金伯利岩:地球深部探测的重要探针

金伯利岩是一种偏碱性的超基性岩,来源于地幔深部,富含挥发份和钾质,属于火成岩类,金伯利岩中主要含有镁铝榴石、金刚石、橄榄石、铬铁矿、铬透辉石、镁钛铁矿,锆石、碳硅石等造岩矿物.同时金伯利岩也被认为是含金刚石最主要的岩石.本文通过文献调研方法,野外现场表明金伯利岩中含有深源包裹体;全球金伯利岩主要分布在俄罗斯、博茨瓦纳、加拿大、安哥拉、南非、刚果民主和纳米比亚;中国金伯利岩主要分布在华北地台,在山东、辽宁、吉林、山西、河南和新疆等地.这些金伯利岩常常与深大断裂甚至地幔深部地质作用关系密切,常出现标志性矿物橄榄石、石榴石、高铬磁铁矿,伴有烃类或氢气.但含金刚石金伯利岩主要沿郯庐断裂带分布,如辽宁瓦房店、山东蒙阴等地.从时代上看,以往认为的早古生代的金伯利岩,更可能都是在早期形成于华北地台之岩石圈底部,而在中生代白垩纪时期才在大规模岩石圈拆沉的地质背景下的以快速上升的,尤其是那些含金刚石的金伯利岩岩管更是快速上升的典型代表,其标型矿物是镁铝榴石、高铬磁铁矿、钙钛矿等.国内辽宁瓦房店含金刚石金伯利岩产于郯庐断裂带东侧,有着与同期金伯利岩相同的岩石矿物学特征,其中的以50号岩管为代表的金刚石矿床是我国重要的战略矿产.金伯利岩及其中的金刚石带来众多直接的深部地幔信息,中国瓦房店、蒙阴一带的金刚石来自上地幔,而一些含硼蓝色金刚石则来自下地幔,不同层圈的金刚石携带不同的标志矿物,以橄榄石为例:来自上地幔金刚石携带的橄榄石为橄榄石;过渡带金刚石携带的主要为瓦兹利石和林伍德石;下地幔的金刚石则为布里奇曼石,它们是深部探测的重要探针.     

佳木斯地块西缘金矿带构造效应与壳幔作用--以鹤岗隆起为例

佳木斯地块西缘金矿带的形成受左行走滑断裂带和深部流体控制，壳-幔作用和地球动力体制转换是成矿物质活化→运移→聚集→成矿的基本动力学保障，构造应力场转换是其重要表现形式。深切地幔牡丹江岩石圈断裂的活动发生了深熔作用，使成矿物质得以活化、运移的重要驱动力，是成岩成矿作用发生的根本原因之一。地幔流体通过壳-幔相互作用形成了含矿流体，为流体成矿作用提供了矿源，并沿深断裂运移到更高的层位，在物理化学条件发生改变时沉积成矿。佳木斯地块西缘金矿带是受深断裂控制的，矿床之间是相互联系的，是在一个构造应力体制下完成它们的成矿作用的。北北东向和伴生的北西西向断裂，并有中生代浅成-超浅成岩体或脉岩侵位是今后找矿的方向。     

胶北地块前寒武纪基底研究新进展

胶北地块位于鲁东的沂沭断裂和五莲—烟台断裂之间,以出露不同变质程度的太古宙—古元古代的结晶基底为特征,其岩石组合为TTG质(英云闪长岩-奥长花岗岩-花岗闪长岩)片麻岩和少量变质表壳岩(变质火山岩-变质沉积岩),它们构成了胶北的花岗-绿岩体。对变质(超)基性岩、TTG岩系的岩石组合、地球化学特征和同位素年代学的研究表明,胶北地块造壳的主要时期为新太古代的2.8～2.7 Ga;在经历了2.5 Ga左右构造事件后,胶北地块进入稳定陆壳沉积阶段,并接受了古元古代的孔兹岩系沉积;最后于1.8 Ga左右发生变质。与苏鲁造山带不同,胶北地块前寒武纪基底具有许多亲华北板块的特征,二者的界线可能是五莲—烟台断裂。     

景德镇-温州大地电磁剖面深部电性结构研究

华南大陆历经长期复杂的构造演化,其浅部复杂而多样的构造形态与深部壳幔结构及其动力学机制有着密切联系,但当前的深部探测资料有限,深部构造并不明确。为了研究华南的深部岩石圈结构状态,布设了多条宽频长周期大地电磁联合探测剖面。通过对景德镇-温州剖面的数据处理,获得了该剖面的岩石圈电性结构模型。分析表明:华夏地块与扬子地块东部的江南造山带以江绍断裂为界;华夏地块整体呈现高阻特征,可能具有深部岩石圈背景的上虞-政和-大浦断裂将其分为华夏褶皱带与东南沿海岩浆岩带;扬子地块东部的江南造山带整体电阻率较低,结构更破碎,受到深部改造明显,岩石圈底界约为110 km;剖面发现3处低阻带通道,可能与软流圈上涌相关;江绍断裂呈喇叭状向深部张开,华夏地块与扬子地块的裂解拼合可能与断裂深部的高导体活动有关。华夏地块与扬子地块的接触状态呈现为双向汇聚,华夏地块在上地幔挤入扬子地块,深部接触边界可能越过江绍断裂带。     

长江中下游及其邻区深部地球物理背景与含金夕卡岩矿床的分布

长江中下游地区是我国重要的铁铜矿产基地。近十年来,我国所发现的含金夕卡岩矿床和铜伴生金夕卡岩矿床也主要产在长江中下游地区。作者借助12条大地电磁测深剖面、5条地震剖面、层析成像速度结构资料、重磁场等区域的和深部的地球物理资料进行综合对比研究,给出长江中下游及其邻区的三维深部构造格架及其与含金夕卡岩矿床和铜伴生金夕卡岩矿床的分布关系。作者认为,上地幔隆起带(岩石圈地幔减薄带)、上地幔异常区(相对低速区)、壳内高导层隆起带、深断裂(岩石圈剪切带)、地壳上地幔不均匀性块体的边缘、重力高反映的基底隆起区、跳跃磁场反映的岩浆岩带和构造交汇处等诸多因素的共同作用控制着含金夕卡岩矿床和铜伴生金夕卡岩矿床的分布。     

"深部地质作用及战略性关键矿产"专辑特邀主编寄语 ——深部过程与地表响应

"向地球深部进军是我们必须解决的战略科学问题"是习近平总书记提出的重要论断,也是国家对地学工作者提出的新要求.深部地质作用地球行星作为载体在太阳恒星系统及其更大尺度空间综合作用的结果.从短周期的月球-地球作用的潮汐,到地球-太阳作用的四季更替,再到较大尺度的冰期-间冰期更替,乃至更大周期,无一不影响到地球自身,诸如膨胀-收缩,海平面升降,活火山爆发与宁静,成灾-成矿/成藏,生存环境的毁灭与再造,深刻地影响着我们地球家园的生态环境.战略性关键矿产多受控于深部地质作用.金刚石产在金伯利岩-钾镁煌斑岩-橄榄玄武岩中,新能源矿产铀矿产于深源断裂控制的火山岩或砂岩中,锂-铷-铯和铌-钽-锆-铪等稀有金属多产于深源流体控制的伟晶岩中,金、银、铂族元素、钴、铼等稀贵金属多受控于深源流体,稀土元素多产于深源的碳酸岩-碱性杂岩中.这些矿产大多数对于新兴产业是必不可少的原料.同时,深部地质作用及其浅部产物是人类认识地核-地幔物质组成的窗口.战略性关键矿产历史性地将深部地质作用研究的重任交给地学工作者.近年来,多家科研单位、高等院校和地勘单位对深部地质作用及相关的战略性关键矿产开展了地质调查和科学研究,在金伯利岩、钾镁煌斑岩、玄武岩等深部地质作用和金刚石、贵金属、铀矿、稀土稀有稀散矿产等成矿作用等方面取得了一系列新进展.为了更好地推动深部地质作用和战略性关键矿产相关的学术研究和应用转化应用,服务国家需求,《地球学报》组织了"深部地质作用及战略性关键矿产"专辑,服务于深部探测和战略性关键矿产(金刚石、铀矿、稀土-稀有-稀散-稀贵金属)相关研究和勘查工作的专家、学者.     

超深金刚石包裹体:对深部地幔物理化学环境的指示

超深金刚石及其包裹体是探究深部地幔组成及物理化学环境的重要样本。梳理了超深金刚石中新发现的典型矿物包裹体及其组合,并结合前人高精度原位分析、高温高压合成金刚石实验的研究成果,综述分析了超深金刚石矿物包裹体及其组合指示的深度范围、微量元素与温压条件之间的关系,超深地幔水的赋存矿物相、金属相以及强还原环境新认识,残留的俯冲洋壳可能是深部地幔水的重要储库,超深金刚石及其包裹体对深俯冲及深部碳循环的指示等研究进展。指出我国学者虽然在华北、扬子克拉通金刚石中也发现了指示超深来源的矿物包裹体,在超高压金刚石形成及蛇绿岩型金刚石成因研究方面获得了某些重要进展,但对超深金刚石包裹体的研究仍然有待深入。     

新疆塔里木地块北缘碱性岩(矿)带的地质构造环境

塔里木地块北缘碱性岩矿带位于哈萨克斯坦板块南缘和塔里木板块会聚的天山造山带中。碱性杂岩和矿产明显受深断裂控制,由北而南划分为活动陆缘深断裂、板边深断裂和板内深断裂三种不同构造类型。     

西藏高原中、北部断裂构造特征:INDEPTH(Ⅲ)-MT观测提供的依据

根据1998年和1999年INDEPTH(Ⅲ)MT在西藏中、北部所完成的德庆-龙尾错(500线)和那曲-格尔木(600线)超宽频带大地电磁深探测剖面数据研究西藏高原中北部断裂构造特征,有助于推进印度板块与亚洲板块碰撞、俯冲构造模式的研究.研究结果表明,区内发育有F1～F10一系列深断裂.其中,F2向北倾斜是早期的主断裂,F1则是后期主逆冲断裂,它们共同构成空间结构复杂的嘉黎深断裂带.班公-怒江缝合带的主断裂系由略微向南陡倾的F3、F4和F5三组超壳深断裂构成;由于受后期构造运动强烈的改造,缝合带内发育多条延深不大的上地壳断层.唐古拉断裂带由F6、F7两组主断裂和一系列次级断裂构成;主断裂产状上陡、下缓,总体向南倾斜,向下延深达下地壳.而金沙江缝合带是由F8(金沙江断裂)和F9(可可西里断裂),以及它们之间存在的一系列上地壳次级断层共同组成的,是一组很宽的地块碰撞缝合带.F10即昆中断裂是产状陡立的超壳深断裂,是昆仑山断裂带的主体构造,它构成松潘-甘孜-可可西里地块的北部边界.从剖面电性结构特征分析,昆中断裂以南属于西藏高原主体;而以北地区是否还归属西藏高原?这有待更深入的讨论.值得特别关注的事实是,研究区内2组缝合带之下都存在向上地幔延伸的壳内高导体,它们可能反映区内壳幔热交换过程的痕迹.     

深地震反射剖面揭露青藏高原陆-陆碰撞与地壳生长的深部过程

印度板块与亚洲板块的碰撞使喜马拉雅-青藏高原隆升,地壳增厚和生长扩展。探测青藏高原深部结构,揭露两个大陆如何碰撞,碰撞如何使大陆变形的过程,是全球关切的科学奥秘。深地震反射剖面探测是打开这个科学奥秘的最有效途径之一。20多年来,运用这项高技术探测到青藏高原巨厚地壳的精细结构,攻克了难以得到下地壳和Moho清晰结构的技术瓶颈,揭露了陆陆碰撞过程。本文在探测研究成果基础上,从青藏高原南北-东西对比,再到高原腹地,系统地综述了青藏高原之下印度板块与亚洲板块碰撞-俯冲的深部行为。印度地壳在高原南缘俯冲在喜马拉雅造山带之下,亚洲板块的阿拉善地块岩石圈在北缘向祁连山下俯冲,祁连山地壳向外扩展,塔里木地块与高原西缘的西昆仑发生面对面的碰撞,在高原东缘发现龙日坝断裂而不是龙门山断裂是扬子板块的西缘边界,高原腹地Moho 薄而平坦,岩石圈伸展垮塌。多条深反射剖面揭露了在雅鲁藏布江缝合带下印度板块与亚洲板块碰撞的行为,印度地壳不仅沿雅鲁藏布江缝合带存在由西向东的俯冲角度变化,而且其向北行进到拉萨地体内部的位置也不同。在缝合带中部,显示印度地壳上地壳与下地壳拆离,上地壳向北仰冲,下地壳向北俯冲,并在俯冲过程发生物质的回返与构造叠置,使印度地壳减薄,喜马拉雅地壳加厚。俯冲印度地壳前缘与亚洲地壳碰撞后沉入地幔,处于亚洲板块前缘的冈底斯岩基与特提斯喜马拉雅近于直立碰撞,冈底斯下地壳呈部分熔融状态,近乎透明的弱反射和局部出现的亮点反射,以及近于平的Moho都反映出亚洲板块南缘的伸展构造环境。     

Andalusite in granulites of the bohemian massif

Summary In granulites of South-Bohemia not only the usually occurring Al₂SiO₅ polymorphs, kyanite and sillimanite, were found but also andalusite. Its presence indicates that the metamorphic development of these granulites is characterized by a high PT-gradient. The granulitic rocks of the Bohemian Massif can be regarded as a facies series ranging from the granulite facies through the amphibolite facies to the hornblende-hornfels facies. The lower limit of the PT-conditions of this series should be placed below the position of the triple point of Al₂SiO₅.

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Andalusit in Granuliten der Böhmischen Masse

Zusammenfassung In den Mineralparagenesen der südböhmischen Granulite wurde neben den üblicherweise auftretenden Al₂SiO₅-Modifikationen, Disthen und Sillimanit, auch Andalusit gefunden. Seine Anwesenheit weist darauf hin, daß die metamorphe Entwicklung der erwähnten Granulite durch einen ausgeprägten PT-Gradienten gekennzeichnet wurde. Die Granulitgesteine der Böhmischen Masse kann man als eine Faziesserie ansehen, die von der Granulitfazies über die Amphibolitfazies bis in die Hornblende-Hornfelsfazies reicht. Die untere Grenze der PT-Bedingungen dieser Serie ist unter die Lage des Tripelpunktes von Al₂SiO₅ zu setzen.

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With 5 Figures     

A rationale for the origins of massif anorthosites

The origin of massif anorthosites cannot be simply explained by a single magma type. Two of the commonly proposed parents for anorthosites are andesites (quartz-diorites) and high-alumina basalts. It is proposed here that these two magmas are the parents for two groups of anorthosites which include all anorthosite massifs, and that the parents for any given anorthosite massif can be determined by the rock sequence associated with the massif.Evidence from experiments and from phenocrysts in volcanics, suggests that andesites crystallizing in the granulite facies would produce plagioclase cumulates (anorthosites) at the base, followed by dioritic and acidic material, whereas high-alumina basalts would produce gabbros followed by anorthosite with very little succeeding acidic material. All massif anorthosites for which relevant data is available have one or the other of these stratigraphic sequences. Grouped according to these sequences, they coincide with two previously proposed groups, i.e. Andesine-type and Labradorite-type, whose characteristics are shown to be compatible with derivation from andesite and high-alumina basalt, respectively.     

On the age of mylonites within the Mont Blanc massif

Abstract

Three generations of mylonites occur in the Mont Blanc Massif :

— the first one has produced mylonitic schists trending N20°E, of regional extension; the late Variscan Mont Blanc granite intruded these mylonites;

— the second one has affected large areas in the Mont Blanc granite, with the same N20°E direction;

— the third one is located along rather narrow bands N45°E, in the granite as well as in the older mylonitic schists.

All theses mylonites have been generated under (Bi) - greenschist facies conditions. They exhibit steeply plunging schistosity and lineation. They are all ante-Alpine; paradoxically, Alpine structures within the massif do not exhibit a striking appearence.     

Structure of Synnyr alkalic rock massif

There are five intrusive complexes in the Synnyr range, one of which is the complex of alkalic igneous rocks discussed. It consists of several phases, some of which have been more or less completely rnetasomatized. These metasomatic rocks are considered by the author as a separate “complex.” K-A determinations on biotite from the syenites of these two complexes indicate an age of between 300 and 350 m.y. The alkalic rocks and their metasomatic equivalents form the equant Synnyr massif, situated at the intersection of two regional faults of northeast and northwest strike. The former is considered to have been the “magma channel.” The periphery of the massif is coarse alkalic syenites that underlie a ring-like erosional depression within which occur finer (trachytoid) Ne-bearing syenites and pulaskites. Contact zones consist of skarn, hornfels, and fenite. Within the intrusive the overall mineral composition of the metasomatized facies is not greatly different from that of the original rocks, but the texture has been changed by neocrystallization and recrystallization and the porosity is distinctly higher. Plagioclase has been replaced by almost pure albite and some of the potassium feldspar by intergrowths with kaliophylite. Fluorite and analcite occur as new minerals. In the late, low-temperature stage scapolite, zeolites, epidote-zoisite, and sparse quartz are found in some places. The other three complexes of the range are described very briefly: subalkalic syenite complex, a complex of silicic intrusive rocks, and a series of late lamprophyric dikes. – E. Ingerson.     

Aureoles of Songshugou Alpine-type ultramafic massif

The Songshugou Alpine-type ultramafic massif intruded into the surrounding plagioclase-amphibole schists where high-temperature aureoles are found well exposed but not distroyed. From the outer part inwards, four aureoles are recognized: the oligoclase-hornblende zone, the andesine-hornblende zone, the garnet zone and the pyroxene zone. Toward the massif, systematic variations are noticed in the rocks from one zone to another, i.e., the rocks vary from fine-grained, fibrous, crystalloblastic texture to medium coarse-grained, granular, crystalloblastic texture and from schistose structure to massive structure; hornblende varies from blue-green to brofn; plagioclases vary in composition from An_12–17 to An₃₇, even to An₆₀ near the contact; garnet and pyroxene become more and more abundant; sphene is replaced progressively by titanomagnetite; and Na(K), Al and Ti in the hornblende tend to increase near the contact. Studies have shown that the typical rocks in the four contact metamorphic zones are generally similar in major and trace elements. But different mineral assemblages and mineral chemistry indicate that the rocks were formed under different physical conditions.     

Geochemistry of the Adamello massif (northern Italy)

The Tertiary Adamello massif, outcropping over an area of more than 550 km² in the southern Alps (northern Italy) is composed mainly of granitoid rocks (granodiorite, tonalite, quartz diorite) with minor amounts of diorite and gabbro. The major and trace element composition of these rocks is comparable to calc-alkaline volcanic rocks of continental margins. The granitoid rocks display spatial and temporal variations in their composition, particularly in Na, P, Sr, La, Nb and Y contents and ⁸⁷Sr/⁸⁶Sr ratios. The variations were probably produced by concurrent contamination/wall-rock assimilation and fractional crystallization of high-alumina basaltic magma.     

Experimental evidence for diamond-facies metamorphism in the Dora-Maira massif

The peak metamorphic conditions of subducted continental crust in the Dora-Maira massif (Western Alps) have been revised by combining experimental results in the KCMASH system with petrologic information from whiteschists. Textural observations in whiteschists suggest that the peak metamorphic assemblage garnet+phengite+kyanite+coesite±talc originates from the reaction kyanite+talc↔garnet+coesite+liquid. In the experimentally determined petrogenetic grid, this reaction occurs above 45 kbar at 730 °C. At lower pressures, talc reacts either to orthopyroxene and coesite or, together with phengite, to biotite, coesite and kyanite. The liberated liquid contains probably similar amounts of H₂O and dissolved granitic components. The composition of the liquid in the whiteschists at peak metamorphic conditions, a major unknown in earlier studies, was probably very similar to the liquid composition produced in the experiments. Therefore, the experimentally determined petrogenetic grid represents a good model for the estimation of the peak metamorphic conditions in whiteschists. Experimentally determined Si-isopleths for phengite further constrain peak pressures to 43 kbar for the measured Si=3.60 of phengite in the natural whiteschists. All these data provide evidence that the whiteschists reached diamond-facies conditions.

The fluid-absent equilibrium 4 kyanite+3 CELADONITE=4 coesite+3 muscovite+pyrope has been calibrated on the basis of garnet and phengite compositions in the experiments and serves as a geothermobarometer for ultra-high-pressure (UHP) metapelites. For graphite-bearing metapelites and kyanite–phengite eclogites, forming the country rocks of the whiteschists, peak metamorphic pressures of about 44±3 kbar were calculated from this barometer for temperatures of 750 °C estimated from garnet–phengite thermometry. Therefore, the whole ultra-high-pressure unit of the Dora-Maira massif most likely experienced peak metamorphic conditions in the diamond stability field. While graphite is common in the metapelites, diamond has not been found so far. The absence of metamorphic microdiamonds might be explained by the low temperature of metamorphism, the absence of a free fluid phase in the metapelites and a short residence time in diamond-facies conditions resulting in kinetic problems in the conversion of graphite to diamond.     

Platinum potential of the Lukkulajsvaara layered massif in North Karelia

This paper discusses geological features of the Lukkulajsvaara platinum-bearing intrusion. Particular attention is paid to platinum-bearing layers, namely petrographic features of ore-bearing rocks, their structure, texture, and the mineralogical composition of the ore. This allowed the revelation of some features of platinum ore formation, in which postcumulus liquids enriched in fluids played the main role.