and V and some parts of Zones III and IV, hydrolysis of albite/K-feldspar/chalcedony system and/or albite/K-feldspar/quartz system enhanced concentrations of Na⁺, K⁺, HCO₃⁻ and silicate. In Zone I, dissolution of carbonate and hydrolysis of feldspar generally controlled the groundwater chemistry. Infiltration of meteoric water promoted the formation of HCO₃⁻ in the water. In Zone II, the main geochemical processes influencing the groundwater chemistry were dissolutions of calcite and dolomite, ion exchange and evaporation. In Zones III and IV, in addition to ion exchange, evaporation and precipitation of calcite and dolomite, leaching of NaHCO₃ in saline–alkaline soils dominated the water quality. Zone IV was under anoxic condition, and reduction reactions led to the decrease of SO₄²⁻, NO₃⁻ and occurrence of H₂S, with the highest arsenic content (mean value of 366 μg/L), far exceeding Maximum Contaminant Level (MCL). Abnormal arsenic in the groundwater resulted in endemic disease of waterborne arsenic poisoning among local people. Zone V overlapped Zone I was intensively affected by coal mining activities. Sulfide minerals, such as pyrite, would have been oxidized when exposed to air due to coal mining, which directly added sulfate to groundwater and thus increased SO₄²⁻ concentration. Oxidization of sulfide minerals also decreased pH and promoted dissolutions of calcite and dolomite.     

Association of hydrogeological factors in temporal variations of fluoride concentration in a crystalline aquifer in India

The major part of groundwater in India is found in granitic aquifers. Fluoride in groundwater from a crystalline aquifer in a semi-arid region of granitic rocks in India, known as Maheshwaram watershed, was analyzed for spatial and temporal variability during 1999–2002 to assess the effect of hydrogeological factors on fluoride concentration. Samples were collected from 32 representative wells in the area for the pre- and post-monsoon seasons and analyzed for F content. The CHESS computer program was used to calculate ionic activities of aqueous species and the mineral saturation index (SI) for calcite and fluorite. The GARDENIA computer program was used to calculate the recharge values in the study area. The influences of dissolution kinetics of fluoride minerals and recharge from rainfall on fluoride concentration were of interest and results clearly indicate that fluoride content in groundwater depends on the interaction period of groundwater with host rock. Results could also be utilized for designing remedial measures particularly with dilution method in an optimal way.     

The origin of fluoride-rich groundwater in Mizunami area, Japan — Mineralogy and geochemistry implications

The aim of this paper was to explore new factors that might be reasons for the occurrence of fluoride-rich groundwater in the area around a construction site. During the construction of two deep shafts of the Mizunami Underground Research Laboratory (MIU) in Mizunami city, central Japan, a large quantity of groundwater with high fluoride concentration was charged into the shafts. Chemical investigation carried out during the excavation revealed that fluoride concentrations in the area around the MIU site greatly exceeded those prescribed by Japanese standards. Therefore, the origin of fluoride ion was experimentally investigated. Samples were collected from the core of a deep borehole drilled in the study area. The weathering - and alteration levels of the collected granites varied greatly. Granitic powders were used to measure fluoride content in the granitic rock mass. The fluoride content ranged between 200 and 1300 mg/kg. The powders were reacted with purified water for 80 days. The results of water–rock interaction showed granitic rock to be one of the main sources of fluoride-rich groundwater in Mizunami area. Fluoride concentrations in these solutions that were shaken for 80 days varied between 2 and 7 mg/l. This change may have occurred as a result of the spatial distribution of fluoride ions in the granite mass as evidenced by mineralogical analysis of fluoride content in several specimens. X-ray powder diffraction analysis of the rock before- and after the water–rock interaction tests manifested that the presence of fluorite mineral was relatively small compared to other minerals. The degree of weathering and alteration might be an additional factor causing dissolution of fluoride-rich minerals. However, it was difficult to interpret the change in fluorite composition by X-ray diffraction analysis.     

Groundwater flow modeling in the Zhangye Basin,Northwestern China

The Zhangye basin is in the middle reaches of the Heihe River, northwestern China. Heavy abstraction of groundwater since the 1970s in the area is for agricultural, industrial and drinking water supplies and has led to a substantial decline in the potentiometric surface. A three-dimensional regional numerical groundwater flow model, calibrated under transient conditions, has been developed and used to predict the drawdown for the period from 2000 to 2030 under two different groundwater management scenarios.     

Enrichment of fluoride in groundwater under the impact of saline water intrusion at the salt lake area of Yuncheng basin,northern China

Long-term intake of high-fluoride groundwater causes endemic fluorosis. This study, for the first time, discovered that the salt lake water intrusion into neighboring shallow aquifers might result in elevation of fluoride content of the groundwater. Two cross-sections along the groundwater flow paths were selected to study the geochemical processes controlling fluoride concentration in Yuncheng basin, northern China. There are two major reasons for the observed elevation of fluoride content: one is the direct contribution of the saline water; the other is the undersaturation of the groundwater with respect to fluorite due to salt water intrusion, which appears to be more important reason. The processes of the fluorine activity reduction and the change of Na/Ca ratio in groundwater induced by the intrusion of saline water favor further dissolution of fluorine-bearing mineral, and it was modeled using PHREEQC. With the increase in Na concentration (by adding NaCl or Na₂SO₄ as Na source, calcium content kept invariable), the increase of NaF concentration was rapid at first and then became slower; and the concentrations of HF, HF₂⁻, CaF⁺, and MgF⁺ were continuously decreasing. The geochemical conditions in the study area are advantageous to the complexation of F⁻ with Na⁺ and the decline of saturation index of CaF₂, regardless of the water type (Cl–Na or SO₄–Na type water).     

塔里木盆地北缘日达里克地区库车组下段砂岩岩石学及地球化学特征

通过大量钻孔岩心的观察及样品数据统计分析,发现日达里克地区库车组下段砂岩成份成熟度及结构成熟度方面均较低,具近物源快速沉积特征.岩石为泥质胶结,固结疏松,属良好的铀储层.通过对砂岩地球化学特征的分析,部分元素含量变化与层间氧化分带关系明显,呈SiO2、Al2O3含量以氧化带为最高,过渡带次之,还原带最低的特点;CaO、...     

Groundwater geochemistry of Ain Azel area,Algeria

Hydrogeochemical data for 18 groundwater samples and 11 hydrochemical parameters were subjected to Q- and R-mode cluster analysis and inverse geochemical modeling. Q-mode cluster analysis resulted in three distinct water types (brackish water type, saline water type and highly saline water type). R-mode cluster analysis led to the conclusion that the water–rock interaction is the major source of contamination for the groundwater in the area. Geochemical modeling results show that carbonates, gypsum, halite, carbon dioxide (gas), and chlorite are dissolving, whereas Ca-montmorillonite, gibbsite, illite, K-mica, kaolinite, and quartz are mostly precipitating along different flow paths in the groundwater system of the area.     

Erratum to: Geochemical and environmental magnetic characteristics of high arsenic aquifer sediments from Datong Basin,northern China

Geochemical and environmental magnetic studies were carried out to identify the effect of iron oxyhydroxides on arsenic mobilization in high arsenic aquifer system. Using high arsenic sediment samples from two boreholes, specifically drilled for this study, chemical composition and magnetic properties including magnetic susceptibility, saturation remnant magnetization, and isothermal remnant magnetization were measured. Results of correlation analysis of element contents show that arsenic and iron are closely associated with each other (r ² = 0.40, α = 0.05, n = 21). In contrast, the correlation of phosphorus with iron (r = 0.11, α = 0.05, n = 21) and arsenic (r ² = 0.18, α = 0.05, n = 21) was poor, which might result from competitive adsorption of phosphorus and arsenic on the surface of Fe-oxyhydroxides. The high correlation coefficients between arsenic contents and magnetic parameters suggest that the ferrimagnetic minerals including maghemite and hematite are the dominant carrier of arsenic in aquifer sediments. The results of sequential extraction experiments also revealed the association of arsenic with reducible iron oxides, such as maghemite and hematite in aquifer sediments. Therefore, under reducing conditions, reductive dissolution and desorption of arsenic from Fe-oxyhydroxides into the aqueous phase should be the dominant geochemical processes for its enrichment in groundwater at Datong. An erratum to this article can be found at     

太原盆地地下水系统水化学特征及形成演化机制

在对太原盆地水文地质进行详细调查基础上,集成应用水化学统计、水化学模拟技术,系统研究了盆地地下水水化学类型、空间分布特征,并对其形成演化机制进行了系统分析,取得了一系列新的认识。按水质类型和分布特征,盆地浅层地下水-含水层埋深小于50 m大致分为盆地边缘地带浅层淡水、盆地中心浅层咸水和浅层高矿化硫酸盐水3种类型。高矿化硫酸盐水主要是由于接受了富含硫酸根离子的周边基岩水补给所致。盆地中深层孔隙水可分为盆地边缘中深层水、盆地中心中深层水和中深层混合水3种类型。浅层地下水存在2种形成机制,一种是高矿化Ca·Mg-SO_4^2-型岩溶水的混合补给形成,另一种高矿化水是在径流演化过程中受蒸发浓缩作用影响,使地下水矿化度不断增高而形成。自盆地边缘至中心地带,中深层地下水水化学特征具有明显的水平变化规律,在盆地中心形成2个高值区,水化学类型依次为Ca·MgHCO₃→Na·CaHCO₃·SO₄→Na·MgHCO₃·Cl→NaHCO₃。      

鄂尔多斯北部直罗组中烃类包裹体地球化学特征及来源分析

对鄂尔多斯盆地东胜地区中侏罗统直罗组砂岩中烃类包裹体进行镜下观察、描述，利用压碎抽提法对烃类包裹体进行色谱—质谱分析，并与白垩系油苗、三叠系油砂及源岩抽提物进行对比，目的是探讨其来源。包裹体油生物标志物成熟度参数，C29ααα甾烷20S/(S+R)、C32αβ藿烷22S/(S+R)比值基本达到平衡值，利用甲基菲指数计算的镜质体反射率参数介于0.64%～0.82％之间，显示包裹体中石油烃已接近成熟—成熟热演化阶段；物质来源及沉积环境参数，ααα20R甾烷百分含量C27>C28相似文献   

华北盆地西部太原组遗迹化石组合对古水深变化的响应*

通过对豫西—晋中南地区上石炭统—下二叠统太原组碳酸盐岩中遗迹化石的组成、产状及分布特征的研究,结合部分生物潜穴中Sr含量、Sr/Ba值、1000×(Sr/Ca)值和δ¹³C值,得到不同地区太原组沉积期古水深的变化曲线,建立了3种不同水深的遗迹组合: (1)Nereites-Chondrites遗迹组合,产生于氧化还原界面附近水体相对较深的浅海下部环境;(2)Zoophycos-Teichichnus遗迹组合,形成于浪基面至氧化还原界面之间的浅海中部沉积环境;(3)Zoophycos-Thalassinoides遗迹组合,出现在平均海平面至浪基面之间的浅海上部或较为闭塞的海湾潟湖沉积环境。依据这3种遗迹组合在各剖面上的变化特征和古水深,认为在豫西—晋中南地区太原组沉积期发生过2次较大规模的海侵。这一成果为精细研究华北西部地区太原期沉积环境演变规律及对比地层提供了生物遗迹学方面的依据。     

Geochemical occurrence of arsenic,vanadium and fluoride in groundwater of Patagonia,Argentina: Sources and mobilization processes

Contamination of groundwater in different parts of the world is a result of natural and/or anthropogenic sources, leading to adverse effects on human health and the ecosystem. In Península Valdés, where groundwater is the only source of supply, high concentrations of As and F- were registered. Since it is a region without industrial activity, an analysis of possible natural sources of contamination is necessary. The aim of this study is to analyse the hydrological processes that determines the presence and mobilization of those elements through the analysis of the mineralogy of the aquifer sediments and the ionic water relationships. The productive aquifer, dominated by psamites, coquinas and siltstone is located between 29 and 42 m below ground surface. The hydrochemistry studied from 105 sampling points, shows that groundwater is dominated by Na-Cl ions and, in the fresh water sectors, the ionic type is Na-HCO3 to Na-Cl. In 17 of these samples, Zn, Cr, Mn, As, V, Sr, Fe, F ions were measured and As and F contents above the potability limit were recorded. These contents vary between 0.01 and 0.40 mg/L in As and between 0.31 and 4 in F- which are both associated with elevated V values. The optical petrographic microscope observations and the X-ray diffraction measurements show that the sediments are dominated by volcanic lithic fragments, volcanic glass shards and quartz, plagioclase, pyroxenes and magnetite clasts. The scanning electron microscopy, combined with the energy dispersive X-ray analysis, shows that the highest concentrations of As are associated with volcanic shards and iron oxides. The combined analysis of all these elements leads to conclude that the processes which explain the presence of those ions are a result of the interaction of groundwater with the components of the aquifer sediments. At alkaline pH, the high solubility of the amorphous silica of vitreous shards allows the release of As, V and F- ions towards the solution. Thus, adsorption-desorption processes can also control the presence of these ions in groundwater. Both As and V (in solution in the form of oxyanions) can be adsorbed by iron oxides, while F- anions have more affinity to be adsorbed by the carbonate facies, some of them re-precipitated as a result of the increase in pH. The identified hydrogeological processes provide information for the planning of water purification measures that tend to improve the water resources management in a large arid region of Patagonia.     

东海盆地的变质岩

东海盆地处于欧亚板块和太平洋板块的交接部位,是全球岩石圈结构和动力学机制研究中涉及众多基础问题的关键地区。它的生成及发展对深化中国东南陆缘地区地壳构造演化的认识,且为能源勘查,研究海平面变化,预测自然灾害,保护环境及国土主权均有重大意义。就其构造机制及性质说法不一,有待商榷。该盆地内已钻井30余口,随改革开放以来,局部凹陷对外公开招标,已施工10余口井,涉及变质岩的仅2口井。变质岩为黑云斜长片麻岩类,原岩恢复为变质火成岩(中性侵入岩,包括石英闪长岩及其相关的浅成岩),属吕梁期,原岩经多期变质或混合岩化作用所致,是中国大陆的自然延伸部位。     

Origin of high fluoride in groundwater in the North Gujarat-Cambay region, India

This paper reports on the origin of high fluoride in a regional alluvial aquifer system under water stress in the North Gujarat-Cambay (NGC) region in western India. This region is severely affected by endemic fluorosis due to ingestion of groundwater containing excessive fluoride. With an objective to understand factors controlling high fluoride concentration in groundwater of this region, 225 groundwater samples have been analysed for various chemical parameters. Samples were collected from different depth zones tapping shallow dug wells, geothermal springs, hand-pumps and tubewells, including free flowing artesian wells up to 450 m depth from the aquifers in the Quaternary alluvial formation covering most of the study area. No relation was found between fluoride concentration and depth of sampled groundwater. However, certain sub-aquifer zones have been identified within the Cambay Basin where groundwater contains relatively high fluoride concentration. In general, areas of high fluoride overlap areas with high electrical conductivity (EC). On the west flank of the Cambay Basin in the low lying belt linking Little Rann of Kachchh-Nalsarovar-Gulf of Khambhat (LRK-NS-GK), high fluoride and EC in shallow aquifers originate from evaporative enrichment. On the east flank of Cambay Basin, some high fluoride pockets are observed which are probably due to preferential dissolution of high fluoride bearing minerals. On this flank high fluoride is also associated with thermal springs. Within the Cambay Basin, alternating belts of low and high fluoride concentrations are ascribed to groundwater recharge during the past wet and arid climatic phases, respectively. This is based on groundwater radiocarbon age contours of ~20 ka overlapping the high fluoride belt.

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Resumen Este artículo reporta sobre el origen de altas concentraciones de flúor en un sistema regional de acuíferos bajo presión hídrica en la región del norte de Gujarat-Cambay (NGC) del occidente de India. Esta región está afectada severamente por fluorosis endémica debido a la ingestión de agua subterránea que contiene exceso de flúor. Se tomaron 225 muestras de agua subterránea las cuales fueron analizadas por varios parámetros químicos con el objetivo de entender los factores que controlan las elevadas concentraciones de flúor en esta región. Las muestras se colectaron a diferentes profundidades en pozos someros, manantiales geotermales, pozos con bombas de mano, y pozos entubados incluyendo pozos artesianos de flujo libre de hasta 450 m de profundidad emplazados en los acuíferos de la formación aluvial Cuaternaria que cubre la mayor parte del área de estudio. No se encontró ninguna relación entre la concentración de flúor y la profundidad de las muestras de agua subterránea. Sin embargo, se identificaron dentro de la cuenca Cambay algunas zonas sub-acuíferas donde el agua subterránea contiene concentraciones relativamente altas de flúor. En general, las áreas con elevada concentración de flúor están sobrepuestas a áreas de alta conductividad eléctrica (CE). Sobre el flanco occidental de la cuenca Cambay, en la faja baja que une Little Rann con Kachchh-Nalsarovar-Golfo de Khamhat (LRK-NS-GK), las altas concentraciones de flúor y altas CE en acuíferos someros se derivan de enriquecimiento por evaporitas. Sobre el flanco oriental de la cuenca Cambay se observaron algunos cuerpos con alta concentración de flúor los cuales se deben probablemente a la disolución preferencial de minerales con alto contenido de flúor. En este flanco el alto contenido de flúor también se asocia con manantiales termales. Dentro de la cuenca Cambay existen fajas alternantes, con concentraciones altas y bajas de flúor, las cuales se atribuyen a recarga de agua subterránea durante las fases climáticas pasadas, húmedas y áridas, respectivamente. Este planteamiento se basa en contornos de edades de ~20 ka de radiocarbono que están sobrepuestos a la faja alta en flúor.

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Résumé Cet article étudie lorigine des teneurs élevées en Fluorure dans un système aquifère alluvial régional, soumis à un stress hydrique dans le Nord Gujarat–région Cambay (NGC) à lOuest de lInde. Cette région est sévèrement affectée par une fluorose endémique, due à lingestion deau souterraine très riche en fluor. Avec pour objectif de comprendre les paramètres contrôlant les fortes teneurs en fluor, 225 échantillons deau souterraine ont été analysés sur différents paramètres. Les échantillons ont été pris à différentes profondeurs : puits de surface, sources géothermiques, pompes à main, forages artésiens jaillissant dont la profondeur avoisine les 450 m dans les formations alluviales quaternaire recouvrant la plus grande partie de la région étudiée. Il ny a pas de relation entre la profondeur et les teneurs en fluorure. Néanmoins, certaines zones sub-aquifères ont été identifiées dans le Basin de Cambay où leau souterraine présentait des concentrations relativement élevées en fluorure. En général les zones de hautes concentrations en fluorure recouvrent les zones à fortes conductivité électrique (abréviation en anglais: EC). Sur le flanc Ouest du bassin de Cambay dans le mince lit reliant Little Ran de Kachchh-Nalsarovar au golfe de Khambhat (LRK-NS-GK), les fortes teneurs en fluorure et les EC dans la nappe phréatique proviennent de lenrichissement par les évaporites. Sur le flanc Est du bassin, des poches de teneurs élevées en fluorures ont été observées, probablement dues à des dissolutions préférentielles de minéraux fluorés. Sur ce flanc des teneurs sont également associées à la présence de sources géothermales. Dans le bassin de Cambay, les alternances de couches lits à fortes teneurs et de lits à faibles teneurs sont expliquées par la recharge durant les périodes climatiques humides et les périodes climatiques plus sèches. Ceci est corroboré par les datations au radiocarbone (environ 20.000 an) au dessus du lit riche en fluorure.

     

鄂尔多斯盆地东部太原组古岩溶特征

鄂尔多斯盆地下二叠统太原组为碳酸盐与陆源碎屑混合沉积,主要由灰岩、岩屑石英砂岩、泥岩和煤岩组成。太原组沉积时期鄂尔多斯盆地东部为碳酸盐与陆源碎屑混合沉积的陆表海潮坪沉积体系和三角洲沉积体系。北部发育三角洲前缘沉积。南部发育碳酸盐潮下带—潮间带及陆源碎屑潮下带。太原组中普遍发育冲刷充填现象,说明短期的沉积间断发生频繁。太原组中岩溶角砾岩发育,主要为镶嵌状角砾岩,见到少量裂缝角砾岩和紊乱角砾岩。太原组中的岩溶形成于同生期,没有形成岩溶地貌。与现代碳酸盐沉积物相比,太原组灰岩具有较高的Mn和Fe含量,明显低的Sr含量和δ18O值。这是由于埋藏作用和淡水淋滤所引起的,低的Sr含量和δ18O值主要由淡水淋滤所致。与大多数地质学家研究得出的二叠纪生物和非生物成因的方解石的δ13C值相比较,太原组方解石的δ13C值无明显差异。宏观和微观特征均说明太原组存在古岩溶。岩溶作用使得灰岩的储集性能在一定程度上得到了改善。     

Development of Overpressure in the Tertiary Damintun Depression, Liaohe Basin, Northern China

The Damintun depression is one of the four depressions in the Liaohe basin in northern China, and is a rift basin developed in the Paleogene. This paper discusses in detail the characteristics of pressure and fluid potential of the Damintun depression based on a synthesis of the data from boreholes, well tests and seismic surveys. Data from sonic logs, well tests and seismic velocity measurements are used to study the pressure characteristics of the areas. From the sonic log data, shales can be characterized as normally pressured, slightly overpressured or highly overpressured; from the well test data, the pressure-depth gradient in oil-producing intervals implies hydrostatic pressure in general. Most seismic profiles in the Damintun depression are of sufficiently high quality for seismic velocities to be measured. The fluid pressures, excess pressures and pressure coefficients in 47 representative seismic profiles are predicted using formula calculation methods, and further transformed to fluid potenti