A new high‐precision 40Ar/39Ar age for the Rochechouart impact structure: At least 5 Ma older than the Triassic–Jurassic boundary

The Rochechourt impact structure in south‐central France, with maximum diameter of 40–50 km, has previously been dated to within 1% uncertainty of the Triassic–Jurassic boundary, at which time ~30% of global genera became extinct. To evaluate the temporal relationship between the impact and the Triassic–Jurassic boundary at high precision, we have re‐examined the structure's age using multicollector ARGUS‐V ⁴⁰Ar/³⁹Ar mass spectrometry. Results from four aliquots of impact melt are highly reproducible, and yield an age of 206.92 ± 0.20/0.32 Ma (2σ, full analytical/external uncertainties). Thus, the Rochechouart impact structure predates the Triassic–Jurassic boundary by 5.6 ± 0.4 Ma and so is not temporally linked to the mass extinction. Rochechouart has formerly been proposed to be part of a multiple impact event, but when compared with new ages from the other purported “paired” structures, the results provide no evidence for synchronous impacts in the Late Triassic. The widespread Central Atlantic Magmatic Province flood basalts remain the most likely cause of the Triassic–Jurassic mass extinction.     

A Rhaetian 40Ar/39Ar age for the Rochechouart impact structure (France) and implications for the latest Triassic sedimentary record

Abstract– ⁴⁰Ar/³⁹Ar dating of potassium feldspar (primary spherulitic‐blocky and secondary idiomorphic K‐feldspar) separated from impact‐metamorphosed gneiss found near Videix in the western central part of the Rochechouart impact structure (NW Massif Central, France) yielded a Rhaetian combined age of 201 ± 2 Ma (2σ), indistinguishable within uncertainty from the age of the Triassic/Jurassic boundary. Ballen quartz intergrown with the primary K‐feldspar indicates post‐shock temperatures exceeding approximately 1000 °C that affected the precursor gneiss. Geochemically, both feldspar types represent essentially pure potassium end‐members. Apart from the approximately 15 km diameter impact deposit area, the youngest crystallization age known for basement rocks in this part of the Massif Central is approximately 300 Ma. No endogenic magmatic‐thermal events are known to have occurred later in this region. The K‐feldspar recrystallized from local feldspar melts and superimposed post‐shock hydrothermal crystallization, probably within some thousands of years after the impact. It is, therefore, suggested that the ⁴⁰Ar/³⁹Ar age for the Videix gneiss (as a potassic “impact metasomatite”) dates the Rochechouart impact, in consistence with evidence for K‐metasomatism in the Rochechouart impactites. The new age value is distinctly younger than the previously obtained Karnian–Norian age for Rochechouart and, thus, contradicts the Late Triassic multiple impact theory postulated some years ago. In agreement with the paleogeographic conditions in the western Tethys domain around the Triassic/Jurassic boundary, the near‐coastal to shallow marine Rochechouart impact is compatible with the formation of seismites and tsunami deposits in the latest Triassic of the British Isles and possible related deposits in other parts of Europe.     

Laser probe argon-40/argon-39 dating of coesite- and stishovite-bearing pseudotachylytes and the age of the Vredefort impact event

Abstract— Age determinations have been made on pseudotachylytic rocks from the controversial Vredefort structure of South Africa using the laser microprobe ⁴⁰Ar/³⁹Ar dating technique. Coesite- and stishovitebearing veins in a quartzite from the Central Rand Group of the collar rocks were dated using a 10-μm diameter focused ultra-violet laser beam. These yielded a weighted mean age of 2027 ± 18 Ma (2σ). Six pseudotachylytes, sampled from four different locations within the Outer Granite Gneiss of the core, were dated using an 50–100-μm diameter focused infrared laser beam. These pseudotachylytes exhibit altered vein margins with apparent ages considerably younger than ages obtained from the fresher centres of veins. The best weighted mean pseudotachylyte matrix age obtained was 2018 ± 14 Ma (2σ). Most of the clasts within the pseudotachylyte matrices retain significantly older (e.g., Archean) ages, indicative of their parent rock history. Our results show that five of the seven dated samples possess matrix ages of ～2000 Ma, similar to the age of the Granophyre (Walraven et al., 1990), a supposed impact melt rock (French and Nielsen, 1990). The dating of coesite- and stishovite-bearing veins equates the shock event with pseudotachylyte formation, generation of the Granophyre and creation of the Vredefort structure. The results affirm that the Vredefort Dome is a meteorite impact structure and show that it formed at 2018 ± 14 Ma (2σ).     

A Middle‐Late Triassic 40Ar/39Ar age for the Paasselkä impact structure (SE Finland)

Abstract– ⁴⁰Ar/³⁹Ar dating of recrystallized feldspar glass particles separated from clast‐rich impact melt rocks from the approximately 10 km Paasselkä impact structure (SE Finland) yielded a Middle to Late Triassic (Ladinian‐Karnian) pseudo‐plateau age of 228.7 ± 3.0 (3.4) Ma (2σ). This new age makes Paasselkä the first known Triassic impact structure dated by isotopic methods on the Baltic Shield. The new Paasselkä impact age is, within uncertainty, coeval with isotopic ages recently obtained for the Lake Saint Martin impact structure in Canada, indicating a new Middle to Late Triassic impact crater population on Earth. The comparatively small crater size, however, suggests no relationship between the Paasselkä impact and a postulated extinction event at the Middle/Late Triassic boundary.     

A Carnian 40Ar/39Ar age for the Paasselkä impact structure (SE Finland)—An update

A recrystallized band of pale feldspathic impact melt in a gneissic impact breccia from the approximately 10 km Paasselkä impact structure in southeast Finland was dated via ⁴⁰Ar/³⁹Ar step‐heating. The newly obtained plateau age of 228.7 ± 1.8 (2.2) Ma (2σ) (MSWD = 0.32; p = 0.93) is equal to the previously published pseudoplateau age of 228.7 ± 3.0 (3.4) (2σ) for the impact event. According to the current international chronostratigraphic chart and using the most recent published suggestions for the K decay constants, a Carnian (Late Triassic) age for the Paasselkä impact structure of 231.0 ± 1.8 (2.2) Ma (2σ) is calculated and considered the most precise and accurate age for this impact structure. The new plateau age for Paasselkä confirms the previous dating result but is, based on its internal statistics, much more compelling.     

Laser argon dating of melt breccias from the Siljan impact structure,Sweden: Implications for a possible relationship to Late Devonian extinction events

Abstract— In earlier studies, the 65‐75 km diameter Siljan impact structure in Sweden has been linked to the Late Devonian mass extinction event. The Siljan impact event has previously been dated by K‐Ar and Ar‐Ar chronology at 342‐368 Ma, with the commonly quoted age being 362.7 ± 2.2 Ma (2 s?, recalculated using currently accepted decay constants). Until recently, the accepted age for the Frasnian/Famennian boundary and associated extinction event was 364 Ma, which is within error limits of this earlier Siljan age. Here we report new Ar‐Ar ages extracted by laser spot and laser step heating techniques for several melt breccia samples from Siljan (interpreted to be impact melt breccia). The analytical results show some scatter, which is greater in samples with more extensive alteration; these samples generally yield younger ages. The two samples with the least alteration yield the most reproducible weighted mean ages: one yielded a laser spot age of 377.2 ± 2.5 Ma (95% confidence limits) and the other yielded both a laser spot age of 376.1 ± 2.8 Ma (95% confidence limits) and a laser stepped heating plateau age over 70.6% ³⁹Ar release of 377.5 ± 2.4 Ma (2 s?). Our conservative estimate for the age of Siljan is 377 ± 2 Ma (95% confidence limits), which is significantly different from both the previously accepted age for the Frasnian/Famennian (F/F) boundary and the previously quoted age of Siljan. However, the age of the F/F boundary has recently been revised to 374.5 ± 2.6 Ma by the International Commission for Stratigraphy, which is, within error, the same as our new age. However, the currently available age data are not proof that there was a connection between the Siljan impact event and the F/F boundary extinction. This new result highlights the dual problems of dating meteorite impacts where fine‐grained melt rocks are often all that can be isotopically dated, and constraining the absolute age of biostratigraphic boundaries, which can only be constrained by age extrapolation. Further work is required to develop and improve the terrestrial impact age record and test whether or not the terrestrial impact flux increased significantly at certain times, perhaps resulting in major extinction events in Earth's biostratigraphic record.     

High resolution U‐Pb ages of Ca‐phosphates in Apollo 14 breccias: Implications for the age of the Imbrium impact

Previous age estimates of the Imbrium impact range from 3770 to 3920 Ma, with the latter being the most commonly accepted age of this basin‐forming event. The occurrence of Ca‐phosphates in Apollo 14 breccias, interpreted to represent ejecta formed by this impact, provides a new opportunity to date the Imbrium event as well as refining the impact history of the Moon. We present new precise U‐Pb analyses of Ca‐phosphates from impact breccia sample 14311 that are concordant and give a reliable weighted average age of 3938 ± 4 Ma (2σ). Comparison with previously published U‐Pb data on phosphate from Apollo 14 samples indicate that all ages are statistically similar and suggest phosphates could have been formed by the same impact at 3934 Ma ± 3 Ma (2σ). However, this age is older than the 3770 to 3920 Ma range determined for other samples and also interpreted as formed during the Imbrium impact. This suggests that several impacts occurred during a 20–30 Ma period around 3900 Ma and formed breccias sampled by the Apollo missions.     

Laser probe argon-40/argon-39 dating of pseudotachylyte from the Sudbury Structure: Evidence for postimpact thermal overprinting in the North Range

Abstract— Ten pseudotachylyte samples from the North Range of the 1850 Ma Sudbury impact structure have been analyzed by the ⁴⁰Ar/³⁹Ar laser spot fusion method. Field and petrological evidence indicate that the pseudotachylytes were formed at 1850 Ma by comminution and frictional melting due to impact-induced faulting. The cryptocrystalline to microcrystalline grain size (<30 μm) of the pseudotachylyte matrices and the predominance of orthoclase as the main K-bearing phase, have rendered the rocks particularly susceptible to Ar loss. The age determinations range from ～1850 to ～1000 Ma, with some samples yielding multiple ages that cannot be correlated with known geological events in the area. However, if the finite-difference algorithm of Wheeler (1996) is used to calculate combined Ar loss and the accumulation of radiogenic Ar for the K-bearing phases, it is possible to reproduce the range of observed ages. The model infers that the long-term volume diffusion of Ar has occurred and that, as a result, the Ar system cannot be treated with a conventional closure temperature approach. The algorithm requires burial of the impact structure to 5–6 km depth and 160–180 °C at 1850 Ma, followed by exhumation at ～1000 Ma. These ages may be equated with two events: Penokean thin-skinned overthrusting in the North Range, immediately following impact, and exhumation ～850 Ma later, coincident with the Grenville orogeny to the southeast. The results suggest that, contrary to previously accepted paradigms, the North Range has been affected by a protracted period of postimpact, low-grade thermal metamorphism. If these events also involved tectonic shortening within the North Range (as has been documented for the South Range), then the original size of the Sudbury impact structure has been underestimated.     

In situ U–Pb analysis of shocked zircon from the Charlevoix impact structure,Québec,Canada

Laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U–Pb geochronology of shocked zircon grains in a vesicular‐fluidal impact melt rock from the ≥54 km Charlevoix impact structure, Québec, Canada, suggests an Ordovician to Silurian age of 450 ± 20 Ma for the impact. This age is anchored by concordant U–Pb results of ~450 Ma for a U‐rich, cryptocrystalline zircon grain in the melt rock, interpreted as a recrystallized metamict zircon crystal; the U–Th–Pb system of the metamict grain was seemingly chronometrically reset by the Charlevoix impact, but withstood later tectonometamorphic events. The new zircon age for Charlevoix is in agreement with a stratigraphically constrained Late Ordovician maximum age of ~453 Ma and corroborates earlier suggestions that the impact occurred most likely in the Ordovician, and not ~100 Myr later, as indicated by previous K/Ar and ⁴⁰Ar/³⁹Ar geochronologic results. The latter may reflect postimpact thermal overprint of impactites during the Salinian (Late Silurian to Early Devonian) and/or Acadian (Late Devonian) orogenies. U–Pb geochronology of zircon crystals in anorthosite exposed in the central uplift of the impact structure yielded a Grenvillian crystallization age of 1062 ± 11 Ma. The preferred Ordovician age for the Charlevoix impact structure, which is partially overthrusted by the Appalachian front, suggests the impact occurred during a phase of Taconian tectonism and an episode of enhanced asteroid bombardment of the Earth. Our results, moreover, demonstrate that (recrystallized) metamict zircon grains may be of particular interest in impact geochronology.     

Ion microprobe uranium‐lead dating of zircons from the Lappajärvi impact crater,western Finland

Abstract— The lake Lappajärvi impact crater lies in Paleoproterozoic Svecofennian metasedimentary rocks, on the western side of the Central Finland granitoid complex (～1.9 Ga). Two conflicting ages have been reported for the meteorite impact: an age of 77.3 ± 0.4 Ma on the basis of Ar‐Ar whole‐rock data from impact melt samples and a paleomagnetic age of 195 Ma. During studies on impact crater indicator minerals at Lappajärvi, zircons with an atypical appearance were found in suevite boulders. These zircons seemed to have been affected by impact shock metamorphism and it was considered that they would be good candidates for ion microprobe U‐Pb dating, allowing a new and independent age estimate for the impact event at Lappajärvi. Four spot analyses on two black‐coated zircons plotted close to the upper intercept end of the concordia curve giving an approximate age of 1.8 Ga for the source rock. Seventeen analyses were done on three dull zircon grains showing patchy impact‐related partial recrystallization. Most of these data fell fairly well on a single discordia line with intercept ages of 73.3 ± 5.3 Ma and 1854 ± 51 Ma. However, five of the data spots near the lower intercept end fell on the younger side of the line. This was interpreted to indicate post‐impact loss of lead. Importantly, the new ion microprobe U‐Pb age of 73.3 ± 5.3 Ma is in a very good agreement with the previously reported Ar‐Ar age.     

New impact‐melt rock from the Roter Kamm impact structure,Namibia: Further constraints on impact age,melt rock chemistry,and projectile composition

Abstract— A new locality of in situ massive impact‐melt rock was discovered on the south‐southwestern rim of the Roter Kamm impact structure. While the sub‐samples from this new locality are relatively homogeneous at the hand specimen scale, and despite being from a nearby location, they do not have the same composition of the only previously analyzed impact‐melt rock sample from Roter Kamm. Both Roter Kamm impact‐melt rock samples analyzed to date, as well as several suevite samples, exhibit a granitic‐granodioritic precursor composition. Micro‐chemical analyses of glassy matrix and Al‐rich orthopyroxene microphenocrysts demonstrate rapid cooling and chemical disequilibrium at small scales. Platinum‐group element abundances and ratios indicate an ordinary chondritic composition for the Roter Kamm impactor. Laser argon dating of two sub‐samples did not reproduce the previously obtained age of 3.7 ± 0.3 (1s?) for this impact event, based on ⁴⁰Ar/³⁹Ar dating of a single vesicular impact‐melt rock. Instead, we obtained ages between 3.9 and 6.3 Ma, with an inverse isochron age of 4.7 ± 0.3 Ma for one analyzed sub‐sample and 5.1 ± 0.4 Ma for the other. Clearly a post‐5 Ma impact at Roter Kamm remains indicated, but further analytical work is required to better constrain the currently best estimate of 4–5 Ma. Both impactor and age constraints are clearly obstructed by the inherent microscopic heterogeneity and disequilibrium melting and cooling processes demonstrated in the present study.     

Impact melt dikes in the Sudbury multi-ring basin (Canada): Implications from uranium-lead geochronology on the Foy Offset Dike

Abstract To investigate the origin of Offset Dikes and their age relationships to major impact generated lithologies in the Sudbury multi-ring impact structure, such as the Main Mass of the Sudbury “Igneous” Complex, zircon and baddeleyite were dated by the U-Pb chronometer. The rocks analysed are one diorite and two quartz diorites from inside the Foy Offset, one quartz diorite from the contact zone, and two country rock samples collected at 10 and 30 m distances from the contact within the Levack Gneiss Complex. The 21 analysed zircon and baddeleyite fractions yield a crystallization age of 1852 +4/-3 (2σ) Ma for the accessory minerals in the Foy Offset Dike and an age of 2635 ± 5 Ma for the shocked Levack country rock, in which zircons show significant shock effects (multiple sets of planar fractures), in contrast to the totally unshocked zircons of the Offset Dike. Within given errors, the new age of 1852 Ma is identical to the pooled 1850 ± 1 Ma U-Pb age determined by Krogh et al. (1984) as the crystallization age of accessory phases in different lithologies of the Sudbury “Igneous” Complex, which has been interpreted to represent the coherent impact melt sheet of the Sudbury Structure. This excellent agreement of the ages substantiates that emplacement of the Offset Dikes occurred coevally with the formation of the impact melt sheet. Total absence of inherited zircons in the central part of the Foy Offset indicates melting of the precursor material at temperatures well above 1700 °C, which emphasizes the origin of the dike lithologies by impact melting.     

Coeval argon‐40/argon‐39 ages of moldavites from the Bohemian and Lusatian strewn fields

Abstract— ⁴⁰Ar/³⁹Ar ages of four tektites (moldavites) from southern Bohemia (near ?eské Budějovice, Czech Republic) and a tektite from Lusatia (near Dresden, Germany) have been determined by 11 step‐degassing experiments. The purpose of the study was to enlarge the ⁴⁰Ar/³⁹Ar data base of moldavites and to check the age relations of the Bohemian and Lusatian samples. The mean plateau‐age of the Bohemian samples, which range from 14.42 to 14.70 Ma, is 14.50 ± 0.16 (0.42) (2σ) Ma (errors in parentheses include age error and uncertainty of standard monitor age). The plateau age of the Lusatian sample of 14.38 ± 0.26 (0.44) (2σ) Ma confirms the previously published ⁴⁰Ar/³⁹Ar age of 14.52 ± 0.08 (0.40) (2σ) Ma, and demonstrates that the fall of Lusatian and Bohemian tektites were contemporaneous. Because of their geochemistry and their ages there is no doubt that the Lusatian tektites are moldavites. Accepting that moldavites are ejecta from the Nördlinger Ries impact, the new ages also date the impact event. This age is slightly younger (about 0.2–0.3 Ma) than the age suggested by earlier K‐Ar determinations.     

Multiple impact events on the L-chondritic parent body: Insights from SIMS U-Pb dating of Ca-phosphates in the NWA 7251 L-melt breccia

Here we report in situ secondary ionization mass spectrometry Ca-phosphate U-Pb ages for an L-impact melt breccia (NWA 7251), which are integrated with petrological and mineral chemical studies of this meteorite. NWA 7251 is a heavily shocked rock that is composed mainly of the chondrite host, impact melt portion, and melt veins (crosscutting and pervasive type). The host is an L4 chondrite that has been shocked to S4. The impact melt portion has a fine-grained igneous texture, and is composed mainly of olivine, low-Ca pyroxene, high-Ca pyroxene, and albitic glass. The impact melt was generated at pressure of >30–35 GPa and temperature of >1300–1500 °C during an impact event. The Ca-phosphate grains in the host were affected by a shock heating event. Most of the Ca-phosphate grains in the melt were neocrystallized, but relatively large grains enclosed by or adjacent to metal veins or melt globules are likely inherited. The U-Pb isotopic systematics of Ca-phosphates in NWA 7251 yield an upper intercept age of 4457 ± 56 Ma and a lower intercept age of 574 ± 82 Ma on the normal U-Pb concordia diagram. The age of 4457 ± 56 Ma is interpreted to be related to an early shocking event rather than the thermal metamorphism of the parent body. The impact melt and veins in NWA 7251 were generated at 574 ± 82 Ma, resulting from disruption of the L chondrite parent body.     

40Ar‐39Ar step‐heating of impact glasses from the Nördlinger Ries impact crater—Implications on excess argon in impact melts and tektites

Seven impact melts from various places in the Nördlinger Ries were dated by ⁴⁰Ar‐³⁹Ar step‐heating. The aim of these measurements was to increase the age data base for Ries impact glasses directly from the Ries crater, because there is only one Ar‐Ar step‐heating spectrum available in the literature. Almost all samples display saddle‐shaped age spectra, indicating the presence of excess argon in most Ries glass samples, most probably inherited argon from incompletely degassed melt and possibly also excess argon incorporated during cooling from adjacent phases. In contrast, moldavites usually contain no inherited argon, probably due to their different formation process implying solidification during ballistic transport. The plateau age of the only flat spectrum is 14.60 ± 0.16 (0.20) Ma (2σ), while the total age of this sample is 14.86 ± 0.20 (0.22) Ma (isochron age: 14.72 ± 0.18 [0.22] Ma [2σ]), proofing the chronological relationship of the Ries impact and moldavites. The total ages of the other samples range between 15.77 ± 0.52 and 20.4 ± 1.0 Ma (2σ), implying approximately 2–40% excess ⁴⁰Ar (compared to the nominal age of the Ries crater) in respective samples. Thus, the age of 14.60 ± 0.16 (0.20) (2σ) (14.75 ± 0.16 [0.20 Ma] [2σ], calculated using the most recent suggestions for the K decay constants) can be considered as reliable and is within uncertainties indistinguishable from the most recent compilation for the age of the moldavite tektites.     

40Ar/39Ar dating of the Araguainha impact structure,Mato Grosso,Brazil

Abstract— Pursuing the exploration of the Araguainha impact structure (Engelhardt et al., 1992), we present ⁴⁰Ar/³⁹Ar ages (1) of biotite samples from the granite, which forms the central uplift of the structure, and (2) of a melt rock, formed by the impact. Total degassing ages of biotites from granite samples range from 326 to 481 Ma. The variation is explained by Ar losses due to the oxidation of divalent Fe and by removal of K. The K loss depends on the time that the granite was exposed to weathering at particular outcrops. The oldest age of the least oxidized biotite from a granite sample, collected at a site most recently exposed, signifies that the ascending granite passed the 300° isotherm earlier than 481 Ma ago. Early Devonian Furnas sandstones, the oldest sediments exposed by the impact, were deposited on this granite basement 410–396 Ma ago. The ⁴⁰Ar/³⁹Ar analyses of two size fractions of an impact melt rock, resulting in plateau ages of 245.5 ± 3.5 Ma and 243.3 ± 3.0 Ma, respectively, indicate that the Araguainha impact occurred close to the Permian-Triassic boundary.     

Establishing a 14.6 ± 0.2 Ma age for the Nördlinger Ries impact (Germany)—A prime example for concordant isotopic ages from various dating materials

Abstract– ⁴⁰Ar/³⁹Ar dating of recrystallized K‐feldspar melt particles separated from partially molten biotite granite in impact melt rocks from the approximately 24 km Nördlinger Ries crater (southern Germany) yielded a plateau age of 14.37 ± 0.30 (0.32) Ma (2σ). This new age for the Nördlinger Ries is the first age obtained from (1) monomineralic melt (2) separated from an impact‐metamorphosed target rock clast within (3) Ries melt rocks and therewith extends the extensive isotopic age data set for this long time studied impact structure. The new age goes very well with the ⁴⁰Ar/³⁹Ar step‐heating and laser probe dating results achieved from mixed‐glass samples (suevite glass and tektites) and is slightly younger than the previously obtained fission track and K/Ar and ages of about 15 Ma, as well as the K/Ar and ⁴⁰Ar/³⁹Ar age data obtained in the early 1990s. Taking all the ⁴⁰Ar/³⁹Ar age data obtained from Ries impact melt lithologies into account (data from the literature and this study), we suggest an age of 14.59 ± 0.20 Ma (2σ) as best value for the Ries impact event.     

U‐Pb dating of zircons from an impact melt of the Nördlinger Ries crater

In situ U‐Pb measurements on zircons of the Ries impact crater are presented for three samples from the quarry at Polsingen. The U‐Pb data of most zircons plot along a discordia line, leading to an upper intercept of Carboniferous age (331 ± 32 Ma [2σ]). Four zircons define a concordia age of 313.2 ± 4.4 Ma (2σ). This age most probably represents the age of a granite from the basement target rocks. From granular textured zircon grains (including baddeleyite and anatase/Fe‐rich phases, first identified in the Ries crater), most probably recrystallized after impact (13 analyses, 4 grains), a concordia age of 14.89 ± 0.34 Ma (2σ) and an error weighted mean ²⁰⁶Pb*/²³⁸U age of Ma 14.63 ± 0.43 (2σ) is derived. Including the youngest concordant ages of five porous textured zircon grains (24 spot analyses), a concordia age of 14.75 ± 0.22 Ma (2σ) and a mean ²⁰⁶Pb*/²³⁸U age of 14.71 ± 0.26 Ma (2σ) can be calculated. These results are consistent with previously published ⁴⁰Ar/³⁹Ar ages of impact glasses and feldspar. Our results demonstrate that even for relatively young impact craters, reliable U‐Pb ages can be obtained using in situ zircon dating by SIMS. Frequently the texture of impact shocked zircon grains is explained by decomposition at high temperatures and recrystallization to a granular texture. This is most probably the case for the observed granular zircon grains having baddeleyite/anatase/Fe‐rich phases. We also observe non‐baddeleyite/anatase/Fe‐rich phase bearing zircons. For these domains, reset to crater age is more frequently for high U,Th contents. We tentatively explain the higher susceptibility to impact resetting of high U,Th domains by enhanced Pb loss and mobilization due to higher diffusivity within former metamict domains that were impact metamorphosed more easily into porous as well as granular textures during decomposition and recrystallization, possibly supported by Pb loss during postimpact cooling and/or hydrothermal activity.     

An Early Jurassic age for the Puchezh‐Katunki impact structure (Russia) based on 40Ar/39Ar data and palynology

The Puchezh‐Katunki impact structure, 40–80 km in diameter, located ~400 km northeast of Moscow (Russia), has a poorly constrained age between ~164 and 203 Ma (most commonly quoted as 167 ± 3 Ma). Due to its relatively large size, the Puchezh‐Katunki structure has been a prime candidate for discussions on the link between hypervelocity impacts and extinction events. Here, we present new ⁴⁰Ar/³⁹Ar data from step‐heating analysis of five impact melt rock samples that allow us to significantly improve the age range for the formation of the Puchezh‐Katunki impact structure to 192–196 Ma. Our results also show that there is not necessarily a simple relationship between the observed petrographic features of an impact melt rock sample and the obtained ⁴⁰Ar/³⁹Ar age spectra and inverse isochrons. Furthermore, a new palynological investigation of the postimpact crater lake sediments supports an age significantly older than quoted in the literature, i.e., in the interval late Sinemurian to early Pliensbachian, in accordance with the new radioisotopic age estimate presented here. The new age range of the structure is currently the most reliable age estimate of the Puchezh‐Katunki impact event.