Assessment of geochemical and sedimentological characteristics of atmospheric dust in Shiraz,southwest Iran

Geogenic dust is commonly believed to be one of the most important environmental problems in the Middle East.The present study investigated the geochemical characteristics of atmospheric dust particles in Shiraz City(south of Iran).Atmospheric dust samples were collected through a dry collector method by using glass trays at 10 location sites in May 2018.Elemental composition was analysed through inductively coupled plasma optical emission spectrometry.Meteorological data showed that the dustiest days were usually in spring and summer,particularly in April.X-ray diffraction analysis of atmospheric dust samples indicated that the mineralogical composition of atmospheric dust was calcite+dolomite(24%)palygorskite(18%)quartz(14%)muscovite(13%)albite(11%)kaolinite(7%)gypsum(7%)zircon=anatase(3%).The high occurrence of palygorskite(16%-23%) could serve as a tracer of the source areas of dust storms from the desert of Iraq and Saudi Arabia to the South of Iran.Scanning electron microscopy indicated that the sizes of the collected dust varied from 50 μm to0.8 μm,but 10 μm was the predominant size.The atmospheric dust collected had prismatic trigonal-rhombohedral crystals and semi-rounded irregular shapes.Moreover,diatoms were detected in several samples,suggesting that emissions from dry-bed lakes,such as Hoor Al-Azim Wetland(located in the southwest of Iran),also contributed to the dust load.Backward trajectory simulations were performed at the date of sampling by using the NOAA HYSPLIT model.Results showed that the sources of atmospheric dust in the study area were the eastern area of Iraq,eastern desert of Saudi Arabia,Kuwait and Khuzestan Province.The Ca/Al ratio of the collected samples(1.14) was different from the upper continental crust(UCC) value(UCC=0.37),whereas Mg/A1(0.29),K/Al(0.22) and Ti/Al(0.07) ratios were close to the UCC value(0.04).This condition favours desert calcisols as the main mineral dust sources.Analysis of the crustal enrichment factor(EF_(crustal)) revealed geogenic sources for V,Mo,Pb,Sr,Cu and Zn(2),whereas anthropogenic sources affected As,Cd,Cr and Ni.     

闽西南地区才溪岩体锆石SHRIMP定年及其地球化学特征

锆石SHRIMP年龄测试结果表明,闽西南地区才溪岩体的形成年龄为150±3Ma。才溪二长花岗岩富硅、富碱,弱过铝。岩石富集LREE,具Eu负异常,*Eu值为0.54~0.66,亏损Ba、Nb、Ta、Sr、P、Eu、Ti。(87Sr/86Sr)i值较高,为0.710462~0.712265,εNd(t)为-8.68~-9.81,t2DM为1.51~1.61Ga。岩石中黑云母富铝、镁,在Fe2 -Fe3 -Mg2 三角图上落入壳幔混源区。根据岩体地质学、地球化学特征,结合岩石学和矿物学特征认为,才溪二长花岗岩是由中元古代地壳物质熔融形成的壳源型花岗岩,在岩浆形成过程中有少量幔源物质的加入,形成于由挤压向伸展过渡的构造环境。     

Heavy metal concentrations in water and surface sediments of Maharlou Lake, SE of Shiraz, Iran

The main objective of this study is to evaluate trace metal distribution and identify their sources in the Maharlou Lake. Trace metals （Cr, Co, Ni, Cu, Zn, Cd, Pb） and major elements （A1, Ca, Fe, K, Mg, Mn, Na, P） were investigated in water and surface sediments. There was a negative relationship between the depth of water and heavy metal concentration. Metal concentrations in water and sediment samples show a high variability and decrease in this order： Al〉Fe〉Ni〉Co〉Pb〉Zn〉Cu〉Mn〉Cd. In the northern parts of the lake, especially at the inflow of drains and the Khoshk River of Shiraz City, metal concentrations are higher in both water and sediment samples. In order to assess the heavy metal enrichment in sediment samples, trace metal concentrations were normalized for Al. Except for Mn, all metals are enriched relative to average crust and average sedimentary rocks. Also, the results showed that stations located at the northern coast of the lake, have higher enrichment factors （EF） than the other stations. The results of this study showed that the Khoshk River and other drains are the main pollutant sources of the Maharluo Lake.     

新疆伽师铜矿床地质-地球化学特征及矿床成因

新疆伽师铜矿床产于新生界古近系苏维依组中，通过对新疆伽师铜矿床地质特征、赋矿的苏维依组岩石化学、微量元素和稀土元素地球化学特征研究表明，伽师铜矿区富集Pb、Cu、Ag、As元素，具有较好的铜成矿背景；赋矿的古近系苏维依组的物源区构造环境为活动大陆边缘；Cu元素主要来自于上白垩统巴什基奇克组的风化产物；铜矿床的形成明显受地层、岩性、古气候环境和构造的控制，属古近系潟湖相沉积作用和构造富集作用有关的砂岩型沉积-构造富集型铜矿床。     

A change-detection application on the evolution of Kahak playa (South Khorasan province, Iran)

Kahak salt playa in South Khorasan province of Iran, have special geomorphological characteristics by the presence of ephemeral saline lakes, wetlands, salt crusts, surface accumulations of salt and zones of patterned ground. Salt crusts in the soil surface are unique in the region and have laminated horizons in the playa soil. Soil-surface salt accumulations are dominated by NaCl and gypsum. It has been found that distribution of chemical soluble is not uniform across the playa landscape, and this result influences on the variety form of patterned ground. In this study, the percent changes in some of the chemical elements such as NaCl, gypsum and also brine extent have been calculated in the playa. Indicating changes in Kahak salt playa is the main aim of this study by using remote sensing and GIS techniques. In this paper, techniques such as spectral un-mixing, maximum likelihood classification, band rationing, fuzzy classification and correlation relationships are discussed. This contribution presents modeling of temporal and spatial changes of salinity and playa developing using combined approaches that incorporate different data-fusion and data-integration techniques for two periods of date. Furthermore, percent changes in the surface-patterned ground of the playa have been calculated using texture and pattern analysis of the PCA1. Results have revealed that, in the playa developing, chemical materials such as sodium, NaCl, gypsum and also brine extent are positively correlated with each other and the most increased changes are related to gypsum and the most decreased changes are related to the NaCl. Also changes in the amount of agricultural area in the playa-lakes margin, show low effects in the desertification process.     

贵州滥木厂金汞铊矿床地质地球化学特征及其地质意义北大核心CSCD

黔西南滥木厂矿床是世界上罕见的汞(大型)-铊(大型)-金(小型)多金属矿床,具有独特的成矿元素分带现象。本文通过系统研究滥木厂矿床金、汞-铊、汞、铊矿石及围岩样品的主量、微量及稀土元素地球化学特征,对比分析不同类型矿化的成矿环境,以探讨成矿元素共生分离机制。研究表明,相对于滥木厂矿床的围岩样品,同岩性的各类矿化岩石的SiO_(2)含量显著增加,CaO和MgO含量之和明显降低,表明成矿过程中伴随广泛的硅化和去碳酸盐化作用,K_(2)O-Al_(2)O_(3)投图表明区内存在显著的高岭石化作用。各类矿石与围岩均显示Au、As、Sb、Hg、T1和轻稀土富集特征,且具有相似的稀土配分模式;但成矿元素分布于不同的特征因子中,并表现出富集程度的差异,表明成矿物质继承了原岩的部分地球化学特征,在成矿过程中发生了分离。Y/Ho比值在金矿石中普遍高于28,在其它矿化类型岩石中均低于28,反映金成矿热液富含氟络合物,汞和铊成矿热液以碳酸氢根的络合物为主。各类矿石通常具有Ce正异常,铊、汞-铊和金矿石普遍显示Eu正异常,汞矿石呈现轻微的Eu负异常,表明成矿环境处于相对氧化的状态,并具氧化还原波动性。综合元素地球化学特征与收集的碳、氢、氧、硫、铅同位素成果,认为滥木厂矿床金、汞、铊矿化的成矿物质及成矿流体具有多源性,各类矿化在温度、氧逸度、酸碱性及配合物类型等方面的差异可能是成矿元素产生分异的重要原因。     

Geochronological and geochemical characteristics of fractionated I-type granites associated with the skarn mineralization in the Sangan mining region,NE Iran

The Sangan mining region, which has a proven reserve of approximately 1000 Mt of 53% iron ore, is located in the Khaf-Kashmar-Bardeskan volcano-plutonic belt in northeastern Iran. The geological units in the eastern zone of the Sangan region consist of Precambrian schists, Jurassic sedimentary rocks and Tertiary subvolcanic granitoid intrusions. Iron skarn mineralization consists of stratiform and massive bodies in the carbonate rocks that are adjacent to the granitoid intrusions. Detailed field mapping revealed that 39-Ma syenitic intrusive bodies in the western and central zones of the Sangan region were the main sources of heat and fluid for the iron mineralization.A Mid-Cenozoic biotite granite pluton is associated with the eastern anomalies. However, field relationships suggested that this pluton is not the source of the metals, heat or fluids that were responsible for the iron mineralization. This pluton is rich in silica (SiO₂ contents from 66.4 to 79.1 wt%) and is characterized by high-K series with metaluminous to slightly peraluminous affinity.Geochronological (U-Pb zircon method) and geochemical data, including major and trace elements and Sr-Nd-Pb isotopes, define the complex origin of these plutons, which consist of alkaline granitoids that appear to be A-type in character but also show I-type affinity.New geochemical and isotopic data from plutons in the eastern anomalies and data from previous studies of the western and central anomalies and the southeastern intrusive rocks in the Sangan region show that these plutons have close affiliation with lower to upper crust-derived melts and were largely modified into highly fractionated I-type granite. These rocks were derived from and emplaced by varying degrees of partial melting during the Middle Eocene (Bartonian to Lutetian, 38.3–43.9 Ma) from a crustal protolith in a normal to mature volcanic continental arc setting.The Sangan granitoids were produced from crustal assimilation by a heat source from mantle melts, which are associated with the Kashmar-Neotethyan slab that subducted under Eurasia. The Khaf-Kashmar-Bardeskan igneous rocks reflect an active Cenozoic plate margin that was related to the closure of the Kashmar-Neotethyan Sea between the Lut and Eurasia blocks because of the continuous convergence between the Arabian and Iran plates during the Late Cretaceous–Early Paleocene.     

江西潭港流纹英安岩LA-ICP-MS锆石U-Pb定年及地球化学特征

江西潭港地区流纹英安岩的LA-ICP-MS锆石U-Pb年龄为(136.2±1.5)Ma,属早白垩世火山-岩浆活动产物。其地球化学特征是:富硅(66.82%~68.04%)、高碱(7.56%~7.73%)、高Al_2O_3(14.91%~15.17%)、准铝—弱过铝质(A/CNK=0.999~1.042);富集大离子亲石元素和轻稀土元素,亏损高场强元素;稀土元素配分曲线模式图为右倾型,轻重稀土分异程度较高(LREE/HREE的平均值为10.04),轻稀土内部分馏程度相对重稀土内部分馏程度高,中等程度的Eu负异常(δEu平均值为0.48)。与相山流纹英安(斑)岩形成时代一致,地球化学特征相同,表明两者成岩物质来源相同,属陆壳硅铝层物质重熔演化产物,且为同一岩浆活动产物,即前人所指的相山第一旋回火山活动的产物。通过地质条件对比与分析,笔者认为潭港地区具有一定的铀矿成矿潜力。     

The nature and provenance of Golestan loess deposits in northeast Iran

Mineralogical, textural, geochemical, and weathering characteristics of loess deposits in Golestan province of Iran suggest that they are mostly derived from felsic igneous rocks and are related to Quaternary palaeoclimate. Whole‐rock analyses indicate heavy minerals such as zircon, tourmaline and phyllosillicate minerals (e.g. muscovite, chlorite, illite) exert a significant control on the chemical composition. The loess samples display uniform chemical composition, indicative of similar alteration history. Chemical index of alteration suggests a weak to moderate degree of weathering in a felsic source area. Scanning electron micrographs of quartz grains reveal abundant silt‐sized quartz particles, a result of glacial grinding during the Late Pleistocene in Central Asia. Subsequently, these silt particles were transported from Central Asia to their depositional site by wind and paraglacial processes. Local topography of northeast Iran (Alborz Mountains) acted as a major barrier, entrapping the airborne particles on the plains of Golestan province. Copyright © 2012 John Wiley & Sons, Ltd.     

Cenozoic post-collisional brittle tectonic history and stress reorientation in the High Zagros Belt (Iran, Fars Province)

The Zagros fold-and-thrust belt of SW-Iran is among the youngest continental collision zones on Earth. Collision is thought to have occurred in the late Oligocene–early Miocene, followed by continental shortening. The High Zagros Belt (HZB) presents a Neogene imbricate structure that has affected the thick sedimentary cover of the former Arabian continental passive margin. The HZB of interior Fars marks the innermost part of SE-Zagros, trending NW–SE, that is characterised by higher elevation, lack of seismicity, and no evident active crustal shortening with respect to the outer (SW) parts. This study examines the brittle structures that developed during the mountain building process to decipher the history of polyphase deformation and variations in compressive tectonic fields since the onset of collision. Analytic inversion techniques enabled us to determine and separate different brittle tectonic regimes in terms of stress tensors. Various strike–slip, compressional, and tensional stress regimes are thus identified with different stress fields. Brittle tectonic analyses were carried out to reconstruct possible geometrical relationships between different structures and to establish relative chronologies of corresponding stress fields, considering the folding process. Results indicate that in the studied area, the main fold and thrust structure developed in a general compressional stress regime with an average N032° direction of σ₁ stress axis during the Miocene. Strike–slip structures were generated under three successive strike–slip stress regimes with different σ₁ directions in the early Miocene (N053°), late Miocene–early Pliocene (N026°), and post-Pliocene (N002°), evolving from pre-fold to post-fold faulting. Tensional structures also developed as a function of the evolving stress regimes. Our reconstruction of stress fields suggests an anticlockwise reorientation of the horizontal σ₁ axis since the onset of collision and a significant change in vertical stress from σ₃ to σ₂ since the late stage of folding and thrusting. A late right-lateral reactivation was also observed on some pre-existing belt-parallel brittle structures, especially along the reverse fault systems, consistent with the recent N–S plate convergence. However, this feature was not reflected by large structures in the HZB of interior Fars. The results should not be extrapolated to the entire Zagros belt, where the deformation front has propagated from inner to outer zones during the younger events.     

Geological and geochemical characteristics of the Baimazhai Ni-Cu-（PGE） sulphide deposit in Yunnan, China

The sulphide ores of the Baimazhai deposit, although typically orthomagmatic, locally exhibit peculiar textural features and are intimately associated with hydrothermal minerals, such as biotite, amphibole and chlorite. This association suggests that the magmatic sulphide ores were subjected to hydrothermal alteration and subsequent redistribution, resulting in the observed textural features. Geochemically, the Baimazhai sulphide ores are enriched in Cu, Pd and Au, which,according to previous studies, reflects the action of hydrothermal fluids. Interestingly, Ar-Ar dating yielded the plateau ages of about 160–170 Ma, which are at odds with the established Permian age of the Emeishan large igneous province. We interpreted these younger ages as due to thermal resetting during post-Permian tectonothermal events. We have proposed a model in which tectonic movements and hydrothermal fluids related to these events modified the pre-existing magmatic sulphides. Given the degree of overprint, we suggested two possible scenarios: 1) the sulphide disseminations that surround the massive magmatic ores are the result of deformation and hydrothermal alteration; and 2) there were both magmatic massive and disseminated sulphides, in which case the scale and relocation of remobilization would have been smaller, but still detectable.     

西藏羌塘盆地上侏罗统索瓦组油藏发现及地球化学特征

在青藏高原羌塘盆地发现规模较大的上侏罗统索瓦组油藏带,主要分布在双湖南、鸭湖、才多茶卡及阿木错一带。利用抽提、分离、GC—MS等地球化学分析手段详细分析了油苗的族组分、有机质来源,沉积环境以及成熟度。生物标志化合物参数分析表明油藏中有机质沉积环境为具有一定盐度的还原性较强的环境,其中,才多茶卡油藏有机质的来源主要为低等水生生物;而双湖南、鸭湖油藏有机质来源则具有低等水生生物和高等植物共同输入;阿木错油藏中有机质以陆源有机质的贡献为主。成熟度参数分析显示油藏样品有机质热演化已达到低成熟—成熟阶段,说明烃源岩的成熟度均已达到生油门限,暗示这些烃源岩曾经有过一定规模的生烃。双湖地区古油藏普遍受自北向南的逆冲推覆构造影响,而位于逆冲推覆构造根带的北羌塘地块索瓦组地层出露较好且具有良好圈闭条件。因此,双湖地区索瓦组古油藏的发现及地球化学特征对于北羌塘盆地上侏罗统油气资源的勘探具有重要指示意义。     

安徽宣城茶亭铜金矿床地质和地球化学特征及成因

安徽宣城茶亭铜金矿床是长江中下游成矿带浅覆盖区新发现的一个大型矿床,产于南陵-宣城中-新生代火山-沉积盆地中。矿床地质研究表明:矿体赋存于早白垩世石英闪长玢岩侵入体中,矿化强烈部位与隐爆角砾岩筒发育部位明显重叠而且范围略大;矿床围岩蚀变发育,以硅化、钾长石化、黑云母化、绢(白)云母化、黄铁矿化为主,分带性较为明显,矽卡岩化、绿泥石化、硬石膏化、碳酸盐化和高岭石化等蚀变仅在局部呈条带状、团块状分布;矿石具角砾状、脉状、细脉-网脉状、细粒浸染状构造和交代残余结构、固溶体分离结构等,其中,角砾状和脉状矿石中常常发育磁铁矿-赤铁矿和矽卡岩矿物石榴子石、透辉石等,硬石膏尤其发育,甚至形成硬石膏岩;矿石中金属矿物有黄铁矿和黄铜矿及少量斑铜矿、黝铜矿、砷黝铜矿等;隐爆角砾岩的角砾成分以石英闪长玢岩为主,胶结物主要为岩屑或岩粉及热液矿物两类。矿床流体包裹体研究表明:矿石石英中发育液相、气液相和含子晶气液相包裹体,气相成分以水为主;含子晶气液相包裹体主要见于成矿较早阶段与具有裂纹的黄铁矿共生的石英中,均一温度为360～420℃,流体盐度较高,而铜金主成矿阶段发育气液相和液相包裹体,均一温度介于270～300℃和190～220℃区间,相应的成矿流体的盐度和密度较低。矿床H-O、C-O和S、Pb同位素组成特征指示成矿流体、成矿金属元素及其化合元素主要来自于岩浆或岩浆岩,沉积地层和大气降水对成矿亦有一定的贡献,但所起作用相对较小。黄铁矿Re-Os同位素年龄与赋矿石英闪长玢岩锆石U-Pb年龄在误差范围内一致。综合矿床地质和地球化学特征,认为宣城茶亭铜金矿床与斑岩型和火山-次火山岩型(浅成低温热液型)矿床既有相似之处,也有明显的差异,因而确定为一个与早白垩世石英闪长玢岩浅成侵入体有关的隐爆角砾岩型矿床,该矿床是长江中下游成矿带中的一个新类型矿床。     

川西木落寨稀土矿床年代学、地球化学与成矿特征

木落寨矿床位于川西冕宁-德昌稀土成矿带的北部,郑家梁子矿段是该矿床的主要成矿段。野外勘查发现,郑家梁子矿段主要的赋矿岩石是大理岩,其中发育的张性断裂充填大量矿脉,与矿带中其他矿床以正长岩为赋矿围岩的特征明显不同,而大理岩是否是成矿物质的主要来源尚不清楚。为进一步明确大理岩、正长岩和稀土物质来源之间的关系,文章对相关岩石和矿石进行地球化学特征对比分析。正长岩全岩稀土元素含量为1211×10-6～2974×10-6,稀土元素配分曲线呈轻稀土元素富集,重稀土元素亏损的特征。近矿蚀变大理岩稀土元素配分曲线整体呈右倾,稀土元素总量为1131×10-6～1935×10-6,而远矿新鲜大理岩稀土元素总量为8.20×10-6～8.69×10-6,由此可见,大理岩很可能不是稀土物质的主要来源。新鲜大理岩的δ13CV-PDB变化范围为1.3‰～1.6‰,δ18OV-SMOW介于23.2‰～23.7‰之间,显示其是海相碳酸盐岩变质的产物,蚀变大理岩的δ13CV-PDB变化范围为0.4‰～0.7‰,δ18OV-SMOW介于15.7‰～16‰之间,显示其受热液蚀变影响,并经历碳酸盐的溶解作用。新鲜大理岩与蚀变大理岩的δ13CV-PDB值变化较小(0.4‰～1.6‰),说明这2种大理岩为同源,近矿大理岩可能只是碳酸盐岩溶解蚀变的产物。矿脉中的方解石δ13CV-PDB变化范围为-4.6‰～-4.7‰,δ18OV-SMOW介于11.8‰～12.5‰之间,显示出碳酸岩岩浆经历低温蚀变的过程,证明矿脉与大理岩没有明显物质来源关系。矿石中氟碳铈矿的206Pb/204Pb、207Pb/204Pb与208Pb/204Pb分别为18.3143～18.3629、15.6243～15.6349和38.6197～38.7309,正长岩的206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.3233～18.3568,15.6298～15.6360和38.6664～38.6880。正长岩和氟碳铈矿的铅同位素特征一致,显示稀土的物质来源很可能是正长岩或隐伏的碳酸岩。本次研究选取典型矿石中与氟碳铈矿密切共生的金云母进行Ar-Ar同位素定年。鉴于矿石中的云母和氟碳铈矿并不存在多期次性,研究测得该矿段金云母的40Ar/39Ar坪年龄为(27.6±0.2)Ma,可以很好地代表成矿时代。     

Magmatic garnet in the Triassic (215 Ma) Dehnow pluton of NE Iran and its petrogenetic significance

The Triassic Dehnow pluton of NE Iran is a garnet-bearing I-type calc-alkaline metaluminous diorite-tonalite-granodiorite intrusion. The parental magma formed as the result of partial melting of intermediate to felsic rocks in the lower crust. Petrological and geochemical evidence, which indicates a magmatic origin for the garnet, includes: large size (~10–20 mm) of crystals, absence of reaction rims, a distinct composition from garnet in adjacent metapelitic rocks, and similarity in the composition of mineral inclusions (biotite, hornblende) in the garnet and in the matrix. Absence of garnet-bearing enclaves in the pluton and lack of sillimanite (fibrolite) and cordierite inclusions in magmatic garnet suggests that the garnet was not produced by assimilation of meta-sedimentary country rocks. Also, the δ¹⁸O values of garnet in the pluton (8.3–8.7‰) are significantly lower than δ¹⁸O values of garnet in the metapelitic rocks (12.5–13.1‰). Amphibole-plagioclase and garnet-biotite thermometers indicate crystallization temperatures of 708°C and 790°C, respectively. A temperature of 692°C obtained by quartz-garnet oxygen isotope thermometry points to a closure temperature for oxygen diffusion in garnet. The composition of epidote (X_ep) and garnet (X_adr) indicates ~800°C for the crystallization temperature of these minerals. Elevated andradite content in the rims of garnet suggests that oxygen fugacity increased during crystallization.     

鄂尔多斯盆地南部旬宜地区中生界延长组天然气地球化学特征及气源分析

鄂尔多斯盆地旬宜地区延长组主研究区几乎全部为产油井,而位于西南部的旬19井、郎字号等多口井见天然气流,这与延长组主研究区揭示的规律存在矛盾,气体来源不明。根据天然气组分、C同位素、C同位素序列等特征,分析认为采集的气样地球化学特征与古生界煤型气存在较大差别,为热成因气中低成熟度阶段的油型伴生气,气源单一,来自于中生界长7烃源岩。因此,旬宜研究区延长组天然气勘探具有一定的潜力,是值得重点关注的对象。     

刚果（金）加丹加省科卢韦齐铜矿床地质特征及矿床成因

科卢韦齐(Kolwezi)铜矿床位于刚果(金)南部Kolwezi市区边部西南方向。通过研究铜矿体所在地层矿化元素的含量及变化系数,得出地层与矿体矿化特征的一致性。查明了矿床规模、矿体形态产状及矿物共生组合特征、物质成分特征、结构构造特征,并对矿物生成世代进行了详细划分,加深了对矿床成矿地质特征的认识。在前人研究的基础上,提出科卢韦齐铜矿床属于热液变质改造沉积型砂页岩铜(钴)矿床,具有典型的层控特征。     

西藏谢通门雄村地区洞嘎金矿赋矿凝灰岩的年代学和地球化学特征

西藏谢通门县雄村地区洞嘎金矿作为南拉萨地体较早发现的独立金矿,其成矿作用研究较为薄弱。笔者等以洞嘎金矿赋矿凝灰岩为研究对象,开展了岩相学、年代学、地球化学和Hf同位素特征研究,探讨洞嘎金矿赋矿凝灰岩的岩石成因及构造背景,揭示凝灰岩对成矿的控制作用。LA- ICP- MS锆石U- Pb定年结果显示,凝灰岩结晶年龄为185. 1 ± 1. 9 Ma（MSWD = 0. 48）,成岩时代为早侏罗世;主量元素地球化学特征显示K2O/Na2O值（2. 91 ~ 12. 3）较高,属于钙碱性系列;微量元素地球化学特征显示富集大离子亲石元素（如Sr、Ba）和轻稀土元素（LREEs）,亏损高场强元素（如Nb、Ta、Ti等）和重稀土元素（HREEs）。结合微量元素构造环境判别图解,认为凝灰岩形成于新特提斯洋洋壳北向俯冲相关的大洋岛弧环境。另外,凝灰岩以Nb/Ta值为14. 0 ~ 17. 8、La/Nb平均值<2. 50、Zr/Ba平均值为0. 31为特征,具有较高的正的εHf(t)（+ 8. 05 ~ + 14. 2）,暗示凝灰岩岩浆源区为受到新特提斯俯冲洋壳释放的流体交代的亏损软流圈地幔楔;岩浆上升侵位的过程中未受到地壳物质的混染,主要经历了橄榄石和单斜辉石结晶分异。洞嘎金矿赋矿凝灰岩中的裂隙构造不仅为洞嘎金矿的含矿热液运移提供了空间,而且也为矿质的沉淀提供了场所;同时,凝灰岩也起到了盖层作用,保护矿床形成后免受剥蚀作用的影响。综合分析认为,洞嘎金矿形成于新特提斯洋北向俯冲的大洋岛弧环境,是斑岩型铜金矿床外侧的热液脉型金矿体。     

西藏申扎西南部甲岗雪山钨钼（铋）矿区墓若二长花岗岩体的地球化学特征

甲岗雪山钨钼（铋）矿床成矿作用受嘎若二长花岗岩体的控制。地球化学特征研究结果表明，嘎若岩体属于钙碱性岩系，为S型花岗岩。结合区域岩浆活动演化历史，判定嘎若岩体形成于碰撞挤压造山作用以后的陆内拉伸构造环境，源区具有壳幔混合带的性质。