Matrix permeability of the confined Floridan Aquifer,Florida, USA

The Upper Floridan Aquifer of peninsular Florida retains most of its depositional porosity and, as a result, is a multi-porosity aquifer: double porosity (fractured porous aquifer) downdip where the aquifer is confined, and triple porosity (karstic, fractured porous aquifer) in the updip, unconfined region. Matrix permeability in the confined region varies in the range <10^–14.4–10^–11.1 m², as determined by 12,000 minipermeameter measurements on 1,210 m of slabbed core. Limestones divide into 13 textural classes and dolomites into two. Depositional facies (textural class) strongly correlates with matrix permeability. As a result, the facies architecture of the Eocene and Oligocene carbonates that compose the confined portion of the aquifer controls the lateral and vertical distribution of its matrix transmissivity. The most-permeable facies are grainstones (median k, 10^–12.4 m²) and sucrosic dolomites (median k, 10^–12.0 m²). Together, they are responsible for ~73% of the matrix transmissivity of the logged cores, although they constitute only ~24% of the thickness. Examination of the flow equations of fractured porous aquifers suggests that the permeability of these two facies is large enough that matrix permeability cannot be discounted in modeling the hydraulics of the double-porosity system. This conclusion likely applies to most, if not all, Cenozoic double-porosity carbonate aquifers, as average matrix and fracture permeabilities in the Floridan Aquifer are similar to other Cenozoic carbonates from around the world.

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Resumen El Acuífero Superior de Florida conserva gran parte de su porosidad deposicional y, como resultado, se comporta como un acuífero multi-poroso: de doble porosidad (acuífero poroso fracturado) a favor del buzamiento, donde se halla confinado, y de triple porosidad (acuífero poroso fracturado y kárstico) en sentido opuesto, en la zona en que se comporta como libre. La permeabilidad de la matriz en la región confinada está comprendida entre menos de 10^–14,4 y 10^–11,1 m², según determinaciones hechas a partir de 12.000 medidas de mini-permeámetro en 1.210 rodajas de testigos. Se ha distinguido quince clases texturales de calcita (n=2.298) y dos de dolomita (n=983), y las facies ejercen un gran control en la permeabilidad de la matriz. Como consecuencia, la arquitectura de las facies de los carbonatos Eocenos y Oligocenos que forman la zona confinada del acuífero controla la distribución lateral y vertical de la transmisividad de la matriz. Las facies más permeables son grainstones o grano-soportadas sin matriz (mediana de permeabilidad de 10^–12,4 m²) y dolomitas sacaroideas (10^–12,0 m²). Ambas son responsables de aproximadamente el 73% de la transmisividad de los testigos ensayados, aunque sólo constituyen el 24% de su espesor. El examen de las ecuaciones de flujo en acuíferos porosos fracturados sugiere que la permeabilidad de estas facies más permeables es lo suficientemente elevada como para no poder despreciar la permeabilidad de la matriz en la modelación hidráulica de dichos sistemas de doble porosidad. La proyección de la estratigrafía regional y de las tendencias de las facies en la parte del acuífero ubicado en sentido contrario al buzamiento, que tiene carácter de libre y está más karstificado, predice que las permeabilidades mayores son debidas al incremento de los porcentajes de grainstones y dolomitas sacaroideas. Por tanto, es probable que la transmisividad de la matriz deba ser tenida en cuenta en el sistema de triple porosidad de la región.

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Résumé Laquifère floridien supérieur de la péninsule de Floride contient plus que sa porosité de dépôt et, par conséquent, est un aquifère à porosité multiple: double porosité (aquifère fracturé poreux) en aval-pendage, là où laquifère est captif, et triple porosité (aquifère karstique et fracturé poreux) en amont-pendage, dans la région où il est libre. La perméabilité de matrice dans la région captive est comprise entre moins de 10^–14,4 et 10^–11,1 m² daprès 12.000 mesures par miniperméamètre sur 1.200 m de carottes. Quinze classes texturales de calcaires (n=2.298) et deux classes de dolomies (n=983) ont été reconnues; il existe un fort contrôle du faciès sur la perméabilité. En effet, larchitecture des carbonates de lEocène et de lOligocène qui constituent la partie captive de laquifère contrôle la distribution latérale et verticale de la transmissivité de la matrice. Les faciès les plus perméables sont les grainstones (k médian, 10^–12,4 m²) et les dolomies saccharoïdes (10^–12,0 m²). Ces deux faciès rendent compte de 73% environ de la transmissivité dans les carottes étudiées, bien quils ne contribuent quà 24% environ de lépaisseur. Lexamen des équations découlement en aquifères fracturés poreux suggère que la perméabilité de ces faciès les plus perméables est assez importante pour que la perméabilité de matrice ne puisse pas être écartée dans la modélisation de lhydraulique de ces systèmes à double porosité. Si lon projette ces tendances de la stratigraphie régionale et des faciès à lamont-pendage, la partie non captive et karstifiée de laquifère laisse prévoir de fortes perméabilités dues à des pourcentages croissants de grainstones et de dolomies saccharoïdes. Il est donc très probable quil sera nécessaire de prendre en compte la transmissivité de matrice dans un système à triple porosité dans cette région.

     

Groundwater arsenic distribution in South-western Uruguay

This is the first specific information regarding arsenic distribution of groundwater in SW Uruguay. Twenty-eight wells were sampled on the aquifers of Mercedes, Raigón and Chuy in five localities. The pH, specific conductivity and temperature were determined in the field. The hydrochemical characterization (major and trace elements) was carried out by both inductively coupled plasma-optical emission spectrometry and inductively coupled plasma-mass spectrometry. The occurring arsenic concentrations exceed the recommended threshold for drinking water of the World Health Organization (10 μg/l of As) in 22 samples, with more than 50 μg/l of As in two cases. The median, minimum and maximum concentrations were 0.1, 16.9 and 58.0 μg/l of As, respectively. The studied aquifers present a horizontal and a vertical variation of the concentrations as a whole as well as individually. The highest values were observed in the Mercedes Aquifer in the areas near the Uruguay River.     

Concentrations and speciation of arsenic along a groundwater flow-path in the Upper Floridan aquifer, Florida, USA

Arsenic (As) concentrations and speciation were determined in groundwaters along a flow-path in the Upper Floridan aquifer (UFA) to investigate the biogeochemical “evolution“ of As in this relatively pristine aquifer. Dissolved inorganic As species were separated in the field using anion-exchange chromatography and subsequently analyzed by inductively coupled plasma mass spectrometry. Total As concentrations are higher in the recharge area groundwaters compared to down-gradient portions of UFA. Redox conditions vary from relatively oxic to anoxic along the flow-path. Mobilization of As species in UFA groundwaters is influenced by ferric iron reduction and subsequent dissolution, sulfate reduction, and probable pyrite precipitation that are inferred from the data to occur along distinct regions of the flow-path. In general, the distribution of As species are consistent with equilibrium thermodynamics, such that arsenate dominates in more oxidizing waters near the recharge area, and arsenite predominates in the progressively reducing groundwaters beyond the recharge area.     

Analysis of radial movement of an unconfined leaky aquifer due to well pumping and injection

Radial movement of an unconfined leaky aquifer was studied with respect to hydraulic forces that are induced by well recharge and discharge. New analytic solutions in the velocity and displacement fields were found and applied to describe transient movement in an unconfined leaky aquifer. Linear momentum and mass balance of saturated porous sediments, the Darcy-Gersevanov law, and the analytic solution of hydraulic drawdown for unsteady flow within the unconfined leaky aquifer were introduced to find the new solutions. Analytic results indicate that the nonlinear relation between the initial hydraulic head (h₀) and the well function has an insignificant effect on the aquifer transient movement when the drawdown s<0.02h ₀. When the well function is simplified with different assumptions and pumping conditions, the new solutions correspondingly reduce to cases that are similar to the Hantush-Jacob, Muskat, and Theis transient movement of a confined leaky aquifer. It was found that large leakance is important in slowing radial movement and reducing aquifer deformation. Flow velocity in the aquifer is more responsive to leakance than to cumulative displacement within the aquifer. The zones and boundary with tensile stress can be located using the same approach applied to a confined aquifer for risk assessment of earth fissuring.

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Résumé Le mouvement radial dans un aquifère semi-perméable libre a été étudié en considérant les forces hydrauliques induites par la recharge et le prélèvement au niveau d’un puits. De nouvelles solutions analytiques des champs de vitesse et de déplacement ont été trouvées et appliquées pour décrire le mouvement transitoire dans un aquifère semi-perméable libre. Pour trouver les nouvelles solutions, le moment linéaire et le bilan de masse dans les sédiments poreux saturés, la loi de Darcy-Gersevanov, et la solution analytique du rabattement hydraulique pour un écoulement transitoire dans un aquifère semi-perméable libre sont pris en compte. Les résultats analytiques montrent que la relation non-linéaire entre le potentiel hydraulique initial (h₀) et la fonction de puits a un effet insignifiant sur le mouvement transitoire de l’aquifère quand le rabattements s <0.02h₀. Si la fonction de puits est simplifiée en tenant compte de différentes hypothèses et conditions de pompage, les nouvelles solutions se réduisent en conséquence à des cas similaires au mouvement transitoire dans un aquifère semi-perméable captif selon Hantush-Jacob, Muskat, et Theis. Il s’est avéré qu’une drainance élevée est importante pour le ralentissement du mouvement radial et la réduction de la déformation de l’aquifère. La vitesse d’écoulement dans l’aquifère est plus sensible à la drainance qu’au déplacement cumulé dans l’aquifère. Les zones et la frontière présentant des contraintes de traction peuvent être localisées en utilisant la même approche appliquée à un aquifère captif pour l’évaluation des risques de fissuration du sol.

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Resumen Se ha estudiado el movimiento radial en un acuífero no confinado con fuga en relación a las fuerzas hidráulicas que son inducidas por la descarga y recarga del pozo. Se encontraron nuevas soluciones analíticas en los campos de desplazamiento y velocidad, las cuales se aplicaron para describir el movimiento transitorio en un acuífero no confinado con fuga. Se han introducido cálculos de balance de masa y momentum lineal de los sedimentos porosos saturados, la Ley Darcy-Gersevanov, y la solución analítica de descenso hidráulico para flujo sin régimen permanente dentro del acuífero no confinado con goteo para encontrar las nuevas soluciones. Los resultados analíticos indican que la relación no lineal entre la presión hidráulica inicial (h₀) y la función del pozo tiene efecto insignificante en el movimiento transitorio del acuífero cuando el descenso s < 0.02h₀. Cuando se simplifica la función del pozo en base a diferentes supuestos y condiciones de bombeo se reducen las nuevas soluciones a casos que son similares a el movimiento transitorio Hantush-Jacob, Muskat, y Theis de un acuífero confinado con goteo. Se encontró que las fugas grandes son importantes en la disminución del movimiento radial y en la reducción de la deformación del acuífero. La velocidad de flujo en el acuífero responde más a las fugas que al desplazamiento acumulativo dentro del acuífero. Pueden localizarse zonas y límites con esfuerzos tensionales usando el mismo enfoque aplicado a acuíferos confinados para evaluación de riesgo de generación de fracturas en el terreno.

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地下咸水层封存CO_2的关键技术研究

CO2 地质储存是减缓温室气体排放的重要手段之一,根据对全球范围内不同形式 CO2 地质埋存能力的计算,地下咸水层以分布广泛,埋存潜力大而成为最有效的地质埋存方式之一.在总结国内外 CO2 地质埋存工程现状的基础上,介绍了利用地下咸水层埋存 CO2 的原理、地下咸水层的关键参数、埋存能力计算、场地调查、数值模拟和监测技术等.并提出了相关建议.     

The role and impact of freshwater–seawater mixing zones in the maturation of regional dolomite bodies within the proto Floridan Aquifer, USA

Palaeogene dolostones from the sub‐surface of Florida are ideal for the study of dolomite maturation because they record the early stages of a secondary dolomite overprint without destruction by later diagenetic overprints. Two distinct dolomite textures occur in the dolostones of the Upper Eocene Ocala and Lower Oligocene Suwannee limestones in west‐central Florida: a porous and permeable sucrosic dolomite and a less porous and relatively impermeable indurated non‐sucrosic dolomite. In both textures, the initial matrix dolomite is dully luminescent, whereas the secondary overprint is dominantly luminescent cement in the Suwannee and only neomorphic luminescent dolomite in the Ocala. The abundance of luminescent dolomite ranges from 2% to 38%, which translates to 1·6 km³ of material in the Suwannee and 13·5 km³ in the Ocala. Extrapolated trace‐element contents (Sr and Na) and δ¹⁸O values for the matrix and luminescent end‐members indicate a marine origin for the matrix dolomite in both units, and a freshwater–seawater mixing‐zone origin for the secondary luminescent dolomites. The δ¹⁸O values indicate that a saline, middle mixing‐zone environment overprinted the Suwannee but a more dilute mixing zone affected the Ocala. Fluid–fluid mixing models constrained by modern Floridan aquifer hydrochemistry and extrapolated ⁸⁷Sr/⁸⁶Sr values of the luminescent phases indicate that the mixing zones operated during the Late Miocene to Pliocene in the Ocala and affected the Suwannee in the Pliocene. The luminescent Suwannee mixing‐zone cement reduced porosity up to threefold and permeability up to 100‐fold, which converted many sucrosic dolomites to indurated dolomites. By contrast, the neomorphic luminescent Ocala dolomite did not have an appreciable impact on the maturations. Although freshwater–seawater mixing zones were not the sites of the initial dolomitization, the mixing‐zone environment did dramatically overprint and mature the regionally widespread dolomites of the Ocala and Suwannee limestones. This maturation occurred shortly after formation of the proto‐Floridan aquifer; the timing suggests the matrix dolomites were ‘ripe’ for alteration and that the only prerequisite for mixing‐zone dolomite is pre‐existing dolomite substrates to reduce kinetic barriers. In contrast to recent claims, the results of this study demonstrate that mixing zones can be effective in forming regionally significant amounts of secondary dolomite and influencing the petrophysical maturation of dolomite bodies.     

淮河流域(河南段)第四系含水层特征

本文确定了第四系含水层划分原则,根据该原则将工作区划分为第一、第二及第三含水层,阐述了各含水层岩性、水文地质参数、富水性及地下水循环特征,建立了地下水循环流动框图.     

Geochemical and stable isotopic evolution of the Guarani Aquifer System in the state of São Paulo, Brazil

The purpose of this report is to explain geochemical and stable isotopes trends in the Brazilian unit of the Guarani Aquifer System (Botucatu and Piramboia aquifers) in S?o Paulo State, Brazil. Trends of dissolved species concentrations and geochemical modeling indicated a significant role of cation exchange and dissolution of carbonates in downgradient evolution of groundwater chemistry. Loss of calcium by the exchange for sodium drives dissolution of carbonates and results in Na–HCO₃ type of groundwater. The cation-exchange front moves downgradient at probably much slower rate compared to the velocity of groundwater flow and at present is located near to the cities of Sert?ozinho and águas de Santa Barbara (wells PZ-34 and PZ-148, respectively) in a shallow confined area, 50–70 km from the recharge zone. Part of the sodium probably enters the Guarani Aquifer System. together with chloride and sulfate from the underlying Piramboia Formation by diffusion related to the dissolution of evaporates like halite and gypsum. High concentrations of fluorine (up to 13.3 mg/L) can be explained by dissolution of mineral fluoride also driven by cation exchange. However, it is unclear if the dissolution takes place directly in the Guarani Aquifer System or in the overlying basaltic Serra Geral Formation. There is depletion in δ ²H and δ ¹⁸O values in groundwater downgradient. Values of δ ¹³C(DIC) are enriched downgradient, indicating dissolution of calcite under closed system conditions. Values of δ ¹³C(DIC) in deep geothermal wells are very high (>–6.0‰) and probably indicate isotopic exchange with carbonates with δ ¹³C about –3.0‰. Future work should be based on evaluation of vertical fluxes and potential for penetration of contamination to the Guarani Aquifer System. Electronic Publication     

地下水人工回灌堵塞问题研究进展

地下水人工回灌堵塞问题的产生与回灌水质、入渗介质的矿物成分及颗粒组成特征等多种因素有关,通常根据成因将堵塞分为物理堵塞、化学堵塞和生物堵塞3种类型。大颗粒悬浮物的物理堵塞效应与机理的研究比较成熟,但对于中间颗粒,尤其是胶体颗粒物的堵塞作用机制的研究还相对比较薄弱;化学堵塞的机理复杂,影响因素众多,水文地球化学模拟技术在化学堵塞机理的研究中显示了良好的应用前景;生物堵塞主要由回灌水中细菌和藻类等微生物的繁殖和代谢导致,大量的研究集中在细菌方面,对藻类引起的堵塞问题研究尚不深入;多种堵塞的相互作用过程和作用机理是目前研究的难点问题。堵塞预测的方法主要包括3种:①指标法(如MFI、悬浮物浓度、浊度、AOC、BFR等),简单实用,但不能对堵塞演化过程进行描述或对堵塞程度进行定量表达;②经验公式法,受特定场地的条件限制,难以直接推广和利用;③解析公式法,对堵塞机理的表达更加科学、合理,但模型的建立与求解难度较大。通过合理的水质预处理技术和合理的回灌工艺,可以有效延迟堵塞发生的时间、减缓堵塞累积的程度。开发快速、高效、简单的堵塞处理技术对于延长工程使用寿命和降低经济成本具有重要的现实意义。     

Erratum to: Geochemical and environmental magnetic characteristics of high arsenic aquifer sediments from Datong Basin,northern China

Geochemical and environmental magnetic studies were carried out to identify the effect of iron oxyhydroxides on arsenic mobilization in high arsenic aquifer system. Using high arsenic sediment samples from two boreholes, specifically drilled for this study, chemical composition and magnetic properties including magnetic susceptibility, saturation remnant magnetization, and isothermal remnant magnetization were measured. Results of correlation analysis of element contents show that arsenic and iron are closely associated with each other (r ² = 0.40, α = 0.05, n = 21). In contrast, the correlation of phosphorus with iron (r = 0.11, α = 0.05, n = 21) and arsenic (r ² = 0.18, α = 0.05, n = 21) was poor, which might result from competitive adsorption of phosphorus and arsenic on the surface of Fe-oxyhydroxides. The high correlation coefficients between arsenic contents and magnetic parameters suggest that the ferrimagnetic minerals including maghemite and hematite are the dominant carrier of arsenic in aquifer sediments. The results of sequential extraction experiments also revealed the association of arsenic with reducible iron oxides, such as maghemite and hematite in aquifer sediments. Therefore, under reducing conditions, reductive dissolution and desorption of arsenic from Fe-oxyhydroxides into the aqueous phase should be the dominant geochemical processes for its enrichment in groundwater at Datong. An erratum to this article can be found at     

考虑温度变化的地下水运动方程及其在储能模型中的应用

从建立一般条件下的多孔介质液相动量守恒方程出发,较严密地堆导了考虑温度变化的地下水运动方程,并在此基础上了一个新的含水层储能模型,该模型用于上海第二承压含水层群井储能试验,取得了令人满意的结果,从而证明了高温差条件下对地下水运动方程进行修正是必要的,具有重要的理论和现实意义。     

滨海多层含水层系统中海潮引起的地下水位波动

通过对一个滨海多层含水层系统的考察,该含水层系统由上、下弱透水层和介于中间的承压含水层组成,海底露头处被淤泥层覆盖.建立了描述该系统中地下水水头随潮汐波动的数学模型,并得到其解析解.该解析解与六个基本参数有关,分别是承压含水层的海潮传播参数,淤泥层的无量纲透水系数,上下弱透层与承压含水层贮水率的比率 (无量纲)和上下弱透层的无量纲越流.当这些参数取某些特殊值时,我们的解便化简为前人考虑的几种简单情形对应的解.分析表明,承压含水层中地下水水头波幅是上、下弱透水层贮水率和越流系数的减函数,是淤泥层相对透水系数的增函数;波动相位(时滞)是上、下弱透水层贮水率和越流系数的增函数,是淤泥层相对透水系数的减函数.     

Determination of hydraulic parameters of an unconfined alluvial aquifer by the floodwave-response technique

Groundwater constitutes a vital component of the water-resource system. Adequate knowledge of aquifer parameters is of utmost importance for proper groundwater management. In the present study, an attempt has been made to critically analyze the river–aquifer interaction and to explore the practicability and reliability of the floodwave-response technique in estimating the hydraulic parameters of the Konan aquifer, Japan. The analysis of the pertinent hydrologic and hydrogeologic data revealed a strong relationship between the Monobe River stage and the groundwater levels over a major portion of the Konan basin. Inverse modeling, using the floodwave-response model at four sites, yielded high values of hydraulic diffusivity that ranged from 16 to 194 m²/s. However, the overall average aquifer diffusivity was found to be reasonable (0.7–3.5 m²/s). All the selected flood events were not found suitable for determining reasonable values of hydraulic diffusivity at a given site. Using the optimal diffusivities at two sites and the aquifer transmissivity from the pumping tests at these sites, the storage coefficient values were estimated as those of truly confined aquifers. In contrast, reasonable values of storage coefficient were obtained based on the average aquifer diffusivity estimates. The sensitivity analysis of the floodwave-response model indicated that the optimal hydraulic diffusivity is very sensitive to the distance parameters of the model, which necessitate precise measurement of these parameters. It is concluded that a judicious application of the floodwave-response technique is essential, especially in the case of unconfined aquifers.

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Resumen El agua subterránea constituye un componente vital de los sistemas de recursos hídricos. El conocimiento adecuado de los parámetros del acuífero es de suma importancia para el manejo apropiado del agua subterránea. En el presente estudio se ha realizado un intento para analizar críticamente la interacción río-acuífero y explorar la confiabilidad y utilidad de la técnica de respuesta de onda de crecida para estimar los parámetros hidráulicos del acuífero Konan, Japón. El análisis de datos hidrológicos e hidrogeológicos pertinentes muestra una relación fuerte entre el nivel del Río Monobe y los niveles de agua subterránea en gran parte de la cuenca Konan. El modelizado de inversión utilizando el modelo de respuesta de onda de crecida en cuatro sitios generó valores altos de difusividad hidráulica que varían de 16 a 194 m²/s. Sin embargo, se encontró que la difusividad promedio global del acuífero tenía valores razonables (0.7 a 3.5 m²/s). Todos los eventos de crecida seleccionados no fueron encontrados satisfactorios para determinar valores razonables de difusividad hidráulica en un sitio determinado. Utilizando las difusividades óptimas en dos sitios y la transmisividad del acuífero proveniente de pruebas de bombeo en esos sitios se estimaron valores del coeficiente de almacenamiento como los que se obtendrían para acuíferos completamente confinados. En contraste, se obtuvieron valores razonables del coeficiente de almacenamiento basados en los cálculos de difusividades promedio del acuífero. Los análisis de sensitividad del modelo de respuesta de onda de crecida indicaron que la difusividad óptima hidráulica es muy sensitiva a los parámetros de distancia del modelo por lo que se necesitan mediciones precisas de esos parámetros. Se concluye que es esencial una aplicación sensata de la técnica de respuesta de onda de crecida, especialmente en el caso de acuíferos no confinados.

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Resumé Leau souterraine constitue une composante vitale des systèmes de ressource en eau. Une connaissance adéquate des paramètres des aquifères est importante pour une gestion correcte de ces systèmes. Dans cette étude, la démarche consiste à analyser linteraction rivière–aquifère de manière critique et dexplorer la technique permettant destimer les paramètres hydrauliques de laquifère Konan, Japon. Lanalyse pertinente des données hydrologiques et hydrogéologiques révèle une relation forte entre le niveau de la rivière Monobe et les niveaux piézométriques sur une grande partie du bassin de Konan. La modélisation inverse utilisant le modèle de réponse aux vagues de crue sur quatre sites fournit des valeurs de diffusivité comprises entre 16 et 194 m²/s. Néanmoins la valeur moyenne de diffusivité est apparue raisonnable (entre 0.7 et 3.5 m²/s). Tous les évènements de crue nont pas été retenus comme permettant de calculer avec une bonne fiabilité la diffusivité sur un site donné. En utilisant les données optimales de diffusivité provenant de deux sites, et la transmissivité fournie par les essais de pompage, le coefficient demmagasinement a été déterminé et correspond bien à un aquifère confiné. Par contraste, des valeurs raisonnables de coefficient demmagasinement ont été déterminées par estimation de la diffusivité moyenne de laquifère. Lanalyse de sensibilité du modèle de réponse aux vagues de crue indique que la diffusivité hydraulique optimale est très sensible à la distance utilisée dans le modèle, qui nécessite dés lors une mesure précise. En conclusion il est essentiel que ce type dapplication doit tre judicieusement mis en oeuvre, et spécialement dans le cadre daquifères captifs.

     

深部含水层储热系统的数值模拟研究

深部含水层储热系统, 是一种以深部含水层介质为载体的“地热+”多能互补储/供能系统。该系统可将各种形式的能量储存于地下并按需求取出加以利用, 能够弥补能源供需的时空分布的不平衡, 是综合利用多种可再生能源, 实现节能减排的有效途径。深部含水层储热是一种水热型地热资源开发利用的新方式。传统的水热型地热资源开采, 受限于地热尾水回灌导致的热突破, 热田寿命有限。而利用深部含水层储能, 不但可以增强热储能力, 而且能够延长热田寿命。本研究通过数值模拟研究表明, 与传统的水热型地热系统相比, 通过采取深部含水层储热技术, 在相同开采流量下, 可以提升单井供热能力20%。其储热效率可以达到60%~90%, 能够保证更高的地热能提取率; 同时, 与传统水热型地热井寿命受限于热突破时间的情况不同, 深部含水层储热系统可以延长地热井寿命, 实现可持续开采。通过参数敏感性分析的方法进一步评估了不同参数对深部含水层储热性能的影响。通过参数研究发现, 储层渗透率和储热温度等是影响储热能力和效率的关键参数。本研究为后续开展深部含水层储热系统工程的设计与优化提供科学参考。     

A 1,800-year record of arsenic concentration in the penguin dropping sediment,Antarctic

Heavy/toxic metals have been widely investigated in the Antarctic. However, there are rare reports on arsenic up to now. Here, we analyzed a 1,800-year record of arsenic concentration in lake sediments affected by penguin droppings. We found that arsenic enriches in the penguin dropping sediments with 12.41 ± 0.45 μg/g (on dry weight), which is about two times higher than the one in the background sediments with absence of penguin. Historical change in arsenic concentration was found to significantly correlate with the fluctuation of penguin number, indicating that penguin activity will result in the enrichment of arsenic somewhere in the maritime Antarctic.     

河北矾山磷矿采空塌陷、地裂缝和含水层破坏评估与防治

矾山磷矿是华北地区大型磷矿生产矿山,为第四系孔隙水及基岩裂隙水充水矿区。本文在分析地质采矿条件基础上,对采空塌陷、地裂缝地质灾害和含水层破坏的成因进行了分析与评估,并提出了相应的防治措施。     

Geostatistical analysis of arsenic concentration in groundwater in Bangladesh using disjunctive kriging

The National Hydrochemical Survey of Bangladesh sampled the water from 3,534 tube wells for arsenic throughout most of Bangladesh. It showed that 27% of the shallow tube wells (less than 150 m deep) and 1% of the deep tube wells (more than 150 m deep) exceeded the Bangladesh standard for arsenic in drinking water (50 µg L^–1). Statistical analyses revealed the main characteristics of the arsenic distribution. Concentrations ranged from less than the detection limit (0.5 µg L^–1), to as much as 1,600 µg L^–1, though with a very skewed distribution, and with spatial dependence extending to some 180 km. Disjunctive kriging was used to estimate concentrations of arsenic in the shallow ground water and to map the probability that the national limit for arsenic in drinking water was exceeded for most of the country (the Chittagong Hill Tracts and the southern coastal region were excluded). A clear regional pattern was identified, with large probabilities in the south of the country and small probabilities in much of the north including the Pleistocene Tracts. Using these probabilities, it was estimated that approximately 35 million people are exposed to arsenic concentrations in groundwater exceeding 50 µg L^–1 and 57 million people are exposed to concentrations exceeding 10 µg L^–1 (the WHO guideline value).     

鄂尔多斯盆地白垩系含水砂岩的特征

最新水文钻孔和露头剖面调查测试资料对鄂尔多斯盆地白垩系含水砂岩的组分特征和空间分布综合研究表明,宜君-洛河含水岩组广泛分布于全盆地,为最主要的区域性含水岩组,以长石石英砂岩、长石砂岩、岩屑长石砂岩发育为主;华池-环河含水岩组分布广泛,也是很好的含水岩组,主要为长石砂岩、长石石英砂岩、岩屑长石砂岩：罗汉洞-泾川含水岩组仅局限于盆地北部和西部,是一套比较局部的含水层,主要为长石石英砂岩和岩屑石英砂岩。总体上,盆地北部白垩系含水砂岩极其发育,南部含水砂岩具多层分布的特点,厚度总体较小。     

Water supply potential and optimal exploitation capacity of karst aquifer systems

The management of groundwater flow systems in karst regions appears, at present, to be the most important procedure for solving water deficiency problems during periods of low rainfall. Faced with a lack of data for characterizing the water supply potential of karst aquifers, analyses of spring hydrographs may provide valuable indirect information regarding the structure of karst hydrogeological systems. To estimate the optimal exploitation capacities of karstic sources, a stochastic-conceptual approach was applied in case studies from the Serbian karst. Water supply potentials were initially evaluated on the basis of groundwater budgets. Further steps towards defining optimal “exploitable” regimes included analyses of storage changes in karst water reservoirs under natural conditions and calculation of the potential expansion of currently tapped sources. The results obtained through these analyses are a significant contribution to feasibility studies and aid in the avoidance of problems of overexploitation.