Petrology, magnetostratigraphy and geochronology of the Miocene volcaniclastic Tepoztlán Formation: implications for the initiation of the Transmexican Volcanic Belt (Central Mexico)

The volcaniclastic Tepoztlán Formation (TF) represents an important rock record to unravel the early evolution of the Transmexican Volcanic Belt (TMVB). Here, a depositional model together with a chronostratigraphy of this Formation is presented, based on detailed field observations together with new geochronological, paleomagnetic, and petrological data. The TF consists predominantly of deposits from pyroclastic density currents and extensive epiclastic products such as tuffaceous sandstones, conglomerates and breccias, originating from fluvial and mass flow processes, respectively. Within these sediments fall deposits and lavas are sparsely intercalated. The clastic material is almost exclusively of volcanic origin, ranging in composition from andesite to rhyolite. Thick gravity-driven deposits and large-scale alluvial fan environments document the buildup of steep volcanic edifices. K-Ar and Ar-Ar dates, in addition to eight magnetostratigraphic sections and lithological correlations served to construct a chronostratigraphy for the entire Tepoztlán Formation. Correlation of the 577 m composite magnetostratigraphic section with the Cande and Kent (1995) Geomagnetic Polarity Time Scale (GPTS) suggests that this section represents the time intervall 22.8–18.8 Ma (6Bn.1n-5Er; Aquitanian-Burdigalian, Lower Miocene). This correlation implies a deposition of the TF predating the extensive effusive activity in the TMVB at 12 Ma and is therefore interpreted to represent its initial phase with predominantly explosive activity. Additionally, three subdivisions of the TF were established, according to the dominant mode of deposition: (1) the fluvial dominated Malinalco Member (22.8–22.2 Ma), (2) the volcanic dominated San Andrés Member (22.2–21.3 Ma) and (3) the mass flow dominated Tepozteco Member (21.3–18.8 Ma).     

An integrated magnetic,geochemical and archeointensity investigation of casting debris from ancient metallurgical sites of Michoacán,Western Mesoamerica

The ability of baked clay-elaborated objects to record the temporal variations of both direction and intensity of the geomagnetic field at the time of their elaboration or last use has been widely used during the last decades to fill the gaps left by available time-discrete volcanic-rock logs for a better knowledge of the evolution of the geomagnetic field. Further refinement of the secular variation curves has motivated the search for alternative non-conventional materials as attractive targets for archeomagnetic studies. Both clay and copper have been used since pre-Hispanic times for the elaboration of a wide variety of ornamental and utilitarian objects in Mesoamerica. Previous studies carried out in Europe and Israel have shown the usefulness of copper slags as one of these non-conventional materials. We present the results of an integrated study carried out on ten copper slags from seven ancient metallurgical sites of Michoacán. The analysis included a series of rock magnetism experiments, scanning electron microscope analysis, archeointensity determinations following the Thellier-Coe method and their corresponding dating. Based on the results obtained the slag-set analyzed can be divided in two main groups: low Fe concentrations (associated with high Cu concentrations) for slags comprising the first group, and high Fe concentrations (associated with low Cu concentrations) for slags from second group. Slags from the first group are characterized by almost reversible thermomagnetic curves, while those corresponding to the second group show a quite irreversible behavior. A crystalline (vitreous) structure within the massive surface of the slags is observed for those coming from the second (first) group. These striking features could reflect significant differences in the metallurgical process followed at these sites, which according to archeological and historical evidences correspond to Colonial and pre-Hispanic usage metallurgical sites; first and second group, respectively. The good experimental behavior exhibited by these materials demonstrates the suitability of copper slag to obtaining absolute archeointensity data which can be used to improve the existing Mesoamerican archeomagnetic record. This in turn, can be used both for geomagnetic field modelling purposes and archeomagnetic dating.     

Space–time evolution of monogenetic volcanism in the mafic Garrotxa Volcanic Field (NE Iberian Peninsula)

We reconstructed the evolution of the volcanic activity within the central Garrotxa monogenetic Volcanic Field, the youngest volcanic area of the Iberian Peninsula, by investigating the stratigraphy of the volcanic successions and the morphology of the monogenetic eruptive centres. Analysis of this volcanic succession has been conducted following the Unconformity Bounded Stratigraphic Units criteria. The detailed stratigraphy of the volcanic successions shows that the central Garrotxa Volcanic Field (GVF) evolved through four main periods of volcanic activity (Synthems) represented by the eruptive products of the mafic monogenetic volcanoes and associated syn-eruptive reworked deposits (Eruptive Units) and by the inter-eruptive deposits (Epiclastic Units). The distribution and the morphologies of the monogenetic volcanoes suggest that feeder dykes were emplaced under influence of the present stress filed and along pre-existing fractures of the basement. Our facies analysis of the deposits and their distribution shows that migration of volcanism toward the centre of the basin was accompanied by a trend of increasing explosivity. Episodic hydromagmatism in central Garrotxa occurred without a specific geographic locus or obvious temporal correlation. Finally, by integrating field data with the stratigraphy extracted from water wells, we determined the volume of the volcanic deposits. The small average volume of products emitted during each eruptive period, and the long quiescence separating them, allow us to classify the GVF as a low-output rate volcanic field.     

Reconstruction of the volcanic history of the Tacámbaro-Puruarán area (Michoacán, México) reveals high frequency of Holocene monogenetic eruptions

The 690?km² Tacámbaro-Puruarán area located at the arc-front part of the Michoácan-Guanajuato volcanic field in the Trans-Mexican Volcanic Belt (TMVB) records a protracted history of volcanism that culminated with intense monogenetic activity in the Holocene. Geologic mapping, ⁴⁰Ar/³⁹Ar and ¹⁴C radiometric dating, and whole-rock chemical analyses of volcanic products provide insights to that history. Eocene volcanics (55–40?Ma) exposed at uplifted blocks are related to a magmatic arc that preceded the TMVB. Early TMVB products are represented by poorly exposed Pliocene silicic domes (5–2?Ma). Quaternary (<2?Ma) volcanoes (114 mapped) are mainly scoria cones with lavas (49 vol.%), viscous lava flows (22 vol.%), and lava shields (22 vol.%). Erupted products are dominantly either basaltic andesites (37 vol. %), or andesites (17 vol.%), or span across both compositions (28 vol.%). Basalts (9 vol.%), dacites (4 vol.%), shoshonites (2 vol.%), and other alkali-rich rocks (<3 vol.%) occur subordinately. Early-Pleistocene volcanism was bimodal (dacites and basalts) and voluminous while since 1?Ma small-volume eruptions of intermediate magmas have dominated. Higher rates of lithospheric extension in the Quaternary may have allowed a larger number of small, poorly evolved dikes to reach the surface during this period. Eruptive centers as old as 1.7?Ma are aligned in a NE direction parallel to both, basement faults and the direction of regional compressive stress, implying structural control on volcanic activity. Data suggest that volcanism was strongly pulsatory and fed by localized low-degree partial melting of mantle sources. In the Holocene, at least 13 eruptions occurred (average recurrence interval of 800?years). These produced ~3.8?km³ of basaltic andesitic to andesitic magma and included four eruptions dated at ~1,000; 4,000; 8,000; and 11,000?years bc (calibrated ¹⁴C ages). To date, this is one of the highest monogenetic eruption frequencies detected within such a small area in a subduction-related arc-setting. These anomalous rates of monogenetic activity in an area with thick crust (>30?km) may be related to high rates of magma production at depth and a favorable tectonic setting.     

Increased winter-spring precipitation from the last glaciation to the Holocene inferred from a δ~(13)C_(org) record from Yili Basin(Xinjiang,NW China)

The nature and dynamics of climate change in central Asia since the late Pleistocene are controversial. Moreover,most of the published studies focus mainly on the evolution of moisture conditions, and there have been few attempts to address changes in seasonality. In this study, records of δ¹³C_org, TOC, TN, C/N and grain size were obtained from lacustrine sediments at Yili Basin, Xinjiang, NW China. Our aim was to reconstruct the trend in seasonality of precipitation from the last glaciation to the Holocene. The organic matter content of the sediments is derived predominantly from terrestrial plants. The δ¹³C_orgvalues vary from-19.4‰ to-24.8‰, indicating that the vegetation was dominated by C_3 plants. Winter-spring precipitation is identified as the factor determining the relative proportions of C_3 and C_4 plants in the region. A negative trend in δ¹³C_orgcorresponding to an increase in the relative abundance of C_3 plants indicate a trend of increasing winter-spring precipitation from the last glaciation to the Holocene. The increased incidence of wintertime storms in the interior of Asia is suggested to result in the increase of winterspring precipitation in the Holocene.     

Volcanic history of El Chichón Volcano (Chiapas, Mexico) during the Holocene, and its impact on human activity

2 abundance and depletion in MgO, CaO, TiO₂, as well as trace and rare earth elements. This suggests segregation of olivine and orthopyroxene from the melt. Since human settlements in southeast Mexico and Central America can be traced as far back as approximately 2500 years BP, most of these events probably affected human activity. In fact, there are reports of pottery shards and other artifacts in deposits from the eruption of 1250 BP. Pottery fragments in deposits of an eruption that took place 2500 BP are also reported in this paper. Thus, the impact of the volcano on human activities has been frequent, with most of the repose intervals lasting between 100 to 600 years. The impact of the eruptions was probably of greater than local extent, because airfall tephra could reach distant sites and possibly even affect weather. The eruptive history of El Chichón also offers clues in the investigation of the Maya civilization. Several researchers have considered the volcano as an important factor in the answer to some intriguing questions such as the extensive use of volcanic ash in Late Classic Maya ceramics or, of greater importance, the causes of the collapse of the Classic Maya civilization. Received : 4 May 1998 / Accepted: 1 November 1999     

Anomalous directions and paleointensity of the geomagnetic field based on paleomagnetic investigations of rocks from the Karadzha Range (Azerbaijan) of the age 45–20 ka

Paleomagnetic investigations of marine and subaqueous deposits in the 12-meter marine terrace of a section of the Karadzha Range (Azerbaijan) are performed. These deposits correspond to OI stage 3 and encompass the time interval ～45–20 ka. Four anomalous deviations of the magnetization from the dipole field at the sampling site are recorded in the upper and lower transgressive members of deposits. Investigations of the influence of the anisotropy of the magnetic susceptibility (AMS) on directions of the natural remanent magnetization (NRM) showed that only three of the four identified intervals can actually reflect geomagnetic field changes. The fourth interval of the anomalous NRM behavior is recorded in samples demonstrating the presence of the identified AMS direction pointing to a possible deformation of layers, which could turn the NRM vector toward the direction of the acting factor. Based on the age of the terrace under investigation, three other anomalous horizons could correspond to heavily reduced records of the Mono and Lashamp excursions of the geomagnetic field.     

Late Pleistocene and Holocene activity of the Atacazo–Ninahuilca Volcanic Complex (Ecuador)

The Atacazo–Ninahuilca Volcanic Complex (ANVC) is located in the Western Cordillera of Ecuador, 10 km southwest of Quito. At least six periods of Pleistocene to Holocene activity (N1 to N6) have been preserved in the geologic record as tephra fallouts and pyroclastic flow deposits. New field data, including petrographic and whole-rock geochemical analyses of over forty soil and tephra sections, 100 pumice and lithic samples, and 10 new ¹⁴C ages allow us to constrain: (1) the tephra fall isopachs and detailed characteristics of the last two events (N5–N6) including volume estimates of the tephra and pyroclastic flow deposits and the corresponding volcanic explosivity index (VEI); (2) the petrographical and geochemical correlations between domes, tephras, and pyroclastic flow deposits; and, (3) the timing of the last 4 eruptive events and a period of quiescence that endured a few thousand years (1000–4000).     

Wavelet analysis of paleomagnetic data: 4. Characteristic short times (0.4–4.5 ky) of variations in the elements of the geomagnetic field during the early Jaramillo reversal and in the stationary field during the Matuyama and Jaramillo chrons (Western Turkmenia)

The geomagnetic variations with characteristic times ranging from 0.4 to 15 ka are shown to be largely stochastic. Variations with different characteristic times appear during different time intervals and reflect accelerating and decelerating processes. The variations do not exhibit any predominant times. At the same time, almost periodic variations in the lithological characteristics are clearly seen in the wavelet diagrams of the parameters that reflect the changes in the composition (quantitative and qualitative) of ferrimagnetic material; i.e., the changes in the conditions of sedimentation related to climate variations. The variations with periods of 5, 8.5, and 13 ka are concurrent with the similar variations in the paleomagnetic data, while the variations with a period of 3.5 ka are only observed in the magnetic parameters. We suggest that the first mentioned oscillations reflect the changes of the external (relative to the Earth) origin, whereas the changes with a period of 3.5 ka are caused by some terrestrial factors.     

Peraluminous igneous rocks as an indicator of thermogenic methane release from the North Atlantic Volcanic Province at the time of the Paleocene–Eocene Thermal Maximum (PETM)

Unusual cordierite-bearing peraluminous dacites, produced by melting of organic-rich sediments by intrusion of basaltic magma, are found within the North Atlantic Volcanic Province (NAVP). Calculations suggest that formation of the dacites, radiometric dated at 55.9?±?0.3 Ma and possibly widespread, could have released an average of ～4,500 Gt (range from 3,000 to 6,000 Gt) of carbon as methane, with a δ¹³C of about ?35‰. Published model results suggest that such a methane release could explain the negative δ¹³C excursion in the oceans and atmosphere, the extreme global warming, and the marked dissolution of carbonates in the deep oceans that accompanied the concurrent Paleocene–Eocene Thermal Maximum (PETM). Outgassing from melting of sediments and formation of dacites, possibly in conjunction with methane produced in contact metamorphic aureoles and by methane hydrate release, provides a novel way of explaining the PETM and its timing.     

Ground deformation effects from the ~M6 earthquakes (2014–2015) on Cephalonia–Ithaca Islands (Western Greece) deduced by GPS observations

The implications of the earthquakes that took place in the central Ionian Islands in 2014 (Cephalonia, M _w6.1, M _w5.9) and 2015 (Lefkas, M _w6.4) are described based on repeat measurements of the local GPS networks in Cephalonia and Ithaca, and the available continuous GPS stations in the broader area. The Lefkas earthquake occurred on a branch of the Cephalonia Transform Fault, affecting Cephalonia with SE displacements gradually decreasing from north (~100 mm) to south (~10 mm). This earthquake revealed a near N–S dislocation boundary separating Paliki Peninsula in western Cephalonia from the rest of the island, as well as another NW–SE trending fault that separates kinematically the northern and southern parts of Paliki. Strain field calculations during the interseismic period (2014–2015) indicate compression between Ithaca and Cephalonia, while extension appears during the following co-seismic period (2015–2016) including the 2015 Lefkas earthquake. Additional tectonically active zones with differential kinematic characteristics were also identified locally.     

Pyroclastic flow deposits of the 1991 eruption of Volcán de Colima,Mexico

The April 16, 1991, eruption of Volcán de Colima represents a classical example of partial dome collapse with the generation of progressively longer-runout, Merapi-type pyroclastic flows that traveled up to 4 km along the El Cordoban gullies (East, Central and West). The flows filled the gullies with block-and-ash flow deposits up to 10 m thick, of which, after 7 years of erosion, only remnants remained in the El Cordoban West and East gullies. The El Cordoban Central gully, however, provided a well-preserved and incised longitudinal section of the 1991 deposits. The deposits were emplaced as proximal and distal facies, separated by a change in slope angle from >30° to <20°. The proximal facies consists of massive, clast-supported flow units (up to 1 m thick) with andesite blocks locally supported by a matrix of coarse ash and devoid of segregation structures or grading. The distal facies consists of a massive, matrix-supported deposit up to 8 m thick, which contains dispersed andesite blocks in a fine ash matrix. In the distal facies, a train of blocks marks flow-unit upper boundaries and, although sorting is poor, some grading is present. Thin, finely stratified, or dune-bedded layers of fine ash material are locally present above or below units of both facies. Sedimentologic parameters show that the size or fraction of large pyroclasts (larger than –1 ) decreases from proximal to distal facies, as the percentage of matrix (0 to 4 ) increases, especially immediately beyond the break in slope. We propose that the propagation of the Colima pyroclastic flows is critically dependent on local slope angle, the presence of erodible slope debris, and the decrease in grain size with distance from the vent. The progressive fining is probably caused by some combination of erosion, clast breakup and deposition of larger pyroclasts, and is itself influenced by the slope angle. In the proximal region, the flows moved as granular avalanches, in which interacting grains ground each other and erosion occurred to produce an overriding dilute ash cloud. The maximum runout distance of the avalanches was controlled by the angle of repose of the material, and the volume and grain size of source and eroded material. Because the slope angle is close to the repose angle for this debris, granular avalanches were not able to propagate far beyond the change in slope. If, however, an avalanche had enough mass in finer grain size fractions, at least part of the flow continued beyond the break in slope and across the volcano apron, propagating in a turbulent state and depositing surge layers, or in an otherwise settling-modified state and depositing block-and-ash flow layers.Editorial responsibility: T Druitt     

PCB-containing paint and plaster caused extreme PCB-concentrations in biota from the Sørfjord (Western Norway)--a case study

The Sørfjord (Western Norway) has a long history of industry and pollution, and has been monitored for several decades. The environmental monitoring has comprised analyses of different contaminants in sea water, mussel, fish, seaweed and sediments. Measurements of polychlorinated biphenyls (PCBs) in blue mussels (Mytilus edulis) some 17 years ago indicated a local source. In 2001 severe concentrations were measured in blue mussels and further investigations disclosed the primary source of PCBs in the Sørfjord. In 2002, extreme PCB-concentrations were found in cod (Gadus morhua) from the same area. However, no induction of EROD activity was detected, indicating the limitations of this assay as marker for PCB contamination. A future scientific challenge will be to understand the specific mechanisms and effects of such PCB accumulation in fish.     

Stress Analyses in the Epicentral Area of Nový Kostel (Western Bohemia)

The focal mechanisms of events from three micro-earthquake swarms (swarm in the years 1985/86, swarm of December 1994, and swarm of January 1997) in the epicentral area of Nový Kostel (West Bohemia region) were used as input data for stress analyses. The simple graphical method of Angelier and Mechler (1977) and inversion by the program BRUTE3 (Hardcastle and Hills, 1993) were applied to the data collections. The results of the stress analyses for the 1985/86 swarm and for the swarm of December 1994 are similar. For the January 1997 swarm, the results of the analyses differ from those for older swarms. The axis of maximum extension is oriented in the NE-SW direction and is subhorizontal, the axis of maximum compression is oriented in the NW-SE direction and perspicuously dips towards SE. These results are similar to older results of stress analyses carried out for the 1985/86 swarm (Antonini, 1988; Sonnleitner,1993). They are also consistent with most of other published results of stress analyses conducted at different sites in the western part of the Bohemian Massif. The orientation of the principal stresses confirms the sinistral strike-slip movement along the Nový Kostel-Poátky-Zwota line (the trend is about 355°) defined by the epicentres of the micro-earthquakes. The eastern tectonic limit of the Cheb Basin (and other respective parallel faults ) could be characterised by normal rather than strike-slip faulting.