Stratigraphy,evolution, and volume of basalts in Mare Serenitatis

Abstract– Fourteen major basaltic units in Mare Serenitatis have been identified and mapped from differences in TiO₂ wt%. The ages of these units have been inferred from their crater densities and reference to isotopically dated Apollo samples. It has been found that FeO and TiO₂ wt% of the units do not show any apparent trend with time. However, the oldest units have much greater variation in FeO and TiO₂ wt% than younger ones. No lateral trend in the age of the basaltic units is apparent within the basin. A vertical profile of Mare Serenitatis has been produced based on the depth of basalt within impact craters. The minimum depth of basalt has been estimated where craters have not exposed underlying highland material. The profile has been used to estimate the minimum volume of basalt within the basin to be ≈500,000 km³.     

Compositional and temporal investigation of exposed lunar basalts in the Mare Imbrium region

This paper presents an updated stratigraphical and compositional study of the exposed maria within the Imbrium basin on the Moon. Clementine multispectral data were employed to derive TiO₂ and FeO wt% abundance estimates of potentially distinct basaltic flows. Additionally, NASA Lunar Orbiter images were used to estimate flow ages using crater count statistics. Mare Imbrium shows evidence of a complex suite of low to high-Ti basaltic lava units infilling the basin over an 800 million year timescale. More than a third (37%) of identified mare basalts were found to contain 1-3 wt% TiO₂. Two other major mare lithological units (representing about 25% of the surface each) show TiO₂ values between 3-5 and 7-9 wt%. The dominant fraction (55%) of the sampled maria contain FeO between 16 and 18 wt%, followed by 27% of maria having 18-20 wt% and the remaining 18%, 14-16 wt% FeO. A crater frequency count (for diameters >500 m) shows that in three quarters of the sampled mare crater counts range between 3.5 and 5.5×¹⁰⁻² per km², which translates, according to a lunar cratering model chronology, into estimated emplacement ages between ∼3.3 and 2.5 Ga. A compositional convergence trend between the variations of iron and titanium oxides was identified, in particular for materials with TiO₂ and FeO content broadly above 5 and 17 wt%, respectively, suggesting a related petrogenesis and evolution. According to these findings, three major periods of mare infill are exposed in the Imbrium basin; despite each period showing a range of basaltic compositions (classified according to their TiO₂ content), it is apparent that, at least within these local geological settings, the igneous petrogenesis generally evolved through time towards more TiO₂- and FeO-rich melts.     

Searching for high alumina mare basalts using Clementine UVVIS and Lunar Prospector GRS data: Mare Fecunditatis and Mare Imbrium

In the context of sample evidence alone, the high-alumina (HA) basalts appear to be an unique, and rare variety of mare basalt. In addition to their distinct chemistry, radiometric dating reveals these basalts to be among the oldest sampled mare basalts. Yet, HA basalts were sampled by four missions spanning a lateral range of ∼2400 km, with ages demonstrating that aluminous volcanism lasted at least 1 billion years. This evidence suggests that HA basalts may be a widespread phenomenon on the Moon. Knowing the distribution of HA mare basalts on the lunar surface has significance for models of the origin and the evolution of the Lunar Magma Ocean. Surface exposures of HA basalts can be detected with compositional remote sensing data from Lunar Prospector Gamma Ray Spectrometer and Clementine. We searched the lunar surface for regions of interest (ROIs) that correspond to the intersection of three compositional constraints taken from values of sampled HA basalts: 12-18 wt% FeO, 1.5-5 wt% TiO₂, and 0-4 ppm Th. We then determined the “true” (unobscured by regolith) composition of basalt units by analyzing the rims and proximal ejecta of small impacts (0.4-4 km in diameter) into the mare surface of these ROIs. This paper focuses on two ROIs that are the best candidates for sources of sampled HA basalts: Mare Fecunditatis, the landing site of Luna 16; and northern Mare Imbrium, hypothesized origin of the Apollo 14 HA basalts. We demonstrate our technique's ability for delineating discrete basalt units and determining which is the best compositional match to the HA basalts sampled by each mission. We identified two units in Mare Fecunditatis that spectrally resemble HA basalts, although only one unit (Iltm) is consistent with the compositional and relative age of the Luna 16 HA samples. Northern Mare Imbrium also reveals two units that are within the compositional constraints of HA basalts, with one (Iltm) best matching the composition of the basalts sampled by Apollo 14.     

Lunar mare volcanism in the eastern nearside region derived from Clementine UV/VIS data

Abstract— Clementine UV/VIS multi‐spectral data were used to map mare deposits in the eastern lunar nearside region (Mare Tranquillitatis, Mare Fecunditatis, Mare Serenitatis, Mare Crisium, Mare Nectaris) to understand the volcanic history of this region. An array of Clementine and Clementine‐derived data were used to classify mare basalts; these include: 750 nm albedo, UV/VIS ratio, 1 μm absorption signatures, and Clementine derived FeO and TiO₂ contents. We have successfully identified several new geological units and have determined their spectral characteristics. For example, the relatively younger low‐Ti basalts were recognized in the eastern part of Mare Tranquillitatis. The central low‐Ti basalts in Mare Serenitatis, which had been classed as mISP, were divided into 2 groups. In Mare Nectaris, 2 types of mare basalts were identified, while only 1 group was recognized in the previous study. The stratigraphy constructed from the spectral analysis indicates that the mare deposits tend to become younger in the northern maria, including Serenitatis and Crisium, and older in the southern maria, including Tranquillitatis, Fecunditatis, and Nectaris. According to the relationship between the titanium contents of the mare units and their stratigraphy, the titanium content decreases with time in the early stage but increases toward the end of volcanism in the Serenitatis and Crisium region, while it increases with time but finally decreases in the Tranquillitatis and Fecunditatis region. In connection with the distribution of mare basalts, a large amount of high‐Ti mare basalts are found in Mare Tranquillitatis, especially in the western part, while other maria are covered by low‐Ti basalts. The iron contents show a similar distribution to that of titanium.     

Stratigraphy and composition of lava flows in Mare Nubium and Mare Cognitum

Abstract— Three major periods of basaltic activity characterize the infill of the basins. Each of these periods was itself punctuated by discrete phases of widespread magma eruptions: three during both the Late Imbrian Epoch and the early Eratosthenian Period and then two in the late Eratosthenian Period. We found the youngest lavas off the eastern border of the Fra Mauro peninsula and, mantling a much larger area, over most of the central western Nubium basin. Our results place the Nubium/Cognitum basalts in the low‐Ti category (1–5 wt% TiO₂). The data indicate that the majority (?90%) of the mare terrain has iron content between 18 and 22 wt%. In particular, FeO contents tend to concentrate toward two compositional poles, each of ?20 wt%, and a much smaller one of ?15 wt%. These values are typical of nearside lunar maria. To complement our compositional data, we present a census of craters larger than 500 m using Orbiter IV images. The result was a crater count average with frequency 5.6 × 10^?2 km^?2, translating into an inferred mean age of 3300 Ma for the exposed lava flows. By combining lava chemistry with age, we find a possible correlation between the ages of the most prominent flow units and their estimated titanium content, with younger basalts becoming progressively Ti‐richer with time (from 2–3 to 4–5 wt% TiO₂).     

Mare humorum: An integrated study of spectral reflectivity

A detailed study was made of the spectral reflectivity (0.3–1.1 μm) of 31 areas (10–20 km in diam) in the Humorum basin region. The results are: (1) There are at least two units in the mare portion of Humorum which are distinguishable by spectral properties. One of these units, called T-type, has a spectral reflectivity resembling that of the Apollo 11 site and also some areas in Oceanus Procellarum. The other unit in southwest Mare Humorum, resembles Mare Serenitatis in spectral character (S-type). An additional unit in the central area (I-type) with intermediate spectral properties is possible. (2) These mare units do not correlate with obvious morphological or albedo changes but agree well with shadings distinguishable on color difference photographs. (3) On the basis of studies of previously sampled sites it is suggested that the T-type unit may be higher in Ti content (similar to Apollo 11) than the S-type material (similar to Apollo 12). (4) The continuity of T-type material through the break in the northeast wall of Mare Humorum and its spectral similarity to areas in Procellarum suggest that the T-type material may result from an event that flooded parts of Mare Procellarum at a period later than the original Humorum basin filling (S-type). Relative ages derived from crater morphology studies support this sequence.     

Tectonic pattern of the Crüger/Rima Sirsalis -Rima de Gasparis region of the moon

Tectonic lunar units were studied in an area of about 540 000 km² in the southwestern part of the Moon's visible disk. The area is situated in the vicinity of Mare Humorum, Oceanus Procellarum, and Mare Orientale. Zones indicated by lineament sets show three preferred orientations (about N55°W, N10°W, N35°E). Probably these zones coincide with deep faults that have been active over a long period of lunar development. The distribution of Eratosthenian and partly also Imbrian lavas coincides with the zones along which re-activations have taken place. This is best seen in the areas where strong zones intersect each other. Local catastrophic forces must also be taken into account. The trends, distribution, and age relations of tectonic zones can be explained by a combination of maximum principal stress in direction about N10°W coupled possibly with old tidal forces and local (?) volcanic expansion of lunar mantle during the last stages of flooding of Oceanus Procellarum.     

Distribution and stratigraphy of basaltic units in Maria Tranquillitatis and Fecunditatis: A Clementine perspective

Abstract— Maria Tranquillitatis and Fecunditatis have been mapped based on Clementine image mosaics and derived iron and titanium maps. Impact craters served as stratigraphic probes enabling better delineation of compositionally different basaltic units, determining the distribution of subsurface basalts, and providing estimates of total basalt thickness and the thickness of the surface units. Collected data indicate that volcanism in these maria started with the eruption of low‐Ti basalts and evolved toward medium‐ and high‐Ti basalts. Some of the high‐Ti basalts in Mare Tranquillitatis began erupting early and were contemporaneous with the low‐ and medium‐Ti basalts; these units form the oldest units exposed on the mare surface. Mare Tranquillitatis is mostly covered with high‐Ti basalts. In Mare Fecunditatis, the volume of erupting basalts clearly decreased as the Ti content increased, and the high‐Ti basalts occur as a few patches on the mare surface. The basalt in both maria is on the order of several hundred meters thick and locally may be as thick as 1600 m. The new basalt thickness estimates generally fall within the range set by earlier studies, although locally differ. The medium‐ to high‐Ti basalts exposed at the surfaces of both maria are meters to tens of meters thick.     

Refinement of lunar TiO2 analysis with multispectral features of Chang’E-1 IIM data

We develop a method based on the samples from Apollo and Luna landing sites to determine lunar TiO₂ content with Chang’E-1 interference imaging spectrometer (IIM) imagery. By analyzing the nonlinear relationship between the optical and compositional parameters of lunar soil samples, the method employs two Support Vector Machines (SVMs) to estimate the titanium abundance of the lunar surface. Developed with the soil compositions of the Apollo and Luna sample-return stations, the RMS (root mean square) error of our method is 0.24 wt% TiO₂, and the correlation coefficient of the TiO₂ values and our predicted ones is 99.72 %. Compared with the other 3 models, the method proposed in this paper exhibits a good performance for determining the chemical composition of the lunar surface. TiO₂ maps of Sinus Iridum, part of the Marius Hills plateau, and part of Mare Smythii are produced using our method, which could be useful for future lunar missions.     

Basalts from Mare Crisium

The stratified core sample returned from Mare Crisium by the Luna 24 unmanned space probe is composed primarily of a new variety of subophitic to ophitic basalt with very low contents of TiO₂ and MgO. This consists of clinopyroxene, calcic plagioclase, olivine, and minor amounts of silica, chromite, ulvöspinel, ilmenite, troilite, apatite, and Fe-metal. Granular metabasalts have the same bulk composition, but mineral phases exhibit less compositional variation. Fine-grained impact melts have similar compositions and are apparently derived from these basalts. We conclude that the basalts, which are chemically distinct from the very-low-titanium basalts found elsewhere on the Moon, represent the local surface flows of Mare Crisium.Sparse fragments of an olivine vitrophyre that is low in TiO₂ but high in MgO and approaches the composition of the Apollo 15 green glasses may be derived from patches of dark mantling materials 20 km from the landing site.Now at Department of Geology, University of California at Davis, Davis, Calif., U.S.A.Now at Department of Geological Sciences, The University of Tennessee, Knoxville, Tenn., U.S.A.     

Low crater frequencies and low model ages in lunar maria: Recent endogenic activity or degradation effects?

Recently a number of studies have identified small lunar geologic structures to be <100 Ma in age using standard remote sensing techniques. Here we present new crater size frequency distributions (CSFDs) and model ages using craters D > 10 m for five small target units: one irregular mare patch (IMP) in Mare Nubium and four regions located on lunar wrinkle ridges in Mare Humorum. For comparison we also date another IMP found in a recent study in Mare Tranquillitatis (Braden et al. 2014 ). Absolute model age (AMA) derivation corresponds to 46 ± 5 Ma and 22 ± 1 Ma for Nubium and Sosigenes IMP, respectively. We show that for IMPs and in nearby control mare regions, similar production-like cumulative log–log SFD slopes of −3 are observed. In contrast, control mare regions in Mare Humorum exhibit shallower equilibrium slopes from −1.83 to −2. Three out of four wrinkle ridges appear to be in equilibrium but with crater lifetimes lower than on the corresponding maria. Low crater frequencies on one wrinkle ridge result in an age of 8.6 ± 1 Ma. This study region contains 80% fresh craters, which suggests that the crater population is still in production indicative of a recent resurfacing event.     

The titanium contents of lunar mare basalts

Abstract— Lunar mare basalt sample data suggest that there is a bimodal distribution of TiO₂ concentrations. Using a refined technique for remote determination of TiO₂, we find that the maria actually vary continuously from low to high values. The reason for the discrepancy is that the nine lunar sample return missions were not situated near intermediate basalt regions. Moreover, maria with 2–4 wt% TiO₂ are most abundant, and abundance decreases with increasing TiO₂. Maria surfaces with TiO₂ >5 wt% constitute only 20% of the maria. Although impact mixing of basalts with differing Ti concentrations may smear out the distribution and decrease the abundance of high‐Ti basalts, the distribution of basalt Ti contents probably reflects both the relative abundances of ilmenite‐free and ilmenite‐bearing mantle sources. This distribution is consistent with models of the formation of mare source regions as cumulates from the lunar magma ocean.     

Lunar meteorite Queen Alexandra Range 94281: Glass compositions and other evidence for launch pairing with Yamato 793274

Abstract— Lunar meteorite Queen Alexandra Range 94281 is remarkably similar to Yamato 793274. Pairing in the conventional Earth-entry sense is difficult to reconcile with the 2500 km separation between the find locations for these two samples. Nonetheless, both of these regolith breccias are dominated by very-low-Ti (VLT) mare basalt, the pyroxenes of which feature exsolution lamellae on a remarkably coarse scale (typical lamella width = 0.5–1 μm) by mare standards. The pyroxenes also show similar compositional variations (e.g., Fe# vs. Ti# trends, which confirm parentage from VLT mare basalt). Plots using Al₂O₃ or FeO as a tracer of the highland component indicate indistinguishable internal mare-highland geochemical mixing trends. The same two distinctive glass types dominate the mare glass populations of both breccias. Glass type YQ1 features 0.37–0.63 wt% TiO₂, 10–17 wt% MgO, and 9–11 wt% Al₂O₃. Glass type YQ2 features higher TiO₂ (0.99–1.22 wt%), which is inversely correlated with MgO (12.6–13.8 wt%), and nearly constant (8.8 wt%) Al₂O₃. All of these similarities suggest that Y-793274 and QUE 94281 are a launch pair, which we designate YQ. Most of these similarities also extend to another mare-breccia meteorite, Elephant Moraine 87521. However, the EET 87521 mare basalt is unusually V-poor (～88 μg/g), whereas the YQ mare component contains ～166 μg/g. Queen Alexandra Range 94281 features a variety of textural domains. Discrete patches of dark matrix material appear to represent clods of mature regolith that have been mixed with a coarser, relatively immature material. Interior to a frothy fusion crust are areas of massive glass that probably formed as a splash coating on QUE 94281 when it was still on the Moon. The coarse YQ and EET 87521 pyroxene exsolution features imply relatively slow cooling in either a very shallow sill or an unusually thick (ponded) lava and/or later annealing within a cryptomare. Mare pyroclastic glasses, including the two YQ varieties, are systematically MgO-rich compared to crystalline mare basalts. This disparity may be a consequence of limited survival of graphite—the main fuel for explosive volcanism—during formation of the mare source regions as magma ocean cumulates. Graphite (2.2 g/cm³) survived preferentially in regions that avoided extensive early melting and thus remained MgO-rich. An apparent bimodality in the TiO₂ contents of mare volcanics, especially the pyroclastic glasses, also seems a plausible consequence of petrogenesis by remelting of magma ocean cumulates. Cumulates deposited after the magma ocean evolved to ilmenite saturation had vastly higher TiO₂ contents than cumulates deposited shortly before. The YQ regolith's subequal proportions of mare and highland matter are consistent with derivation from a terrain close to a mare-highland boundary. However, a similar mixture might also develop through vertical mixing in a cryptomare or a region of thin mare coverage. Thus, unfortunately, the YQ bulk composition is not a very useful clue to the identity of the source crater.     

Effect of chlorine on near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 at 1 GPa: Implication for volatile‐induced melting of the Martian mantle

Martian magmas are thought to be rich in chlorine compared with their terrestrial counterparts. Here, we experimentally investigate the effect of chlorine on liquidus depression and near‐liquidus crystallization of olivine‐phyric shergottite NWA 6234 and compare these results with previous experimental results on the effect of chlorine on near‐liquidus crystallization of the surface basalts Humphrey and Fastball. Previous experimental results showed that the change in liquidus temperature is dependent on the bulk composition of the basalt. The effect of chlorine on liquidus depression is greater for lower SiO₂ and higher Al₂O₃ magmas than for higher SiO₂ and lower Al₂O₃ magmas. The bulk composition for this study has lower Al₂O₃ and higher FeO contents than previous work; therefore, we provide additional constraints on the effect of the bulk composition on the influence of chlorine on near‐liquidus crystallization. High pressure and temperature crystallization experiments were performed at 1 GPa on a synthetic basalt, of the bulk composition of NWA 6234, with 0–4 wt% Cl added to the sample as AgCl. The results are consistent with previous notions that with increasing wt% Cl in the melt, the crystallization temperature decreases. Importantly, our results have a liquidus depression ?T (°C) from added chlorine that is consistent with the difference in bulk composition and suggest a dependence on both the bulk Al₂O₃ and FeO content. Our results suggest that the addition of chlorine to the Martian mantle may lower magma genesis temperatures and potentially aid in the petrogenesis of Martian magmas.     

Earliest high-Ti volcanism on the Moon: 40Ar-39Ar,Sm-Nd,and Rb-Sr isotopic studies of Group D basalts from the Apollo 11 landing site

Abstract High-Ti basalts from the Apollo collections span a range in age from 3.87 Ga to 3.55 Ga. The oldest of these are the common Apollo 11 Group B2 basalts which yield evidence of some of the earliest melting of the lunar mantle beneath Mare Tranquillitatis. Rare Group D high-Ti basalts from Mare Tranquillitatis have been studied in an attempt to confirm a postulated link with Group B2 basalts (Jerde et al., 1994). The initial Sr isotopic ratio of a known Group D basalt (0.69916 ± 3 at 3.85 Ga) lies at the lower end of the tight range for Group B2 basalts (⁸⁷Sr/⁸⁶Sr = 0.69920 to 0.69921). One known Group D basalt and a second postulated Group D basalt yield indistinguishable initial ?_Nd (1.2 ± 0.6 and 1.2 ± 0.3) and again lie at the lower end of the range for the Group B2 basalts from Apollo 11 (+2.0 ± 0.4 to +3.9 ± 0.6, at 3.85 Ga). A third sample has isotopic (⁸⁷Sr/⁸⁶Sr = 0.69932 ± 2; ?_Nd = 2.5 ± 0.4; at 3.59 Ga; as per Snyder et al., 1994b) and elemental characteristics similar to the Group A high-Ti basalts returned from the Apollo 11 landing site. Ages of ⁴⁰Ar-³⁹Ar have been determined for one known Group D basalt and a second postulated Group D basalt using step-heating with a continuous-wave laser. Suspected Group D basalt, 10002, 1006, yielded disturbed age spectra on two separate runs, which was probably due to ³⁹Ar recoil effects. Using the “reduced plateau age” method of Turner et al. (1978), the ages derived from this sample were 3898 ± 19 and 3894 ± 19 Ma. Three separate runs of known Group D basalt 10002, 116 yielded ⁴⁰Ar/³⁹Ar plateau ages of 3798 ± 9 Ma, 3781 ± 8 Ma, and 3805 ± 7 Ma (all errors 2σ). Furthermore, this sample has apparently suffered significant ⁴⁰Ar loss either due to solar heating or due to meteorite impact. The loss of a significant proportion of ⁴⁰Ar at such a time means that the plateau ages underestimate the “true” crystallization age of the sample. Modelling of this Ar loss yields older, “true” ages of 3837 ± 18, 3826 ± 16, and 3836 ± 14 Ma. These ages overlap the ages of Group B2 high-Ti basalts (weighted average age = 3850 ± 20 Ma; range in ages = 3.80 to 3.90 Ga). The combined evidence indicates that the Group D and B2 high-Ti basalts could be coeval and may be genetically related, possibly through increasing degrees of melting of a similar source region in the upper mantle of the Moon that formed >4.2 Ga ago. The Group D basalts were melted from the source first and contained 3–5×more trapped KREEP-like liquid than the later (by possibly only a few million years) Group B2 basalts. Furthermore, the relatively LREE- and Rb-enriched nature of these early magmas may lend credence to the idea that the decay of heat-producing elements enriched in the KREEP-like trapped liquid of upper mantle cumulates, such as K, U, and Th, could have initiated widespread lunar volcanism.     

Lunar thermal anomalies and internal heating

The evidence for the existence of the so-called linear thermal anomaly recently reported on the western margin of Mare Humorum is examined critically. Whether the anomalous cooling of Mare Humorum considered as a whole can be caused by internal heating is rejected on the basis of (1) the measured temperature differential compared to the environs observed during the lunar day, (2) the required temperature gradient, and (3) energy considerations compared to terrestrial heat flow. It is concluded that the observed hot spots are unlikely to be caused by internal heating.     

Basaltic fragments in lunar feldspathic meteorites: Connecting sample analyses to orbital remote sensing

Abstract– The feldspathic lunar meteorites contain rare fragments of crystalline basalts. We analyzed 16 basalt fragments from four feldspathic lunar meteorites (Allan Hills [ALHA] 81005, MacAlpine Hills [MAC] 88104/88105, Queen Alexandra Range [QUE] 93069, Miller Range [MIL] 07006) and utilized literature data for another (Dhofar [Dho] 1180). We compositionally classify basalt fragments according to their magma’s estimated TiO₂ contents, which we derive for crystalline basalts from pyroxene TiO₂ and the mineral‐melt Ti distribution coefficient. Overall, most of the basalt fragments are low‐Ti basalts (1–6% TiO₂), with a significant proportion of very‐low‐Ti basalts (<1% TiO₂). Only a few basalt clasts were high‐Ti or intermediate Ti types (>10% TiO₂ and 6–10% TiO₂, respectively). This distribution of basalt TiO₂ abundances is nearly identical to that obtained from orbital remote sensing of the moon (both UV‐Vis from Clementine, and gamma ray from Lunar Prospector). However, the distribution of TiO₂ abundances is unlike those of the Apollo and Luna returned samples: we observe a paucity of high‐Ti basalts. The compositional types of basalt differs from meteorite to meteorite, which implies that all basalt subtypes are not randomly distributed on the Moon, i.e., the basalt fragments in each meteorite probably represent basalts in the neighborhood of the meteorite launch site. These differences in basalt chemistry and classifications may be useful in identifying the source regions of some feldspathic meteorites. Some of the basalt fragments probably originate from ancient cryptomaria, and so may hold clues to the petrogenesis of the Moon’s oldest volcanism.     

Petrogenesis of Chang'E-5 young mare low-Ti basalts

The regolith samples returned by the Chang'E-5 mission (CE-5) contain the youngest radiometrically dated mare basaltic clasts, which provide an opportunity to elucidate the magmatic activities on the Moon during the late Eratosthenian. In this study, detailed petrographic observations and comprehensive geochemical analyses were performed on the CE-5 basaltic clasts. The major element concentrations in individual plagioclase grain of the CE-5 basalts may vary slightly from core to rim, whereas pyroxene has clear chemical zonation. The crystallization sequence of the CE-5 mare basalts was determined using petrographic and geochemical relations in the basaltic clasts. In addition, both fractional crystallization (FC) and assimilation and fractional crystallization models were applied to simulate the chemical evolution of melt equilibrated with plagioclase in CE-5 basalts. Our results reveal that the melt had a TiO₂ content of ~3 wt% and an Mg# of ~45 at the onset of plagioclase crystallization, suggesting a low-Ti parental melt of the CE-5 basalts. The relatively high FeO content (>14.5 wt%) in melt equilibrated with plagioclase could have resulted in extensive crystallization of ilmenite, unlike in Apollo low-Ti basalts. Furthermore, our calculations showed that the geochemical evolution of CE-5 basaltic melt could not have occurred in a closed system. On the contrary, the CE-5 basalts could have assimilated mineral, rock, and glass fragments that have higher concentrations of KREEP elements (potassium, rare earth elements, and phosphorus) in the regolith during magma flow on the Moon's surface. The presence of the KREEP signature in the CE-5 basalts is consistent with literature remote sensing data obtained from the CE-5 landing site. These KREEP-bearing fragments could originate from KREEP basaltic melts that may have been emplaced at the landing site earlier than the CE-5 basalts.     

Lunar gravity: apollo 15 doppler radio tracking

New detailed gravity measurements were obtained over a 10- to 70-km surface strip from ? 70° to + 70° long. during low-altitude orbits (≈ 12 km at periapsis). The trajectory path (Figure 1) went over the centers of both Maria Serenitatis and Crisium, providing a complete center gravity profile of two large mascons. Consistent with the previous results for Mare Nectaris and Mare Humorum, both Serenitatis and Crisium mascons are approximately disk-shaped near-surface mass anomalies of net uncompensated loading, 800 kg cm^?2. This strengthens Booker's contention that all mascons are approximately the same thickness. Also revealed for the first time are significant positive gravity measurements over mountain ranges - Apennines (near Hadley Mountain) and the Marius Hills. The data suggests that the Apennines have undergone some isostatic compensation, whereas the Marius Hills have not. The crater anomalies detected are all consistently negative as observed before, implying loss of mass from the impact event which formed them.     

Petrography and geochemistry of five new Apollo 16 mare basalts and evidence for post‐basin deposition of basaltic material at the site

Abstract— We present the petrography and geochemistry of five 2–4 mm basalt fragments from the Apollo 16 regolith. These fragments are 1) a high‐Ti vitrophyric basalt compositionally similar to Apollo 17 high‐Ti mare basalts, 2) a very high‐Ti vitrophyric basalt compositionally similar to Apollos 12 and 14 red‐black pyroclastic glass, 3) a coarsely crystalline high‐Al basalt compositionally similar to group 5 Apollo 14 high‐Al mare basalts, 4) a very low‐Ti (VLT) crystalline basalt compositionally similar to Luna 24 VLT basalts, and 5) a VLT basaltic glass fragment compositionally similar to Apollo 17 VLT basalts. High‐Ti basalt has been reported previously at the Apollo 16 site; the other basalt types have not been reported previously. As there are no known cryptomaria or pyroclastic deposits in the highlands near the Apollo 16 site (ruling out a local origin), and scant evidence for basaltic material in the Apollo 16 ancient regolith breccias or Apollo 16 soils collected near North Ray Crater (ruling out a basin ejecta origin), we infer that the basaltic material in the Apollo 16 regolith originated in maria near the Apollo 16 site and was transported laterally to the site by small‐ to medium‐sized post‐basin impacts. On the basis of TiO₂ concentrations derived from the Clementine UVVIS data, Mare Tranquillitatis (?300 km north) is the most likely source for the high‐Ti basaltic material at the Apollo 16 site (craters Ross, Arago, Dionysius, Maskelyne, Moltke, Sosigenes, Schmidt), Mare Nectaris/Sinus Asperitatis (?220 km east) is the most likely source for the low‐Ti and VLT basaltic material (craters Theophilus, Madler, Torricelli), and a large regional pyroclastic deposit near Mare Vaporum (?600 km northwest) is the most likely source region for pyroclastic material (although no source craters are apparent in the region).